JP6509563B2 - Apparatus for dispensing and discharging a liquid agent - Google Patents

Description

(Cross-reference to related applications)
The present application claims the benefit of priority from the above-mentioned patent application based on Chinese Patent Application No. CN20121006417.77 entitled “RICE TRANSPLANTER-MOUNTED LIQUID REAGENT APPLICATION DEVICE” filed on March 12, 2012. And the contents of all of the above applications are incorporated into the contents of the present specification.
The present invention relates generally to an apparatus for dispensing and dispensing liquid agents. More specifically, the present invention relates to a rice transplanter mounted liquid sprayer and a rice transplant simultaneous liquid spray using the same.

The so-called control work, which involves spraying chemicals simultaneously with rice planting for the purpose of weeding, aims to save labor by applying pesticides simultaneously with rice planting. A rice transplanter-mounted drug sprayer is a machine that sprays granules and a liquid, for example, a suspension (a flowable, an emulsion), a water solvent, etc., simultaneously with the planting of seedlings by the rice transplanter.

Rice planter type drug sprayer has granules and solutions according to the properties of the drug to be sprayed, and it performs herbicide spray simultaneously with rice planting, which was a separate operation from rice planting before. It is possible to perform quantitative spraying and micro weighing. As disclosed in JP-A-11-308959 and JP-A-2008-048659, a rice transplanter-mounted granule spraying apparatus meters granules by a metering device that operates in synchronization with the rice planting speed. It is possible to perform uniform distribution of the granules by dropping the metered granules onto a high-speed rotating disk and repelling the granules with a hitting plate formed on the disk, all of those applications. The content is incorporated by reference into the content of the present description. In addition, “Common technologies for agricultural chemical application: Soil application”, “Agricultural chemical application technology” (1998), “Agricultural chemical application technology” edited by editorial board, published by Japan Plant Protection Association, page 122. The rice planting simultaneous liquid agent dispersing device is a method of squeezing a tube connecting a tank and a nozzle by using a roller, and the contents of all of them are incorporated into the contents of the present specification by reference.

A rice planting simultaneous liquid agent spraying device used by attaching it to the rear of a rice transplanter is put to practical use under the trade name "Drip Man (trademark registration No. 2419217)", the entire contents of which are incorporated herein by reference. A "drop man" spreader has only one nozzle, i.e. a one-drip apparatus. This device often spreads the solution unevenly, especially for poorly water-soluble active substances such as the herbicide oxadiargyl. Such non-uniform spread causes non-uniform control of weeds, pests and / or fungi and / or causes crop damage.

Japanese Patent Application Laid-Open No. 11-308959 JP 2008-48659 A

"Common technologies for spraying pesticides: Soil application", "Pesticide spraying technology", (1998), "Pesticide spraying technology" edited by editorial board, published by Japan Plant Protection Association, page 122

Rice planting work (person, machine transplantation) has been done in shallow water (water depth is 0 to 3 cm) to maintain planting accuracy. In the conventional spray apparatus for granules, depending on the strength or angle of repelling the granules, the granules may be buried in the soil of the paddy field and there may be places where they are not weeded because the efficacy of the drug is not exhibited. On the other hand, granules placed near planted rice seedlings can cause phytotoxic effects on the seedlings. Granule spreaders are also susceptible to weather conditions such as rainfall and wind. Rainfall is very important as it causes the granules to stick to the spreader. In addition, it is difficult to spray a mixture of several types of granules on a large-scale field without supplying granules during rice planting because the granules are heavy and bulky. It is also undesirable to mix granules with different specific gravities, as the granules can not be distributed uniformly. In addition, since the conventional spray equipment for liquid preparation is mounted on a 6 to 8 row planted rice planter, and the liquid preparation is dropped only during the middle weir (ie, dropping between 1 strain), the liquid preparation is 6 to 8 It may not spread to all of the ridges of the streak and uniform control effect may not be obtained. In particular, if the field is shallow or there is no water depth at the time of rice planting, or if the water can not be immediately formed after the simultaneous treatment with rice planting, the active substance of the drug does not diffuse sufficiently and the expected effect, for example, weeding, It may not be possible to obtain effects such as pest control or fungal disease control. Also, the uneven distribution of drugs may promote the harm to rice plants.

Embodiments of the present invention aim to at least partially improve some of these points, and medium-sized fields (paddy areas of 1000 to 3000 square meters (0.1 to 0.3 ha per area)) ) A rice transplanter mounted liquid sprayer, and a rice transplant simultaneous liquid spray method using the same, which enables pesticides to be sprayed on large-scale fields (paddy areas having an area of 3000 square meters (0.3 ha) per side)) .

According to the embodiment of the present invention, the liquid medicine can be uniformly dropped to each of a plurality of ridges to be planted after the rice transplanter has traveled (the error rate of the dropping amount from each nozzle is 50% compared to the average dropping amount, 30) %, Less than 20% or 10%). Since the sprayed solution can be diffused to all of a plurality of straws, it is possible to obtain excellent safety (selectivity) to paddy rice with a uniform control effect. In addition, the method of the present invention can prevent direct contact of the drug with the rice during liquid solution spraying, and can prevent the contact phytotoxicity of the drug on the rice leaf, as compared with the conventional liquid solution spraying method. And can effectively enhance rice growth (more than 10% or 30% compared to untreated rice). Another advantage of the present invention as compared to the prior art is that the solution can be uniformly dispersed even if the solution is very low or moderate in water solubility. An example of a very poorly water-soluble active agent is oxadiargyl (0.37 mg / L at pH 5.6 and 20 ° C.), and an example of a moderately water-soluble active agent is triafamone (each value measured at 20 ° C. 33 mg / L at pH 7, 36 mg / L at pH 4, 34 mg / L at pH 9). Even when the water solubility of the solution is very low, uniform dispersion of the solution prevents uneven dispersion results, results in uniform control of weeds, pests and / or fungi, and / or prevents crop damage.

According to another embodiment of the present invention,

In one aspect of the present invention, an apparatus is provided for dispensing and dispensing a liquid agent. The apparatus comprises: a tank for storing a liquid agent, a pump for drawing the liquid agent from the tank, a pipe line connected to the pump for conveying the liquid medicine drawn by the pump, and the pipe line The system may include a distribution unit connected to the conduit for dispensing and discharging the liquid agent, and a mechanism for receiving the liquid agent transported by the conduit and capturing air contained in the received liquid agent.

The mechanism may include an additional conduit connected between the distribution unit and the tank for receiving the liquid agent supplied to the distribution unit and transporting the received liquid agent to the tank. The distribution unit may include a hollow member extending in a substantially horizontal direction, and two or more conduits connected to the hollow member and extending downward, the two or more conduits being connected by the hollow member. The conveyed liquid agent is drained, and each of the two or more pipelines is disposed at a distance from the adjacent pipeline. An additional conduit of the mechanism is connected to the hollow member of the distributor. Additional conduits of the mechanism are connected to the ends of the hollow member. An additional conduit of the mechanism is connected to the upper surface of the hollow member. Each of the two or more conduits includes a valve that adds resistance to the fluid passing through the interior of the conduit.

Alternatively, the mechanism includes a chamber which extends in a substantially vertical direction and is incorporated in the conduit, and the conduit is a first conduit for discharging a liquid agent sucked by the pump, One end of one line is connected to the pump, and the other end of the first line is a first line connected to the chamber, and a second line for discharging the liquid stored in the chamber. An end of the second conduit is connected to the chamber, and the other end of the second conduit includes a second conduit connected to the distribution unit, wherein the other end of the first conduit is , Disposed at a position higher than the one end of the second conduit. An exhaust connected to the chamber at a location higher than the other end of the first conduit to exhaust air from the chamber. A drain connected to the chamber at a location lower than one end of the second conduit for draining the solution from the chamber.

The distribution unit includes a hollow member extending in a substantially horizontal direction, and two or more conduits extending downward in communication with the hollow member, the two or more conduits being conveyed by the hollow member The liquid agent is drained, and each of the two or more conduits is disposed at a distance from the adjacent conduit, and the other end of the second conduit is connected to the hollow member.

Each of the two or more conduits includes a valve that adds resistance to the fluid passing through the interior of the conduit.

In one aspect of the invention, a valve may be provided. The valve is a first valve member configured to have a tubular shape and having an upper surface at one end and an opening at the other end, the upper surface comprising a first valve member including a notch; The case may include an inlet for receiving a valve member and facing the opening of the valve member and an outlet for the upper surface of the first valve member.

The valve is a second valve member configured to have a tubular shape and having an upper surface at one end and an opening at the other end, the upper surface including a notch and the second valve member A second valve member may be engaged within the case with the first valve member, the upper surface of the second valve member being spaced from the upper surface of the first valve member.

Each of the first and second valve members is a first hollow member provided with a top surface having a first inner diameter and a first outer diameter longer than the first inner diameter, and a second hollow member connected to the first hollow member The second hollow member may include a second hollow member having a second inner diameter longer than both of the first inner diameter and the outer diameter and a second outer diameter longer than the first outer diameter; One and second valve members are configured to be screwed together such that the first hollow member of the second valve member is received and supported within the second hollow member of the first valve member Be done.

Each of the first and second valve members is a third member connected to the second hollow member, the third hollow member having a third inner diameter longer than both the second inner diameter and the outer diameter, and The first and second valve members may further include a third member having a second outer diameter greater than the first outer diameter, and the first hollow member of the second valve member may be the third valve member of the first valve member. The three hollow members are configured to be mutually engaged to be received and supported.

One aspect of the present invention relates to a rice transplanter including the above-described apparatus for discharging a liquid agent in synchronization with the rice transplanting operation of the rice transplanter.

One aspect of the present invention is a rice planting simultaneous solution application method for controlling pests, fungi and / or weeds using the above-mentioned apparatus or rice planter, wherein the liquid agent is dispersed via the distribution unit, and The present invention relates to a method of applying a solution to one or more places between a plurality of pots to be planted.

One aspect of the present invention relates to a method for applying a solution, which comprises applying more than half of the plurality of gaps among the plurality of gaps.

One aspect of the present invention relates to a method of spraying a solution using the above described apparatus or rice planter to enhance rice growth by more than 10% or 30% compared to untreated rice.

A first aspect of the present invention relates to a rice transplanter-mounted liquid agent spraying device that can be mounted on a rice transplanter and that sprays a liquid agent in synchronization with the rice planting operation by the rice transplanter.

According to a first aspect of the rice transplanter-mounted liquid agent dispersion apparatus, a tank for storing a liquid agent, a pump for conveying the liquid agent stored in the tank, and one end of the pump are connected to drive the pump. A first conduit communicating a liquid agent discharged from the tank, a gas intake chamber connected to the other end of the first conduit, and one end connected to the gas intake chamber, the first conduit and the gas intake A second conduit communicating a liquid agent discharged from the tank via a chamber is connected to the other end of the second conduit, and the first conduit, the gas intake chamber and the second conduit are connected. And a distribution unit for distributing and discharging the liquid agent supplied from the tank.

The other end of the first conduit is connected to an upper portion of the gas intake chamber than one end of the second conduit.

The second aspect of the present invention further includes an exhaust unit for exhausting the air in the gas intake chamber, wherein the exhaust unit is connected to the upper portion of the gas intake chamber more than the other end of the first pipeline. Related to the liquid sprayer.

The third aspect of the present invention further comprises a drainage unit for draining the residual liquid agent in the suction chamber, wherein the drainage unit is located at a lower portion of the suction chamber than one end of the second pipeline. The present invention relates to a liquid spray apparatus connected.

In the fourth aspect of the present invention, the distribution unit includes a cylindrical distribution chamber connected to the other end of the second pipeline, and one end connected to the distribution chamber, the first pipeline, the trapped air And a plurality of third conduits for discharging the liquid agent supplied from the tank to the distribution chamber through the second conduit, wherein the plurality of third conduits are separated from the distribution chamber by a distance The present invention relates to a liquid spray apparatus connected.

A fifth aspect of the present invention relates to the liquid agent spray device in which each of the plurality of third pipelines is provided with a valve for adding resistance to the liquid agent passing therethrough.

The sixth aspect of the present invention relates to a method of spraying a solution onto some of a plurality of bushes to which a seedling is planted through the distribution unit using a rice planting simultaneous solution spray device attached to a rice planter. .

A seventh aspect of the present invention relates to a liquid agent spraying method of spraying between half or more of the plurality of chewing spaces.

The eighth aspect of the present invention relates to a solution spraying method, wherein the solution comprises at least one selected from the group consisting of herbicides.

The ninth aspect of the present invention relates to a solution spraying method wherein the above-mentioned herbicide is a herbicide for paddy field.

In a tenth aspect of the present invention, the above-mentioned liquid preparation is pyrimisulfan, tefuryl trione, ketospiridox, mesotrione, benzobicyclon, sulcotrione, tembotrione bromotide, triafamone, propyrisulfuron, benzosulfuron-methyl, A solution comprising at least one compound selected from the group consisting of pyrazosulfuron, imazosulfuron, penoxram, pyraclonyl, pentoxazone, oxadiazone, oxadiargyl, butachlor, pretilachlor, fentrazamide, mefenacet, oxadiclomephone, ipfencarbazone and fenoxasulfone It relates to the spraying method.

According to an eleventh aspect of the present invention, the liquid preparation comprises a herbicide, a plant growth regulator, a fungicide, an insecticide, an acaricide, a nematocide, a microorganism, a molluscicide, a fertilizer, a safener, and The invention relates to a solution spraying method comprising at least one compound selected from the group consisting of plant tonic compounds and combinations thereof.

The twelfth aspect of the present invention relates to a method wherein the water solubility of the solution is lower than 100 mg / L, preferably lower than 50 mg / L, most preferably lower than 10 mg / L.

In the sense of the present invention, water solubility is a value measured at pH 7 and 20 ° C.

According to the embodiment of the present invention, it is possible to uniformly drop the liquid agent between each of the plurality of weirs planted after the rice transplanter has traveled. Since it can be diffused to all drops dripped, excellent safety (selectivity) for rice with uniform control effect can be obtained. In addition, the method described in the embodiment of the present invention can prevent direct contact of the drug with rice during liquid solution spraying as compared with the conventional liquid agent spraying method, and prevent the contact injury of the drug to the rice leaf blade. Can also effectively enhance rice growth. Another advantage of the present invention compared to the prior art is that the solution is uniformly diffused even when the solution is very low or moderate in water solubility. An example of a very poorly water soluble activator is oxadiargyl (0.37 mg / L) and an example of a moderately water soluble activator is triafamone (39 mg / L). Even when the water solubility of the solution is very low, uniform dispersion of the solution results in uniform control of weeds, pests and / or fungi and / or prevents crop damage.

It is a functional block diagram which shows the structure of the rice transplanter mounting type liquid agent dispersing device 1 of this invention. It is a schematic diagram which shows the structure of the spreading | diffusion part 2 as described in one Embodiment. It is a disassembled perspective view of a valve. It is a schematic diagram which shows the state which mounted the spraying apparatus of this invention in the rice transplanter. It is a schematic diagram which shows the structure of spraying part 2 'by another embodiment.

Hereinafter, the present invention will be described in detail in line with the embodiments and with reference to the accompanying drawings. The contents of all the documents referred to in the present specification are incorporated in the content of the present specification.

It should be noted that elements common to the drawings are identified by the same reference numerals in the drawings.

As shown in FIG. 1 and FIG. 2, the rice transplanter-mounted liquid drug sprayer 1 according to one embodiment includes a spray unit 2 for spraying a solution and a spray unit 2 in synchronization with the planting operation of seedlings by the rice transplanter. It comprises a spraying operation control device 3 for spraying a solution and a battery 4 as a power supply of each part. In addition, the battery 4 may share the existing battery for a rice transplanter.

The spreader 2 includes a tank 10, a pump 12, a first line 14, a second line 16, an air-catch chamber 18, and a distribution unit 20.

The tank 10 stores a liquid agent such as a suspension agent (flowable agent). The pump 12 sucks the liquid agent from the tank 10 and conveys the liquid agent to the distribution unit 20 through the first and second pipes 14 and 16. As the pump 12, a so-called tube pump is employed. The tube pump has a structure in which the solution filled in the tube is pushed out of the tube by pressing the roller against the tube and rotating the roller.

The first pipeline 14 is, for example, a soft tube made of silicon resin, and one end 14a is inserted into the tank 10 via the pump 12 and the other end 14b is connected to the gas intake chamber 18 extending in a substantially vertical direction. It is done. The second conduit 16 is a soft resin tube, and one end 16 a is connected to the gas intake chamber 18, and the other end 16 b is connected to the distribution unit 20. That is, the chamber 18 can be expressed as a chamber incorporated in a conduit including the first and second conduits 14 and 16. The capture chamber 18 captures air contained in the solution supplied from the tank 10 through the first conduit 14. That is, the chamber 18 can be described as a mechanism that receives the liquid agent transported by the first conduit 14 and captures the air contained in the received liquid agent. The distribution unit 20 distributes and discharges the liquid agent supplied from the tank 10 via the first line 14, the gas intake chamber 18 and the second line 16.

The other end 14 b of the first conduit 14 is connected to the upper portion of the gas intake chamber 18 more than the one end 16 a of the second conduit 16. A sufficient space is left inside the gas intake chamber 18 above the other end of the first conduit 14. The gas intake chamber 18 is provided with an exhaust unit 22 for exhausting the air in the chamber, and a drainage unit 25 for discharging the residual liquid agent in the chamber.

The exhaust unit 22 is connected to one end 23 a of the gas intake chamber 18 and the other end 23 b of the exhaust pipe 23 and is provided in the middle of the exhaust pipe 23, and can seal the same. And an exhaust valve 24. Here, the exhaust pipe line 23 is a soft resin tube, and one end 23 a thereof is connected to the upper portion of the gas intake chamber 18 in the vertical direction than the other end 14 b of the first pipe line 14.

The drainage portion 25 is connected to the drainage pipe 26 whose one end 26a is connected to the gas intake chamber 18 and whose other end 26b is open, and in the middle of the drainage pipe 26 to seal the same. And a drain valve 27 capable of Here, the drainage conduit 26 is a soft resin tube, and one end 26 a thereof is connected to the lower part of the gas intake chamber 18 in the vertical direction than any of the conduits connected to the gas intake chamber 18. The drainage valve 27 is used when the liquid inside the gas intake chamber 18 is drained after the work by the spray device 1 is finished.

The distribution unit 20 includes a cylindrical distribution chamber 30 made of a hard material, and a plurality of (two or more) third pipelines 32 having one end 32 a connected to the distribution chamber 30 and the other end 32 b open to the atmosphere. , A valve 40 provided in each of the third conduits 32. The other end 16 b of the second conduit 16 connected to the distribution chamber 30 is located higher than one end 32 a of the third conduit 32 connected to the distribution chamber 30. The chamber 30 may have a hollow shape that is as long as possible so that the liquid agent can be transported along the direction in which the chamber 30 extends. For example, the chamber 30 may have any cross-sectional shape including, but not limited to, circular, oval, rectangular, triangular and polygonal.

Extension building distribution chamber 30 in a substantially horizontal direction, at a position lower than the Toki chamber 18 is mounted so as to keep a substantially horizontal to the planting machine. That is, one end 16a of the second pipeline 16 is disposed at a position higher than the other end 16b of the second pipeline.

The third conduit 32 is a soft resin tube, and one end 32 a thereof is connected to the lower portion of the distribution chamber 30 in the vertical direction than the other end 16 b of the second conduit 16. Further, one end 32 a of the third conduit 32 is disposed at a position higher than the other end 32 b of the same conduit. The third lines 32 are arranged at equal intervals in the longitudinal direction with respect to the distribution chamber 30. The number of third pipelines 32 is five for rice planters with six-rows and seven for eight-rows. That is, the structure of the distribution part 20 is suitably selected according to the specification of a rice transplanter so that each other end of the 3rd pipe line 32 may respond | correspond to each of the clearance gap.

Each conduit of the third conduit 32 includes a faucet 32c that can be selectively opened and closed. The faucet, when open, can cause the fluid to flow through the conduit. In addition, the cock can prevent the fluid from flowing through the conduit when it is closed. The cock 32 c allows the spreader 2 to prevent the liquid agent from flowing unintentionally through each conduit 32. For example, when the sparging section 2 is not activated, each cock 32c can be closed to prevent the flow of fluid through the corresponding conduit 32.

The valve 40 adds resistance to the fluid leading from the third line 32 to the interior. As shown in FIG. 3, the valve 40 has a two-part case 41 and at least one valve member, for example, two valve members 42 and 43 made of rubber disposed inside the case 41 in one embodiment, and A rubber O-ring 48 is provided.

The case 41 includes a female case 44 and a male case 45, each having a generally cylindrical shape for receiving the valve members 42,43.

A female screw 44a is formed on the inner peripheral surface of the female case 44, and a male screw 45a is formed on the outer peripheral surface of the male case 45. The male screw 45a is screwed to the female screw 44a. Therefore, the female screw portion 44a and the female screw portion 45a can screw the female case 44 with the male case 45. Further, an inlet port 44 b for the liquid agent is formed in the female case 44, and an outlet port 45 b for the liquid agent is formed in the male case 45. The inflow port 44 b is connected to the upstream portion of the third conduit 32, and the outflow port 45 b is connected to the downstream portion of the third conduit 32.

