JP6811774B2 - 異性体のアルカジエナール又は異性体のアルカジエンニトリルを含む芳香組成物及び風味組成物 - Google Patents
異性体のアルカジエナール又は異性体のアルカジエンニトリルを含む芳香組成物及び風味組成物 Download PDFInfo
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- JP6811774B2 JP6811774B2 JP2018525358A JP2018525358A JP6811774B2 JP 6811774 B2 JP6811774 B2 JP 6811774B2 JP 2018525358 A JP2018525358 A JP 2018525358A JP 2018525358 A JP2018525358 A JP 2018525358A JP 6811774 B2 JP6811774 B2 JP 6811774B2
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- 238000006731 degradation reaction Methods 0.000 description 1
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- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 1
- 150000002016 disaccharides Chemical class 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- ZOPSBGWAEUUZRZ-UHFFFAOYSA-N dodeca-2,11-dienal Chemical compound C=CCCCCCCCC=CC=O ZOPSBGWAEUUZRZ-UHFFFAOYSA-N 0.000 description 1
- VPEGROOEBNSCCL-UHFFFAOYSA-N dodeca-2,6-dienal Chemical class CCCCCC=CCCC=CC=O VPEGROOEBNSCCL-UHFFFAOYSA-N 0.000 description 1
- IGHIBSCIQDZQGE-UHFFFAOYSA-N dodeca-2,7-dienal Chemical compound CCCCC=CCCCC=CC=O IGHIBSCIQDZQGE-UHFFFAOYSA-N 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 235000019414 erythritol Nutrition 0.000 description 1
- UNXHWFMMPAWVPI-ZXZARUISSA-N erythritol Chemical compound OC[C@H](O)[C@H](O)CO UNXHWFMMPAWVPI-ZXZARUISSA-N 0.000 description 1
- 229940009714 erythritol Drugs 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- 235000019325 ethyl cellulose Nutrition 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
- 229940057975 ethyl citrate Drugs 0.000 description 1
- 229940093503 ethyl maltol Drugs 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 210000004709 eyebrow Anatomy 0.000 description 1
- 230000001815 facial effect Effects 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000012458 free base Substances 0.000 description 1
- 229930182830 galactose Natural products 0.000 description 1
- 235000008397 ginger Nutrition 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 239000001087 glyceryl triacetate Substances 0.000 description 1
- 235000013773 glyceryl triacetate Nutrition 0.000 description 1
- 235000009569 green tea Nutrition 0.000 description 1
- 239000000118 hair dye Substances 0.000 description 1
- 239000008266 hair spray Substances 0.000 description 1
- 239000008123 high-intensity sweetener Substances 0.000 description 1
- 150000004678 hydrides Chemical class 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 235000015243 ice cream Nutrition 0.000 description 1
- 239000000077 insect repellent Substances 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- 239000000905 isomalt Substances 0.000 description 1
- 235000010439 isomalt Nutrition 0.000 description 1
- HPIGCVXMBGOWTF-UHFFFAOYSA-N isomaltol Natural products CC(=O)C=1OC=CC=1O HPIGCVXMBGOWTF-UHFFFAOYSA-N 0.000 description 1
