JP6824319B2 - ポリケトンおよびゴムを含有するポリアミドベースの組成物 - Google Patents
ポリケトンおよびゴムを含有するポリアミドベースの組成物 Download PDFInfo
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- JP6824319B2 JP6824319B2 JP2019075657A JP2019075657A JP6824319B2 JP 6824319 B2 JP6824319 B2 JP 6824319B2 JP 2019075657 A JP2019075657 A JP 2019075657A JP 2019075657 A JP2019075657 A JP 2019075657A JP 6824319 B2 JP6824319 B2 JP 6824319B2
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- Prior art keywords
- acid
- polyamide
- composition
- weight
- rubber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000203 mixture Substances 0.000 title claims description 131
- 229920002647 polyamide Polymers 0.000 title claims description 65
- 229920001971 elastomer Polymers 0.000 title claims description 53
- 239000005060 rubber Substances 0.000 title claims description 53
- 229920001470 polyketone Polymers 0.000 title claims description 40
- 239000004952 Polyamide Substances 0.000 claims description 58
- 238000004519 manufacturing process Methods 0.000 claims description 16
- 229920001577 copolymer Polymers 0.000 claims description 13
- 238000001125 extrusion Methods 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 11
- 239000004014 plasticizer Substances 0.000 claims description 9
- 125000001931 aliphatic group Chemical group 0.000 claims description 8
- 125000004432 carbon atom Chemical group C* 0.000 claims description 8
- 229920006226 ethylene-acrylic acid Polymers 0.000 claims description 7
- 229920002302 Nylon 6,6 Polymers 0.000 claims description 6
- 150000001413 amino acids Chemical class 0.000 claims description 5
- 238000001746 injection moulding Methods 0.000 claims description 5
- 238000000465 moulding Methods 0.000 claims description 5
- PBLZLIFKVPJDCO-UHFFFAOYSA-N 12-aminododecanoic acid Chemical compound NCCCCCCCCCCCC(O)=O PBLZLIFKVPJDCO-UHFFFAOYSA-N 0.000 claims description 4
- 229920002292 Nylon 6 Polymers 0.000 claims description 4
- 229920000305 Nylon 6,10 Polymers 0.000 claims description 4
- 229920006152 PA1010 Polymers 0.000 claims description 4
- 150000002430 hydrocarbons Chemical group 0.000 claims description 4
- 238000000071 blow moulding Methods 0.000 claims description 3
- 229920001038 ethylene copolymer Polymers 0.000 claims description 3
- XAUQWYHSQICPAZ-UHFFFAOYSA-N 10-amino-decanoic acid Chemical compound NCCCCCCCCCC(O)=O XAUQWYHSQICPAZ-UHFFFAOYSA-N 0.000 claims description 2
- GUOSQNAUYHMCRU-UHFFFAOYSA-N 11-Aminoundecanoic acid Chemical compound NCCCCCCCCCCC(O)=O GUOSQNAUYHMCRU-UHFFFAOYSA-N 0.000 claims description 2
- REBJWNWFRPUXDE-UHFFFAOYSA-N 12-(azacycloundec-1-yl)-12-oxododecanamide Chemical compound NC(=O)CCCCCCCCCCC(=O)N1CCCCCCCCCC1 REBJWNWFRPUXDE-UHFFFAOYSA-N 0.000 claims description 2
- SLXKOJJOQWFEFD-UHFFFAOYSA-N 6-aminohexanoic acid Chemical compound NCCCCCC(O)=O SLXKOJJOQWFEFD-UHFFFAOYSA-N 0.000 claims description 2
- OECUQWQIGXMPAN-UHFFFAOYSA-N 6-oxo-6-pyrrolidin-1-ylhexanamide Chemical compound NC(=O)CCCCC(=O)N1CCCC1 OECUQWQIGXMPAN-UHFFFAOYSA-N 0.000 claims description 2
- VWPQCOZMXULHDM-UHFFFAOYSA-N 9-aminononanoic acid Chemical compound NCCCCCCCCC(O)=O VWPQCOZMXULHDM-UHFFFAOYSA-N 0.000 claims description 2
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical compound NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 claims description 2
- 229960002684 aminocaproic acid Drugs 0.000 claims description 2
- 238000000748 compression moulding Methods 0.000 claims description 2
- 239000007859 condensation product Substances 0.000 claims description 2
- 229920000933 poly (ε-caprolactam) Polymers 0.000 claims description 2