The valve members 42 and 43 may be formed, for example, in the same shape, and in the shape of a cone whose diameter gradually decreases. A radially extending notch 46 is formed on the distal end surface of the valve member 42 (or 43). The notch 46 communicates with the inside and the outside of the valve member 42 (or 43), but is closed in a state where a pressure greater than a predetermined magnitude is not applied to the liquid flowing in from the inflow port 44b. When the pressure acting on the solution exceeds a predetermined level, the mouth is opened and the solution is allowed to flow from the inflow port 44b to the outflow port 45b.

The structure of the valve members 42 and 43 will be described in detail.

As shown in FIG. 3, each of the valve members 42, 43 can be configured to have a tubular shape. Specifically, in each valve member, a first cylindrical member 42a (43a), a second cylindrical member 42b (43b) connected to the first cylindrical member 42a (43a), and a second cylindrical member 42b A third cylindrical member 42c (43c) connected to (43b) and a fourth cylindrical member 42d (43d) connected to the third cylindrical member 42c (43c) are included. All of the first, second, third and fourth members are in communication with one another.

The first tubular member 42a (43a) has an upper surface (e.g., a flat upper surface) on which the notch 46 is formed. The upper surface faces the outflow port 45 b of the male case 45. The fourth tubular member 42d (43d) has an opening (not shown in FIG. 3) communicating the first, second and third members. The opening faces the inflow port 44 b of the female case 44.

Each of the first, second, third and fourth tubular members has an inner diameter and an outer diameter. The outer diameter of each member is greater than the inner diameter of the member. The inner diameter of the second member 42b (43b) is longer than either the inner diameter or the outer diameter of the first member 42a (43a). The inner diameter of the third member 42c (43c) is longer than both the inner diameter and the outer diameter of the second member 42b (43b). The inner diameter of the fourth member 42d (43d) is longer than both the inner diameter and the outer diameter of the second member 42c (43c).

When the valve member 42 engages with the valve member 43, the first cylindrical member 43a of the valve member 43 can enter into the fourth, third and second cylindrical members 42d, 42c, 42b of the valve member 42. However, the first member 43a can not be inserted into the first tubular member 42a of the valve member 42 because the outer diameter of the first member 43a of the valve member 43 is longer than the inner diameter of the first member 42a. Thus, the upper surface of the first member 43a is disposed at a distance from the upper surface of the first member 42a when the valve member 43 engages with the valve member 42.

According to the structure of the valve members 42 and 43, the following advantages can be obtained. Specifically, on the one hand, it may be the case that small substances, such as, for example, contaminants contained in the solution are captured and left in the notch 46 of the valve member 43. In this case, the substance may cause the notches 46 to open and unintentionally increase the amount of solution. However, there is also another notch 46, namely the notch 46 of the valve member 42 below the notch 46 of the valve member 43. Also, in the region between the upper surface of the valve member 43 and the upper surface of the valve member 42, there is a layer filled with the liquid agent. Thus, the amount of fluid flowing through the valve 40 can be maintained as intended due to the notches 46 of the valve member 42 and the fluid filled layer.

On the other hand, there may be other cases where the small substance contained in the solution is trapped and left in the notch 46 of the valve member 42. In this case, there is another notch, namely the notch 46 of the valve member 43 above the notch 46 of the valve member 42. Thus, the amount of fluid flowing through the valve 40 can be maintained as intended due to the notch 46 in the valve member 43.

FIG. 3 shows an example in which the valve 40 can be configured to receive two valve members. However, in one embodiment, the valve 40 can be configured to receive more than two valve members. Those skilled in the art will appreciate that the more valve members (notches 46) in the valve 40, the smaller the difference in the amount of fluid flowing through the valve 40.

FIG. 3 shows an example in which each valve member includes one or more tubular members. However, each valve member can include one or more members having any hollow shape as long as the one or more members can carry the fluid agent. For example, the one or more members may have any cross-sectional shape including, but not limited to, circular, oval, rectangular, triangular, polygonal and the like.

The O-ring 48 is interposed between the female case 44 and the male case 45 constituting the case 41, and seals between the two screwed together.

The spraying operation control device 3 includes a conversion mechanism, a proximity switch, a control unit, and the like that convert the reciprocating motion of the seed bed S of the rice transplanter into a rotational motion. The structure of the spray operation control device 3 is described in detail in Japanese Patent Application Laid-Open No. 2008-48659, and thus the description thereof is omitted here.

In the spray unit 2, the tank 10, the pump 12, and the gas intake chamber 18 are accommodated in the first casing 13a together with the control unit 3a included in the spray operation control device 3, and each portion of the spray operation control device 3 excluding the control unit is , And the second casing 13b.

As shown in FIG. 4, the first casing 13 a and the distribution chamber 30 are fixed to a portal frame F erected at the rear of the bedbed S. In particular, in the distribution chamber 30, the other end 32b of the third conduit 32 corresponds to the space between the pots to which the seedlings are planted, that is, the other end 32b of the third conduit is between the scraping claws C of the rice transplanter. It is fixed to the portal frame F so as to be arranged (see FIG. 1). There is no particular limitation on the mounting position of the first casing 13a, but it should be installed at least above the distribution chamber 30.

The second casing 13 b is fixed to the back side of the seed bed S. The method of fixing the second casing 13b is also described in detail in the above-mentioned Japanese Patent Application Laid-Open No. 2008-48659, so the description thereof is omitted here.

The control performed using the spraying apparatus 1 and 1 '(It replaces with the spreading part 2 and uses the spreading part 2') comprised as mentioned above is demonstrated. The agents to be sprayed for control include herbicides, plant growth regulators, fungicides, insecticides, acaricides, nematocides, microorganisms, molluscicides, fertilizers, safeners and plant tonics. Sex compounds and combinations thereof can be mentioned, and specific examples thereof will be described later.

First, the rice transplanter carrying a bundle of seedlings on the nursery bed S is loaded into the field, and the main switches of the scattering devices 1 and 1 'are turned ON. Then, when the rice transplanter is operated to start the planting operation of the seedlings, the nursery bed S synchronizes with the scraping operation of the seedlings by the scraping claw C and starts the reciprocating motion. The proximity switch included in the spraying operation control device 3 transmits a signal in synchronization with the reciprocating operation of the nursery bed S. The controller 3a intermittently drives the pump 12 each time it receives a signal transmitted from the proximity switch. The pump 12 rotates the roller by a preset rotation amount every one intermittent operation, and discharges a liquid agent in an amount corresponding to the rotation amount. The amount of rotation of the roller can be arbitrarily adjusted, and the amount of discharge of the liquid agent (that is, the amount of dispersion) per intermittent operation can be changed according to the type of liquid agent. Further, as will be described later, the pump 12 can be operated independently alone in consideration of the preparatory operation of the spraying device 1 and the like separately from the synchronization with the planting operation of the rice transplanter.

Each time the pump 12 is driven, the liquid agent is discharged from the other end 32 b of all the third pipelines 32. Here, since the other end 32b of the third pipeline is respectively disposed between the scraping claws C of the rice transplanter, the liquid agent discharged from the other end 32b of the third pipeline 32 is eventually planted in the field It is dripped to all between the cocoons of the seedling. In other words, if the rice transplanter has specifications for six-row planting, the liquid agent is intermittently spaced between the six ridges of the rice transplanter after the rice transplanter travels, that is, between all five cages, at intervals corresponding to the traveling speed of the rice transplanter. It is dripped. In addition, if the rice transplanter has a specification of eight rows of planting, the liquid agent is intermittently spaced at intervals corresponding to the traveling speed of the rice transplanter between the eight cages planted after the rice transplanter travels, that is, all seven cages. It is dripped. The dropped solution spreads in all six to eight rows, so that uniform control effect can be obtained. Furthermore, the active substance of the drug is sufficiently diffused even when the water depth of the field is shallow at the time of rice planting.

By the way, in the above description, the liquid agent is dropped to all the spaces between the plurality of ridges planted by the rice transplanter, but depending on the properties of the liquid agent, the liquid agent may be dropped to some of the plurality of ridges. In that case, some of the third pipelines 32 may be sealed using a separately prepared sealing device (such as a clip), or the distribution unit may be replaced with one having a smaller number of third pipelines 32. You may

By the way, when the liquid agent is passed through the thin and long pipeline, the most serious problem is that an air pool remains in the middle of the pipeline. Such an air pool is a factor that impedes the smooth flow of the solution. In particular, in the above-described spray apparatus 1 having a plurality of liquid agent discharge ends (32b), the presence of an air pool is a great obstacle in dispersing approximately equal amounts of liquid agents from the respective discharge ends.

In most cases, an air pool will remain inside the pipeline at the time of initial passage into the spray device 1, and conversely if air can be removed from the inside of the tube at the time of initial passage, air will be used in the subsequent spraying operation. There will be no dumb.

Therefore, the preliminary operation until the empty tank 10 is filled with the liquid agent and the entire apparatus is passed through in the spraying device 1 will be described.

First, the prepared solution is poured into the tank 10. Next, the exhaust valve 24 and the drain valve 27 are closed and the pump 12 is continuously rotated. Thereby, the liquid agent stored in the tank 10 is sucked, and the sucked liquid agent is discharged from the pump 12.

The liquid agent discharged from the pump 12 flows into the gas intake chamber 18 in such a manner that the air remaining inside the first line 14 is pushed out from the other end 14 b of the first line 14. As a result, air stagnation hardly remains in the first conduit 14.

The liquid which has flowed into the gas intake chamber 18 is accumulated at the lower part of the gas intake chamber 18 and flows into one end 16 a of the second conduit 16. The liquid agent flowing into the second conduit 16 flows into the distribution chamber 30, and then flows into one end 32a of the plurality of third conduits 32. Since the flow resistance is added by the valve 40 to the liquid flowing into the third pipe 32, the discharge of the liquid from the other end 32b of the third pipe 32 does not occur for a while, and the first pipe 14 The internal pressure of a series of paths of the suction chamber 18, the second conduit 16, the distribution chamber 30, and the third conduit 32 is gradually increased by the supply of the liquid agent by the pump 12. During this time, in particular, the passage from the gas intake chamber 18 to the third conduit 32 does not cause the flow of the liquid agent.

On the other hand, one end 32a of the third pipeline 32 is disposed higher than the other end 32b of the same pipeline, and one end 16a of the second pipeline 16 is also disposed higher than the other end 16b of the same pipeline There is. Furthermore, the other end 16 b of the second conduit 16 connected to the distribution chamber 30 is located higher than one end 32 a of the third conduit 32 connected to the distribution chamber 30. Therefore, the air remaining in the third conduit 32 floats up in the third conduit 32 toward the distribution chamber 30 and the air remaining in the distribution chamber 30 with little flow downstream of the liquid agent. The air flowing into the second line 16 and remaining inside the second line 16 floats up in the second line 16 towards the capture chamber 18.

That is, the air remaining inside the first conduit 14 flows into the gas intake chamber 18 by the pressurizing action of the pump 12, and the air remaining inside the second conduit 16, the distribution chamber 30, and the third conduit 32 Depending on the respective height differences, it floats towards the trapping chamber 18. In this manner, almost all of the air remaining in the path from the tank 10 to the third conduit 32 collects in the capture chamber 18.

The internal pressure of a series of paths of the first pipe 14, the gas intake chamber 18, the second pipe 16, the distribution chamber 30, and the third pipe 32 is gradually increased by the supply of the liquid agent by the pump 12, and the internal pressure is finally reduced. When the flow path resistance added by 40 is exceeded, the liquid agent is discharged from the other end 32 b of all the third pipelines 32.

After the discharge of the liquid agent from the other end 32b of the third conduit 32 is confirmed, pull out the interior air accumulated Toki chamber 18 by opening the exhaust valve 24. The air inside the gas intake chamber 18 is also pressurized depending on the internal pressure rise of the above-mentioned series of paths, and is vigorously exhausted from the other end 23 b of the exhaust pipeline 23 opened to the atmosphere.

When air is exhausted from the intake chamber 18, the exhaust valve 24 is closed, the pump 12 is stopped, and the preliminary operation is finished.

According to the rice transplanter-mounted liquid agent dispersing device 1, it is possible to remove most of the air inside the pipeline by performing the above-mentioned preliminary operation at the time of initial passage. As a result, no air accumulation will occur in the middle of the pipe line in the subsequent spraying operation. As a result, the liquid agent can be discharged and dropped substantially uniformly from the other end 32 b of all the third pipelines 32. Here, to uniformly drip the liquid agent, the amount of liquid agent dripped from each other end 32b may deviate up to 50% from the average value of the amount of liquid agent dripped from all the other ends 32b, preferably the deviation Is less than or equal to 30%, most preferably less than or equal to 20%.

Also, in one embodiment, the sparging section 2 may be configured to include an optional tank 10 'for storing liquid agents as shown in FIGS. The tank 10 ′ is connected to the tank 10 via a pipe line 11. One end of the conduit 11 communicates with the tank 10 ′, and the other end of the conduit 11 communicates with the tank 10. Line 11 includes a pump 12 'which is used to aspirate fluid from tank 10' and to deliver fluid to tank 10. Inside the tank 10, there is provided a sensor 13 for transmitting a control signal to the pump 12 'depending on whether the upper surface of the liquid contained in the tank 10 has reached a prescribed level and the result of detection. . The tank 10 'can be housed inside the casing 13a together with the tank 10 and the like.

According to this configuration, when the sensor 13 detects that the top surface of the solution has reached a prescribed level, the sensor 13 sends a control signal to stop the operation of the pump 12 '. On the contrary, when the sensor 13 detects that the top surface of the solution has not reached the prescribed level, the sensor 13 sends a control signal to operate the pump 12 '. Thus, the top surface of the solution can be maintained near a prescribed level.

FIG. 5 is a schematic view showing the structure of the spreader 2 'according to another embodiment. In the following, the structure of the spreader according to another embodiment will be described in detail. It should be noted that only certain structures are described in alternative embodiments, and descriptions of structures common to those described above with reference to FIGS.

FIG. 5 shows a spreader 2 'according to another embodiment. The pump 12 is connected to the distribution chamber 30 via a line 52. One end of the conduit 52 is connected to the pump 12, and the other end of the conduit 52 is connected to the chamber 30. The conduit 52 conveys the fluid drawn by the pump 12 to the chamber 30.

Additional conduit 54 is provided between the chamber 30 and the tank 10. One end 54 a of the conduit 54 is connected to the tank 10, while the other ends 54 b and 54 c of the conduit 54 are connected to the chamber 30. Specifically, for example, two other ends 54b, 54c may be connected to both ends of the extension building chamber 30 in the horizontal direction. The conduit 54 receives the liquid agent supplied from the pump 12 to the chamber 30 and conveys the received liquid agent to the tank 10.

According to the above structure, even when air is present in the chamber 30, the air can be forced to move toward either end of the chamber 30 for the flow of the liquid agent dispersed by the pump 12 it can. There, the air that tends to float in the solution can finally reach the other end 54b or the other end 54c and then move upward along the conduit 54 . Thus, air can be transported to the tank 10 along the conduit 54. As mentioned above, the conduit 54 can function to receive the fluid conveyed by the conduit 52 and the chamber 30 and to capture the air contained in the received fluid. As a result, the amount of air that can reach the conduit 32 can be minimized, so that the fluid volume difference flowing through the conduit 32 can also be minimized, and into the tank 10 from the one end 54a. The drainage of the liquid containing air agitates the liquid in the tank 10, so that the separation of the liquid is prevented.

FIG. 5 shows a preferred embodiment in which the other ends 54 b and 54 c of the conduit 54 are connected to both ends of the chamber 30. In one embodiment, the other end 54b, 54c of the conduit 54 is connected at any location away from the ends of the chamber 30 as these other ends 54b, 54c can capture more or less air present in the chamber 30. it can. However, in this case, the air carried by the conduit 52 can reach a position near both ends of the chamber 30 and can then move downward to the conduit 32 so that a difference in the amount of liquid dispensed by the conduit 32 is intended. It is not possible to increase it. To this end, the other ends 54b, 54c may advantageously be connected to both ends of the chamber 30 shown in FIG.

Furthermore, since the air contained in the solution tends to float, the other end 54b, 54c of the conduit 54 can advantageously be connected to the top of the chamber 30 relative to the side or bottom of the chamber 30. However, in one embodiment, the other end of the conduit 54 may be connected to the side or bottom of the chamber 30 as these other ends can still capture more or less air present in the chamber 30.

The approach described above with reference to FIG. 5 may be performed instead of or in conjunction with the approach described above with reference to FIG. That is, the structure shown in FIG. 5 can operate in cooperation with the structure shown in FIG.

For example, the sparger described above with reference to FIGS. 2 and 5 can advantageously be mounted on a rice transplanter. However, the spreader is mounted on a device that requires a structure that must discharge the liquid from two or more lines (valves) so as to minimize differences in the amount of liquid flowing through the lines (valves) You can also

Each conduit 32 can include a cock 32c that can be selectively opened and closed as described above with reference to FIG. In one embodiment, each stop 32c is also closed when the spreader 2 'is deactivated. Next, several hours after the operation of the spray unit 2 'is stopped, air may be generated somewhere in the spray unit 2' (for example, the chamber 30, the conduits 52, 54, etc.). Then, when the operation of the spray portion 2 'is started, the pump 12 can close and operate the respective cocks 32c before discharging the liquid agent through the respective conduits 32. By operating the pump 12 for 1 to 3 minutes, the air generated in the sparging section 2 ′ can be captured by the line 54 and returned to the tank 10. Thus, the amount of air contained in the chamber 30 can be minimized. Each faucet 32 can then be opened so that each conduit 32 can drain the liquid agent.

Further, in one embodiment, the conduit 54 may include the same valve as the valve 40 described above near one end 54a of the conduit 54, as shown in FIG. With the valve 40, the pressure of the fluid flowing through one end 54 a of the conduit 54 can be adjusted to be in equilibrium with the fluid flowing through the end 32 b of each conduit 32. Although FIG. 5 shows that the valve 40 is provided inside the tank 10, the valve 40 can also be provided outside the tank 10.

As in the embodiment described with reference to FIG. 2, using the optional tank 10 ′ and the elements associated with the tank 10 ′ (including the conduit 11, the pump 12 ′ and the sensor 13), FIG. The top surface of the solution contained in the tank 10 can be maintained near the level defined in the embodiment described with reference.

As herbicides and plant growth regulators used for control, for example, acetolactate synthase, acetyl-CoA carboxylase, cellulose synthase, enolpyruvyl shikimate 3-phosphate synthase, glutamine synthase, p-hydroxyphenylpyruvate It is a known active substance that acts as an inhibitor of dioxygenase, phytoene desaturase, photosystem I, photosystem II, protoporphyrinogen oxidase, for example, Weed Research 26 (1986). 441-445 or "The Pesticide Manual", 15th Edition, The British Crop Protection Council and the R yal Soc. of Chemistry, 2006 and the documents cited therein.

