JP6673596B2 - 金属錯体触媒、それを使用した重合方法、及びそのポリマー生成物 - Google Patents

金属錯体触媒、それを使用した重合方法、及びそのポリマー生成物 Download PDF

Info

Publication number
JP6673596B2
JP6673596B2 JP2017514996A JP2017514996A JP6673596B2 JP 6673596 B2 JP6673596 B2 JP 6673596B2 JP 2017514996 A JP2017514996 A JP 2017514996A JP 2017514996 A JP2017514996 A JP 2017514996A JP 6673596 B2 JP6673596 B2 JP 6673596B2
Authority
JP
Japan
Prior art keywords
group
polymer
complex
aluminum
polymerization
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
JP2017514996A
Other languages
English (en)
Japanese (ja)
Other versions
JP2017516911A5 (OSRAM
JP2017516911A (ja
Inventor
ジョシュア ピー アベル
ジョシュア ピー アベル
ヅァンチュアン チン
ヅァンチュアン チン
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bridgestone Corp
Original Assignee
Bridgestone Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bridgestone Corp filed Critical Bridgestone Corp
Publication of JP2017516911A publication Critical patent/JP2017516911A/ja
Publication of JP2017516911A5 publication Critical patent/JP2017516911A5/ja
Application granted granted Critical
Publication of JP6673596B2 publication Critical patent/JP6673596B2/ja
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F236/06Butadiene
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00Metallocenes
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02Silicon compounds
    • C07F7/08Compounds having one or more C—Si linkages
    • C07F7/10Compounds having one or more C—Si linkages containing nitrogen having a Si-N linkage
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/06Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/54Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with other compounds thereof
    • C08F4/545Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with other compounds thereof rare earths being present, e.g. triethylaluminium + neodymium octanoate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/639Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/6392Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00Metallocene catalysts
    • C08F2420/03Cp or analog not bridged to a non-Cp X ancillary neutral donor
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2800/00Copolymer characterised by the proportions of the comonomers expressed
    • C08F2800/10Copolymer characterised by the proportions of the comonomers expressed as molar percentages
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2810/00Chemical modification of a polymer
    • C08F2810/40Chemical modification of a polymer taking place solely at one end or both ends of the polymer backbone, i.e. not in the side or lateral chains

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polymerization Catalysts (AREA)
  • Graft Or Block Polymers (AREA)
JP2017514996A 2014-05-31 2015-05-26 金属錯体触媒、それを使用した重合方法、及びそのポリマー生成物 Active JP6673596B2 (ja)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US201462006119P 2014-05-31 2014-05-31
US62/006,119 2014-05-31
US201562136302P 2015-03-20 2015-03-20
US62/136,302 2015-03-20
PCT/US2015/032373 WO2015183781A1 (en) 2014-05-31 2015-05-26 Metallic complex catalyst, polymerization methods employing same and polymer products thereof

Related Child Applications (1)

Application Number Title Priority Date Filing Date
JP2019229141A Division JP7187432B2 (ja) 2014-05-31 2019-12-19 金属錯体触媒、それを使用した重合方法、及びそのポリマー生成物

Publications (3)

Publication Number Publication Date
JP2017516911A JP2017516911A (ja) 2017-06-22
JP2017516911A5 JP2017516911A5 (OSRAM) 2017-10-05
JP6673596B2 true JP6673596B2 (ja) 2020-03-25

Family

ID=54699635

Family Applications (2)

Application Number Title Priority Date Filing Date
JP2017514996A Active JP6673596B2 (ja) 2014-05-31 2015-05-26 金属錯体触媒、それを使用した重合方法、及びそのポリマー生成物
JP2019229141A Active JP7187432B2 (ja) 2014-05-31 2019-12-19 金属錯体触媒、それを使用した重合方法、及びそのポリマー生成物

Family Applications After (1)

Application Number Title Priority Date Filing Date
JP2019229141A Active JP7187432B2 (ja) 2014-05-31 2019-12-19 金属錯体触媒、それを使用した重合方法、及びそのポリマー生成物

Country Status (7)

