JP6927929B2 - 耐火性樹脂組成物 - Google Patents
耐火性樹脂組成物 Download PDFInfo
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- JP6927929B2 JP6927929B2 JP2018134663A JP2018134663A JP6927929B2 JP 6927929 B2 JP6927929 B2 JP 6927929B2 JP 2018134663 A JP2018134663 A JP 2018134663A JP 2018134663 A JP2018134663 A JP 2018134663A JP 6927929 B2 JP6927929 B2 JP 6927929B2
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- 229910000165 zinc phosphate Inorganic materials 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
- 229960001763 zinc sulfate Drugs 0.000 description 1
- 229910000368 zinc sulfate Inorganic materials 0.000 description 1
- 229910052984 zinc sulfide Inorganic materials 0.000 description 1
- NDKWCCLKSWNDBG-UHFFFAOYSA-N zinc;dioxido(dioxo)chromium Chemical compound [Zn+2].[O-][Cr]([O-])(=O)=O NDKWCCLKSWNDBG-UHFFFAOYSA-N 0.000 description 1
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 1
- 229910000859 α-Fe Inorganic materials 0.000 description 1
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Description
亜鉛化合物を、金属量として、熱膨張性黒鉛100重量部に対して0.5〜10重量部、及び/または、マンガン化合物を、金属量として、熱膨張性黒鉛100重量部に対して0重量部超、0.5重量部以下含むことを特徴とする耐火性樹脂組成物。
の直鎖状あるいは分岐状のアルキル基、炭素数1〜16の直鎖状あるいは分岐状のアルコキシル基、炭素数6〜16のアリール基、または、炭素数6〜16のアリールオキシ基を表す。
スホン酸、ブチルホスホン酸、2−メチルプロピルホスホン酸、t−ブチルホスホン酸、2,3−ジメチル−ブチルホスホン酸、オクチルホスホン酸、フェニルホスホン酸、ジオクチルフェニルホスホネート、ジメチルホスフィン酸、メチルエチルホスフィン酸、メチルプロピルホスフィン酸、ジエチルホスフィン酸、ジオクチルホスフィン酸、フェニルホスフィン酸、ジエチルフェニルホスフィン酸、ジフェニルホスフィン酸、ビス(4−メトキシフェニル)ホスフィン酸等が挙げられる。中でも、t−ブチルホスホン酸は、高価ではあるが、高難燃性の点において好ましい。前記のリン化合物は、単独で用いても、2種以上を併用してもよい。
り、好ましくは65重量%以下である。斯かる数値範囲とすることで、優れた耐火性を発現することができる。
鉛100重量部に対して0重量部超、0.5重量部以下とすることで、膨張効率の向上、特に内部での膨張効率の向上を達成することができる。規定量以上に含まれると燃焼時の残さ形状保持力がわるくなる
CROS 487」等が挙げられる。シラン被覆ポリリン酸アンモニウム粒子の市販品としては、例えば、Budenheim Iberica社製「FR CROS 486」が挙げられる。
ジ−2−エチルヘキシルフタレート(DOP)、ジ−n−オクチルフタレート、ジイソノニルフタレート(DINP)、ジイソデシルフタレート(DIDP)、ジウンデシルフタレート(DUP)、または炭素原子数10〜13程度の高級アルコールまたは混合アルコールのフタル酸エステル等のフタル酸エステル系可塑剤;
ジ−2−エチルヘキシルアジペート、ジ−n−オクチルアジペート、ジ−n−デシルアジペート、ジイソデシルアジペート、ジ−2−エチルヘキシルアゼレート、ジブチルセバケート、ジ−2−エチルヘキシルセバケート等の脂肪族二塩基酸エステル系可塑剤;
トリ−2−エチルヘキシルトリメリテート(TOTM)、トリ−n−オクチルトリメリテート、トリデシルトリメリテート、トリイソデシルトリメリテート、ジ−n−オクチル−n−デシルトリメリレート等のトリメリット酸エステル系可塑剤;
アジピン酸ジ−2−エチルヘキシル(DOA)およびアジピン酸ジイソデシル(DIDA)等のアジピン酸エステル系可塑剤;
セバシン酸ジブチル(DBS)およびセバシン酸ジ−2−エチルヘキシル(DOS)等のセバシン酸エステル系可塑剤;
トリブチルホスフェート、トリオクチルホスフェート、オクチルジフェニルホスフェート、トリブトキシエチルホスフェート、トリクロロエチルホスフェート、トリス(2−クロロプロピル)ホスフェート、トリス(2,3−ジクロロプロピル)ホスフェート、トリス(2,3−ジブロモプロピル)ホスフェート、トリス(ブロモクロロプロピル)ホスフェート、ビス(2,3−ジブロモプロピル)−2,3−ジクロロプロピルホスフェート、ビス(クロロプロピル)モノオクチルホスフェート等のリン酸エステル系可塑剤;
2,3,3',4'−ビフェニルテトラカルボン酸テトラヘプチルエステル等のビフェニルテトラカルボン酸テトラアルキルエステル系可塑剤;
ポリエステル系高分子可塑剤;
エポキシ化大豆油、エポキシ化亜麻仁油、エポキシ化綿実油、液状エポキシ樹脂等のエポキシ系可塑剤;
塩素化パラフィン;
五塩化ステアリン酸アルキルエステル等の塩素化脂肪酸エステル;および
パラフィン系プロセスオイル、ナフテン系プロセスオイル、芳香族系プロセスオイルなどのプロセスオイル等。
枠は2つの内枠2と、内枠2を包囲する1つの外枠3とを有し、内枠2および外枠3の枠本体の各辺に沿って、内枠2および外枠3の内部に耐火性樹脂成形体3が取り付けられている。このようにして、本発明の耐火性樹脂成形体3を設けることにより、窓1に耐火性を付与することができる。
が挙げられる。
[実施例1]
表1に示した配合量で、合成樹脂としてポリ塩化ビニル100重量部、可塑剤としてジイソデシルフタレート(DIDP)100重量部、熱膨張性黒鉛(東ソー社製「GREP−EG」)100重量部、無機充填剤として炭酸カルシウム100重量部及び二酸化マンガン0.1重量部を130℃下、ニーダーにて混合した。混合後、その混合物をカレンダーロールにてシート化に成型し、幅150mm、厚さ1.5mm、長さ50cmの耐火性樹脂成形体としての耐火シートを得た。
[実施例2〜20、比較例1]
実施例2〜20および比較例1についても、表1〜3に示した配合量で成分を混合および押出成形し、耐火シートを得た。
得られた耐火シートから作製した試験片(長さ100mm、幅100mm、厚さ1.5mm)を電気炉に供給し、600℃で30分間加熱した後、試験片の厚さを測定し、(加熱後の試験片の厚さ)/(加熱前の試験片の厚さ)を膨張倍率として算出した。
Claims (3)
- マトリックス成分と、熱膨張性黒鉛及び無機充填材を含む耐火性樹脂組成物において、前記マトリックス成分がゴムを含み、
マンガン化合物を、金属量として、熱膨張性黒鉛100重量部に対して0重量部超、0.5重量部以下含み、
リン化合物を含まないことを特徴とする耐火性樹脂組成物。 - 請求項1に記載の耐火性樹脂組成物よりなる耐火性樹脂成形体。
- 請求項2に記載の耐火性樹脂成形体を備えた建具。
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