- 125000000468 ketone group Chemical group 0.000 description 1
- 239000000832 lactitol Substances 0.000 description 1
- 235000010448 lactitol Nutrition 0.000 description 1
- VQHSOMBJVWLPSR-JVCRWLNRSA-N lactitol Chemical compound OC[C@H](O)[C@@H](O)[C@@H]([C@H](O)CO)O[C@@H]1O[C@H](CO)[C@H](O)[C@H](O)[C@H]1O VQHSOMBJVWLPSR-JVCRWLNRSA-N 0.000 description 1
- 229960003451 lactitol Drugs 0.000 description 1
- 229930007744 linalool Natural products 0.000 description 1
- CSNNHWWHGAXBCP-UHFFFAOYSA-L magnesium sulphate Substances [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- 239000000594 mannitol Substances 0.000 description 1
- 235000010355 mannitol Nutrition 0.000 description 1
- 229960001855 mannitol Drugs 0.000 description 1
- 235000020331 mate tea Nutrition 0.000 description 1
- 229940103903 medicated shampoo Drugs 0.000 description 1
- 239000001525 mentha piperita l. herb oil Substances 0.000 description 1
- 239000001683 mentha spicata herb oil Substances 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- OSWPMRLSEDHDFF-UHFFFAOYSA-N methyl salicylate Chemical compound COC(=O)C1=CC=CC=C1O OSWPMRLSEDHDFF-UHFFFAOYSA-N 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 239000004530 micro-emulsion Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
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- 230000004048 modification Effects 0.000 description 1
- 235000019426 modified starch Nutrition 0.000 description 1
- 150000002772 monosaccharides Chemical class 0.000 description 1
- DUNCVNHORHNONW-UHFFFAOYSA-N myrcenol Chemical compound CC(C)(O)CCCC(=C)C=C DUNCVNHORHNONW-UHFFFAOYSA-N 0.000 description 1
- 229930008383 myrcenol Natural products 0.000 description 1
- 235000019412 neotame Nutrition 0.000 description 1
- HLIAVLHNDJUHFG-HOTGVXAUSA-N neotame Chemical compound CC(C)(C)CCN[C@@H](CC(O)=O)C(=O)N[C@H](C(=O)OC)CC1=CC=CC=C1 HLIAVLHNDJUHFG-HOTGVXAUSA-N 0.000 description 1
- 108010070257 neotame Proteins 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 235000013615 non-nutritive sweetener Nutrition 0.000 description 1
- 235000020333 oolong tea Nutrition 0.000 description 1
- JVTCAITYYWADCL-UHFFFAOYSA-N pentadeca-2,11-dienenitrile Chemical compound C(C=CCCCCCCCC=CCCC)#N JVTCAITYYWADCL-UHFFFAOYSA-N 0.000 description 1
- GNRUODIJARTZQU-UHFFFAOYSA-N pentadeca-2,14-dienal Chemical class C=CCCCCCCCCCCC=CC=O GNRUODIJARTZQU-UHFFFAOYSA-N 0.000 description 1
- 125000002255 pentenyl group Chemical group C(=CCCC)* 0.000 description 1
- 150000002972 pentoses Chemical class 0.000 description 1
- 235000019477 peppermint oil Nutrition 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 239000000825 pharmaceutical preparation Substances 0.000 description 1
- 229940127557 pharmaceutical product Drugs 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 235000011962 puddings Nutrition 0.000 description 1