- 238000003856 thermoforming Methods 0.000 claims description 2
- 229930195735 unsaturated hydrocarbon Natural products 0.000 claims description 2
- JNULBACNFINPDL-UHFFFAOYSA-N 1-(azacycloundec-1-yl)decan-1-one Chemical compound C(CCCCCCCCC)(=O)N1CCCCCCCCCC1 JNULBACNFINPDL-UHFFFAOYSA-N 0.000 claims 1
- PZUOZVRWVVCKAR-UHFFFAOYSA-N 1-(azepan-1-yl)decan-1-one Chemical compound CCCCCCCCCC(=O)N1CCCCCC1 PZUOZVRWVVCKAR-UHFFFAOYSA-N 0.000 claims 1
- QHZOMAXECYYXGP-UHFFFAOYSA-N ethene;prop-2-enoic acid Chemical compound C=C.OC(=O)C=C QHZOMAXECYYXGP-UHFFFAOYSA-N 0.000 claims 1
- 229920003986 novolac Polymers 0.000 claims 1
- 229920005989 resin Polymers 0.000 claims 1
- 239000011347 resin Substances 0.000 claims 1
- -1 2,2-bis (3-carboxyphenyl) Carboxyphenyl Chemical group 0.000 description 31
- 239000002253 acid Substances 0.000 description 24
- 229920000642 polymer Polymers 0.000 description 22
- 150000001412 amines Chemical class 0.000 description 19
- 239000010949 copper Substances 0.000 description 15
- 239000000178 monomer Substances 0.000 description 14
- IPRJXAGUEGOFGG-UHFFFAOYSA-N N-butylbenzenesulfonamide Chemical class CCCCNS(=O)(=O)C1=CC=CC=C1 IPRJXAGUEGOFGG-UHFFFAOYSA-N 0.000 description 13
- 239000000945 filler Substances 0.000 description 13
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 11
- 150000001875 compounds Chemical class 0.000 description 11
- 239000003381 stabilizer Substances 0.000 description 11
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 10
- 150000002148 esters Chemical class 0.000 description 10
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 9
- 239000002826 coolant Substances 0.000 description 9
- 229910052802 copper Inorganic materials 0.000 description 9
- 239000003365 glass fiber Substances 0.000 description 9
- 150000003839 salts Chemical class 0.000 description 9
- 239000000126 substance Substances 0.000 description 9
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 8
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 8
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 8
- 239000000654 additive Substances 0.000 description 8
- 239000002585 base Substances 0.000 description 8
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 8
- 238000012360 testing method Methods 0.000 description 8
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 7
- 239000005977 Ethylene Substances 0.000 description 7
- 125000003118 aryl group Chemical group 0.000 description 7
- 125000002843 carboxylic acid group Chemical group 0.000 description 7
- 150000004820 halides Chemical class 0.000 description 7
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 6
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 6
- 150000001993 dienes Chemical class 0.000 description 6
- TVIDDXQYHWJXFK-UHFFFAOYSA-N dodecanedioic acid Chemical compound OC(=O)CCCCCCCCCCC(O)=O TVIDDXQYHWJXFK-UHFFFAOYSA-N 0.000 description 6
- 238000002156 mixing Methods 0.000 description 6
- 150000002989 phenols Chemical class 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- 239000002904 solvent Substances 0.000 description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 5
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 5
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 5
- 125000003277 amino group Chemical group 0.000 description 5
- YQLZOAVZWJBZSY-UHFFFAOYSA-N decane-1,10-diamine Chemical compound NCCCCCCCCCCN YQLZOAVZWJBZSY-UHFFFAOYSA-N 0.000 description 5
- 239000000835 fiber Substances 0.000 description 5
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 5
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 5
