JP6923508B2 - 表面の汚れを除去するための、液体洗浄組成物におけるグリコールエーテル溶媒 - Google Patents
表面の汚れを除去するための、液体洗浄組成物におけるグリコールエーテル溶媒 Download PDFInfo
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- JP6923508B2 JP6923508B2 JP2018501938A JP2018501938A JP6923508B2 JP 6923508 B2 JP6923508 B2 JP 6923508B2 JP 2018501938 A JP2018501938 A JP 2018501938A JP 2018501938 A JP2018501938 A JP 2018501938A JP 6923508 B2 JP6923508 B2 JP 6923508B2
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- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 125000002252 acyl group Chemical group 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 125000005210 alkyl ammonium group Chemical group 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000001099 ammonium carbonate Substances 0.000 description 1
- 235000012501 ammonium carbonate Nutrition 0.000 description 1
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 235000003704 aspartic acid Nutrition 0.000 description 1
- 229960005261 aspartic acid Drugs 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- OQFSQFPPLPISGP-UHFFFAOYSA-N beta-carboxyaspartic acid Natural products OC(=O)C(N)C(C(O)=O)C(O)=O OQFSQFPPLPISGP-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000000872 buffer Substances 0.000 description 1
- 230000003139 buffering effect Effects 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 229960004203 carnitine Drugs 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 150000001767 cationic compounds Chemical class 0.000 description 1
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 description 1
- 229940073507 cocamidopropyl betaine Drugs 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000000306 component Substances 0.000 description 1
- 229920013750 conditioning polymer Polymers 0.000 description 1
- 239000013256 coordination polymer Substances 0.000 description 1
- 235000005687 corn oil Nutrition 0.000 description 1
- 239000002285 corn oil Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 125000006165 cyclic alkyl group Chemical group 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- 229940008099 dimethicone Drugs 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 1
- 235000021186 dishes Nutrition 0.000 description 1
- PXEDJBXQKAGXNJ-QTNFYWBSSA-L disodium L-glutamate Chemical compound [Na+].[Na+].[O-]C(=O)[C@@H](N)CCC([O-])=O PXEDJBXQKAGXNJ-QTNFYWBSSA-L 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- 229940071106 ethylenediaminetetraacetate Drugs 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 229940013317 fish oils Drugs 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 210000004907 gland Anatomy 0.000 description 1
- 229960002989 glutamic acid Drugs 0.000 description 1
- 235000013922 glutamic acid Nutrition 0.000 description 1
- 239000004220 glutamic acid Substances 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 229960002449 glycine Drugs 0.000 description 1
- 159000000011 group IA salts Chemical class 0.000 description 1
- 239000003966 growth inhibitor Substances 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 150000007529 inorganic bases Chemical class 0.000 description 1
- 229910001411 inorganic cation Inorganic materials 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 229940116335 lauramide Drugs 0.000 description 1
- 229940094506 lauryl betaine Drugs 0.000 description 1
- IZWSFJTYBVKZNK-UHFFFAOYSA-N lauryl sulfobetaine Chemical compound CCCCCCCCCCCC[N+](C)(C)CCCS([O-])(=O)=O IZWSFJTYBVKZNK-UHFFFAOYSA-N 0.000 description 1
- 229910003002 lithium salt Inorganic materials 0.000 description 1
- 159000000002 lithium salts Chemical class 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 229910001425 magnesium ion Inorganic materials 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- 229920003145 methacrylic acid copolymer Polymers 0.000 description 1
- 150000002740 methanolamines Chemical class 0.000 description 1
- 150000004702 methyl esters Chemical class 0.000 description 1
- 239000003094 microcapsule Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 235000013923 monosodium glutamate Nutrition 0.000 description 1
- QEALYLRSRQDCRA-UHFFFAOYSA-N myristamide Chemical compound CCCCCCCCCCCCCC(N)=O QEALYLRSRQDCRA-UHFFFAOYSA-N 0.000 description 1