More specifically, herbicides include, for example, the following active substances (compounds are described by a “general name” according to the International Organization for Standardization (ISO) or by a chemical name or code number) . And always includes all application forms such as acids, salts, esters, and isomeric forms such as stereoisomers and optical isomers. By way of example, at least one application form and / or variant form is described below: Acetochlor, Acibenzolar, Acibenzolar-S-Methyl, Acifluorphen, Acifluorphen-sodium, Acronifen, Alachlor, Aridochlor, Allodymium, Aloxydim- Sodium, ametrine, amicarbazone, amidochlor, amidosulfuron, aminocyclopyrachlor, aminocyclopyrachlor-methyl, aminocyclopyrachloro-potassium, aminopyralid, amitrole, ammonium sulfamate, ancimidol, anilophos, asulam, atrazine, azaphenidine , Azimlsulfuron, aziprothrin, beflubutamide, benazoline, benazoline-ethyl, bencarbazone, benfluralin, benfrice To bensulide, bensulfuron, bensulfuron-methyl, bentazone, benzphendizone, benzobicyclon, benzophenap, benzofluor, benzoylprop, bicyclopyrone, bifenox, birinaphos, biranafos-sodium, bispyribac, bispyribac-sodium, Bromacil, bromobutide, bromophenoxy, bromoxynil, bromoxynil,-potassium,-heptanoate and-octanoate, bromolone, buminaphos, busoxinone, butachlor, butaphenal, butamiphor, butalinel, butoraline, butoryzim, butyrate, cafentrol, calbetamide, carfenamide Zone, carfentrazone-ethyl, cromethoxyphene, chloramine Chloradihop, Chloradihop-butyl, Chlorbromuron, Chlorbufam, Chlorphenac, Chlorphenac-sodium, Chlorfenprop, Chlorflurenol, Chlorflurenol-Methyl, Chloridazone, Chlorimurone, Chlorimurone-ethyl, Chlormecote-Chloride, Chlornitrufen, Chlorphthalim, Chlorthal-dimethyl, chlorotoluron, chlorsulfuron, cinsulfuron, cynidone-ethyl, cinmethrin, cinosulfuron, cretodym, clodinafop, clodinafop-propargyl, clofensone, cromazone, clomeprop, cloprop, clopyralid, cloransulam, chloranthramu-methyl, cumilron, cyanamide , Cyanazine, cyclanilide, cycloate, cyclopyrimo , Cyclosulfamurone, cycloxydim, cyclulon, cyhalofop, cyhalofop-butyl, cypercoat, cyprazine, cyprazole, 2,4-D, 2,4-D-, -butyl, -dimethylammonium, -diolamine, -ethyl, -2-ethylhexyl, isobutyl, -isooctyl, -isopropylammonium, -potassium and -triisopropanolammonium, 2,4-DB, 2,4-DB-butyl, -dimethylammonium, -isooctyl, -potassium and -sodium, Diamron (Daimron), Darapon, Daminozide, Dazomet, n-Decanol, Desmedipham, Desmethrin, Detosyl-Pyrazolate (DTP), Dialate, Dicamba, Diclobenyl, Dichlorprop, Dichlorprop -P, dicrofop, diclohop-methyl, diclohop-p-methyl, dicloslam, dietyl, dietyl-ethyl, dipenoxyl, diphenzo coat, diflufenican, diflufenzopyr, diflufenzopyr-sodium, diqueglac-sodium, dimeflon, dimepiperate, dimethacolate , Dimethamethinamide, dimethenamide, P, dimethypinamide, dimethypine, dimethassulfuron, dinitramine, dinoseb, dinoterb, diphenamide, dipropetrine, diquat, diquat-dibromide, dithiopyr, diuron, DNOC, eglinazine-ethyl, endothal, EPTC, estrofulb Phosphorus, etamethosulfuron, etamethosulfuron-methyl, ethephon, ethidimolone, ethiodine Etofumesate, Ethoxyphen, Ethoxyphen-ethyl, Ethoxysulfuron, Etobenzanide, F-5231, ie N- [2-chloro-4-fluoro-5- [4- (3-fluoropropyl) -4,5-dihydro- 5-oxo-1H-tetrazol-1-yl] phenyl] -ethanesulfonamide, F-7967, ie 3- [7-chloro-5-fluoro-2- (trifluoromethyl) -1H-benzimidazole-4- [Ill] -l-Methyl-6- (trifluoromethyl) pyrimidine-2,4- (1H, 3H) -dione, phenoprop, fenoxaprop, fenoxaprop-P, fenoxaprop-ethyl, fenoxaprop -P-ethyl, fenoxasulfone, fentrazamide, phenuron, flamprop Flamprop-M-isopropyl, flamprop-M-methyl, flazasulfuron, floraziram, fluazifop, fluazifop-P, fluazifop-butyl, fluazifop-p-butyl, fluazolate, flucarbazone, flucarbazone-sodium, flucetosulfuron, fluchloraline, Flufenaset (thiafluamide), flufenpyr, flufenpyr-ethyl, flumetraline, flumetram, flumicrolac, flumicrolac-pentyl, flumioxazin, flumipropine, fluometulone, fluorodiphen, fluoroglycophene, fluoroglycophene-ethyl, flupoxam , Flupropacil, flupropanate, flupyrsulfuron, flupyrsulfuron-methyl-sodium, flureno , Flurenol-butyl, -dimethylammonium and -methyl, fluridone, flurochloridone, fluroxypyr, fluroxypyr-meptyl, fluruprimol, flurutamon, flutiaset, flutiaset-methyl, fluthiamide, fomethafen, fomesaphene-sodium, holhamus Rufuron, forchlorphenuron, fosamine, furyloxyphen, gibberellic acid, glufosinate, glufosinate-ammonium, glufosinate-P, glufosinate-P-ammonium, glufosinate-P-sodium, glyphosate, glyphosate, isopropyl ammonium, -ammonium, diphos Ammonium, dimethylammonium, -potassium, -sodium and trimesium, H-9201, ie O- (2 4-Dimethyl-6-nitrophenyl) -O-ethyl-isopropylphosphoramidothioate, halauxifene, halosaphene, halosulfuron, halosulfuron-methyl, haloxifop, haloxifop-P, haloxyfop-ethoxyethyl, haloxypop-P -Ethoxyethyl, haloxyfop-methyl, haloxyfop-P-methyl, hexadinone, HW-02, ie 1- (dimethoxyphosphoryl) -ethyl- (2,4-dichlorophenoxy) acetate, imazamethabenz, imazamethabenz-methyl, imazamox, imazamox- Ammonium, imazapic, imazapyr, imazapyr-isopropylammonium, imazaquin, imazaquin-ammonium, imazethapyr, imazethapyr-ammonium, Mazosulfuron, inabenfide, indanophane, indadifulam, indol-3-ylacetic acid (IAA), 4-indol-3-ylbutyric acid (IBA), iodosulfuron, iodosulfuron-methyl-sodium, ionfensulfuron, ionfensulfuron- Sodium, ioxynyl, ioxynyl-octanoate, -potassium and -sodium, ifphencarbazone, isocarbamide, isopropaline, isoproturon, isouron isoxaben, isoxacrotol, isoxaflutole, isoxapyrihop, carbutylate, KUH-043, ie 3-({[5- (difluoromethyl) -1-methyl-3- (trifluoromethyl) -1H-pyrazol-4-yl] methyl} sulfonyl) -5,5-dimethyl-4 5-Dihydro-1,2-oxazole, Carbutylate, Ketospiradox, Lactophene, Lenacil, Linuron, Maleic Hydrazide, MCPA, MCPA-Butyl, -Dimethylammonium, -2-Ethylhexyl, Isopropylammonium,-Potassium and-Sodium , MCPB, MCPB-methyl, -ethyl and-sodium, mecoprop, mecoprop-sodium, mecoprop-butyt, mecoprop-P-butyt, mecoprop-P, mecoprop-P-dimethylammonium, mecoprop-P-2-ethylhexyl, mecoprop- P-potassium, mefenacet, mefluidide, mepicoteto-chloride, mesosulfuron, mesosulfuron-methyl, mesotrione, methabenzthiazurone, , Metamihop, metamitrone, metazachlor, metazasulfuron, metabenzthiazolone, metazole, methiopyrsulfuron, methiozoline, methoxyphenone, methyl dymuron, 1-methylcyclopropene, methyl isothiocyanate, methobenzolone, methobromone, metolachlor S-metolachlor, methosulam, methoxuron, metribuzin, methsulfuron, methsulfuron-methyl, molinate, monarid, monocarbamide, monocarbamido dihydrogen sulfate, monolinuron, monosulfuron, monosulfuron ester, monuron, MT 128, ie 6-chloro- N-[(2E) -3-Chloroprop-2-en-1-yl] -5-methyl-N-phenylpyridazin-3-amine, MT-5950, abrading N- [3-chloro-4- (1-methylethyl) -phenyl] -2-methylpentanamide, NGGC-011, naproanilide, napropamide, napthalam, NC-310, i.e. 4- (2,4-dichlorobenzoyl) -1-methyl-5-benzyloxypyrazole, nebrone, nicosulfuron, nipiraclofen, nitraline, nitrophen, nitrophenolato-sodium (isomer mixture), nitrofluorfen, nonanoic acid, norflurazon, oleic acid (fatty acid), olbencarb, Orthosulfamurone, orizarin, oxadiargyl, oxadiazon, oxasulfuron, oxadiclomefone, oxyfluorfen, paclobutrazol, paraquat, paraquat-dichloride, pebrate, pelargonic acid (nonanoic acid , Pendimethalin, pendraline, penoxsulam, pentanochlor, pentachlorophenol, pentoxazone, perfluidon, petoxamide, petroleum, phenisocham, fenmedifam, fenmedifam-ethyl, picloram, picolinafen, pinoxaden, piperophos, pifenofop, piryfenop-butyl, pretilacrole pri, Missulfuron, primisulfuron-methyl, probenazole, profluazole, prolysazine, prodiamine, prifluraline, profoxydim, prohexadione, prohexadione-calcium, prohydrojasmone, prometon, promethrin, propachlor, propanil, propakihop, Propazine, Propham, Propisochlor, Propoxycarbazone, Propoxyca Rubazone-sodium, propyrisulfuron, propizamide, prosulfaline, prosulfocarb, prosulfuron, prinacurol, pyraclonyl, pyraflufen, pyraflufen-ethyl, pyrasulfotol, pyrazolinate (pyrazolate), pyrazosulfuron, pyrazosulfuron-ethyl, pyrazoxifene, pyri- bambenz , Piribam benz-isopropyl, pyri bumb-propyl, pyribenzoxim, pyributoxib, pyridaphor, pyridate, pyriphthalide, pyriminobac, pyriminobac-methyl, pyrimisulfan, pyrithiobac, pyrithiobac, pyrioxabac-sodium, piroxisulfone, pyroxyslam, quinclorac, quinmerac, quinoxamine, xizarohop , Kizaro hop-ethyl, Kizaro hop- , Qizarohop-P-ethyl, Qizarohop-P-tefuryl, rimsulfuron, saflufenacil, secubumetone, cetoxidim, sidurone, simazine, simetryn, SN-106279, ie methyl- (2R) -2-({7- [2-chloro- 4- (trifluoromethyl) phenoxy] -2-naphthyl} oxy) propanoate, sulcotrione, sulfarate (CDEC), sulfentrazone, sulfometuron, sulfometuron-methyl, sulfosate (glyphosate-trimesium), sulfosulfuron, SW- 065, SYN-523, SYP-249, ie 1-ethoxy-3-methyl-1-oxobut-3-en-2-yl-5- [2-chloro-4- (trifluoromethyl) phenoxy] -2- Nitro benzoate SYP-300, i.e. 1- [7-fluoro-3-oxo-4- (prop-2-yn-1-yl) -3,4-dihydro-2H-1,4-benzoxazin-6-yl]- 3-Propyl-2-thioxoimidazolidine-4,5-dione, 2,3,6-TBA, tebutam, tebuthiuron, technazene, tebuthiuron, tefuryltrione, tebotorion, tepraroxidim, terbacyl, terbucarb, terbuchlor, terbumetone , Terbutyrazin, terbutrin, tenicrol, thiafluamide, thiazafluron, thiazopyr, thidiazimine, thidiazurone, thienecarbazone, thienecarbazone-methyl, thifensulfuron, thifensulfuron-methyl, thiobencarb, thiocarbilis, topramezone, tolarcoxizim, tri Afamon, Trialato, Triasulfuron, Triadiphram, Triazophenamide, Tribenuron, Tribenuron-Methyl, Trichloroacetic Acid (TCA), Tebutyuron, Triclopyr, Tridiphane, Triethadine, Trifloxysulfuron, Trifloxysulfuron-sodium, Trifluralin, Trifluroline Sulfuron, triflusulfuron-methyl, trimeturon, trinexapac, trinexapac-ethyl, tritosulfuron, titofef, uniconazole, uniconazole-P, urea sulfate, vernolate, ZJ-0862, ie 3, 4 -Dichloro-N- {2- [4,6-dimethoxypyrimidin-2-yl) oxy] benzyl} aniline, and the following compounds:

Hereinafter, examples of herbicides which can be used in the present invention are classified and illustrated according to the mechanism of action.

(1) Acetyl-CoA carboxylase (ACCase) inhibitors Aroxyphenoxypropionic acid-based ACCase inhibitors: clodinafop propargyl, cyhalohop-butyl, diclohop-methyl, fenoxaprop-P-ethyl, fluazifop-P-butyl, halokihop-R・ Methyl, propakizap, quizarohop ・ P, ethyl, metamihop, cyclohexanedione ACCase inhibitor: Alloxydim, butoroxidim, cresodym, cycloxidim, profoxydim, cetoxydim, tralkoxidim phenylpyrazoline based ACCase inhibitor: pinoxaden (2 ) Acetolactate synthetase (ALS) inhibitor sulfonylurea type ALS inhibitor: amidosulfuron, azimsulfuron, bens Ruflon methyl, chlorimuron ethyl, chlorsulfuron, cinosulfuron, cyclosulfamuron, etamethosulfuron methyl, ethoxysulfuron, flazasulfuron, flupyrsulfuron methyl Na, foramsulfuron methyl, halosulfuron methyl, Imazosulfuron, iodosulfuron, mesosulfuron methyl, methosulfuron methyl, nicosulfuron, oxsulfuron, primisulfuron methyl, pyrazosulfuron ethyl, rimsulfuron, sulfomethuron methyl, sulfosulfuron, thifensulfuron methyl, triasulfuron , Tribenuron methyl, trifloxysulfuron, triflusulfuron methyl, tritosulfuron, orthosulfamuron, TH547, NC620 imidazolinone type (ALS) inhibitors: imazapic, imazamethabenz methyl, imazamox, imazapyr, imazaquin, imazetapyr triazolo pyrimidine ALS inhibitor: chlorans lum methyl, dicloslam, florasulam, flumetulam, metoslam, penoxsulam pyrimidinyl salicylic acid based ALS inhibitor: Bispyribac sodium salt, pyribenzoxim, pyriphthalide, pyrithiobac sodium salt, pyriminobac methyl, pyrimisulfan Triazolinone ALS inhibitor: flucarbazone sodium salt, propoxycarbazone sodium salt, thienecarbazone (3) photosynthesis inhibitor (photosystem II) ) Triazines: ametrine, atrazine, cyanazine, desmethrin, dimetamethrin, promethone, promethrin, Propazine, simazine, simetryn, terbumetone, terbutyrazine, terbutrin, triethazine triazinone: hexazinone, metamitrone, metribuzine triazolinone: amicarbazone uracil: bromacil, lenacil, terabacil pyridazinone: chloridazone phenyl carbamate system: desmedum fame femjum : Chlorbromulon, chlorotoluron, chloroxuron, dimefron, diuron, etidimolone, phenuron, fluometuron, isopromone, isuronone, linuron, methabenzthiazuron, methobromone, methoxuron, monolinuron, nebron, siduron, tebutiuron amide system: propanil, pentanochlor Nitrile series: Bromophenoxyme, Bromoxini , Ioxynyl Benzothiadiazinone: Bentazone Phenylpyridazine: Pyridate, pyridaphor (4) Photoactive agent for developing toxicity (Photosystem II) Bipyridinium: Diquat, Paraquat (5) Protoporphyrinogen oxidase (PPO) inhibitor Diphenyl ether system: acifluorphen, biphenox, chloromethoxyphen, fluoroglycophene, fomethafen, halosaphene, lactofen, oxyfluorphen, cromethoxynyl phenylpyrazole system: fluazolate, pyraflufen-ethyl N-phenylphthalimide system: sinidone ethyl, flumioxazin Microlac pentyl thiadiazole system: fluthiaset methyl, thidiazimine oxadiazole system: oxadiazone, Xazadialgyl triazolinone: azaphenidine, carfentrazone ethyl, sulfentrazone oxazolidinedione: pentoxazone pyrimidinedione: benzphendizone, butaphenacil others: pyraclonyl, profluazole, flufenpyr ethyl (6) carotenoid biosynthesis inhibition Agents (a) PDS inhibitors Pyridazinone: norflurazon Pyridinecarboxamide: Diflufenican, picolinaphen Others: Beflubutamide, fluridone, flurochloridone, flurtamone (b) 4-HPPD inhibitors Triketones: Mesotrione, sulcotrione, benzobicyclone, Tefuryltrione isoxazole system: isoxachlortol, isoxaflutole pyrazole system: benzophenap, pyrazoline , Pyrazoxifene Other: Benzobicyclone (c) Targets not elucidated Triazole: Amitrole Isoxazolidinone: Chromazone Diphenylether: Acronifene (7) EPSP Synthase Inhibitor Glycine: Glyphosate, Glyphosate Trimesium Salt (8) Glutamine synthetase inhibitors Phosphinic acid system: glufosinate, bialaphos (9) DHP biosynthesis inhibitor carbamate system: ashram (10) microtubule polymerization inhibitor dinitroaniline system: Vethrosin, butoralin, dinitramine, etalfluralin, orizarin, pendy Metaline, trifluralin Phosphoric acid amide system: amiprophos methyl, butamiphos pyridine system: dithiopyr, thiazopyr benzamide system: propizamide, tebutam, chlorthal dimethyl (11) Mitotic and microtubule formation inhibitors Carbamate: chlorprofam, profam, calbetamide (12) Very long chain fatty acid biosynthesis inhibitor Chloroacetamide: Acetochlor, alachlor, butachlor, dimethachlor, dimethenamide, metazachlor, metolachlor , Petoxamide, pretilacurol, propacrole, propisocurol, tenicrol acetamide system: diphenamide, napropamide, naproanilide oxyacetamide system: flufenaset, mefenaset tetrazolinone system: fentrazamide others: anilophos, cafentrol, piperophos (13) cellulose biosynthesis inhibitor nitrile system : Niclobenyl, chlorthiamide, benzamide type: isoxaben triazolocarboxamide type: flupoxam quinoline Carboxylic acid system: quinclorac (14) uncoupler dinitrophenol system: DNOC, dinoseb, dinoterb (15) fatty acid elongation inhibitor (non ACCase inhibition) Thiocarbamate system: butyrate, cycloate, dimepiperate, EPTC, esprocarb, molinate, Orbencarb, Peblate, Prosulfocarb, Benthiocarb, Pyributicarb, Thiocarbasil, Trialate, Barnarate Phosphate Dithioate: Benthride Benzophenate: Benfletherate, Etofumesate Chlorcarbonic Acid: TCA, Darapon, Tetrapion (16) Auxin-like Herbicide Phenoxycarbon Acid system: Clomeprop, 2,4-D, 2,4-DB, dicloprop, MCPA, MCPB, MCPP Benzoate system: Chlorane Ben, dicamba, 2,3,6-TBA Pyridine carboxylic acid system: Clopyralide, fluroxypyr, picloram, triclopyr, quinclorac, quinmelac Others: Benazoline ethyl (17) auxin translocation inhibitor Naftaramate system: Napthalam, semicarbazone system: Diflufenzopyr sodium salt, (18) Other (action mechanism unknown) Arylamino propionic acid system: Flamprop M, Methyl, flamprop isopropyl, Pyrazolium system: Diphenzo coat, Organic Arsenic system: DSMA, MSMA, Others: Bromobutide, chlorflurenol, cimetriline, cumylone, dazomet, dymuron, methyl dymuron, ethybenzonide, fosamine, indanophane, metam, oxadiclomephone, oleic acid, pelargo Acid, Pyributicarb.

Moreover, as a herbicide, what consists of a sulfonylurea type compound, a sulfone anilide type compound, a benzoyl cyclohexane dione type compound, or its salt is preferable. Particularly preferable examples include pyrimisulfan, triafamone and the like as examples of sulfone anilide type compounds. In addition, examples of benzoylcyclohexanedione compounds include tefuryltrione, ketospiradox, mesotrione, sulcotrione, tembotrione and the like.

Examples of plant growth regulators are acibenzolar, acibenzolar-S-methyl, 5-aminolevulinic acid, ancimidol, 6-benzylaminopurine, brassinolide, catechin, chlormecoat chloride, cloprop, cyclanilide, 3- (cycloprop -1-enyl) propionic acid, daminozide, dazomet, n-decanol, dikeglac, dikeglac-sodium, endothal, endothal-dipotassium, -disodium and -mono (N, N-dimethylalkylammonium), ethephon, flumetraline , Flurenol, flurenol-butyl, fluprimidol, forchlorphenuron, gibberellic acid, inabenfide, indole-3-acetic acid (IAA), 4-indol-3-ylbutyric acid, isoprothiolane, probena , Jasmonic acid, maleic acid hydrazide, mepiquat chloride, 1-methylcyclopropene, methyl jasmonate, 2- (1-naphthyl) acetamide, 1-naphthylacetic acid, 2-naphthyloxyacetic acid, nitrophenolate mixture Paclobutrazol, N- (2-phenylethyl) -β-alanine, N-phenylphthalamic acid, prohexadione, prohexadione-calcium, prohydrojasmone, salicylic acid, strigolactone, technazen, thidiazuron, Thiacontanol, trinexapac, trinexapac-ethyl, chitodef, uniconazole, uniconazole-P.

Examples of fungicides in mixed preparations or tank mixes as defined herein by their "generic name" which can be used in the control step are known and are described, for example, in the Pesticide Manual, or You can search on the Internet (eg, http://www.alanwood.net/pesticides).