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 4
- 229920002943 EPDM rubber Polymers 0.000 description 4
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 4
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 150000007513 acids Chemical class 0.000 description 4
- 230000000996 additive effect Effects 0.000 description 4
- 239000001361 adipic acid Substances 0.000 description 4
- 235000011037 adipic acid Nutrition 0.000 description 4
- 229910001508 alkali metal halide Inorganic materials 0.000 description 4
- 150000008045 alkali metal halides Chemical class 0.000 description 4
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 4
- 229910002091 carbon monoxide Inorganic materials 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 150000004985 diamines Chemical class 0.000 description 4
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 4
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 4
- 239000011159 matrix material Substances 0.000 description 4
- 125000000896 monocarboxylic acid group Chemical group 0.000 description 4
- FJKROLUGYXJWQN-UHFFFAOYSA-N 4-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 3
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 3
- VMQMZMRVKUZKQL-UHFFFAOYSA-N Cu+ Chemical class [Cu+] VMQMZMRVKUZKQL-UHFFFAOYSA-N 0.000 description 3
- 239000004593 Epoxy Substances 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- 150000008065 acid anhydrides Chemical class 0.000 description 3
- 239000003963 antioxidant agent Substances 0.000 description 3
- 150000004984 aromatic diamines Chemical class 0.000 description 3
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 3
- 239000003153 chemical reaction reagent Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- QFTYSVGGYOXFRQ-UHFFFAOYSA-N dodecane-1,12-diamine Chemical compound NCCCCCCCCCCCCN QFTYSVGGYOXFRQ-UHFFFAOYSA-N 0.000 description 3
- 230000009477 glass transition Effects 0.000 description 3
- 238000002347 injection Methods 0.000 description 3
- 239000007924 injection Substances 0.000 description 3
- 150000003951 lactams Chemical class 0.000 description 3
- 239000000314 lubricant Substances 0.000 description 3
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 3
- 239000011976 maleic acid Substances 0.000 description 3
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 150000008301 phosphite esters Chemical class 0.000 description 3
- XRBCRPZXSCBRTK-UHFFFAOYSA-N phosphonous acid Chemical compound OPO XRBCRPZXSCBRTK-UHFFFAOYSA-N 0.000 description 3
- 229910052698 phosphorus Inorganic materials 0.000 description 3
- 239000011574 phosphorus Substances 0.000 description 3
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 3
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 3
- PZWQOGNTADJZGH-SNAWJCMRSA-N (2e)-2-methylpenta-2,4-dienoic acid Chemical compound OC(=O)C(/C)=C/C=C PZWQOGNTADJZGH-SNAWJCMRSA-N 0.000 description 2
- PWGJDPKCLMLPJW-UHFFFAOYSA-N 1,8-diaminooctane Chemical compound NCCCCCCCCN PWGJDPKCLMLPJW-UHFFFAOYSA-N 0.000 description 2
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 2
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- 239000005711 Benzoic acid Substances 0.000 description 2
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 239000005749 Copper compound Substances 0.000 description 2
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 2
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- 125000005396 acrylic acid ester group Chemical group 0.000 description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 230000002528 anti-freeze Effects 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 235000010233 benzoic acid Nutrition 0.000 description 2