- HTBSGBIWKJSAGD-UHFFFAOYSA-N n,n-dimethylpropan-1-amine oxide Chemical class CCC[N+](C)(C)[O-] HTBSGBIWKJSAGD-UHFFFAOYSA-N 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- DVEKCXOJTLDBFE-UHFFFAOYSA-N n-dodecyl-n,n-dimethylglycinate Chemical compound CCCCCCCCCCCC[N+](C)(C)CC([O-])=O DVEKCXOJTLDBFE-UHFFFAOYSA-N 0.000 description 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 229960002446 octanoic acid Drugs 0.000 description 1
- 235000014593 oils and fats Nutrition 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 235000021313 oleic acid Nutrition 0.000 description 1
- 150000007530 organic bases Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000001139 pH measurement Methods 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- 239000011049 pearl Substances 0.000 description 1
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- 230000002085 persistent effect Effects 0.000 description 1
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 239000011970 polystyrene sulfonate Substances 0.000 description 1
- 229960002796 polystyrene sulfonate Drugs 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- CHWRSCGUEQEHOH-UHFFFAOYSA-N potassium oxide Chemical compound [O-2].[K+].[K+] CHWRSCGUEQEHOH-UHFFFAOYSA-N 0.000 description 1
- 229910001950 potassium oxide Inorganic materials 0.000 description 1
- 239000002516 radical scavenger Substances 0.000 description 1
- 230000003716 rejuvenation Effects 0.000 description 1
- 239000013557 residual solvent Substances 0.000 description 1
- 229960004889 salicylic acid Drugs 0.000 description 1
- FSYKKLYZXJSNPZ-UHFFFAOYSA-N sarcosine Chemical compound C[NH2+]CC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-N 0.000 description 1
- 230000037307 sensitive skin Effects 0.000 description 1
- 229940073490 sodium glutamate Drugs 0.000 description 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- 229910001948 sodium oxide Inorganic materials 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 229940117986 sulfobetaine Drugs 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 239000000375 suspending agent Substances 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- ILJSQTXMGCGYMG-UHFFFAOYSA-N triacetic acid Chemical compound CC(=O)CC(=O)CC(O)=O ILJSQTXMGCGYMG-UHFFFAOYSA-N 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2068—Ethers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B1/00—Cleaning by methods involving the use of tools
- B08B1/10—Cleaning by methods involving the use of tools characterised by the type of cleaning tool
- B08B1/14—Wipes; Absorbent members, e.g. swabs or sponges
- B08B1/143—Wipes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/75—Amino oxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0026—Low foaming or foam regulating compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0094—High foaming compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/43—Solvents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
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- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
- Cleaning By Liquid Or Steam (AREA)
Description
本明細書で記載されるグリコールエーテル溶媒は、疎水性汚れ、特に、動物又は植物源に由来している油、脂肪、及びポリマーグリース、とりわけ植物油を含む汚れの除去の改善を提供する。グリコールエーテル溶媒は、式1又は式2のグリコールエーテルから選択される。
式1:R1O(R2O)nR3
(式中、
R1は直鎖又は分枝鎖C4、C5、又はC6アルキル、又は置換又は非置換フェニルであり、好ましくはn−ブチルであり(ベンジルは、本明細書で用いる置換フェニルの1つである)、
R2はエチル又はイソプロピルであり、好ましくはイソプロピルであり、
R3は水素又はメチルであり、好ましくは水素であり、
nは1、2又は3であり、好ましくは1又は2である)
式2:R4O(R5O)mR6
(式中、
R4はn−プロピル又はイソプロピルであり、好ましくはn−プロピルであり、
R5はイソプロピルであり、
R6は水素又はメチルであり、好ましくは水素であり、
mは1、2又は3であり、好ましくは1又は2である)
本発明で使用するための液体洗浄組成物は、本明細書に記載したグリコールエーテル溶媒を含む。
液体洗浄組成物は界面活性剤を含む。液体洗浄組成物は3重量%を超える界面活性剤を含むことが好ましい。組成物は、組成物の3重量%〜60重量%、より好ましくは5重量%〜50重量%、そして最も好ましくは8重量%〜40重量%の量で界面活性剤を含むのが好ましい。
アニオン性界面活性剤としては、その分子構造中に一般に8〜22個の炭素原子又は一般に8〜18個の炭素原子を含む有機疎水基と、水溶性化合物を形成するための、好ましくはスルホネート、サルフェート、及びカルボキシレートから選択される少なくとも1つの水可溶化基と、を含有する、界面活性化合物が挙げられるが、これらに限定されない。通常、疎水基は、C8〜C22のアルキル又はアシル基を含む。このような界面活性剤は水溶性塩の形態で用いられ、塩形成カチオンは通常、ナトリウム、カリウム、アンモニウム、マグネシウム、及びモノ、ジ又はトリC2〜C3アルカノールアンモニウムから選択され、ナトリウムが通常選択されるカチオンである。
重量平均アルコキシル化度=(x1*界面活性剤1のアルコキシ化度+x2*界面活性剤2のアルコキシ化度+...)/(x1+x2+...)
