JP6839481B2 - 水素発生システムとそのプロセス - Google Patents
水素発生システムとそのプロセス Download PDFInfo
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- JP6839481B2 JP6839481B2 JP2018512495A JP2018512495A JP6839481B2 JP 6839481 B2 JP6839481 B2 JP 6839481B2 JP 2018512495 A JP2018512495 A JP 2018512495A JP 2018512495 A JP2018512495 A JP 2018512495A JP 6839481 B2 JP6839481 B2 JP 6839481B2
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- Prior art keywords
- hydrogen
- water
- alkali
- metals
- solid
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- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims description 42
- 229910052739 hydrogen Inorganic materials 0.000 title claims description 41
- 239000001257 hydrogen Substances 0.000 title claims description 41
- 238000000034 method Methods 0.000 title claims description 29
- 230000008569 process Effects 0.000 title claims description 22
- 239000000463 material Substances 0.000 claims description 33
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 32
- 239000000376 reactant Substances 0.000 claims description 24
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 21
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 18
- 229910052783 alkali metal Inorganic materials 0.000 claims description 16
- 150000001340 alkali metals Chemical class 0.000 claims description 16
- 150000001342 alkaline earth metals Chemical class 0.000 claims description 15
- 238000006243 chemical reaction Methods 0.000 claims description 15
- 229910045601 alloy Inorganic materials 0.000 claims description 14
- 239000000956 alloy Substances 0.000 claims description 14
- 239000006227 byproduct Substances 0.000 claims description 11
- 239000003638 chemical reducing agent Substances 0.000 claims description 10
- 239000007787 solid Substances 0.000 claims description 10
- 229910052742 iron Inorganic materials 0.000 claims description 9
- 229910052782 aluminium Inorganic materials 0.000 claims description 8
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 8
- 229910052749 magnesium Inorganic materials 0.000 claims description 7
- 239000011777 magnesium Substances 0.000 claims description 7
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 6
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 6
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 6
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 6
- 229910052790 beryllium Inorganic materials 0.000 claims description 6
- ATBAMAFKBVZNFJ-UHFFFAOYSA-N beryllium atom Chemical compound [Be] ATBAMAFKBVZNFJ-UHFFFAOYSA-N 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 6
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 6
- 229910052710 silicon Inorganic materials 0.000 claims description 6
- 239000010703 silicon Substances 0.000 claims description 6
- 239000011135 tin Substances 0.000 claims description 6
- 229910052718 tin Inorganic materials 0.000 claims description 6
- 239000011701 zinc Substances 0.000 claims description 6
- 229910052725 zinc Inorganic materials 0.000 claims description 6
- 150000004678 hydrides Chemical class 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 4
- 239000012466 permeate Substances 0.000 claims description 4
- 239000007795 chemical reaction product Substances 0.000 claims description 3
- 229910000941 alkaline earth metal alloy Inorganic materials 0.000 claims description 2
- 150000004681 metal hydrides Chemical class 0.000 claims description 2
- 239000000047 product Substances 0.000 claims description 2
- 229910052751 metal Inorganic materials 0.000 description 11
- 239000002184 metal Substances 0.000 description 11
- 239000011734 sodium Substances 0.000 description 8
- 229910000831 Steel Inorganic materials 0.000 description 7
- 239000010959 steel Substances 0.000 description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 5
- WDIHJSXYQDMJHN-UHFFFAOYSA-L barium chloride Chemical compound [Cl-].[Cl-].[Ba+2] WDIHJSXYQDMJHN-UHFFFAOYSA-L 0.000 description 5
- 229910001626 barium chloride Inorganic materials 0.000 description 4
- 229910052744 lithium Inorganic materials 0.000 description 4
- 230000008018 melting Effects 0.000 description 4