Country Link
US (2) US10457765B2 (OSRAM)
EP (2) EP3148938B1 (OSRAM)
JP (2) JP6673596B2 (OSRAM)
CN (2) CN106660819B (OSRAM)
BR (1) BR112016027987B1 (OSRAM)
RU (3) RU2690373C2 (OSRAM)
WO (1) WO2015183781A1 (OSRAM)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BR112016028132B1 (pt) 2014-05-30 2022-04-19 Bridgestone Corporation Catalisador de complexo metálico e métodos de polimerização usando os mesmos
EP3680265B1 (en) * 2017-09-04 2024-01-17 Bridgestone Corporation Method for producing copolymer, copolymer, rubber composition, and tire
JP7495880B2 (ja) * 2018-03-30 2024-06-05 ダウ グローバル テクノロジーズ エルエルシー オレフィン重合のための助触媒としての高溶解性アルキル置換ホウ酸カルベニウム
EP3774934A1 (en) 2018-03-30 2021-02-17 Dow Global Technologies LLC Highly soluble bis-borate as binuclear co-catalysts for olefin polymerizations
JP7041585B2 (ja) * 2018-05-21 2022-03-24 株式会社ブリヂストン 重合触媒、及び、共重合体の製造方法
JP7009307B2 (ja) * 2018-05-21 2022-01-25 株式会社ブリヂストン 重合触媒、及び、共重合体の製造方法
US12227018B2 (en) 2020-11-25 2025-02-18 Nidek Co., Ltd. Dye-deposited base body manufacturing apparatus and dyeing system
JP7654963B2 (ja) 2020-11-25 2025-04-02 株式会社ニデック 染料付基体製造装置および染色システム
CN120981495A (zh) 2023-02-08 2025-11-18 埃克森美孚技术与工程公司 用于共聚的催化剂
WO2024253829A1 (en) 2023-06-06 2024-12-12 ExxonMobil Technology and Engineering Company Solution catalyst systems and uses thereof