- 230000035909 sensory irritation Effects 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 229960002920 sorbitol Drugs 0.000 description 1
- 235000019721 spearmint oil Nutrition 0.000 description 1
- 235000019654 spicy taste Nutrition 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 235000020354 squash Nutrition 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 150000005846 sugar alcohols Chemical class 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 230000000475 sunscreen effect Effects 0.000 description 1
- 239000000516 sunscreening agent Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- UUCDPGSGMIHSHN-UHFFFAOYSA-N tetradeca-2,10-diene Chemical compound CCCC=CCCCCCCC=CC UUCDPGSGMIHSHN-UHFFFAOYSA-N 0.000 description 1
- 229940095068 tetradecene Drugs 0.000 description 1
- 235000015149 toffees Nutrition 0.000 description 1
- 235000015961 tonic Nutrition 0.000 description 1
- 230000001256 tonic effect Effects 0.000 description 1
- 229960000716 tonics Drugs 0.000 description 1
- 230000000699 topical effect Effects 0.000 description 1
- 230000002110 toxicologic effect Effects 0.000 description 1
- 231100000027 toxicology Toxicity 0.000 description 1
- 229960002622 triacetin Drugs 0.000 description 1
- MRRQJBCDRPFHRW-UHFFFAOYSA-N trideca-2,8-dienenitrile Chemical compound C(C=CCCCCC=CCCCC)#N MRRQJBCDRPFHRW-UHFFFAOYSA-N 0.000 description 1
- 239000001069 triethyl citrate Substances 0.000 description 1
- VMYFZRTXGLUXMZ-UHFFFAOYSA-N triethyl citrate Natural products CCOC(=O)C(O)(C(=O)OCC)C(=O)OCC VMYFZRTXGLUXMZ-UHFFFAOYSA-N 0.000 description 1
- 150000004043 trisaccharides Chemical class 0.000 description 1
- BZLIQDALOXDGLU-UHFFFAOYSA-N undeca-2,10-dienenitrile Chemical compound C=CCCCCCCC=CC#N BZLIQDALOXDGLU-UHFFFAOYSA-N 0.000 description 1
- OGWRDLVGVIJYOK-UHFFFAOYSA-N undeca-2,6-dienal Chemical compound CCCCC=CCCC=CC=O OGWRDLVGVIJYOK-UHFFFAOYSA-N 0.000 description 1
- WKFRCXVGJNWFMI-UHFFFAOYSA-N undeca-2,8-dienal Chemical compound CCC=CCCCCC=CC=O WKFRCXVGJNWFMI-UHFFFAOYSA-N 0.000 description 1
- 208000011479 upper respiratory tract disease Diseases 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 239000009637 wintergreen oil Substances 0.000 description 1
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
- C11B9/0007—Aliphatic compounds
- C11B9/0023—Aliphatic compounds containing nitrogen as the only heteroatom
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23C—DAIRY PRODUCTS, e.g. MILK, BUTTER OR CHEESE; MILK OR CHEESE SUBSTITUTES; MAKING THEREOF
- A23C9/00—Milk preparations; Milk powder or milk powder preparations
- A23C9/152—Milk preparations; Milk powder or milk powder preparations containing additives
- A23C9/156—Flavoured milk preparations ; Addition of fruits, vegetables, sugars, sugar alcohols or sweeteners
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L2/00—Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
- A23L2/52—Adding ingredients