- 238000002844 melting Methods 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 3
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 3
- 229910000366 copper(II) sulfate Inorganic materials 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 239000012782 phase change material Substances 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 229910000528 Na alloy Inorganic materials 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 235000019270 ammonium chloride Nutrition 0.000 description 2
- 238000001311 chemical methods and process Methods 0.000 description 2
- SZVJSHCCFOBDDC-UHFFFAOYSA-N ferrosoferric oxide Chemical compound O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 2
- 239000011888 foil Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000010517 secondary reaction Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229910001148 Al-Li alloy Inorganic materials 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910000519 Ferrosilicon Inorganic materials 0.000 description 1
- 229910000799 K alloy Inorganic materials 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- JFBZPFYRPYOZCQ-UHFFFAOYSA-N [Li].[Al] Chemical compound [Li].[Al] JFBZPFYRPYOZCQ-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 229910001860 alkaline earth metal hydroxide Inorganic materials 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 159000000009 barium salts Chemical class 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 230000005496 eutectics Effects 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000005431 greenhouse gas Substances 0.000 description 1
- 230000020169 heat generation Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910003480 inorganic solid Inorganic materials 0.000 description 1
- 229910000103 lithium hydride Inorganic materials 0.000 description 1
- 229910001092 metal group alloy Inorganic materials 0.000 description 1
- 229910000000 metal hydroxide Inorganic materials 0.000 description 1
- 150000004692 metal hydroxides Chemical class 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- -1 oxides Chemical class 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 235000019795 sodium metasilicate Nutrition 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 230000002269 spontaneous effect Effects 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
- C01B3/08—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents with metals
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J7/00—Apparatus for generating gases
- B01J7/02—Apparatus for generating gases by wet methods
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
- C01B3/065—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents from a hydride
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
- C01B3/068—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents the hydrogen being generated from the water as a result of a cyclus of reactions, not covered by groups C01B3/063 or C01B3/105
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Fuel Cell (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Catalysts (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Manufacture And Refinement Of Metals (AREA)
Description
水から水素を生成するためのシステムであって、下記の構造を有する:
(a)支持用の構造材料:
アルカリ金属、アルカリ土類金属、アルカリ-アルカリ土類金属合金、アルカリ金属またはアルカリ土類金属の水素化物から選択される固体状態の1次反応物;および
珪素、スズ、鉄、亜鉛、マンガン、アルミニウム、鉄、ベリリウム、マグネシウムまたはそれらの合金から選択される固体状態のブースト反応物;
(b)構造材料と接触する減速器材料
(c)1次反応物と反応する前に水が拡散され、得られた水素が透過する拡散器材料。
(a)アルカリ金属、アルカリ土類金属、アルカリ-アルカリ土類金属合金、固体状態のアルカリ金属またはアルカリ土類金属の水素化物から選択される固体状態の反応物と液体水を室温で反応させ、1次生成物として対応する水酸化物を得る;
(b)珪素、スズ、亜鉛、マンガン、アルミニウム、鉄、ベリリウム、マグネシウムまたはそれらの合金から選択された固体状態のブースト反応物と水と、段階aで得た水酸化物を反応させて、追加の水素と2次副生成物としての酸化物を得る;
(c)残留反応生成物から水素を分離する
(d)水素を回収する。
(a)支持用の構造材料:
アルカリ金属、アルカリ土類金属、アルカリ-アルカリ土類金属合金、アルカリ金属またはアルカリ土類金属の水素化物から選択される固体状態の1次反応物;および
珪素、スズ、鉄、亜鉛、マンガン、アルミニウム、鉄、ベリリウム、マグネシウムまたはそれらの合金から選択される固体状態のブースト反応物;
(b)構造材料と接触する減速器材料
(c)1次反応物と反応する前に水が拡散され、得られた水素が透過する拡散器材料。
(b)段階aで得られた水酸化物を水および珪素、スズ、亜鉛、マンガン、アルミニウム、鉄、ベリリウム、マグネシウムまたはこれらの合金の中から選択された金属と、固体状態で反応させ、追加の水素および酸化物を2次副産物として得るプロセス;
(c)残留反応生成物から水素を分離するプロセス
(d)水素を収集するプロセス。
例
この例は次のように準備される:
反応物質と材料
反応物質:金属ナトリウム;フェロシリコン;構造材料:スチール箔減速材:CuSO4+BaCl2+NH4Cl;メッシュ:鋼SS304メッシュ
反応の進行は以下の通りである:
1.
Na+H2O→NaOH+1/2・H2
2.
