WO2022152728A1 - Herbicidal compositions - Google Patents
Herbicidal compositions Download PDFInfo
- Publication number
- WO2022152728A1 WO2022152728A1 PCT/EP2022/050502 EP2022050502W WO2022152728A1 WO 2022152728 A1 WO2022152728 A1 WO 2022152728A1 EP 2022050502 W EP2022050502 W EP 2022050502W WO 2022152728 A1 WO2022152728 A1 WO 2022152728A1
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- WO
- WIPO (PCT)
- Prior art keywords
- cas
- methyl
- ene
- amino
- carbonyl
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims abstract description 112
- 230000002363 herbicidal effect Effects 0.000 title claims abstract description 107
- 150000001875 compounds Chemical class 0.000 claims abstract description 112
- 239000004009 herbicide Substances 0.000 claims abstract description 87
- 150000003839 salts Chemical class 0.000 claims abstract description 34
- 238000000034 method Methods 0.000 claims abstract description 19
- 239000004480 active ingredient Substances 0.000 claims description 139
- -1 methoxy, ethoxy, prop-1-yloxy, but-1-yloxy Chemical group 0.000 claims description 103
- 239000001257 hydrogen Substances 0.000 claims description 43
- 229910052739 hydrogen Inorganic materials 0.000 claims description 43
- 239000013543 active substance Substances 0.000 claims description 34
- IWEDIXLBFLAXBO-UHFFFAOYSA-N dicamba Chemical compound COC1=C(Cl)C=CC(Cl)=C1C(O)=O IWEDIXLBFLAXBO-UHFFFAOYSA-N 0.000 claims description 25
- 239000005504 Dicamba Substances 0.000 claims description 20
- 244000038559 crop plants Species 0.000 claims description 20
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 20
- FBUKVWPVBMHYJY-UHFFFAOYSA-N nonanoic acid Chemical compound CCCCCCCCC(O)=O FBUKVWPVBMHYJY-UHFFFAOYSA-N 0.000 claims description 20
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 20
- 125000001153 fluoro group Chemical group F* 0.000 claims description 19
- 239000005562 Glyphosate Substances 0.000 claims description 17
- XDDAORKBJWWYJS-UHFFFAOYSA-N glyphosate Chemical compound OC(=O)CNCP(O)(O)=O XDDAORKBJWWYJS-UHFFFAOYSA-N 0.000 claims description 16
- 239000005631 2,4-Dichlorophenoxyacetic acid Substances 0.000 claims description 15
- IAJOBQBIJHVGMQ-UHFFFAOYSA-N 2-amino-4-[hydroxy(methyl)phosphoryl]butanoic acid Chemical compound CP(O)(=O)CCC(N)C(O)=O IAJOBQBIJHVGMQ-UHFFFAOYSA-N 0.000 claims description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 15
- 229940097068 glyphosate Drugs 0.000 claims description 14
- 229910052760 oxygen Inorganic materials 0.000 claims description 14
- JLYFCTQDENRSOL-UHFFFAOYSA-N 2-chloro-N-(2,4-dimethylthiophen-3-yl)-N-(1-methoxypropan-2-yl)acetamide Chemical compound COCC(C)N(C(=O)CCl)C=1C(C)=CSC=1C JLYFCTQDENRSOL-UHFFFAOYSA-N 0.000 claims description 13
- XFZUQTKDBCOXPP-UHFFFAOYSA-N florpyrauxifen Chemical compound COC1=C(Cl)C=CC(C=2C(=C(N)C(Cl)=C(C(O)=O)N=2)F)=C1F XFZUQTKDBCOXPP-UHFFFAOYSA-N 0.000 claims description 13
- 239000011734 sodium Substances 0.000 claims description 13
- 229910052708 sodium Inorganic materials 0.000 claims description 13
- AIAYSXFWIUNXRC-PHIMTYICSA-N (1r,5s)-3-[hydroxy-[2-(2-methoxyethoxymethyl)-6-(trifluoromethyl)pyridin-3-yl]methylidene]bicyclo[3.2.1]octane-2,4-dione Chemical compound COCCOCC1=NC(C(F)(F)F)=CC=C1C(O)=C1C(=O)[C@@H](C2)CC[C@@H]2C1=O AIAYSXFWIUNXRC-PHIMTYICSA-N 0.000 claims description 12
- WVQBLGZPHOPPFO-LBPRGKRZSA-N (S)-metolachlor Chemical compound CCC1=CC=CC(C)=C1N([C@@H](C)COC)C(=O)CCl WVQBLGZPHOPPFO-LBPRGKRZSA-N 0.000 claims description 12
- WVQBLGZPHOPPFO-UHFFFAOYSA-N 2-chloro-N-(2-ethyl-6-methylphenyl)-N-(1-methoxypropan-2-yl)acetamide Chemical compound CCC1=CC=CC(C)=C1N(C(C)COC)C(=O)CCl WVQBLGZPHOPPFO-UHFFFAOYSA-N 0.000 claims description 12
- XMTQQYYKAHVGBJ-UHFFFAOYSA-N 3-(3,4-DICHLOROPHENYL)-1,1-DIMETHYLUREA Chemical compound CN(C)C(=O)NC1=CC=C(Cl)C(Cl)=C1 XMTQQYYKAHVGBJ-UHFFFAOYSA-N 0.000 claims description 12
- VTNQPKFIQCLBDU-UHFFFAOYSA-N Acetochlor Chemical compound CCOCN(C(=O)CCl)C1=C(C)C=CC=C1CC VTNQPKFIQCLBDU-UHFFFAOYSA-N 0.000 claims description 12
- XVOKUMIPKHGGTN-UHFFFAOYSA-N Imazethapyr Chemical compound OC(=O)C1=CC(CC)=CN=C1C1=NC(C)(C(C)C)C(=O)N1 XVOKUMIPKHGGTN-UHFFFAOYSA-N 0.000 claims description 12
- CHNUNORXWHYHNE-UHFFFAOYSA-N Oxadiazon Chemical compound C1=C(Cl)C(OC(C)C)=CC(N2C(OC(=N2)C(C)(C)C)=O)=C1Cl CHNUNORXWHYHNE-UHFFFAOYSA-N 0.000 claims description 12
- OQMBBFQZGJFLBU-UHFFFAOYSA-N Oxyfluorfen Chemical compound C1=C([N+]([O-])=O)C(OCC)=CC(OC=2C(=CC(=CC=2)C(F)(F)F)Cl)=C1 OQMBBFQZGJFLBU-UHFFFAOYSA-N 0.000 claims description 12
- 239000005643 Pelargonic acid Substances 0.000 claims description 12
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 12
- ZOMSMJKLGFBRBS-UHFFFAOYSA-N bentazone Chemical compound C1=CC=C2NS(=O)(=O)N(C(C)C)C(=O)C2=C1 ZOMSMJKLGFBRBS-UHFFFAOYSA-N 0.000 claims description 12
- SILSDTWXNBZOGF-KUZBFYBWSA-N chembl111058 Chemical compound CCSC(C)CC1CC(O)=C(\C(CC)=N\OC\C=C\Cl)C(=O)C1 SILSDTWXNBZOGF-KUZBFYBWSA-N 0.000 claims description 12
- WYEHFWKAOXOVJD-UHFFFAOYSA-N diflufenican Chemical compound FC1=CC(F)=CC=C1NC(=O)C1=CC=CN=C1OC1=CC=CC(C(F)(F)F)=C1 WYEHFWKAOXOVJD-UHFFFAOYSA-N 0.000 claims description 12
- IANUJLZYFUDJIH-UHFFFAOYSA-N flufenacet Chemical compound C=1C=C(F)C=CC=1N(C(C)C)C(=O)COC1=NN=C(C(F)(F)F)S1 IANUJLZYFUDJIH-UHFFFAOYSA-N 0.000 claims description 12
- FOUWCSDKDDHKQP-UHFFFAOYSA-N flumioxazin Chemical compound FC1=CC=2OCC(=O)N(CC#C)C=2C=C1N(C1=O)C(=O)C2=C1CCCC2 FOUWCSDKDDHKQP-UHFFFAOYSA-N 0.000 claims description 12
- BGZZWXTVIYUUEY-UHFFFAOYSA-N fomesafen Chemical compound C1=C([N+]([O-])=O)C(C(=O)NS(=O)(=O)C)=CC(OC=2C(=CC(=CC=2)C(F)(F)F)Cl)=C1 BGZZWXTVIYUUEY-UHFFFAOYSA-N 0.000 claims description 12
- OYIKARCXOQLFHF-UHFFFAOYSA-N isoxaflutole Chemical compound CS(=O)(=O)C1=CC(C(F)(F)F)=CC=C1C(=O)C1=C(C2CC2)ON=C1 OYIKARCXOQLFHF-UHFFFAOYSA-N 0.000 claims description 12
- FOXFZRUHNHCZPX-UHFFFAOYSA-N metribuzin Chemical compound CSC1=NN=C(C(C)(C)C)C(=O)N1N FOXFZRUHNHCZPX-UHFFFAOYSA-N 0.000 claims description 12
- 239000001301 oxygen Substances 0.000 claims description 12
- FIKAKWIAUPDISJ-UHFFFAOYSA-L paraquat dichloride Chemical compound [Cl-].[Cl-].C1=C[N+](C)=CC=C1C1=CC=[N+](C)C=C1 FIKAKWIAUPDISJ-UHFFFAOYSA-L 0.000 claims description 12
- MEFOUWRMVYJCQC-UHFFFAOYSA-N rimsulfuron Chemical compound CCS(=O)(=O)C1=CC=CN=C1S(=O)(=O)NC(=O)NC1=NC(OC)=CC(OC)=N1 MEFOUWRMVYJCQC-UHFFFAOYSA-N 0.000 claims description 12
- GNHDVXLWBQYPJE-UHFFFAOYSA-N saflufenacil Chemical compound C1=C(Cl)C(C(=O)NS(=O)(=O)N(C)C(C)C)=CC(N2C(N(C)C(=CC2=O)C(F)(F)F)=O)=C1F GNHDVXLWBQYPJE-UHFFFAOYSA-N 0.000 claims description 12
- AZHZOGYUMMIAOF-UHFFFAOYSA-N trifludimoxazin Chemical compound O=C1N(C)C(=S)N(C)C(=O)N1C(C(=C1)F)=CC2=C1OC(F)(F)C(=O)N2CC#C AZHZOGYUMMIAOF-UHFFFAOYSA-N 0.000 claims description 12
- UPMXNNIRAGDFEH-UHFFFAOYSA-N 3,5-dibromo-4-hydroxybenzonitrile Chemical compound OC1=C(Br)C=C(C#N)C=C1Br UPMXNNIRAGDFEH-UHFFFAOYSA-N 0.000 claims description 11
- DDBMQDADIHOWIC-UHFFFAOYSA-N aclonifen Chemical compound C1=C([N+]([O-])=O)C(N)=C(Cl)C(OC=2C=CC=CC=2)=C1 DDBMQDADIHOWIC-UHFFFAOYSA-N 0.000 claims description 11
- MXWJVTOOROXGIU-UHFFFAOYSA-N atrazine Chemical compound CCNC1=NC(Cl)=NC(NC(C)C)=N1 MXWJVTOOROXGIU-UHFFFAOYSA-N 0.000 claims description 11
- JEDYYFXHPAIBGR-UHFFFAOYSA-N butafenacil Chemical compound O=C1N(C)C(C(F)(F)F)=CC(=O)N1C1=CC=C(Cl)C(C(=O)OC(C)(C)C(=O)OCC=C)=C1 JEDYYFXHPAIBGR-UHFFFAOYSA-N 0.000 claims description 11
- 125000004093 cyano group Chemical group *C#N 0.000 claims description 11
- PXDNXJSDGQBLKS-UHFFFAOYSA-N foramsulfuron Chemical compound COC1=CC(OC)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=C(NC=O)C=2)C(=O)N(C)C)=N1 PXDNXJSDGQBLKS-UHFFFAOYSA-N 0.000 claims description 11
- YFONKFDEZLYQDH-BOURZNODSA-N indaziflam Chemical compound CC(F)C1=NC(N)=NC(N[C@H]2C3=CC(C)=CC=C3C[C@@H]2C)=N1 YFONKFDEZLYQDH-BOURZNODSA-N 0.000 claims description 11
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 11
- KPUREKXXPHOJQT-UHFFFAOYSA-N mesotrione Chemical compound [O-][N+](=O)C1=CC(S(=O)(=O)C)=CC=C1C(=O)C1C(=O)CCCC1=O KPUREKXXPHOJQT-UHFFFAOYSA-N 0.000 claims description 11
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 claims description 11
- IUQAXCIUEPFPSF-UHFFFAOYSA-N tembotrione Chemical compound ClC1=C(COCC(F)(F)F)C(S(=O)(=O)C)=CC=C1C(=O)C1C(=O)CCCC1=O IUQAXCIUEPFPSF-UHFFFAOYSA-N 0.000 claims description 11
- NUPJIGQFXCQJBK-UHFFFAOYSA-N 2-(4-isopropyl-4-methyl-5-oxo-4,5-dihydro-1H-imidazol-2-yl)-5-(methoxymethyl)nicotinic acid Chemical compound OC(=O)C1=CC(COC)=CN=C1C1=NC(C)(C(C)C)C(=O)N1 NUPJIGQFXCQJBK-UHFFFAOYSA-N 0.000 claims description 10