- A23L2/56—Flavouring or bittering agents
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L27/00—Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
- A23L27/20—Synthetic spices, flavouring agents or condiments
- A23L27/202—Aliphatic compounds
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L27/00—Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
- A23L27/20—Synthetic spices, flavouring agents or condiments
- A23L27/24—Synthetic spices, flavouring agents or condiments prepared by fermentation
- A23L27/25—Dairy flavours
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L27/00—Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
- A23L27/20—Synthetic spices, flavouring agents or condiments
- A23L27/29—Fruit flavours
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q13/00—Formulations or additives for perfume preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q15/00—Anti-perspirants or body deodorants
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/002—Aftershave preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/02—Preparations for care of the skin for chemically bleaching or whitening the skin
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C255/00—Carboxylic acid nitriles
- C07C255/01—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms
- C07C255/06—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms of an acyclic and unsaturated carbon skeleton
- C07C255/07—Mononitriles
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C47/00—Compounds having —CHO groups
- C07C47/20—Unsaturated compounds having —CHO groups bound to acyclic carbon atoms
- C07C47/21—Unsaturated compounds having —CHO groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
- C11B9/0007—Aliphatic compounds
- C11B9/0015—Aliphatic compounds containing oxygen as the only heteroatom
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2072—Aldehydes-ketones
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Wood Science & Technology (AREA)
- Food Science & Technology (AREA)
- Polymers & Plastics (AREA)
- Nutrition Science (AREA)
- Dermatology (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Emergency Medicine (AREA)
- Biotechnology (AREA)
- Fats And Perfumes (AREA)
- Cosmetics (AREA)
- Seasonings (AREA)
- Detergent Compositions (AREA)
- Dairy Products (AREA)
- Non-Alcoholic Beverages (AREA)
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
Description
E,Z−2,7−デカジエナールの調製
cis−5−オクテナール 15.1g(120mmol)が、温度を20℃未満に保ちながら、無水エタノール(1.5g)及び17.8g オルトギ酸トリエチル(120mmol)に溶解された触媒量のPTSAに供給される。ジエチルアセタールの生成が完了したら、反応混合物が、メタノール中のナトリウムメトキシドの25%溶液で中和され、次いで、軽質分が大気中で100℃までストリッピングされる。
E,Z−2,11−テトラデカジエナールの調製
cis−9−ドデセナール 22.1g(120mmol)が、温度を20℃未満に保ちながら、無水エタノール(1.5g)及び17.8g オルトギ酸トリエチル(120mmol)に溶解された触媒量のPTSAに供給される。ジエチルアセタールの生成が完了したら、反応混合物が、メタノール中のナトリウムメトキシドの25%溶液で中和され、次いで、軽質分が大気中で100℃までストリッピングされる。
E,Z−2,6−オクタジエナールの調製