3Fe+4H2O→Fe3O4+4H2
2NaOH+Si+H2O→Na2SiO3+2H2
相変化材料の反応
BaCl2+NaOH→Ba(OH)2+NaCl(反応媒体から水酸化物を除去する)
Ba(OH)2.8H2O(s)+2NH4Cl(s)→2NH3(g)+10H2O(l)+BaCl2(s)(強吸熱性)
CuSO4+4NH3+H2O→[Cu(NH3)4]SO4.H2O(NH3を分泌)
異なる元素の総重量は以下の通りである:
金属Na;50g
金属Si;50g
金属Fe;200g
BaCl2;75g
NH4Cl;35g
CuSO4;210g
鋼箔:90g
鋼SS304メッシュ:14g
総重量:724g
発生した水素(重量):H2;13g
発生した水素(体積):145,6SL
貯蔵エネルギー:433.33Wh
重量エネルギー密度:724Wh/Kg
反応に必要な最小限の水:125g
Claims (2)
- 水から水素を生成するためのシステムであって、下記の構造を有する:
(a)支持用の構造材料:
アルカリ金属、アルカリ土類金属、アルカリ-アルカリ土類金属合金、アルカリ金属またはアルカリ土類金属の水素化物から選択される固体状態の1次反応物;および
珪素、スズ、鉄、亜鉛、マンガン、アルミニウム、鉄、ベリリウム、マグネシウムまたはそれらの合金から選択される固体状態のブースト反応物;
(b)水素を生成するプロセスの速度を遅くする材料であって、構造材料と接触する減速器材料
(c)1次反応物と反応する前に水が拡散され、得られた水素が透過する拡散器材料。 - 請求項1に記載のシステムで実行される連鎖反応で水から水素を生成する方法であって、次の段階を含む:
(a)アルカリ金属、アルカリ土類金属、アルカリ-アルカリ土類金属合金、固体状態のアルカリ金属またはアルカリ土類金属の水素化物から選択される固体状態の反応物と液体水を室温で反応させ、1次生成物として対応する水酸化物を得るプロセス;
(b)珪素、スズ、亜鉛、マンガン、アルミニウム、鉄、ベリリウム、マグネシウムまたはそれらの合金から選択された固体状態のブースト反応物と水と、段階aで得た水酸化物を反応させて、追加の水素と2次副生成物としての酸化物を得るプロセス;
(c)残留反応生成物から水素を分離するプロセス
(d)水素を収集するプロセス。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP15382262.2A EP3095758B1 (en) | 2015-05-20 | 2015-05-20 | A system and a process for generating hydrogen |
EP15382262.2 | 2015-05-20 | ||
PCT/ES2016/070377 WO2016185075A1 (es) | 2015-05-20 | 2016-05-19 | Un sistema y un procedimiento para generar hidrógeno |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2018515418A JP2018515418A (ja) | 2018-06-14 |
JP6839481B2 true JP6839481B2 (ja) | 2021-03-10 |
Family
ID=53269425
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2018512495A Active JP6839481B2 (ja) | 2015-05-20 | 2016-05-19 | 水素発生システムとそのプロセス |
Country Status (12)
Country | Link |
---|---|
US (1) | US11383976B2 (ja) |
EP (1) | EP3095758B1 (ja) |
JP (1) | JP6839481B2 (ja) |
CN (1) | CN107922187B (ja) |
AU (1) | AU2016265482B2 (ja) |
CA (1) | CA2986516C (ja) |
CO (1) | CO2017011707A2 (ja) |
ES (1) | ES2716423T3 (ja) |
MX (1) | MX2017014786A (ja) |
PT (1) | PT3095758T (ja) |
RU (1) | RU2729502C2 (ja) |
WO (1) | WO2016185075A1 (ja) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111481425A (zh) * | 2019-01-25 | 2020-08-04 | 曹荣华 | 微环境氢气供给透气层及外敷袋 |
US11655148B2 (en) * | 2020-03-03 | 2023-05-23 | Massachusetts Institute Of Technology | Hydrogen generating reactions |
US11383975B2 (en) | 2020-05-25 | 2022-07-12 | Silican Inc. | Composite for generating hydrogen |
CN112079333B (zh) * | 2020-09-07 | 2022-08-09 | 东方电气集团东方锅炉股份有限公司 | 一种链式反应制氢系统及制氢方法 |
Family Cites Families (26)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
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CA2986516C (en) | 2022-10-18 |
CN107922187A (zh) | 2018-04-17 |
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US20180297841A1 (en) | 2018-10-18 |
EP3095758A1 (en) | 2016-11-23 |
RU2017144609A3 (ja) | 2019-08-19 |
US11383976B2 (en) | 2022-07-12 |
PT3095758T (pt) | 2019-03-29 |
WO2016185075A1 (es) | 2016-11-24 |
AU2016265482B2 (en) | 2020-07-09 |
AU2016265482A1 (en) | 2017-12-14 |
CO2017011707A2 (es) | 2018-01-31 |
RU2017144609A (ru) | 2019-06-20 |
CA2986516A1 (en) | 2016-11-24 |
ES2716423T3 (es) | 2019-06-12 |
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RU2729502C2 (ru) | 2020-08-07 |
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