- MAYMYMXYWIVVOK-UHFFFAOYSA-N 2-[(4,6-dimethoxypyrimidin-2-yl)carbamoylsulfamoyl]-4-(methanesulfonamidomethyl)benzoic acid Chemical compound COC1=CC(OC)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=C(CNS(C)(=O)=O)C=2)C(O)=O)=N1 MAYMYMXYWIVVOK-UHFFFAOYSA-N 0.000 claims description 10
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 10
- HWATZEJQIXKWQS-UHFFFAOYSA-N Flazasulfuron Chemical compound COC1=CC(OC)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=CN=2)C(F)(F)F)=N1 HWATZEJQIXKWQS-UHFFFAOYSA-N 0.000 claims description 10
- OORLZFUTLGXMEF-UHFFFAOYSA-N sulfentrazone Chemical compound O=C1N(C(F)F)C(C)=NN1C1=CC(NS(C)(=O)=O)=C(Cl)C=C1Cl OORLZFUTLGXMEF-UHFFFAOYSA-N 0.000 claims description 10
- FZXISNSWEXTPMF-UHFFFAOYSA-N terbutylazine Chemical compound CCNC1=NC(Cl)=NC(NC(C)(C)C)=N1 FZXISNSWEXTPMF-UHFFFAOYSA-N 0.000 claims description 10
- YIVXMZJTEQBPQO-UHFFFAOYSA-N 2,4-DB Chemical compound OC(=O)CCCOC1=CC=C(Cl)C=C1Cl YIVXMZJTEQBPQO-UHFFFAOYSA-N 0.000 claims description 9
- BXEHUCNTIZGSOJ-UHFFFAOYSA-N Esprocarb Chemical compound CC(C)C(C)N(CC)C(=O)SCC1=CC=CC=C1 BXEHUCNTIZGSOJ-UHFFFAOYSA-N 0.000 claims description 9
- 239000005561 Glufosinate Substances 0.000 claims description 9
- FCOHEOSCARXMMS-UHFFFAOYSA-N Oxaziclomefone Chemical compound C1OC(C)=C(C=2C=CC=CC=2)C(=O)N1C(C)(C)C1=CC(Cl)=CC(Cl)=C1 FCOHEOSCARXMMS-UHFFFAOYSA-N 0.000 claims description 9
- MWBPRDONLNQCFV-UHFFFAOYSA-N Tri-allate Chemical compound CC(C)N(C(C)C)C(=O)SCC(Cl)=C(Cl)Cl MWBPRDONLNQCFV-UHFFFAOYSA-N 0.000 claims description 9
- NUFNQYOELLVIPL-UHFFFAOYSA-N acifluorfen Chemical compound C1=C([N+]([O-])=O)C(C(=O)O)=CC(OC=2C(=CC(=CC=2)C(F)(F)F)Cl)=C1 NUFNQYOELLVIPL-UHFFFAOYSA-N 0.000 claims description 9
- KIEDNEWSYUYDSN-UHFFFAOYSA-N clomazone Chemical compound O=C1C(C)(C)CON1CC1=CC=CC=C1Cl KIEDNEWSYUYDSN-UHFFFAOYSA-N 0.000 claims description 9
- BXIGJZDQFDFASM-UHFFFAOYSA-N cyclopyrimorate Chemical compound N=1N=C(Cl)C=C(OC(=O)N2CCOCC2)C=1OC=1C(C)=CC=CC=1C1CC1 BXIGJZDQFDFASM-UHFFFAOYSA-N 0.000 claims description 9
- DWSPRBSLSXQIEJ-UHFFFAOYSA-N pyrasulfotole Chemical compound CC1=NN(C)C(O)=C1C(=O)C1=CC=C(C(F)(F)F)C=C1S(C)(=O)=O DWSPRBSLSXQIEJ-UHFFFAOYSA-N 0.000 claims description 9
- GHLCSCRDVVEUQD-UHFFFAOYSA-N 1-({1-ethyl-4-[3-(2-methoxyethoxy)-2-methyl-4-(methylsulfonyl)benzoyl]-1H-pyrazol-5-yl}oxy)ethyl methyl carbonate Chemical compound CCN1N=CC(C(=O)C=2C(=C(OCCOC)C(=CC=2)S(C)(=O)=O)C)=C1OC(C)OC(=O)OC GHLCSCRDVVEUQD-UHFFFAOYSA-N 0.000 claims description 8
- MZHCENGPTKEIGP-UHFFFAOYSA-N 2-(2,4-dichlorophenoxy)propanoic acid Chemical compound OC(=O)C(C)OC1=CC=C(Cl)C=C1Cl MZHCENGPTKEIGP-UHFFFAOYSA-N 0.000 claims description 8
- CLQMBPJKHLGMQK-UHFFFAOYSA-N 2-(4-isopropyl-4-methyl-5-oxo-4,5-dihydro-1H-imidazol-2-yl)nicotinic acid Chemical compound N1C(=O)C(C(C)C)(C)N=C1C1=NC=CC=C1C(O)=O CLQMBPJKHLGMQK-UHFFFAOYSA-N 0.000 claims description 8
- YHKBGVDUSSWOAB-UHFFFAOYSA-N 2-chloro-3-{2-chloro-5-[4-(difluoromethyl)-3-methyl-5-oxo-4,5-dihydro-1H-1,2,4-triazol-1-yl]-4-fluorophenyl}propanoic acid Chemical compound O=C1N(C(F)F)C(C)=NN1C1=CC(CC(Cl)C(O)=O)=C(Cl)C=C1F YHKBGVDUSSWOAB-UHFFFAOYSA-N 0.000 claims description 8
- MBFHUWCOCCICOK-UHFFFAOYSA-N 4-iodo-2-[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)carbamoylsulfamoyl]benzoic acid Chemical compound COC1=NC(C)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=C(I)C=2)C(O)=O)=N1 MBFHUWCOCCICOK-UHFFFAOYSA-N 0.000 claims description 8
- 239000002890 Aclonifen Substances 0.000 claims description 8
- 239000005476 Bentazone Substances 0.000 claims description 8
- CRJNVKRUGKSRPD-IJPZITHUSA-N C[C@@](C1)(C(N[C@H](C2)C=C[C@H]2C(O)=O)=O)ON=C1C1=CC(F)=CC(F)=C1 Chemical compound C[C@@](C1)(C(N[C@H](C2)C=C[C@H]2C(O)=O)=O)ON=C1C1=CC(F)=CC(F)=C1 CRJNVKRUGKSRPD-IJPZITHUSA-N 0.000 claims description 8
- 239000005507 Diflufenican Substances 0.000 claims description 8
- 239000005510 Diuron Substances 0.000 claims description 8
- 239000005514 Flazasulfuron Substances 0.000 claims description 8
- 239000005531 Flufenacet Substances 0.000 claims description 8
- 239000005560 Foramsulfuron Substances 0.000 claims description 8
- 239000005566 Imazamox Substances 0.000 claims description 8
- 239000005568 Iodosulfuron Substances 0.000 claims description 8
- 239000005571 Isoxaflutole Substances 0.000 claims description 8
- 239000005577 Mesosulfuron Substances 0.000 claims description 8
- 239000005583 Metribuzin Substances 0.000 claims description 8
- 239000005588 Oxadiazon Substances 0.000 claims description 8
- 239000005590 Oxyfluorfen Substances 0.000 claims description 8
- 239000005616 Rimsulfuron Substances 0.000 claims description 8
- 239000005617 S-Metolachlor Substances 0.000 claims description 8
- CNBGNNVCVSKAQZ-UHFFFAOYSA-N benzidamine Natural products C12=CC=CC=C2C(OCCCN(C)C)=NN1CC1=CC=CC=C1 CNBGNNVCVSKAQZ-UHFFFAOYSA-N 0.000 claims description 8
- SYJFEGQWDCRVNX-UHFFFAOYSA-N diquat Chemical compound C1=CC=[N+]2CC[N+]3=CC=CC=C3C2=C1 SYJFEGQWDCRVNX-UHFFFAOYSA-N 0.000 claims description 8
- KKLBEFSLWYDQFI-UHFFFAOYSA-N halauxifen Chemical compound COC1=C(Cl)C=CC(C=2N=C(C(Cl)=C(N)C=2)C(O)=O)=C1F KKLBEFSLWYDQFI-UHFFFAOYSA-N 0.000 claims description 8
- PUIYMUZLKQOUOZ-UHFFFAOYSA-N isoproturon Chemical compound CC(C)C1=CC=C(NC(=O)N(C)C)C=C1 PUIYMUZLKQOUOZ-UHFFFAOYSA-N 0.000 claims description 8
- 229940088649 isoxaflutole Drugs 0.000 claims description 8
- CONWAEURSVPLRM-UHFFFAOYSA-N lactofen Chemical compound C1=C([N+]([O-])=O)C(C(=O)OC(C)C(=O)OCC)=CC(OC=2C(=CC(=CC=2)C(F)(F)F)Cl)=C1 CONWAEURSVPLRM-UHFFFAOYSA-N 0.000 claims description 8
- TVMYHMXZYVGODK-DDUZABMNSA-N methyl (2R,4R)-4-[[(5S)-3-(3,5-difluorophenyl)-5-ethenyl-4H-1,2-oxazole-5-carbonyl]amino]oxolane-2-carboxylate Chemical compound COC(=O)[C@H]1C[C@H](CO1)NC(=O)[C@]2(CC(=NO2)C3=CC(=CC(=C3)F)F)C=C TVMYHMXZYVGODK-DDUZABMNSA-N 0.000 claims description 8
- QPTPZPIXUPELRM-UHFFFAOYSA-N methyl 3-[2-[2-chloro-4-fluoro-5-[3-methyl-2,6-dioxo-4-(trifluoromethyl)pyrimidin-1-yl]phenyl]sulfanylpropanoylamino]propanoate Chemical compound C1=C(Cl)C(SC(C)C(=O)NCCC(=O)OC)=CC(N2C(N(C)C(=CC2=O)C(F)(F)F)=O)=C1F QPTPZPIXUPELRM-UHFFFAOYSA-N 0.000 claims description 8
- RTCOGUMHFFWOJV-UHFFFAOYSA-N nicosulfuron Chemical compound COC1=CC(OC)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=CN=2)C(=O)N(C)C)=N1 RTCOGUMHFFWOJV-UHFFFAOYSA-N 0.000 claims description 8
- MGOHCFMYLBAPRN-UHFFFAOYSA-N pinoxaden Chemical compound CCC1=CC(C)=CC(CC)=C1C(C1=O)=C(OC(=O)C(C)(C)C)N2N1CCOCC2 MGOHCFMYLBAPRN-UHFFFAOYSA-N 0.000 claims description 8
- YXIIPOGUBVYZIW-UHFFFAOYSA-N pyraflufen Chemical compound ClC1=C(OC(F)F)N(C)N=C1C1=CC(OCC(O)=O)=C(Cl)C=C1F YXIIPOGUBVYZIW-UHFFFAOYSA-N 0.000 claims description 8
- 239000002794 2,4-DB Substances 0.000 claims description 7
- IRJQWZWMQCVOLA-DNTJNYDQSA-N 2-[(e)-n-[(3,5-difluorophenyl)carbamoylamino]-c-methylcarbonimidoyl]pyridine-3-carboxylic acid Chemical compound N=1C=CC=C(C(O)=O)C=1C(/C)=N/NC(=O)NC1=CC(F)=CC(F)=C1 IRJQWZWMQCVOLA-DNTJNYDQSA-N 0.000 claims description 7
- MPPOHAUSNPTFAJ-UHFFFAOYSA-N 2-[4-[(6-chloro-1,3-benzoxazol-2-yl)oxy]phenoxy]propanoic acid Chemical compound C1=CC(OC(C)C(O)=O)=CC=C1OC1=NC2=CC=C(Cl)C=C2O1 MPPOHAUSNPTFAJ-UHFFFAOYSA-N 0.000 claims description 7
- 239000005489 Bromoxynil Substances 0.000 claims description 7
- 239000005497 Clethodim Substances 0.000 claims description 7
- 239000005499 Clomazone Substances 0.000 claims description 7
- NNYRZQHKCHEXSD-UHFFFAOYSA-N Daimuron Chemical compound C1=CC(C)=CC=C1NC(=O)NC(C)(C)C1=CC=CC=C1 NNYRZQHKCHEXSD-UHFFFAOYSA-N 0.000 claims description 7
- 239000005532 Flumioxazine Substances 0.000 claims description 7
- 239000005578 Mesotrione Substances 0.000 claims description 7
- 239000005620 Tembotrione Substances 0.000 claims description 7
- 239000000654 additive Substances 0.000 claims description 7
- 125000001246 bromo group Chemical group Br* 0.000 claims description 7
- 125000001309 chloro group Chemical group Cl* 0.000 claims description 7
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 7
- 230000008635 plant growth Effects 0.000 claims description 7
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- ZTYVMAQSHCZXLF-UHFFFAOYSA-N methyl 2-[[4,6-bis(difluoromethoxy)pyrimidin-2-yl]carbamoylsulfamoyl]benzoate Chemical compound COC(=O)C1=CC=CC=C1S(=O)(=O)NC(=O)NC1=NC(OC(F)F)=CC(OC(F)F)=N1 ZTYVMAQSHCZXLF-UHFFFAOYSA-N 0.000 claims description 2
- RSMUVYRMZCOLBH-UHFFFAOYSA-N metsulfuron methyl Chemical compound COC(=O)C1=CC=CC=C1S(=O)(=O)NC(=O)NC1=NC(C)=NC(OC)=N1 RSMUVYRMZCOLBH-UHFFFAOYSA-N 0.000 claims description 2