1) Inhibitors of ergosterol biosynthesis, such as (1.1) aldimorph, (1.2) azaconazole, (1.3) bitertanol, (1.4) bromuconazole, (1.5) cyproconazole, (1.6) diclobutrazol, (1.7) difenoconazole, (1.8) diniconazole, (1.9) diniconazole-M, (1. 10) dodemorph, (1.11) dodemorph acetate, (1.12) epoxiconazole, (1.13) etaconazole, (1.14) phenalimol, (1.15) fenbuconazole, (1.16) fenhexamide, (1. 17) fenpropidine, (1.18) fenpromimorph, (1.19) fluquinconazole, (1. 20) flurprimidol, (1.21) flusilazole, (1.22) Triaphor, (1.23) fluconazole, (1.24) fluconazole-cis, (1.25) hexaconazole, (1.26) imazalil, (1.27) imazalil sulfate, (1.28) imevenco Nazole, (1.29) Ipconazole, (1.30) Metoconazole, (1.31) Microbutanil, (1.32) Naftifine, (1.33) Nuarimol, (1.34) Oxypoconazole, (1.35) ) Paclobutrazol, (1.36) peflazoate, (1.37) penconazole, (1.38) piperaline, (1.39) prochloraz, (1.40) propiconazole, (1.41) prothiocona Zol, (1.42) pyributycarb, (1.43) pyriphenox, (1.44) quinconazole, (1.45) simecona (1.46) spiroxamine, (1.47) tebuconazole, (1.48) terbinafine, (1.49) tetraconazole, (1.50) triadimefon, (1.51) triadimenol ( 1.52) Tridemorph, (1.53) Triflumizole, (1.54) Triphorin, (1.55) Triticonazole, (1.56) Uniconazole, (1.57) Uniconazole-p, ( 1.58) Viniconazole, (1.59) Voriconazole, (1.60) 1- (4-Chlorophenyl) -2- (1H-1,2,4-triazol-1-yl) cycloheptanol, (1. 61) Methyl 1- (2,2-dimethyl-2,3-dihydro-1H-inden-1-yl) -1H-imidazole-5-carboxylate, (1.62) N'-
{5- (Difluoromethyl) -2-methyl-4- [3- (trimethylsilyl) propoxy] phenyl} -N-ethyl-N-methylimidoformamide, (1.63) N-ethyl-N-methyl-N ' -{2-methyl-5- (trifluoromethyl) -4- [3- (trimethylsilyl) propoxy] phenyl} imidoformamide, (1.64) O- [1- (4-methoxyphenoxy) -3,3- Dimethylbutan-2-yl] 1 H-imidazole-1-carbothioate, (1.65) pyrazoloxazole.

2) Inhibitors of the respiratory chain in complex I or II, for example (2.1) bixafen, (2.2) boscalid, (2.3) carboxin, (2.4) diflumetrim, (2.5 ) Fenfram, (2.6) Fluopyram, (2.7) Flutolanil, (2.8) Fluxapiroxide, (2.9) Flamethopyr, (2.10) Flumecrox, (2.11) Isopyrazam ( syn-epimeric racemate 1RS, 4SR, 9RS and anti-epimer racemate 1RS, a mixture of 4SR, 9SR), (2.12) isopyrazam (anti-epimeric racemate 1RS, 4SR, 9SR), (2.13) isopyrazam (anti-epimeric enantiomer 1R) , 4S, 9S), (2.14) Isopyrazam (anti-epimeric enantiomers 1S, 4R, 9R), (2.15) Isopyrazam (syn-epimeric racemate 1RS, 4SR, 9RS), (2.16) Isopyrazam (syn-epimeric enantiomer 1R, 4S, 9R), (2.17) Isopyrazam (syn-epimeric enantiomer 1S, 4R, 9S), ( 2.18) Mepronil, (2.19) Oxycarboxin, (2.20) Penfluene, (2.21) Penthiopyrade, (2.22) Sedaxane, (2.23) Thifluzamide, (2.24) 1- Methyl-N- [2- (1,1,2,2-tetrafluoroethoxy) phenyl] -3- (trifluoromethyl) -1H-pyrazole-4-carboxamide, (2.25) 3- (difluoromethyl) -1-Methyl-N- [2- (1,1,2,2-tetrafluoroethoxy) phenyl] -1H-pyrazole 4-carboxamide, (2.26) 3- (difluoromethyl) -N- [4-fluoro-2- (1,1,2,3,3,3-hexafluoropropoxy) phenyl] -1-methyl-1H -Pyrazole-4-carboxamide, (2.27) N- [1- (2,4-dichlorophenyl) -1-methoxypropan-2-yl] -3- (difluoromethyl) -1-methyl-1H-pyrazole- 4-carboxamide, (2.28) 5, 8-difluoro-N- [2- (2-fluoro-4-{[4- (trifluoromethyl) pyridin-2-yl] oxy} phenyl) ethyl] quinazoline- 4-amine, (2.29) benzobin diflupyr, (2.30) N-[(1S, 4R) -9- (dichloromethylene) -1,2,3,4-tetrahydro-1,4-methanonaphthale -5-yl] -3- (difluoromethyl) -1-methyl-1H-pyrazole-4-carboxamide, (2.31) N-[(1R, 4S) -9- (dichloromethylene) -1,2 , 3,4-tetrahydro-1,4-methanonaphthalen-5-yl] -3- (difluoromethyl) -1-methyl-1H-pyrazole-4-carboxamide, (2.32) 3- (difluoromethyl)- 1-Methyl-N- (1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl) -1H-pyrazole-4-carboxamide, (2.33) 1,3,5-trimethyl -N- (1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl) -1H-pyrazole-4-carboxamide, (2.34) 1-methyl-3- (trifluoromethyl) )-N- 1,1,3-Trimethyl-2,3-dihydro-1H-inden-4-yl) -1H-pyrazole-4-carboxamide, (2.35) 1-methyl-3- (trifluoromethyl) -N- [(3R) -1,1,3-Trimethyl-2,3-dihydro-1H-inden-4-yl] -1H-pyrazole-4-carboxamide, (2.36) 1-methyl-3- (trifluoro) Methyl) -N-[(3S) -1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl] -1H-pyrazole-4-carboxamide, (2.37) 3- (difluoro) Methyl) -1-methyl-N-[(3S) -1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl] -1H-pyrazole-4-carboxamide, (2.38) 3- (difluorome) L) -Methyl-N-[(3R) -1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl] -1H-pyrazole-4-carboxamide, (2.39) 1,3,5-trimethyl-N-[(3R) -1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl] -1H-pyrazole-4-carboxamide, (2.40 ) 1,3,5-trimethyl-N-[(3S) -1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl] -1H-pyrazole-4-carboxamide, (2. 41) Benodanyl, (2.42) 2-chloro-N- (1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl) pyridine-3-carboxamide, (2.43) N -[1- (4-Isopropoxy-2-methyl] Rulphenyl) -2-methyl-1-oxopropan-2-yl] -3-methylthiophene-2-carboxamide.

3) Inhibitors of the respiratory chain in complex III, for example (3.1) ametocutrazine, (3.2) amiculblom, (3.3) azoxystrobin, (3.4) ciazofamide, (3.5 ) Cow Methoxystrobin, (3.6) Cumoxystrobin, (3.7) Dymoxystrobin, (3.8) Enoxastrobin, (3.9) Famoxadone, (3.10) Fenamidon, (3.11) Fluphenoxystrobin, (3.12) Fluoxastrobin, (3.13) Kresoxim-methyl, (3.14) Metominostrobin, (3.15) Orysastrobin. (3.16) picoxystrobin, (3.17) pyraclostrobin, (3.18) pyramethostrobin, (3.19) pyraxystrobin, (3. 20) pyribencarb, (3.21) Triclopyricarb, (3.22) Trifloxystrobin, (3.23) (2E) -2- (2-{[6- (3-chloro-2-methylphenoxy) -5-fluoropyrimidine-4-) [Il] oxy} phenyl) -2- (methoxyimino) -N-methylacetamide, (3.24) (2E) -2- (methoxyimino) -N-methyl-2- (2-{[({({(1E) )-[3- (Trifluoromethyl) phenyl] ethylidene} amino] oxy] methyl} phenyl) acetamide, (3.25) (2E) -2- (methoxyimino) -N-methyl-2- {2 -[( )-({1- [3- (trifluoromethyl) phenyl] ethoxy} imino) methyl] phenyl} acetamide, (3.26) (2E) -2- {2-[({[(1E) -1-] (3-{[(E) -1-Fluoro-2-phenylvinyl] oxy} phenyl) ethylidene] amino} oxy) methyl] phenyl} -2- (methoxyimino) -N-methylacetamide, (3.27) Phenaminostrobin, (3.28) 5-methoxy-2-methyl-4- (2-{[({(1E) -1- [3- (trifluoromethyl) phenyl] ethylidene} amino) oxy] methyl } Phenyl) -2,4-dihydro-3H-1,2,4-triazol-3-one, (3.29) methyl (2E) -2- {2-[({cyclopropyl [(4-methoxyphenyl)] ) Imino] [Silyl] sulfanyl) methyl] phenyl} -3-methoxyacrylate, (3.30) N- (3-ethyl-3,5,5-trimethylcyclohexyl) -3-formamide-2-hydroxybenzamide, (3.31) 2- {2-[(2,5-dimethylphenoxy) methyl] phenyl} -2-methoxy-N-methylacetamide, (3.32) 2- {2-[(2,5-dimethylphenoxy) methyl] phenyl } -2-Methoxy-N-methylacetamide.

4) Inhibitors of mitosis and cell division, such as (4.1) benomyl, (4.2) carbendazim, (4.3) chlorphenazole, (4.4) dietophene carb, (4.5) Etavoxam, (4.6) fluopicolide, (4.7) fuberidazole, (4.8) penciclone, (4.9) thiabendazole, (4. 10) thiophanate-methyl, (4.11) thiophanate, (4.12) ) Zoxamide, (4.13) 5-chloro-7- (4-methylpiperidin-1-yl) -6- (2,4,6-trifluorophenyl) [1,2,4] triazolo [1,5] -A] pyrimidine, (4.14) 3-chloro-5- (6-chloropyridin-3-yl) -6-methyl-4- (2,4,6-trifluorophenyl) pyridazine.

5) Compounds capable of exhibiting multipoint action, such as (5.1) Bordeaux mixture, (5.2) captaphor, (5.3) captan, (5.4) chlorothalonil, (5.5) water Copper oxide, (5.6) Copper naphthenate, (5.7) Copper oxide, (5.8) Copper oxychloride, (5.9) Copper sulfate (2+), (5. 10) Dichlorofluanid (, 5.11) Dithianone, (5.12) Dodine, (5.13) Tozine free base, (5.14) Ferbum, (5.15) Fluorophorpet, (5.16) Folpet, (5.17) ) Guazatine, (5.18) Guazatine Acetate, (5.19) Iminoctadine, (5.20) Iminoctazine Albesylate, (5.21) Iminoctadine Triacetate, (5.22) Mancoper, (5.23) Mankozeb, (5.24) Maneb, 5.25) Methylam, (5.26) Methylamzinc, (5.27) Oxine-Copper, (5.28) Propamidine, (5.29) Propineb, (5.30) Sulfur and Sulfur Containing Calcium Polysulfide Formulation, (5.31) Thiram, (5.32) Tolylfluanide, (5.33) Dineb, (5.34) Diram, (5.35) Anilazine.

6) Compounds capable of inducing host defense, such as (6.1) Acibenzolar-S-methyl, (6.2) Isotianil, (6.3) Probenazole, (6.4) Thiazinyl, (6.5) Laminarin.

7) Inhibitors of amino acid and / or protein biosynthesis, such as (7.1) and prim, (7.2) blasticidin-S, (7.3) cyprodinil, (7.4) kasugamycin, (7.5 ) Kasugamycin salt trihydrate, (7.6) mepanipyrim, (7.7) pyrimethanyl, (7.8) 3- (5-fluoro-3,3,4,4-tetramethyl-3,4-dihydro) Isoquinolin-1-yl) quinoline, (7.9) oxytetracycline, (7.10) streptomycin.

8) Inhibitors of ATP production, such as (8.1) Pentin acetate, (8.2) Pentin chloride, (8.3) Pentin hydroxylate, (8.4) Sylthiofam.

9) Inhibitors of cell wall synthesis, such as (9.1) Benchavariculab, (9.2) dimethomorph, (9.3) flumorph, (9.4) iprobicarb, (9.5) mandipropamide, (9) .6) Polyoxin, (9.7) Polyoxolim, (9.8) Validamycin A, (9.9) Varifenarate, (9.10) Polyoxin B.

10) Inhibitors of lipid and membrane synthesis, such as (10.1) biphenyl, (10.2) chloroneb, (10.3) dichlorane, (10.4) edifenphos, (10.5) etoridiazole, (10. 6) Iodocarb, (10.7) Iprobenphos, (10.8) Isoprothiolane, (10.9) Propamocarb, (10.10) Propamocarb Hydrochloride, (10. 11) Prothiocarb, (10. 12) Pyrazophos, (10. 13) Quintozene, (10.14) Technazen, (10.15) Torclophos-Methyl.

11) Inhibitors of melanin biosynthesis, such as (11.1) carpropamide, (11.2) diclocimet, (11.3) phenoxanyl, (11.4) phthalide, (11.5) piroxolone, (11.6) ) Tricyclazole, (11.7) 2,2,2-trifluoroethyl {3-methyl-1-[(4-methylbenzoyl) amino] butan-2-yl} carbamate.

12) Inhibitors of nucleic acid synthesis, such as (12.1) Benaraxil, (12.2) Benaraxyl-M (chiralaxyl), (12.3) Bupyrimiate, (12.4) Clodirachone, (12.5) Dimethymol, (12.6) Ethylimol, (12.7) flalaxyl, (12.8) hymexazole, (12.9) metalaxyl, (12. 10) metalaxyl-M (mefenoxam), (12. 11) off race, (12 .12) Oxadixyl, (12.13) oxophosphoric acid, (12.14) octylinone.

13) Inhibitors of signal transduction, such as (13.1) clozolinate, (13.2) pheniclonyl, (13.3) fludioxonil, (13.4) iprodione, (13.5) procymidone, (13.6) Quinoxifene, (13.7) vinclozolin, (13.8) proquinazid.

14) Compounds that can act as uncouplers, for example (14.1) binapacryl, (14.2) dinocup, (14.3) ferrimzone, (14.4) fluazinam, (14.5) methyl dinocup.