- WGQKYBSKWIADBV-UHFFFAOYSA-N benzylamine Chemical compound NCC1=CC=CC=C1 WGQKYBSKWIADBV-UHFFFAOYSA-N 0.000 description 2
- HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 description 2
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- 150000001880 copper compounds Chemical class 0.000 description 2
- BERDEBHAJNAUOM-UHFFFAOYSA-N copper(i) oxide Chemical compound [Cu]O[Cu] BERDEBHAJNAUOM-UHFFFAOYSA-N 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- MGNZXYYWBUKAII-UHFFFAOYSA-N cyclohexa-1,3-diene Chemical compound C1CC=CC=C1 MGNZXYYWBUKAII-UHFFFAOYSA-N 0.000 description 2
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- 238000006731 degradation reaction Methods 0.000 description 2
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- PYGSKMBEVAICCR-UHFFFAOYSA-N hexa-1,5-diene Chemical compound C=CCCC=C PYGSKMBEVAICCR-UHFFFAOYSA-N 0.000 description 2
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- 229910052739 hydrogen Inorganic materials 0.000 description 2
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- 238000002844 melting Methods 0.000 description 2
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- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 2
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- RRKODOZNUZCUBN-CCAGOZQPSA-N (1z,3z)-cycloocta-1,3-diene Chemical compound C1CC\C=C/C=C\C1 RRKODOZNUZCUBN-CCAGOZQPSA-N 0.000 description 1
- PRBHEGAFLDMLAL-GQCTYLIASA-N (4e)-hexa-1,4-diene Chemical compound C\C=C\CC=C PRBHEGAFLDMLAL-GQCTYLIASA-N 0.000 description 1
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- NSGXIBWMJZWTPY-UHFFFAOYSA-N 1,1,1,3,3,3-hexafluoropropane Chemical compound FC(F)(F)CC(F)(F)F NSGXIBWMJZWTPY-UHFFFAOYSA-N 0.000 description 1
- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 description 1
- WZCQRUWWHSTZEM-UHFFFAOYSA-N 1,3-phenylenediamine Chemical compound NC1=CC=CC(N)=C1 WZCQRUWWHSTZEM-UHFFFAOYSA-N 0.000 description 1
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- 229920001194 natural rubber Polymers 0.000 description 1
- SXJVFQLYZSNZBT-UHFFFAOYSA-N nonane-1,9-diamine Chemical compound NCCCCCCCCCN SXJVFQLYZSNZBT-UHFFFAOYSA-N 0.000 description 1
- 239000002667 nucleating agent Substances 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- HYBLFDUGSBOMPI-UHFFFAOYSA-N octa-1,4-diene Chemical compound CCCC=CCC=C HYBLFDUGSBOMPI-UHFFFAOYSA-N 0.000 description 1
- BNJOQKFENDDGSC-UHFFFAOYSA-N octadecanedioic acid Chemical compound OC(=O)CCCCCCCCCCCCCCCCC(O)=O BNJOQKFENDDGSC-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- IOQPZZOEVPZRBK-UHFFFAOYSA-N octan-1-amine Chemical compound CCCCCCCCN IOQPZZOEVPZRBK-UHFFFAOYSA-N 0.000 description 1
- 229960002446 octanoic acid Drugs 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- AJCDFVKYMIUXCR-UHFFFAOYSA-N oxobarium;oxo(oxoferriooxy)iron Chemical compound [Ba]=O.O=[Fe]O[Fe]=O.O=[Fe]O[Fe]=O.O=[Fe]O[Fe]=O.O=[Fe]O[Fe]=O.O=[Fe]O[Fe]=O.O=[Fe]O[Fe]=O AJCDFVKYMIUXCR-UHFFFAOYSA-N 0.000 description 1
- MUJIDPITZJWBSW-UHFFFAOYSA-N palladium(2+) Chemical compound [Pd+2] MUJIDPITZJWBSW-UHFFFAOYSA-N 0.000 description 1
- QYZLKGVUSQXAMU-UHFFFAOYSA-N penta-1,4-diene Chemical compound C=CCC=C QYZLKGVUSQXAMU-UHFFFAOYSA-N 0.000 description 1
- GPCKFIWBUTWTDH-UHFFFAOYSA-N pentane-3,3-diamine Chemical compound CCC(N)(N)CC GPCKFIWBUTWTDH-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical class C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 description 1
- 150000003018 phosphorus compounds Chemical class 0.000 description 1
