JP6694454B2 - Device for distributing and discharging liquid agent and method for simultaneously spraying rice planting liquid agent - Google Patents

Description

(Cross-reference of related applications)
This application claims priority benefit from said patent application based on a prior Chinese patent application No. CN20121210064117.7, entitled "RICE TRANSPLANTER-MOUNTED LIQUID REAGENT APPLICATION DEVICE", filed March 12, 2012. All the contents of the above-mentioned application are incorporated into the contents of the present specification.
The present invention relates generally to devices for dispensing and dispensing liquid agents. More specifically, the present invention relates to a rice planter-mounted liquid agent spraying device and a method for simultaneously spraying rice planting liquids using the device.

  The so-called pest control work, which involves spraying chemicals at the same time as rice planting for the purpose of weeding, aims to save labor by applying pesticides at the same time as rice planting. The rice sprayer-installed chemical spraying device is a machine for spraying granules or liquids, for example, suspensions (flowable agents, emulsions), water solvents, etc., at the same time when seedlings are planted by the rice transplanter.

  There are rice sprayer-equipped drug sprayers for granules, liquids, etc. according to the properties of the drug to be sprayed, and the herbicide spraying, which was a separate operation from rice transplantation, was performed at the same time as rice planting. Quantitative spraying and fine weighing are possible. As disclosed in JP-A-11-308959 and JP-A-2008-048659, a rice transplanter-mounted granule spraying device adjusts the granules by a dosing device that operates in synchronization with the rice planting speed. It is possible to evenly disperse the granules by dropping the metered and metered granules onto a disc that rotates at high speed, and repelling the granules with a striking plate formed on the disc. All contents are incorporated herein by reference. In addition, "Common techniques for pesticide application: soil application," "Agricultural application techniques," (1998), "Pesticide application techniques," edited by the Editorial Committee, published by the Japan Plant Protection Association, page 122 In addition, the rice planting simultaneous liquid agent spraying device is a system of squeezing out the tube connecting from the tank to the nozzle by using a roller, and all the contents thereof are incorporated into the contents of the present specification by reference.

  The rice planting simultaneous liquid agent spraying device mounted on the rear portion of the rice transplanter and used is put into practical use under the trade name “Dripman (trademark registration 2419217)”, the entire contents of which are incorporated herein by reference. A "drip man" sparging device has only one nozzle, i.e., a one-drip device. This device often disperses liquids unevenly, especially for poorly water-soluble active substances such as the herbicide oxadiargyl. Such uneven distribution causes uneven control of weeds, pests and / or fungi, and / or causes crop damage.

JP, 11-308959, A JP, 2008-48659, A

"Common technology of pesticide application soil application", "Pesticide application technology", (1998), "Pesticide application technology" edited by the editorial board, published by Japan Plant Protection Association, page 122

  Rice planting work (human and machine transplantation) has been performed in a shallow water state (submersion depth 0 to 3 cm) in order to maintain planting accuracy. In the conventional spraying apparatus for granules, the granules are buried in the paddy soil depending on the strength or the angle at which the granules are repelled, and there is a place where weeding is not performed because the effect of the medicine is not exerted. On the other hand, granules placed near planted rice seedlings can cause phytotoxic effects on the seedlings. Granule sprayers are also susceptible to weather conditions such as rainfall and wind. Rainfall is extremely important because it causes granules to stick to the sprinkler. Further, it is difficult to spray a mixture of several granules on a large-scale field without supplying granules during rice planting because the granules are heavy and bulky. Mixing granules with different specific gravities is also not desirable, as the granules cannot be evenly distributed. Further, the conventional spraying device for liquid agent is mounted on the rice transplanter for planting 6 to 8 rows, and since the liquid agent is dropped only between the central ridges (that is, one drop between the plants), the liquid agent is spread from 6 to 8 rows. It may not spread to all the ridges of the strip, and a uniform control effect may not be obtained. In particular, if the field is shallow water at the time of rice planting, or if there is no waterlogging depth, further after simultaneous rice planting treatment, if waterlogging was not possible immediately, the active substance of the drug does not sufficiently diffuse, the expected effect, for example, weeding, It may not be possible to obtain effects such as pest control or fungal disease control. In addition, the uneven distribution of the drug may promote phytotoxicity to rice.

  Embodiments of the present invention aim to at least partially improve some of these points, and include medium-sized fields (1000-3000 square meters (0.1-0.3 ha) of paddy field per side). ), And a method for spraying pesticides on a large-scale field (a paddy field with an area of more than 3000 square meters (0.3 ha) per surface), which is equipped with a rice planting machine-equipped liquid spraying device, and a method for simultaneously spraying rice planting using the same. ..

  The embodiment of the present invention can uniformly drop the liquid agent in each of the plurality of ridges that are planted after the rice transplanter has run (the error rate of the drop amount from each nozzle is 50%, 30% compared to the average drop amount). %, 20% or less than 10%). Since the sprayed liquid can spread to all of a plurality of ridges, uniform control effect and excellent safety (selectivity) for paddy rice can be obtained. Further, the method of the present invention can prevent direct contact of the drug with paddy rice at the time of liquid spray application, as compared with the conventional liquid spray application method, and can prevent contact phytotoxicity of the drug on the leaf blade of the rice, and , Can effectively enhance the growth of rice (more than 10% or 30% compared to untreated rice). Another advantage of the present invention over the prior art is that it allows the liquid to be evenly diffused even when the liquid has very low or moderate water solubility. An example of an activator with very low water solubility is oxadiaargyl (0.37 mg / L at pH 5.6 and 20 ° C) and an example of an activator with moderate water solubility is triafamone (each value measured at 20 ° C: 33 mg / L at pH 7, 36 mg / L at pH 4, 34 mg / L at pH 9). Even if the solution is very poorly soluble in water, uniform dispersion of the solution prevents uneven dispersion results, results in uniform control of weeds, pests and / or fungi, and / or prevents crop damage.

  In one aspect of the invention, an apparatus is provided for dispensing and dispensing a liquid agent. This device is provided with a tank for storing a liquid agent, a pump for sucking the liquid agent from the tank, a pipe connected to the pump for conveying the liquid agent sucked by the pump, and a pipe for conveying the liquid agent. And a mechanism for receiving the liquid agent carried by the pipe and capturing the air contained in the received liquid agent.

  The mechanism may include an additional conduit connected between the dispenser and the tank for receiving the liquid dispensed in the dispenser and delivering the received dispensed liquid to the tank. The distributor may include a hollow member extending in a substantially horizontal direction, and two or more pipe lines connected to the hollow member and extending downward, the two or more pipe lines being defined by the hollow member. The transported liquid agent is drained, and each of the two or more pipelines is arranged at a distance from its adjacent pipeline. The additional conduit of the mechanism is connected to the hollow member of the distributor. Additional conduits for the mechanism are connected to both ends of the hollow member. The additional conduit of the mechanism is connected to the upper surface of the hollow member. Each of the two or more conduits includes a valve that adds resistance to the liquid agent passing through the interior of the conduit.

  Alternatively, the mechanism includes a chamber that extends in a substantially vertical direction and is installed in the conduit, and the conduit is a first conduit for discharging the liquid agent sucked by the pump, One end of one conduit is connected to the pump, the other end of the first conduit is a first conduit connected to the chamber, and a second conduit for discharging the liquid agent stored in the chamber. , One end of the second pipeline is connected to the chamber, the other end of the second pipeline includes a second pipeline connected to the distributor, wherein the other end of the first pipeline is , Located higher than the one end of the second conduit. An exhaust unit connected to the chamber at a position higher than the other end of the first conduit to exhaust air from the chamber. A drainage unit connected to the chamber at a position lower than one end of the second conduit for draining the liquid agent from the chamber.

  The distributor includes a hollow member extending in a substantially horizontal direction, and two or more pipe lines communicating with the hollow member and extending downward, and the two or more pipe lines are conveyed by the hollow member. The liquid agent is drained, each of the two or more pipelines is arranged at a distance from an adjacent pipeline, and the other end of the second pipeline is connected to the hollow member.

  Each of the two or more conduits includes a valve that adds resistance to the liquid agent passing through the interior of the conduit.

  In one aspect of the invention, a valve may be provided. The valve is a first valve member configured to have a tubular shape and having an upper surface at one end and an opening at the other end, the upper surface including a notch (slot); And a case having an inlet for receiving the one valve member and facing the opening of the valve member and an outlet for the upper surface of the first valve member.

  The valve is a second valve member configured to have a tubular shape and having an upper surface at one end and an opening at the other end, the upper surface including a notch (slot), and the second valve member is A second valve member may be included in the case that is engaged with the first valve member, the upper surface of the second valve member being spaced from the upper surface of the first valve member.

  Each of the first and second valve members is a first hollow member having a first inner diameter and an upper surface having a first outer diameter longer than the first inner diameter, and a second hollow member connected to the first hollow member. There, the second hollow member may include a second hollow member having a second inner diameter longer than both the first inner diameter and the outer diameter and a second outer diameter longer than the first outer diameter, The first and second valve members are configured to be screwed together such that the first hollow member of the second valve member is received and supported within the second hollow member of the first valve member. To be done.

  Each of the first and second valve members is a third member connected to the second hollow member, wherein the third hollow member has a third inner diameter longer than both the second inner diameter and the outer diameter. The first and second valve members further include a third member having a second outer diameter that is longer than the first outer diameter, wherein the first hollow member of the second valve member is the first valve member of the first valve member. The three hollow members are configured to be interengaged to be received and supported within the hollow members.

  One aspect of the present invention relates to a rice transplanter including the above device that discharges a liquid agent in synchronization with the rice transplanting operation of the rice transplanter.

  One aspect of the present invention is a method for simultaneously spraying rice planting for controlling pests, fungi and / or weeds using the above-mentioned device or rice planting machine, wherein the liquid agent is passed through the dispensing unit to obtain seedlings. The present invention relates to a liquid agent spraying method for spraying at one or more locations between a plurality of ridges to be planted.

  One aspect of the present invention relates to a liquid agent spraying method, which relates to a liquid agent spraying method of spraying between half or more of the plurality of ridges.

  One aspect of the present invention relates to a method of spraying a solution using the above described device or rice transplanter to enhance the growth of rice by more than 10% or 30% compared to untreated rice.

  A first aspect of the present invention relates to a rice-planting machine-mounted liquid agent spraying device that can be mounted on a rice-planting machine and sprays a liquid agent in synchronization with a rice-planting operation by the rice-planting machine.

  The first aspect of this rice transplanter-mounted liquid agent spraying device is a tank for storing the liquid agent, a pump for conveying the liquid agent stored in the tank, one end of which is connected to the pump, and by driving the pump, A first conduit through the liquid agent carried out from the tank, an air capturing chamber connected to the other end of the first conduit, one end connected to the air capturing chamber, the first conduit and the air capturing A second pipeline through which the liquid agent carried out from the tank through the chamber is connected, and the other end of the second pipeline is connected, and the first pipeline, the trap chamber and the second pipeline are connected. And a distributor for distributing and discharging the liquid agent supplied from the tank.

  The other end of the first conduit is connected to the upper portion of the air capturing chamber rather than one end of the second conduit.

  A second aspect of the present invention further comprises an exhaust unit for exhausting air in the air capturing chamber, the exhaust unit being connected to an upper portion of the air capturing chamber more than the other end of the first conduit. Liquid spraying device.

  A third aspect of the present invention further comprises a drainage part for discharging the residual liquid agent in the gas collection chamber, wherein the liquid drainage part is located below the one end of the second conduit in the gas collection chamber. It relates to a connected liquid agent spraying device.

  In a fourth aspect of the present invention, the distribution unit has a cylindrical distribution chamber to which the other end of the second conduit is connected, and one end to the distribution chamber, wherein the first conduit and the air trap are provided. A plurality of third conduits for discharging the liquid agent supplied from the tank to the distribution chamber via the chamber and the second conduit, and the plurality of third conduits provide a distance to the distribution chamber. The liquid agent spraying device connected in advance.

  A fifth aspect of the present invention relates to a liquid agent spraying device in which each of the plurality of third pipelines is provided with a valve that adds resistance to the liquid agent passing through the inside.

  A sixth aspect of the present invention relates to a liquid agent spraying method of spraying the liquid agent onto some of the plurality of ridges where seedlings are planted, using the rice planting simultaneous liquid agent spraying device attached to the rice transplanter, via the distributor. ..

  A seventh aspect of the present invention relates to a liquid agent spraying method of spraying more than half of the ridges among the plurality of ridges.

  An eighth aspect of the present invention relates to a liquid agent spraying method, wherein the liquid agent contains at least one selected from the group consisting of herbicides.

  A ninth aspect of the present invention relates to a liquid spraying method, wherein the above herbicide is a paddy herbicide.

  In a tenth aspect of the present invention, the liquid preparation is pyrimisulfan, tefryltrione, ketospiradox, mesotrione, benzobicyclone, sulcotrione, tembotrione bromotide, triafamon, propyrisulfuron, benzosulfuron-methyl, Liquid formulation containing at least one compound selected from the group consisting of pyrazosulfuron, imazosulfuron, penoxlam, pyraclonyl, pentoxazone, oxadiazone, oxadiaargyl, butachlor, pretilachlor, fentrazamide, mefenacet, oxadiclomefone, ipphencarbazone and phenoxasulfone. Regarding spraying method.

  The eleventh aspect of the present invention, the liquid preparation is a herbicide, a plant growth regulator, a fungicide, an insecticide, an acaricide, a nematicide, a microorganism, a molluscicidal agent, a fertilizer, a toxicity reducing agent and It relates to a solution application method comprising at least one compound selected from the group consisting of plant tonic compounds as well as combinations thereof.

  A twelfth aspect of the present invention relates to a method wherein the water solubility of the above liquid preparation is lower than 100 mg / L, preferably lower than 50 mg / L, most preferably lower than 10 mg / L.

  In the sense of the present invention, water solubility is a number measured at pH 7 and 20 ° C.

  According to the embodiment of the present invention, the liquid agent can be uniformly dropped onto each of the plurality of ridges to be planted after the rice transplanter has run. Since it can be diffused to all of the dropped ridges, a uniform control effect and excellent safety (selectivity) for paddy rice can be obtained. In addition, the method described in the embodiment of the present invention can prevent the chemical agent from directly contacting the paddy rice at the time of the liquid agent application, as compared with the conventional liquid agent application method, and prevent the contact phytotoxicity of the agent on the leaf blade of the rice. Can also effectively enhance the growth of rice. Another advantage of the present invention over the prior art is that the solution is evenly diffused, even when the solution has very low or moderate water solubility. An example of an activator that has very low water solubility is oxadiargyl (0.37 mg / L), and an example of an activator that has moderate water solubility is triafamone (39 mg / L). Even if the solution is very poorly soluble in water, a uniform dispersion of the solution results in uniform control of weeds, pests and / or fungi and / or prevents crop damage.

FIG. 1 is a functional block diagram showing a structure of a rice transplanter-mounted liquid agent spraying device 1 of the present invention. FIG. 2 is a schematic diagram showing the structure of the spraying unit 2 according to the embodiment. FIG. 3 is an exploded perspective view of the valve. FIG. 4 is a schematic diagram showing a state in which the spraying device of the present invention is mounted on a rice transplanter. FIG. 5 is a schematic view showing the structure of the sprinkling portion 2'according to another embodiment.

  Hereinafter, the present invention will be described in detail according to embodiments with reference to the accompanying drawings. All the contents of the documents referred to in this specification are incorporated into the contents of the present specification.

  Note that elements that are common to the figures are identified by the same reference numbers in the figures.

  As shown in FIG. 1 and FIG. 2, a rice planting machine-installed liquid agent spraying device 1 according to one embodiment has a spraying section 2 for spraying a liquid agent and a spraying section 2 in synchronization with a planting operation of seedlings by the rice transplanter. It is provided with a spraying operation control device 3 for spraying a liquid agent, and a battery 4 as a power source for each part. The battery 4 may be an existing battery for the rice transplanter.

  The spraying unit 2 includes a tank 10, a pump 12, a first pipe line 14, a second pipe line 16, an air-capture chamber 18, and a distribution unit 20.

  The tank 10 stores a liquid agent such as a suspension agent (flowable agent). The pump 12 sucks the liquid agent from the tank 10 and conveys the liquid agent to the distribution unit 20 through the first and second pipelines 14 and 16. A so-called tube pump is adopted as the pump 12. The tube pump has a structure in which a roller is pressed against the tube and the roller is rotated to push out the liquid agent filled in the tube from the tube.

  The first pipe line 14 is, for example, a soft tube made of silicon resin or the like, one end 14a is inserted into the tank 10 via the pump 12, and the other end 14b is connected to an air capturing chamber 18 extending in a substantially vertical direction. Has been done. The second conduit 16 is a soft resin tube, one end 16a of which is connected to the air capturing chamber 18, and the other end 16b of which is connected to the distributor 20. That is, the chamber 18 can be expressed as a chamber incorporated in the pipeline including the first and second pipelines 14 and 16. The air capturing chamber 18 captures air contained in the liquid agent supplied from the tank 10 through the first conduit 14. That is, it can be said that the chamber 18 is a mechanism that receives the liquid agent conveyed by the first conduit 14 and captures the air contained in the received liquid agent. The distributor 20 distributes and discharges the liquid agent supplied from the tank 10 via the first conduit 14, the air trap chamber 18, and the second conduit 16.

  The other end 14b of the first conduit 14 is connected to the upper portion of the air capturing chamber 18 rather than the one end 16a of the second conduit 16. Inside the air collection chamber 18, sufficient space is left above the other end of the first conduit 14. The air trap chamber 18 is provided with an exhaust unit 22 for exhausting the air in the chamber and a drain unit 25 for exhausting the residual liquid agent in the chamber.

  The exhaust unit 22 is provided in the middle of the exhaust pipe line 23 and the exhaust pipe line 23 to which one end 23a of the air trap chamber 18 is connected and the other end 23b is opened, and the pipe line can be sealed. And an exhaust valve 24. Here, the exhaust pipe line 23 is a soft resin tube, and one end 23a of the exhaust pipe line 23 is connected to the upper portion of the air capturing chamber 18 in the vertical direction with respect to the other end 14b of the first pipe line 14.

  The drainage section 25 is provided in the middle of the drainage pipeline 26 and the drainage pipeline 26 whose one end 26a is connected to the gas collection chamber 18 and the other end 26b is open, and the drainage pipeline 25 is sealed. And a drainage valve 27 capable of Here, the drainage pipe line 26 is a soft resin tube, and one end 26a thereof is connected to the lower portion of the air trap chamber 18 in the vertical direction than any of the pipe lines connected to the air trap chamber 18. The drainage valve 27 is used when the liquid agent inside the air capturing chamber 18 is drained after the work by the spraying device 1 is completed.

The distribution unit 20 includes a cylindrical distribution chamber 30 made of a hard material, and a plurality of (two or more) third conduits 32 having one end 32a connected to the distribution chamber 30 and the other end 32b open to the atmosphere. , And a valve 40 provided in each of the third conduits 32. The other end 16b of the second conduit 16 connected to the distribution chamber 30 is arranged at a position higher than the one end 32a of the third conduit 32 connected to the distribution chamber 30. The chamber 30 may have a hollow shape that is as long as possible so that the liquid agent can be conveyed along the direction in which the chamber 30 extends. For example, the chamber 30 may have any cross-sectional shape, including but not limited to circular, oval, rectangular, triangular and polygonal.

  The distribution chamber 30 extending in a substantially horizontal direction is mounted at a position lower than the air capturing chamber 18 so as to be maintained substantially horizontal to the rice transplanter. That is, one end 16a of the second pipeline 16 is arranged at a position higher than the other end 16b of the same pipeline.

  The third conduit 32 is a soft resin tube, and one end 32a thereof is connected to the lower portion of the distribution chamber 30 in the vertical direction than the other end 16b of the second conduit 16. Further, one end 32a of the third conduit 32 is arranged at a position higher than the other end 32b of the same conduit. The third conduits 32 are arranged at equal intervals in the longitudinal direction with respect to the distribution chamber 30. The number of the third conduits 32 is 5 if the rice transplanter has a 6-row planting specification, and 7 if it has an 8-row planting specification. That is, the structure of the distribution unit 20 is appropriately selected according to the specifications of the rice transplanter such that the other end of the third conduit 32 corresponds to each of the gaps of the ridges.

  Each conduit of the third conduit 32 includes a cock 32c that can be selectively opened and closed. When opened, the cock allows fluid to flow through the conduit. Furthermore, the cock can prevent liquid from flowing through the conduit when closed. By the cock 32c, the spraying part 2 can prevent the liquid agent from unintentionally flowing through the respective conduits 32. For example, when the spraying part 2 is not operating, each cock 32c can be closed to prevent the liquid agent from flowing through the corresponding conduit 32.