- CHEDHKBPPDKBQF-UPONEAKYSA-N n-[5-[(6s,7ar)-6-fluoro-1,3-dioxo-5,6,7,7a-tetrahydropyrrolo[1,2-c]imidazol-2-yl]-2-chloro-4-fluorophenyl]-1-chloromethanesulfonamide Chemical compound N1([C@@H](C2=O)C[C@@H](C1)F)C(=O)N2C1=CC(NS(=O)(=O)CCl)=C(Cl)C=C1F CHEDHKBPPDKBQF-UPONEAKYSA-N 0.000 claims description 2
- BFFLCMLOXQNHJA-UHFFFAOYSA-N n-[ethoxy-(4-methyl-2-nitrophenoxy)phosphinothioyl]propan-2-amine Chemical compound CCOP(=S)(NC(C)C)OC1=CC=C(C)C=C1[N+]([O-])=O BFFLCMLOXQNHJA-UHFFFAOYSA-N 0.000 claims description 2
- VHEWQRWLIDWRMR-UHFFFAOYSA-N n-[methoxy-(4-methyl-2-nitrophenoxy)phosphinothioyl]propan-2-amine Chemical compound CC(C)NP(=S)(OC)OC1=CC=C(C)C=C1[N+]([O-])=O VHEWQRWLIDWRMR-UHFFFAOYSA-N 0.000 claims description 2
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 claims description 2
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 2
- 125000001971 neopentyl group Chemical group [H]C([*])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 2
- OLZQTUCTGLHFTQ-UHFFFAOYSA-N octan-2-yl 2-(4-amino-3,5-dichloro-6-fluoropyridin-2-yl)oxyacetate Chemical compound CCCCCCC(C)OC(=O)COC1=NC(F)=C(Cl)C(N)=C1Cl OLZQTUCTGLHFTQ-UHFFFAOYSA-N 0.000 claims description 2
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- INFDPOAKFNIJBF-UHFFFAOYSA-N paraquat Chemical compound C1=C[N+](C)=CC=C1C1=CC=[N+](C)C=C1 INFDPOAKFNIJBF-UHFFFAOYSA-N 0.000 claims description 2
- 125000003538 pentan-3-yl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])C([H])([H])[H] 0.000 claims description 2
- KJMADHVXBWVFBX-UHFFFAOYSA-M potassium;2,3,6-trichlorobenzoate Chemical compound [K+].[O-]C(=O)C1=C(Cl)C=CC(Cl)=C1Cl KJMADHVXBWVFBX-UHFFFAOYSA-M 0.000 claims description 2
- SIVJKMBJGCUUNS-UHFFFAOYSA-M potassium;2-(2,4-dichlorophenoxy)propanoate Chemical compound [K+].[O-]C(=O)C(C)OC1=CC=C(Cl)C=C1Cl SIVJKMBJGCUUNS-UHFFFAOYSA-M 0.000 claims description 2
- ORHJUFUQMQEFPQ-UHFFFAOYSA-M potassium;2-(4-chloro-2-methylphenoxy)acetate Chemical compound [K+].CC1=CC(Cl)=CC=C1OCC([O-])=O ORHJUFUQMQEFPQ-UHFFFAOYSA-M 0.000 claims description 2
- OFCQYQOZASISIU-UHFFFAOYSA-M potassium;2-(4-chloro-2-methylphenoxy)propanoate Chemical compound [K+].[O-]C(=O)C(C)OC1=CC=C(Cl)C=C1C OFCQYQOZASISIU-UHFFFAOYSA-M 0.000 claims description 2
- RLQCYSVYYHHLIL-UHFFFAOYSA-M potassium;3,6-dichloropyridine-2-carboxylate Chemical compound [K+].[O-]C(=O)C1=NC(Cl)=CC=C1Cl RLQCYSVYYHHLIL-UHFFFAOYSA-M 0.000 claims description 2
- WRBJKRRJBCSNLE-UHFFFAOYSA-M potassium;4-(2,4-dichlorophenoxy)butanoate Chemical compound [K+].[O-]C(=O)CCCOC1=CC=C(Cl)C=C1Cl WRBJKRRJBCSNLE-UHFFFAOYSA-M 0.000 claims description 2
- ZRHANBBTXQZFSP-UHFFFAOYSA-M potassium;4-amino-3,5,6-trichloropyridine-2-carboxylate Chemical compound [K+].NC1=C(Cl)C(Cl)=NC(C([O-])=O)=C1Cl ZRHANBBTXQZFSP-UHFFFAOYSA-M 0.000 claims description 2
- XUYNZTABHAFFAO-UHFFFAOYSA-M potassium;4-amino-3,6-dichloropyridine-2-carboxylate Chemical compound [K+].NC1=CC(Cl)=NC(C([O-])=O)=C1Cl XUYNZTABHAFFAO-UHFFFAOYSA-M 0.000 claims description 2
- ASRAWSBMDXVNLX-UHFFFAOYSA-N pyrazolynate Chemical compound C=1C=C(Cl)C=C(Cl)C=1C(=O)C=1C(C)=NN(C)C=1OS(=O)(=O)C1=CC=C(C)C=C1 ASRAWSBMDXVNLX-UHFFFAOYSA-N 0.000 claims description 2
- PJPDUXCVLFAQBM-UHFFFAOYSA-N quinclorac-dimethylammonium Chemical compound CNC.ClC1=CN=C2C(C(=O)O)=C(Cl)C=CC2=C1 PJPDUXCVLFAQBM-UHFFFAOYSA-N 0.000 claims description 2
- 125000003548 sec-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 2
- RTWIRLHWLMNVCC-WQYNNSOESA-M sodium (2S)-2-[[(2S)-2-[[(2S)-2-amino-4-[hydroxy(methyl)phosphoryl]butanoyl]amino]propanoyl]amino]propanoate Chemical compound [Na+].[O-]C(=O)[C@H](C)NC(=O)[C@H](C)NC(=O)[C@@H](N)CCP(C)(O)=O RTWIRLHWLMNVCC-WQYNNSOESA-M 0.000 claims description 2
- JKPSVOHVUGMYGH-UHFFFAOYSA-M sodium;(4,6-dimethoxypyrimidin-2-yl)-[[3-methoxycarbonyl-6-(trifluoromethyl)pyridin-2-yl]sulfonylcarbamoyl]azanide Chemical compound [Na+].COC(=O)C1=CC=C(C(F)(F)F)N=C1S(=O)(=O)NC(=O)[N-]C1=NC(OC)=CC(OC)=N1 JKPSVOHVUGMYGH-UHFFFAOYSA-M 0.000 claims description 2
- UFEIWEXHHOXPGP-UHFFFAOYSA-M sodium;(4,6-dimethoxypyrimidin-2-yl)carbamoyl-[3-(2,2,2-trifluoroethoxy)pyridin-2-yl]sulfonylazanide Chemical compound [Na+].COC1=CC(OC)=NC(NC(=O)[N-]S(=O)(=O)C=2C(=CC=CN=2)OCC(F)(F)F)=N1 UFEIWEXHHOXPGP-UHFFFAOYSA-M 0.000 claims description 2
- UEFBGOFTQWGYCJ-BNSHTTSQSA-M sodium;(6z)-2-methoxycarbonyl-3,3-dimethyl-5-oxo-6-[1-(prop-2-enoxyamino)butylidene]cyclohexen-1-olate Chemical compound [Na+].C=CCONC(/CCC)=C1\C(=O)CC(C)(C)C(C(=O)OC)=C1[O-] UEFBGOFTQWGYCJ-BNSHTTSQSA-M 0.000 claims description 2
- DPMABEYFRYKAHD-UHFFFAOYSA-M sodium;2,3,6-trichlorobenzoate Chemical compound [Na+].[O-]C(=O)C1=C(Cl)C=CC(Cl)=C1Cl DPMABEYFRYKAHD-UHFFFAOYSA-M 0.000 claims description 2
- RFOHRSIAXQACDB-UHFFFAOYSA-M sodium;2-(2,4-dichlorophenoxy)acetate Chemical compound [Na+].[O-]C(=O)COC1=CC=C(Cl)C=C1Cl RFOHRSIAXQACDB-UHFFFAOYSA-M 0.000 claims description 2
- STAPBGVGYWCRTF-UHFFFAOYSA-M sodium;2-(4-chloro-2-methylphenoxy)acetate Chemical compound [Na+].CC1=CC(Cl)=CC=C1OCC([O-])=O STAPBGVGYWCRTF-UHFFFAOYSA-M 0.000 claims description 2
- DHJHUXNTNSRSEX-UHFFFAOYSA-M sodium;2-(4-chloro-2-methylphenoxy)propanoate Chemical compound [Na+].[O-]C(=O)C(C)OC1=CC=C(Cl)C=C1C DHJHUXNTNSRSEX-UHFFFAOYSA-M 0.000 claims description 2
- NAGWPMWBTLVULC-UHFFFAOYSA-M sodium;2-(4-methyl-5-oxo-4-propan-2-yl-1h-imidazol-2-yl)quinoline-3-carboxylate Chemical compound [Na+].N1C(=O)C(C(C)C)(C)N=C1C1=NC2=CC=CC=C2C=C1C([O-])=O NAGWPMWBTLVULC-UHFFFAOYSA-M 0.000 claims description 2
- JUNDBKFAZXZKRA-MAFYXNADSA-M sodium;2-[(e)-n-[(3,5-difluorophenyl)carbamoylamino]-c-methylcarbonimidoyl]pyridine-3-carboxylate Chemical compound [Na+].N=1C=CC=C(C([O-])=O)C=1C(/C)=N/NC(=O)NC1=CC(F)=CC(F)=C1 JUNDBKFAZXZKRA-MAFYXNADSA-M 0.000 claims description 2
- WMWBBXKLYSGKDY-UHFFFAOYSA-M sodium;3-amino-2,5-dichlorobenzoate Chemical compound [Na+].NC1=CC(Cl)=CC(C([O-])=O)=C1Cl WMWBBXKLYSGKDY-UHFFFAOYSA-M 0.000 claims description 2
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- 102000042094 ryanodine receptor (TC 1.A.3.1) family Human genes 0.000 description 1
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- 229960004546 thiabendazole Drugs 0.000 description 1
- NWWZPOKUUAIXIW-FLIBITNWSA-N thiamethoxam Chemical compound [O-][N+](=O)\N=C/1N(C)COCN\1CC1=CN=C(Cl)S1 NWWZPOKUUAIXIW-FLIBITNWSA-N 0.000 description 1
- DNVLJEWNNDHELH-UHFFFAOYSA-N thiocyclam Chemical compound CN(C)C1CSSSC1 DNVLJEWNNDHELH-UHFFFAOYSA-N 0.000 description 1
- 125000003396 thiol group Chemical group [H]S* 0.000 description 1
- OPASCBHCTNRLRM-UHFFFAOYSA-N thiometon Chemical compound CCSCCSP(=S)(OC)OC OPASCBHCTNRLRM-UHFFFAOYSA-N 0.000 description 1
- QGHREAKMXXNCOA-UHFFFAOYSA-N thiophanate-methyl Chemical compound COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC QGHREAKMXXNCOA-UHFFFAOYSA-N 0.000 description 1
- QSOHVSNIQHGFJU-UHFFFAOYSA-L thiosultap disodium Chemical compound [Na+].[Na+].[O-]S(=O)(=O)SCC(N(C)C)CSS([O-])(=O)=O QSOHVSNIQHGFJU-UHFFFAOYSA-L 0.000 description 1
- 229960002447 thiram Drugs 0.000 description 1
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- VJQYLJSMBWXGDV-UHFFFAOYSA-N tiadinil Chemical compound N1=NSC(C(=O)NC=2C=C(Cl)C(C)=CC=2)=C1C VJQYLJSMBWXGDV-UHFFFAOYSA-N 0.000 description 1
- 229950007146 tigolaner Drugs 0.000 description 1
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- OBZIQQJJIKNWNO-UHFFFAOYSA-N tolclofos-methyl Chemical compound COP(=S)(OC)OC1=C(Cl)C=C(C)C=C1Cl OBZIQQJJIKNWNO-UHFFFAOYSA-N 0.000 description 1
- WPALTCMYPARVNV-UHFFFAOYSA-N tolfenpyrad Chemical compound CCC1=NN(C)C(C(=O)NCC=2C=CC(OC=3C=CC(C)=CC=3)=CC=2)=C1Cl WPALTCMYPARVNV-UHFFFAOYSA-N 0.000 description 1
- HYVWIQDYBVKITD-UHFFFAOYSA-N tolylfluanid Chemical compound CN(C)S(=O)(=O)N(SC(F)(Cl)Cl)C1=CC=C(C)C=C1 HYVWIQDYBVKITD-UHFFFAOYSA-N 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- DDVNRFNDOPPVQJ-HQJQHLMTSA-N transfluthrin Chemical compound CC1(C)[C@H](C=C(Cl)Cl)[C@H]1C(=O)OCC1=C(F)C(F)=CC(F)=C1F DDVNRFNDOPPVQJ-HQJQHLMTSA-N 0.000 description 1
- 230000014616 translation Effects 0.000 description 1
- 125000005270 trialkylamine group Chemical group 0.000 description 1
- 229940055764 triaz Drugs 0.000 description 1
- NKNFWVNSBIXGLL-UHFFFAOYSA-N triazamate Chemical compound CCOC(=O)CSC1=NC(C(C)(C)C)=NN1C(=O)N(C)C NKNFWVNSBIXGLL-UHFFFAOYSA-N 0.000 description 1
- 150000003918 triazines Chemical class 0.000 description 1
- DQJCHOQLCLEDLL-UHFFFAOYSA-N tricyclazole Chemical compound CC1=CC=CC2=C1N1C=NN=C1S2 DQJCHOQLCLEDLL-UHFFFAOYSA-N 0.000 description 1