式中、x1、x2、...は、混合物の各アニオン性界面活性剤のグラム単位の重量であり、アルコキシ化度は、各アニオン性界面活性剤のアルコキシ基の数である。
分枝の重量平均(%)=[(x1*アルコール1中の分枝アルコール1の重量%+x2*アルコール2中の分枝アルコール2の重量%+...)/(x1+x2+...)]*100
式中、x1、x2、...は、本発明の洗剤のアニオン性界面活性剤のための出発原料として使用したアルコールの全アルコール混合物中の各アルコールのグラム単位の重量である。重量平均分枝化度の計算において、分枝基を有さないアニオン性界面活性剤成分の重量も含める必要がある。
本明細書で使用するのに好適なサルフェート界面活性剤としては、C8〜C18のアルキル若しくはヒドロキシアルキル、サルフェート及び/又はエーテルサルフェートの水溶性塩が挙げられる。好適な対イオンとしては、アルカリ金属カチオン又はアンモニウム若しくは置換アンモニウムが挙げられるが、ナトリウムが好ましい。
本明細書に用いるのに好適なスルホネート界面活性剤としては、C8〜C18アルキル又はヒドロキシアルキルスルホネートの水溶性塩;国際公開第99/05243号、同第99/05242号、第99/05244号、同第99/05082号、同第99/05084号、同第99/05241号、同第99/07656号、同第00/23549号、及び同第00/23548号に論じられているような、C11〜C18アルキルベンゼンスルホネート(LAS)、修飾アルキルベンゼンスルホネート(MLAS);メチルエステルスルホネート(MES);並びにα−オレフィンスルホネート(AOS)が挙げられる。スルホネート界面活性剤としては、10〜20個の炭素原子を有するパラフィンのスルホン化により得られる、モノスルホネート及び/又はジスルホネートであり得るパラフィンスルホネートも挙げられる。スルホネート界面活性剤としては、アルキルグリセリルスルホネート界面活性剤も挙げられる。
好ましい両性界面活性剤としては、アミンオキシド界面活性剤が挙げられる。好ましいアミンオキシドは、アルキルジメチルアミンオキシド又はアルキルアミドプロピルジメチルアミンオキシド、より好ましくはアルキルジメチルアミンオキシド、そして特にはココジメチルアミノオキシドである。アミンオキシドは、線状又は中等度分枝状アルキル基を有し得る。典型的な直鎖アミンオキシドとしては、1)C8〜C18アルキル部位であるR1、並びに、2)C1〜3アルキル基及びC1〜3ヒドロキシアルキル基からなる群から選択されるR2及びR3部位、を含有する水溶性アミンオキシドが挙げられる。好ましくは、アミンオキシドは、式R1−N(R2)(R3)O(式中、R1はC8〜18アルキルであり、R2及びR3はメチル、エチル、プロピル、イソプロピル、2−ヒドロキシエチル、2−ヒドロキシプロピル、及び3−ヒドロキシプロピルからなる群から選択される)により特徴付けられる。直鎖アミンオキシド界面活性剤としては特に、直鎖C10〜C18アルキルジメチルアミンオキシド及び直鎖C8〜C12アルコキシエチルジヒドロキシエチルアミンオキシドを挙げることができる。好ましいアミンオキシドとしては、直鎖C10、直鎖C10〜C12、及び直鎖C12〜C14アルキルジメチルアミンオキシドが挙げられる。本明細書で使用するとき、「中鎖分枝状(mid-branched)」とは、アミンオキシドが、炭素原子n1個を有する1つのアルキル部分を有し、このアルキル部分上の1つのアルキル分枝が炭素原子n2個を有することを意味する。アルキル分枝は、アルキル部分の窒素のα炭素に位置する。アミンオキシドにおけるこのタイプの分枝は、当該技術分野において、内部アミンオキシドとしても知られている。n1とn2の合計は、10〜24個、好ましくは12〜20個、より好ましくは10〜16個の炭素原子である。1つのアルキル部分と1つのアルキル分枝とが対称となるように、1つのアルキル部分の炭素原子数(n1)は、1つのアルキル分枝の炭素原子数(n2)とおよそ同じであるべきである。本明細書で使用するとき、「対称」は、本明細書で用いられる中鎖分枝状アミンオキシドの少なくとも50重量%、より好ましくは少なくとも75重量%〜100重量%が、|n1〜n2|が5以下、好ましくは4、最も好ましくは0〜4の炭素原子であることを意味する。