  The valve 40 adds resistance to the liquid agent communicating from the third conduit 32 to the inside. As shown in FIG. 3, the valve 40 includes a two-piece type case 41 and at least one valve member, for example, two rubber valve members 42 and 43 arranged inside the case 41 in one embodiment. A rubber O-ring 48 is provided.

  The case 41 includes a female case 44 and a male case 45, each having a generally tubular shape for receiving the valve members 42, 43.

  A female screw portion 44a is formed on the inner peripheral surface of the female case 44, and a male screw portion 45a screwed to the female screw portion 44a is formed on the outer peripheral surface of the male case 45. Therefore, the female screw portion 44a and the female screw portion 45a can screw the female case 44 and the male case 45 together. The female case 44 is formed with a liquid agent inflow port 44b, and the male case 45 is formed with a liquid agent outflow port 45b. The inflow port 44b is connected to the upstream portion of the third pipeline 32, and the outflow port 45b is connected to the downstream portion of the third pipeline 32.

  The valve members 42 and 43 may be formed, for example, in exactly the same shape and in a conical shape whose diameter gradually decreases. A notch (slot) 46 running in the radial direction is formed on the front end surface of the valve member 42 (or 43). The notch 46 communicates with the inside and the outside of the valve member 42 (or 43), but is closed in a state where the liquid agent flowing from the inflow port 44b is not subjected to a pressure of a predetermined magnitude or more. When the pressure acting on the liquid agent exceeds a predetermined value, the mouth is opened to allow the liquid agent to flow from the inflow port 44b toward the outflow port 45b.

  The structure of the valve members 42 and 43 will be described in detail.

  As shown in FIG. 3, each of the valve members 42, 43 can be configured to have a tubular shape. Specifically, each valve member includes a first tubular member 42a (43a), a second tubular member 42b (43b) connected to the first tubular member 42a (43a), and a second tubular member 42b. The third tubular member 42c (43c) connected to (43b) and the fourth tubular member 42d (43d) connected to the third tubular member 42c (43c) are included. All of the first, second, third and fourth members are in communication with each other.

The first tubular member 42a (43a) has an upper surface (for example, a flat upper surface) on which the notch 46 is formed. The upper surface faces the outflow port 45b of the male case 45. The fourth cylindrical member 42d (43d) has an opening (not shown in FIG. 3) that communicates the first, second, and third members. The opening faces the inflow port 44b of the female case 44.

Each of the first, second, third and fourth tubular members has an inner diameter and an outer diameter. The outer diameter of each member is longer than the inner diameter of the member. The inner diameter of the second member 42b (43b) is longer than both the inner diameter and the outer diameter of the first member 42a (43a). The inner diameter of the third member 42c (43c) is longer than both the inner diameter and the outer diameter of the second member 42b (43b). The inner diameter of the fourth member 42d (43d) is longer than both the inner diameter and the outer diameter of the second member 42c (43c).

When the valve member 42 engages the valve member 43, the first tubular member 43a of the valve member 43 can enter into the fourth, third and second tubular members 42d, 42c, 42b of the valve member 42. However, the first member 43a cannot be inserted into the first tubular member 42a of the valve member 42 because the outer diameter of the first member 43a of the valve member 43 is longer than the inner diameter of the first member 42a. Therefore, the upper surface of the first member 43a is arranged at a distance from the upper surface of the first member 42a when the valve member 43 engages with the valve member 42.

The following advantages can be obtained according to the structure of the valve members 42 and 43. Specifically, on the other hand, it may be a case where a small substance such as a contaminant contained in the liquid agent is captured and left in the notch 46 of the valve member 43. In this case, the material may cause the notch 46 to open, unintentionally increasing the volume of solution. However, there is another notch 46, namely the notch 46 of the valve member 42 below the notch 46 of the valve member 43. Further, in the region between the upper surface of the valve member 43 and the upper surface of the valve member 42, there is a layer filled with the liquid agent. There, the amount of fluid flowing through the valve 40 can be maintained as intended due to the notch 46 of the valve member 42 and the fluid-filled layer.

  On the other hand, there may be another case where the small substance contained in the liquid drug is trapped and left in the notch 46 of the valve member 42. In this case, there is another cutout, namely the cutout 46 of the valve member 43 above the cutout 46 of the valve member 42. There, the amount of liquid flowing through the valve 40 can be maintained as intended due to the notch 46 in the valve member 43.

  FIG. 3 illustrates an example where valve 40 can be configured to receive two valve members. However, in one embodiment, the valve 40 can be configured to accept more than two valve members. One of ordinary skill in the art will appreciate that the more valve members (notches 46) in valve 40, the smaller the difference in the amount of liquid agent flowing through valve 40.

  FIG. 3 illustrates an example where each valve member includes one or more tubular members. However, each valve member may include one or more members having any hollow shape, as long as the one or more members can carry a liquid agent. For example, the one or more members may have any cross-sectional shape, including but not limited to circular, oval, rectangular, triangular and polygonal.

  The O-ring 48 is interposed between the female case 44 and the male case 45 that form the case 41, and seals between the two that are screwed together.

  The spraying operation control device 3 includes a conversion mechanism that converts the reciprocating motion of the nursery bed S of the rice transplanter into a rotary motion, a proximity switch, a control unit, and the like. The structure of the spraying operation control device 3 is described in detail in Japanese Patent Application Laid-Open No. 2008-48659, so the description thereof will be omitted here.

  In the spraying unit 2, the tank 10, the pump 12, and the air trap chamber 18 are housed in the first casing 13a together with the control unit 3a included in the spraying operation control device 3, and each part of the spraying operation control device 3 except the control unit is , The second casing 13b.

  As shown in FIG. 4, the first casing 13 a and the distribution chamber 30 are fixed to a gate-shaped frame F that is erected at the rear of the nursery bed S. In particular, in the distribution chamber 30, the other end 32b of the third conduit 32 corresponds to each of the furrows on which seedlings are planted, that is, the other end 32b of the third conduit is positioned between the scraping claws C of the rice transplanter. It is fixed to the portal frame F so as to be arranged (see FIG. 1). There is no particular limitation on the mounting position of the first casing 13a, but it should be installed at least above the distribution chamber 30.

  The second casing 13b is fixed to the back surface side of the nursery stand S. The method of fixing the second casing 13b is also described in detail in Japanese Patent Application Laid-Open No. 2008-48659, so the description thereof will be omitted here.

  A description will be given of the control performed using the spraying devices 1 and 1 '(using the spraying unit 2'instead of the spraying unit 2) configured as described above. Agents to be applied for control include herbicides, plant growth regulators, fungicides, insecticides, acaricides, nematicides, microorganisms, molluscicides, fertilizers, toxic-reducing agents and plant tonics. Examples of the compound include a compound and a combination thereof, and specific examples thereof will be described later.

  First, the rice transplanter with a bundle of seedlings placed on the seedbed S is put into the field, and the main switches of the sprayers 1 and 1'are turned on. Then, when the rice transplanter is operated to start the seedling planting operation, the seed bed S starts the reciprocating operation in synchronization with the scraping operation of the seedlings by the scraping claws C. The proximity switch included in the spraying operation control device 3 transmits a signal in synchronization with the reciprocating operation of the seed bed S. The controller 3a intermittently drives the pump 12 each time it receives the signal transmitted from the proximity switch. The pump 12 rotates the roller by a preset rotation amount each time the intermittent operation is performed, and discharges the liquid agent in an amount corresponding to the rotation amount. The amount of rotation of the roller can be adjusted arbitrarily, and the discharge amount (that is, the spray amount) of the liquid agent per one intermittent operation can be changed according to the type of the liquid agent. Further, as will be described later, the pump 12 can be continuously operated independently in consideration of the preliminary operation of the spraying device 1 and the like in addition to the synchronization with the planting operation of the rice transplanter.

  Each time the pump 12 is driven, the liquid agent is discharged from the other ends 32b of all the third pipelines 32. Here, since the other end 32b of the third conduit is arranged between the scraping claws C of the rice transplanter, the liquid agent discharged from the other end 32b of the third conduit 32 is eventually planted in the field. It is dripped on all the furrows of the seedlings. In other words, if the rice transplanter is a 6-row planting specification, the liquid agent is intermittently applied at intervals corresponding to the traveling speed of the rice transplanter in the 6 row ridges to be planted after the rice transplanter has run, that is, in all the 5 ridges. Dropped. Also, if the rice transplanter has a specification of 8 rows planting, the liquid agent is intermittently applied at intervals corresponding to the traveling speed of the rice transplanter in the 8 rows of ridges to be planted after the rice transplanter has run, that is, in all 7 ridges. Dropped. Since the dripped liquid agent diffuses into all of the 6 to 8 ridges, a uniform control effect can be obtained. Further, the active substance of the drug sufficiently diffuses even when the water depth in the field is shallow at the time of rice planting.

  By the way, in the above description, the liquid agent is dropped onto all of the plurality of ridges planted by the rice transplanter, but depending on the property of the liquid agent, the liquid agent may be dropped onto some of the plurality of ridges. In that case, some of the third conduits 32 may be sealed using a separately prepared sealing device (clip or the like), or the distribution unit may be replaced with one having a small number of the third conduits 32. You may.

  By the way, the most problematic point when passing a liquid agent through a thin and long pipeline is that an air pool remains in the pipeline. Such an air pocket becomes a factor that hinders the smooth flow of the liquid agent. In particular, in the spraying device 1 having a plurality of liquid agent discharge ends (32b), the presence of air pockets is a great obstacle in spraying an approximately equal amount of liquid agent from each discharge end.

  In most cases, the air pool remains inside the pipeline during the initial passage of the liquid to the spraying device 1. Conversely, if air can be removed from the inside of the pipeline during the initial passage of the spraying device, the air will not be removed during the subsequent spraying operation. There is no accumulation.

  Therefore, in the spraying device 1, a preliminary operation until the empty tank 10 is filled with the liquid agent and the liquid is passed through the entire device will be described.

  First, the prepared liquid agent is put into the tank 10. Next, the exhaust valve 24 and the drainage valve 27 are closed, and the pump 12 is continuously rotated. As a result, the liquid agent stored in the tank 10 is sucked out, and the sucked liquid agent is discharged from the pump 12.

  The liquid agent discharged from the pump 12 flows into the air capturing chamber 18 such that the air remaining inside the first pipeline 14 is pushed out from the other end 14b of the first pipeline 14. As a result, almost no air pool remains in the first conduit 14.

  The liquid agent that has flowed into the air capturing chamber 18 accumulates in the lower portion of the air capturing chamber 18 and flows into the one end 16a of the second conduit 16. The liquid agent that has flowed into the second pipeline 16 flows into the distribution chamber 30, and then flows into one end 32 a of the plurality of third pipelines 32. Since the flow resistance is added to the liquid agent that has flowed into the third pipeline 32 by the valve 40, the liquid agent is not discharged from the other end 32b of the third pipeline 32 for a while, and the first pipeline 14 The internal pressure of the series of passages of the air trap chamber 18, the second pipe line 16, the distribution chamber 30, and the third pipe line 32 is gradually increased by the supply of the liquid agent by the pump 12. During this time, the liquid agent does not flow in the path from the air trap chamber 18 to the third conduit 32.

  On the other hand, one end 32a of the third conduit 32 is arranged at a position higher than the other end 32b of the same conduit, and one end 16a of the second conduit 16 is also arranged at a position higher than the other end 16b of the same conduit. There is. Further, the other end 16b of the second conduit 16 connected to the distribution chamber 30 is arranged at a position higher than the one end 32a of the third conduit 32 connected to the distribution chamber 30. Therefore, in a state where there is almost no downstream flow of the liquid agent, the air remaining inside the third conduit 32 floats in the third conduit 32 toward the distribution chamber 30, and the air remaining inside the distribution chamber 30 is The air that flows into the second pipeline 16 and remains inside the second pipeline 16 floats in the second pipeline 16 toward the air capturing chamber 18.

  That is, the air remaining inside the first conduit 14 flows into the air capturing chamber 18 by the pressurizing action of the pump 12, and the air remaining inside the second conduit 16, the distribution chamber 30, and the third conduit 32 is It floats up toward the air capturing chamber 18 depending on the height difference. In this way, almost all of the air remaining in the path from the tank 10 to the third conduit 32 is collected in the air capturing chamber 18.

  The internal pressure of a series of paths of the first pipe line 14, the air trap chamber 18, the second pipe line 16, the distribution chamber 30, and the third pipe line 32 gradually increases due to the supply of the liquid agent by the pump 12, and the internal pressure finally reaches the valve. When the flow resistance added by 40 is exceeded, the liquid agent is discharged from the other ends 32b of all the third pipelines 32.

  When it is confirmed that the liquid agent is discharged from the other end 32b of the third conduit 32, the exhaust valve 24 is opened to remove the air accumulated in the air trap chamber 18. The air inside the air capturing chamber 18 is also pressurized depending on the increase in the internal pressure of the above series of paths, and is expelled vigorously from the other end 23b of the exhaust pipe line 23 that is open to the atmosphere.

  When the air is exhausted from the air collection chamber 18, the exhaust valve 24 is closed, the pump 12 is stopped, and the preliminary operation is completed.

  According to the rice transplanter-installed liquid agent spraying device 1, it is possible to remove most of the air inside the pipeline by performing the above-described preliminary operation during the initial liquid passage. As a result, in the subsequent spraying operation, no air pool is generated in the middle of the pipeline. As a result, the liquid agent can be almost uniformly discharged and dropped from the other ends 32b of all the third pipelines 32. Here, to uniformly drop the liquid agent means that the amount of the liquid agent dropped from each of the other ends 32b may deviate from the average value of the amount of the liquid agent dropped from all the other ends 32b by up to 50%, and preferably the deviated amount. Means less than 30%, most preferably less than 20%.

  Also, in one embodiment, the sparging section 2 may be configured to include an optional tank 10 'that stores a liquid agent, as shown in FIGS. The tank 10 ′ is connected to the tank 10 via the conduit 11. One end of the conduit 11 communicates with the tank 10 ′, and the other end of the conduit 11 communicates with the tank 10. The conduit 11 includes a pump 12 'that is used to draw liquid from the tank 10' and deliver the liquid to the tank 10. Inside the tank 10, there is provided a sensor 13 which transmits a control signal to the pump 12 ′ depending on whether or not the upper surface of the liquid agent contained in the tank 10 has reached a specified level and the detection result. .. The tank 10 'can be housed inside the casing 13a together with the tank 10 and the like.

  According to this three-dimensional arrangement, when the sensor 13 detects that the upper surface of the liquid has reached the specified level, the sensor 13 sends a control signal to stop the operation of the pump 12 '. Conversely, when the sensor 13 detects that the upper surface of the liquid has not reached the specified level, the sensor 13 sends a control signal to activate the pump 12 '. Therefore, the upper surface of the liquid agent can be maintained near the prescribed level.

  FIG. 5 is a schematic view showing the structure of the distribution unit 2'according to another embodiment. Hereinafter, the structure of the spray unit according to another embodiment will be described in detail. It should be noted that only specific structures will be described in the alternative embodiments, and descriptions of structures common to those described above with reference to FIGS. 1-4 will be omitted.

  FIG. 5 shows a sprinkler 2'according to another embodiment. Pump 12 is connected to distribution chamber 30 via line 52. One end of the pipe line 52 is connected to the pump 12, and the other end of the pipe line 52 is connected to the chamber 30. The conduit 52 conveys the liquid agent sucked by the pump 12 to the chamber 30.

  An additional conduit 54 is provided between the chamber 30 and the tank 10. One end 54 a of the conduit 54 is connected to the tank 10, while the other ends 54 b and 54 c of the conduit 54 are connected to the chamber 30. Specifically, for example, the two other ends 54b and 54c may be connected to both ends of the chamber 30 extending in the horizontal direction. The pipeline 54 receives the liquid agent supplied from the pump 12 to the chamber 30, and conveys the received liquid agent to the tank 10.

  According to the above structure, even when air is present in the chamber 30, the air can be forced to move toward either end of the chamber 30 due to the flow of the liquid agent dispensed by the pump 12. it can. Thus, the air, which tends to float in the liquid agent, finally reaches the other end 54b or the other end 54c, and can then move upward along the pipe line 54. Therefore, the air can be conveyed to the tank 10 along the pipe line 54. As mentioned above, the conduit 54 can function to receive the liquid agent carried by the conduit 52 and the chamber 30 and trap the air contained in the received liquid agent. As a result, the amount of air that can reach the conduit 32 can be minimized, so that the difference in the amount of the liquid agent flowing through the conduit 32 can also be minimized, and the one end 54a to the inside of the tank 10 can be reduced. Since the drainage of the liquid agent containing air agitates the liquid agent in the tank 10, separation of the liquid agent is prevented.

  FIG. 5 shows the best embodiment in which the other ends 54 b and 54 c of the conduit 54 are connected to both ends of the chamber 30. In one embodiment, the other ends 54b, 54c of the conduit 54 are connected to any location away from the ends of the chamber 30 as the other ends 54b, 54c can more or less trap the air present in the chamber 30. it can. However, in this case, since the air carried by the conduit 52 reaches the positions near both ends of the chamber 30 and can move downward to the conduit 32, the difference in the amount of the liquid agent discharged by the conduit 32 is intended. May increase rather than target. Thus, the other ends 54b, 54c may advantageously be connected to both ends of the chamber 30 shown in FIG.

  Further, since the air contained in the liquid agent tends to float, the other ends 54b, 54c of the conduit 54 can be beneficially connected to the upper surface of the chamber 30 as compared to the side or bottom surface of the chamber 30. However, in one embodiment, the other ends of the conduits 54 may be connected to the sides or bottom of the chamber 30 as these ends are still able to trap the air present in the chamber 30 to a greater or lesser extent.

  The approach described above with reference to FIG. 5 may be performed in place of, or in conjunction with, the approach described above with reference to FIG. That is, the structure shown in FIG. 5 can operate in cooperation with the structure shown in FIG.

  For example, the spreading section described above with reference to FIGS. 2 and 5 can advantageously be mounted on a rice transplanter. However, the spraying part is mounted on a device that requires a structure in which the liquid agent must be discharged from two or more pipelines (valves) so as to minimize the difference in the amount of fluid flowing through the pipelines (valves). You can also do it.

  Each conduit 32 can include a cock 32c that can be selectively opened and closed, as described above with reference to FIG. In one embodiment, when the spreading part 2'is deactivated, each cock 32c is also closed. Next, when several hours have passed after the operation of the spraying section 2'is stopped, air may be generated somewhere in the spraying section 2 '(for example, the chamber 30, the pipe lines 52, 54, etc.). Then, when the operation of the spraying section 2 ′ is started, the pump 12 can be operated by closing each cock 32 c before discharging the liquid agent through each pipe 32. By operating the pump 12 for 1 to 3 minutes, the air generated in the spraying section 2 ′ can be captured by the pipe line 54 and returned to the tank 10. Therefore, the amount of air contained in the chamber 30 can be minimized. Next, each cock 32 can be opened so that each pipe 32 can discharge the liquid agent.

  Further, in one embodiment, the conduit 54 can include the same valve 40 described above near one end 54a of the conduit 54, as shown in FIG. Using valve 40, the pressure of the liquid agent flowing through one end 54a of conduit 54 can be adjusted to balance the liquid agent flowing through the end 32b of each conduit 32. Although FIG. 5 shows that the valve 40 is provided inside the tank 10, the valve 40 can be provided outside the tank 10.

  As with the embodiment described with reference to FIG. 2, using optional tank 10 ′ and elements associated with tank 10 ′ (including line 11, pump 12 ′ and sensor 13), FIG. The top surface of the liquid contained in the tank 10 can be maintained near the levels defined in the embodiments described with reference.

  Herbicides and plant growth regulators used for control include, for example, acetolactate synthase, acetyl-CoA carboxylase, cellulose synthase, enolpyruvylshikimate-3-phosphate synthase, glutamine synthase, p-hydroxyphenylpyruvate. It is a known active substance that acts as an inhibitor of dioxygenase, phytoene desaturase, photosystem I (photosystem I), photosystem II (photosystem II), and protoporphyrinogen oxidase, for example, Weed Research 26 (1986). ) 441-445 or "The Pesticide Manual", 15th edition, The British Crop Protection Council and the Roy. l Soc. of Chemistry, 2006 and the references cited therein.