- UGCNRZFAUBJVPT-UHFFFAOYSA-N tricyclohexyltin;hydrate Chemical compound O.C1CCCCC1[Sn](C1CCCCC1)C1CCCCC1 UGCNRZFAUBJVPT-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-O triethanolammonium Chemical compound OCC[NH+](CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-O 0.000 description 1
- NRZWQKGABZFFKE-UHFFFAOYSA-N trimethylsulfonium Chemical class C[S+](C)C NRZWQKGABZFFKE-UHFFFAOYSA-N 0.000 description 1
- DFFWZNDCNBOKDI-UHFFFAOYSA-N trinexapac Chemical compound O=C1CC(C(=O)O)CC(=O)C1=C(O)C1CC1 DFFWZNDCNBOKDI-UHFFFAOYSA-N 0.000 description 1
- RVKCCVTVZORVGD-UHFFFAOYSA-N trinexapac-ethyl Chemical group O=C1CC(C(=O)OCC)CC(=O)C1=C(O)C1CC1 RVKCCVTVZORVGD-UHFFFAOYSA-N 0.000 description 1
- YNWVFADWVLCOPU-MAUPQMMJSA-N uniconazole P Chemical compound C1=NC=NN1/C([C@@H](O)C(C)(C)C)=C/C1=CC=C(Cl)C=C1 YNWVFADWVLCOPU-MAUPQMMJSA-N 0.000 description 1
- DBXFMOWZRXXBRN-LWKPJOBUSA-N valifenalate Chemical compound CC(C)OC(=O)N[C@@H](C(C)C)C(=O)NC(CC(=O)OC)C1=CC=C(Cl)C=C1 DBXFMOWZRXXBRN-LWKPJOBUSA-N 0.000 description 1
- LESVOLZBIFDZGS-UHFFFAOYSA-N vamidothion Chemical compound CNC(=O)C(C)SCCSP(=O)(OC)OC LESVOLZBIFDZGS-UHFFFAOYSA-N 0.000 description 1
- 239000012873 virucide Substances 0.000 description 1
- 238000009369 viticulture Methods 0.000 description 1
- 239000000664 voltage gated sodium channel blocking agent Substances 0.000 description 1
- 239000004552 water soluble powder Substances 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 238000001238 wet grinding Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 235000014101 wine Nutrition 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- WCJYTPVNMWIZCG-UHFFFAOYSA-N xylylcarb Chemical compound CNC(=O)OC1=CC=C(C)C(C)=C1 WCJYTPVNMWIZCG-UHFFFAOYSA-N 0.000 description 1
- 239000005943 zeta-Cypermethrin Substances 0.000 description 1
- 229940048462 zinc phosphide Drugs 0.000 description 1
- AMHNZOICSMBGDH-UHFFFAOYSA-L zineb Chemical compound [Zn+2].[S-]C(=S)NCCNC([S-])=S AMHNZOICSMBGDH-UHFFFAOYSA-L 0.000 description 1
- DUBNHZYBDBBJHD-UHFFFAOYSA-L ziram Chemical compound [Zn+2].CN(C)C([S-])=S.CN(C)C([S-])=S DUBNHZYBDBBJHD-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
Definitions
- salts are compounds in which the acidic hydrogen is replaced by an agriculturally suitable cation, for example metal salts, in particular alkali metal salts or alkaline earth metal salts, in particular sodium and potassium salts, or else ammonium salts, salts with organic amines or quaternary (quaternary) ammonium salts, for example with cations of the formula [NRR'R''R''] + , in which R to R''' are each independently of the other represent an organic radical, in particular alkyl, aryl, aralkyl or alkylaryl.
- an agriculturally suitable cation for example metal salts, in particular alkali metal salts or alkaline earth metal salts, in particular sodium and potassium salts, or else ammonium salts, salts with organic amines or quaternary (quaternary) ammonium salts, for example with cations of the formula [NRR'R''R''] + , in which R to R''' are each independently of the other
- herbicidally active substances (A) are compounds of the formula (I), wherein R 1 is hydrogen, R 2 is fluoro, R 3 is fluoro, R 4 is chloro, bromo, or cyano, R 5 is hydrogen, R 6 is hydrogen, fluorine, R 7 is hydrogen, G is methylene, X is O (oxygen), Y is O (oxygen), and Q is any of the moieties specifically mentioned stands.
- the herbicidal composition in addition to at least one component (B) as defined above, preferably contains one or more compounds [component (A)] of the general formula (I) or their agrochemically compatible salts [herbicides (A)].
- Tables 1a and 1b Preferred compounds of the formula (I) as herbicide (A)): All of these preferred compounds are listed again in Table 1b below by their structural formula and corresponding IUPAC name.
- Table 1b IUPAC names and structural formulas of the preferred compounds of formula (I) (herbicide (A))
- the compounds of the formula (I) are known from the international application with the application number PCT/EP2020/070463 (published as WO2021/013799) and can be prepared by the processes described there.
- Fungicidally active compounds which can be used in combination with the herbicide combinations according to the invention are preferably commercially available active compounds, for example (analogously to the herbicides, the compounds are generally referred to by their common names, here in the usual English notation): 1) Inhibitors of ergosterol Biosynthesis, for example (1.001) cyproconazole, (1.002) difenoconazole, (1.003) epoxiconazole, (1.004) fenhexamide, (1.005) fenpropidin, (1.006) fenpropimorph, (1.007) fenpyrazamine, (1.008) fluquinconazole, (1.009) flutriafol, (1.010 ) imazalil, (1.011) imazalil sulfate, (1.012) ipconazole, (1.013) metconazole, (1.014) myclobutanil, (1.015) paclobutrazole, (1.016) prochloraz, (1.017) prop
- Preferred fungicides are selected from the group consisting of benalaxyl, bitertanol, bromuconazole, captafol, carbendazim, carpropamid, cyazofamid, cyproconazole, diethofencarb, edifenphos, fenpropimorph, fentine, fluquinconazole, fosetyl, fluoroimide, folpet, iminoctadine, iprodionem, iprovalicarb, kasugamycin, maneb , Nabam, Pencycuron, Prochloraz, Propamocarb, Propineb, Pyrimethanil, Sprioxamine, Quintozene, Tebuconazole, Tolylfluanid, Triadimefon, Triadimenol, Trifloxystrobin, Zineb.
- the spectrum of activity extends to species such as Abutilon, Amaranthus, Ambrosia, Anoda, Anthemis, Aphanes, Artemisia, Atriplex, Bellis, Bidens, Capsella, Carduus, Cassia, Centaurea, Chenopodium, Cirsium, Convolvulus, Datura, Desmodium, Emex , Erodium, Erysimum, Euphorbia, Galeopsis, Galinsoga, Galium, Geranium, Hibiscus, Ipomoea, Kochia, Lamium, Lepidium, Lindernia, Matricaria, Mentha, Mercurialis, Mullugo, Myosotis, Papaver, Pharbitis, Plantago, Polygonum, Portulaca, Ranunculus, Raphanus, Rorippa, Rotala, Rumex, Salsola, Senecio, Sesbania, Sida, Sinapis,
- the active compound combinations according to the invention are applied to the surface of the soil before germination, either the emergence of the weed seedlings is completely prevented or the weeds grow to the cotyledon stage, but then stop growing and finally die off completely after three to four weeks.
- the active ingredients are applied to the green parts of the plant post-emergence, growth stops after the treatment and the harmful plants remain in the growth stage present at the time of application or die off completely after a certain time, so that in this way weed competition that is harmful to the crop plants occurs very early and permanently eliminated.
- the herbicidal compositions according to the invention are distinguished by a rapidly onset and long-lasting herbicidal action. The rainfastness of the active ingredients in the combinations according to the invention is generally favorable.
- the invention therefore also provides a method for controlling undesired plant growth, if appropriate in crops of useful plants, preferably in non-crop land or in plantation crops, characterized in that one or more herbicides of type (A) are used with one or more herbicides of type (B). applied to the harmful plants, parts of plants or plant seeds (seeds) thereof or the cultivated area.
- the invention also relates to the use of the new combinations of compounds (A)+(B) for controlling harmful plants, if appropriate in crops of useful plants, preferably in non-crop land and plantation crops, but also for controlling harmful plants before sowing the following useful plant, such as in particular for Seed preparation ("burn-down application").
- a water-dispersible, wettable powder is obtained by mixing 25 parts by weight of an active ingredient/active ingredient mixture, 64 parts by weight of kaolin-containing quartz as the inert substance, 10 parts by weight of potassium lignosulfonate and 1 part by weight of sodium oleoylmethyltaurine mixed as a wetting and dispersing agent and ground in a pin mill.
Abstract
The present invention relates to compositions comprising herbicidally active compounds (A) and (B), wherein (A) represents one or more compounds of the general formula (I) or agrochemically compatible salts thereof [component (A)], (I) and (B) represents one or more herbicides [component (B)]. The application further relates to a process and to the use of the herbicidal composition of the invention for the control of harmful plants or for growth regulation.