15) Other compounds, for example, (15.1) benzazole, (15.2) betoxazine, (15.3) capcymycin, (15.4) carvone, (15.5) quinomethionate, (15.6) Pyrofenone (clazaphenone), (15.7) kuflaneb, (15.8) cyflufenamide, (15.9) shimoxanyl, (15. 10) cyprosulfamide, (15. 11) dazomet, (15. 12) debucarb, (15.13) Dichlorophene, (15.14) Dichromedin, (15.15) Diphenzocoat, (15.16) Diphenzocoat Methyl Sulfate, (15.17) Diphenylamine, (15.18) Ecomate, ( 15.19) Fenpyrazamine, (15.20) fulmethobel, (15.21) fluoroimide, (15. 20). 2) Flusulfamide, (15. 23) flutianil, (15. 24) focetyl-aluminum, (15.25) focetyl-calcium, (15. 26) focetyl-sodium, (15. 27) hexachlorobenzene, (15. 28) ) Irmamycin, (15.29) methasulfocarb, (15.30) methyl isothiocyanate, (15. 31) metraphenone, (15. 32) mildiomycin, (15. 33) natamycin, (15. 34) Nickel dimethyl dithiocarbamate, (15.35) nitrotal-isopropyl, (15.37) oxamocarb, (15. 38) oxyphenthiin, (15. 39) pentachlorophenol and salts, (15. 40) phenothrin, (15. .41) Phosphoric acid and its salts, (15 42) Propamocarb-Fosetilate, (15.43) Propanocine-sodium, (15.44) Pyrimorph, (15.45) (2E) -3- (4-tert-butylphenyl) -3- (2-chloropyridine- 4-yl) -1- (morpholin-4-yl) prop-2-en-1-one, (15.46) (2Z) -3- (4-tert-butylphenyl) -3- (2-chloro) Pyridin-4-yl) -1- (morpholin-4-yl) prop-2-en-1-one, (15.47) pyrrolnitrine, (15.48) tebufloquine, (15.49) teclophthalam, ( 15.50) Tornifanide, (15.51) Triazoxide, (15.52) Triclamide, (15. 53) Zarylamide, (15. 54) (3S, 6S, 7R, 8R) -8- Benzyl-3-[({3-[(isobutyryloxy) methoxy] -4-methoxypyridin-2-yl} carbonyl) amino] -6-methyl-4,9-dioxo-1,5-dioxonan-7 -Yl 2-methylpropanoate, (15.55) 1- (4- {4-[(5R) -5- (2,6-difluorophenyl) -4,5-dihydro-1,2-oxazole- 3-yl] -1,3-thiazol-2-yl} piperidin-1-yl) -2- [5-methyl-3- (trifluoromethyl) -1H-pyrazol-1-yl] ethanone, (15. 56) 1- (4- {4-[(5S) -5- (2,6-difluorophenyl) -4,5-dihydro-1,2-oxazol-3-yl] -1,3-thiazole-2 -Yl} piperidin-1-yl) -2- [5-methyl -3- (trifluoromethyl) -1H-pyrazol-1-yl] ethanone, (15.57) 1- (4- {4- [5- (2,6-difluorophenyl) -4,5-dihydro- 1,2-oxazol-3-yl] -1,3-thiazol-2-yl} piperidin-1-yl) -2- [5-methyl-3- (trifluoromethyl) -1H-pyrazol-1-yl Ethanone, (15.58) 1- (4-Methoxyphenoxy) -3,3-dimethylmethan-2-yl 1H-imidazole-1-carboxylate, (15.59) 2,3,5,6-tetra Chloro-4- (methylsulfonyl) pyridine, (15.60) 2,3-dibutyl-6-chlorothieno [2,3-d] pyrimidin-one, (15.61) 2,6-dimethyl-1H, 5H- [1,4] jichi [2,3-c: 5,6-c ′] dipyrrole-1,3,5,7 (2H, 6H) -tetron, (15.62) 2- [5-methyl-3- (trifluoromethyl) -1H-Pyrazole-1-yl] -1- (4- {4-[(5R) -5-phenyl-4,5-dihydro-1,2-oxazol-3-yl] -1,3-thiazole- 2-yl} piperidin-1-yl) ethanone, (15.63) 2- [5-methyl-3- (trifluoromethyl) -1H-pyrazol-1-yl] -1- (4- {4- [4 (5S) -5-phenyl-4,5-dihydro-1,2-oxazol-3-yl] -1,3-thiazol-2-yl} piperidin-1-yl) ethanone, (15.64) 2- [5-Methyl-3- (trifluoromethyl) -1H-pyrazol-1-yl] -1- 4- [4- (5-phenyl-4,5-dihydro-1,2-oxazol-3-yl) -1,3-thiazol-2-yl] piperidin-1-yl} ethanone, (15.65) 2-butoxy-6-iodo-3-propyl-4H-chromen-4-one, (15.66) 2-chloro-5- [2-chloro-1- (2,6-difluoro-4-methoxyphenyl) -4-Methyl-1H-imidazol-5-yl] pyridine, (15.67) 2-phenylphenol and salts, (15.68) 3- (4,4,5-trifluoro-3,3-dimethyl- 3,4-Dihydroisoquinolin-1-yl) quinoline, (15.69) 3,4,5-trichloropyridine-2,6-dicarbonitrile, (15.70) 3-chloro-5- (4-chlorophenyl) ) -4- (2, 6-) Difluorophenyl) -6-methylpyridazine, (15.71) 4- (4-chlorophenyl) -5- (2,6-difluorophenyl) -3,6-dimethylpyridazine, (15.72) 5-amino-1 3,4-thiadiazole-2-thiol, (15.73) 5-chloro-N'-phenyl-N '-(prop-2-yn-1-yl) thiophene-2-sulfonohydrazide, (15. 74) 5-fluoro-2-[(4-fluorobenzyl) oxy] pyrimidin-4-amine, (15.75) 5-fluoro-2-[(4-methylbenzyl) oxy] pyrimidin-4-amine, ((5.75) 15.76) 5-Methyl-6-octyl [1,2,4] triazolo [1,5-a] pyrimidin-7-amine, (15.77) ethyl (2Z) -3-amino-2-cyano- 3- Henyl acrylate, (15.78) N '-(4-{[3- (4-chlorobenzyl) -1,2,4-thiadiazol-5-yl] oxy} -2,5-dimethylphenyl) -N- Ethyl-N-methylimidoformamide, (15.79) N- (4-chlorobenzyl) -3- [3-methoxy-4- (prop-2-yn-1-yloxy) phenyl] propanamide, (15. 80) N-[(4-Chlorophenyl) (cyano) methyl] -3- [3-methoxy-4- (prop-2-yn-1-yloxy) phenyl] propanamide, (15.81) N-[(( 5-bromo-3-chloropyridin-2-yl) methyl] -2,4-dichloronicotinamide, (15.82) N- [1- (5-bromo-3-chloropyridin-2-yl) ethyl] -2,4-di Rolonicotinamide, (15.83) N- [1- (5-bromo-3-chloropyridin-2-yl) ethyl] -2-fluoro-4-iodonicotinamide, (15.84) N-{(( E)-[(Cyclopropylmethoxy) imino] [6- (difluoromethoxy) -2,3-difluorophenyl] methyl} -2-phenylacetamide, (15.85) N-{(Z)-[(cyclopropyl) Methoxy) imino] [6- (difluoromethoxy) -2,3-difluorophenyl] methyl} -2-phenylacetamide, (15.86) N '-{4-[(3-tert-butyl-4-cyano- 1,2-thiazol-5-yl) oxy] -2-chloro-5-methylphenyl} -N-ethyl-N-methylimido formamide, (15.87) N-methyl-2- ( -{[5-methyl-3- (trifluoromethyl) -1H-pyrazol-1-yl] acetyl} piperidin-4-yl) -N- (1,2,3,4-tetrahydronaphthalen-1-yl) 1,3-thiazole-4-carboxamide, (15.88) N-methyl-2- (1-{[5-methyl-3- (trifluoromethyl) -1H-pyrazol-1-yl] acetyl} piperidine -4-yl) -N-[(1R) -1,2,3,4-tetrahydronaphthalen-1-yl] -1,3-thiazole-4-carboxamide, (15.89) N-methyl-2- (1-{[5-Methyl-3- (trifluoromethyl) -1H-pyrazol-1-yl] acetyl} piperidin-4-yl) -N-[(1S) -1,2,3,4-tetrahydro Naphthalen-1-yl]- 1,3-thiazole-4-carboxamide, (15.90) pentyl {6-[({[(1-methyl-1H-tetrazol-5-yl) (phenyl) methylene] amino} oxy] methyl] pyridine-2 -Yl} carbamate, (15.91) phenazine-1-carboxylic acid, (15.92) quinolin-8-ol, (15.93) quinolin-8-ol sulfate (2: 1), (15.94) ) Tert-Butyl {6-[({[(1-methyl-1H-tetrazol-5-yl) (phenyl) methylene] amino} oxy) methyl] pyridin-2-yl} carbamate, (15.95) 1- Methyl-3- (trifluoromethyl) -N- [2 '-(trifluoromethyl) biphenyl-2-yl] -1H-pyrazole-4-carboxamide, (15.96) N- ( 4'-Chlorobiphenyl-2-yl) -3- (difluoromethyl) -1-methyl-1H-pyrazole-4-carboxamide, (15.97) N- (2 ', 4'-dichlorobiphenyl-2-yl ) -3- (Difluoromethyl) -1-methyl-1H-pyrazole-4-carboxamide, (15.98) 3- (difluoromethyl) -1-methyl-N- [4 ′-(trifluoromethyl) biphenyl- 2-yl] -1H-pyrazole-4-carboxamide, (15.99) N- (2 ′, 5′-difluorobiphenyl-2-yl) -1-methyl-3- (trifluoromethyl) -1H-pyrazole -4-carboxamide, (15.100) 3- (difluoromethyl) -1-methyl-N- [4 '-(prop-1-yn-1-yl) biphenyl-2-yl] -1H-pyrazo 4-carboxamide, (15.101) 5-fluoro-1,3-dimethyl-N- [4 '-(prop-1-yn-1-yl) biphenyl-2-yl] -1H-pyrazole- 4-carboxamide, (15.102) 2-chloro-N- [4 '-(prop-1-yn-1-yl) biphenyl-2-yl] nicotinamide, (15.103) 3- (difluoromethyl) -N- [4 '-(3,3-dimethylbut-1-yn-1-yl) biphenyl-2-yl] -1-methyl-1H-pyrazole-4-carboxamide, (15.10
4) N- [4 '-(3,3-Dimethylbut-1-yn-1-yl) biphenyl-2-yl] -5-fluoro-1,3-dimethyl-1H-pyrazole-4-carboxamide, (15 .105) 3- (Difluoromethyl) -N- (4'-ethynylbiphenyl-2-yl) -1-methyl-1H-pyrazole-4-carboxamide, (15.106) N- (4'-ethynylbiphenyl- 2-yl) -5-fluoro-1,3-dimethyl-1H-pyrazole-4-carboxamide, (15.107) 2-chloro-N- (4'-ethynylbiphenyl-2-yl) nicotinamide, (15 .108) 2-Chloro-N- [4 '-(3,3-dimethylbut-1-yn-1-yl) biphenyl-2-yl] nicotinamide, (15.109) 4- (difluoromethyl) -2 Methyl-N- [4 '-(trifluoromethyl) biphenyl-2-yl] -1,3-thiazole-5-carboxamide, (15.110) 5-fluoro-N- [4'-(3-hydroxy-) 3-Methylbut-1-yn-1-yl) biphenyl-2-yl] -1,3-dimethyl-1H-pyrazole-4-carboxamide, (15.111) 2-chloro-N- [4 '-(3) -Hydroxy-3-methylbut-in-1-yl) biphenyl-2-yl] nicotinamide, (15.112) 3- (difluoromethyl) -N- [4 '-(3-methoxy-3-methylbut-1] -In-1-yl) biphenyl-2-yl] -1-methyl-1H-pyrazole-4-carboxamide, (15.113) 5-fluoro-N- [4 ′-(3-methoxy-3-methylbuto- 1-In 1-yl) biphenyl-2-yl] -1,3-dimethyl-1H-pyrazole-4-carboxamide, (15.114) 2-chloro-N- [4 '-(3-methoxy-3-methylbut-1] -In-1-yl) biphenyl-2-yl] nicotinamide, (15.115) (5-bromo-2-methoxy-4-methylpyridin-3-yl) (2,3,4-trimethoxy-6-) Methylphenyl) methanone, (15.116) N- [2- (4-{[3- (4-chlorophenyl) prop-2-yn-1-yl] oxy} -3-methoxyphenyl) ethyl] -N2- (Methylsulfonyl) valine amide, (15.117) 4-oxo-4-[(2-phenylethyl) amino] butanoic acid, (15.118) but-3-yn-1-yl {6-[({ (Z)-(1-) Ethyl-1H-tetrazol-5-yl) (phenyl) methylene] amino} oxy) methyl] pyridin-2-yl} carbamate, (15.119) 4-amino-5-fluoropyrimidin-2-ol (mesomeric form: 4-amino-5-fluoropyrimidin-2 (1H) -one), (15.120) propyl 3,4,5-trihydroxybenzoate, (15.121) 1,3-dimethyl-N- (1,1) , 3-trimethyl-2,3-dihydro-1H-inden-4-yl) -1H-pyrazole-4-carboxamide, (15.122), 1,3-dimethyl-N-[(3R) -1,1 , 3-trimethyl-2,3-dihydro-1H-indene] -1H-pyrazole-4-carboxamide, (15.123) 1,3-dimethyl-N-[(3S) 1,1,3-Trimethyl-2,3-dihydro-1H-inden-4-yl] -1H-pyrazole-4-carboxamide, (15.124) [3- (4-chloro-2-fluorophenyl)- 5- (2,4-Difluorophenyl) -1,2-oxazol-4-yl] (pyridin-3-yl) methanol, (15.125) (S)-[3- (4-chloro-2-fluoro) Phenyl) -5- (2,4-difluorophenyl) -1,2-oxazol-4-yl] (pyridin-3-yl) methanol, (15.126) (R)-[3- (4-chloro-) 2-fluorophenyl) -5- (2,4-difluorophenyl) -1,2-oxazol-4-yl] (pyridin-3-yl) methanol, (15.127) 2-{[3- (2-) Chlorophenyl) -2- (2,4-Difluorophenyl) oxiran-2-yl] methyl} -2,4-dihydro-3H-1,2,4-triazole-3-thione, (15.128) 1-{[3- (2) -Chlorophenyl) -2- (2,4-difluorophenyl) oxirane-2-yl] methyl} -1H-1,2,4-triazol-5-ylthiocyanate, (15.129) 5- (allylsulfanyl)- 1-{[3- (2-chlorophenyl) -2- (2,4-difluorophenyl) oxiran-2-yl] methyl} -1H-1,2,4-triazole, (15.130) 2- [1 -(2,4-Dichlorophenyl) -5-hydroxy-2,6,6-trimethylheptan-4-yl] -2,4-dihydro-3H-1,2,4-triazole-3-thione, (15. 13 ) 2-{[rel (2R, 3S) -3- (2-chlorophenyl) -2- (2,4-difluorophenyl) oxiran-2-yl] methyl} -2,4-dihydro-3H-1,2 , 4-Triazole-3-thione, (15.132) 2-{[rel (2R, 3R) -3- (2-chlorophenyl) -2- (2,4-difluorophenyl) oxiran-2-yl] methyl } -2,4-Dihydro-3H-1,2,4-triazole-3-thione, (15.133) 1-{[rel (2R, 3S) -3- (2-chlorophenyl) -2- (2) , 4-Difluorophenyl) oxiran-2-yl] methyl} -1H-1,2,4-triazol-5-ylthiocyanate, (15.134) 1-{[rel (2R, 3R) -3- (2) -Chlorophenyl) -2- (2,4 Difluorophenyl) oxirane-2-yl] methyl} -1H-1,2,4-triazol-5-ylthiocyanate, (15.135) 5- (allylsulfanyl) -1-{[rel (2R, 3S)- 3- (2-chlorophenyl) -2- (2,4-difluorophenyl) oxirane-2-yl] methyl} -1H-1,2,4-triazole, (15.136) 5- (allylsulfanyl) -1 -{[Rel (2R, 3R) -3- (2-chlorophenyl) -2- (2,4-difluorophenyl) oxiran-2-yl] methyl} -1H-1,2,4-triazole, (15. 137) 2-[(2S, 4S, 5S) -1- (2,4-dichlorophenyl) -5-hydroxy-2,6,6-trimethylheptan-4-yl] -2,4-dihydro-3H- 1,2,4-triazole-3-thione, (15.138) 2-[(2R, 4S, 5S) -1- (2,4-dichlorophenyl) -5-hydroxy-2,6,6-trimethylheptane -4-yl] -2,4-dihydro-3H-1,2,4-triazole-3-thione, (15.139) 2-[(2R, 4R, 5R) -1- (2,4-dichlorophenyl) ) -5-Hydroxy-2,6,6-trimethylheptane-4-yl] -2,4-dihydro-3H-1,2,4-triazole-3-thione, (15.140) 2-[(2S) , 4R, 5R) -1- (2,4-dichlorophenyl) -5-hydroxy-2,6,6-trimethylheptan-4-yl] -2,4-dihydro-3H-1,2,4-triazole- 3-thione, (15. 141) 2-[(2S 4S, 5R) -1- (2,4-Dichlorophenyl) -5-hydroxy-2,6,6-trimethylheptan-4-yl] -2,4-dihydro-3H-1,2,4-triazole-3 -Thione, (15.142) 2-[(2R, 4S, 5R) -1- (2,4-dichlorophenyl) -5-hydroxy-2,6,6-trimethylheptan-4-yl] -2,4 -Dihydro-3H-1,2,4-triazole-3-thione, (15.143) 2-[(2R, 4R, 5S) -1- (2,4-dichlorophenyl) -5-hydroxy-2,6 , 6-trimethylheptane-4-yl] -2,4-dihydro-3H-1,2,4-triazole-3-thione, (15.144) 2-[(2S, 4R, 5S) -1- ( 2,4-Dichlorophenyl) -5-hydroxy- , 6,6-trimethylheptan-4-yl] -2,4-dihydro-3H-1,2,4-triazole-3-thione, (15.145) 2-fluoro-6- (trifluoromethyl)- N- (1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl) benzamide, (15.146) 2- (6-benzylpyridin-2-yl) quinazoline, (15.147) ) 2- [6- (3-Fluoro-4-methoxyphenyl) -5-methylpyridin-2-yl] quinazoline, (15.148) 3- (4,4-difluoro-3,3-dimethyl-3, 4-Dihydroisoquinolin-1-yl) quinoline, (15.149) abscisic acid.

All listed mixing partners of classes (1) to (15) can form salts with suitable bases or acids, if their functional groups make this possible.

Examples of insecticides / acaricides / nematocides in mixed formulations or tank mixes as defined by their "general name", which can be used in the control step, are known, for example, the Pesticide Manual ( "The Pesticide Manual", 14th Ed., British Crop Protection Council 2006) or can be searched on the Internet (e.g. http://www.alanwood.net/pesticides).

(1) Acetylcholinesterase (AChE) inhibitors, such as carbamates such as alnalycarb, aldicarb, benzidocarb, benfracarb, butocarboxim, butoxycarbim, carbaryl, carbofuran, carbosulfan, ethiophene carb, fenobucarb, formetanate, frathiocarb, isoprocarb , Methiocarb, methomyl, methol, metholcarb, oxamyl, pyroxycarb, thiodicarb, thiophanox, triazamate, trimetacarb, XMC and xylylcarb; or organophosphates such as acephate, azamethyphos, azinphos-ethyl, azinphos-methyl, kazusaphos, chloretoxyphos, Chlorfenvinphos, chlormephos, chlorpyri , Chlorpyrifos-methyl, coumaphos, cyanophos, demeton-S-methyl, diazinon, dichlorvos / DDVP, dicrotophos, dimethoate, dimethylbinphos, disulfoton, EPN, ethion, etofolophos, fanphor, fenamiphos, fenitrothion, fenthione, heptiatephos, , Imiciaphos, isofenphos, isopropyl O- (methoxyaminothio-phosphoryl) salicylate, isoxathion, melathion, mecarbam, methamidophos, methidaphos, mevinphos, monocrotophos, nared, omethoate, oxydemethone-methyl, parathion, parathion-methyl, phenate, pholate, Hosalone, hosmet, phosphanide, foskim, pirimiphos-methyl, propheno Vinegar, Puropetamuhosu, prothiofos, pyraclofos, pyridaphenthion, quinalphos, sulfotep, tebupirimfos, temephos, terbufos, tetrachlorvinphos, thiometon, triazophos, trichlorfon and vamidothion.

(2) GABAergic chloride channel antagonists such as cyclodienes organochlorins such as chlordane and endosulfan; or phenyl pyrazoles (Fiprol) such as ethiprole and fipronil.

(3) Sodium channel modulators / membrane voltage-gated sodium channel blockers such as pyrethroids such as acrinatrin, aretrin, d-cis-trans-arethrin, d-trans-arethrin, bifenthrin, bio-allethrin, bio-allethrin S-cyclopentenyl isomer Body, biolessmethrin, cycloprotoline, cyfluthrin, beta-cyfluthrin, cyhalothrin, λ-cyhalothrin, gamma-cyhalothrin, cypermethrin, alpha-cypermethrin, beta-cypermethrin, theta-cypermethrin, zeta-cypermethrin, cypenothrin [ (1R) -trans isomer], deltamethrin, empentrin [(E
Z)-(1R) isomer), esfenvalerate, etofenprox, fenpropatrine, fenvalerate, flucithinate, flumethrinate, τ-fluvalinate, halfenprox, imiprothrin, cadethrin, permethrin, phenothrin [(1R A)-trans isomers), prarethrin, pyrethrins (joutoki chrysanthemum), resmethrin, silafluofen, tefluthrin, tetramethrin, tetramethrin [(1R) isomer)], tralomethrin and transfluthrin; or DDT; or methoxychlor.

(4) Nicotinic acetylcholine receptor (nAChR) agonists such as neonicotinoids, such as acetamiprid, clothianidin, dinotefuran, imidacloprid, nitenpyram, thiacloprid and thiamethoxam; or nicotine; or sulfoxafol.

(5) Nicotinic acetylcholine receptor (nAChR) allosteric activators, such as spinosyns, such as spinetoram and spinosad.

(6) Chloride channel activators, such as avermectins / milbemycins, such as abamectin, emamectin benzoate, lepimectin and milbemectin.

(7) Juvenile hormone mimics, such as juvenile hormone analogues, such as hydroprene, quinoprene and methoprene; or phenoxycarb; or pyriproxyfen.

(8) Various non-specific (multi-site) inhibitors such as alkyl halides, such as methyl bromide and other alkyl halides; or chloropicrin; or sulfuryl fluoride; or borax; or sake stone.

(9) Selective homozygous feeding blockers, eg, pimetrodin; or flonicamide.

(10) mite growth inhibitors such as, for example, clofenthezin, hexythiazox and diflovidazine; or etoxazole (11) microbial disruptors of insect midgut membranes, such as Bacillus thuringiensis subspecies israelensis), Bacillus thuringiensis subspecies aizawai, Bacillus thuringiensis subspecies aizawai, Bacillus thuringiensis subspecies spp. Bacillus thuringiensis subspecies kurstaki, Bacillus thuringiensis subspecies Bacillus thuringiensis subspeci es tenebrionis) and B. t. Crop proteins: Cry1Ab, Cry1Ac, Cry1Fa, Cry1A. 105, Cry2Ab, Vip3A, mCry3A, Cry3Ab, Cry3Bb, Cry34 Ab1 / 35Ab1; or Bacillus sphaericus.

(12) Inhibitors of mitochondrial ATP synthase, such as diafenthiuron; or organotin acaricides, such as azocyclotin, cyhexatin, and fenbutatin oxide; or propargite; or tetradiphone (13) oxidative by disruption of a proton gradient Phosphorylation uncouplers, such as chlorfenapyr, DNOC and sulphuramide.

(14) Nicotinic acetylcholine receptor (nAChR) channel blockers such as bensultap, cartap hydrochloride, thiocyclam and thiosultap-sodium.

(15) Inhibitors of chitin biosynthesis (type 0), for example, bistrifluron, chlorfluazuron, diflubenzuron, flucycloxron, flufenoxuron, hexaflumuron, lufenuron, novaron, noviflumuron, teflubenzuron and Triflumuron.

(16) Inhibitors of chitin biosynthesis (type 1), for example buprofezin.

(17) Moult disrupters such as cypromazine

(18) Ecdysone receptor agonists such as chromafenozide, halofenozide, methoxyfenozide and tebufenozide.

(19) Octopamine receptor agonists such as amitraz.

(20) Mitochondrial complex III electron transfer inhibitors, such as hydramethylnon; or acequinosyl; or fluacripyrim.

(21) Mitochondrial complex I electron transfer inhibitors such as METI acaricides such as phenazaquin, fenpyroximate, pyrimidifene, pyridaben, tebufenpyrado and tolfenpyrade; or rotenone (Deris).

(22) Voltage-gated sodium channel blockers, such as indoxacarb; or metaflumizone.

(23) Inhibitors of acetyl-CoA carboxylase, such as tetronic and tetramic acid derivatives, such as spirodiclofen, spiromesifen and spirotetramat.

(24) Mitochondrial complex IV electron transfer inhibitors such as phosphines such as aluminum phosphide, calcium phosphide, phosphine and zinc phosphide; or cyanide.

(25) Mitochondrial complex II electron transfer inhibitors, for example, β-ketonitrile derivatives such as sienopyraphen and ciflumethofene.

(28) Ryanodine receptor modulators such as diamides, such as chlorantraniliprole and flubendiamide.