cis−4−ヘキセナール 11.8g(120mmol)が、温度を20℃未満に保ちながら、無水エタノール(1g)及び17.8g オルトギ酸トリエチル(120mmol)に溶解された触媒量のPTSAに供給される。ジエチルアセタールの生成が完了したら、反応混合物が、メタノール中のナトリウムメトキシドの25%溶液で中和され、次いで、軽質分が大気中で100℃までストリッピングされる。
E,Z−2,7−デカジエナールを含む芳香配合物
アイリスノートを強調するフレッシュ、グリーン、オゾンの、フローラルの香りを与えるために、適切な量のE,Z−2,7−デカジエナールを使用して、嗅覚ファミリーグリーンフローラルに属する香料組成物が配合された。
E,Z−デカジエンニトリル及びその異性体の調製
35.1gのcis−5−オクテナール(198mmol)が、25gのシアノメチルホスホン酸ジエチル(198mmol)と混合され、20〜25℃の温度を保ちながら、24.5gの水中の水酸化カリウムの45%溶液が供給される。反応が完了したら、10gのシクロヘキサンが加えられ、溶液が水で洗われ、クエン酸の5%水溶液で酸性化され、次いで、蒸留前に、炭酸ナトリウムの5%水溶液で中和される。未精製の異性体比は、31% E,Eに対して約69% E,Zである。異性体の含有量は蒸留を経て向上され得る。
Claims (11)
- 組成物であって、芳香又は風味を前記組成物に与えるために有効な量の少なくとも1つの異性体のアルカジエナール又は少なくとも1つの異性体のアルカジエンニトリルを含み;前記少なくとも1つの異性体のアルカジエナールが、
E,Z−2,7−デカジエナール、
E,Z−2,7−ウンデカジエナール、
E,Z−2,8−ウンデカジエナール、
E,Z−2,10−トリデカジエナール、及び
E,Z−2,11−テトラデカジエナールからなる群から選択され;
且つ前記少なくとも1つの異性体のアルカジエンニトリルが、
E,Z−2,7−デカジエンニトリルから選択され;
前記少なくとも1つの異性体のアルカジエナール又は前記少なくとも1つの異性体のアルカジエンニトリルが、前記組成物中の全Z及びE異性体に基づいて、0.1体積パーセント〜99.5体積パーセントのE,Z異性体、0.1体積パーセント〜99.5体積パーセントのZ,E異性体、0.1体積パーセント〜99.5体積パーセントのE,E異性体、及び0.1体積パーセント〜99.5体積パーセントのZ,Z異性体を有する、組成物。 - 前記少なくとも1つの異性体のアルカジエナール又は前記少なくとも1つの異性体のアルカジエンニトリルが、前記組成物中の全Z及びE異性体に基づいて、10体積パーセント〜98体積パーセントのE,Z異性体、0.5体積パーセント〜40体積パーセントのZ,E異性体、0.1体積パーセント〜40体積パーセントのE,E異性体、及び2体積パーセント〜40体積パーセントのZ,Z異性体を有する、請求項1に記載の組成物。
- 前記少なくとも1つの異性体のアルカジエナール又は前記少なくとも1つの異性体のアルカジエンニトリルが、芳香を前記組成物に与えるために、前記組成物の全重量に基づいて、少なくとも1重量ppmの量で存在する、請求項1に記載の組成物。
- 前記少なくとも1つの異性体のアルカジエナール又は前記少なくとも1つの異性体のアルカジエンニトリルが、風味を前記組成物に与えるために、前記組成物の全重量に基づいて、少なくとも0.1重量ppmの量で存在する、請求項1に記載の組成物。
- 前記少なくとも1つの異性体のアルカジエナール又は前記少なくとも1つの異性体のアルカジエンニトリルが、芳香を前記組成物に与えるために、ゲラニオール、酢酸ゲラニル、リナロール、酢酸リナリル、テトラヒドロリナロール、シトロネロール、酢酸シトロネリル、ジヒドロミルセノール、ジヒドロミルセニルアセタート、テトラヒドロミルセノール、テルピネオール、酢酸テルピニル、ノポール、ノピルアセタート、2−フェニルエタノール、2−フェニルエチルアセタート、ベンジルアルコール、酢酸ベンジル、サリチル酸ベンジル、スチラリルアセタート、安息香酸ベンジル、サリチル酸アミル、ジメチル−ベンジルカルビノール、トリクロロメチルフェニルカルビニルアセタート、p−tert−ブチルシクロヘキシルアセタート、酢酸イソノニル、ベチベリルアセタート、ベチベロール、アルファ−ヘキシルシンナム−アルデヒド、2−メチル−3−(p−tert−ブチルフェニル)−プロパナール、2−メチル−3−(p−イソプロピルフェニル)−プロパナール、3−(p−tert−ブチルフェニル)−プロパナール、トリシクロデセニルアセタート、トリシクロデセニルプロピオナート、4−(4−ヒドロキシ−4−メチルペンチル)−3−シクロヘキセンカルボアルデヒド、4−(4−メチル−3−ペンテニル)−3−シクロヘキセンカルボアルデヒド、4−アセトキシ−3−ペンチル−テトラヒドロピラン、3−カルボキシメチル−2−ペンチルシクロペンタン、2−n−ヘプチルシクロペンタノン、3−メチル−2−ペンチル−2−シクロペンテノン、n−デカナール、n−ドデカナール、9−デセン−1−オール、フェノキシエチルイソブチラート、フェニルアセトアルデヒドジメチルアセタール、フェニルアセトアルデヒド−ジエチルアセタール、ゲラニルニトリル、シトロネリルニトリル、セドリルアセタート、3−イソカンフィルシクロヘキサノール、セドリルメチルエーテル、イソロンギホラノン、オーベピニトリル、オーベピン、ヘリオトロピン、クマリン、オイゲノール、バニリン、ジフェニルオキシド、ヒドロキシシトロネラール、イオノン類、メチルイオノン類、イソメチルイオノン類、イロン類、cis−3−ヘキセノール及びcis−3−ヘキセノールのエステル類、インダン−ムスク類、テトラリン−ムスク類、イソクロマン−ムスク類、大環状ケトン類、マクロラクトン−ムスク類、ブラシル酸エチレン、又は芳香族ニトロムスク類と組み合わせられる、請求項1に記載の組成物。
- 前記少なくとも1つの異性体のアルカジエナール又は前記少なくとも1つの異性体のアルカジエンニトリルが、風味を前記組成物に与えるために、ゲラニオール、酢酸ゲラニル、リナロール、酢酸リナリル、シトロネロール、酢酸シトロネリル、テルピネオール、酢酸テルピニル、2−フェニルエタノール、2−フェニルエチルアセタート、ベンジルアルコール、酢酸ベンジル、サリチル酸ベンジル、ヘリオトロピン、ベンズアルデヒド、アニスアルデヒド、サリチル酸ベンジル、n−デカナール、n−ドデカナール、9−デセン−1−オール、クマリン、オイゲノール、バニリン、ヘキサナール、ユーカリプトール、イオノン類、メチルイオノン類、イソメチルイオノン類、イロン類、cis−3−ヘキセノール及びcis−3−ヘキセノールのエステル類、アセトアルデヒド、酢酸エチル、エチルブチラートシンナミックアルデヒド、クミンアルデヒド、フルフラール、シンナミックアルデヒド、マルトール、エチルマルトール、ジメチルスルフィド、ガンマデカラクトン、ガンマウンデカラクトン、ジアセチル、吉草酸エチル、ダマスコン、ダマセノン、カプロン酸メチル、シクロテン、酪酸、アセトイン、デルタデカラクトン、フラネオール、アセトイン、ベンゾジヒドロピロン、2,6−ノナジエナール、メロナール又はメチルヘプタンカルボナートと組み合わせられる、請求項1に記載の組成物。