Description
Herbizide Zusammensetzungen Beschreibung Die Erfindung liegt auf dem technischen Gebiet der Pflanzenschutzmittel, die gegen unerwünschten Pflanzenwuchs in Nichtkulturland, zur Saatvorbereitung oder in Pflanzenkulturen eingesetzt werden können und als Herbizidwirkstoffe eine Kombination von mindestens zwei Herbiziden enthalten, wobei die Zusammensetzungen herbizid wirksame Verbindungen (A) und (B) enthält, worin (A) eine oder mehrere Verbindungen der allgemeinen Formel (I) oder deren agrochemisch verträglichen Salze [Herbizide (A) bzw. Komponente (A)] und (B) ein oder mehrere Herbizide (Komponente B) bedeutet. Verbindungen aus der Strukturklasse der substituierten N-Phenyluracile sind als Herbizide bekannt (siehe internationale Anmeldung mit der Anmeldenummer PCT/EP2020/070463, veröffentlicht als WO2021/013799). Die Verbindungen sind gegen ein breites Spektrum von Schadpflanzen im Vorauflauf wie auch im Nachauflaufapplikationsverfahren wirksam, wobei ein nichtselektiver Einsatz zur Bekämpfung von unerwünschtem Pflanzenwuchs oder ein selektiver Einsatz in Pflanzenkulturen möglich ist. Die Wirksamkeit dieser Herbizide gegen Schadpflanzen liegt auf einem hohen Niveau, hängt jedoch im Allgemeinen von der Aufwandmenge, der jeweiligen Zubereitungsform, dem Schadpflanzenspektrum, den jeweils zu bekämpfenden Schadpflanzen, den Klima- und Bodenverhältnissen, etc. ab. Ein weiteres Kriterium ist die Dauer der Wirkung bzw. die Abbaugeschwindigkeit des Herbizids. Zu berücksichtigen sind gegebenenfalls auch Veränderungen in der Empfindlichkeit von Schadpflanzen, die bei längerer Anwendung der Herbizide oder geographisch begrenzt auftreten können. Wirkungsverluste bei einzelnen Pflanzen lassen sich nur bedingt durch höhere Aufwandmengen der Herbizide ausgleichen, z. B. weil damit häufig die Selektivität der Herbizide verschlechtert wird oder eine Wirkungsverbesserung auch bei höherer Aufwandmenge nicht eintritt. Generell besteht Bedarf an Methoden, die Herbizidwirkung mit geringerer Aufwandmenge an Wirkstoffen zu erreichen. Eine geringere Aufwandmenge reduziert nicht nur die für die Applikation erforderliche Menge eines Wirkstoffs, sondern reduziert in der Regel auch die Menge an nötigen Formulierungshilfsmitteln. Beides verringert den wirtschaftlichen Aufwand und verbessert die ökologische Verträglichkeit der Herbizidbehandlung. Eine Möglichkeit zur Verbesserung des Anwendungsprofils eines Herbizids kann in der Kombination des Wirkstoffs mit einem oder mehreren anderen Wirkstoffen bestehen, welche die gewünschten
zusätzlichen Eigenschaften beisteuern. Allerdings treten bei der kombinierten Anwendung mehrerer Wirkstoffe nicht selten Phänomene der physikalischen und biologischen Unverträglichkeit auf, z. B. mangelnde Stabilität in einer Coformulierung, Zersetzung eines Wirkstoffes bzw. Antagonismus der Wirkstoffe. Erwünscht dagegen sind Kombinationen von Wirkstoffen mit günstigem Wirkungsprofil, hoher Stabilität und möglichst unerwartet synergistisch verstärkter Wirkung, welche eine Reduzierung der Aufwandmenge im Vergleich zur Einzelapplikation der zu kombinierenden Wirkstoffe erlaubt. Die Aufgabe der vorliegenden Erfindung besteht in der Bereitstellung alternativer oder vorteilhafter herbizider Zusammensetzungen, welche ein gutes biologisches Anwendungsprofil und möglichst mehrere der oben genannten gewünschten günstigen Eigenschaften aufweisen. Überraschenderweise wurde nun gefunden, dass diese Aufgabe durch Verwendung einer Zusammensetzung enthaltend herbizid wirksame Verbindungen (A) und (B) gelöst werden kann, wobei (A) eine oder mehrere Verbindungen der allgemeinen Formel (I) oder deren agrochemisch verträglichen Salze [Komponente (A)] bedeutet und (B) ein oder mehrere Herbizide [Komponente (B)] ausgewählt aus der Gruppe der herbiziden Wirkstoffe (B1) bis (B11) bedeutet. Die erfindungsgemäßen Zusammensetzungen wirken in besonders günstiger Weise zusammen, z.B. wenn sie zur Bekämpfung von unerwünschtem Pflanzenwuchs in Kulturpflanzen wie Weizen (Hart- und Weichweizen), Mais, Soja, Zuckerrübe, Zuckerrohr, Baumwolle, Reis, Bohnen (wie beispielsweise Buschbohne und Pferdebohne), Flachs, Gerste, Hafer, Roggen, Triticale, Kartoffel und Hirse (Sorghum), Nichtkulturland Weideland und Grün-/Rasenflächen und Plantagenkulturen eingesetzt werden. Gegenstand der vorliegenden Erfindung sind somit Zusammensetzungen enthaltend herbizid wirksame Verbindungen (A) und (B), wobei (A) für eine oder mehrere Verbindungen der allgemeinen Formel (I) oder deren agrochemisch verträglichen Salze [Komponente (A)] steht,
worin R1 für Wasserstoff steht,
R2 für Wasserstoff, Fluor, Chlor, Brom, Trifluormethyl, Methoxy, Ethoxy, Prop-1-yloxy, But-1-yloxy steht, R3 für Wasserstoff, Fluor, Chlor, Brom, Methoxy, Ethoxy, Prop-1-yloxy, Prop-2-yloxy, But-1-yloxy, But-2-yloxy, 2-Methylprop-1-yloxy, 1,1-Dimethyleth-1-yloxy steht, R4 für Fluor, Chlor, Brom, Cyano, NO2, C(O)NH2, C(S)NH2, Trifluormethyl, Difluormethyl, Pentafluorethyl, Ethinyl, Propin-1-yl, 1-Butin-1-yl, Pentin-1-yl, Hexin-1-yl steht, R5, R6 und R7 unabhängig voneinander für Wasserstoff, Fluor, Chlor, Brom, Iod, Cyano, Methyl, Ethyl, Prop-1-yl, 1-Methylethyl, But-1-yl, 1-Methylpropyl, 2-Methylpropyl, 1,1-Dimethylethyl, n-Pentyl, 1-Methylbutyl, 2-Methylbutyl, 3-Methylbutyl, 1,1- Dimethylpropyl, 1,2-Dimethylpropyl, 2,2-Dimethylpropyl, 1-Ethylpropyl, n-Hexyl, 1- Methylpentyl, 2-Methylpentyl, 3-Methylpentyl, 4-Methylpentyl, 1,1-Dimethylbutyl, 1,2-Dimethylbutyl, 1,3-Di-methylbutyl, 2,2-Dimethylbutyl, 2,3-Dimethylbutyl, 3,3- Dimethylbutyl, 1-Ethylbutyl, 2-Ethylbutyl, 1,1,2-Trimethylpropyl, 1,2,2- Trimethylpropyl, 1-Ethyl-1-methylpropyl, 1-Ethyl-2-methylpropyl, Trifluormethyl, Difluormethyl, Pentafluorethyl, 2,2-Difluorethyl, 2,2,2-Trifluorethyl, Methoxy, Ethoxy, Prop-1-yloxy, Prop-2-yloxy, But-1-yloxy, But-2-yloxy, 2-Methylprop-1-yloxy, 1,1- Dimethyleth-1-yloxy, Difluormethoxy, Trifluormethoxy, Pentafluorethoxy, 2,2-Difluorethoxy, 2,2,2-Trifluorethoxy stehen, G für Methylen, (Methyl)methylen, (Ethyl)methylen, (Prop-1-yl)methylen, (Prop-2- yl)methylen, (But-1-yl)methylen, (But-2-yl)methylen, (Pent-1-yl)methylen, (Pent-2- yl)methylen, (Pent-3-yl)methylen, (Dimethyl)methylen, (Diethyl)methylen, Ethylen, n- Propylen, (1-Methyl)ethyl-1-en, (2-Methyl)ethyl-1-en, n-Butylen, 1-Methylpropyl-1-en, 2-Methylpropyl-1-en, 3-Methylpropyl-1-en, 1,1-Dimethylethyl-1-en, 2,2-Dimethylethyl- 1-en, 1-Ethylethyl-1-en, 2-Ethylethyl-1-en, 1-(Prop-1-yl)ethyl-1-en, 2-(Prop-1-yl)ethyl- 1-en, 1-(Prop-2-yl)ethyl-1-en, 2-(Prop-2-yl)ethyl-1-en, 1,1,2-Trimethylethyl-1-en, 1,2,2- Trimethylethyl-1-en, 1,1,2,2-Tetramethylethyl-1-en, n-Pentylen, 1-Methylbutyl-1-en, 2- Methylbutyl-1-en, 3-Methylbutyl-1-en, 4-Methylbutyl-1-en, 1,1-Dimethylpropyl-1-en, 2,2-Dimethylpropyl-1-en, 3,3-Dimethylpropyl-1-en, 1,2-Dimethylpropyl-1-en, 1,3- Dimethylpropyl-1-en, 1-Ethylpropyl-1-en, n-Hexylen, 1-Methylpentyl-1-en, 2- Methylpentyl-1-en, 3-Methylpentyl-1-en, 4-Methylpentyl-1-en, 1,1-Dimethylbutyl-1-en, 1,2-Dimethylbutyl-1-en, 1,3-Di-methylbutyl-1-en, 2,2-Dimethylbutyl-1-en, 2,3-
Dimethylbutyl-1-en, 3,3-Dimethylbutyl-1-en, 1-Ethylbutyl-1-en, 2-Ethylbutyl-1-en, 1,1,2-Trimethylpropyl-1-en, 1,2,2-Trimethylpropyl-1-en, 1-Ethyl-1-methylpropyl-1-en, 1-Ethyl-2-methylpropyl-1-en steht, X und Y unabhängig voneinander für O (Sauerstoff) oder S (Schwefel) stehen und Q für eine der nachfolgend spezifisch genannten Gruppierungen Q-1 bis Q-54, Q-56 bis Q- 57, Q-60 bis Q-89, Q-91 bis Q-129, Q-131 bis Q-139, Q-141 bis Q-144, Q-146 bis Q- 180, Q-182 bis Q-185, Q-193 bis Q-195, Q-200 bis Q-208, Q-210 bis Q-370, Q-395 bis Q-440 steht:
Description The invention is in the technical field of crop protection agents which can be used against undesired plant growth in non-crop land, for seed preparation or in plant cultures and which contain a combination of at least two herbicides as herbicidal active ingredients, the compositions containing herbicidally active compounds (A) and ( B) in which (A) is one or more compounds of the general formula (I) or their agrochemically acceptable salts [herbicides (A) or component (A)] and (B) is one or more herbicides (component B). Compounds from the structural class of the substituted N-phenyluracils are known as herbicides (see international application with the application number PCT/EP2020/070463, published as WO2021/013799). The compounds are effective against a broad spectrum of harmful plants both pre-emergence and post-emergence, with non-selective use for controlling undesired plant growth or selective use in crops being possible. The effectiveness of these herbicides against harmful plants is at a high level, but generally depends on the application rate, the particular form of preparation, the spectrum of harmful plants, the particular harmful plants to be controlled, the climatic and soil conditions, etc. Another criterion is the duration of the effect or the degradation rate of the herbicide. Changes in the susceptibility of harmful plants, which can occur in the event of prolonged use of the herbicides or in a geographically restricted area, must also be taken into account. Losses of activity in individual plants can only be compensated to a limited extent by higher application rates of the herbicides, e.g. B. because the selectivity of the herbicides is often deteriorated or an improvement in the effect does not occur even at higher application rates. In general, there is a need for methods of achieving the herbicidal action with a lower application rate of active ingredients. A lower application rate not only reduces the amount of an active ingredient required for the application, but also generally reduces the amount of formulation auxiliaries required. Both reduce the economic outlay and improve the ecological compatibility of the herbicide treatment. One way of improving the application profile of a herbicide