Further active ingredients of unknown or unclear action mechanism, such as amidoflumetho, azadirachtin, benclothiaz, benzoxiate, biphenazate, bromopropilate, quinomethionate, cryolite, dicophor, diflovidazine, fluenesulfone, flufenelim, full Fiprole, fluopiram, fufenozide, imidaclotiz, iprodione, meperfluthrin, pyridalyl, pyrifluquinazone, tetramethylfluthrin and iodomethane; but also Bacillus firmus (strain CNCMI-1582, eg VOTiVOTM, including BioNem etc. Not limited thereto) or one of the following known active compounds: 3-bromo-N- {2-bromo-4-chloro-6-[( 1-Cyclopropylethyl) carbamoyl] phenyl} -1- (3-chloropyridin-2-yl) -1H-pyrazole-5-carboxamide (known from WO 2005/077934), 4-{[(6 -Bromopyridin-3-yl) methyl] (2-fluoroethyl) amino} furan-2 (5H) -one (known from WO 2007/115644), 4-{[(6-fluoropyridine-3) -Yl) methyl] (2,2-difluoroethyl) amino} furan-2 (5H) -one (known from WO 2007/115644), 4-{[(2-chloro-1,3-thiazole) -5-yl) methyl] (2-fluoroethyl) amino} furan-2 (5H) -one (WO 2007/115644) 4-{[(6-chloropyridin-3-yl) methyl] (2-fluoroethyl) amino} furan-2 (5H) -one (known from WO 2007/115644), known from the brochure), Flupyradifluro, 4-{[(6-chloro-5-fluoropyridin-3-yl) methyl] (methyl) amino} furan-2 (5H) -one (known from WO 2007/115643), 4- {[(5,6-Dichloropyridin-3-yl) methyl] (2-fluoroethyl) amino} furan-2 (5H) -one (known from WO 2007/115646), 4- {[( 6-Chloro-5-fluoropyridin-3-yl) methyl] (cyclopropyl) amino} furan-2 (5H) -one (WO 20 7/115643) 4-{[(6-chloropyridin-3-yl) methyl] (cyclopropyl) amino} furan-2 (5H) -one (European Patent Application Publication No. 0539588 (A) Known from the brochure), 4-{[(6-chloropyridin-3-yl) methyl] (methyl) amino} furan-2 (5H) -one (known from EP-A-0539588), {[1 -(6-Chloropyridin-3-yl) ethyl] (methyl) oxide-λ ⁴ -sulfanylidene} cyanamide (known from WO 2007/149134) and its diastereomer {[(1R) -1-(-) 6-chloropyridin-3-yl) ethyl] (methyl) oxide 1-? ⁴ - Surufaniriden} cyanamide (A) Oyo {[(1S) -1- (6- chloropyridin-3-yl) ethyl] (methyl) oxide 1-? ⁴ - Surufaniriden} cyanamide (B) (known from WO 2007/149134 pamphlet) and diastereomer [(R) -Methyl (oxide) {(1R) -1- [6- (trifluoromethyl) pyridin-3-yl] ethyl} -λ ⁴ -sulfanylidene] cyanamide (A1) and a group of diastereomer A ( [(S) -Methyl (oxide) {(1S) -1- [6- (trifluoromethyl) pyridine-3-3] called WO 2010/074747, known from WO 2010/074751). [I] ethyl} -λ 4-sulfanylidene] cyanamide (A2), [(R) -methyl (oxide) { 1S)-1-[6- (trifluoromethyl) pyridin-3-yl] ethyl} 1-? ⁴ - Surufaniriden] cyanamide (B1) and diastereomer B of the group (WO 2010/074747 pamphlet, International Publication [(S) -Methyl (oxide) {(1R) -1- [6- (trifluoromethyl) pyridin-3-yl] ethyl} -λ ⁴ -sulfanylidene] cyanamide, which is known from 2010/074751) (B2), and 11- (4-chloro-2,6-dimethylphenyl) -12-hydroxy-1,4-dioxa-9-azaspiro [4.2.4.2] tetradec-11-en-10- On (known from WO 2006/089633), 3- (4'-fluoro-2,4-dimethylbiphenyl) -3-yl) -4-hydroxy-8-oxa-1-azaspiro [4.5] dec-3-en-2-one (known from WO 2008/067911), 1- {2-fluoro -4-Methyl-5-[(2,2,2-trifluoroethyl) sulfinyl] phenyl} -3- (trifluoromethyl) -1H-1,2,4-triazol-5-amine (WO 2006) Afido pyrrolene (known from WO 2008/066153), 2-cyano-3- (difluoromethoxy) -N, N-dimethylbenzenesulfonamide (WO 2006/056433) Known), 2-cyano-3- (difluoromethoxy) -N-methylbenzenesulfonamide ( 2-cyano-3- (difluoromethoxy) -N-ethylbenzenesulfonamide (known from WO2005 / 035486), 4- (difluoromethoxy) -N- Ethyl-N-methyl-1,2-benzothiazol-3-amine 1,1-dioxide (known from WO 2007/057407), N- [1- (2,3-dimethylphenyl) -2- (3,5-Dimethylphenyl) ethyl] -4,5-dihydro-1,3-thiazole-2-amine (known from WO 2008/104503), {1 ′-[(2E) -3- (4-Chlorophenyl) prop-2-en-1-yl] -5-fluorospiro [indole-3,4′-pipe Jin] -1 (2H) - yl} (2-chloropyridin-4-yl) methanone (known from WO 2003/106457 pamphlet), 3- (2
5-dimethylphenyl) -4-hydroxy-8-methoxy-1,8-diazaspiro [4.5] dec-3-en-2-one (known from WO 2009/049851), 3- ( 2,5-Dimethylphenyl) -8-methoxy-2-oxo-1,8-diazaspiro [4.5] dec-3-en-4-ylethyl carbonate (known from WO 2009/049851), 4- (But-2-yn-1-yloxy) -6- (3,5-dimethylpiperidin-1-yl) -5-fluoropyrimidine (known from WO 2004/099160), (2,2 3,3,4,4,5,5-octafluoropentyl) (3,3,3-trifluoropropyl) malononitrile (WO 2005/063) 94, which is known from pamphlet 94), (2,2,3,3,4,4,5,5-octafluoropentyl) (3,3,4,4,4-pentafluorobutyl) malononitrile (WO2005 / 06-3094) 8- [2- (Cyclopropylmethoxy) -4- (trifluoromethyl) phenoxy] -3- [6- (trifluoromethyl) pyridazin-3-yl] -3-azabicyclo [3 .2.1] Octane (known from WO2007 / 040280), furometoquine, PF1364 (CAS registration number: 1204776-60-2) (known from JP-A-2010 / 018586), 5- [5-] (3,5-Dichlorophenyl) -5- (trifluoromethyl) -4,5-dihydro-1,2-oxazole-3 [Yl] -2- (1H-1,2,4-triazol-1-yl) benzonitrile (known from WO 2007/075459), 5- [5- (2-chloropyridin-4-yl), 5- (trifluoromethyl) -4,5-dihydro-1,2-oxazol-3-yl] -2- (1H-1,2,4-triazol-1-yl) benzonitrile (WO 2007) 4- (5- (3,5-Dichlorophenyl) -5- (trifluoromethyl) -4,5-dihydro-1,2-oxazol-3-yl] -2-methyl-). N- {2-oxo-2-[(2,2,2-trifluoroethyl) amino] ethyl} benzamide (known from WO 2005/085216), 4- {[(6 -Chloropyridin-3-yl) methyl] (cyclopropyl) amino} -1,3-oxazol-2 (5H) -one, 4-{[(6-chloropyridin-3-yl) methyl] (2,2 -Difluoroethyl) amino} -1,3-oxazol-2 (5H) -one, 4-{[(6-chloropyridin-3-yl) methyl] (ethyl) amino} -1,3-oxazole-2 ( 5H) -one, 4-{[(6-chloropyridin-3-yl) methyl] (methyl) amino} -1,3-oxazol-2 (5H) -one (known from WO 2010/005692) ), Piflubumide (known from WO 2002/096882), methyl 2- [2-({[3-bromo-1- (3-chloropyridin-2-yl) -1H-pyrazole- -Yl] carbonyl} amino) -5-chloro-3-methylbenzoyl] -2-methylhydrazine carboxylate (known from WO 2005/085216), methyl 2- [2-({[3-bromo-] 1- (3-chloropyridin-2-yl) -1H-pyrazol-5-yl] carbonyl} amino) -5-cyano-3-methylbenzoyl] -2-ethylhydrazinecarboxylate (WO 2005/085216 It is known from the pamphlet) methyl 2- [2-({[3-bromo-1- (3-chloropyridin-2-yl) -1H-pyrazol-5-yl] carbonyl} amino) -5-cyano-3- Methyl benzoyl] -2- methyl hydrazine carboxylate (WO 2005/085216 pamphlet ), Methyl 2- [3,5-dibromo-2-({[3-bromo-1- (3-chloropyridin-2-yl) -1H-pyrazol-5-yl] carbonyl} amino) benzoyl] -1 , 2-diethylhydrazinecarboxylate (known from WO 2005/085216), methyl 2- [3,5-dibromo-2-({[3-bromo-1- (3-chloropyridin-2-yl) ) -1H-Pyrazol-5-yl] carbonyl} amino) benzoyl] -2-ethylhydrazinecarboxylate (known from WO 2005/085216), (5RS, 7RS; 5RS, 7SR) -1- (6) -Chloro-3-pyridylmethyl) -1,2,3,5,6,7-hexahydro-7-methyl-8-nitro-5-propoxyimidazo [1,2-a] pyridine (known from WO 2007/101369), 2- {6- [2- (5-fluoropyridin-3-yl) -1,3-thiazol-5-yl] Pyridin-2-yl} pyrimidine (known from WO 2010/006713), 2- {6- [2- (pyridin-3-yl) -1,3-thiazol-5-yl] pyridine-2- 1'-Pyrimidine (known from WO 2010/006713), 1- (3-chloropyridin-2-yl) -N- [4-cyano-2-methyl-6- (methylcarbamoyl) phenyl] -3 -{[5- (trifluoromethyl) -1H-tetrazol-1-yl] methyl} -1H-pyrazole-5-carboxamide (WO 2010/069502 Known from the pamphlet) 1- (3-chloropyridin-2-yl) -N- [4-cyano-2-methyl-6- (methylcarbamoyl) phenyl] -3-{[5- (trifluoromethyl)- 2H-Tetrazol-2-yl] methyl} -1H-pyrazole-5-carboxamide (known from WO 2010/069502), N- [2- (tert-butylcarbamoyl) -4-cyano-6-methyl Phenyl] -1- (3-chloropyridin-2-yl) -3-{[5- (trifluoromethyl) -1H-tetrazol-1-yl] methyl} -1H-pyrazole-5-carboxamide 2010/069502), N- [2- (tert-butylcarbamoyl) -4-cyano-6-methylphenyl -1- (3-chloropyridin-2-yl) -3-{[5- (trifluoromethyl) -2H-tetrazol-2-yl] methyl} -1H-pyrazole-5-carboxamide (WO 2010 / No. 069502), (1E) -N-[(6-chloropyridin-3-yl) methyl] -N'-cyano-N- (2,2-difluoroethyl) ethanimidamine (WO 2008/009360). No. pamphlet) N- [2- (5-amino-1,3,4-thiadiazol-2-yl) -4-chloro-6-methylphenyl] -3-bromo-1- (3-chloropyridine -2-yl) -1H-pyrazole-5-carboxamide (known from Chinese Patent No. 102057925), methyl 2- [3,5-dibromo-2-({[[ -Bromo-1- (3-chloropyridin-2-yl) -1H-pyrazol-5-yl] carbonyl} amino) benzoyl] -2-ethyl-1-methylhydrazinecarboxylate (WO 2011/049233) known) from hepta full Trinh, pyriminobac Azoxystrobin, full phenoxide cysts robin and 3-chloro ^-N 2 - ^{(2-cyano-2-yl)} -N 1 - [4- (1,1,1,2 , 3, 3, 3- heptafluoropropan-2-yl) -2- methylphenyl] phthalamide (known from WO 2012/034472).

Examples of microorganisms in a mixed preparation or tank mix that can be used in the control step.

The microbes of the invention, which are well tolerated from the environment in combination with good plant resistance and favorable toxicity for warm-blooded animals, protect the plants and plant organs and thus increase the yield and thus the quality of the harvested material Animal pests, especially insects, arachnids, reptiles, nematodes and molluscs encountered in the field of agriculture, horticulture, livestock, forests, gardens and leisure facilities, storage products and materials protection and hygiene. Appropriate for control. These can preferably be used as plant protection agents. They are active against normally sensitive and resistant species and against all or some stages of development. The above-mentioned microorganisms include microorganisms derived from bacterial regions, microorganisms derived from fungal regions, insecticidal microorganisms derived from protozoan regions, insecticidal microorganisms derived from viral regions, and microorganisms derived from regions of insect pathogenic nematodes.

The following groups of compounds are regarded, for example, as safeners: S1) Compounds of the group of heterocyclic carboxylic acid derivatives: S1 ^a ) Compounds of the type of dichlorophenyl pyrazoline 3-carboxylic acid (S1 ^a ), preferably 1- (2,4-dichlorophenyl) -5- (ethoxycarbonyl) -5-methyl-2-pyrazoline-3-carboxylic acid, ethyl 1- (2) described in WO 91/07874 (A) Compounds such as 4, 4-dichlorophenyl) -5- (ethoxycarbonyl) -5-methyl-2-pyrazoline-3-carboxylate (S1-1) ("mephenpyr (-diethyl)") and related compounds; S1 ^b ) derivatives dichlorophenyl pyrazole carboxylic acid (S1 ^b), Oyo preferably, European Patent application 333131 (a) Pat For example, ethyl 1- (2,4-dichlorophenyl) -5-methylpyrazole-3-carboxylate (S1-2), ethyl 1- (2,4-dichlorophenyl) described in U.S. Pat. No. 2,696,806 (A). -5-isopropylpyrazole-3-carboxylate (S1-3), ethyl 1- (2,4-dichlorophenyl) -5- (1,1-dimethylethyl) pyrazole-3-carboxylate (S1-4), etc. Compounds and related compounds; S1 ^c ) derivatives of 1,5-diphenylpyrazole-3 carboxylic acid (S1 ^c ), preferably, for example, ethyl 1- (2) as described, for example, in European Patent Application No. 268554 (A) , 4-Dichlorophenyl) -5-phenylpyrazole-3-carboxylate (S1-5), methyl 1- (2-chlorophenyl) Le) -5-phenylpyrazole-3-carboxylate (S1-6) and related compounds, such as; S1 ^d) compounds of the type triazole carboxylic acid ^(S1 d), preferably, European Patent Application 174562 (A) Fenchlorazole (-ethyl) described in the specification and the specification 346620 (A), that is, ethyl 1- (2,4-dichlorophenyl) -5-trichloromethyl- (1H) -1,2, 4-triazole-3-carboxylate (S1-7) compounds and related compounds; S1 ^e 5-benzyl- or 5-phenyl-2-isoxazoline-3-carboxylic acid or 5,5-diphenyl-2-isoxazoline-3 compounds of the type carboxylic acid ^(S1 e), preferably, WO 91/08202 (a) No. pamphlet Ethyl 5- (2,4-dichlorobenzyl) -2-isoxazoline-3-carboxylate (S1-8) or ethyl 5-phenyl-2-isoxazoline-3-carboxylate (S1-9) Compound and related compounds, 5,5-diphenyl-2-isoxazoline carboxylic acid (S1-10) or ethyl 5,5-diphenyl-2-isoxazoline carboxylate (S1-11) ("isoxadiphen-ethyl") Or n-propyl 5,5-diphenyl-2-isoxazoline carboxylate (S1-12) or ethyl 5- (4-fluorophenyl) -5- as described in WO 95/07897 (A) pamphlet Phenyl-2-isoxazoline-3-carboxylate (S1-13).

S2) compounds of the group of 8-quinoline-oxy derivative (S2): ^S2 a) 8-quinoline oxy compounds of the type acetic acid (S2
^a ), preferably as described in European Patent Application Nos. 86 750 (A), 94 349 (A) and 191 736 (A) or 0 492 366 (A). 1-Methylhexyl (5-chloro-8-quinolineoxy) acetate (common name "cloquintoset-mexyl" (S2-1), 1,3-dimethyl-but-1-yl (5-chloro-8-quinoline) Oxy) acetate (S2-2), 4-allyloxybutyl (5-chloro-8-quinolineoxy) acetate (S2-3), 1-allyloxyprop-2-yl (5-chloro-8-quinolineoxy) Acetate (S2-4), Ethyl (5-chloro-8-quinolineoxy) acetate (S2-5), Methyl (5-chloro-8-quinolineoxy) acetate (S2-) 6), allyl (5-chloro-8-quinolineoxy) acetate (S2-7), 2- (2-propylideneiminooxy) -1-ethyl (5-chloro-8-quinolineoxy) acetate (S2-8) ), 2-oxo-prop-1-yl (5-chloro-8-quinolineoxy) acetate (S2-9) and related compounds, and further described in European Patent Application No. 2002/34048 (A). (5-chloro-8-quinolineoxy) acetic acid (S2-10), its hydrates and salts, such as its lithium, sodium, potassium, calcium, magnesium, aluminum, iron, ammonium, quaternary ammonium, sulfonium or Phosphonium salt; S2 ^b ) (5-chloro-8-quinolineoxy) malonic acid type compound (S2 ^b ), preferably Diethyl (5-chloro-8-quinolineoxy) malonate, diallyl (5-chloro-8-quinolineoxy) malonate, methyl ethyl (5-hydroxy-8 malonate), as described in European Patent Application No. 0582 198 (A). Compounds such as chloro-8-quinolineoxy) malonate compounds and related compounds.

S3) Active compounds of the dichloroacetamide type frequently used as plant pre-emergence toxicity reducers (soil-action toxicity reducers) (S3), for example “Dichlormid” (N, N-diallyl-2,2- Dichloroacetamide) (S3-1), "R-29148" (3-dichloroacetyl-2,2,5-trimethyl-1,3-oxazolidine manufactured by Stauffer) (S3-2), "R manufactured by Stauffer" -28725 "(3-dichloroacetyl-2,2-dimethyl-1,3-oxazolidine) (S3-3)," Benoxacol "(4-dichloroacetyl-3,4-dihydro-3-methyl-2H-1, 4-benzoxazine) (S3-4), “PPG-1292” manufactured by PPG Industries (N-allyl-N-[(1,3-dioxo) -2-yl) methyl] dichloroacetamide) (S3-5), "DKA-24" (N-allyl-N-[(allylaminocarbonyl) methyl] dichloroacetamide) (S3-6) manufactured by Sagro-Chem. ), “AD-67” or “MON 4660” (3-dichloroacetyl-1-oxa-3-aza-spiro [4,5] decane) (S3-7) manufactured by Nitrokemia or Monsanto, TRI-Chemical RT Manufactured "TI-35" (1-dichloroacetyl azepan) (S3-8), BASF "diclonone" (dicyclonone) or "BAS 145138" or "LAB 145138" (S3-9) ((RS)- 1-Dichloroacetyl-3,3,8a-trimethylperhydropyrrolo [1,2-a] pyrimidi -6-one), "frillazole" or "MON 13900" ((RS) -3-dichloroacetyl-5- (2-furyl) -2,2-dimethyloxazolidine) (S3-10) and also its (R)- Isomer (S3-11).

S4) Compound of the class of acylsulfonamides (S4): S4 ^a ) Formula (S4 ^a ) described in WO 97/45016 (A):

(Wherein, R _A ¹ is (C ₁ -C ₆ ) -alkyl, (C ₃ -C ₆ ) -cycloalkyl, and the last two radicals are halogen, (C ₁ -C ₄ ) -alkoxy, halo - _(C 1 -C ₆₎ - alkoxy and _(C 1 -C ₄₎ - substituted alkylthio, by _{v a} substituent, in the case of cyclic radicals, further _(C 1 -C ₄₎ - alkyl and (C ₁ -C ₄ ) -haloalkyl; R _A ² is halogen, (C ₁ -C ₄ ) -alkyl, (C ₁ -C ₄ ) -alkoxy, CF ₃ ; m _A is 1 or 2; v _D is 0, 1, 2 or 3) N-acylsulfonamide and salts thereof, S4 ^b ) Formula (S4 ^b ) described in WO 99/16744 (A) ):

(Wherein, R _B ¹ and R _B ² are independently of each other hydrogen, (C ₁ -C ₆ ) -alkyl, (C ₃ -C ₆ ) -cycloalkyl, (C ₃ -C ₆ ) -alkenyl , (C ₃ -C ₆ ) -alkynyl, R _B ³ is halogen, (C ₁ -C ₄ ) -alkyl, (C ₁ -C ₄ ) -haloalkyl or (C ₁ -C ₄ ) -alkoxy M _B is 1 or 2) compounds of the benzamide type and salts thereof, such as, for example, in the formula R _B ¹ = cyclopropyl, R _B ² = hydrogen and (R _B ³ ) = 2-OMe (""Cyprosulfamide", S4-1), R _B ¹ = cyclopropyl, R _B ² = hydrogen and (R _B ³ ) = 5-Cl-2-OMe (S4-2), R _B ¹ = ethyl, R _B ² = hydrogen and ^{_{(R B 3) = 2-}} OMe (S4 _{3), R} ^{B 1} = _{isopropyl, R} ^{B 2} = hydrogen and ^{_{(R B 3) = 5-}} Cl-2-OMe (S4-4) and R _B ¹ = _{isopropyl, R} ^{B 2} = hydrogen and _(R ^{B 3} Compounds) and salts thereof, which are 4- (benzoylsulfamoyl) of 2-OMe (S4-5).

S4 ^c ) Formula (S4 ^c ) described in European Patent Application No. 365484 (A):

(Wherein, R _C ¹ and R _C ² independently of each other are hydrogen, (C ₁ -C ₈ ) -alkyl, (C ₃ -C ₈ ) -cycloalkyl, (C ₃ -C ₆ ) — Alkenyl, (C ₃ -C ₆ ) -alkynyl, R _C ³ is halogen, (C ₁ -C ₄ ) -alkyl, (C ₁ -C ₄ ) -alkoxy, CF ₃ , m _C is Compounds of the class of benzoylsulfamoylphenylureas of 1 or 2), for example 1- [4- (N-2-methoxybenzoylsulfamoyl) phenyl] -3-methylurea, 1- [4- (N) -2-Methylbenzoylsulfamoyl) phenyl] -3,3-dimethylurea, 1- [4- (N-4,5-dimethylbenzoylsulfamoyl) phenyl] -3-methylurea, S4 ^d ), for example, Chinese Patent Tenth It is known from 838227 Pat formula ^(S4 d):

(Wherein R _D ⁴ is halogen, (C ₁ -C ₄ ) -alkyl, (C ₁ -C ₄ ) -alkoxy, CF ₃ ; m _D is 1 or 2; R _D ⁵ is Hydrogen, (C ₁ -C ₆ ) -alkyl, (C ₃ -C ₆ ) -cycloalkyl, (C ₂ -C ₆ ) -alkenyl, (C ₂ -C ₆ ) -alkynyl, (C ₅ -C ₆₎ Compounds of the type N) -phenylsulfonylterephthalamide which is-)-cycloalkenyl) and salts thereof.