他の好適な界面活性剤としては、アルキルベタイン、アルキルアミドベタイン、アミダゾリニウムベタイン、スルホベタイン(INCIスルタイン)並びにホスホベタインなどのベタインが挙げられ、好ましくは次の式(I)に合致する。
R1−[CO−X(CH2)n]x−N+(R2)(R3)−(CH2)m−[CH(OH)−CH2]y−Y−(I)式中、
R1は飽和又は不飽和C6〜22アルキル残基であり、好ましくはC8〜18アルキル残基、特に飽和C10〜16アルキル残基、例えば飽和C12〜14アルキル残基であり、
Xは、NH、C1〜4アルキル残基R4を有するNR4、O又はSであり、
nは、1〜10の数、好ましくは2〜5、特に3であり、
xは0又は1、好ましくは1であり、
R2、R3は独立して、ヒドロキシエチル、好ましくはメチルなどのヒドロキシ置換される可能性のあるC1〜4アルキル残基であり、
mは1〜4の数、特に1、2又は3であり、
yは0又は1であり、
YはCOO、SO3、OPO(OR5)O又はP(O)(OR5)Oであり、式中R5は水素原子H又はC1〜4アルキル残基である。
R1−N+(CH3)2−CH2COO- (Ia)
R1−CO−NH(CH2)3−N+(CH3)2−CH2COO-−( Ib)
R1−N+(CH3)2−CH2CH(OH)CH2SO3− (Ic)
R1−CO−NH−(CH2)3−N+(CH3)2−CH2CH(OH)CH2SO3−(Id)式中、R11は式Iにおけるものと同じ意味を有する。特に好ましいベタインはカルボベタイン[Y-=COO-]、特に式(Ia)及び(Ib)のカルボベタインであり、式(Ib)のアルキルアミドベタインがより好ましい。
キレート剤:液体洗浄組成物は、キレート化剤又は結晶成長抑制剤を含むことが好ましい。好適なキレート剤は、界面活性剤と組み合わせて、光沢効果、並びに、グリース及び漂白剤感受性汚れ等における特定の汚れ除去性能効果を改善する。より具体的には、水の硬度は、洗浄組成物による粒子の除去を困難にする可能性がある。キレート剤、特にアミノカルボキシレートキレート剤、より好ましくはグルタミン−N,N−二酢酸の塩からなる群から選択されるキレート剤は、疎水性汚れに固着する粒子状汚れの除去を改善するため、このような疎水性汚れの除去を改善する。
記載する液体洗浄組成物は、家庭の表面の洗浄に適している。特に、このような組成物は、汚れ、特に疎水性汚れ、そしてとりわけ、油、脂肪、ポリマーグリース、及びこれらの混合物からなる群から選択される疎水性汚れの除去に対して特に有用である。
A)pH測定:
pHは、取扱説明マニュアルに従って較正した、ゲル充填プローブ(Toledoプローブ(品番52 000 100)等)を備えたSartarius PT−10P pHメーターを使用して、20℃における10重量%の調製物の脱イオン水溶液として測定する。
20℃で、調製物100gと共に水酸化ナトリウム溶液を使用して組成物の1%溶液の滴定することにより、予備アルカリ度をpH7.0まで測定する。
20℃で、調製物100gと共に塩酸を使用して組成物の1%溶液を滴定することにより、予備酸性度をpH7.0まで測定する。
1 Huntsmanから市販されている直鎖アルキルベンゼンスルホン酸
2 Shellから市販されている非イオン性界面活性剤
3 Huntsmanから市販されているアミンオキシド非イオン性界面活性剤
4 SasolからIsofol 12(登録商標)として市販
5 Monsantoから入手可能なジエチレントリアミンペンタメチレンホスホネート
6 Dow Chemical Company製のドワノールPnP