can be to combine the active ingredient with one or more other active ingredients that have the desired effect add additional properties. However, phenomena of physical and biological incompatibility, e.g. B. lack of stability in a co-formulation, decomposition of an active substance or antagonism of the active substances. What is desired, on the other hand, are combinations of active ingredients with a favorable action profile, high stability and, if possible, unexpectedly synergistically enhanced action, which allows a reduction in the application rate compared to individual application of the active ingredients to be combined. The object of the present invention is to provide alternative or advantageous herbicidal compositions which have a good biological application profile and as many as possible of the desired beneficial properties mentioned above. Surprisingly, it has now been found that this object can be achieved by using a composition containing herbicidally active compounds (A) and (B), where (A) is one or more compounds of the general formula (I) or their agrochemically compatible salts [component (A )] and (B) means one or more herbicides [component (B)] selected from the group consisting of the herbicidally active compounds (B1) to (B11). The compositions according to the invention work together in a particularly favorable manner, for example when they are used to control undesired plant growth in crops such as wheat (durum and common wheat), corn, soybeans, sugar beets, sugar cane, cotton, rice, beans (such as bush beans and horse beans), flax, barley, oats, rye, triticale, potato and millet (sorghum), non-crop land pasture and green/lawn areas and plantation crops. The present invention thus relates to compositions containing herbicidally active compounds (A) and (B), where (A) is one or more compounds of the general formula (I) or their agrochemically compatible salts [component (A)], where R 1 is hydrogen, R 2 is hydrogen, fluoro, chloro, bromo, trifluoromethyl, methoxy, ethoxy, prop-1-yloxy, but-1-yloxy, R 3 is hydrogen, fluoro, chloro, bromo, methoxy, ethoxy, prop-1-yloxy , prop-2-yloxy, but-1-yloxy, but-2-yloxy, 2-methylprop-1-yloxy, 1,1-dimethyleth-1-yloxy, R 4 is fluoro, chloro, bromo, cyano, NO2 , C(O)NH 2 , C(S)NH 2 , trifluoromethyl, difluoromethyl, pentafluoroethyl, ethynyl, propyn-1-yl, 1-butyn-1-yl, pentyn-1-yl, hexyn-1-yl, R 5 , R 6 and R 7 are independently hydrogen, fluoro, chloro, bromo, iodo, cyano, methyl, ethyl, prop-1-yl, 1-methylethyl, but-1-yl, 1-methylpropyl, 2-methylpropyl , 1,1-dimethylethyl, n-pentyl, 1-methylbutyl, 2-methylbutyl, 3-methylbutyl, 1,1-dimethylpropyl, 1,2-dimethylpropyl, 2,2-dimethylpropyl, 1-ethylpropyl, n-hexyl, 1 - methylpentyl, 2-methylpentyl, 3-methylpentyl, 4-methylpentyl, 1,1-dimethylbutyl, 1,2-dimethylbutyl, 1,3-dimethylbutyl, 2,2-dimethylbutyl, 2,3-dimethylbutyl, 3,3 - dimethylbutyl, 1-ethylbutyl, 2-ethylbutyl, 1,1,2-trim ethylpropyl, 1,2,2-trimethylpropyl, 1-ethyl-1-methylpropyl, 1-ethyl-2-methylpropyl, trifluoromethyl, difluoromethyl, pentafluoroethyl, 2,2-difluoroethyl, 2,2,2-trifluoroethyl, methoxy, ethoxy, prop-1-yloxy, prop-2-yloxy, but-1-yloxy, but-2-yloxy, 2-methylprop-1-yloxy, 1,1-dimethyleth-1-yloxy, difluoromethoxy, trifluoromethoxy, pentafluoroethoxy, 2, 2-difluoroethoxy, 2,2,2-trifluoroethoxy, G is methylene, (methyl)methylene, (ethyl)methylene, (prop-1-yl)methylene, (prop-2-yl)methylene, (but-1- yl)methylene, (but-2-yl)methylene, (pent-1-yl)methylene, (pent-2-yl)methylene, (pent-3-yl)methylene, (dimethyl)methylene, (diethyl)methylene, ethylene, n-propylene, (1-methyl)ethyl-1-ene, (2-methyl)ethyl-1-ene, n-butylene, 1-methylpropyl-1-ene, 2-methylpropyl-1-ene, 3- Methylpropyl-1-ene, 1,1-dimethylethyl-1-ene, 2,2-dimethylethyl-1-ene, 1-ethylethyl-1-ene, 2-ethylethyl-1-ene, 1-(prop-1-yl )ethyl-1-ene, 2-(prop-1-yl)ethyl-1-ene, 1-(prop-2-yl)ethyl-1-ene, 2-(prop-2-yl)ethyl-1- en, 1,1,2-trimethylethyl-1-ene, 1,2,2-trimethylet hyl-1-ene, 1,1,2,2-tetramethylethyl-1-ene, n-pentylene, 1-methylbutyl-1-ene, 2-methylbutyl-1-ene, 3-methylbutyl-1-ene, 4- Methylbutyl-1-ene, 1,1-dimethylpropyl-1-ene, 2,2-dimethylpropyl-1-ene, 3,3-dimethylpropyl-1-ene, 1,2-dimethylpropyl-1-ene, 1,3- dimethylpropyl-1-ene, 1-ethylpropyl-1-ene, n-hexylene, 1-methylpentyl-1-ene, 2-methylpentyl-1-ene, 3-methylpentyl-1-ene, 4-methylpentyl-1-ene, 1,1-dimethylbutyl-1-ene, 1,2-dimethylbutyl-1-ene, 1,3-dimethylbutyl-1-ene, 2,2-dimethylbutyl-1-ene, 2,3- dimethylbutyl-1-ene, 3,3-dimethylbutyl-1-ene, 1-ethylbutyl-1-ene, 2-ethylbutyl-1-ene, 1,1,2-trimethylpropyl-1-ene, 1,2,2- trimethylpropyl-1-ene, 1-ethyl-1-methylpropyl-1-ene, 1-ethyl-2-methylpropyl-1-ene, X and Y independently represent O (oxygen) or S (sulphur), and Q represents one of the groups specifically mentioned below Q-1 to Q-54, Q-56 to Q-57, Q-60 to Q-89, Q-91 to Q-129, Q-131 to Q-139, Q-141 to Q-144, Q-146 to Q- 180, Q-182 to Q-185, Q-193 to Q-195, Q-200 to Q-208, Q-210 to Q-370, Q-395 to Q- 440 says:
und (B) für ein oder mehrere Herbizide [Komponente (B)] aus der Gruppe der herbiziden Wirkstoffe (B1) bis (B11) steht, worin (B1) für herbizide Wirkstoffe aus der Gruppe der nachfolgend genannten 1,3-Diketoverbindungen steht (B1.1) Alloxydim, (CAS 55634-91-8), (CAS 55635-13-7) (B1.2) Bicyclopyrone, (CAS 352010-68-5) (B1.3) Butroxydim, (CAS 138164-12-2) (B1.4) Clethodim, (CAS 99129-21-2) (B1.5) Cycloxydim, (CAS 101205-02-1) (B1.6) Fenquinotrione, (CAS 1342891-70-6) (B1.7) Mesotrione, (CAS 104206-82-8) (B1.8) Pinoxaden, (CAS 243973-20-8) (B1.9) Profoxydim, (CAS 139001-49-3) (B1.10) Sethoxydim, (CAS 74051-80-2) (B1.11) Sulcotrione, (CAS 99105-77-8) (B1.12) SYP-9121 (CAS 1976053-87-8) (B1.13) Tefuryltrione, (CAS 473278-76-1) (B1.14) Tembotrione, (CAS 335104-84-2)
(B1.15) Tepraloxydim, (CAS 149979-41-9) (B1.16) Tralkoxydim, (CAS 87820-88-0) (B1.17) Y13161, (CAS 1639426-14-4) (B1.18) Y13287 (CAS 1639426-42-8) (B2) für herbizide Wirkstoffe aus der Gruppe der nachfolgend genannten (Sulfon)Amide steht (B2.1) Acetochlor, (CAS 34256-82-1) (B2.2) Alachlor, (CAS 15972-60-8) (B2.3) Amidosulfuron, (CAS 120923-37-7) (B2.4) Asulam, (CAS 3337-71-1), (CAS 14089-43-1), (CAS 2302-17-2) (B2.5) Azimsulfuron, (CAS 120162-55-2) (B2.6) Beflubutamid, (CAS 113614-08-7), (CAS 113614-09-8) (B2.7) Bensulfuron, (CAS 83055-99-6), (CAS 83055-99-6) (B2.8) Butachlor, (CAS 23184-66-99) (B2.9) Carbetamide, (CAS 16118-49-3) (B2.10) Chlorimuron, (CAS 99283-00-8), (CAS 90982-32-4) (B2.11) Chlorpropham, (CAS 101-21-3) (B2.12) Chlorsulfuron, (CAS 64902-72-3) (B2.13) Cinosulfuron, (CAS 94593-91-6) (B2.14) Cloransulam, (CAS159518-97-5), (CAS 147150-35-4) (B2.15) Cyclosulfamuron, (CAS 136849-15-5) (B2.16) Desmedipham, (CAS 13684-56-5) (B2.17) Diclosulam, (CAS 145701-21-9) (B2.18) Diflufenican, (CAS 83164-33-4) (B2.19) Dimethachlor, (CAS 50563-36-5) (B2.20) Dimethenamid, (CAS 87674-68-8), (CAS 163515-14-8) (B2.21) Esprocarb (CAS 85785-20-2) (B2.22) Ethametsulfuron, (CAS 111353-84-5), (CAS 97780-06-8)
(B2.23) Ethoxysulfuron, (CAS 126801-58-9) (B2.24) Flazasulfuron, (CAS 104040-78-0) (B2.25) Florasulam, (CAS 145701-23-1) (B2.26) Flucarbazone, (CAS 145026-88-6), (CAS 181274-17-9) (B2.27) Flucetosulfuron, (CAS 412928-75-7) (B2.28) Flufenacet, (CAS 142459-58-3) (B2.29) Flumetsulam, (CAS 98967-40-9) (B2.30) Flupyrsulfuron, (CAS 150315-10-9), (CAS 144740-53-4), (CAS 144740-54-5) (B2.31) Foramsulfuron, (CAS 173159-57-4) (B2.32) Halosulfuron, (CAS 135397-30-7), (CAS 100784-20-1) (B2.33) Imazosulfuron, (CAS 122548-33-8) (B2.34) Iodosulfuron, (CAS 185119-76-0), (CAS 144550-06-1), (CAS 144550-36-7) (B2.35) Ipfencarbazone, (CAS 212201-70-2) (B2.36) Mefenacet, (CAS 73250-68-7) (B2.37) Mesosulfuron, (CAS 400852-66-6), (CAS 208465-21-8) (B2.38) Metazachlor, (CAS 67129-08-2) (B2.39) Metazosulfuron, (CAS 868680-84-6) (B2.40) Metolachlor, (CAS 51218-45-2) (B2.41) Metosulam, (CAS 139528-85-1) (B2.42) Metsulfuron, (CAS 79510-48-8), (CAS 74223-64-6) (B2.43) Nicosulfuron, (CAS 111991-09-4) (B2.44) Orthosulfamuron, (CAS 213464-77-8) (B2.45) Oxasulfuron, (CAS 144651-06-9) (B2.46) Penoxsulam, (CAS 219714-96-2) (B2.47) Pethoxamide, (CAS 106700-29-2) (B2.48) Phenmedipham, (CAS 13684-63-4) (B2.49) Picolinafen, (CAS 137641-05-5) (B2.50) Pretilachlor, (CAS 51218-49-6)
(B2.51) Primisulfuron, (CAS 113036-87-6), (CAS 86209-51-0) (B2.52) Propachlor, (CAS 1918-16-7) (B2.53) Propanil, (CAS 709-98-8) (B2.54) Propham, (CAS 122-42-9) (B2.55) Propisochlor, (CAS 86763-47-5) (B2.56) Propoxycarbazone, (CAS 145026-81-9), (CAS 181274-15-7) (B2.57) Propyrisulfuron, (CAS 570415-88-2) (B2.58) Propyzamide, (CAS 23950-58-5) (B2.59) Prosulfocarb, (CAS 52888-80-9) (B2.60) Prosulfuron, (CAS 94125-34-5) (B2.61) Pyrazosulfuron, (CAS 98389-04-9), (CAS 93697-74-6) (B2.62) Pyroxsulam, (CAS 422556-08-9) (B2.63) Rimsulfuron, (CAS 122931-48-0) (B2.64) S-metolachlor, (CAS 87392-12-9) (B2.65) Sulfometuron, (CAS 74223-56-6), (CAS 74222-97-2), (CAS 144651-06-9) (B2.66) Sulfosulfuron, (CAS 141776-32-1) (B2.67) Thenylchlor, (CAS 96491-05-3) (B2.68) Thiencarbazone, (CAS 936331-72-5), (CAS 317815-83-1) (B2.69) Thifensulfuron, (CAS 79277-67-1), (CAS 79277-27-3) (B2.70) Tri-allat, (CAS 2303-17-5) (B2.71) Triasulfuron, (CAS 82097-50-5) (B2.72) Tribenuron, (CAS 106040-48-6), (CAS 101200-48-0) (B2.73) Trifloxysulfuron, (CAS 145099-21-4, (CAS 199119-58-9) (B2.74) Triflusulfuron, (CAS 135990-29-3), (CAS 126535-15-7) (B2.75) Tritosulfuron, (CAS 142469-14-5) (B2.76) Esprocarb, (CAS 85785-20-2)