- 125000005498 phthalate group Chemical class 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- ARJOQCYCJMAIFR-UHFFFAOYSA-N prop-2-enoyl prop-2-enoate Chemical compound C=CC(=O)OC(=O)C=C ARJOQCYCJMAIFR-UHFFFAOYSA-N 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- AOHJOMMDDJHIJH-UHFFFAOYSA-N propylenediamine Chemical compound CC(N)CN AOHJOMMDDJHIJH-UHFFFAOYSA-N 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 229910052705 radium Inorganic materials 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- 238000001175 rotational moulding Methods 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000001384 succinic acid Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- HQHCYKULIHKCEB-UHFFFAOYSA-N tetradecanedioic acid Chemical compound OC(=O)CCCCCCCCCCCCC(O)=O HQHCYKULIHKCEB-UHFFFAOYSA-N 0.000 description 1
- SDVHRXOTTYYKRY-UHFFFAOYSA-J tetrasodium;dioxido-oxo-phosphonato-$l^{5}-phosphane Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)P([O-])([O-])=O SDVHRXOTTYYKRY-UHFFFAOYSA-J 0.000 description 1
- 239000003017 thermal stabilizer Substances 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 150000004992 toluidines Chemical class 0.000 description 1
- 239000012745 toughening agent Substances 0.000 description 1
- BPSKTAWBYDTMAN-UHFFFAOYSA-N tridecane-1,13-diamine Chemical compound NCCCCCCCCCCCCCN BPSKTAWBYDTMAN-UHFFFAOYSA-N 0.000 description 1
- 229940005605 valeric acid Drugs 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000010456 wollastonite Substances 0.000 description 1
- 229910052882 wollastonite Inorganic materials 0.000 description 1
- 150000003952 β-lactams Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/06—Polyamides derived from polyamines and polycarboxylic acids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/0001—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor characterised by the choice of material
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/02—Polyamides derived from omega-amino carboxylic acids or from lactams thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2019/00—Use of rubber not provided for in a single one of main groups B29K2007/00 - B29K2011/00, as moulding material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2061/00—Use of condensation polymers of aldehydes or ketones or derivatives thereof, as moulding material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2077/00—Use of PA, i.e. polyamides, e.g. polyesteramides or derivatives thereof, as moulding material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2995/00—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
- B29K2995/0037—Other properties
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C08L23/0869—Acids or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L73/00—Compositions of macromolecular compounds obtained by reactions forming a linkage containing oxygen or oxygen and carbon in the main chain, not provided for in groups C08L59/00 - C08L71/00; Compositions of derivatives of such polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Materials Engineering (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
Description
本出願は、2013年9月17日出願の欧州特許出願第13184671.9号に対する優先権を請求するものであり、この出願の全内容は、参照により本明細書に援用される。参照により本明細書に援用される特許、特許出願、および刊行物のいずれかの開示が、用語を不明瞭にさせ得る程度まで本出願の記載と矛盾する場合、本記載が優先するものとする。
ポリアミド組成物[組成物(C)]であって、
− 少なくとも1種のポリアミド[ポリアミド(A)]と;
− 組成物(C)の総重量を基準として、5重量%以下の量で、少なくとも1種のポリケトン[ポリケトン(K)]と;
− 少なくとも1種のゴム[ゴム(R)]と
を含む、ポリアミド組成物に関する。
本発明の目的のためには、用語「ポリアミド」は、ポリマー鎖の不可欠な部分として繰り返しアミド基(−NH−CO−)を有する任意のポリマーを意味することを意図する。
− 少なくとも二酸[酸(DA)](またはその誘導体)と少なくともジアミン[アミン(NN)](またはその誘導体)とを含む混合物(M1);
− 少なくともラクタム[ラクタム(L)]を含む混合物(M2);