More specifically, herbicides include, for example, the following active substances (compounds are described by "general name" according to International Organization for Standardization (ISO) or by chemical name or code number): .. And always includes all applications such as acids, salts, esters, and variants such as isomers, eg stereoisomers and optical isomers. By way of example, at least one application and / or variant is described below: Acetochlor, acibenzolar, acibenzolar-S-methyl, acifluorfen, acifluorfen-sodium, aclonifene, alachlor, alidochlor, alloxidim, alloxidim- Sodium, Amethrin, Amicarbazone, Amidochlor, Amidosulfuron, Aminocyclopyrachlor, Aminocyclopyrachlor-methyl, Aminocyclopyrachlor-potassium, Aminopyralide, Amitrole, Ammonium sulfamate, Ansimidol, Anilophos, Aslam, Atrazine, Azaphenidine , Azimuthulfuron, adiprothrin, beflubutamide, benazoline, benazoline-ethyl, bencarbazone, benfluralin, benfresate , Bensuride, bensulfuron, bensulfuron-methyl, bentazone, benzfendizone, benzobicyclone, benzophenap, benzofluor, benzoylprop, bicyclopyrone, bifenox, vilanafos, vilanafos-sodium, bispyribac, bispyribac-sodium, bromacil. Bromobutide, bromophenoxime, bromoxynil, bromoxynil-butyrate, -potassium, -heptanoate and octanoate, bromuron, buminafos, butoxynone, butachlor, butaphenacyl, butamiphos, butenachlor, butralin, butroxidim, butyrate, cafenstrol, carbetamide, carfentrazone, calphentrazone. Fentrazone-ethyl, clomethoxyphene, chloramben, chlora Hops, chloradifop-butyl, chlorbromuron, chlorbufum, chlorfenac, chlorfenac-sodium, chlorfenprop, chlorflurenol, chlorflurenol-methyl, chloridazone, chlorimuron, chlorimuron-ethyl, chlormequat-chlorid, chlornitorfen, chlorophthalim, Chlortal-dimethyl, chlorotoluron, chlorsulfuron, cinidone, sinidone-ethyl, symmethrin, cinosulfuron, crethodim, clodinafop, clodinafop-propargyl, clofenset, clomazone, clomeprop, cloprop, clopyralid, chloranthrum, chloranslam-methyl, cumyluron, cyanamide. , Cyanadine, cyclanilide, cycloate, cyclopyrimoleate, Crosulfamuron, cycloxydim, cyclulone, cyhalofop, cyhalofop-butyl, cyperquat, ciprazine, ciprazole, 2,4-D, 2,4-D-, -butyl, -dimethylammonium, -diolamine, -ethyl, 2-ethylhexyl. , Isobutyl, -isooctyl, -isopropylammonium, -potassium and triisopropanolammonium, 2,4-DB, 2,4-DB-butyl, -dimethylammonium, -isooctyl, -potassium and sodium, diamuron (Daimuron), darapone , Daminozide, dazomet, n-decanol, desmedifam, desmethrin, detosyl-pyrazolate (DTP), dialate, dicamba, diclovenil, dichlorprop, dichlorprop-P, diclohot , Diclofop-methyl, diclofop-P-methyl, diclosulam, dietatyl, dietatyl-ethyl, difenoxuron, difenzocoat, diflufenican, diflufenzopyr, diflufenzopyr-sodium, dikeglac-sodium, dimefron, dimepiperate, dimetachlor, dimetamethrin, Dimethenamide, Dimetenamide-P, Dimethipine, Dimetrasulfuron, Dinitramine, Dinoceb, Dinoterb, Diphenamide, Dipropetrin, Diquat, Diquat-dibromide, Dithiopyr, Diuron, DNOC, Eglinazine-Ethyl, Endothal, EPTC, Esprocarin, Eprocarulin, Etalcarb Tosulfuron, etamethosulfuron-methyl, ethephon, ethidimurone, ethiozine, etofumesate Ethoxyphene, ethoxyphen-ethyl, ethoxysulfuron, etobenzanide, F-5231, i.e. N- [2-chloro-4-fluoro-5- [4- (3-fluoropropyl) -4,5-dihydro-5-. Oxo-1H-tetrazol-1-yl] phenyl] -ethanesulfonamide, F-7967, ie 3- [7-chloro-5-fluoro-2- (trifluoromethyl) -1H-benzimidazol-4-yl] -1-Methyl-6- (trifluoromethyl) pyrimidine-2,4- (1H, 3H) -dione, fenoprop, phenoxaprop, phenoxaprop-P, phenoxaprop-ethyl, phenoxaprop-P -Ethyl, phenoxasulphone, fentrazamide, fenuron, flamprop, flamprop M-isopropyl, flamprop-M-methyl, flazasulfuron, floraslam, fluazifop, fluazifop-P, fluazifop-butyl, fluazifop-P-butyl, fluazolate, flucarbazone, flucarbazone-sodium, flucetosulfuron, fluchloraline, flufenaset. (Thiafluamide), flufenpyr, flufenpyr-ethyl, flumetraline, flumetulam, flumicrolac, flumicrolac-pentyl, flumioxazin, flumipropine, fluometuron, fluorodiphen, fluoroglycophene, fluoroglycophene-ethyl, flupoxam, flupropacil, Flupropanate, Flupyrsulfuron, Flupyrsulfuron-methyl-sodium, Flurenol, Flurenol Ru-butyl, -dimethylammonium and methyl, fluridone, flurochloridone, fluroxypyr, fluroxypyr-meptyl, flurprimidol, flutamon, fluthiaset, fluthiaset-methyl, fluthiamide, fomesafen, fomesafen-sodium, foramsulfuron, forchlor Fenuron, fosamine, furyloxyphene, gibberellic acid, glufosinate, glufosinate-ammonium, glufosinate-P, glufosinate-P-ammonium, glufosinate-P-sodium, glyphosate, glyphosate-isopropylammonium, -ammonium, diammonium, dimethylammonium. , -Potassium, -sodium and trimesium, H-9201, i.e. O- (2,4-dimethyl-6-di Rophenyl) -O-ethyl-isopropylphosphoramide thioate, haloxifene, halosaphen, halosulfuron, halosulfuron-methyl, haloxyfop, haloxyfop-P, haloxyfop-ethoxyethyl, haloxyfop-P-ethoxyethyl, haloxyfop-methyl. , Haloxyfop-P-methyl, hexadinone, HW-02, ie 1- (dimethoxyphosphoryl) -ethyl- (2,4-dichlorophenoxy) acetate, imazametabenz, imazametabenz-methyl, imazamox, imazamox-ammonium, imazapic, imazapyr, imazapyr -Isopropylammonium, Imazaquin, Imazaquin-ammonium, Imazethapyr, Imazethapyr-ammonium, Imazosulfuron, Ina Nfido, indanophane, indazifram, indol-3-ylacetic acid (IAA), 4-indole-3-ylbutyric acid (IBA), iodosulfuron, iodosulfuron-methyl-sodium, iofensulfuron, iofensulfuron-sodium, Ioxynil, ioxynyl-octanoate, potassium and sodium, ipfencarbazone, isocarbamide, isopropaline, isoproturon, isouron isoxaben, isoxacrotol, isoxaflutol, isoxapyrihop, carbutyrate, KUH-043 I.e. 3-({[5- (difluoromethyl) -1-methyl-3- (trifluoromethyl) -1H-pyrazol-4-yl] methyl} sulfonyl) -5,5-dimethyl-4,5-dihydro -1,2-O Xazole, carbutyrate, ketospiradox, lactofen, lenacyl, linuron, maleic hydrazide, MCPA, MCPA-butyl, -dimethylammonium, 2-ethylhexyl, isopropylammonium, -potassium and sodium, MCPB, MCPB-methyl, -ethyl and Sodium, mecoprop, mecoprop-sodium, mecoprop-butytyl, mecoprop-P-butyl, mecoprop-P, mecoprop-P-dimethylammonium, mecoprop-P-2-ethylhexyl, mecoprop-P-potassium, mefenacet, mefluided, mepicote-chloride. , Mesosulfuron, mesosulfuron-methyl, mesotrione, metabenzthiazulone, metam, metamihop, metamitron, Tazachlor, metazasulfuron, metabenzthiazulone, methazole, methiopyrsulfuron, methiozoline, methoxyphenone, methyldimulone, 1-methylcyclopropene, methyl isothiocyanate, metobenzuron, metobromurone, metolachlor, S-metolachlor, metslam , Metoxuron, metribuzin, metsulfuron, metsulfuron-methyl, molinate, monalide, monocarbamide, monocarbamide dihydrogen sulfate, monolinuron, monosulfuron, monosulfuron ester, monuron, MT 128, ie 6-chloro-N-[(2E)-. 3-chloroprop-2-en-1-yl] -5-methyl-N-phenylpyridazin-3-amine, MT-5950, i.e. N- [3-chloro-4- (1-methyi). Ethyl) -phenyl] -2-methylpentanamide, NGGC-011, naproanilide, napropamide, naptalum, NC-310, i.e. 4- (2,4-dichlorobenzoyl) -1-methyl-5-benzyloxypyrazole, nebulon, Nicosulfuron, nipyraclofen, nitraline, nitrophen, nitrophenolato-sodium (mixture of isomers), nitrofluorfen, nonanoic acid, norflurazone, oleic acid (fatty acid), orbencarb, orthosulfamlone, oryzalin, oxadialygyl, oxadiazone, oxas Luflon, oxadichromefone, oxyfluorfen, paclobutrazol, paraquat, paraquat-dichloride, pebrate, pelargonic acid (nonanoic acid), pendimethalin, pendralin, Noxsulam, pentanochlor, pentachlorphenol, pentoxazone, perfluidone, petoxamide, petroleum, phenisopam, fenmedifam, fenmedifam-ethyl, picloram, picolinaphen, pinoxaden, piperofos, pirifenop, pirifenop-butyl, pretilachlor, primisulfuron, primisulfuron, primisulfuron. Luflon-methyl, probenazole, profluazole, procyanazine, prodiamine, prifluralin, propoxydim, prohexadione, prohexadione-calcium, prohydrojasmon, promethone, promethrin, propachlor, propanil, propakizahop, propazine, propham, pro Pisochlor, propoxycarbazone, propoxycarbazone-sodium, propyrisul Freon, propizzamide, prosulfarin, prosulfocarb, prosulfuron, purinachlor, pyraclonyl, pyraflufen, pyraflufen-ethyl, pyrasulfotol, pyrazolinate (pyrazolate), pyrazosulfuron, pyrazosulfuron-ethyl, pyrazoxifene, pyribambenz, pyribambenz-isopropyl, pyribambenz. -Propyl, pyribenzoxime, pyributycarb, pyridafol, pyridate, pyriftalide, pyriminobac, pyriminobac-methyl, pyrimisulfan, pyrithiobac, pyrithiobac-sodium, pyroxasulfone, piroxisulam, quinclorac, quinmelac, quinoclamin, quizalofop, quizalofop-ethyl, quizalofop -P, quizalofop-P-ethyl, quiz Hop-P-tefuryl, rimsulfuron, saflufenacil, secuvmetone, cetoxidime, ciduron, simazine, cimetrin, SN-106279, ie methyl- (2R) -2-({7- [2-chloro-4- (trifluoromethyl)). Phenoxy] -2-naphthyl} oxy) propanoate, sulcotrione, sulfarate (CDEC), sulfentrazone, sulfometuron, sulfometuron-methyl, sulfosate (glyphosate-trimesium), sulfosulfuron, SW-065, SYN-523, SYP -249, that is, 1-ethoxy-3-methyl-1-oxobut-3-en-2-yl-5- [2-chloro-4- (trifluoromethyl) phenoxy] -2-nitrobenzoate, SYP-300, That is, 1- [7 Fluoro-3-oxo-4- (prop-2-yn-1-yl) -3,4-dihydro-2H-1,4-benzoxazin-6-yl] -3-propyl-2-thioxoimidazolidine -4,5-dione, 2,3,6-TBA, tebutam, tebutyuron, technazen, tebutyurone, tefryltrione, tembotrione, tepraloxydim, terbacil, terbucarb, terbuchlor, terbumethone, terbutyrazine, terbutryn, tenilchlor, thiafluamide, Thiazafluron, thiazopyr, thiadimine, thidiazuron, thiencarbazone, thiencarbazone-methyl, thifensulfuron, thifensulfuron-methyl, thiobencarb, thiocarbazyl, topramesone, trarkoxim, triafamone, trialert, trias Ruflon, triadifuram, triazophenamide, tribenuron, tribenuron-methyl, trichloroacetic acid (TCA), tebutyuron, triclopyr, tridifane, triethazine, trifloxysulfuron, trifloxysulfuron-sodium, trifluralin, triflusulfuron, triflusulfuron. -Methyl, trimeturon, trinexapac, trinexapac-ethyl, tritosulfuron, titofef, uniconazole, uniconazole-P, urea sulfate, vernolate, ZJ-0862, i.e. 3,4-dichloro-N- { 2- [4,6-dimethoxypyrimidin-2-yl) oxy] benzyl} aniline, and the following compounds:

  Hereinafter, examples of the herbicides that can be used in the present invention will be exemplified by classifying them by action mechanism.

  (1) Acetyl CoA carboxylase (ACCase) inhibitor Aryloxyphenoxypropionic acid type ACCase inhibitor: Clodinahop propargyl, cyhalofop butyl, diclofop methyl, phenoxaprop P. ethyl, fluazifop P. butyl, halakifop R. -Methyl, Propaxazahop, Quizalofop-P-Ethyl, Metamifop, Cyclohexanedione ACCase Inhibitor: Aloxidim, Butroxidim, Cresodim, Cycloxydim, Propoxydim, Setoxydim, Tepraloxydim, Tralkoxydim, Phenylpyrazoline ACCase Inhibitor: Pinoxaden (2 ) Acetolactate synthase (ALS) inhibitor Sulfonylurea-based ALS inhibitor: Amidosulfuron, Azimsulfuron, Be Sulfuron-methyl, chlorimuron-ethyl, chlorsulfuron, shinosulfuron, cyclosulfamuron, etamethosulfuron-methyl, ethoxysulfuron, flazasulfuron, flupirsulfuron-methyl-na, foramsulfuron, halosulfuron-methyl, Imazosulfuron, iodosulfuron, mesosulfuron-methyl, metsulfuron-methyl, nicosulfuron, oxasulfuron, primisulfuron-methyl, pyrazosulfuron-ethyl, rimsulfuron, sulfometuron-methyl, sulfosulfuron, thifensulfuron-methyl, triasulfuron , Tribenuron-methyl, trifloxysulfuron, triflusulfuron-methyl, tritosulfuron, orthosulfamuron, TH547, NC620 imidazolino System (ALS) inhibitors: imazapic, imazametabenz-methyl, imazamox, imazapyr, imazaquin, imazethapyr triazolopyrimidine-based ALS inhibitors: chloranthransulam-methyl, diclosulam, phlorasulam, flumetulam, metoslam, penoxsulam pyrimidinyl-salicylate : Bispyribac sodium salt, pyribenzoxime, pyriphthalide, pyrithiobac sodium salt, pyriminobac methyl, pyrimisulfan triazolinone ALS inhibitor: flucarbazone sodium salt, propoxycarbazone sodium salt, thiencarbazone (3) photosynthesis inhibitor (photochemical system) II) Triazine type: amethrin, atrazine, cyanazine, desmethrin, dimetamethrin, promethone, prometh Phosphorus, propazine, simazine, cimetrin, terbumethone, terbutyrazine, terbutrin, triethazine triazinone series: hexazinone, metamitron, metribuzin triazolinone series: amicarbazone uracil series: bromacil, lenacyl, terbacil pyridazinone series: chloridafen medicaphamide series Urea series: chlorbromuron, chlorotoluron, chloroxuron, dimefron, diuron, etidimurone, fenuron, fluometuron, isoproturon, isouron, linuron, metabenzthiazurone, metobromuron, metoxuron, monolinuron, nebulon, ciduron, tebutyuron amide: propanil. Nochlor nitrile type: bromophenoxime, bromine Lomoxynil, Aioxynil Benzothiadiadinone: Bentazone Phenylpyridazine: Pyridate, Pyridafol (4) Toxic agent by photoactivation (photosystem II) Bipyridinium: Diquat, Paraquat (5) Protoporphyrinogen oxidase (PPO) inhibition Agents Diphenyl ether type: Acifluorfen, Biphenox, Clomethoxyphene, Fluoroglycophene, Fomesafen, Halosaphene, Lactofen, Oxyfluorfen, Chlomethoxynyl phenylpyrazole type: Fluazolate, Pyraflufen-ethyl N-phenylphthalimide type: Cinidon-ethyl, Flumioxazine, Flumicrolac pentyl thiadiazole type: fluthiaset methyl, thidiazimine oxadiazole type: Oxadiazone, Oxadiargyl Triazolinones: Azaphenidine, Carfentrazone-ethyl, Sulfentrazone Oxazolidinediones: Pentoxazone Pyrimidinediones: Benzfendizone, Butaphenacyl Others: Pyraclonil, Profluazole, Flufenpyr-ethyl (6) Carotenoid raw Synthetic Inhibitor (a) PDS Inhibitor Pyridazinone: Norflurazone Pyridine Carboxamide: Diflufenican, Picolinaphene Others: Beflubutamide, Fluridone, Flurochloridone, Flutamon (b) 4-HPPD Inhibitor Triketone: Mesotrione, Sulcotrione, Benzobicyclo , Tefryltrione isoxazole type: isoxachlortol, isoxaflutol pyrazole type Benzophenap, pyrazolinate, pyrazoxifene Others: benzobicyclone (c) Unclear target triazoles: amitrol isoxazolidinone: chromazone diphenyl ethers: aclonifene (7) EPSP synthase inhibitors glycine: glyphosate, glyphosate Trimesium salt (8) Glutamine synthase inhibitor Phosphinic acid system: Glufosinate, Bialaphos (9) DHP biosynthesis inhibitor Carbamate system: Ashram (10) Microtubule polymerization inhibitor Dinitroaniline system: Bethrosine, Butorualine, Dinitramine, Etalfluralin , Oryzalin, Pendimethalin, Trifluralin Phosphoric acid amide type: Amiprophosmethyl, Butamiphos Pyridine type: Dithiopyr, Thiazopyr Benzamide type: Propyl Zamide, tebutam, chlortar dimethyl (11) Mitotic / microtubule formation inhibitor Carbamate type: Chlorpropham, Propham, Carbetamide (12) Very long chain fatty acid biosynthesis inhibitor Chloroacetamide type: Acetochlor, Arakulor, Butachlor , Dimethacrole, dimetenamide, metazachlor, metolachlor, petoxamide, pretilachlor, propachlor, propisochlor, tenilchlor acetamide type: diphenamide, napropamide, naproanilide oxyacetamide type: flufenacet, mefenacet tetrazolinone type: anthracenazole, fenothrazamide, fenfolazoramide (13) Cellulose biosynthesis inhibitor Nitrile type: niclobenil, chlorthiamid benzamide type: isoxabe Triazolocarboxamide type: flupoxam quinolinecarboxylic acid type: quinchlorac (14) uncoupler dinitrophenol type: DNOC, dinoseb, dinoterb (15) fatty acid elongation inhibitor (non-ACCase inhibitor) thiocarbamate type: butyrate, cycloate, dimepipe Rate, EPTC, esprocarb, molinate, orbencarb, pebrate, prosulfocarb, benchocarb, pyributycarb, thiocarbazyl, trialate, vernalate phosphoric acid dithioate type: bensullide benzofuran type: benflateate, etofumesate chlorocarbonic acid type: TCA, darapone, tetrapion ( 16) Auxin-like herbicide Phenoxycarboxylic acid type: Kromeprop, 2,4-D, 2,4-DB, diclop Ropp, MCPA, MCPB, MCPP Benzoic acid type: chloramben, dicamba, 2,3,6-TBA pyridinecarboxylic acid type: clopyralide, fluroxypyr, picloram, triclopyr, quinclorac, quinmelac Others: Benazoline ethyl (17) auxin transfer Flow inhibitors Naphthalamate type: Naphthalam, Semicarbazone type: Diflufenzopyr sodium salt, (18) Others (mechanism of action unknown) Arylaminopropionic acid type: Flamprop, M, Methyl, Flamprop, Isopropyl, Pyrazolium type: Difenzocoat , Organic arsenic system: DSMA, MSMA, Others: Bromobutide, Chlorflurenol, Symmethyline, Cumyluron, Dazomet, Daimuron, Methyldaimuron, Etobenzanide, Hosamine, A Danofan, metam, oxaziclomefone, oleic acid, pelargonic acid, Pyributicarb.