7 Dow Chemical Company製のドワノールDPnP
8 Dow Chemical Company製のドワノールPnB
9 Dow Chemical Company製のドワノールDPnB
10 BASFから市販されているSokalan(登録商標)AT 120
0.15重量%のキサンタンガム(CP−kelco製のKeltrol(商標)RDを含有する水溶液(35g)を、光沢のある白色セラミックディッシュプレート(Ikeaより供給、製品:S.Pryle #13781、直径26.5cm)へと注いだ。
14 BASFから市販されている非イオン性界面活性剤
15 Sasolから市販されている非イオン性界面活性剤
16 Huntsmanから市販されている直鎖アルキルベンゼンスルホン酸ナトリウム
17 ICSから市販されているパラフィンスルホン酸ナトリウム
18 MC Intyreグループから市販されている両性界面活性剤
19 疎水変性ヒドロキシエチルセルロース(セチルヒドロキシエチルセルロール)
20 CP Kelcoから市販されているKelzan T
21 BASFから入手可能なジエチレントリアミンペンタアセテート
22 Akzo Nobelから市販されているグルタミン酸二酢酸四ナトリウム
23 JT Bakerから市販されているイソプロパノール
25 硫酸化Safol 23は、Sasolから市販されているアルコールのSafol 23をベースにした、硫酸化されている分枝状C12〜13サルフェート界面活性剤である
26 PVPは、ISP Corporationから市販されているビニルピロリドンホモポリマーである
Claims (19)
- 表面の疎水性汚れを処理するための、及び泡寿命(suds longevity)を付与するための、界面活性剤を含み、8超10未満のpHを有する液体洗浄組成物におけるグリコールエーテル溶媒の使用であって、
前記グリコールエーテル溶媒は、
i.式I:R1O(R2O)nR3;
ii.式II:R4O(R5O)mR6;及び
iii.これらの混合物
(式中、
R1は直鎖又は分枝鎖C4、C5又はC6アルキル又は置換若しくは非置換フェニルであり、R2はイソプロピルであり、R3は水素又はメチルであり、nは1、2又は3であり、
R4はn−プロピル又はイソプロピルであり、R5はイソプロピルであり、R6は水素又はメチルであり、mは1、2又は3である。)
からなる群から選択されるグリコールエーテルを含み、
前記界面活性剤及びグリコールエーテル溶媒は、5:1〜1:1(但し、1:1は除く)の重量比で存在し、
前記表面は、食卓用食器具または台所用品であり、前記食卓用食器具または台所用品はガラス製品を含まず、
前記泡寿命は、以下の方法:
前記組成物10gを、ガラス瓶(直径2cm、高さ8.5cm)に入れた後、ガラス瓶を閉じる。瓶をラックに配置して、1秒当たり1回の上下振盪とする一定周期の上下運動(開始地点から10〜15cm上方に上げ、及び開始地点に戻してそこから10〜15cm下げる)にて、手動で20秒間、振盪する。
を使用して測定される、1時間後の泡の高さによって定義される、使用。 - 前記疎水性汚れは、油、脂肪、ポリマーグリース、及びこれらの混合物からなる群から選択される、請求項1に記載の使用。
- 前記疎水性汚れは、植物油である、請求項2に記載の使用。
- 前記植物油は、ゴマ油、キャノーラ油、オリーブ油、菜種油、ヤシ油、トウモロコシ油、ピーナッツ油、ヒマワリ油、及びこれらの混合物からなる群から選択される、請求項3に記載の使用。
- 前記界面活性剤は、非イオン性界面活性剤を含む、請求項1〜4のいずれか一項に記載の使用。
- 前記非イオン性界面活性剤は、アルコキシル化非イオン性界面活性剤、アルキルポリグリコシド、アミンオキシド、及びこれらの混合物からなる群から選択される、請求項5に記載の使用。
- 前記界面活性剤は、アニオン性界面活性剤と両性界面活性剤及び/又は双性イオン性界面活性剤を含む、請求項1〜6のいずれか一項に記載の使用。