Family Cites Families (89)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4926307B1 (OSRAM) * 1970-06-10 1974-07-08
US3978103A (en) 1971-08-17 1976-08-31 Deutsche Gold- Und Silber-Scheideanstalt Vormals Roessler Sulfur containing organosilicon compounds
US3873489A (en) 1971-08-17 1975-03-25 Degussa Rubber compositions containing silica and an organosilane
GB1423016A (en) * 1972-12-20 1976-01-28 Snam Progetti Mono-olefin-conjugated diene copolymerisation using a ternary catalyst system
SU580840A3 (ru) 1974-02-07 1977-11-15 Дегусса (Фирма) Способ получени серосодержащих кремнийорганических соединений
US4015061A (en) 1975-02-14 1977-03-29 The Firestone Tire & Rubber Company Protected amino-functional initiators and amino-terminated polymers and their production
US4002594A (en) 1975-07-08 1977-01-11 Ppg Industries, Inc. Scorch retardants for rubber reinforced with siliceous pigment and mercapto-type coupling agent
DE3021273A1 (de) * 1979-06-12 1981-01-08 Mitsubishi Petrochemical Co Ungesaettigte mischpolymerisate
DE2943129A1 (de) * 1979-10-25 1981-05-07 Bayer Ag, 5090 Leverkusen Alternierende isopren-ethylen-copolymere sowie ein verfahren zu ihrer herstellung
DE3017539A1 (de) * 1980-05-08 1981-11-12 Bayer Ag, 5090 Leverkusen Verfahren zur herstellung von alternierenden butadien-propylen-copolymeren
US4616069A (en) 1984-10-26 1986-10-07 Nippon Zeon Co., Ltd. Process for making diene polymer rubbers
US5191052A (en) * 1985-06-21 1993-03-02 Exxon Chemical Patents Inc. Copolymers of ethylene and 1,3-butadiene
US4906706A (en) 1986-09-05 1990-03-06 Japan Synthetic Rubber Co., Ltd. Modified conjugated diene polymer and process for production thereof
US5064910A (en) 1986-09-05 1991-11-12 Japan Synthetic Rubber Co., Ltd. Preparation of conjugated diene polymers modified with an organo-tin or germanium halide
US4935471A (en) 1987-10-15 1990-06-19 The Goodyear Tire & Rubber Company Capped polydienes
IT1230756B (it) 1989-02-17 1991-10-29 Enichem Elastomers Metodo per la preparazione di polibutadiene a lavorabilita' migliorata.
US5149457A (en) 1989-06-30 1992-09-22 Cyprus Foote Mineral Company Stable mixed lithium amide reagent compositions
US5196138A (en) 1989-06-30 1993-03-23 Cyprus Foote Mineral Company Preparation of mixed lithium amide reagents
US5153159A (en) 1990-04-09 1992-10-06 Bridgestone/Firestone, Inc. Elastomers and products having reduced hysteresis
US5329005A (en) 1992-10-02 1994-07-12 Bridgestone Corporation Soluble anionic polymerization initiators and preparation thereof
BE1006438A3 (fr) * 1992-12-17 1994-08-30 Solvay Systeme catalytique, utilisation de ce systeme catalytique pour la (co)polymerisation d'olefines, procede de preparation de ce systeme catalytique et procede de (co)polymerisation d'olefines.
US5844050A (en) 1993-07-30 1998-12-01 Nippon Zeon Co., Ltd. Modified conjugated diene polymer, process for producing same and composition comprising same
US5567815A (en) 1994-07-18 1996-10-22 Bridgestone Corporation Teritary amine containing antonic initiators used in preparing polymers and process for the preparation thereof
DE4436059A1 (de) 1994-10-10 1996-04-11 Bayer Ag Verfahren zur Herstellung von mittels Nd-Katalysatoren polymerisierten Dienkautschuken mit niedrigem cold-flow und geringem Eigengeruch
DE69518830T2 (de) * 1994-12-20 2001-03-22 Montell Technology Co. B.V., Hoofddorp Polypropylenreaktionsmischung und verfahren zu ihrer herstellung
US5521309A (en) 1994-12-23 1996-05-28 Bridgestone Corporation Tertiary-amino allyl-or xylyl-lithium initiators and method of preparing same
US5496940A (en) 1995-02-01 1996-03-05 Bridgestone Corporation Alkyllithium compounds containing cyclic amines and their use in polymerization
US5580919A (en) 1995-03-14 1996-12-03 The Goodyear Tire & Rubber Company Silica reinforced rubber composition and use in tires
US5610227A (en) 1995-06-07 1997-03-11 Bridgestone/Firestone, Inc. Lithium amino magnesiate polymerization initiators and elastomers having reduced hysteresis
US5583245A (en) 1996-03-06 1996-12-10 The Goodyear Tire & Rubber Company Preparation of sulfur-containing organosilicon compounds
AU2214997A (en) 1996-03-27 1997-10-17 Dow Chemical Company, The Highly soluble olefin polymerization catalyst activator
US5663398A (en) 1996-05-17 1997-09-02 Fmc Corporation Processes for preparing functionalized alkyllithium compounds
US5696197A (en) 1996-06-21 1997-12-09 The Goodyear Tire & Rubber Company Heterogeneous silica carbon black-filled rubber compound
US5663396A (en) 1996-10-31 1997-09-02 The Goodyear Tire & Rubber Company Preparation of sulfur-containing organosilicon compounds
US5786441A (en) 1996-12-31 1998-07-28 Bridgestone Corporation Polymers, elastomeric compounds and products thereof, derived from novel amine compounds containing side-chain organolithium moieties
US5684171A (en) 1997-02-11 1997-11-04 The Goodyear Tire & Rubber Company Process for the preparation of organosilicon polysulfide compounds
US5684172A (en) 1997-02-11 1997-11-04 The Goodyear Tire & Rubber Company Process for the preparation of organosilicon polysulfide compounds
ES2198651T3 (es) 1997-03-05 2004-02-01 Jsr Corporation Metodo para producir polimeros dieno conjugados.
TWI246520B (en) 1997-04-25 2006-01-01 Mitsui Chemicals Inc Processes for olefin polymerization