  Further, as the herbicide, a compound comprising a sulfonylurea compound, a sulfoneanilide compound, a benzoylcyclohexanedione compound, or a salt thereof is preferable. Particularly preferred examples include pyrimisulfan, triafamone and the like as examples of sulfoneanilide compounds. Examples of the benzoylcyclohexanedione-based compound include tefryltrione, ketospiradox, mesotrione, sulcotrione, and tembotrione.

  Examples of plant growth regulators include acibenzolar, acibenzolar-S-methyl, 5-aminolevulinic acid, ancimidol, 6-benzylaminopurine, brassinolide, catechin, chlormequat chloride, cloprop, cyclanilide, 3- (cycloprop -1-enyl) propionic acid, daminozide, dazomet, n-decanol, dikeglac, dikeglac-sodium, endothal, endothal-dipotassium, disodium and mono (N, N-dimethylalkylammonium), ethephon, flumetraline, Flurenol, flurenol-butyl, fluprimidol, forchlorfenuron, gibberellic acid, inabenfide, indole-3-acetic acid (IAA), 4-indole-3-ylbutyric acid, isoprothiolane, probenazo , Jasmonic acid, maleic hydrazide, mepiquat chloride, 1-methylcyclopropene, methyl jasmonate, 2- (1-naphthyl) acetamide, 1-naphthyl acetic acid, 2-naphthyloxyacetic acid, nitrophenolate mixture, pac Lobutrazole, N- (2-phenylethyl) -β-alanine, N-phenylphthalamic acid, prohexadione, prohexadione-calcium, prohydrojasmon, salicylic acid, strigolactone, technazene, thidiazuron, thiacon Tanol, trinexapac, trinexapac-ethyl, titofef, uniconazole, uniconazole-P.

  Examples of fungicides in mixed formulations or tank mixes defined herein by their "generic name" that can be used in control processes are known and are described, for example, in the Pesticide Manual, or It can be searched on the Internet (eg, http://www.alanwood.net/pestides).

  1) Inhibitors of ergosterol biosynthesis, such as (1.1) aldimorph, (1.2) azaconazole, (1.3) bitertanol, (1.4) bromconazole, (1.5) cyproconazole, (1.6) diclobutrazole, (1.7) difenoconazole, (1.8) diniconazole, (1.9) diniconazole-M, (1. 10) dodemorph, (1.11) dodemorph acetate, (1.12) Epoxyconazole, (1.13) Etaconazole, (1.14) Phenalimol, (1.15) Fenbuconazole, (1.16) Fenhexamide, (1.17) Fenpropidine, (1.18) Fenpromimorph, (1.19) Fluquinconazole, (1.20) Flurprimidol, (1.21) Flusilazole, (1.22) Triafol, (1.23) Fluconazole, (1.24) Fluconazole-cis, (1.25) Hexaconazole, (1.26) Imazalil, (1.27) Imazalyl Sulfate, (1.28) Imbenco Nazole, (1.29) ipconazole, (1.30) metconazole, (1.31) microbutanyl, (1.32) naphthifine, (1.33) nuarimol, (1.34) oxypoconazole, (1.35) ) Paclobutrazol, (1.36) pefurazoate, (1.37) penconazole, (1.38) piperaline, (1.39) prochloraz, (1.40) propiconazole, (1.41) prothiocona Zole, (1.42) Pyributycarb, (1.43) Pyrifenox, (1.44) Quinconazole, (1.45) Simecona , (1.46) spiroxamine, (1.47) tebuconazole, (1.48) terbinafine, (1.49) tetraconazole, (1.50) triadimefone, (1.51) triadimenol, ( 1.52) tridemorph, (1.53) triflumizole, (1.54) triphorine, (1.55) trithiconazole, (1.56) uniconazole, (1.57) uniconazole-p, ( 1.58) Viniconazole, (1.59) Voriconazole, (1.60) 1- (4-chlorophenyl) -2- (1H-1,2,4-triazol-1-yl) cycloheptanol, (1. 61) Methyl 1- (2,2-dimethyl-2,3-dihydro-1H-inden-1-yl) -1H-imidazole-5-carboxylate, (1.62) N '-{5- (Difluoromethyl) -2-methyl-4- [3- (trimethylsilyl) propoxy] phenyl} -N-ethyl-N-methylimidoformamide, (1.63) N-ethyl-N-methyl-N '-{2 -Methyl-5- (trifluoromethyl) -4- [3- (trimethylsilyl) propoxy] phenyl} imidoformamide, (1.64) O- [1- (4-methoxyphenoxy) -3,3-dimethylbutane- 2-yl] 1H-imidazol-1-carbothioate, (1.65) pyrisoxazole.

  2) Inhibitors of the respiratory chain in complex I or II, eg (2.1) Bixaphene, (2.2) Boscalide, (2.3) Carboxin, (2.4) Diflumetrim, (2.5 ) Fenfram, (2.6) fluopyram, (2.7) flutolanil, (2.8) fluxapyroxad, (2.9) flametopyr, (2.10) flumecilux, (2.11) isopyrazam ( A mixture of syn-epimer racemate 1RS, 4SR, 9RS and anti-epimer racemate 1RS, 4SR, 9SR), (2.12) isopyrazam (anti-epimer racemate 1RS, 4SR, 9SR), (2.13) isopyrazam (anti-epimer enantiomer 1R). , 4S, 9S), (2.14) Isopyrazam (anti-epimer enantiomer 1S, 4R, 9R), (2.15) Pyrazam (syn-epimer racemate 1RS, 4SR, 9RS), (2.16) isopyrazam (syn-epimer enantiomer 1R, 4S, 9R), (2.17) isopyrazam (syn-epimer enantiomer 1S, 4R, 9S), ( 2.18) Mepronil, (2.19) Oxycarboxin, (2.20) Penfluene, (2.21) Penthiopyrad, (2.22) Sedaxane, (2.23) Thifluzamide, (2.24) 1- Methyl-N- [2- (1,1,2,2-tetrafluoroethoxy) phenyl] -3- (trifluoromethyl) -1H-pyrazole-4-carboxamide, (2.25) 3- (difluoromethyl) -1-Methyl-N- [2- (1,1,2,2-tetrafluoroethoxy) phenyl] -1H-pyrazole-4 Carboxamide, (2.26) 3- (difluoromethyl) -N- [4-fluoro-2- (1,1,2,3,3,3-hexafluoropropoxy) phenyl] -1-methyl-1H-pyrazole -4-carboxamide, (2.27) N- [1- (2,4-dichlorophenyl) -1-methoxypropan-2-yl] -3- (difluoromethyl) -1-methyl-1H-pyrazole-4- Carboxamide, (2.28) 5,8-difluoro-N- [2- (2-fluoro-4-{[4- (trifluoromethyl) pyridin-2-yl] oxy} phenyl) ethyl] quinazoline-4- Amine, (2.29) benzobindiflupyr, (2.30) N-[(1S, 4R) -9- (dichloromethylene) -1,2,3,4-tetrahydro-1,4-methanonaphthalene- 5-yl] -3- (difluoromethyl) -1-methyl-1H-pyrazole-4-carboxamide, (2.31) N-[(1R, 4S) -9- (dichloromethylene) -1,2,3 , 4-Tetrahydro-1,4-methanonaphthalen-5-yl] -3- (difluoromethyl) -1-methyl-1H-pyrazole-4-carboxamide, (2.32) 3- (difluoromethyl) -1- Methyl-N- (1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl) -1H-pyrazole-4-carboxamide, (2.33) 1,3,5-trimethyl-N -(1,1,3-Trimethyl-2,3-dihydro-1H-inden-4-yl) -1H-pyrazole-4-carboxamide, (2.34) 1-methyl-3- (trifluoromethyl)- N- (1 1,3-Trimethyl-2,3-dihydro-1H-inden-4-yl) -1H-pyrazole-4-carboxamide, (2.35) 1-methyl-3- (trifluoromethyl) -N-[( 3R) -1,1,3-Trimethyl-2,3-dihydro-1H-inden-4-yl] -1H-pyrazole-4-carboxamide, (2.36) 1-methyl-3- (trifluoromethyl) -N-[(3S) -1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl] -1H-pyrazole-4-carboxamide, (2.37) 3- (difluoromethyl) -1-Methyl-N-[(3S) -1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl] -1H-pyrazole-4-carboxamide, (2.38) 3- (Difluoromethyl -1-Methyl-N-[(3R) -1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl] -1H-pyrazole-4-carboxamide, (2.39) 1, 3,5-Trimethyl-N-[(3R) -1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl] -1H-pyrazole-4-carboxamide, (2.40) 1 , 3,5-Trimethyl-N-[(3S) -1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl] -1H-pyrazole-4-carboxamide, (2.41) Benodanyl, (2.42) 2-chloro-N- (1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl) pyridin-3-carboxamide, (2.43) N- [ 1- (4-isopropoxy-2-methylphenyl) Phenyl) -2-methyl-1-oxopropan-2-yl] -3-methylthiophene-2-carboxamide.

  3) Respiratory chain inhibitors in complex III, such as (3.1) amethoctrazine, (3.2) amisulbrom, (3.3) azoxystrobin, (3.4) cyazofamide, (3.5 ) Coumethoxystrobin, (3.6) Comoxystrobin, (3.7) Dimoxystrobin, (3.8) Enoxastrobin, (3.9) Famoxadon, (3.10) Fenamidone, (3.11) Fluphenoxystrobin, (3.12) Fluoxastrobin, (3.13) Kresoxime-methyl, (3.14) Metominostrobin, (3.15) Orysastrobin. (3.16) picoxystrobin, (3.17) pyraclostrobin, (3.18) pyrametostrobin, (3.19) pyraoxystrobin, (3.20) pyribencarb, (3.21) Triclopyricarb, (3.22) trifloxystrobin, (3.23) (2E) -2- (2-{[6- (3-chloro-2-methylphenoxy) -5-fluoropyrimidine-4- Ill] oxy} phenyl) -2- (methoxyimino) -N-methylacetamide, (3.24) (2E) -2- (methoxyimino) -N-methyl-2- (2-{[({(1E ) -1- [3- (Trifluoromethyl) phenyl] ethylidene} amino) oxy] methyl} phenyl) acetamide, (3.25) (2E) -2- (methoxyimino) -N-methyl-2- {2 -[( )-({1- [3- (Trifluoromethyl) phenyl] ethoxy} imino) methyl] phenyl} acetamide, (3.26) (2E) -2- {2-[({[(1E) -1- (3-{[(E) -1-fluoro-2-phenylvinyl] oxy} phenyl) ethylidene] amino} oxy) methyl] phenyl} -2- (methoxyimino) -N-methylacetamide, (3.27) Phenaminostrobin, (3.28) 5-methoxy-2-methyl-4- (2-{[({(1E) -1- [3- (trifluoromethyl) phenyl] ethylidene} amino) oxy] methyl } Phenyl) -2,4-dihydro-3H-1,2,4-triazol-3-one, (3.29) methyl (2E) -2- {2-[({cyclopropyl [(4-methoxyphenyl ) Imino] (Cyl} sulfanyl) methyl] phenyl} -3-methoxyacrylate, (3.30) N- (3-ethyl-3,5,5-trimethylcyclohexyl) -3-formamide-2-hydroxybenzamide, (3.31) 2- {2-[(2,5-dimethylphenoxy) methyl] phenyl} -2-methoxy-N-methylacetamide, (3.32) 2- {2-[(2,5-dimethylphenoxy) methyl] phenyl } -2-Methoxy-N-methylacetamide.

  4) inhibitors of mitosis and cell division, eg (4.1) benomyl, (4.2) carbendazim, (4.3) chlorphenazole, (4.4) dietofencarb, (4.5) Ethaboxam, (4.6) fluopicolide, (4.7) fuberidazole, (4.8) penciclone, (4.9) thiabendazole, (4.10) thiophanate-methyl, (4.11) thiophanate, (4.12). ) Zoxamide, (4.13) 5-chloro-7- (4-methylpiperidin-1-yl) -6- (2,4,6-trifluorophenyl) [1,2,4] triazolo [1,5 -A] pyrimidine, (4.14) 3-chloro-5- (6-chloropyridin-3-yl) -6-methyl-4- (2,4,6-trifluorophenyl) pyridazine.

  5) Compounds capable of exhibiting multipoint action, for example, (5.1) Bordeaux mixture, (5.2) captafol, (5.3) captan, (5.4) chlorothalonil, (5.5) water Copper oxide, (5.6) copper naphthenate, (5.7) copper oxide, (5.8) copper oxychloride, (5.9) copper sulfate (2+), (5.10) diclofluanide, ( (5.11) Dithianon, (5.12) Dodine, (5.13) Todine Free Base, (5.14) Felbum, (5.15) Fluorofolpet, (5.16) Folpet, (5.17) ) Guazatine, (5.18) Guazatine acetate, (5.19) Iminoctadine, (5.20) Iminoctadine Albesylate, (5.21) Iminoctadine triacetate, (5.22) Mancopper, (5.23) Mancozeb, (5.24) Maneb, Sulfur including 5.25) methylam, (5.26) methylam zinc, (5.27) oxine-copper, (5.28) propamidine, (5.29) propineb, (5.30) sulfur and calcium polysulfide. Formulation, (5.31) thiram, (5.32) tolylfluanid, (5.33) zineb, (5.34) diram, (5.35) anilazine.

  6) Compounds capable of inducing host defense, for example (6.1) acibenzolar-S-methyl, (6.2) isotianil, (6.3) probenazole, (6.4) thiazinyl, (6.5) laminarin.

  7) Inhibitors of amino acid and / or protein biosynthesis, such as (7.1) Andoprim, (7.2) Blasticidin-S, (7.3) Cyprodinil, (7.4) Kasugamycin, (7.5). ) Kasugamycin salt trihydrate, (7.6) mepanipyrim, (7.7) pyrimethanil, (7.8) 3- (5-fluoro-3,3,4,4-tetramethyl-3,4-dihydro Isoquinolin-1-yl) quinoline, (7.9) oxytetracycline, (7.10) streptomycin.

  8) ATP production inhibitors, for example, (8.1) fentin acetate, (8.2) fentin chloride, (8.3) hydroxylated fentin, (8.4) silthiofam.

  9) Inhibitors of cell wall synthesis, for example, (9.1) bentavalicarb, (9.2) dimethomorph, (9.3) flumorph, (9.4) iprovaricarb, (9.5) mandipropamide, (9) .6) Polyoxine, (9.7) Polyoxolim, (9.8) Validamycin A, (9.9) Variphenalate, (9.10) Polyoxine B.

  10) Inhibitors of lipid and membrane synthesis, such as (10.1) biphenyl, (10.2) chloroneb, (10.3) dichlorane, (10.4) edifenphos, (10.5) etridiazole, (10. 6) Iodocarb, (10.7) iprobenphos, (10.8) isoprothiolane, (10.9) propamocarb, (10.10) propamocarb hydrochloride, (10.11) prothiocarb, (10.12) pyrazophos, (10. 13) quintozen, (10.14) technazen, (10.15) tolclofos-methyl.

  11) Inhibitors of melanin biosynthesis, for example, (11.1) carpropamide, (11.2) diclocymet, (11.3) phenoxanil, (11.4) phthalide, (11.5) pyroquilon, (11.6). ) Tricyclazole, (11.7) 2,2,2-trifluoroethyl {3-methyl-1-[(4-methylbenzoyl) amino] butan-2-yl} carbamate.

  12) Inhibitors of nucleic acid synthesis, for example, (12.1) benalaxyl, (12.2) benalaxyl-M (chiralaxyl), (12.3) bupirimate, (12.4) clodilacone, (12.5) dimethymol, (12.6) Ethirimol, (12.7) Furalaxyl, (12.8) Hymexazole, (12.9) Metalaxyl, (12.10) Metalaxyl-M (Mefenoxam), (12.11) Offlace, (12 .12) oxadixyl, (12.13) oxophosphoric acid, (12.14) octirinone.

  13) Inhibitors of signal transduction, such as (13.1) clozolinate, (13.2) phenyluronyl, (13.3) fludioxonil, (13.4) iprodione, (13.5) procymidone, (13.6). Quinoxifene, (13.7) vinclozolin, (13.8) proquinazide.

14) A compound capable of acting as an uncoupler, for example, (14.1) binapacryl, (14.2) zinocap, (14.3) ferrimzone, (14.4) fluazinam, (14.5) methylzinocap.