S5) Active compounds of the class of hydroxyaromatic and araliphatic carboxylic acid derivatives (S5), for example as described in WO 2004/084631 pamphlet, WO 2005/015994 pamphlet, WO 2005/016001 pamphlet Ethyl 3,4,5-triacetoxybenzoate, 3,5-dimethoxy-4-hydroxybenzoic acid, 3,5-dihydroxybenzoic acid, 4-hydroxysalicylic acid, 4-fluorosalicylic acid, 2-hydroxycinnamic acid, 2, 4-dichlorocinnamic acid.

S6) Active compounds of the class of 1,2-dihydroquinoxalin-2-ones (S6), for example 1-methyl-3- (2-thienyl) as described in WO 2005/112630 (A) 1,2-dihydroquinoxalin-2-one, 1-methyl-3- (2-thienyl) -1,2-dihydroquinoxaline-2-thione, 1- (2-aminoethyl) -3- (2-thienyl) -1,2-dihydroquinoxalin-2-one hydrochloride, 1- (2-methylsulfonylaminoethyl) -3- (2-thienyl) -1,2-dihydroquinoxaline-2-one.

S7) Compounds of the class of diphenyl methoxyacetic acid derivatives (S7) described in WO 98/38856, for example methyl diphenyl methoxy acetic acid (CAS registration number: 41858-19-9) (S7-1), Ethyl diphenyl methoxyacetic acid or diphenyl methoxy acetic acid.

S8) Formula (S8) described in WO 98/27049 (A) pamphlet:

Wherein the symbols and indices have the following meanings: R _D ¹ is halogen, (C ₁ -C ₄ ) -alkyl, (C ₁ -C ₄ ) -haloalkyl, (C ₁ -C ₄ ) -alkoxy , (C ₁ -C ₄ ) -haloalkoxy, R _D ² is hydrogen or (C ₁ -C ₄ ) -alkyl, R _D ³ is hydrogen, (C ₁ -C ₈ ) -alkyl, (C ₂ -C ₄ ) -Alkenyl, (C ₂ -C ₄ ) -alkynyl or aryl, wherein each of the above-mentioned carbon-containing radicals is unsubstituted or one or more, preferably up to 3 halogens And alkoxy), and n _D is an integer of 0 to 2) or a salt thereof.

S9) Active compounds (S9) from the class of 3- (5-tetrazolylcarbonyl) -2-quinolones, as described in WO 1999/000020 (A), for example 1,2-dihydro- 4-hydroxy-1-ethyl-3- (5-tetrazolylcarbonyl) -2-quinolone (CAS registration number: 219479-18-2), 1,2-dihydro-4-hydroxy-1-methyl-3- (5-Tetrazolylcarbonyl) -2-quinolone (CAS Registry Number: 95855-00-8).

S10) Formulas (S10 ^a ) or (S10 ^b ) described in WO 2007/023719 (A) and 2007/023764 (A) pamphlets:

(Wherein, R _E ¹ is halogen, (C ₁ -C ₄ ) -alkyl, methoxy, nitro, cyano, CF ₃ , OCF ₃ , Y _E , Z _E are independently of each other, O or is S, _{n E} is an integer of 0 to 4, _R ^{E 2} _is, (C 1 _{-C 16)} - _{alkyl, (C} 2 -C ₆₎ - _{alkenyl, (C} 3 -C ₆₎ - cycloalkyl Compounds of alkyl, aryl; benzyl, halobenzyl and R _E ³ is hydrogen or (C ₁ -C ₆ ) -alkyl).

S11) Active compounds of the type of oximino compounds known as seed dressings (S11), for example “Oxavetrinyl” ((Z) -1,3-dioxolan-2-ylmethoxyimino (phenyl) for miscellaneous cereals against metolachlor damage )) Acetonitrile) (S11-1), “Fluxophenim” (1- (4-chlorophenyl) -2,2,2-trifluoro-1-ethanone O-(-) known as seed dressing for miscellaneous cereals for metolachlor 1,3-Dioxolan-2-ylmethyl) oxime) (S11-2), and “Ciometrinil” or “CGA-43089” ((Z) -cyanomethoxyimino, which is known as seed dressing for cereals to metolachlor (Phenyl) acetonitrile) (S11-3).

S12) Active compounds of the class of isothiochromanones (S12), for example methyl [(3-oxo-1H-2-benzothiopyran-4 (3H) -ylidene) from WO 1998/13361 (A) pamphlet Methoxy] acetate (CAS Registry Number: 205121-04-6) (S12-1) and related compounds.

S13) One or more compounds from the following group (S13): "Naphthalic anhydride" (1,8-naphthalenedicarboxylic acid anhydride, known as seed dressing for corn against thiocarbamate herbicide damage ) (S13-1), "phenclorim" (4,6-dichloro-2-phenyl pyrimidine) (S13-2), known as a safener for pretilachlor in planted rice, against alachlor and metolachlor damage "Flurazol" (benzyl 2-chloro-4-trifluoromethyl-1,3-thiazole-5-carboxylate) (S13-3), known as a seed dusting agent for mites, against imidazoline damage American Cyanamid, known as a safener for corn CL 304 415 "(CAS Registry Number: 31541-57-8) (4-Carboxy-3,4-dihydro-2H-1-benzopyran-4-acetic acid) (S13-4), known as a safener for corn “MG 191” (CAS registration number: 96420-72-3) (2-dichloromethyl-2-methyl-1,3-dioxolane) (S13-5) manufactured by Nitrokemia, “MG MG” manufactured by Nitrokemia 838 "(CAS Registry Number: 133993-74-5) (2-propenyl 1-oxa-4-azaspiro [4.5] decane-4-carbiothioate) (S13-6)," disulfoton "(0,0) -Diethyl S-2-ethylthioethyl phosphorodithioate) (S13-7), "dietolate" (O, O-diethyl O-phenyl) Phosphorothioate) (S13-8), "mephenate" (4-chlorophenylmethylcarbamate) (S13-9).

S14) Active compounds which, in addition to their herbicidal action against harmful plants, also have a safener action on crop plants such as rice, eg "dimepiperate" or "known as a safener for rice against molinate herbicide damage, MY93 ”(S-1-Methyl-1-phenylethylpiperidine-1-carbothioate),“ Idemron ”or“ SK23 ”(1- (I-), which is known as a safener for rice against imazosulfuron herbicide damage 1-Methyl-1-phenylethyl) -3-p-tolylurea), known as a safener for rice to some herbicide damage, "cumylon" = "JC 940" (3- (2-chlorophenyl) Methyl) -1- (1-methyl-1-phenylethyl) urea (see JP-A-60-087254), part “Methoxyphenone” or “NK049” (3,3′-Dimethyl-4-methoxybenzophenone), a known safener for rice plants against herbicide damage, a safener for some herbicide damage in rice “CSB” (1-bromo-4- (chloromethylsulfonyl) benzene) from Kumiai (CAS Registry No. 54091-06-4), known as

S15) Formulas (S15) described in WO 2008/131861 (A) pamphlet and WO 2008/131860 (A) pamphlet:

(Wherein, R _H ¹ is (C ₁ -C ₆ ) -haloalkyl, R _H ² is hydrogen or halogen, R _H ³ and R _H ⁴ are each independently hydrogen, hydrogen ( C ₁ -C ₁₆ ) -alkyl, (C ₂ -C ₁₆ ) -alkenyl or (C ₂ -C ₁₆ ) -alkynyl, wherein the last three radicals mentioned are each unsubstituted or halogen, hydroxy , Cyano, (C ₁ -C ₄ ) -alkoxy, (C ₁ -C ₄ ) -haloalkoxy, (C ₁ -C ₄ ) -alkylthio, (C ₁ -C ₄ ) -alkylamino, di-[(C _1- C ₄ ) -alkyl] -amino, [(C ₁ -C ₄ ) -alkoxy] -carbonyl, [(C ₁ -C ₄ ) -haloalkoxy] -carbonyl, unsubstituted or substituted (C ₃ -C ₆₎ )-Cycloalkyl Or unsubstituted or substituted phenyl and one or more radicals from the group consisting of unsubstituted or substituted heterocyclyl; or one of the rings fused together with a 4 to 6 membered saturated or unsaturated carbocycle At the site are fused with (C ₃ -C ₆ ) -cycloalkyl, (C ₄ -C ₆ ) -cycloalkenyl, (C ₃ -C ₆ ) -cycloalkenyl, or a 4- to 6-membered saturated or unsaturated carbocycle At one site of the substituted ring is (C ₄ -C ₆ ) -cycloalkenyl, wherein each of the last four radicals mentioned is either unsubstituted or halogen, hydroxy, cyano, (C ₁ -C ₄ ) - _{alkyl, (C} 1 -C ₄₎ - _{haloalkyl, (C} 1 -C ₄₎ - _{alkoxy, (C} 1 -C ₄₎ - _haloalkoxy, (C 1 _-C 4) - _{Alkylthio, (C} 1 -C ₄₎ - alkylamino, di - _(C 1 -C ₄₎ - alkyl] - amino, _[(C 1 -C ₄₎ - alkoxy] - _{carbonyl, [(C} 1 _-C 4) - haloalkoxy] - carbonyl, unsubstituted or substituted (C 3 _-C 6) _- or cycloalkyl is substituted with one or more radicals from the group consisting of unsubstituted or substituted phenyl, and unsubstituted or substituted heterocyclyl; Or R _H ³ is (C ₁ -C ₄ ) -alkoxy, (C ₂ -C ₄ ) -alkenyloxy, (C ₂ -C ₆ ) -alkynyloxy or (C ₂ -C ₄ ) -haloalkoxy; , and R _H4 is hydrogen or _(C 1 -C ₄₎ - alkyl, or R _H ³ and _R ^{H 4,} together with the direct coupling N atom, still in addition to the N atom May, and unsubstituted or halogen, cyano, nitro, optionally containing hetero ring atoms, preferably another hetero ring atom up to two from the group consisting of O and S (C 1 _{-C 4)} - One or more from the group consisting of alkyl, (C ₁ -C ₄ ) -haloalkyl, (C ₁ -C ₄ ) -alkoxy, (C ₁ -C ₄ ) -haloalkoxy and (C ₁ -C ₄ ) -alkylthio Or a tautomer thereof which is a 4-8 membered heterocycle substituted with a radical of

S16) Active compounds not only mainly used as herbicides but also having a safener action on crop plants, such as (2,4-dichlorophenoxy) acetic acid (2,4-D), (4-chlorophenoxy) acetic acid , (R, S) -2- (4-chloro-o-tolyloxy) propionic acid (mecoprop), 4- (2,4-dichlorophenoxy) butyric acid (2,4-DB), (4-chloro-o-) Tolyloxy) acetic acid (MCPA), 4- (4-chloro-o-tolyloxy) butyric acid, 4- (4-chlorophenoxy) butyric acid, 3,6-dichloro-2-methoxybenzoic acid (dicamba), 1- (ethoxycarbonyl) ) Ethyl 3,6-dichloro-2-methoxybenzoate (Lactidichloro-ethyl).

Preferred safeners are: cloquintocet-mexyl, cyprosulfamide, fenchlorazole-ethyl, isoxadiphen-ethyl, mefenpyr-diethyl, fenclorim, cumylone, S4-1 and S4-5, with particular preference: Cloquintocet-mexyl, cyprosulfamide, isoxadiphen-ethyl and mefenpyr-diethyl.

The following is a limited list of drugs that may be used according to the present invention.

Herbicides: eg Triaphamone, tefuryl trione, oxadiargyl, ethoxysulfuron, dymuron Insecticides: eg imidacloprid Fungicides: eg, isothianyl Fertilizers: eg, ZnSO ₄ Toxic modifiers: eg, isoxadiphen-ethyl molluscicide : Eg, niclosamide (Bayluscide®) biological substances: eg, microorganisms or signaling molecules; Bacillus subtilis (QST 713) (Serenade®), Bacillus pumilis (Bacillus pumilis) QST 2818) (Sonata®), a blend of three terpenes (Requiem®) plant tonic compounds and combinations thereof.

In the liquid preparation of the present invention, one kind of compound (agent) may be used as the agrochemical active ingredient, or a plurality of kinds may be used in combination.

According to a preferred embodiment, the solution sprayed in the method of the present invention comprises a combination of at least two different compounds selected from the group consisting of herbicides, fungicides, insecticides, molluscicides and fertilizers .

Preferably, the herbicide is selected from the group consisting of oxadiargyl, triaphamone, tefuryl trione, fentrazamide, mefenaceto, bensulfuron-methyl and pretilachlor; the fungicide is isotianil; the insecticide is imidacloprid; A molluscicidal agent is niclosamide; and a fertilizer is zinc.

Preferred examples of such combinations of at least two different compounds are oxadiargyl and triaphamone; oxadiargyl and tefuryl trione; oxadiargyl and tefuryl trione and fentrazamide; triafamone and tefuryl trione; fentrazamide and tefuryl trione; triafamone and fentrazamide and It is selected from the group consisting of: tefuryl trione; mefenaceto and bensulfuron-methyl; pretilachlor and bensulfuron-methyl; triafamone and mephenaceto and bensulfuron-methyl; and triafamone and pretilachlor and bensulfuron-methyl. Further preferred are triaffamone, tefuryl trione and oxadiargyl; and combinations of three of triaphamone, oxadiargyl and bensulfuron-methyl.

Further preferred examples of solutions comprising a combination of at least two different compounds are triaphamone and tefuryl trione and isothianyl; triafamone and tefuryl trione and imidacloprid; triaphamone and tefuryl trione and isothianyl and imidacloprid; triaphamone and tefuryl trione and isothianyl And niclosamide; selected from the group consisting of triaphamone and tefuryl trione and isothianyl and imidacloprid and niclosamide and triaphamone and tefuryl trione isothianyl and imidacloprid and niclosamide and zinc.

Particularly preferably, the solution is selected from the group consisting of oxadiargyl and trifafamon; and the group consisting of triafamone and tefuryl trione; triafamone, tefuryl trione and oxadiargyl; and three combinations consisting of triafamone, oxadiargyl and bensulfuron-methyl It contains a combination of at least two different herbicides. Even more particularly preferred, the solution comprises triafamone and a combination of tefuryl trione and isotianil. Even more particularly preferred, the solution comprises a combination of triaphamone, tefuryl trione, isotianil, imidacloprid and niclosamide.

In the method of the present invention, the solution may be in the form of various preparations, and specific examples thereof include, for example, a solution (water suspension (flowable, emulsion or suspension of water dispersible in water), water solvent ), AL agent, microcapsules, etc. can be exemplified. These preparations are mixed in a manner known per se, for example, with the agrochemical active substance, together with a spreading agent, ie a liquid diluent or carrier, optionally with a surfactant, ie an emulsifier and / or a dispersing agent. Done by When water is used as a developing agent at that time, for example, an organic solvent can be used as an auxiliary solvent. In the present invention, the flowable is preferable from the viewpoint of workability. As a flowable, water, surfactant, liquid diluent (organic solvent) and polymer resin, especially acrylic resin (acrylic acid alkyl ester and / or methacrylic acid alkyl ester) are used as structural units in addition to the agrochemical active substance Aqueous suspension compositions comprising (co) polymer resins) are preferred. An antifoamer, an antiseptic, a thickener, a dispersing agent, an antifreezing agent and the like can be appropriately added to the aqueous suspension composition according to need. The content of the agrochemical active substance in the flowable is preferably 1 to 50 parts by weight, particularly 5 to 40 parts by weight. The content of the surfactant is preferably in the range of 0.01 to 10 parts by weight, particularly 0.1 to 5 parts by weight. The content of the diluent is preferably 1 to 50 parts by weight, and more preferably 5 to 30 parts by weight. The content of the acrylic resin is preferably in the range of 0.1 to 20 parts by weight, particularly 1 to 10 parts by weight. The total amount of 0 to 10 parts by weight, particularly 0 to 5 parts by weight is preferable for other additive components such as antifoaming agents, preservatives and thickeners. The polymer resin in the aqueous suspension composition is preferably a granular polymer resin, and in particular, it is preferable to be finely divided by grinding or the like.

Liquid diluents or carriers include, for example, aromatic hydrocarbons (eg, xylene, toluene, alkyl naphthalene, etc.), chlorinated aromatic or chlorinated aliphatic hydrocarbons (eg, chlorobenzenes, chlorinated ethylenes, methylene chloride) Etc.), aliphatic hydrocarbons [eg cyclohexane, etc., paraffins (eg mineral oil fraction etc.)], alcohols (eg C.sub.2 -C.sub.10 alcohols such as butanol, etc., glycols such as ethylene glycol, propylene glycol etc. and the like) Ether, ester and the like), ketones (for example, acetone, methyl ethyl ketone, methyl isobutyl ketone, cyclohexanone and the like), strongly polar solvents (for example, dimethylformamide, dimethyl sulfoxide and the like), water and the like can be mentioned.

As the surfactant, for example, nonionic and anionic surfactants [eg, polyoxyethylene fatty acid ester, polyoxyethylene fatty acid alcohol ether (eg, alkyl aryl polyglycol ether, alkyl sulfonate, alkyl sulfate, aryl) Sulfonates, tristilphenol and its ethoxylates], albumin hydrolysis products and the like can be mentioned.

Dispersants include, for example, lignin sulfite waste liquor, methylcellulose and the like.

Fixing agents can also be used in the preparation (powders, granules, emulsions), examples of which include carboxymethylcellulose, natural and synthetic polymers (eg gum arabic, polyvinyl alcohol, polyvinyl acetate etc) Can.

A coloring agent can also be used, and the coloring agent includes, for example, inorganic pigments (for example, iron oxide, titanium oxide, Prussian blue etc.), organic dyes such as alizarin dyes, azo dyes or metal phthalocyanine dyes, Trace elements such as salts of metals such as iron, manganese, boron, copper, cobalt, molybdenum, zinc etc. can be mentioned.

The solution used in the method of the present invention and the rice transplanter-mounted solution spreader can be prepared by diluting the above-described flowable, emulsion, or wettable powder with a diluent such as water to a predetermined concentration.

Although the amount of medicine to be sprayed in the rice transplanter-mounted liquid agent spraying apparatus of the present invention can be appropriately adjusted, it is preferably 3 to 100 L / ha, more preferably 5 to 30 L / ha.

The agrochemical preparation according to the embodiment of the present invention can obtain selective herbicidal effects between rice and paddy weeds. And the following are mentioned as an example of the paddy field weed which can be controlled.

Dicotyledonous plants of the following genera: Polygonum, Roiripa, Rolippa, Rotala, Azena (Lindernia), Salixia (Bidens), Apenome (Dopatrium), Takasaburo (Eclipta), And the like (Elatine, Gratiola, Lindernia, Ludwigia, Oenanthe, Ranunculus, Deinostema).

Monocotyledonous plants of the following genera: Echinochloa, millet (Panicum), Scutellaria (Poa), Scutellaria (Cyperus), Scutellaria (Monochoria), Tensock (Fimbristylis), Scutellaria (Sagitaria), Hari (Eleocharis), Firefly (Scirpus), Sakimodaka (Alisma), Iboksa (Aneilema), Sbuta (Blyxa), Hoshikusa (Eriocaulon), Hirumushi (Potamogeton), Nikkibi (Brachiaria), Azegaya (Leptochloa), Sphenoclea (Sphenoclea), rice (Oryza) and the like.

More specifically, it can be used, for example, for the following representative paddy field weeds.

Plant name Latin name Dicotyledon dinoflagellate Marisilea quadrifolia iderico Fimbristylis miliacea ボ S Sphenoclea zeylanica Am Ammannia sp. Chrysalis Rotala indica Koehne Azena Lindernia procumbens Philcox America Azena Lindernia dubia L. Penn. Taketo Azena Lindernia dubia subsp. Dubia Takasaburo Eclipta prostrata Azetophila Lindernia angustifolia ヨ ウ dw dw Ludwigia prostrata Roxburgh h Polygonum sp. American hornets Sesbania exaltata Hirumshiro Potamogeton distinctus A. Benn Mizohakobe Elatine triandra Schk Seri Oenanthe javanica ク ネ ー A Aeschynomene indica キ ア ゼ Bacopa rotundifolia a サ den Bidens frondosa ノ Do Dopatium junceum ア ブ ti ti ti chin 子 chin chin chin chin chin crus-galli Iboxa Aneilema keisak Paspalum disticum Pisticum distichum Kogomegagatsutori Cyperus iria Hamasuge C. rotundus pine tree Eleocharis acicularis L. Krogwai Eleochris kuroguwai Ohwi Tamagaya Cyperus differm L. Squirrel Cyperus serotinus Rottboel Squirrel Scirpus mucronatus Scutellariae S. planiculmis Canopus spp Scirpus juncoides Roxb Tree scoop Scirupus Wallichii Nees Red spurge Scirpus Lineolatus Schizus Scirpus etuberculatus Monochoria Monocholia vaginalis Presl Scutellata Sigittaria pygmaea Miq Heramorous Alismicaluca Br. et Bouche Sagiomodaka Alisma plantago-aquatica var. Orientale Samuels. Omodaka Sagittaria trifolia mizu ao Monochoria korsakowii Azegaya Leptochloa chinensis Tenchi Fimbristylis bentgrass Agrostis spec. The agrochemical formulation of the present invention Heteranthera limosa (SW.) WILL The pesticide formulations of the present invention are not limited to the use of these grass species for weeds, and may be similarly applied to weeds of other grass species. it can.