− 少なくともアミノカルボン酸[アミノ酸(AN)]を含む混合物(M3);および
− それらの組み合わせ
から選択される少なくとも1つの混合物の縮合生成物である。
− アジピン酸と1,6−ジアミノヘキサンとの混合物;
− アジピン酸と、テレフタル酸と1,6−ジアミノヘキサンとの混合物;
− セバシン酸と1,6−ジアミノヘキサンとの混合物;
− セバシン酸と1,10−ジアミノデカンとの混合物;
− ドデカン二酸と1,10−ジアミノデカンとの混合物;および
− ドデカン二酸と1,12−ジアミノドデカンとの混合物
から選択される。
本発明に従って使用されるポリケトン(K)は、脂肪族および/または芳香族、好ましくは脂肪族であり得る。
(式中、Rは炭化水素基を表す)
の繰り返し単位を含む。ポリケトン(K)が芳香族ポリケトンである場合、Rは出現ごとに独立して、6〜30個の炭素を有する、置換もしくは非置換の、単環もしくは多環芳香族基であり、例示的な芳香族基には、フェニル、トリル、ナフチル、およびビフェニルが含まれる。
−(CO−CH2−CH2)x−(CO−A)y− (b)
(式中、Aは、プロピレン−CH2−CH(CH3)−などの、少なくとも3個の炭素原子を有するエチレン性不飽和炭化水素基、フェニレン−C6H4−またはアリールエーテル−C6H4−O−C6H4−ラジカルを意味する。x/y比は、少なくとも2であり得る)
の繰り返し単位を含む。前記繰り返し単位は、ポリケトン(K)の主鎖中にランダムに分布することができる。
典型的には、本発明による組成物(C)は、組成物(C)の総重量を基準として、5重量%〜35重量%、好ましくは10重量%〜30重量%、より好ましくは15重量%〜25重量%のゴム(R)を含有する。
− 米国特許第5030689号明細書(BASF AKTIENGESELLSCHAFT)1991年7月9日に記載されているものなどの、40:60〜90:10の範囲内のエチレン/プロピレン比を好ましくは有するエチレン−プロピレン(EPM)およびエチレン−プロピレン−ジエン(EPDM)ゴム、ならびに
− エチレンアクリル酸(EAA)コポリマーおよびエチレンメタクリル酸(EMAA)コポリマー、好ましくはEAAコポリマーなどの、エチレンとアクリル酸および/またはメタクリル酸および/またはこれらの酸のエステルとのコポリマー
などの、エチレンコポリマーゴム[ゴム(ER)]である。
(式中、R1〜R9はそれぞれ、水素または1〜6個の炭素原子のアルキルであり、mは0〜20の整数であり、nは0〜10の整数であり、pは0〜5の整数である)
のジカルボキシル−およびエポキシ含有モノマーをモノマー混合物に加えることによってポリマー鎖に組み込むことができる。好ましくは、R1〜R9はそれぞれ水素であり、mは0または1であり、nは1である。相当する化合物は、マレイン酸、フマル酸、無水マレイン酸、アルキルグリシジルエーテルおよびビニルグリシジルエーテルである。
50重量%〜98重量%、特に60重量%〜95重量%のエチレンと、
0.5重量%〜40重量%、特に3重量%〜20重量%のグリシジルアクリレートおよび/またはグリシジルメタクリレート、アクリル酸無水物および/または無水マレイン酸と、
1重量%〜45重量%、特に10重量%〜35重量%のn−ブチルアクリレートおよび/または2−エチルヘキシルアクリレートと
のコポリマーが特に好ましい。
グラフティングベース(ベースポリマー)としての−20℃よりも下のガラス転移温度を有する25重量%〜98重量%のアクリレートゴムと
グラフト表面(グラフトシース)としてのそのホモポリマーまたはコポリマーが25℃超のガラス転移温度を有する2〜75重量%の共重合可能なエチレン性不飽和モノマーと
のグラフトポリマー(本明細書では以下「ゴム(GAR)」と言われる)であってもよい。
任意選択的に、本発明の組成物(C)は、ポリアミドベースの組成物の製造に従来使用される充填材(F)をさらに含むことができる。
組成物(C)はまた、本明細書によって補助安定剤(S)と言われる、1種もしくは2種以上の熱安定剤または酸化防止剤を含んでもよい。
任意選択的に、組成物(C)はまた、加工助剤としての可塑剤を含有する。好適な可塑剤は、N−ブチルベンゼンスルホンアミド(BBSA)、エチルトルエンスルホンアミドまたはN−シクロヘキシルトルエンスルホンアミドなどの、ベンゼンスルホンアミド誘導体;パラ−ヒドロキシ安息香酸2−エチルヘキシルおよびパラ−ヒドロキシ安息香酸2−デシルヘキシルなどの、ヒドロキシ安息香酸のエステル:オリゴエトキシル化テトラヒドロフルフリルアルコールのような、テトラヒドロフルフリルアルコールのエステルまたはエーテル;ならびにオリゴエトキシル化マロネートなどの、クエン酸またはヒドロキシマロン酸のエステルから選ぶことができる。パラ−ヒドロキシ安息香酸デシルヘキシルおよびパラ−ヒドロキシ安息香酸エチルヘキシルが挙げられてもよい。上記の群の中で、N−ブチルベンゼンスルホンアミド(BBSA)が、有効な可塑剤と考えられ、広く使用されている。
組成物(C)はまた、潤滑剤、着色剤、顔料、帯電防止剤、難燃剤、核形成剤、触媒などの、当技術分野で一般に使用される他の従来型添加剤を含んでもよい。
本発明はさらに、上に詳述されたような組成物(C)の製造方法であって、前記方法が、どれか他の任意選択の原料の存在下で、ポリアミド(A)と、ポリケトン(K)とゴム(R)とを溶融ブレンドする工程を含む方法に関する。
一態様では、本発明は、自動車および電気/エレクトロニクス用途向けの組成物(C)の使用に関する。
(1)ポリアミド:
PA 6:Hyosung Corpによって製造される、1031 BRT(相対粘度*=3.1)
PA 610:Nexis−Fibers AGによって製造される(相対粘度=3.7)
PA 1010:Shandong Dongchen Engineering Plastic Co.,Ltdによって提供される高粘度ポリアミド
(2)ポリケトン:エチレンと、プロピレンと一酸化炭素とのコポリマーであり、M630Aと命名される、Hyosung Corpによって製造される脂肪族ポリケトン
(3)ゴム:Escor(商標)5050、Exxon Mobile Chemical Corpによって製造されるEAAゴム
(4)酸化防止剤:0.2%濃度でのIrganox(登録商標)1098
(5)熱安定剤:0.3%濃度でのCuI/KI型マスターバッチ
(6)潤滑剤:0.5%濃度でのEAAオリゴマーACP−540
(7)クーラントA:Dex−Cool(登録商標)と特定されるTexaco市販調合物;
クーラントB:GS Caltex Corporationによって製造されるGS Caltexクーラント
* 前述の説明と一致して、相対粘度は、25℃で毛管粘度計で測定される溶液粘度対溶媒粘度の比であり、ここで、溶媒は96%硫酸であり、溶液は、前記溶媒に溶解した1.0重量%ポリアミドポリマーである。
耐ZnCl2塩性試験
この試験に使用される検体は、射出成形品からカットされた射出成形試験片であったし、それぞれ、80×10×2mmの寸法を有する。試験片をU字形に曲げ、18mmのインサイダー幅を持ったホルダーへ入れた。ホルダーを、試験片を完全に浸す50重量%ZnCl2溶液であらかじめ満たされた、大きな容器に入れた。容器を次に、90℃の温度が維持される、空気循環オーブンに72時間入れた。その後、検体ホルダー中の試験片を、容器から引き出し、90℃での同じ空気循環オーブンにもう24時間入れ、その後試験片の亀裂を調べた。
(クーラントAを使用して)504時間130℃で、または(クーラントBを使用して)144時間146℃で50容積%の水性クーラント溶液中に浸漬し、老化させたタイプ1A検体を使用して、引張強度をISO 527−2に従って測定した。
表1に示されるように量またはポリマー成分が変わる、そしてそれぞれ、上に詳述されたような同じ酸化防止剤、熱安定剤、および潤滑剤などの1重量%の他の添加剤を組み込んだ、少なくとも1種のポリアミドポリマーと、ポリケトンとゴム成分とのブレンド試料を、Coperion二軸スクリュー押出機を用いて調製する。これらの試料を次に、二個取りISO金型を用いて射出成形した。このように成形された物品をそれぞれ、表2に示されるように、機械的および化学的特性について(成形されたまま乾燥状態で)試験した。