15) Another compound, for example, (15.1) benazole, (15.2) betoxazine, (15.3) capsimycin, (15.4) carvone, (15.5) quinomethionate, (15.6). Pliophenone (Clazaphenone), (15.7) Kufuraneb, (15.8) Ciflufenamide, (15.9) Cimoxanil, (15.10) Cyprosulfamide, (15.11) Dazomet, (15.12) Debacarb, (15.13) dichlorophen, (15.14) dichromedine, (15.15) diphenzocoat, (15.16) diphenzocoat methyl sulfate, (15.17) diphenylamine, (15.18) ecomate, ( 15.19) Fenpyrazamine, (15.20) Flumetbell, (15.21) Fluorimide, (15. 2) Fursulfamide, (15.23) Furtianil, (15.24) Fosetyl-aluminum, (15.25) Fosetyl-calcium, (15.26) Fosetyl-sodium, (15.27) Hexachlorobenzene, (15.28). ) Irmamycin, (15.29) Metasulfocarb, (15.30) Methylisothiocyanate, (15.31) Metraphenone, (15.32) Mildiomycin, (15.33) Natamycin, (15.34) Nickel dimethyldithiocarbamate, (15.35) nitrotar-isopropyl, (15.37) oxamocarb, (15.38) oxyphenthiine, (15.39) pentachlorophenol and salts, (15.40) phenothrin, (15 .41) phosphoric acid and salts thereof, (15.4) ) Propamocarb-fosetylate, (15.43) propanosine-sodium, (15.44) pyrimorph, (15.45) (2E) -3- (4-tert-butylphenyl) -3- (2-chloropyridine-4) -Yl) -1- (morpholin-4-yl) prop-2-en-1-one, (15.46) (2Z) -3- (4-tert-butylphenyl) -3- (2-chloropyridine -4-yl) -1- (morpholin-4-yl) prop-2-en-1-one, (15.47) pyrrole nitrin, (15.48) tebufloquine, (15.49) teclophthalam, (15 .50) tornifanide, (15.51) triazoxide, (15.52) trichlamide, (15.53) zalilamide, (15.54) (3S, 6S, 7R, 8R) -8-ben. Dil-3-[({3-[(isobutyryloxy) methoxy] -4-methoxypyridin-2-yl} carbonyl) amino] -6-methyl-4,9-dioxo-1,5-dioxonan-7 -Yl 2-methylpropanoate, (15.55) 1- (4- {4-[(5R) -5- (2,6-difluorophenyl) -4,5-dihydro-1,2-oxazole- 3-yl] -1,3-thiazol-2-yl} piperidin-1-yl) -2- [5-methyl-3- (trifluoromethyl) -1H-pyrazol-1-yl] ethanone, (15. 56) 1- (4- {4-[(5S) -5- (2,6-difluorophenyl) -4,5-dihydro-1,2-oxazol-3-yl] -1,3-thiazole-2 -Yl} piperidin-1-yl) -2- [5-methyl- -(Trifluoromethyl) -1H-pyrazol-1-yl] ethanone, (15.57) 1- (4- {4- [5- (2,6-difluorophenyl) -4,5-dihydro-1, 2-Oxazol-3-yl] -1,3-thiazol-2-yl} piperidin-1-yl) -2- [5-methyl-3- (trifluoromethyl) -1H-pyrazol-1-yl] ethanone , (15.58) 1- (4-Methoxyphenoxy) -3,3-dimethylmethan-2-yl 1H-imidazol-1-carboxylate, (15.59) 2,3,5,6-tetrachloro- 4- (methylsulfonyl) pyridine, (15.60) 2,3-dibutyl-6-chlorothieno [2,3-d] pyrimidin-one, (15.61) 2,6-dimethyl-1H, 5H- [1 , 4] Dichiino [ , 3-c: 5,6-c '] dipyrrole-1,3,5,7 (2H, 6H) -tetron, (15.62) 2- [5-methyl-3- (trifluoromethyl) -1H. -Pyrazol-1-yl] -1- (4- {4-[(5R) -5-phenyl-4,5-dihydro-1,2-oxazol-3-yl] -1,3-thiazol-2- Yl} piperidin-1-yl) ethanone, (15.63) 2- [5-methyl-3- (trifluoromethyl) -1H-pyrazol-1-yl] -1- (4- {4-[(5S ) -5-Phenyl-4,5-dihydro-1,2-oxazol-3-yl] -1,3-thiazol-2-yl} piperidin-1-yl) ethanone, (15.64) 2- [5 -Methyl-3- (trifluoromethyl) -1H-pyrazol-1-yl] -1- {4 [4- (5-phenyl-4,5-dihydro-1,2-oxazol-3-yl) -1,3-thiazol-2-yl] piperidin-1-yl} ethanone, (15.65) 2- Butoxy-6-iodo-3-propyl-4H-chromen-4-one, (15.66) 2-chloro-5- [2-chloro-1- (2,6-difluoro-4-methoxyphenyl) -4. -Methyl-1H-imidazol-5-yl] pyridine, (15.67) 2-phenylphenol and salts, (15.68) 3- (4,4,5-trifluoro-3,3-dimethyl-3,3. 4-dihydroisoquinolin-1-yl) quinoline, (15.69) 3,4,5-trichloropyridine-2,6-dicarbonitrile, (15.70) 3-chloro-5- (4-chlorophenyl)- 4- (2,6-diful Orophenyl) -6-methylpyridazine, (15.71) 4- (4-chlorophenyl) -5- (2,6-difluorophenyl) -3,6-dimethylpyridazine, (15.72) 5-amino-1, 3,4-thiadiazole-2-thiol, (15.73) 5-chloro-N'-phenyl-N '-(prop-2-yn-1-yl) thiophene-2-sulfonohydrazide, (15.74) ) 5-Fluoro-2-[(4-fluorobenzyl) oxy] pyrimidin-4-amine, (15.75) 5-Fluoro-2-[(4-methylbenzyl) oxy] pyrimidin-4-amine, (15 .76) 5-Methyl-6-octyl [1,2,4] triazolo [1,5-a] pyrimidin-7-amine, (15.77) ethyl (2Z) -3-amino-2-cyano-3. -Pheny Acrylate, (15.78) N '-(4-{[3- (4-chlorobenzyl) -1,2,4-thiadiazol-5-yl] oxy} -2,5-dimethylphenyl) -N-ethyl -N-methylimidoformamide, (15.79) N- (4-chlorobenzyl) -3- [3-methoxy-4- (prop-2-yn-1-yloxy) phenyl] propanamide, (15.80) ) N-[(4-chlorophenyl) (cyano) methyl] -3- [3-methoxy-4- (prop-2-yn-1-yloxy) phenyl] propanamide, (15.81) N-[(5 -Bromo-3-chloropyridin-2-yl) methyl] -2,4-dichloronicotinamide, (15.82) N- [1- (5-bromo-3-chloropyridin-2-yl) ethyl]- 2,4-dichloro Cotinamide, (15.83) N- [1- (5-Bromo-3-chloropyridin-2-yl) ethyl] -2-fluoro-4-iodonicotinamide, (15.84) N-{(E). -[(Cyclopropylmethoxy) imino] [6- (difluoromethoxy) -2,3-difluorophenyl] methyl} -2-phenylacetamide, (15.85) N-{(Z)-[(cyclopropylmethoxy) Imino] [6- (difluoromethoxy) -2,3-difluorophenyl] methyl} -2-phenylacetamide, (15.86) N '-{4-[(3-tert-butyl-4-cyano-1,1, 2-Thiazol-5-yl) oxy] -2-chloro-5-methylphenyl} -N-ethyl-N-methylimidoformamide, (15.87) N-methyl-2- (1- { 5-Methyl-3- (trifluoromethyl) -1H-pyrazol-1-yl] acetyl} piperidin-4-yl) -N- (1,2,3,4-tetrahydronaphthalen-1-yl) -1, 3-thiazol-4-carboxamide, (15.88) N-methyl-2- (1-{[5-methyl-3- (trifluoromethyl) -1H-pyrazol-1-yl] acetyl} piperidine-4- Yl) -N-[(1R) -1,2,3,4-tetrahydronaphthalen-1-yl] -1,3-thiazole-4-carboxamide, (15.89) N-methyl-2- (1- {[5-Methyl-3- (trifluoromethyl) -1H-pyrazol-1-yl] acetyl} piperidin-4-yl) -N-[(1S) -1,2,3,4-tetrahydronaphthalene-1 -Ill] -1,3 -Thiazole-4-carboxamide, (15.90) pentyl {6-[({[(1-methyl-1H-tetrazol-5-yl) (phenyl) methylene] amino} oxy) methyl] pyridin-2-yl} Carbamate, (15.91) phenazine-1-carboxylic acid, (15.92) quinolin-8-ol, (15.93) quinolin-8-ol sulfate (2: 1), (15.94) tert-. Butyl {6-[({[(1-methyl-1H-tetrazol-5-yl) (phenyl) methylene] amino} oxy) methyl] pyridin-2-yl} carbamate, (15.95) 1-methyl-3 -(Trifluoromethyl) -N- [2 '-(trifluoromethyl) biphenyl-2-yl] -1H-pyrazole-4-carboxamide, (15.96) N- (4'- Lorobiphenyl-2-yl) -3- (difluoromethyl) -1-methyl-1H-pyrazole-4-carboxamide, (15.97) N- (2 ′, 4′-dichlorobiphenyl-2-yl) -3 -(Difluoromethyl) -1-methyl-1H-pyrazole-4-carboxamide, (15.98) 3- (difluoromethyl) -1-methyl-N- [4 '-(trifluoromethyl) biphenyl-2-yl ] -1H-Pyrazole-4-carboxamide, (15.99) N- (2 ', 5'-difluorobiphenyl-2-yl) -1-methyl-3- (trifluoromethyl) -1H-pyrazole-4- Carboxamide, (15.100) 3- (difluoromethyl) -1-methyl-N- [4 '-(prop-1-yn-1-yl) biphenyl-2-yl] -1H-pyrazole- 4-carboxamide, (15.101) 5-fluoro-1,3-dimethyl-N- [4 '-(prop-1-yn-1-yl) biphenyl-2-yl] -1H-pyrazole-4-carboxamide , (15.102) 2-Chloro-N- [4 '-(prop-1-yn-1-yl) biphenyl-2-yl] nicotinamide, (15.103) 3- (difluoromethyl) -N-. [4 ′-(3,3-Dimethylbut-1-yn-1-yl) biphenyl-2-yl] -1-methyl-1H-pyrazole-4-carboxamide, (15.104) N- [4 ′-( 3,3-Dimethylbut-1-yn-1-yl) biphenyl-2-yl] -5-fluoro-1,3-dimethyl-1H-pyrazole-4-carboxamide, (15.105) 3- (difluoromethyl) -N- (4'- Tinylbiphenyl-2-yl) -1-methyl-1H-pyrazole-4-carboxamide, (15.106) N- (4′-ethynylbiphenyl-2-yl) -5-fluoro-1,3-dimethyl- 1H-pyrazole-4-carboxamide, (15.107) 2-chloro-N- (4′-ethynylbiphenyl-2-yl) nicotinamide, (15.108) 2-chloro-N- [4 ′-(3 , 3-Dimethylbut-1-yn-1-yl) biphenyl-2-yl] nicotinamide, (15.109) 4- (difluoromethyl) -2-methyl-N- [4 ′-(trifluoromethyl) biphenyl -2-yl] -1,3-thiazol-5-carboxamide, (15.110) 5-fluoro-N- [4 '-(3-hydroxy-3-methylbut-1-yn-1-yl) bife Lu-2-yl] -1,3-dimethyl-1H-pyrazole-4-carboxamide, (15.111) 2-chloro-N- [4 ′-(3-hydroxy-3-methylbut-in-1-yl ) Biphenyl-2-yl] nicotinamide, (15.
112) 3- (difluoromethyl) -N- [4 '-(3-methoxy-3-methylbut-1-yn-1-yl) biphenyl-2-yl] -1-methyl-1H-pyrazole-4-carboxamide , (15.113) 5-Fluoro-N- [4 '-(3-methoxy-3-methylbut-1-yn-1-yl) biphenyl-2-yl] -1,3-dimethyl-1H-pyrazole- 4-carboxamide, (15.114) 2-chloro-N- [4 '-(3-methoxy-3-methylbut-1-yn-1-yl) biphenyl-2-yl] nicotinamide, (15.115). (5-Bromo-2-methoxy-4-methylpyridin-3-yl) (2,3,4-trimethoxy-6-methylphenyl) methanone, (15.116) N- [2- (4-{[3 -(4-chlorophenyl) Lop-2-yn-1-yl] oxy} -3-methoxyphenyl) ethyl] -N2- (methylsulfonyl) valinamide, (15.117) 4-oxo-4-[(2-phenylethyl) amino] butane Acid, (15.118) but-3-yn-1-yl {6-[({[(Z)-(1-methyl-1H-tetrazol-5-yl) (phenyl) methylene] amino} oxy) methyl ] Pyridin-2-yl} carbamate, (15.119) 4-amino-5-fluoropyrimidin-2-ol (mesomeric form: 4-amino-5-fluoropyrimidin-2 (1H) -one), (15. 120) Propyl 3,4,5-trihydroxybenzoate, (15.121) 1,3-dimethyl-N- (1,1,3-trimethyl-2,3-dihydro-1H-indene 4-yl) -1H-pyrazole-4-carboxamide, (15.122), 1,3-dimethyl-N-[(3R) -1,1,3-trimethyl-2,3-dihydrolo-1H-indene] -1H-pyrazole-4-carboxamide, (15.123) 1,3-dimethyl-N-[(3S) -1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl]- 1H-pyrazole-4-carboxamide, (15.124) [3- (4-chloro-2-fluorophenyl) -5- (2,4-difluorophenyl) -1,2-oxazol-4-yl] (pyridine -3-yl) methanol, (15.125) (S)-[3- (4-chloro-2-fluorophenyl) -5- (2,4-difluorophenyl) -1,2-oxazol-4-yl ] (Piriji N-3-yl) methanol, (15.126) (R)-[3- (4-chloro-2-fluorophenyl) -5- (2,4-difluorophenyl) -1,2-oxazole-4- Yl] (pyridin-3-yl) methanol, (15.127) 2-{[3- (2-chlorophenyl) -2- (2,4-difluorophenyl) oxiran-2-yl] methyl} -2,4 -Dihydro-3H-1,2,4-triazol-3-thione, (15.128) 1-{[3- (2-chlorophenyl) -2- (2,4-difluorophenyl) oxiran-2-yl] Methyl} -1H-1,2,4-triazol-5-ylthiocyanate, (15.129) 5- (allylsulfanyl) -1-{[3- (2-chlorophenyl) -2- (2,4-difluoro) Phenyl) Silan-2-yl] methyl} -1H-1,2,4-triazole, (15.130) 2- [1- (2,4-dichlorophenyl) -5-hydroxy-2,6,6-trimethylheptane- 4-yl] -2,4-dihydro-3H-1,2,4-triazol-3-thione, (15.131) 2-{[rel (2R, 3S) -3- (2-chlorophenyl) -2] -(2,4-Difluorophenyl) oxiran-2-yl] methyl} -2,4-dihydro-3H-1,2,4-triazol-3-thione, (15.132) 2-{[rel (2R , 3R) -3- (2-Chlorophenyl) -2- (2,4-difluorophenyl) oxiran-2-yl] methyl} -2,4-dihydro-3H-1,2,4-triazole-3-thione , (15.133) 1-{[ (2R, 3S) -3- (2-chlorophenyl) -2- (2,4-difluorophenyl) oxiran-2-yl] methyl} -1H-1,2,4-triazol-5-ylthiocyanate, (15 .134) 1-{[rel (2R, 3R) -3- (2-chlorophenyl) -2- (2,4-difluorophenyl) oxiran-2-yl] methyl} -1H-1,2,4-triazole -5-yl thiocyanate, (15.135) 5- (allylsulfanyl) -1-{[rel (2R, 3S) -3- (2-chlorophenyl) -2- (2,4-difluorophenyl) oxirane-2 -Yl] methyl} -1H-1,2,4-triazole, (15.136) 5- (allylsulfanyl) -1-{[rel (2R, 3R) -3- (2-chlorophenyl) -2- ( Two , 4-Difluorophenyl) oxiran-2-yl] methyl} -1H-1,2,4-triazole, (15.137) 2-[(2S, 4S, 5S) -1- (2,4-dichlorophenyl) -5-hydroxy-2,6,6-trimethylheptan-4-yl] -2,4-dihydro-3H-1,2,4-triazol-3-thione, (15.138) 2-[(2R, 4S, 5S) -1- (2,4-Dichlorophenyl) -5-hydroxy-2,6,6-trimethylheptan-4-yl] -2,4-dihydro-3H-1,2,4-triazole-3 -Thion, (15.139) 2-[(2R, 4R, 5R) -1- (2,4-dichlorophenyl) -5-hydroxy-2,6,6-trimethylheptan-4-yl] -2,4 -Dihydro-3H-1,2,4-to Azol-3-thione, (15.140) 2-[(2S, 4R, 5R) -1- (2,4-dichlorophenyl) -5-hydroxy-2,6,6-trimethylheptan-4-yl]- 2,4-dihydro-3H-1,2,4-triazole-3-thione, (15.141) 2-[(2S, 4S, 5R) -1- (2,4-dichlorophenyl) -5-hydroxy- 2,6,6-Trimethylheptan-4-yl] -2,4-dihydro-3H-1,2,4-triazol-3-thione, (15.142) 2-[(2R, 4S, 5R)- 1- (2,4-dichlorophenyl) -5-hydroxy-2,6,6-trimethylheptan-4-yl] -2,4-dihydro-3H-1,2,4-triazol-3-thione, (15 .143) 2-[(2R, 4R, 5S) 1- (2,4-dichlorophenyl) -5-hydroxy-2,6,6-trimethylheptan-4-yl] -2,4-dihydro-3H-1,2,4-triazol-3-thione, (15 144) 2-[(2S, 4R, 5S) -1- (2,4-dichlorophenyl) -5-hydroxy-2,6,6-trimethylheptan-4-yl] -2,4-dihydro-3H-. 1,2,4-triazole-3-thione, (15.145) 2-fluoro-6- (trifluoromethyl) -N- (1,1,3-trimethyl-2,3-dihydro-1H-indene- 4-yl) benzamide, (15.146) 2- (6-benzylpyridin-2-yl) quinazoline, (15.147) 2- [6- (3-fluoro-4-methoxyphenyl) -5-methylpyridine -2-yl] Nazoline, (15.148) 3- (4,4-difluoro-3,3-dimethyl-3,4-dihydroisoquinolin-1-yl) quinoline, (15.149) abscisic acid.

  All the listed mixing partners of classes (1) to (15) can form salts with suitable bases or acids, if their functional groups allow this.

  Examples of insecticides / acaricides / nematicides in mixed formulations or tank mixes defined herein by their "generic name" that can be used in the control step are known and include, for example, the Pesticide Manual ( "The Pesticide Manual", 14th Ed., British Crop Protection Council 2006) or can be searched on the internet (eg, http://www.alanwood.net/pestides).

  (1) Inhibitors of acetylcholinesterase (AChE) such as carbamates such as arnalicarb, aldicarb, benzidocarb, benfulacarb, butocarboxyme, butoxycarboxyme, carbaryl, carbofuran, carbosulfan, etiophencarb, fenocarb, formetate, fratiocarb, isoprocarb. , Methiocarb, Methomyl, Metolcarb, Oxamyl, Pirimicarb, Propoxur, Thiodicarb, Thiofanox, Triazamate, Trimetacarb, XMC and Xylylcarb; Chlorfenvinphos, chlormephos, chlorpyrifos Chlorpyrifos-methyl, coumaphos, cyanophos, demeton-S-methyl, diazinone, dichlorvos / DDVP, dicrotophos, dimethoate, dimethylvinphos, disulfoton, EPN, ethione, etoprophos, fanfer, fenamiphos, fenitrothion, phenthion, fosthiazate, heptenophos, imitophos. , Isofenphos, isopropyl O- (methoxyaminothio-phosphoryl) salicylate, isoxathione, melathion, mecarbam, methamidophos, methidathione, mevinphos, monocrotophos, nared, ometoate, oxydemeton-methyl, parathione, parathione-methyl, fentoate, folates, hosalon, Phosmet, phosphanidone, foskim, pirimiphos-methyl, profenofos Puropetamuhosu, prothiofos, pyraclofos, pyridaphenthion, quinalphos, sulfotep, tebupirimfos, temephos, terbufos, tetrachlorvinphos, thiometon, triazophos, trichlorfon and vamidothion.

  (2) GABAergic chloride channel antagonists such as cyclodiene organochlorins such as chlordane and endosulfan; or phenylpyrazoles (fiprol) such as ethiprole and fipronil.

  (3) Sodium channel modulators / membrane voltage-dependent sodium channel blockers, such as pyrethroids, for example, acrinathrin, allethrin, d-cis-transalletrin, d-transallethrin, bifenthrin, bioarethrin, bioallethrin S-cyclopentenyl isomerism Body, bioresmethrin, cycloprothrin, cyfluthrin, β-cyfluthrin, cyhalothrin, λ-cyhalothrin, γ-cyhalothrin, cypermethrin, α-cypermethrin, β-cypermethrin, θ-cypermethrin, ζ-cypermethrin, cyphenothrin [ (1R) -trans isomer], deltamethrin, empentrin [(EZ)-(1R) isomer), esfenvalerate, etofenprox, fenpropatorin, fenvalerate, Lucitrinate, flumethrin, τ-fluvalinate, halfenprox, imiprothrin, cadethrin, permethrin, phenothrin [(1R) -trans isomer], prarethrin, pyrethrin (Jew eucalyptus), resmethrin, cilafluofen, tefluthrin, tetramethrin, tetramethrin [(1R)]. Isomers)], tralomethrin and transfluthrin; or DDT; or methoxychlor.

  (4) Nicotinic acetylcholine receptor (nAChR) agonists such as neonicotinoids such as acetamiprid, clothianidin, dinotefuran, imidacloprid, nitenpyram, thiacloprid and thiamethoxam; or nicotine; or sulfoxaflor.

  (5) Nicotinic acetylcholine receptor (nAChR) allosteric activators, such as spinosyns, eg spinetoram and spinosad.

  (6) Chloride channel activators such as avermectins / milbemycins such as abamectin, emamectin benzoate, lepimectin and milbemectin.

  (7) Juvenile hormone mimics, such as juvenile hormone analogs, such as hydroprene, quinoprene and methoprene; or phenoxycarb; or pyriproxyfen.

  (8) Various non-specific (multi-site) inhibitors such as alkyl halides such as methyl bromide and other alkyl halides; or chloropicrin; or sulfuryl fluoride; or borax; stone.

  (9) Selective homophyte feeding blockers, eg pymetrozine; or flonicamid.

  (10) Mite growth inhibitors such as clofentezine, hexithiazox and difrovidadine; or etoxazole (11) Microbial destroyers of insect midgut membranes such as Bacillus thuringiensis subspecies Islaelensis (bacillus thuringiensis subspecies). israelensis), Bacillus thuringiensis subis var. subspecies tenebrionis) and B. t. Crop proteins: Cry1Ab, Cry1Ac, Cry1Fa, Cry1A. 105, Cry2Ab, Vip3A, mCry3A, Cry3Ab, Cry3Bb, Cry34 Ab1 / 35Ab1; or Bacillus sphaericus.

  (12) Inhibitors of mitochondrial ATP synthase such as diafenthiuron; or organotin acaricides such as azocyclotin, cyhexatin, and fenbutatin oxide; or propargite; or oxidative by disruption of the tetradiphone (13) proton gradient. Phosphorylated uncouplers such as chlorfenapyr, DNOC and sulfamide.

  (14) Nicotinic acetylcholine receptor (nAChR) channel blockers such as bensultap, cartap hydrochloride, thiocyclam and thiosultap-sodium.

(15) Inhibitors of chitin biosynthesis (type 0), for example, bistrifluron, chlorfluazuron, diflubenzuron, flucycloxuron, flufenoxuron, hexaflumuron, rufenuron, novalron, noviflumuron, teflubenzuron and Triflumuron.

  (16) An inhibitor of chitin biosynthesis (type 1), for example, buprofezin.

  (17) Molting and destroying agents such as cypromazine.

  (18) Ecdysone receptor agonists such as chromafenozide, halofenozide, methoxyfenozide and tebufenozide.

  (19) Octopamine receptor agonists such as amitraz.

  (20) Mitochondrial complex III electron transfer inhibitor, for example, hydramethylnon; or acequinocyl; or fluacrypirim.

  (21) Mitochondrial complex I electron transfer inhibitors such as METI acaricides such as fenazaquin, fenpyroximate, pyrimidifen, pyridaben, tebufenpyrad and tolfenpyrad; or rotenone (Dellis).

  (22) Voltage-gated sodium channel blockers, such as indoxacarb; or metaflumizone.