US6525118B2 (en) 1997-07-11 2003-02-25 Bridgestone Corporation Processability of silica-filled rubber stocks with reduced hysteresis
SG75157A1 (en) * 1998-03-06 2000-09-19 Sumitomo Chemical Co Etylene-isoprene random copolymer
JP3577978B2 (ja) * 1998-03-06 2004-10-20 住友化学工業株式会社 エチレン−イソプレンランダム共重合体、エラストマー組成物及び架橋エラストマー組成物
JP2001081143A (ja) 1999-09-17 2001-03-27 Nippon Zeon Co Ltd 共役ジエン単量体と極性ビニル単量体との交互共重合体および交互共重合体の製造方法
FR2799468B1 (fr) 1999-10-12 2006-04-28 Michelin Soc Tech Systeme catalytique utilisable pour la copolymerisation de l'ethylene et d'un diene conjugue, procede de preparation de ce systeme catalytique et d'un copolymere d'ethylene et d'un diene conjugue
US6977281B1 (en) 1999-11-12 2005-12-20 Bridgestone Corporation Modified polymers prepared with lanthanide-based catalysts
EP1099711B1 (en) 1999-11-12 2006-03-29 JSR Corporation Modified conjugated diene polymer, method of producing it and rubber composition comprising the same
DE60041550D1 (de) 1999-11-12 2009-03-26 Bridgestone Corp Modifizierte polymere hergestellt mit katalysator auf basys von lanthaniden
EP1332162B1 (en) 2000-11-10 2013-05-01 Bridgestone Corporation Functionalized high cis-1,4-polybutadiene prepared using novel functionalizing agents
MXPA01001160A (es) 2001-01-31 2002-08-05 Ct De Investigacion En Quimica Poli(metacrilato de metilo) semicristalino con alta temperatura de fusion y proceso para su separacion.
GB2389855B (en) 2001-02-01 2005-09-21 Fmc Corp Functionalized initiators for anionic polymerization,protected funtionalized polymers,deprotected analogues thereof,and method of making the same
CN100523023C (zh) 2002-10-16 2009-08-05 米其林技术公司 乙烯/丁二烯共聚物,用于合成其的催化体系和方法
JP4522947B2 (ja) 2002-10-30 2010-08-11 株式会社ブリヂストン モノマーのアニオン重合に硫黄含有開始剤を使用する方法
FR2858817B1 (fr) 2003-08-13 2006-02-03 Michelin Soc Tech Systeme catalytique pour l'obtention de copolymeres diene(s) conjugue(s)/ mono-olefine(s) et ces copolymeres
ES2588177T3 (es) 2004-03-02 2016-10-31 Bridgestone Corporation Proceso de polimerización en masa
US20080064818A1 (en) * 2004-04-28 2008-03-13 Mitsui Chemicals, Inc. Nonconjugated Polyene Copolymer, Rubber Composition and Uses Thereof
CN101010349B (zh) * 2004-07-02 2013-10-23 独立行政法人理化学研究所 含金属茂配合物的聚合催化剂组合物和使用其制备的聚合物
CN101445568B (zh) 2004-10-26 2014-11-19 株式会社普利司通 具有连接基团的官能化聚合物
US7816483B2 (en) 2005-08-11 2010-10-19 Bridgestone Corporation Amine functionalized polymer
JP5079294B2 (ja) 2005-10-04 2012-11-21 株式会社ブリヂストン アミンで官能化されたポリマー
US7879952B2 (en) 2005-12-28 2011-02-01 Bridgestone Corporation Functionalized polymers
CN101443343B (zh) * 2006-05-09 2014-11-12 独立行政法人理化学研究所 金属茂络合物和含有它的聚合反应催化剂组合物
US7671138B2 (en) 2006-05-26 2010-03-02 Bridgestone Corporation Polymers functionized with hydrobenzamides
US7732534B2 (en) 2006-08-28 2010-06-08 Bridgestone Corporation Polymers functionalized with nitro compounds
US9084621B2 (en) * 2006-12-01 2015-07-21 Boston Scientific Scimed, Inc. Guide tube systems and methods
US8088868B2 (en) 2006-12-19 2012-01-03 Bridgestone Corporation Polymers functionalized with protected oxime compounds
ZA200711158B (en) 2006-12-28 2009-03-25 Bridgestone Corp A method for producing functionalized cis-1,4-polydienes having high cis-1,4-linkage content and high functionality
US8324329B2 (en) 2007-08-07 2012-12-04 Bridgestone Corporation Process for producing functionalized polymers
US7879958B2 (en) 2007-08-07 2011-02-01 Bridgestone Corporation Polyhydroxy compounds as polymerization quenching agents
CN101220060B (zh) * 2008-01-23 2012-08-29 中国科学院上海有机化学研究所 单茚基稀土配合物、合成方法以及应用
JP2011524447A (ja) 2008-06-18 2011-09-01 ダウ グローバル テクノロジーズ エルエルシー ポリマー組成物、該ポリマー組成物の作製方法及び該ポリマー組成物からの調製物
JP4962619B2 (ja) 2008-07-16 2012-06-27 日本エクスラン工業株式会社 制電性アクリル繊維およびその製造方法
JP5557835B2 (ja) * 2009-03-30 2014-07-23 三井化学株式会社 オレフィンと共役ジエンとの共重合体、およびその製造方法
RU2500691C2 (ru) * 2009-08-07 2013-12-10 Бриджстоун Корпорейшн Способ получения сополимера
WO2012014420A1 (ja) * 2010-07-30 2012-02-02 株式会社ブリヂストン 共重合体の連鎖構造を制御する方法
JP5918134B2 (ja) 2010-07-30 2016-05-18 株式会社ブリヂストン 共役ジエン化合物と非共役オレフィンとの共重合体、ゴム組成物、及びタイヤ
WO2012014456A1 (ja) 2010-07-30 2012-02-02 株式会社ブリヂストン 共役ジエン化合物と非共役オレフィンとの共重合体、ゴム組成物、架橋ゴム組成物、及びタイヤ
EP2599804B1 (en) * 2010-07-30 2019-02-20 Bridgestone Corporation Copolymer, rubber composition, cross-linked rubber composition, and tire
JP5764128B2 (ja) 2010-07-30 2015-08-12 株式会社ブリヂストン 共重合体及びその製造方法
CN103154061B (zh) 2010-07-30 2014-12-17 株式会社普利司通 共聚物、橡胶组合物、交联橡胶组合物和轮胎
WO2012014455A1 (ja) 2010-07-30 2012-02-02 株式会社ブリヂストン 共役ジエン化合物と非共役オレフィンとの共重合体、ゴム組成物、架橋ゴム組成物、及びタイヤ
CN103562301B (zh) 2010-12-30 2017-10-20 陶氏环球技术有限责任公司 组合物、其制备方法和由其制备的制品
JP5932224B2 (ja) 2011-02-04 2016-06-08 株式会社ブリヂストン 共重合体、ゴム組成物、架橋ゴム組成物、及びタイヤ
JP5731217B2 (ja) * 2011-02-04 2015-06-10 株式会社ブリヂストン 共重合体、ゴム組成物、架橋ゴム組成物、及びタイヤ
JP5722664B2 (ja) 2011-03-01 2015-05-27 株式会社ブリヂストン 積層体
EP2794693B1 (en) 2011-12-20 2020-09-23 Dow Global Technologies LLC Ethylene/alpha-olefin/nonconjugated polyene interpolymers and processes to form the same
BR112014032673B1 (pt) * 2012-06-29 2021-07-06 Dow Global Technologies Llc composição, composição reticulada e artigo
JP5902587B2 (ja) * 2012-08-20 2016-04-13 株式会社ブリヂストン 共重合体の製造方法
JP6267575B2 (ja) * 2014-05-02 2018-01-24 株式会社ブリヂストン マルチブロック共重合体、ゴム組成物及びタイヤ
BR112016028132B1 (pt) 2014-05-30 2022-04-19 Bridgestone Corporation Catalisador de complexo metálico e métodos de polimerização usando os mesmos