(B2.77) Profluazol, (CAS 190314-43-3) (B2.78) Tri-allate, (CAS 2303-17-5) (B2.79) Methyl rel-(2R,4R)-4-[[3-(3,5-dichlorophenyl)-5- methoxy-4H-isoxazol-5- carbonyl]amino]tetrahydrofuran-2-carboxylat, (B2.80) Methyl rel-(2R,4R)-4-[[3-(3,5-dichlorophenyl)-5- vinyl-4H-isoxazol-5- carbonyl]amino]tetrahydrofuran-2-carboxylat, (B2.81) Methyl –rel-(2R,4R)-4-[[(5S)-3-(3,5- difluorophenyl)-5-vinyl-4H-isoxazol-5- carbonyl]amino]tetrahydrofuran-2-carboxylat, (B2.82) Isopropyl rel-(2R,4R)-4-[[3-(3-fluorophenyl)-5- methyl-4H-isoxazol-5- carbonyl]amino]tetrahydrofuran-2-carboxylat, (B2.83) Methyl (3R)-3-[[(5S)-3-(3,5-difluorophenyl)-5- vinyl-4H-isoxazol-5-carbonyl]amino]-2,3- dihydrofuran-5-carboxylat, (B2.84) Methyl (3R)-3-[[(5R)-3-(3,5-difluorophenyl)-5- methyl-4H-isoxazol-5-carbonyl]amino]-2,3- dihydrofuran-5-carboxylat, (B2.85) Methyl (1S,4R)-4-[[[(5S)-3-(3,5-difluorphenyl)-5- vinyl-4H-1,2-oxazol-5-yl]carbonyl]amino]- cyclopent-2-en-1-carboxylat, (B2.86) Ethyl (1S,4R)-4-[[[3-(3,5-difluorphenyl)-5- methoxy-4H-1,2-oxazol-5- yl]carbonyl]amino]cyclopent-2-en-1-carboxylat, (B2.87) 2-Methoxyethyl (1S,4R)-4-[[[(5R)-3-(3-cyano-5- fluorphenyl)-5-(trifluormethyl)-4H-1,2-oxazol-5- yl]carbonyl]amino]cyclopent-2-en-1-carboxylat, (B2.88) Methyl (4S)-4-[[[3-(3,5-difluorphenyl)-5-methyl- 4H-1,2-oxazol-5-yl]carbonyl]amino]cyclopenten-1- carboxylat, (B2.89) Methyl (3S)-3-[[[(5R)-3-(3,5-difluorphenyl)-5- methyl-4H-1,2-oxazol-5-yl]carbonyl]amino]- cyclopenten-1-carboxylat,
(B2.90) 3-(3,5-Difluorphenyl)-N-[(1R,4S)-4-(oxazinan-2- ylcarbonyl)cyclopent-2-en-1-yl]-5-(trifluormethyl)- 4H-1,2-oxazol-5-carboxamid, (B2.91) 3-(3,5-Difluorphenyl)-N-[(1R,4S)-4- [(propylsulfonylamino)carbonyl]cyclopent-2-en-1- yl]-5-(trifluormethyl)-4H-1,2-oxazol-5-carboxamid, (B2.92) (1S,4R)-4-[[(5R)-3-(3,5-difluorophenyl)-5-methyl- 4H-isoxazol-5-carbonyl]amino]cyclopent-2-ene-1- carbonsäure (B3) für herbizide Wirkstoffe aus der Gruppe der nachfolgend genannten Arylnitrile steht (B3.1) Bromoxynil, (CAS 1689-84-5) (CAS 3861-41-4), (CAS 56634-95-8), (CAS 1689-99-2), (CAS 2961-68-4) (B3.2) Chlorthiamid, (CAS 1918-13-4) (B3.3) Dichlobenil, (CAS 1194-65-6) (B3.4) Ioxynil, (CAS 1689-83-4), (CAS 2961-61-7), (CAS 3861-47-0), (CAS 2961-62-8) (B3.5) Pyraclonil (CAS 158353-15-2) (B4) für herbizide Wirkstoffe aus der Gruppe der nachfolgend genannten Azole steht (B4.1) Amicarbazone, (CAS 129909-90-6) (B4.2) Amitrole, (CAS 61-82-5) (B4.3) Azafenidin, (CAS 68049-83-2) (B4.4) Benzofenap, (CAS 82692-44-2) (B4.5) Benzuofucaotong (CAS 1992017-55-6) (B4.6) Biscarfentrazone (CAS 1622908-18-2) (B4.7) Cafenstrole, (CAS 125306-83-4) (B4.8) Carfentrazone, (CAS 128621-72-7), (CAS128639-02-1) (B4.9) Fentrazamide, (CAS 158237-07-1) (B4.10) Imazamethabenz, (CAS 100728-84-5), (CAS 81405-85-8) (B4.11) Imazamox, (CAS 114311-32-9), (CAS 247057-22-3) (B4.12) Imazapic, (CAS 104098-48-8), (CAS 115136-53-3) (B4.13) Imazapyr, (CAS 81334-34-1), (CAS 81510-83-0) (B4.14) Imazaquin, (CAS 81335-37-7), (CAS 81335-47-9), (CAS 81335-43-5), (CAS 81335-46-8)
(B4.15) Imazethapyr, (CAS 81335-77-5), (CAS 101917-66-2) (B4.16) Isouron, (CAS 55861-78-4) (B4.17) Isoxaben, (CAS 82558-50-7) (B4.18) Isoxaflutole, (CAS 141112-29-0) (B4.19) Oxadiargyl, (CAS 39807-15-3) (B4.20) Oxadiazon, (CAS 19666-30-9) (B4.21) Pyraflufen, (CAS 129630-17-7), (CAS 129630-19-9) (B4.22) Pyrasulfotole, (CAS 365400-11-9) (B4.23) Pyrazolynate, (CAS 58011-68-0) (B4.24) Pyrazoxyfen, (CAS 71561-11-0) (B4.25) Pyroxasulfone, (CAS 447399-55-5) (B4.26) Sulfentrazone, (CAS 122836-35-5) (B4.27) Tolpyralate, (CAS 1101132-67-5) (B4.28) Topramezone, (CAS 210631-68-8) (B4.29) Triazolesulcotrione (CAS 1911613-97-2) (QYR-301), (B4.30) QYM-201, (CAS 1855925-45-1) (B4.31) Bencarbazone, (CAS 173980-17-1) (B4.32) Fluazolate, (CAS 174514-07-9) (B4.33) Flupoxam, (CAS 119126-15-7) (B4.34) Isoxachlortole (CAS 141112-06-3) (B5) für weitere nachfolgend genannte herbizide Wirkstoffe steht, (B5.1) Aminocyclopyrachlor, (CAS 858956-08-8), (CAS 858954-83-3), (CAS 858956-35-1) (B5.2) Aminopyralid, (CAS 150114-71-9), (CAS 566191-87-5), (CAS 566191-89-7) (B5.3) Benazolin-ethyl, (CAS 3813-05-6), (CAS 38561-76-1), (CAS 25059-80-7), (CAS 67338-65-2) (B5.4) Benfluralin, (CAS 1861-40-1) (B5.5) Bentazone, (CAS 25057-89-0), (CAS 50723-80-3) (B5.6) Benzobicyclon, (CAS 156963-66-5) (B5.7) Bixlozone (CAS 81777-95-9) (B5.8) Bromofenoxim, (CAS 13181-17-4) (B5.9) Butralin, (CAS 33629-47-9) (B5.10) Chloridazon/Pyrazon, (CAS 1698-60-8)
(B5.11) Chlorthal, (CAS 2136-79-0), (CAS 1861-32-1), (CAS 887-54-7) (B5.12) Cinidon-ethyl, (CAS 142891-20-1) (B5.13) Cinmethylin, (CAS 87818-31-3) (B5.14) Clomazone, (CAS 81777-89-1) (B5.15) Cyclopyrimorat, (CAS 499231-24-2) (B5.16) Dinitramine, (CAS 29091-05-2) (B5.17) Diquat, (CAS 2764-72-9), (CAS 85-00-7), (CAS 4032-26-2) (B5.18) Dithiopyr, (CAS 97886-45-8) (B5.19) Essigsäure, (CAS 64-19-7) (B5.20) Ethalfluralin, (CAS 55283-68-6) (B5.21) Ethofumesate, (CAS 26225-79-6) (B5.22) Flamprop, (CAS 58667-63-3, (CAS 90134-59-1), (CAS 63782-90-1), (CAS 63729-98-6) (B5.23) Florpyrauxifen, (CAS 943832-81-3), (CAS 1390661-72-9) (B5.24) Flufenpyr, (CAS 188490-07-5), (CAS 188489-07-8) (B5.25) Flumiclorac, (CAS 87547-04-4), (CAS 87546-18-7) (B5.26) Flumioxazin, (CAS 103361-09-7) (B5.27) Fluridone, (CAS 59756-60-4) (B5.28) Flurochloridone, (CAS 61213-25-0) (B5.29) Flurtamone, (CAS 96525-23-4) (B5.30) Fluthiacet-methyl, (CAS 149253-65-6) (B5.31) Halauxifen, (CAS 943832-60-8), (CAS 943831-98-9) (B5.32) Indanofan, (CAS 13320-30-1) (B5.33) Norflurazon, (CAS 27314-13-2) (B5.34) Oleinsäure (CAS 112-80-1) (B5.35) Oryzalin, (CAS 19044-88-3) (B5.36) Oxaziclomefone, (CAS 153197-14-9) (B5.37) Paraquat, (CAS 4685-14-7), (CAS 1910-42-5), (CAS 2074-50-2) (B5.38) Pelargonsäure, (CAS 112-05-0) (B5.39) Pendimethalin, (CAS 40487-42-1) (B5.40) Pentoxazone, (CAS 110956-75-7) (B5.41) Pyridafol, (CAS 40020-01-7) (B5.42) Pyridate, (CAS 55512-33-9)
(B5.43) Tetflupyrolimet, (CAS 2053901-33-8) (B5.44) Thiazopyr, (CAS 117718-60-2) (B5.45) Triafamone, (CAS 874195-61-6) (B5.46) Trifluralin, (CAS 1582-09-8) (B5.47) 4-Amino-3-chloro-5-fluoro- 6-(7-fluoro-1H-indol-6- yl)pyridine-2-carbonsäure (B5.48) Cyclopyrimorate, (CAS 499231-24-2) (B5.49) Diquat, (CAS 2764-72-9), (CAS 85-00-7), (CAS4032-26-2) (B5.50) Oxaziclomefone, (CAS 153197-14-9) (B5.51) Pentanochlor, (CAS 2307-68-8) (B5.52) Tebutam, (CAS 35256-85-0) (B5.53) Thidiazimin, (CAS 123249-43-4) (B5.54) 4-Hydroxy-1-methyl-3-[4- (CAS 1708087-22-2) (trifluoromethyl)-2- pyridinyl]-2-imidazolidinon (B6) für herbizide Wirkstoffe aus der Gruppe der nachfolgend genannten (Het)Arylcarbonsäuren steht (B6.1) Chloramben, (CAS 133-90-4), (CAS 1076-46-6), (CAS 53404-16-3), (CAS 7286-84-2), (CAS 25182-03-0), (1954-81-0) (B6.2) Clopyralid, (CAS 1702-17-6), (CAS 1532-24-7), (CAS 57754-85-5), (CAS 58509-83-4), (CAS 73455-09-1) (B6.3) Dicamba, (CAS 1918-00-9), (CAS 1286239-22-2), (CAS 104040-79-1), (CAS 2300-66-5), (CAS 25059-78-3), (CAS 55871-02-8), (CAS 6597-78-0), (CAS 53404-28-7), (CAS 10007-85-9), (CAS 1982-69-0), (53404-29-8), (CAS 56141-00-5) (B6.4) Fluroxypyr, (CAS 69377-81-7), (CAS -27-8), (CAS 81406-37-3)
(B6.5) Picloram, (CAS 1918-02-1), (CAS 55870-98-9), (CAS 36374-99-9), (CAS 26952-20-5), (CAS 14143-55-6), (CAS 55871-00-6), (CAS 2545-60-0), (CAS 35832-11-2), (CAS 6753-47-5), (CAS 82683-78-1) (B6.6) Quinclorac, (CAS 84087-01-4), (CAS 84087-48-9), (CAS 84087-33-2) (B6.7) Quinmerac, (CAS 90717-03-6) (B6.8) TBA, (CAS 50-31-7), (CAS 3426-62-8), (CAS 71750-37-3), (CAS 4559-30-2), (CAS 2078-42-4) (B6.9) Triclopyr (CAS 55335-06-3), (CAS [64700-56-7), (CAS 1048373-85-8), (CAS 60825-27-6), (CAS 57213-69-1) (B7) für herbizide Wirkstoffe aus der Gruppe der nachfolgend genannten organischen Phosphorverbindungen steht (B7.1) Anilofos, (CAS 64249-01-0) (B7.2) Bialaphos, (CAS 35597-43-4), (CAS 71048-99-2) (B7.3) Butamifos, (CAS 36335-67-8) (B7.4) Glufosinate, (CAS 51276-47-2), (CAS 35597-44-5), (CAS 77182-82-2), (CAS 70033-13-5) (B7.5) Glyphosate, (CAS 1071-83-6), (CAS 69254-40-6), (CAS 34494-04-7), (CAS 38641-94-0), (CAS 40465-66-5), (CAS 39600-42-5), (CAS 70393-85-0), (CAS 81591-81-3) (B7.6) Piperophos, (CAS 24151-93-7) (B7.7) Sulfosate, (CAS 1591-81-3) (B7.8) Amiprofos (CAS 33857-23-7, (CAS 36001-88-4) (B8) für herbizide Wirkstoffe aus der Gruppe der nachfolgend genannten Phenylether steht (B8.1) 2,4-D, (CAS 94-75-7), (CAS 2307-55-3), (CAS 1929-73-3), (CAS 1320-18-9), (CAS 1928-45-6), (CAS 94-80-4), (CAS 1048373-72-3), (CAS 20940-37-8), (CAS 2008-39-1), (CAS 5742-19-8),
(CAS 2212-54-6), (CAS 533-23-3), (CAS 1928-43-4), (CAS 37102-63-9), (CAS 713-15-1), (CAS 25168-26-7), (CAS 94-11-1), (CAS 5742-17-6), (CAS 3766-27-6), (CAS 1917-97-1), (CAS 1928-38-7), (CAS 1928-44-5), (CAS 1917-92-6), (CAS 1928-61-6), (CAS 2702-72-9), (CAS 15146-99-3), (CAS 28685-18-9), (CAS 2646-78-8), (CAS 18584-79-7), (CAS 2569-01-9), (CAS 215655-76-8) (B8.2) 2,4-DB, (CAS 94-82-6), (CAS 2758-42-1), (CAS 1320-15-6), (CAS 19480-40-1), (CAS 10433-59-7) (B8.3) 2,4-DP, (CAS 120-36-5), (CAS 53404-31-2), (CAS 53404-32-3), (CAS 79270-78-3), (CAS 28631-35-8), (CAS 57153-17-0), (CAS 5746-17-8), (CAS 39104-30-8) (B8.4) Acifluorfen, (CAS 50594-66-6), (CAS 50594-67-7), (CAS 62476-59-9) (B8.5) Aclonifen, (CAS 74070-46-5) (B8.6) Bifenox, (CAS 42576-02-3) (B8.7) Chlomethoxyfen, (CAS 32861-85-1) (B8.8) Clodinafop- (CAS 114420-56-3), (CAS 105512-06-9) propargyl, (B8.9) Clomeprop, (CAS 84496-56-0) (B8.10) Cyhalofop, (CAS 122008-78-0), (CAS 122008-85-9) (B8.11) Diclofop, (CAS 40843-25-2), (CAS 51338-27-3) (B8.12) Ethoxyfen, (CAS 188634-90-4), (CAS 131086-42-5) (B8.13) Fenoxaprop, (CAS 95617-09-7), (CAS 113158-40-0), (CAS 71283-80-2) (B8.14) Fluazifop, (CAS 69335-91-7), (CAS 83066-88-0), (CAS 79241-46-6) (B8.15) Fluoroglycofen, (CAS 77501-60-1), (CAS 77501-90-7) (B8.16) Fomesafen, (CAS 72178-02-0), (CAS 108731-70-0) (B8.17) Halosafen, (CAS 77227-69-1)