  (23) Inhibitors of acetyl-CoA carboxylase, such as tetronic acid and tetramic acid derivatives, such as spirodiclofen, spiromesifen and spirotetramat.

  (24) Mitochondrial complex IV electron transfer inhibitors such as phosphines such as aluminum phosphide, calcium phosphide, phosphine and zinc phosphide; or cyanide.

  (25) Mitochondrial complex II electron transfer inhibitors such as β-ketonitrile derivatives such as cienopyraphen and cyflumethofen.

  (28) Ryanodine receptor modulators such as diamides such as chlorantraniliprole and fulvendiamide.

Another active ingredient whose mechanism of action is unknown or unclear, for example, amidoflumet, azadirachtin, benclothiaz, benzoximate, bifenazate, bromopropylate, quinomethionate, cryolite, dicofol, difrovidazine, fluenesulfone, fluphenerim, flu Fiprol, fluopyram, fufenozide, imidacrotiz, iprodione, meperfluthrin, pyridalyl, pyrifluquinazone, tetramethylfluthrin and iodomethane; and also Bacillus firmus (including strains CNCMI-1582, such as VOTiVO (TM), BioN), BioN. (But not limited thereto) or one of the following known active compounds: 3-bromo-N- {2-bromo-4-chloro-6-[(1- Cyclopropylethyl) carbamoyl] phenyl} -1- (3-chloropyridin-2-yl) -1H-pyrazole-5-carboxamide (known from WO 2005/077934 pamphlet), 4-{[(6-bromo Pyridin-3-yl) methyl] (2-fluoroethyl) amino} furan-2 (5H) -one (known from WO 2007/115644), 4-{[(6-fluoropyridin-3-yl ) Methyl] (2,2-difluoroethyl) amino} furan-2 (5H) -one (known from WO 2007/115644), 4-{[(2-chloro-1,3-thiazole-5. -Yl) methyl] (2-fluoroethyl) amino} furan-2 (5H) -one (Patent Publication No. WO2007 / 115644) Known from frets), 4-{[(6-chloropyridin-3-yl) methyl] (2-fluoroethyl) amino} furan-2 (5H) -one (known from WO 2007/115644), Flupyradifuron, 4-{[(6-chloro-5-fluoropyridin-3-yl) methyl] (methyl) amino} furan-2 (5H) -one (known from WO 2007/115643 pamphlet), 4- {[(5,6-Dichloropyridin-3-yl) methyl] (2-fluoroethyl) amino} furan-2 (5H) -one (known from WO 2007/115646), 4-{[( 6-chloro-5-fluoropyridin-3-yl) methyl] (cyclopropyl) amino} furan-2 (5H) -one (WO 2007 115643 pamphlet), 4-{[(6-chloropyridin-3-yl) methyl] (cyclopropyl) amino} furan-2 (5H) -one (from EP 0539588 (A) pamphlet). Known), 4-{[(6-chloropyridin-3-yl) methyl] (methyl) amino} furan-2 (5H) -one (known from European Patent Application Publication No. 0539588), {[1- ( 6-chloropyridin-3-yl) ethyl] (methyl) oxide-λ4-sulfanylidene} cyanamide (known from WO 2007/149134 pamphlet) and its diastereomer {[(1R) -1- (6-chloro) Pyridin-3-yl) ethyl] (methyl) oxide-λ4-sulfanylidene} cyanamide (A) and {[(1 ) -1- (6-Chloropyridin-3-yl) ethyl] (methyl) oxide-λ4-sulfanylidene} cyanamide (B) (known from WO 2007/149134 pamphlet) and diastereomer [(R)- Methyl (oxide) {(1R) -1- [6- (trifluoromethyl) pyridin-3-yl] ethyl} -λ4-sulfanylidene] cyanamide (A1) and diastereomer A groups (WO 2010/074747). [(S) -methyl (oxide) {(1S) -1- [6- (trifluoromethyl) pyridin-3-yl] ethyl} -λ4, which is referred to as "(S) -methyl (oxide) {known from WO 2010/074751 pamphlet). -Sulfanilidene] cyanamide (A2), [(R) -methyl (oxide) {(1S) -1- [ 6- (trifluoromethyl) pyridin-3-yl] ethyl} -λ4-sulfanylidene] cyanamide (B1) and the diastereomer B group (from International Publication No. 2010/074747 pamphlet, International Publication No. 2010/074751 pamphlet) [(S) -methyl (oxide) {(1R) -1- [6- (trifluoromethyl) pyridin-3-yl] ethyl} -λ4-sulfanylidene] cyanamide (B2), which is called (known), and 11- ( 4-chloro-2,6-dimethylphenyl) -12-hydroxy-1,4-dioxa-9-azaspiro [4.2.4.2] tetradec-11-en-10-one (WO 2006/089633) No. pamphlet), 3- (4′-fluoro-2,4-dimethylbiphenyl-3-yl) -4-hi Roxy-8-oxa-1-azaspiro [4.5] dec-3-en-2-one (known from WO 2008/067911 pamphlet), 1- {2-fluoro-4-methyl-5- [ (2,2,2-trifluoroethyl) sulfinyl] phenyl} -3- (trifluoromethyl) -1H-1,2,4-triazol-5-amine (known from WO 2006/043635 pamphlet), Afidopyropene (known from WO 2008/066153 pamphlet), 2-cyano-3- (difluoromethoxy) -N, N-dimethylbenzenesulfonamide (known from WO 2006/056433 pamphlet), 2-cyano- 3- (difluoromethoxy) -N-methylbenzenesulfonamide (International Publication No. 2006/1 (Known from No. 00288 pamphlet), 2-cyano-3- (difluoromethoxy) -N-ethylbenzenesulfonamide (known from WO 2005/035486 pamphlet), 4- (difluoromethoxy) -N-ethyl-N-methyl. -1,2-benzothiazol-3-amine 1,1-dioxide (known from WO 2007/057407), N- [1- (2,3-dimethylphenyl) -2- (3,5-) Dimethylphenyl) ethyl] -4,5-dihydro-1,3-thiazol-2-amine (known from WO 2008/104503 pamphlet), {1 '-[(2E) -3- (4-chlorophenyl). Prop-2-en-1-yl] -5-fluorospiro [indole-3,4'-piperidine] -1 (2H)- Ru} (2-chloropyridin-4-yl) methanone (known from WO 2003/106457 pamphlet), 3- (2,5-dimethylphenyl) -4-hydroxy-8-methoxy-1,8-diazaspiro [4.5] Dec-3-en-2-one (known from WO 2009/049851 pamphlet), 3- (2,5-dimethylphenyl) -8-methoxy-2-oxo-1,8- Diazaspiro [4.5] dec-3-en-4-ylethyl carbonate (known from WO 2009/049851 pamphlet), 4- (but-2-yn-1-yloxy) -6- (3,5 -Dimethylpiperidin-1-yl) -5-fluoropyrimidine (known from WO 2004/099160 pamphlet), (2,2,3,3,4,4) , 5,5-Octafluoropentyl) (3,3,3-trifluoropropyl) malononitrile (known from WO 2005/063094 pamphlet), (2,2,3,3,4,4,5,5) -Octafluoropentyl) (3,3,4,4,4-pentafluorobutyl) malononitrile (known from WO 2005/063094 pamphlet), 8- [2- (cyclopropylmethoxy) -4- (trifluoro) Methyl) phenoxy] -3- [6- (trifluoromethyl) pyridazin-3-yl] -3-azabicyclo [3.2.1] octane (known from WO 2007/040280 pamphlet), Fromotkin, PF1364 ( CAS registration number: 1204776-60-2) (known from Japanese Patent Publication No. 2010/018586) 5- [5- (3,5-Dichlorophenyl) -5- (trifluoromethyl) -4,5-dihydro-1,2-oxazol-3-yl] -2- (1H-1,2,4-triazole -1-yl) benzonitrile (known from WO 2007/075459), 5- [5- (2-chloropyridin-4-yl) -5- (trifluoromethyl) -4,5-dihydro- 1,2-Oxazol-3-yl] -2- (1H-1,2,4-triazol-1-yl) benzonitrile (known from WO 2007/075459 pamphlet), 4- [5- (3 , 5-Dichlorophenyl) -5- (trifluoromethyl) -4,5-dihydro-1,2-oxazol-3-yl] -2-methyl-N- {2-oxo-2-[(2,2, 2-triff Oroethyl) amino] ethyl} benzamide (known from WO 2005/085216), 4-{[(6-chloropyridin-3-yl) methyl] (cyclopropyl) amino} -1,3-oxazole-2 (5H) -one, 4-{[(6-chloropyridin-3-yl) methyl] (2,2-difluoroethyl) amino} -1,3-oxazol-2 (5H) -one, 4-{[ (6-chloropyridin-3-yl) methyl] (ethyl) amino} -1,3-oxazol-2 (5H) -one, 4-{[(6-chloropyridin-3-yl) methyl] (methyl) Amino} -1,3-oxazol-2 (5H) -one (known from WO 2010/005692 pamphlet), pifluvmid (WO 2002/096882) Known from M. Fret), methyl 2- [2-({[3-bromo-1- (3-chloropyridin-2-yl) -1H-pyrazol-5-yl] carbonyl} amino) -5-chloro-3-. Methylbenzoyl] -2-methylhydrazinecarboxylate (known from WO 2005/085216), methyl 2- [2-({[3-bromo-1- (3-chloropyridin-2-yl) -1H] -Pyrazol-5-yl] carbonyl} amino) -5-cyano-3-methylbenzoyl] -2-ethylhydrazinecarboxylate (known from WO 2005/085216), methyl 2- [2-({[ 3-Bromo-1- (3-chloropyridin-2-yl) -1H-pyrazol-5-yl] carbonyl} amino) -5-cyano-3 Methylbenzoyl] -2-methylhydrazinecarboxylate (known from WO 2005/085216), methyl 2- [3,5-dibromo-2-({[3-bromo-1- (3-chloropyridine- 2-yl) -1H-pyrazol-5-yl] carbonyl} amino) benzoyl] -1,2-diethylhydrazinecarboxylate (known from WO 2005/085216), methyl 2- [3,5-dibromo -2-({[3-Bromo-1- (3-chloropyridin-2-yl) -1H-pyrazol-5-yl] carbonyl} amino) benzoyl] -2-ethylhydrazinecarboxylate (International Publication No. 2005 / No. 085216 pamphlet), (5RS, 7RS; 5RS, 7SR) -1- (6- Lolo-3-pyridylmethyl) -1,2,3,5,6,7-hexahydro-7-methyl-8-nitro-5-propoxyimidazo [1,2-a] pyridine (WO 2007/101369) (Known from pamphlet), 2- {6- [2- (5-fluoropyridin-3-yl) -1,3-thiazol-5-yl] pyridin-2-yl} pyrimidine (WO 2010/006713 pamphlet) Known from No.), 2- {6- [2- (pyridin-3-yl) -1,3-thiazol-5-yl] pyridin-2-yl} pyrimidine (known from WO 2010/006713 pamphlet), 1- (3-chloropyridin-2-yl) -N- [4-cyano-2-methyl-6- (methylcarbamoyl) phenyl] -3-{[5- (trifluoromethyl) -1H-tetrazol-1-yl] methyl} -1H-pyrazole-5-carboxamide (known from WO 2010/069502 pamphlet), 1- (3-chloropyridin-2-yl) -N- [4- Cyano-2-methyl-6- (methylcarbamoyl) phenyl] -3-{[5- (trifluoromethyl) -2H-tetrazol-2-yl] methyl} -1H-pyrazole-5-carboxamide (International Publication No. 2010 / 069502 pamphlet), N- [2- (tert-butylcarbamoyl) -4-cyano-6-methylphenyl] -1- (3-chloropyridin-2-yl) -3-{[5- ( Trifluoromethyl) -1H-tetrazol-1-yl] methyl} -1H-pyrazole-5-carboxamide (International Publication No. 2010 / 69502 pamphlet), N- [2- (tert-butylcarbamoyl) -4-cyano-6-methylphenyl] -1- (3-chloropyridin-2-yl) -3-{[5- (tri (Fluoromethyl) -2H-tetrazol-2-yl] methyl} -1H-pyrazole-5-carboxamide (known from WO 2010/069502 pamphlet), (1E) -N-[(6-chloropyridine-3- Iyl) methyl] -N'-cyano-N- (2,2-difluoroethyl) ethaneimidamine (known from WO 2008/009360), N- [2- (5-amino-1,3,4-) Thiadiazol-2-yl) -4-chloro-6-methylphenyl] -3-bromo-1- (3-chloropyridin-2-yl) -1H-pyrazo -5-carboxamide (known from Chinese Patent No. 1020557925), methyl 2- [3,5-dibromo-2-({[3-bromo-1- (3-chloropyridin-2-yl) -1H- Pyrazol-5-yl] carbonyl} amino) benzoyl] -2-ethyl-1-methylhydrazinecarboxylate (known from WO 2011/049233 pamphlet), heptafluthrin, pyriminostrobin, fluphenoxystrobin and 3-chloro-N2- (2-cyanopropan-2-yl) -N1- [4- (1,1,1,2,3,3,3-heptafluoropropan-2-yl) -2-methylphenyl ] Phthalamide (known from WO 2012/034472 pamphlet).

  Examples of microorganisms in a mixed preparation or tank mix that can be used in the control process.

  The microorganisms of the invention, which are well tolerated from the environment in combination with good plant tolerance and virulence favoring warm-blooded animals, protect the plants and plant organs and thus increase the yield, thus improving the quality of the harvested material. Animal pests, in particular insects, arachnids, helminths, nematodes and mollusks encountered in order to improve and in the fields of agriculture, horticulture, livestock, forests, gardens and leisure facilities, protection of stored products and substances and hygiene. Suitable for controlling. These can preferably be used as plant protection agents. They are active against normally sensitive and resistant species, as well as against all or some stages of development. The above-mentioned microorganisms include microorganisms derived from the bacterial domain, microorganisms derived from the fungal domain, insecticidal microorganisms derived from the protozoan domain, insecticidal microorganisms derived from the viral domain, and microorganisms derived from the entomopathogenic nematode domain.

  The following groups of compounds are considered, for example, as safeners: S1) Compounds of the group of heterocyclic carboxylic acid derivatives: S1a) Compounds of the type dichlorophenylpyrazoline-3-carboxylic acid (S1a), preferably international publications. 1- (2,4-dichlorophenyl) -5- (ethoxycarbonyl) -5-methyl-2-pyrazoline-3-carboxylic acid, ethyl 1- (2,4) described in No. 91/07874 (A) pamphlet. -Dichlorophenyl) -5- (ethoxycarbonyl) -5-methyl-2-pyrazoline-3-carboxylate (S1-1) ("mefenpyr- (diethyl)"), and related compounds; S1b) dichlorophenylpyrazolecarvone Derivatives of acids (S1b), preferably European Patent Application No. 333131 (A) and No. 26. 806 (A), for example, ethyl 1- (2,4-dichlorophenyl) -5-methylpyrazole-3-carboxylate (S1-2), ethyl 1- (2,4-dichlorophenyl) -5. Compounds such as -isopropylpyrazole-3-carboxylate (S1-3), ethyl 1- (2,4-dichlorophenyl) -5- (1,1-dimethylethyl) pyrazole-3-carboxylate (S1-4) and Related compounds; S1c) Derivatives of 1,5-diphenylpyrazole-3carboxylic acid (S1c), preferably eg ethyl 1- (2,4-dichlorophenyl as described in European patent application 268554 (A). ) -5-Phenylpyrazole-3-carboxylate (S1-5), methyl 1- (2-chlorophenyl) -5- Compounds such as phenylpyrazole-3-carboxylate (S1-6) and related compounds; S1d) Compounds of the type of triazolecarboxylic acid (S1d), preferably European Patent Application No. 174562 (A) and No. 346620. (A) the phenchlorazole (-ethyl) described in the specification, namely ethyl 1- (2,4-dichlorophenyl) -5-trichloromethyl- (1H) -1,2,4-triazole-3-carboxy. Slate (S1-7) compounds and related compounds; S1e) 5-benzyl- or 5-phenyl-2-isoxazoline-3-carboxylic acid or 5,5-diphenyl-2-isoxazoline-3carboxylic acid type compounds (S1e) ), Preferably ethyl as described in WO 91/08202 (A) 5- (2,4-dichlorobenzyl) -2-isoxazoline-3-carboxylate (S1-8) or ethyl 5-phenyl-2-isoxazoline-3-carboxylate (S1-9) compound and related compounds, 5, 5-diphenyl-2-isoxazolinecarboxylic acid (S1-10) or ethyl 5,5-diphenyl-2-isoxazolinecarboxylate (S1-11) (“isoxadiphen-ethyl”) or n-propyl 5,5 -Diphenyl-2-isoxazoline carboxylate (S1-12) or ethyl 5- (4-fluorophenyl) -5-phenyl-2-isoxazoline-3 described in WO 95/07897 (A) pamphlet. -Carboxylate (S1-13).

  S2) Compounds of the group of 8-quinolineoxy derivatives (S2): S2a) Compounds of the type of 8-quinolineoxyacetic acid (S2a), preferably European Patent Application No. 86750 (A), No. 94349 (A). 1-Methylhexyl (5-chloro-8-quinolineoxy) acetate (generic name "Cloquintocet-") described in the specification and No. 191736 (A) or No. 0492366 (A). "Mexyl" (S2-1), 1,3-dimethyl-but-1-yl (5-chloro-8-quinolineoxy) acetate (S2-2), 4-allyloxybutyl (5-chloro-8-quinolineoxy) ) Acetate (S2-3), 1-allyloxyprop-2-yl (5-chloro-8-quinolineoxy) acetate (S2-4), ethyl (5-chloro-8) Quinolineoxy) acetate (S2-5), methyl (5-chloro-8-quinolineoxy) acetate (S2-6), allyl (5-chloro-8-quinolineoxy) acetate (S2-7), 2- (2 -Propylideneiminooxy) -1-ethyl (5-chloro-8-quinolineoxy) acetate (S2-8), 2-oxo-prop-1-yl (5-chloro-8-quinolineoxy) acetate (S2- 9) and related compounds, as well as (5-chloro-8-quinolineoxy) acetic acid (S2-10), hydrates and salts thereof, as described in EP 2002/34048 (A). , Its lithium, sodium, potassium, calcium, magnesium, aluminum, iron, ammonium, quaternary ammonium, sulfonium or phosphorus. Fonium salt; S2b) (5-chloro-8-quinolineoxy) malonic acid type compound (S2b), preferably diethyl (5-chloro-8) as described in European patent application 0582198 (A). -Compounds such as quinolineoxy) malonate, diallyl (5-chloro-8-quinolineoxy) malonate, methylethyl (5-chloro-8-quinolineoxy) malonate compounds and related compounds.

  S3) Active compounds of the type of dichloroacetamide (soil-acting safeners) (S3) often used as pre-emergence safeners, eg "dichlormide" (N, N-diallyl-2,2-). Dichloroacetamide) (S3-1), "R-29148" (3-dichloroacetyl-2,2,5-trimethyl-1,3-oxazolidine manufactured by Stauffer) (S3-2), "R manufactured by Stauffer". 28725 "(3-dichloroacetyl-2,2-dimethyl-1,3-oxazolidine) (S3-3)," benoxacol "(4-dichloroacetyl-3,4-dihydro-3-methyl-2H-1, 4-benzoxazine) (S3-4), “PPG-1292” (N-allyl-N-[(1,3-dioxo) manufactured by PPG Industries, Inc. (N-2-yl) methyl] dichloroacetamide) (S3-5), "DKA-24" (N-allyl-N-[(allylaminocarbonyl) methyl] dichloroacetamide) (S3-6) manufactured by Sagro-Chem. ), Nitrochemia or Monsanto "AD-67" or "MON4660" (3-dichloroacetyl-1-oxa-3-aza-spiro [4,5] decane) (S3-7), TRI-Chemical RT. "TI-35" (1-dichloroacetylazepane) (S3-8) manufactured by the company, "diclonone" (dicyclonone) or "BAS145138" or "LAB145138" (S3-9) manufactured by BASF ((RS)- 1-Dichloroacetyl-3,3,8a-trimethylperhydropyrrolo [1,2-a] pyrimidine-6- ), "Frilazole" or "MON13900" ((RS) -3-dichloroacetyl-5- (2-furyl) -2,2-dimethyloxazolidine) (S3-10) and further its (R) -isomer ( S3-11).