- 芳香又は風味組成物であって、芳香又は風味を前記組成物に与えるために有効な量の少なくとも1つの異性体のアルカジエナール又は少なくとも1つの異性体のアルカジエンニトリルを含み;前記少なくとも1つの異性体のアルカジエナールが、
E,Z−2,7−デカジエナール、
E,Z−2,7−ウンデカジエナール、
E,Z−2,8−ウンデカジエナール、
E,Z−2,10−トリデカジエナール、及び
E,Z−2,11−テトラデカジエナールからなる群から選択され;
且つ前記少なくとも1つの異性体のアルカジエンニトリルが、
E,Z−2,7−デカジエンニトリルから選択され;
前記少なくとも1つの異性体のアルカジエナール又は前記少なくとも1つの異性体のアルカジエンニトリルが、前記組成物中の全Z及びE異性体に基づいて、0.1体積パーセント〜99.5体積パーセントのE,Z異性体、0.1体積パーセント〜99.5体積パーセントのZ,E異性体、0.1体積パーセント〜99.5体積パーセントのE,E異性体、及び0.1体積パーセント〜99.5体積パーセントのZ,Z異性体を有する、芳香又は風味組成物。 - 請求項7に記載の芳香又は風味組成物を含む消費者製品。
- ろうそく、エアケア製品、香水、コロン、石けん、パーソナルケア製品、洗剤、ファブリックケア製品、及び家庭用洗浄製品からなる群から選択される、請求項8に記載の消費者製品。
- 石けん、洗剤、エアフレッシュナー、ルームスプレー、匂い玉、ろうそく、並びにクリーム、軟膏、化粧水、プレシェーブローション、アフターシェーブローション、タルカムパウダー、ヘアケア剤、ボディデオドラント、及び制汗剤を含む化粧品からなる群から選択される、請求項8に記載の消費者製品。
- 芳香又は風味を消費者製品に与える方法であって、芳香又は風味を前記消費者製品に与えるために有効な量の少なくとも1つの異性体のアルカジエナール又は少なくとも1つの異性体のアルカジエンニトリルを含む芳香又は風味組成物を前記消費者製品に加えることを含み;前記少なくとも1つの異性体のアルカジエナールが、
E,Z−2,7−デカジエナール、
E,Z−2,7−ウンデカジエナール、
E,Z−2,8−ウンデカジエナール、
E,Z−2,10−トリデカジエナール、及び
E,Z−2,11−テトラデカジエナールからなる群から選択され;
且つ前記少なくとも1つの異性体のアルカジエンニトリルが、
E,Z−2,7−デカジエンニトリルから選択され;
前記少なくとも1つの異性体のアルカジエナール又は前記少なくとも1つの異性体のアルカジエンニトリルが、前記組成物中の全Z及びE異性体に基づいて、0.1体積パーセント〜99.5体積パーセントのE,Z異性体、0.1体積パーセント〜99.5体積パーセントのZ,E異性体、0.1体積パーセント〜99.5体積パーセントのE,E異性体、及び0.1体積パーセント〜99.5体積パーセントのZ,Z異性体を有する、方法。
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US20220042051A1 (en) * | 2018-10-19 | 2022-02-10 | Firmenich Sa | Lipoxygenase-catalyzed production of unsaturated c10-aldehydes from polyunsatrurated fatty acids |
RU2769674C1 (ru) * | 2021-09-20 | 2022-04-04 | Елена Викторовна Борисенко | Пищевой ароматизатор, придающий вкус и аромат концентрированного молока |
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CH527897A (de) | 1969-04-26 | 1972-09-15 | Givaudan & Cie Sa | Riech- oder Geschmackstoffkomposition |
FR2119580A5 (ja) | 1970-12-22 | 1972-08-04 | Firmenich & Cie | |
US3821421A (en) | 1971-07-06 | 1974-06-28 | Lever Brothers Ltd | Process for the flavouring of foods |
US3922310A (en) * | 1972-10-12 | 1975-11-25 | Gen Foods Corp | Flavor compositions and processes |
US3960923A (en) * | 1973-12-03 | 1976-06-01 | Rhodia, Inc. | Process for the preparation of α,β-unsaturated nitriles |
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NL185194C (nl) * | 1976-07-27 | 1990-02-16 | Naarden International Nv | Werkwijze voor de bereiding van reukstofcomposities, alsmede werkwijze voor de bereiding van een reukstof. |
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WO2004071194A2 (en) * | 2003-02-13 | 2004-08-26 | University Of Florida | Enhancing the fragrance of an article |
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