- 前記アニオン性界面活性剤と前記両性界面活性剤及び/又は前記双性イオン性界面活性剤は、9:1未満の重量比で存在する、請求項7に記載の使用。
- 前記アニオン性界面活性剤は、アルコキシル化アニオン性界面活性剤である、請求項7または8に記載の使用。
- 前記アルコキシル化アニオン性界面活性剤は、アルキルアルコキシル化サルフェートである、請求項9に記載の使用。
- 前記界面活性剤は、両性界面活性剤を含み、前記両性界面活性剤は少なくとも60重量%のアミンオキシド界面活性剤を含む、請求項1〜10のいずれか一項に記載の使用。
- 前記界面活性剤は、両性界面活性剤及び双性イオン性界面活性剤を含む、請求項1〜11のいずれか一項に記載の使用。
- 前記両性界面活性剤及び前記双性イオン性界面活性剤は、約2:1〜約1:2の重量比で存在する、請求項12に記載の使用。
- 前記両性界面活性剤はアミンオキシド界面活性剤であり、前記双性イオン性界面活性剤はベタインである、請求項12または13に記載の使用。
- 前記組成物は、共溶媒を更に含む、請求項1〜14のいずれか一項に記載の使用。
- 前記共溶媒は、C2〜C4アルコール、C2〜C4ポリオール、ポリアルキレングリコール及びこれらの混合物からなる群から選択される、請求項15に記載の使用。
- 前記食卓用食器具は、セラミックス、金属製のカトラリー、及びこれらの組み合わせからなる群から選択される、請求項1〜16のいずれか一項に記載の使用。
- 前記組成物は、前記方法を使用して測定すると、1時間後に1.5cmより大きい泡の高さをもたらす、泡寿命を付与するための、請求項1〜17のいずれか一項に記載の使用。
- 前記組成物は、前記方法を使用して測定すると、1時間後に2cmより大きい泡の高さをもたらす、請求項1〜18のいずれか一項に記載の使用。
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-
2015
- 2015-07-13 EP EP15176529.4A patent/EP3118295B1/en not_active Not-in-force
- 2015-07-13 ES ES15176529T patent/ES2704082T3/es active Active
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2016
- 2016-07-05 JP JP2018501938A patent/JP6923508B2/ja active Active
- 2016-07-05 WO PCT/US2016/040932 patent/WO2017011216A1/en active Application Filing
- 2016-07-05 CA CA2992114A patent/CA2992114A1/en not_active Abandoned
- 2016-07-06 US US15/202,748 patent/US20170015946A1/en not_active Abandoned
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WO2017011216A1 (en) | 2017-01-19 |
JP2018522116A (ja) | 2018-08-09 |
CA2992114A1 (en) | 2017-01-19 |
EP3118295A1 (en) | 2017-01-18 |
ES2704082T3 (es) | 2019-03-14 |
US20170015946A1 (en) | 2017-01-19 |
EP3118295B1 (en) | 2018-10-17 |
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