S4) The compounds of the acylsulfonamide classes (S4): S4 ^a) is the formula ^(S4 a described in WO 97/45016 (A) pamphlet):

(In the formula, RA1 is (C1-C6) -alkyl, (C3-C6) -cycloalkyl, and the last two radicals are halogen, (C1-C4) -alkoxy, and halo- (C1-C6) -alkoxy. And (C1-C4) -alkylthio is substituted with a vA substituent from the group consisting of, and in the case of a cyclic radical, further (C1-C4) -alkyl and (C1-C4) -haloalkyl; RA2 is halogen; (C1-C4) -alkyl, (C1-C4) -alkoxy, CF3; mA is 1 or 2; vD is 0, 1, 2 or 3) and N-acyl sulfonamides thereof Salt, S4b) Formula (S4b) described in WO 99/16744 (A):

  (In the formula, RB1 and RB2 are independently of each other hydrogen, (C1-C6) -alkyl, (C3-C6) -cycloalkyl, (C3-C6) -alkenyl, (C3-C6) -alkynyl and RB3 is halogen, (C1-C4) -alkyl, (C1-C4) -haloalkyl, or (C1-C4) -alkoxy, mB is 1 or 2) benzamide type compounds and salts thereof , RB1 = cyclopropyl, RB2 = hydrogen and (RB3) = 2-OMe (“cyprosulfamide”, S4-1), RB1 = cyclopropyl, RB2 = hydrogen and (RB3) = 5-Cl -2-OMe (S4-2), RB1 = ethyl, RB2 = hydrogen and (RB3) = 2-OMe (S4-3), RB1 = isopropyl, RB2 = hydrogen and (RB3) = 5-Cl-2-OMe (S4-4) and RB1 = isopropyl, RB2 = hydrogen and (RB3) = 2-OMe (S4-5) 4- (benzoylsulfamoyl) compound and its salt.

S4 ^c ) Formula (S4 ^c ), described in European Patent Application No. 365485 (A):

(Wherein RC1 and RC2 independently of one another are hydrogen, (C1-C8) -alkyl, (C3-C8) -cycloalkyl, (C3-C6) -alkenyl, (C3-C6) -alkynyl and RC3 is halogen, (C1-C4) -alkyl, (C1-C4) -alkoxy, CF3, and mC is 1 or 2) compounds of the benzoylsulfamoylphenylurea class, for example, 1- [4- (N-2-methoxybenzoylsulfamoyl) phenyl] -3-methylurea, 1- [4- (N-2-methylbenzoylsulfamoyl) phenyl] -3,3-dimethylurea, 1 -[4- (N-4,5-Dimethylbenzoylsulfamoyl) phenyl] -3-methylurea, S4d) For example, Chinese Patent No. 101828227. It is known, formula (S4d):

  (In the formula, RD4 is halogen, (C1-C4) -alkyl, (C1-C4) -alkoxy, CF3; mD is 1 or 2; RD5 is hydrogen, (C1-C6) -alkyl , (C3-C6) -cycloalkyl, (C2-C6) -alkenyl, (C2-C6) -alkynyl, (C5-C6) -cycloalkenyl) N-phenylsulfonyl terephthalamide type compounds and Its salt.

  S5) Active compounds (S5) of the class of hydroxyaromatic and araliphatic carboxylic acid derivatives, for example described in WO 2004/084631, WO 2005/015994 and WO 2005/016001. Ethyl 3,4,5-triacetoxybenzoate, 3,5-dimethoxy-4-hydroxybenzoic acid, 3,5-dihydroxybenzoic acid, 4-hydroxysalicylic acid, 4-fluorosalicylic acid, 2-hydroxycinnamic acid, 2, 4-dichlorocinnamic acid.

  S6) Active compounds of the class of 1,2-dihydroquinoxalin-2-one (S6), for example 1-methyl-3- (2-thienyl) -described in WO 2005/112630 (A). 1,2-dihydroquinoxalin-2-one, 1-methyl-3- (2-thienyl) -1,2-dihydroquinoxaline-2-thione, 1- (2-aminoethyl) -3- (2-thienyl) -1,2-Dihydroquinoxalin-2-one hydrochloride, 1- (2-methylsulfonylaminoethyl) -3- (2-thienyl) -1,2-dihydroquinoxalin-2-one.

  S7) Compounds of the class of diphenylmethoxyacetic acid derivatives described in WO 98/38856 (S7), for example, methyldiphenylmethoxyacetic acid (CAS registration number: 41858-19-9) (S7-1), Ethyldiphenylmethoxyacetic acid or diphenylmethoxyacetic acid.

S8) Formula (S8) described in the pamphlet of International Publication No. 98/27049 (A):

  (Wherein the symbols and indices have the following meanings: RD1 is halogen, (C1-C4) -alkyl, (C1-C4) -haloalkyl, (C1-C4) -alkoxy, (C1-C4) -halo. Alkoxy, RD2 is hydrogen or (C1-C4) -alkyl, RD3 is hydrogen, (C1-C8) -alkyl, (C2-C4) -alkenyl, (C2-C4) -alkynyl or aryl ( Wherein each of the above carbon-containing radicals is unsubstituted or substituted with one or more, preferably up to 3, identical or different radicals from the group consisting of halogen and alkoxy), and nD is , An integer of 0 to 2) or a salt thereof.

  S9) Active compounds (S9) from the class of 3- (5-tetrazolylcarbonyl) -2-quinolones described in WO 1999/000020 (A), eg 1,2-dihydro-. 4-Hydroxy-1-ethyl-3- (5-tetrazolylcarbonyl) -2-quinolone (CAS registration number: 219479-18-2), 1,2-dihydro-4-hydroxy-1-methyl-3- (5-Tetrazolylcarbonyl) -2-quinolone (CAS Registry Number: 95855-00-8).

S10) WO 2007/023719 (A) pamphlet and is the formula described in the first 2007/023764 (A) pamphlet (S10 ^a) or ^(S10 b):

  (Wherein RE1 is halogen, (C1-C4) -alkyl, methoxy, nitro, cyano, CF3, OCF3, YE, ZE are, independently of each other, O or S, and nE is 0. Is an integer from 4 to 4, RE2 is (C1-C16) -alkyl, (C2-C6) -alkenyl, (C3-C6) -cycloalkyl, aryl; benzyl, halobenzyl, RE3 is hydrogen or (C1 A compound of -C6) -alkyl).

  S11) Active compounds of the type of oximino compounds known as seed dressings (S11), eg "oxabetrinyl" ((Z) -1,3-dioxolan-2-ylmethoxyimino (phenyl) for millet against metolachlor damage. ) Acetonitrile) (S11-1), "fluxophenim" (1- (4-chlorophenyl) -2,2,2-trifluoro-1-ethanone O- () known as seed dressing for millet against metolachlor. 1,3-dioxolan-2-ylmethyl) oxime) (S11-2), and "ciometrinil" or "CGA-43089" ((Z) -cyanomethoxyimino) known as seed dressing for millet against metolachlor. (Phenyl) acetonitrile) (S11-3).

  S12) Active compounds of the class of the isothiochromanones (S12), eg methyl [(3-oxo-1H-2-benzothiopyran-4 (3H) -ylidene) from WO 1998/13361 (A). Methoxy] acetate (CAS registration number: 205121-04-6) (S12-1) and related compounds.

  S13) One or more compounds from the following group (S13): "Naphthalic anhydride" (1,8-naphthalenedicarboxylic anhydride, known as seed dressing for corn against thiocarbamate herbicide damage. ) (S13-1), "fenchlorim" (4,6-dichloro-2-phenylpyrimidine) (S13-2), known as a safener for pretilachlor in planted rice, against alachlor and metolachlor damage. "Flurazole" (benzyl 2-chloro-4-trifluoromethyl-1,3-thiazole-5-carboxylate) (S13-3), which is known as a seed dressing toxicity mitigator for ticks, against imidazoline damage Known as a safener for corn, manufactured by American Cyanamid. L 304415 "(CAS registration number: 31541-57-8) (4-carboxy-3,4-dihydro-2H-1-benzopyran-4-acetic acid) (S13-4), known as a safener for corn. "MG 191" (CAS registration number: 96420-72-3) (2-dichloromethyl-2-methyl-1,3-dioxolane) (S13-5) manufactured by Nitrochemia, and "MG manufactured by Nitrochemia". 838 "(CAS registration number: 133993-74-5) (2-propenyl 1-oxa-4-azaspiro [4.5] decane-4-carbodithioate) (S13-6)," disulfoton "(0.0) -Diethyl S-2-ethylthioethyl phosphorodithioate) (S13-7), "dietolate" (O, O-diethyl O-phenylphohate Sphorothioate) (S13-8), "Mephenate" (4-chlorophenylmethyl carbamate) (S13-9).

  S14) Active compounds which, in addition to herbicidal action on harmful plants, also have a safener action on crop plants such as rice, for example "dimepiperate" or "dimepiperate", which is known as a safener for rice plants against molinate herbicide damage. MY93 "(S-1-methyl-1-phenylethylpiperidine-1-carbothioate), an imazosulfuron known as a safener for rice against damage to herbicides," Daimuron "or" SK23 "(1- ( 1-methyl-1-phenylethyl) -3-p-tolylurea), known as a safener for rice against some herbicide damage, “cumyluron” = “JC940” (3- (2-chlorophenyl) Methyl) -1- (1-methyl-1-phenylethyl) urea, see JP-A-60-0887254), partly "Methoxyphenone" or "NK049" (3,3'-dimethyl-4-methoxybenzophenone), which is known as a safener for rice against herbicide damage, a safener for some herbicide damage in rice Known as "CSB" (1-Bromo-4- (chloromethylsulfonyl) benzene) from Kumiai (CAS Registry Number 54091-06-4).

S15) Formula (S15) described in International Publication No. 2008/131860 (A) pamphlet and No. 2008/131860 (A) pamphlet:

  (In the formula, RH1 is (C1-C6) -haloalkyl, RH2 is hydrogen or halogen, RH3 and RH4 are independently of each other hydrogen, (C1-C16) -alkyl, (C2- C16) -alkenyl or (C2-C16) -alkynyl, where each of the last three radicals is unsubstituted or halogen, hydroxy, cyano, (C1-C4) -alkoxy, (C1-C4). -Haloalkoxy, (C1-C4) -alkylthio, (C1-C4) -alkylamino, di-[(C1-C4) -alkyl] -amino, [(C1-C4) -alkoxy] -carbonyl, [(C1 -C4) -haloalkoxy] -carbonyl, unsubstituted or substituted (C3-C6) -cycloalkyl, unsubstituted or substituted phenyl, and Is substituted with one or more radicals from the group consisting of substituted or substituted heterocyclyl; or (C3-C6) -cycloalkyl at one site of the ring fused with a 4-6 membered saturated or unsaturated carbocycle , (C4-C6) -cycloalkenyl, (C3-C6) -cycloalkenyl, or (C4-C6) -cycloalkenyl at one site of the ring fused with a 4-6 membered saturated or unsaturated carbocycle. At this time, each of the four radicals listed last is unsubstituted or halogen, hydroxy, cyano, (C1-C4) -alkyl, (C1-C4) -haloalkyl, (C1-C4) -alkoxy, ( C1-C4) -haloalkoxy, (C1-C4) -alkylthio, (C1-C4) -alkylamino, di- (C1-C4) -a Kill] -amino, [(C1-C4) -alkoxy] -carbonyl, [(C1-C4) -haloalkoxy] -carbonyl, unsubstituted or substituted (C3-C6) -cycloalkyl, unsubstituted or substituted phenyl, and Unsubstituted or substituted with one or more radicals from the group consisting of heterocyclyl; or RH3 is (C1-C4) -alkoxy, (C2-C4) -alkenyloxy, (C2-C6) -alkynyloxy. Or (C2-C4) -haloalkoxy, and RH4 is hydrogen or (C1-C4) -alkyl, or RH3 and RH4 are, in addition to the N atom, N in addition to the N atom, It may contain a heterocyclic atom from the group consisting of O and S, preferably up to 2 further heterocyclic atoms, and Substituted or consisting of halogen, cyano, nitro, (C1-C4) -alkyl, (C1-C4) -haloalkyl, (C1-C4) -alkoxy, (C1-C4) -haloalkoxy and (C1-C4) -alkylthio. 4-8 membered heterocycle substituted with one or more radicals from the group) or tautomers thereof.

  S16) An active compound which is mainly used as a herbicide but also has a safener action on crop plants, for example, (2,4-dichlorophenoxy) acetic acid (2,4-D), (4-chlorophenoxy) acetic acid , (R, S) -2- (4-chloro-o-tolyloxy) propionic acid (mecoprop), 4- (2,4-dichlorophenoxy) butyric acid (2,4-DB), (4-chloro-o- Trilyloxy) acetic acid (MCPA), 4- (4-chloro-o-tolyloxy) butyric acid, 4- (4-chlorophenoxy) butyric acid, 3,6-dichloro-2-methoxybenzoic acid (dicamba), 1- (ethoxycarbonyl) ) Ethyl 3,6-dichloro-2-methoxybenzoate (lactide dichloro-ethyl).

  Preferred safeners are: cloquintocet-mexyl, cyprosulfamide, fenchlorazole-ethyl, isoxadifen-ethyl, mefenpyr-diethyl, fenchlorim, cumyluron, S4-1 and S4-5, particularly preferred: Cloquintocet-mexyl, cyprosulfamide, isoxadifen-ethyl and mefenpyr-diethyl.

  The following is a limited list of agents that may be used according to the present invention.

  Herbicides: eg, triafamone, tefryltrione, oxadiaargyl, ethoxysulfuron, diimurone Insecticides: eg, imidacloprid Fungicides: eg, isotianil fertilizer: eg, ZnSO4 Toxic mitigants: eg, isoxadifen-ethyl molluscicide: Example: Niclosamide (Bayluscide (R)) biological material: Example, microorganism or signaling molecule; Bacillus subtilis (QST713) (Serenade (R)), Bacillus pumilis (QST2818) ) (Sonata®), a blend of three terpenes (Requiem®) plant tonic compounds and combinations thereof.

  In the liquid preparation of the present invention, one kind of compound (agent) may be used as the agrochemical active ingredient, or a plurality of kinds may be used in combination.

  According to a preferred embodiment, the solution applied by the method of the invention comprises a combination of at least two different compounds selected from the group consisting of herbicides, fungicides, insecticides, molluscicides and fertilizers. ..

  Preferably, the herbicide is selected from the group consisting of oxadiaargyl, triafamone, tefryltrione, fentrazamide, mefenacet, bensulfuron-methyl and pretilachlor; the fungicide is isotianil; the insecticide is imidacloprid; The molluscicide is niclosamide; and the fertilizer is zinc.

  Preferred examples of such combinations of at least two different compounds are: oxadiaargyl and triafamone; oxadiaargyl and tefryltrione; oxadiargyl and tefryltrione and fentrazamide; triafamone and tefryltrione; fentrazamide and tefryltrione; triafamone and fentrazamide and Tefryltrione; mephenaceto and bensulfuron-methyl; pretilachlor and bensulfuron-methyl; triafamon and mephenaceto and bensulfuron-methyl; and trifamon and pretilachlor and bensulfuron-methyl. Even more preferred is the combination of triafamon, tefryltrione and oxadiaargyl; and trifamon, oxadialygyl and bensulfuron-methyl.

  Further preferred examples of liquid formulations containing a combination of at least two different compounds are triafamone and tefryltrione and isotianil; triafamone and tefryltrione and imidacloprid; triafamone and tefryltrione and isotianil and imidacloprid; triafamone and tefryltrione and isothianyl. And niclosamide; selected from the group consisting of triafamone and tefryltrione and isotianil and imidacloprid and niclosamide and triafamone and tefryltrione isotianil and imidacloprid and niclosamide and zinc.

  Particularly preferably, the solution is selected from the group consisting of oxadiaargyl and triafamon; and the group consisting of triafamon and tefryltrione; triafamon, tefryltrione and oxadiaargyl; and the group of three combinations consisting of triafamon, oxadialygyl and bensulfuron-methyl. It contains a combination of at least two different herbicides. Even more particularly preferred, the solution comprises a combination of triafamone and tefryltrione and isotianil. Even more particularly preferred, the solution comprises a combination of triafamone, tefryltrione, isotianil, imidacloprid and niclosamide.

  In the method of the present invention, the liquid preparation may be in the form of various preparations, and specific examples thereof include a liquid preparation (aqueous suspension (flowable, emulsion or wettable powder suspended in water), aqueous solvent). ), AL agents, microcapsules and the like. These formulations are prepared in a manner known per se, for example by mixing the pesticidal active substance with a spreading agent, ie a liquid diluent or carrier, and optionally a surfactant, ie an emulsifier and / or dispersant. Done by In that case, when water is used as a developing agent, for example, an organic solvent can be used as an auxiliary solvent. In the present invention, a flowable is preferable from the viewpoint of workability. As flowable, in addition to the agrochemical active substance, water, surfactant, liquid diluent (organic solvent) and polymer resin, especially acrylic resin (acrylic acid alkyl ester and / or methacrylic acid alkyl ester as a structural unit) Aqueous suspension compositions containing (co) polymer resins) are preferred. If necessary, an antifoaming agent, a preservative, a thickener, a dispersant, an antifreezing agent and the like can be appropriately added to the aqueous suspension composition. The content of the agrochemical active substance in the flowable is preferably 1 to 50 parts by weight, particularly preferably 5 to 40 parts by weight. The content of the surfactant is preferably 0.01 to 10 parts by weight, particularly preferably 0.1 to 5 parts by weight. Further, the content of the diluent is preferably 1 to 50 parts by weight, particularly preferably 5 to 30 parts by weight. The content of the acrylic resin is preferably 0.1 to 20 parts by weight, particularly preferably 1 to 10 parts by weight. With respect to other additive components such as defoaming agents, preservatives and thickeners, the total amount is preferably 0 to 10 parts by weight, more preferably 0 to 5 parts by weight. The polymer resin in the aqueous suspension composition is preferably a granular polymer resin, and particularly preferably a finely divided polymer resin obtained by pulverization treatment or the like.

  Examples of the liquid diluent or carrier include aromatic hydrocarbons (eg, xylene, toluene, alkylnaphthalene, etc.), chlorinated aromatic or chlorinated aliphatic hydrocarbons (eg, chlorobenzenes, ethylene chloride, methylene chloride). Etc.), aliphatic hydrocarbons [eg, cyclohexane, paraffins (eg, mineral oil fractions)], alcohols (eg, C2-C10 alcohols such as butanol, glycols such as ethylene glycol and propylene glycol, and the like). Ethers, esters, etc.), ketones (eg, acetone, methyl ethyl ketone, methyl isobutyl ketone, cyclohexanone, etc.), strong polar solvents (eg, dimethylformamide, dimethyl sulfoxide, etc.), water and the like.

  Examples of the surfactant include nonionic and anionic surfactants [for example, polyoxyethylene fatty acid ester, polyoxyethylene fatty acid alcohol ether (for example, alkylaryl polyglycol ether, alkylsulfonate, alkyl sulfate, aryl Sulfonate), tristylphenol and its ethoxylates], albumin hydrolysis products and the like.

  The dispersant includes, for example, lignin sulfite waste liquid, methyl cellulose and the like.

  Adhesives can also be used in the formulation (powder, granules, emulsions), examples of which include carboxymethyl cellulose, natural and synthetic polymers (eg, gum arabic, polyvinyl alcohol, polyvinyl acetate, etc.). You can

  A colorant can also be used, and examples of the colorant include inorganic pigments (for example, iron oxide, titanium oxide, Prussian blue, etc.), organic dyes such as alizarin dyes, azo dyes, and metal phthalocyanine dyes, and Mention may be made of trace elements such as salts of metals such as iron, manganese, boron, copper, cobalt, molybdenum, zinc and the like.

  The liquid agent used in the method of the present invention and the rice sprayer-mounted liquid agent spraying device can be prepared by diluting the above-mentioned flowable, emulsion, or wettable powder to a predetermined concentration with a diluent such as water.

  The amount of drug sprayed by the rice transplanter-mounted liquid drug spraying device of the present invention can be appropriately adjusted, but is preferably 3 to 100 L / ha, more preferably 5 to 30 L / ha.

  The pesticide formulation according to the embodiment of the present invention can obtain a selective herbicidal effect between paddy rice and paddy field weeds. The following are examples of paddy weeds that can be controlled.

  Dicotyledonous plants of the following genera: Polygonum, Capsicum (Rorippa), Cyperus (Rotala), Genus (Lindernia), Genus (Bidens), Genus Abdomen (Dopatrium), Genus Takaplau (Ecli). The genus Elatine, the giant genus Gratiola, the genus Capsicum (Lindernia), the genus Ludwigia, the genus Oenthe, the genus Ranunculus, and the genus Dwarf pepper (Ranunculus).