これらの比較例では、様々なポリアミド/ポリケトンブレンドを、ただゴム成分なしで、実施例1〜3と同じ方法で作製した。これらのブレンドをまた、二個取りISO金型を用いて射出成形した。それらからのこのように成形された物品をそれぞれ、表2に比較例1〜4として示される、機械的および化学的特性について(成形されたまま乾燥状態で)試験した。
Claims (13)
- ポリアミド組成物[組成物(C)]であって、
− 少なくとも1種のポリアミド[ポリアミド(A)]と;
− 前記組成物(C)の総重量を基準として、1〜4重量%の量で、少なくとも1種のポリケトン[ポリケトン(K)]と;
− 前記組成物(C)の総重量を基準として、15〜35重量%の量で、少なくとも1種のゴム[ゴム(R)]と
を含むポリアミド組成物において、
前記組成物(C)がノボラック樹脂を含まない、ポリアミド組成物。 - 少なくとも2種のポリアミドのブレンドを含む、請求項1のポリアミド組成物。
- 前記ポリアミド(A)が、ポリ(ε−カプロラクタム)(PA 6)、ポリ(テトラメチレンアジパミド)(PA 46)、ポリ(ヘキサメチレンアジパミド)(PA 66)、ポリ(ヘキサメチレンデカンジアミド)(PA 610)、ポリ(デカメチレンデカンジアミド)(PA 1010)、ポリ(デカメチレンドデカンジアミド)(PA 1012)、およびポリ(ドデカメチレンドデカンジアミド)(PA 1212)からなる群から選択される、請求項1または2に記載のポリアミド組成物。
- 少なくともアミノカルボン酸[アミノ酸(AN)]を含む混合物(M3)の縮合生成物である少なくとも1種のポリアミド(A)を含む、請求項1または2に記載のポリアミド組成物であって、前記アミノ酸(AN)が、6−アミノヘキサン酸、9−アミノノナン酸、10−アミノデカン酸、11−アミノウンデカン酸、および12−アミノドデカン酸からなる群から選択されるポリアミド組成物。
- 前記ポリケトン(K)が脂肪族である、請求項1〜4のいずれか一項に記載のポリアミド組成物。
- 前記ポリケトン(K)が、下式:
−(CO−CH2−CH2)x−(CO−A)y−
(式中、Aは、少なくとも3個の炭素原子を有するエチレン性不飽和炭化水素基を意味し、x/y比は少なくとも2である)
の繰り返し単位を含む、請求項1〜5のいずれか一項に記載のポリアミド組成物。 - 前記ゴム(R)がエチレンコポリマーゴムである、請求項1〜6のいずれか一項に記載のポリアミド組成物。
- 前記ゴム(R)が、エチレンアクリル酸(EAA)コポリマーである、請求項7に記載のポリアミド組成物。
- 前記組成物(C)が、前記組成物(C)の総重量を基準として、5重量%よりも低い、好ましくは1重量%よりも低い量で可塑剤を含有する、請求項1〜8のいずれか一項に記載のポリアミド組成物。
- 前記組成物(C)を押出成形すること、または前記組成物(C)を射出成形することによって、請求項1〜9のいずれか一項に記載のポリアミド組成物から製造される物品。
- 押出、射出成形、熱成形、圧縮成形およびブロー成形からなる群から好ましくは選択される、任意の造形技術によって、請求項1〜9のいずれか一項に記載の前記組成物(C)を造形することによる物品の製造方法。
- 前記造形技術が押出を含む、請求項11に記載の方法。
- 前記物品が、フィルム、チューブ類、自動車部品、エンジン部品および電気/エレクトロニクス部品のいずれかである、請求項11または12に記載の方法。
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Families Citing this family (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3168252B1 (de) * | 2015-11-13 | 2019-01-09 | Ems-Patent Ag | Polyketon-formmassen mit verbesserten eigenschaften, hieraus hergestellter formkörper sowie verfahren zu dessen herstellung |
CN106336658B (zh) * | 2016-08-29 | 2019-06-28 | 会通新材料股份有限公司 | 一种红磷阻燃增强pa66与pok合金材料及其制备方法 |
KR102278533B1 (ko) | 2016-12-27 | 2021-07-16 | 주식회사 엘지화학 | 폴리알킬렌 카보네이트계 수지 필름 |
KR101878795B1 (ko) * | 2017-03-22 | 2018-08-16 | 주식회사 효성 | 내열성이 개선된 폴리케톤 조성물 |
KR102011912B1 (ko) * | 2017-11-14 | 2019-08-20 | 효성화학 주식회사 | 유연성이 향상된 고충격 내열 폴리케톤 얼로이 수지 조성물 |
KR102011917B1 (ko) * | 2017-11-16 | 2019-08-20 | 효성화학 주식회사 | 장기 내열성이 우수한 고충격 폴리케톤 조성물 |
KR101956616B1 (ko) * | 2018-01-18 | 2019-03-11 | 효성화학 주식회사 | 폴리케톤 튜브 및 이의 제조방법 |
KR20180085374A (ko) | 2018-06-14 | 2018-07-26 | 주식회사 효성 | 폴리케톤이 적용된 예초기용 커버 부품 |
KR102101214B1 (ko) * | 2018-10-02 | 2020-04-20 | 효성화학 주식회사 | 난연성 및 내열성이 향상된 폴리케톤 조성물 |
KR20200115784A (ko) * | 2019-03-26 | 2020-10-08 | 현대모비스 주식회사 | 내구성 및 내흡습성이 우수한 웜휠용 조성물 및 이를 이용하여 제조된 웜휠 |
CN115066454A (zh) * | 2020-02-05 | 2022-09-16 | 科德宝集团 | 交联脂肪族聚酮 |
KR102264823B1 (ko) * | 2020-03-26 | 2021-06-15 | 주식회사 엘라스코 | 연료 주입관 제조용 열가소성 수지 조성물 및 이의 제조방법 |
US20230242761A1 (en) * | 2020-06-30 | 2023-08-03 | Avient Corporation | Polymer blends of polyamide and aliphatic polyketone |
CN113388246B (zh) * | 2021-05-27 | 2022-10-25 | 广州辰东新材料有限公司 | 一种长碳链聚酰胺、聚酮和聚苯硫醚合金材料及其制备方法 |
EP4373898A1 (en) | 2021-07-19 | 2024-05-29 | Zephyros Inc. | Acrylate adhesive for contact with liquid coolant |
WO2024041951A1 (en) * | 2022-08-23 | 2024-02-29 | Basf Se | Polyamide composition and article produced from the composition |
CN115637030B (zh) * | 2022-10-31 | 2023-07-21 | 链行走新材料科技(广州)有限公司 | 一种含有聚酮的组合物及其在制备高分子复合材料中的应用 |
WO2024127346A1 (en) * | 2022-12-16 | 2024-06-20 | 3M Innovative Properties Company | Cooling plate assembly and two-part curable adhesive composition |
CN118063961B (zh) * | 2024-04-17 | 2024-07-19 | 山东祥龙新材料股份有限公司 | 一种柔性阻隔挤出聚酰胺材料及其制备方法和尼龙管 |
