JP6830448B2 - 高いｇ’及び広いｍｗｄを有する管状エチレン系ポリマーを作製するための改善されたプロセス - Google Patents

高いｇ’及び広いｍｗｄを有する管状エチレン系ポリマーを作製するための改善されたプロセス Download PDF

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Publication number
JP6830448B2
JP6830448B2 JP2017564376A JP2017564376A JP6830448B2 JP 6830448 B2 JP6830448 B2 JP 6830448B2 JP 2017564376 A JP2017564376 A JP 2017564376A JP 2017564376 A JP2017564376 A JP 2017564376A JP 6830448 B2 JP6830448 B2 JP 6830448B2
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ethylene
cta
reaction zone
formula
polyene
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JP2018518574A (ja
JP2018518574A5 (enExample
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オットー・ジェイ・バービー
ステファン・ヒンリクス
ショーン・ダブリュ・エワート
ジョン・オー・オズビー
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Dow Global Technologies LLC
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Dow Global Technologies LLC
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/01—Processes of polymerisation characterised by special features of the polymerisation apparatus used
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/001—Multistage polymerisation processes characterised by a change in reactor conditions without deactivating the intermediate polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/07—Aldehydes; Ketones
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/10—Esters; Ether-esters
    • C08K5/101—Esters; Ether-esters of monocarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/04—Broad molecular weight distribution, i.e. Mw/Mn > 6
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/11—Melt tension or melt strength
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00—Properties characterising the ingredient of the composition
    • C08L2207/06—Properties of polyethylene
    • C08L2207/066—LDPE (radical process)
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
JP2017564376A 2015-06-25 2016-06-23 高いｇ’及び広いｍｗｄを有する管状エチレン系ポリマーを作製するための改善されたプロセス Active JP6830448B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201562184549P 2015-06-25 2015-06-25
US62/184,549 2015-06-25
PCT/US2016/039061 WO2016210160A1 (en) 2015-06-25 2016-06-23 Improved process to make tubular ethylene based polymers with high g' and broad mwd

Publications (3)

Publication Number Publication Date
JP2018518574A JP2018518574A (ja) 2018-07-12
JP2018518574A5 JP2018518574A5 (enExample) 2020-12-10
JP6830448B2 true JP6830448B2 (ja) 2021-02-17

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JP2017564376A Active JP6830448B2 (ja) 2015-06-25 2016-06-23 高いｇ’及び広いｍｗｄを有する管状エチレン系ポリマーを作製するための改善されたプロセス

Country Status (8)

Country Link
US (1) US10730977B2 (enExample)
EP (1) EP3313894B1 (enExample)
JP (1) JP6830448B2 (enExample)
KR (1) KR102577463B1 (enExample)
CN (1) CN107750257B (enExample)
BR (1) BR112017026984B1 (enExample)
ES (1) ES2774813T3 (enExample)
WO (1) WO2016210160A1 (enExample)

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KR102284307B1 (ko) 2013-12-26 2021-08-04 다우 글로벌 테크놀로지스 엘엘씨 비대칭 폴리엔을 이용하여 에틸렌계 중합체의 제조를 위한 반응기 안정성을 개선하는 방법
US9944733B2 (en) 2013-12-26 2018-04-17 Dow Global Technologies Llc Ethylene-based polymers formed using asymmetrical polyenes
US11084893B2 (en) 2017-06-02 2021-08-10 Dow Global Technologies Llc Ethylene-based polymers and processes for the same
CN109593148B (zh) * 2017-09-30 2020-10-27 中国科学院化学研究所 一种链转移法制备高熔融指数乙烯聚合物的方法

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Also Published As

Publication number Publication date
KR102577463B1 (ko) 2023-09-14
CN107750257B (zh) 2021-03-30
EP3313894B1 (en) 2019-12-18
BR112017026984B1 (pt) 2022-01-18
BR112017026984A2 (enExample) 2017-12-14
KR20180021793A (ko) 2018-03-05
US10730977B2 (en) 2020-08-04
JP2018518574A (ja) 2018-07-12
EP3313894A1 (en) 2018-05-02
US20180171047A1 (en) 2018-06-21
ES2774813T3 (es) 2020-07-22
WO2016210160A1 (en) 2016-12-29
CN107750257A (zh) 2018-03-02

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