There is no particular limitation on the diseases contemplated by the method of the present invention, but the solution is, for example, Plasmodiophoromycetes, Oomycetes, Zygomycetes, Ascomycetes, Basidiomycetes And can be used against imperfect fungi (Deuteromycetes). In particular, for example, fool seedling disease (Gibberella fujikuroi), Fusarium moniliforme (Fusarium moniliforme), blast, leaf blast, panicle blast and rot (Pyriculaia oryzae), Pyricularia gricea (Pyricularia grisea)), pseudosclerosis (Ustilaginoidea virens), brown spot (Cochliobolus miyabeanus), seedling blight (Burkholderia plantarii) Bacterial blight (Burkholde gourmet (Burkholde) ia glumae), internal browning disease (Erwinia herbicola), white leaf blight disease (Pseudomonas oryzae), Xanthomonas oryzae (Xanthomonas oryzae), brown stripe disease (Pseudomonas avenae (Pseivemonas) ), Pseudomonas albop recipetos (P. alboprecipitans), sheath blight (Sanathephorus cucumeris), Rhizoctonia solani (Rizoctonia solani), gangrene mosaic disease (rice gangrene mosaic virus), grassy stunt disease (rice nematode) Rice grassy stunt virus)), dwarfism Virus), dwarf disease (rice dwarf virus), ragged stunt (rice ragged stunt virus), transient yellow dwarf disease (rice transient yellowing virus), streak blight blight (rice streak blight virus), black streak dwarf disease (Rice black dwarf virus), yellow dwarf (Phytoplasma), seedling blight (Fusarium sp.), Rhizopus sp. (Rhizopus sp.), Trichoderma sp. (Mucor sp.), Forma species (Phoma sp.), Pythium sp. (Pythium sp.), Stock rot (Erwinia chrysanthemi pv. zeae)), scleroderma (Magnaporthe salvinii), micrococcal karyopathy (Helminthosporium sigmoideum)), brown leaf blight (Metasphaeria albescens)), Scaly leaf blight (Sphaerulina oryzina), leaf browning disease (Pseudomonas fuscovaginae), false blast disease (Alternaria oryzae), Epicoccum nigram (Epicoccutum nigrum) Sporium helvalum (Cladosporium) (herbarum), Pseudocochiliobolus lunatus, Phytophthora blight (Ceratobasidium setariae), black disease (Cladosporium herbarum), black-particle blight Helicocelias oryzae (Helicoceras oryzae), blight (Phoma glumarum), leaf rot (Sarcocladium oryzae (Sarocladium oryzae, Pyrenochaeta sp.)), Leaf blotch disease (Cylindrocladium scopariu m)) Diseases derived from plant pathogens such as X. oryzae (Thanatephorus cucumeris), in particular diseases derived from filamentous fungi and / or microorganisms, such as rice blast disease, brown spot disease and white leaf blight It can prevent the disease effectively.

There is no particular limitation on the harmful insects contemplated by the method of the present invention, but the solution is, for example, Lissophoptrus oryzophilus, Oilema oryzae, Parnara guttata, Chilo suppressalis, (Scirpophaga incertulas), rice ladybug (Sesamia inferens), phalaenopsis moth (Naranga aenescens), pokeweed moth (Cnaphalocrocis medinalis), moth loaf planthopper (Laodelphax striatella), sejilounka (Sogatella furcifera N) laparvata lugens), green leafhopper (Nephotettix cincticeps), rice bug (Lagynotomos elongatus), rice sturgeon (Stenchaetothrips biformis), red clover (Pomacea canaliculata), rice leafhopper (Agromyza oryzae), , Imiditemigiwawi (Notiphila sekiyai), rice fly (Chlorops oryzae), yellow-backed eagle (Tipula aino), seed fly (Delia platura), rice weevil (Echi) nocnemus squameus, green leaf beetle (Donacia provosti), arrowhead moth (Mythimna separata), white-spotted moth (Protodeltote distinguenda), rice scallop (Crapaphrocrocis exigua), blue-spotted beetle (Rhopalosiphum padi) (Recilia dorsalis), rice bug (Scotinophora lurida), rice bug (Cletus punctiger), spider bug (Leptocorisa chinensis), southern beetle (N ezara viridula), spurge beetles (Eysarcoris aeneus), stalagmites (Eysarcoris ventralis), rice clover (Trigonotylus caelestialium), clams (Steodema sibiricum), akas sichika mich (Senotus rivucititus) White-faced moth (Oxya yezoensis), Yellow-tailed eagle (Oxya japonica), Red-winged scale insect (Geococco oryzae), cricket (Gryllotalpa orientalis), Red-winged nematode (Aphelenchoi) It can be used against des besseyi), black-tailed nematode (Heterodera elachista), green-legged nematode (Hirschmanniella Oryzae), red crayfish (Precambarus clarkii) and the like. In particular, it is possible to effectively prevent rice thrips, sejironuka and snail.

[Example] A rice transplanter-mounted liquid agent spraying apparatus according to the present invention was mounted on a six-row planted rice transplanter, and under the conditions described in Table 1 below, a spraying test was carried out according to the following procedure. We observed what kind of effect appeared in the field.

(Test 1) 72 grams of oxadiargyl single agent per hectare was sprayed in the following three ways.

(A) Drop between 1 share per 5 rows: 6 rows between 6 rows of plants planted by the rice transplanter will be 5 rows. Among the five rows of strains, the liquid agent was dropped only in the middle row between the strains (drop between one strain).

(B) Dropping between 3 strains per 5 rows of strains: Among the 5 rows of strains, the liquid agent was dropped between the middle strain and between the two strains at each of the two strains between the middle strains and a total of 3 strains in total Drop between 3 stocks).

(C) Drop between 5 strains per 5 strains between strains: The liquid agent was dropped into all the strains among 5 rows (drop between 5 strains).

Then, the result of having observed the effect by solution spraying for every kind of weed is shown in the following table 2.

Test 2 Thirty-six grams of oxadiargyl single agent per hectare was sprayed in three ways (A) to (C) above. The results obtained by observing the effects of solution spraying for each type of weed are shown in Table 3 below.

(Test 3) Thirty-six grams of oxadiargyl per hectare and thirty-six grams of triafamone per hectare were mixed and dispersed as described in (A) to (C) above. Table 4 below shows the results of observing the effects of solution spraying for each type of weed.

Test 4 Thirty-six grams of oxadiargyl per hectare and 72 grams of tefryltrione per hectare were mixed and dispersed as described in (A) to (C) above. The results obtained by observing the effects of solution spraying for each type of weed are shown in Table 5 below.

(Test 5) A mixture of 36 grams of oxadiargyl per hectare, 72 grams of tefuryltrione per hectare, and 100 grams of fentrazamide per hectare is sprayed in the same manner as in (A) to (C) above. did. The results obtained by observing the effects of solution spraying for each type of weed are shown in Table 6 below.

(Test 6) Thirty-six grams of trifafamon per hectare and seventy-two grams of tefryltrione per hectare were mixed and dispersed as described in (A) to (C) above. The results obtained by observing the effects of solution spraying for each type of weed are shown in Table 7 below.

(Test 7) One hundred and fifty grams of phentrazamide per hectare and one hundred and fifty grams of tefryltrione per hectare were mixed and dispersed as described in (A) to (C) above. The results obtained by observing the effects of solution spraying for each type of weed are shown in Table 8 below.

(Test 8) Mix 36 grams of triafammon per hectare, 72 grams of fentrazamide per hectare, and 72 grams of tefuryltrione per hectare, and spray them in the same manner as in (A) to (C) above. did. The results obtained by observing the effects of solution spraying for each type of weed are shown in Table 9 below.

(Test 9) A mixture of 450 grams of mefenaset per hectare and 27 grams of bensulfuron methyl per hectare was dispersed as described in (A) to (C) above. The results obtained by observing the effects of solution spraying for each type of weed are shown in Table 10 below.

(Test 10) A mixture of 450 grams of pretilacurol per hectare and 31.5 grams of bensulfuron methyl per hectare was sprayed in the same manner as the above (A) to (C). The results obtained by observing the effects of the solution spraying for each type of weed are shown in Table 11 below.

(Test 11) Mix 36 grams of trifafamon per hectare, 450 grams of mefenacet per hectare, and 27 grams of bensulfuron methyl per hectare, and spray them in the same manner as in (A) to (C) above. did. The results obtained by observing the effects of the solution spraying for each type of weed are shown in Table 12 below.

(Test 12) A mixture of 36 grams of triafammon per hectare, 450 grams of pretilachlor per hectare, and 31.5 grams of bensulfuron methyl per hectare Scattered The results obtained by observing the effects of the solution application for each type of weed are shown in Table 13 below.

From the observation results of (Test 1) to (Test 12) above, depending on the type of applied solution, depending on the type of applied solution, the solution is dropped between all the five rows of strains, thereby all weeds targeted for observation. Turned out to be effective.

As mentioned above, although the preferable embodiment of this invention was described, this invention is not limited to said embodiment. Additions, omissions, substitutions, and other modifications of the configuration are possible without departing from the spirit of the present invention. The invention is not limited by the foregoing description, but is only limited by the scope of the appended claims.

The rice planter type liquid agent spraying apparatus according to the present invention was mounted on a six-row planted rice planter, and the spraying test was performed in the following manner under the conditions described in Tables 14 and 15 below. At a later date, it was observed what kind of effect appeared in the paddy field where the spray test was conducted.

The results of Tests 13-22 according to the procedures set forth in Tables 14 and 15 are listed below. The test results set forth in Tables 17-26 are the results from both procedures set forth in Tables 14 and 15, with the exception of the test results set forth in procedures set forth in Table 14 alone and those set forth in PORECA conducted according to the procedure set forth in Table 15 alone. Is the average value of One, three and all drops have the same definition as in procedures (A), (B) and (C) above.

The abbreviations and terms used in Tables 17-24 are described in Table 16.

(Test 13) The mixture of TRF & TEF was sprayed by one drop, three drops or a full drop spray method. The results of observing the effects of Test 13 on various targets are shown in Table 17 below.

Test 14 One, three or all drops of IST (isotianil) were applied by spraying. The results of observing the effects of Test 14 on various targets are shown in Table 18 below.

(Test 15) IMD (imidacloprid) was applied by 1 drop, 3 drops or full drop spray method. The results of observing the effects of Test 15 on various targets are shown in Table 19 below.

(Test 16) The NCS (niclosamide: bayluscide) was applied by one drop, three drops or a full drop spray method. The results of observing the effects of Test 16 on various targets are shown in Table 20 below.

(Test 17) The mixture of TRF & TEF + IST (isothianyl) was dispersed by 1 drop, 3 drops or a total drop spray method. The results of observing the effects of Test 17 on various targets are shown in Table 21 below.

(Test 18) The mixture of TRF & TEF + IMD (imidacloprid) was dispersed by 1 drop, 3 drops or a full drop spray method. The results of observing the effects of Test 18 on various targets are shown in Table 22 below.

(Test 19) The mixture of TRF & TEF + IST (isothianyl) + IMD (imidacloprid) was dispersed by one drop, three drops or a total drop spray method. The results of observing the effects of Test 19 on various targets are shown in Table 23 below.

(Test 20) The mixture of TRF & TEF + IST (isothianyl) + NCS (niclosamide: bayluscide) was dispersed by one drop, three drops or a total drop spray method. The results of observing the effects of Test 20 on various targets are shown in Table 24 below.

(Test 21) TRF & TEF + IST (isothianyl) + IMD (imidacloprid) + NCS (niclosamide: bayluscide) mixture was applied by one drop, three drops or a total drop spray method. The results of observing the effects of Test 21 on various targets are shown in Table 25 below.

(Test 22) TRF & TEF + IST (isothianyl) + IMD (imidacloprid) + NCS (niclosamide: bayluscide) mixture was applied by one drop, three drops or a total drop spray method. The results of observing the effects of Test 22 on various targets are shown in Table 26 below.

Testing of uniform dripping of solution by the mechanism shown in FIG.

Condition: The dripping amount from each nozzle (the total number of the nozzles is 5 in this case) of the solution consisting of water and detergent was measured using a solution spreading device mounted on a rice transplanter. One trial consisted of 40 signals from the spray motion controller that were generated automatically in response to a spray rate of 15 L / ha. The amount of dripping solution from each nozzle and their average value, total dripping amount, error and RSD (error and definition of RSD are shown below) are listed in each row of Table 27 below. One set of trials consisted of three trials, and the average value of each set of trial data is listed in the bottom row of Table 27.

Nine sets of trials (meaning a total of 27 trials) were repeated in the same manner.

Average error of drop volume for each nozzle in each set ("drop" in Table 28), average error of RSD for each nozzle in each set ("RSD" in Table 28) and for each trial in each set The average error of the total drop volume ("total amount" in Table 28) is listed in lines 1-9, and their average value is listed in the bottom line.

The test results listed in Tables 27 and 28 reveal that the rice transplanter-mounted liquid agent spraying device of the present invention can uniformly spray the liquid agent, and the dropping error is 10% or less.

The present invention relates to a rice transplanter-mounted liquid agent spraying device that can be mounted on a rice transplanter and that sprays a liquid agent in synchronization with the rice planting operation by the rice transplanter. According to the present invention, it is possible to save control work and enable pesticide spraying on medium-scale fields and large-scale fields.

Claims (27)

An apparatus for dispensing and discharging a liquid agent,
A tank for storing the liquid agent;
A pump for drawing the liquid from the tank;
A conduit connected to the pump to deliver the fluid drawn by the pump;
A dispensing unit connected to the conduit for dispensing and discharging the liquid agent conveyed by the conduit;
A mechanism for receiving the solution conveyed by the pipeline and capturing air contained in the received solution;
The mechanism includes an additional conduit connected between the distribution unit and the tank for receiving the solution supplied to the distribution unit and transporting the received solution to the tank,
The distribution unit
A generally horizontally extending hollow member;
Two or more conduits connected to the hollow member and extending downwardly and discharging the liquid agent conveyed by the hollow member, each being spaced from the adjacent conduits And,
It is a cock provided openably and closably in each pipeline, and by closing when the pump is operating, the liquid agent is not discharged from the pipeline, and the air contained in the hollow member is added to the hollow member. A faucet configured to facilitate returning to the tank via a pipeline of
Including
An additional conduit of the mechanism is connected to the hollow member of the distribution section;
From the hollow member, the additional conduit is arranged with all its parts above the distribution part and does not include a pump and is always in communication with the tank and the hollow member An apparatus characterized in that the transport of the liquid agent to the tank is not impeded.   The apparatus of claim 1, wherein the additional conduit of the mechanism is connected to opposite ends of the hollow member.   The apparatus of claim 2, wherein the additional conduit of the mechanism is connected to the top surface of the hollow member. An apparatus for dispensing and discharging a liquid agent,
A tank for storing the liquid agent;
A pump for drawing the liquid from the tank;
A conduit connected to the pump to deliver the fluid drawn by the pump;
A dispensing unit connected to the conduit for dispensing and discharging the liquid agent conveyed by the conduit;
A mechanism for receiving the solution conveyed by the pipeline and capturing air contained in the received solution;
The mechanism includes a chamber extending generally vertically and incorporated into the conduit,
The pipe line is
A first conduit for conveying the liquid agent sucked by the pump, wherein one end is connected to the pump and the other end is connected to the chamber;
A second conduit for conveying the liquid agent stored by the chamber, wherein one end is connected to the chamber and the other end is connected to the distribution unit;
The other end of the first conduit is disposed higher than the one end of the second conduit,
Further comprising a drain line connected to the chamber at a location lower than the one end of the second channel to drain the fluid agent from the chamber;
An apparatus characterized in that it does not have a pipeline for connecting the distribution unit and the tank to return the liquid agent to the tank.   5. The apparatus of claim 4, further comprising an exhaust line connected to the chamber at a location higher than the other end of the first line to exhaust air from the chamber. The distribution unit
A generally horizontally extending hollow member;
Two or more conduits for communicating with the hollow member and discharging downward the liquid agent conveyed by the hollow member, the two or more conduits each being spaced from the adjacent conduits Including pipelines,
5. The apparatus of claim 4, wherein the other end of the second conduit is connected to the hollow member. Each pipe of the two or more conduit includes a valve for adding a resistance to the liquid passing through the interior of the conduit, apparatus according to any one of claims 3 and claims 1 to 6. It is a rice transplanter mounting type liquid agent dispersing device which comprises the device according to any one of claims 1 to 7, and the distributing unit of the device discharges the liquid agent in synchronization with the rice planting operation of the rice transplanter. apparatus. The valve is
It is configured to have a tubular, having a top surface including a slot at one end, a first valve member having an opening at the other end,
The receiving the first valve member includes a case having an outlet facing the upper surface of the inlet and the first valve member facing the opening of the first valve member, the apparatus of claim 7. The valve is
Is configured to have a tubular, having a top surface including a slot at one end, a second valve member having an opening at the other end, the second engaging said first valve member at the inner portion of the case Further including a valve member,
10. The apparatus of claim 9, wherein the top surface of the second valve member is spaced from the top surface of the first valve member. Each of the first valve member and the second valve member is
A first hollow member comprising the upper surface having a first inner diameter and a first outer diameter larger than the first inner diameter;
A second hollow member connected to the first hollow member, having a second inner diameter larger than both the first inner diameter and the first outer diameter, and having a second outer diameter larger than the first outer diameter; Including
Wherein the first valve member and the second valve member, as the first hollow member of said second valve member is supported acceptance in the inner portion of the second hollow member of the first valve member, mutually 11. The device of claim 10, wherein the device is configured to engage. Each of the first valve member and the second valve member is a third hollow member connected to the second hollow member, the third inner diameter being larger than both the second inner diameter and the second outer diameter. Further comprising a third hollow member having a third outer diameter greater than the second outer diameter,
Wherein the first valve member and the second valve member, so that said second hollow member of said second valve member is supported acceptance in the inner portion of the third hollow member of said first valve member, mutually The device of claim 11 configured to engage. A device for dispensing and discharging the liquid preparation according to any one of claims 1 to 7 or a rice planter mounted liquid preparation sprayer according to claim 8 for controlling pests, fungi and / or weeds Rice planting simultaneous solution spraying method,
The liquid agent spraying method which sprays the said liquid agent on some between some ridges where a seedling is planted through the said distribution part.   The liquid agent spraying method according to claim 13, wherein the spraying is performed among half or more of the plurality of chewing spaces.   15. The method according to claim 14, wherein the solution is applied to all the spaces between the plurality of bottles. The liquid drug application method according to any one of claims 13 to 15, wherein the water solubility of the liquid drug is lower than 100 mg / L. The solution comprises herbicides, plant growth regulators, fungicides, insecticides, acaricides, nematocides, microorganisms, molluscicides, fertilizers, safeners and plant tonic compounds and combinations thereof The liquid drug application method according to any one of claims 13 to 16, comprising at least one selected. The liquid preparation method according to any one of claims 13 to 17, wherein the liquid preparation contains at least one selected from the group consisting of herbicides.   The method according to claim 18, wherein the herbicide is a herbicide for paddy field. The above solutions are pyrimisulfan, tefuryl trione, keto spiridox, mesotrione, benzobicyclone, benzocociclone, sulcotrione, tenbotrione bromotide, triaphamone, propiylsulfuron, benzosulfuron-methyl, pyrazosulfuron, imazosulfuron, penoxram, pyraclonyl pentoxazone, oxadiazon, oxadiargyl, butachlor, pretilachlor, fentrazamide, mefenacet, any of oxadiazole chromate phone, claims 13 comprising at least one compound selected from the group consisting of type phen carbazone and phenoxazine sulfone according to claim 19 Solution dispensing method described in. 21. The liquid preparation according to any of claims 13 to 20, wherein the solution comprises a combination of at least two compounds selected from the group consisting of herbicides, fungicides, insecticides, molluscicides and fertilizers. Liquid spray method.   The herbicide is selected from the group consisting of oxadiargyl, triaphamone, tefuryl trione, fentrazamide, mefenaceto, bensulfuron-methyl and pretilachlor, the fungicide is isotianil, and the insecticide is imidacloprid, 22. A method according to claim 21, wherein the molluscicidal agent is niclosamide and the fertilizer is zinc.   The solution is at least selected from the group consisting of oxadiargyl and trifafamon, and a group consisting of triafamone and tefuryl trione, triaphamone, tefuryl trione and oxadiargyl, and three combinations consisting of triaphamone, oxadiargyl and bensulfuron-methyl. 22. A solution spraying method according to claim 21 comprising a combination of two different herbicides.   22. The method of claim 21 wherein the solution comprises triafamone and a combination of tefuryl trione and isotianil.   22. The method of claim 21, wherein the solution comprises a combination of triafamone, tefuryl trione, isotianil, imidacloprid and niclosamide. 26. A method according to any of claims 13 to 25, wherein the growth of rice is increased by more than 10% as compared to untreated rice.   The method according to claim 26, wherein the growth of rice is increased by more than 30% as compared to untreated rice.

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