Family Cites Families (27)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1694173A1 (de) | 1967-07-22 | 1971-06-09 | Hoechst Ag | Thermoplastische Polyesterformmassen |
US3694412A (en) | 1971-03-04 | 1972-09-26 | Shell Oil Co | Process for preparing interpolymers of carbon monoxide in the presence of aryl phosphine-palladium halide complex |
IT963692B (it) | 1972-08-03 | 1974-01-21 | Montedison Spa | Poliesteri antiurto |
DE2927576A1 (de) | 1979-07-07 | 1981-01-15 | Bayer Ag | Hochschlagzaehes polybutylenterephthalat |
DE3039115A1 (de) | 1980-10-16 | 1982-05-13 | Bayer Ag, 5090 Leverkusen | Thermoplastische polyester-formmassen mit verbesserter zaehigkeit |
IN166314B (ja) | 1985-08-29 | 1990-04-07 | Shell Int Research | |
NL8602164A (nl) | 1986-08-26 | 1988-03-16 | Shell Int Research | Katalysatorcomposities. |
DE3735404A1 (de) | 1987-10-20 | 1989-05-03 | Basf Ag | Thermoplastische formmassen auf der basis von polyamidmischungen |
USH988H (en) * | 1989-10-31 | 1991-11-05 | Shell Oil Company | Polymer blends |
USH1021H (en) * | 1989-10-31 | 1992-02-04 | Shell Oil Company | Reinforced polymer blends |
US5175210A (en) * | 1991-06-14 | 1992-12-29 | Shell Oil Company | Polymer blends |
JPH07504587A (ja) | 1992-03-16 | 1995-05-25 | マッカーサー−オンスロー、ローン・ジェイムズ | 飲食用器具 |
EP0682057A1 (en) | 1994-05-09 | 1995-11-15 | Dsm N.V. | Process for improvement of the processing characteristics of a polymer composition and polymer compositions obtained therefrom |
US5486594A (en) | 1994-07-11 | 1996-01-23 | Shell Oil Company | Polyketone polymers as nylon toughners |
DE69609417T2 (de) | 1995-05-03 | 2001-03-15 | Dsm N.V., Heerlen | Verzweigtes sternförmiges polyamid |
EP0832149B1 (en) | 1995-05-03 | 2000-07-19 | Dsm N.V. | Star-shaped branched polyamide |
PT869987E (pt) | 1995-12-29 | 2002-11-29 | Rhodia Eng Plastics Srl | Composicao que contem uma poliamida e processo para a sua fabricacao |
FR2743077B1 (fr) | 1995-12-29 | 1998-02-20 | Nyltech Italia | Polyamide et un procede de fabrication de celui-ci, et des compositions le contenant |
DE19654179A1 (de) | 1996-12-23 | 1998-06-25 | Basf Ag | H-förmige Polyamide |
JPH1171514A (ja) * | 1997-06-25 | 1999-03-16 | Toray Ind Inc | 熱可塑性樹脂組成物 |
FR2766197B1 (fr) | 1997-07-17 | 1999-09-03 | Nyltech Italia | Copolyamide thermoplastique, composition a base de ce copolyamide thermoplastique |
DE19757607A1 (de) * | 1997-12-23 | 1999-07-01 | Inventa Ag | Polyamid/Polyketon-Blends |
FR2779730B1 (fr) | 1998-06-11 | 2004-07-16 | Nyltech Italia | Polyamides a fluidite elevee, son procede de fabrication, compositions comprenant ce copolyamide |
FR2793252B1 (fr) | 1999-05-05 | 2001-07-20 | Rhodianyl | Copolyamide hyperbranche, composition a base de ce copolyamide hyperbranche et procede d'obtention de ce dernier |
FR2958652B1 (fr) * | 2010-04-13 | 2013-09-06 | Rhodia Operations | Composition thermoplastique a base de polyamide et de polycetone. |
KR20120077366A (ko) * | 2010-12-30 | 2012-07-10 | 주식회사 효성 | 내충격성이 향상된 폴리케톤과 나일론의 블렌드 |
KR20120118737A (ko) * | 2011-04-19 | 2012-10-29 | 현대자동차주식회사 | 내충격성이 우수한 폴리케톤 조성물 |
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US20160222209A1 (en) | 2016-08-04 |
EP3046965B1 (en) | 2018-05-02 |
KR102232673B1 (ko) | 2021-03-29 |
JP6595485B2 (ja) | 2019-10-23 |
JP2019143154A (ja) | 2019-08-29 |
BR112016005658B1 (pt) | 2021-10-26 |
JP2016530391A (ja) | 2016-09-29 |
US10336903B2 (en) | 2019-07-02 |
BR112016005658A2 (ja) | 2017-08-01 |
EP3046965A1 (en) | 2016-07-27 |
KR20160056917A (ko) | 2016-05-20 |
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CN105722917B (zh) | 2019-03-01 |
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