Also Published As

Publication number Publication date
RU2016147087A (ru) 2018-05-30
RU2723019C2 (ru) 2020-06-08
EP3148938B1 (en) 2020-07-08
WO2015183781A1 (en) 2015-12-03
US20200031974A1 (en) 2020-01-30
US11124591B2 (en) 2021-09-21
US20170114170A1 (en) 2017-04-27
RU2690373C2 (ru) 2019-06-03
RU2019115933A (ru) 2019-05-31
BR112016027987B1 (pt) 2022-04-19
CN106660819B (zh) 2019-06-28
US10457765B2 (en) 2019-10-29
RU2020117998A (ru) 2021-12-01
BR112016027987A2 (OSRAM) 2017-08-22
EP3738927A1 (en) 2020-11-18
CN110283280A (zh) 2019-09-27
JP2020041166A (ja) 2020-03-19
EP3148938A4 (en) 2018-05-30
JP2017516911A (ja) 2017-06-22
EP3148938A1 (en) 2017-04-05
JP7187432B2 (ja) 2022-12-12
CN106660819A (zh) 2017-05-10
RU2019115933A3 (OSRAM) 2019-08-12
CN110283280B (zh) 2022-11-04
RU2016147087A3 (OSRAM) 2018-12-11

Similar Documents

Publication Publication Date Title
JP7187432B2 (ja) 金属錯体触媒、それを使用した重合方法、及びそのポリマー生成物
JP6445629B2 (ja) 有機金属触媒錯体及びこれを使用する重合方法
WO2012106695A2 (en) Metal complex catalysts and polymerization methods employing same
US9416205B2 (en) Organometallic complex catalyst and polymerization method employing same
WO2012106694A2 (en) Lanthanide complex catalyst and polymerization method employing same
CN103459402B (zh) 镧系元素络合物催化剂以及使用其的聚合方法
JP6607615B2 (ja) 金属錯体触媒及びそれを用いた重合方法

Legal Events

Date Code Title Description
A524 Written submission of copy of amendment under article 19 pct

Free format text: JAPANESE INTERMEDIATE CODE: A525

Effective date: 20170124

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20170823

A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20180523

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20190313

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20190326

A601 Written request for extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A601

Effective date: 20190522

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20190723

A02 Decision of refusal

Free format text: JAPANESE INTERMEDIATE CODE: A02

Effective date: 20190924

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20191219

A911 Transfer to examiner for re-examination before appeal (zenchi)

Free format text: JAPANESE INTERMEDIATE CODE: A911

Effective date: 20191227

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20200204

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20200228

R150 Certificate of patent or registration of utility model

Ref document number: 6673596

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R150

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250