  Monocotyledonous plants of the following genera: Echinochloa, Panicum, Poa, Poa, Cyperus, Monochoria, Fimbristya, Soda, Odaka. The genus Eleocharis, the genus Firefly (Sirrpus), the genus Sidioma (Alisma), the genus Anemone (Aneilema), the genus Blyxa, the genus Eriochaula, the genus Potteryra (Potamochia), the genus Potamobiga (Potamochia vulgaris), (Leptochloa), Sphenoclea, rice (Oryza) and the like.

  More specifically, for example, the following representative paddy field weeds can be used.

  Botanical name Latin name Dicotyledonous plant Denjisou Marisilea quadrifolia Hyderico Fimbristylis miliacea Nagabonosumushi Phenoclea zeylanica Species Ammania sp. Yellow sedge Rotala indica Koehne Azena Lindernia procumbens Philcox America Azena Lindernia dubia L. Penn. Taketoazena Lindernia dubia subsp. Dubia Takasaburo Eclipta prostrata Capsicum Lindernia angustifolia Ludwigia prostrata Roxburgh Polygonum sp. American Asteraceae Sesbania exaltata Hirumushiro Potamogeton distinctus A. Benn Elatine triandra Schk Elatine triandra Schk Seri Oenanthe javanica Aeschynomene indica Aeschynomene indica Ukiazena Bacopa rotundifolia Bidens frondosa Bidens frondosa Abunome Dopatrium junceum Ooabunome Gratiola japonica monocots barnyardgrass Echinochloa oryzicola Vasing junglerice Echinochlor colonum Amaranthus lividus E. crus-galli Anemone keisak Paspalum distichum Cogomegayasu Cyperus iria rotundus pine by Eleocharis acicularis L. Eleochris kuroguwai Ohwi Cyperus difformis L. Cyperus serotonus Rottboel Squirrels Sirrpus mucronatus S. planiculmis Scirpus Scirpus juncoides Roxb Taiwan Yamai Scirupus Wallichii Nees Himehotarui Scirupus Lineolatus pulp Scirpus etuberculatus Monochoria Monochoria vaginalis Presl Urigawa Sagittaria pygmaea Miq alisma canaliculatum Alisma canaliculatum A. Br. et Bouche Sidiomodaka Alisma plantago-aquatica var. Oriente Samuels. Omodaka Sagittaria trifolia Water mallow Monochoria korsakowii Azegaya Leptochloa chinensis Tentsuki Fimbristylis bentgrass Agrostis spec. American eel Heteranthera limosa (SW.) WILL Note that the pesticide formulation of the present invention is not limited to use on weeds of these grass species, and may be similarly applied to weeds of other grass species. it can.

  Although the disease contemplated by the method of the present invention is not particularly limited, the liquid agent is, for example, Plasmodiophoromycetes, Oomycetes, Zygomycetes, Ascomycetes, Basidiomycetes. ) And imperfect fungi (Deuteromycetes). In particular, for example, scabbardling disease (Gibberella fujikuroi, Fusarium moniliforme), blast disease, leaf blast disease, panicle blast disease and rot disease (Pyricularia oryzae (i, pyriculaea), Pyriculia (a, pyriculia)). Pyricularia grisea), false black scab (Ustilaginoidea virens), brown spot (Cochliobolus miyabureanus), seedling blight (Branchhordea planta). , Bacterial wilt disease (Burkholderia Gourmet) a glumae)), internal browning disease (Erwinia herbicola), white leaf blight (Pseudomonas oryzae), Xanthomonas oresa (Xanthomonas odorae) ), Pseudomonas arboprecipitans), Bacterial blight (Thanatephorus cucumeris), Rhizoctonia solani (Rizoctonia solani), Mosaic necrotic moss gangrene (Klebsiella vulgaris). Rice grassy stunt virus)), dwarf disease (rice tunguro globular shape) Ils), dwarf disease (rice dwarf virus), rugged stunt (rice ragged stunt virus), transistry yellow dwarf disease (rice transistry yellowing virus), striped leaf blight (rice banded leaf blight virus), black stripe dwarf disease (Rice black stripe dwarf virus), yellow wilt (Phytoplasma), seedling blight (Fusarium sp.), Rhizopus sp., Trichoderma sp., Mucor sp. (Mucor sp.), Phoma sp., Pythium sp.), Strain rot (Erwinia chrysanthemi pv. Zeae (Erwinia chrysanthemi pv. zeae)), sclerotium disease (Magnaporthe salvinii), Helminthosporium sigmoideum), and brown leaf blight (Metasferia albesense). Streak blight (Sphaerulina oryzina), leaf browning (Pseudomonas fuscovaginae), false blast (Alteraria uricae), Alternaria oryzae Cladosporium herbarum), Pseudocochiliobolus lunatus, Pseudocochiliobolus lunatus), brown sclerotium (Ceratobasidium setariae), black scab (Cladosporium herbaum kernel, Cladospora) Helicoceras oryzae, rice blight (Phoma glumarum), leaf rot (sarcocladium oryzae, sarocladium oryzae, Pyrenospora leaf spot, Pyrenosca variae). (Cylindrocladium scoparium m)), diseases caused by phytopathogens such as small black rot (Thanatephorus cucumeris), especially diseases derived from filamentous fungi and / or microorganisms, such as rice blast, brown spot and white leaf blight. The disease can be effectively prevented.

  There is no particular limitation on the harmful insects contemplated by the method of the present invention, but the liquid agents include, for example, rice weevil (Lissophoptrus oryzophilus), rice weevil (Oulema oryzae), rice corn sedge (Parnara guttasa p. (Sirpophaga incerturas), rice yew (Sesamia inferens), Phellinus linteus (Naranga aenecescens), Kobunomeiga (Cnaphaloca tericula serrata), Larva serrata (L.). laparvata lugens), green rice leafhopper (Nephotettix cincticeps), Inekamemushi (Lagynotomus elongatus), rice thrips (Stenchaetothrips biformis), apple snail (Pomacea canaliculata), rice leafminer (Agromyza oryzae), Inemigiwabae (Hydrellia griseola), rice click Kimi Giwa fly (Hydrellia sasakii) , Dirty leaf fly (Notiphila sekiyai), rice leaf fly (Chlorops oryzae), yellow squirrel (Tipula aino), rice fly (Delia plura), weevil (Echi) nocnemus squameus), Inenekuihamushi (Donacia provosti), armyworm (Mythimna separata), Shiromadarakoyaga (Protodeltote distinguenda), Inetatehamaki (Craphalocrocis exigua), wheat constricted aphid (Rhopalosiphum padi), Oka Bono aphid (Rhopalosiphum rufiabdominalis), Inazuma leafhopper (Recilia dorsalis), rice stink bug (Scotinophora lurida), rice stink bug (Cletus punctiger), spider helicopter bug (Leptocorisa chinensis), minamia stink bug (N) ezara viridula), thorns Shirahoshi bug (Eysarcoris aeneus), Shirahoshi stink bug (Eysarcoris ventralis), rice caelestialium (Trigonotylus caelestialium), Naga wheat Kasumi turtle (Stenodema sibiricum), red streaks Kasumi turtle (Stenotus rubrovittatus), Himekusakiri (Ruspolia jezoensis), White-faced Egg (Oxya yezoensis), Rana japonica (Oxya japonica), Rice plant scale insect (Geococcus oryzae), kerula (Gryllotalpa orientalis), rice singale enchu des besseyi), octopus cyst nematode (Heterodera elachista), rice moguri nematode (Hirschmannniella Oryzae), American crayfish (Precambarus clarkii) and the like. In particular, it can effectively prevent rice thrips, white-spotted planthopper, and snail apple snail.

[Example] A 6-row planting rice planter equipped with the rice planter-mounted liquid agent spraying device of the present invention was subjected to a spraying test in the following manner under the conditions shown in Table 1 below, and a spraying test was conducted at a later date. It was observed what kind of effect appeared in the rice field.

  (Test 1) 72 g of oxadiaargyl single agent was applied per hectare according to the following three procedures.

  (A) 1 drop per 5 rows between stocks: 6 rows of 6 row ridges planted by a 6-row planting machine have 5 rows between stocks. Among the 5 rows of the stocks, the liquid agent was dropped only in the 1st row between the stocks (drop between stocks).

  (B) Drop between 3 strains per 5 rows between stocks: Among the stocks in 5 rows, the liquid was dropped between the stocks in the center and between the stocks at both ends with one stock sandwiched between the stocks in the center, in total 3 stocks ( Drop between 3 strains).

  (C) Drop between 5 stocks per 5 rows between stocks: The liquid agent was dropped onto all the stocks in 5 rows (dropping between 5 stocks).

Thereafter, the results of observing the effect of spraying the liquid agent for each kind of weeds are shown in Table 2 below.

(Test 2) 36 g of oxadiaargyl single agent per hectare was sprayed in the three manners (A) to (C) above. Table 3 below shows the results of observing the effect of spraying the liquid agent for each type of weed.

(Test 3) 36 g of oxadiaargyl per hectare and 36 g of triafamon per hectare were mixed and sprayed in the three manners (A) to (C) above. Table 4 below shows the results of observing the effect of spraying the liquid agent for each type of weed.

(Test 4) 36 g of oxadiaargyl per hectare and 72 g of tefryltrione per hectare were mixed and sprinkled in the above three ways (A) to (C). Table 5 below shows the results of observing the effect of spraying the liquid agent for each type of weed.

(Test 5) 36 g of oxadiaargyl per hectare, 72 g of tefryltrione per hectare, and 100 g of fentrazamide per hectare were mixed, and sprayed in the three manners (A) to (C) above. did. Table 6 below shows the results of observing the effect of spraying the liquid agent for each type of weed.

(Test 6) 36 g of triafamone per hectare and 72 g of tefryltrione per hectare were mixed and sprayed in the three manners (A) to (C) above. Table 7 below shows the results of observing the effects of liquid agent spraying for each type of weed.

(Test 7) Fentrazamide (150 g per hectare) and Tefryltrione (150 g per hectare) were mixed and sprayed in the three manners (A) to (C). Table 8 below shows the results of observing the effect of spraying the liquid agent for each type of weed.

(Test 8) 36 grams of triafamone per hectare, 72 grams of fentrazamide per hectare, and 72 grams of tefryltrione per hectare were mixed, and sprayed in the following three ways (A) to (C). did. Table 9 shows the results of observing the effect of spraying the liquid agent for each type of weeds.

(Test 9) 450 grams of mefenacet per hectare and 27 grams of bensulfuron-methyl per hectare were mixed and sprayed in the three manners (A) to (C) above. Table 10 shows the results of observing the effect of spraying the liquid agent for each type of weed.

(Test 10) 450 g of pretilachlor per hectare and 31.5 g of bensulfuron-methyl per hectare were mixed and sprinkled in the three manners (A) to (C) above. Table 11 shows the results of observing the effect of spraying the liquid agent for each type of weed.

(Test 11) 36 grams of triafamone per hectare, 450 grams of mefenacet per hectare, and 27 grams of bensulfuron-methyl per hectare were mixed, and sprayed in the three manners (A) to (C) above. did. Table 12 shows the results of observing the effect of spraying the liquid agent for each type of weeds.

(Test 12) 36 g of triafamon per hectare, 450 g of pretilachlor per hectare, and 31.5 g of bensulfuron-methyl per hectare were mixed, and the three procedures (A) to (C) above were mixed. It was sprayed with. Table 13 below shows the results of observing the effect of spraying the liquid agent for each type of weed.

  From the observation results of (Test 1) to (Test 12), there is a difference in degree depending on the type of liquid agent sprayed, and by adding the liquid agent to all of the 5 rows of plants, all the weeds to be observed were observed. Proved to be effective.

  Although the preferred embodiment of the present invention has been described above, the present invention is not limited to the above embodiment. Additions, omissions, substitutions, and other changes can be made to the configuration without departing from the spirit of the present invention. The invention is not limited by the above description, but only by the scope of the appended claims.

The rice transplanter-mounted liquid agent spraying device of the present invention was mounted on a six-row rice transplanter, and a spraying test was conducted under the conditions shown in Tables 14 and 15 below. At a later date, it was observed what kind of effect appeared in the rice field where the spraying test was conducted.

  The results of tests 13-22 according to the procedure described in Tables 14 and 15 are listed below. The test results listed in Tables 17-26 are the results from both procedures listed in Tables 14 and 15, except for ELOKU performed according to the procedure in Table 14 only and POMACA performed according to the procedure in Table 15 only. Is the average value of. One drop, three drops and all drops have the same definition as in procedures (A), (B) and (C) above.

The abbreviations and terms used in Tables 17-24 are set forth in Table 16.

(Test 13) The mixture of TRF & TEF was sprayed by 1 drop, 3 drops or whole drop spraying method. The results of observing the effects of Test 13 on various targets are shown in Table 17 below.

(Test 14) IST (isotianil) was sprayed by 1 drop, 3 drops or the whole drop spraying method. The results of observing the effects of Test 14 on various targets are shown in Table 18 below.

(Test 15) IMD (imidacloprid) was sprayed by 1 drop, 3 drops or whole drop spraying method. The results of observing the effects of Test 15 on various targets are shown in Table 19 below.

(Test 16) NCS (niclosamide: bayluscide) was sprayed by 1 drop, 3 drops or whole drop spraying method. The results of observing the effects of Test 16 on various targets are shown in Table 20 below.

(Test 17) A mixture of TRF & TEF + IST (isotianil) was sprayed by 1 drop, 3 drops or all-drops spraying method. The results of observing the effects of Test 17 on various targets are shown in Table 21 below.

(Test 18) A mixture of TRF & TEF + IMD (imidacloprid) was sprayed by 1 drop, 3 drops or whole drop spraying method. The results of observing the effects of Test 18 on various targets are shown in Table 22 below.

(Test 19) A mixture of TRF & TEF + IST (isotianil) + IMD (imidacloprid) was sprayed by 1 drop, 3 drops or the whole drop spraying method. The results of observing the effects of Test 19 on various targets are shown in Table 23 below.

(Test 20) A mixture of TRF & TEF + IST (isotianil) + NCS (niclosamide: bayluscide) was sprayed by 1 drop, 3 drops or all-drops spraying method. The results of observing the effects of Test 20 on various targets are shown in Table 24 below.

(Test 21) A mixture of TRF & TEF + IST (isotianil) + IMD (imidacloprid) + NCS (niclosamide: bayluscide) was sprayed by 1 drop, 3 drops or whole drop spraying method. The results of observing the effects of Test 21 on various targets are shown in Table 25 below.

(Test 22) A mixture of TRF & TEF + IST (isotianil) + IMD (imidacloprid) + NCS (niclosamide: bayluscide) was sprayed by 1 drop, 3 drops or whole drop spraying method. The results of observing the effects of Test 22 on various targets are shown in Table 26 below.

  Test of uniform dropping of liquid by the mechanism shown in FIG.

Conditions: The amount of the liquid agent consisting of water and detergent dropped from each nozzle (the total number of nozzles is 5 in this case) was measured using the liquid agent spraying device mounted on the rice transplanter. One trial consisted of 40 signals from the spray motion controller that were automatically generated in response to a spray rate of 15 L / ha. The amount of liquid agent dropped from each nozzle and their average value, total amount dropped, error, and RSD (error and RSD are defined below) are listed in each row of Table 27 below. One set of trials consisted of three trials, and the average value of each data of the trials as one set is listed in the bottom row of Table 27.

  Nine sets of trials (meaning a total of 27 trials) were repeated in the same way.

The average error of the drop amount of each nozzle in each set (“drop” in Table 28), the average error of the RSD of each nozzle in each set (“RSD” in Table 28), and the trial of each trial in each set The average errors of all the dropped amounts (“total amount” in Table 28) are listed in lines 1 to 9, and their average values are listed in the bottom line.

  The test results listed in Tables 27 and 28 reveal that the rice transplanter-mounted liquid agent spraying device of the present invention can uniformly spray the liquid agent, and the dropping error is 10% or less.

The present invention relates to a rice planter-mounted liquid agent spraying device that can be mounted on a rice transplanter and sprays a liquid agent in synchronization with the rice planting operation by the rice transplanter. ADVANTAGE OF THE INVENTION According to this invention, labor control work can be labor-saving and pesticide application on a medium-scale field and a large-scale field can be attained.

Claims (16)

A valve for adding a resistance to the liquid agent,
A first valve member configured to have a tubular shape and having an upper surface including a slot at one end and an opening at the other end;
A case that receives the first valve member and has an inlet facing the opening of the first valve member and an outlet facing the upper surface of the first valve member;
A second valve member configured to have a tubular shape and having an upper surface including a slot at one end and an opening at the other end, the second valve member engaging the first valve member inside the case, A second valve member in which the upper surface of the two-valve member is arranged at a distance from the upper surface of the first valve member;
Equipped with,
Each of the first valve member and the second valve member,
A first hollow member having a first inner diameter and the upper surface having a first outer diameter larger than the first inner diameter;
A second hollow member connected to the first hollow member, having a second inner diameter larger than both the first inner diameter and the first outer diameter, and having a second outer diameter larger than the first outer diameter; Including,
The first valve member and the second valve member are engaged with each other such that the first hollow member of the second valve member is received and supported inside the second hollow member of the first valve member. A valve, characterized in that it is adapted to fit . Each of the first valve member and the second valve member is a third hollow member connected to the second hollow member and has a third inner diameter larger than both the second inner diameter and the second outer diameter. Further including a third hollow member having a third outer diameter greater than the second outer diameter,
The first valve member and the second valve member are engaged with each other such that the second hollow member of the second valve member is received and supported within the third hollow member of the first valve member. The valve of claim 1 , wherein the valve is configured to mate. Since the outer diameter of the first hollow member of the second valve member is larger than the inner diameter of the first hollow member of the first valve member, the first hollow member of the second valve member is the first valve. The valve according to claim 1 or claim 2 , which is not inserted inside the first hollow member of the member. The valve according to any one of claims 1 to 3 , wherein the first valve member and the second valve member have the same shape as each other. The valve according to any one of claims 1 to 4 , wherein the slot of the first valve member extends radially in the upper surface of the first valve member. The slot of the first valve member is closed when the pressure acting on the liquid agent flowing into the case from the inlet of the case is equal to or smaller than a predetermined magnitude, and the slot flows into the case from the inlet of the case. The valve according to any one of claims 1 to 5 , which opens when the pressure acting on the liquid agent exceeds a predetermined magnitude. 7. The valve according to any one of claims 1 to 6 , wherein the slot of the second valve member extends radially on the upper surface of the second valve member. The slot of the second valve member is closed when the pressure acting on the liquid agent flowing into the case from the inlet of the case is equal to or less than a predetermined magnitude, and flows into the case from the inlet of the case. The valve according to any one of claims 1 to 7 , which opens when the pressure acting on the liquid agent exceeds a predetermined magnitude. The valve according to any one of claims 1 to 8 , wherein the case includes a first case having the inlet and a second case having the outlet. The valve according to claim 9 , wherein the first case and the second case are connected by screwing. The first case has a female screw portion formed on the inner peripheral surface of the first case, and the second case has a female screw portion formed on the outer peripheral surface of the second case. The valve according to claim 10 , wherein the valve has a male screw portion that is screwed. Interposed between the first case and the second case includes an O-ring that seals between mutually between the first case screwed to the second casing, claim 9 The valve according to claim 11 . Even when the slot of the second valve member is opened by trapping a substance,
Amount of liquid agent that flows through the valve in a layer filled with the liquid agent in the region between the upper surface of the first valve member and the upper surface of the second valve member and the slot of the first valve member. The valve according to any one of claims 1 to 12 , which maintains Even when the slot of the first valve member is opened by trapping a substance,
Wherein the slot of the second valve member, to maintain the amount of liquid flowing through the valve, the valve according to any one of claims 1 to 12. A device for discharging a liquid agent,
A pipe having an open end for discharging the liquid agent,
A valve attached to the pipe to add resistance to the liquid agent discharged from the open end toward the ground and control the amount of the liquid agent discharged from the open end,
Equipped with,
The valve
A first valve member configured to have a tubular shape and having an upper surface including a slot at one end and an opening at the other end;
A case that receives the first valve member and has an inlet facing the opening of the first valve member and an outlet facing the upper surface of the first valve member;
A second valve member configured to have a tubular shape and having an upper surface including a slot at one end and an opening at the other end, the second valve member engaging the first valve member inside the case, A second valve member in which the upper surface of the two-valve member is arranged at a distance from the upper surface of the first valve member;
An apparatus comprising: 16. The device of claim 15, wherein the case comprises a first case having the inlet and a second case having the outlet.

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