(B8.18) Haloxyfop, (CAS 69806-34-4), (CAS 95977-29-0), (CAS 72619-32-0) (B8.19) Lactofen, (CAS 77501-63-4) (B8.20) MCPA, (CAS 94-74-6), (CAS 19480-43-4), (CAS 1713-12-8), (CAS 2039-46-5), (CAS 20405-19-0), (CAS 2698-38-6), (CAS 29450-45-1), (CAS 1713-11-7), (CAS 26544-20-7), (CAS 2698-40-0), (CAS 2436-73-9), (CAS 6365-62-4), (CAS 5221-16-9), (CAS 3653-48-3), (CAS 42459-68-7) (B8.21) MCPB, (CAS 94-81-5), (CAS 10443-70-6), (CAS 57153-18-1), (CAS 6062-26-6) (B8.22) Mecoprop, (CAS 93-65-2), (CAS 32351-70-5), (CAS 1432-14-0), (CAS 71526-69-7), (CAS 28473-03-2), (CAS 2786-19-8), (CAS 1929-86-8), (CAS 19095-88-6), (CAS 53404-61-8), (CAS 16484-77-8) (B8.23) Metamifop, (CAS 256412-89-2) (B8.24) Oxyfluorfen, (CAS 42874-03-3) (B8.25) Propaquizafop, (CAS 111479-05-1) (B8.26) Quizalofop, (CAS 76578-12-6), (CAS 76578-14-8), (B8.27) Quizalofop-P, (CAS 94051-08-8), (CAS 100646-51-3), (CAS 200509-41-7) (B8.28) Benzfendizone (CAS 158755-95-4) (B9) für herbizide Wirkstoffe aus der Gruppe der nachfolgend genannten Pyrimidine steht (B9.1) Bispyrac-sodium, (CAS 125401-92-5) (B9.2) Bromacil, (CAS 314-40-9), (CAS 53404-19-6), (CAS 69484-12-4) (B9.3) Butafenacil, (CAS 134605-64-4) (B9.4) Lenacil, (CAS 2164-08-1) (B9.5) Pyribenzoxim, (CAS 168088-61-7) (B9.6) Pyriftalid, (CAS 135186-78-6) (B9.7) Pyriminobac, (CAS 136191-56-5), (CAS 136191-64-5) (B9.8) Pyrimisulfan, (CAS 221205-90-9)
(B9.9) Pyrithiobac-sodium, (CAS 123342-93-8), (CAS 123343-16-8) (B9.10) Saflufenacil, (CAS 372137-35-4) (B9.11) Terbacil, (CAS 5902-51-2) (B9.12) Tiafenacil, (CAS 1220411-29-9) (B9.13) Trifludimoxazin, (CAS 1258836-72-4) (B9.14) Ethyl[3-[2-chloro-4-fluoro-5- (CAS 353292-31-6) (1-methyl-6-trifluoromethyl- 2,4-dioxo-1,2,3,4- tetrahydropyrimidin-3- yl)phenoxy]-2- pyridyloxy]acetat (B10) für herbizide Wirkstoffe aus der Gruppe der nachfolgend genannten (Thio)harnstoffe steht (B10.1) Chlorobromuron, (CAS 13360-45-7) (B10.2) Chlorotoluron, (CAS 15545-48-9) (B10.3) Daimuron, (CAS 42609-52-9) (B10.4) Dimefuron, (CAS 34205-21-5) (B10.5) Diuron, (CAS 330-54-1) (B10.6) Diflufenzopyr (CAS 1957168-02-3) (B10.7) Fluometuron, (CAS 2164-17-2) (B10.8) Isoproturon, (CAS 34123-59-6) (B10.9) Linuron, (CAS 330-55-2) (B10.10) Methabenzthiazuron, (CAS 18691-97-9) (B10.11) Metobromuron, (CAS 3060-89-7) (B10.12) Metoxuron, (CAS 19937-59-8) (B10.13) Monolinuron, (CAS 1746-81-2) (B10.14) Neburon, (CAS 555-37-3) (B10.15) Siduron, (CAS 1982-49-6) (B10.16) Tebuthiuron, (CAS 34014-18-1) (B10.17) Fenuron, (CAS 101-42-8) (B10.18) Chloroxuron, (CAS 1982-47-4) (B10.19) Diflufenzopyr, (CAS 1957168-02-3, CAS 109293-98-3) (B10.20) Ethidimuron (CAS 30043-49-3)
(B11) für herbizide Wirkstoffe aus der Gruppe der nachfolgend genannten Triazine steht (B11.1) Ametryne, (CAS 834-12-8) (B11.2) Atrazine, (CAS 1912-24-9) (B11.3) Cyanazine, (CAS 21725-46-2) (B11.4) Dimethametryn, (CAS 22936-75-0) (B11.5) Hexazinone, (CAS 51235-04-2) (B11.6) Indaziflam, (CAS 950782-86-2) (B11.7) Metamitron, (CAS 41394-05-2) (B11.8) Metribuzin, (CAS 21087-64-9) (B11.9) Prometon, (CAS 1610-18-0) (B11.10) Prometryne, (CAS 7287-19-6) (B11.11) Propazine, (CAS 139-40-2) (B11.12) Simazine, (CAS 122-34-9) (B11.13) Simetryne, (CAS 1014-70-6) (B11.14) Terbumeton, (CAS 33693-04-8) (B11.15) Terbuthylazine, (CAS 5915-41-3) (B11.16) Terbutryne, (CAS 886-50-0) (B11.17) Triaziflam, (CAS 131475-57-5) (B11.18) Trietazine, (CAS 1912-26-1) (B11.19) Desmetryne (CAS 1014-69-3) bedeuten. Die Bezeichnungen der oben aufgelisteten Herbizide (Common name) ist durch die in Klammern aufgeführte „CAS RN“ (Chemical Abstract Service Registry Number) (kurz „CAS“) ergänzt. Die CAS RN ist eine allgemein gebräuchlichen Referenznummer, die eine eindeutige Zuordnung der bezeichneten Substanzen ermöglicht, da die „CAS RN“ u.a. zwischen Isomeren, einschließlich Stereoisomeren, sowie Salzen und Estern unterscheidet. Für Wirkstoffe, die in verschiedenen Formen existieren, ist in der obigen Auflistung jeweils der Name der Neutralverbindung angegeben. Die in Klammern angegeben CAS richten auf diese, sowie auf sämtliche, weitere bekannte Formen des Wirkstoffs, wie zum Beispiel Salze oder Addukte. Beispielhaft, aber nicht einschränkend, seien an dieser Stelle genannt: 2,4-D-Ammonium; 2,4-D-Cholin (das Choline Salz von 2,4-D); 2,4-D-BAPMA (N,N-Bis-(3- aminopropyl)methylamin Salz von 2,4-D); 2,4-D-Diethylammonium; 2,4-D-Dimethylammonium; 2,4- D-Dodecylammonium; 2,4-D-Heptylammonium; 2,4-D-Isopropylammonium; 2,4-D-Lithium; 2,4-D- Kalium; 2,4-D-Natrium; 2,4-D-Tetradecylammonium; 2,4-D-Triethylammonium; 2,4-D-Tris(2- hydroxypropyl)ammonium; 2,4-D-Monoethanolammonium (das Monoethanolamin Salz von 2,4-D); 2,4-D-Diethanolammonium (das Diethanolamin Salz von 2,4-D oder 2,4-D-Diolamin); 2,4-D-
Triethanolammonium (das Triethanolamin salt of 2,4-D oder 2,4-D-Triolamin); das Tetrabutylamin Salz von Dicamba; das Dimethylamin Salz von Dicamba; das Isopropylamin Salz von Dicamba; das Diglycolamin Salz von Dicamba; das N,N-Bis-(3-aminopropyl)methylamin Salz von Dicamba; das Cholin Salz von Dicamba; das Monoethanolamin Salz von Dicamba; das Diethanolamin Salz von Dicamba; das Triethanolamin Salz von Dicamba; Das Kalium-Salz von Dicamba; das Natrium-Salz von Dicamba; Glyphosate-diammonium; Glyphosate-dimethylammonium; Glyphosate-isopropylammonium; Glyphosate-monoammonium; Glyphosate-Kalium; Glyphosate-Dikalium; Glyphosate-sesquisodium (N- (phosphonomethyl)glycin Natrium-Salz (2:3)); das Trimethylsulfonium Salz von Glyphosate (Glyphosate-trimesium); das Triethanolamin Salz von Glyphosate; das Diethanolamin Salz von Glyphosate; und das Monoethanolamin Salz von Glyphosate. Im Folgenden wird immer nur die Neutralverbindung genannt und umfasst damit sämtliche existieren Formen wie aufgelistet, es sei denn, eine spezifische Form des Wirkstoffs ist in einem bestimmten Zusammenhang relevant, wie z.B. in nachstehenden Tabellenbeispiele für die biologische Wirksamkeit. Die erfindungsgemäßen Zusammensetzungen können weitere Komponenten enthalten, z. B. andere Wirkstoffe gegen Schadorganismen wie Schadpflanzen, pflanzenschädliche Tiere oder pflanzenschädliche Pilze, insbesondere dabei Wirkstoffe aus der Gruppe der Herbizide, Fungizide, Insektizide, Akarizide, Nematizide und Mitizide und verwandte Stoffe, oder auch Pflanzenschutzmittelwirkstoffe anderer Art (z. B. Resistenzinduktoren), kulturpflanzenschonende Wirkstoffe (Safener, Antidots), Pflanzenwachstumsregulatoren und/oder im Pflanzenschutz übliche Zusatzstoffe und/oder Formulierungshilfsmittel. Die Komponenten können dabei gemeinsam formuliert (Fertigformulierung) und angewendet werden oder sie können getrennt formuliert und gemeinsam angewendet werden, z. B. im Tank-Mix oder in sequentieller Applikation. Die als Komponente (A) enthaltenen einzelnen herbiziden Wirkstoffe der allgemeinen Formel (I) werden im Folgenden auch als Verbindungen (A), Wirkstoffe (A), Komponenten (A) oder Herbizide (A) bezeichnet. Entsprechend werden die als Komponente (B) enthaltenen einzelnen herbiziden Wirkstoffe im Folgenden auch als Verbindungen (B), Wirkstoffe (B), Komponenten (B) oder Herbizide (B) bezeichnet. Als vorteilhafte Eigenschaft der erfindungsgemäßen Kombination von Herbiziden (A) und (B) zeigt sich, dass Wirkstoffe (A) und (B) miteinander kompatibel sind, d. h. sie lassen sich gemeinsam anwenden, ohne dass wesentliche chemische Unverträglichkeiten der Wirkstoffe (A) und/oder (B) auftreten, die zu einer Zersetzung eines oder mehrerer Wirkstoffe führen. Damit wird eine Reduzierung des Wirkstoffgehalts in Formulierungen oder Spritzbrühen vermieden. Die günstige Kompatibilität erstreckt sich auch auf die biologischen Eigenschaften der Wirkstoffe bei der kombinierten Anwendung.
So werden antagonistische Effekte bei der Kontrolle von Schadpflanzen mit den erfindungsgemäßen Wirkstoff-Kombinationen in der Regel nicht beobachtet. Damit sind die Wirkstoffe (A) und (B) besonders geeignet, gemeinsam oder zusätzlich mit weiteren Pflanzenschutzmittelwirkstoffen oder Agrochemikalien angewendet zu werden. Die ermöglichte kombinierte Anwendung erlaubt die Nutzung vorteilhafter Effekte, wie beispielsweise die Ausweitung des Spektrums der zu kontrollierenden oder zu bekämpfenden Schadpflanzen bei einer Anwendung, die Reduzierung der Aufwandmenge der einzelnen Herbizide (A) bzw. (B) im Vergleich zur jeweiligen Aufwandmenge des betreffenden Herbizids bei der Einzelapplikation. Damit kann das Abbauverhalten der Wirkstoffe beeinflusst und günstigere Bedingungen für den Nachbau von Kulturpflanzen erreicht werden. Ein weiterer Vorteil ist darin zu sehen, dass die Entstehung von Resistenzen der Schadpflanzen gegen die Wirkstoffe durch Kombination von Wirkstoffen mit unterschiedlichem Wirkungsmechanismus oft wesentlich verringert werden oder vermieden werden kann. Insbesondere treten überraschenderweise bei der kombinierten Anwendung der Wirkstoffe (A) und (B) bei einer größeren Zahl wirtschaftlich wichtiger Schadpflanzen überadditive (= synergistische) Effekte auf. Dabei ist die Wirkung in der Kombination stärker als die zu erwartende Summe der Wirkungen der eingesetzten Einzelherbizide. Die synergistischen Effekte erlauben eine weitere Reduzierung der Aufwandmenge, die Bekämpfung eines breiteren Spektrums von Unkräutern und Ungräsern, einen schnelleren Einsatz der herbiziden Wirkung, eine längere Dauerwirkung, eine bessere Kontrolle der Schadpflanzen mit nur einer bzw. wenigen Applikationen sowie eine Ausweitung des möglichen Anwendungszeitraumes. Teilweise wird durch den Einsatz der Mittel auch die Menge an schädlichen Inhaltsstoffen, wie Stickstoff oder Ölsäure, und deren Eintrag in den Boden reduziert. Die genannten Eigenschaften und Vorteile sind in der praktischen Unkrautbekämpfung gewünscht, um landwirtschaftliche Kulturen von unerwünschten Konkurrenzpflanzen freizuhalten und damit die Erträge qualitativ und quantitativ zu sichern und/oder zu erhöhen. Der technische Standard wird durch die neuen Kombinationen hinsichtlich der beschriebenen Eigenschaften deutlich übertroffen. Die synergistischen Wirkungen werden bei gemeinsamer Ausbringung der Wirkstoffe (A) und (B) beobachtet, können jedoch auch häufig bei zeitlich versetzter Anwendung (Splitting) auftreten. Möglich ist auch die Anwendung der Herbizide (A) bzw. (B) oder der herbiziden Zusammensetzung (A) und (B) in mehreren Portionen (Sequenzanwendung). Beispielsweise kann nach einer oder mehreren Anwendungen im Vorauflauf eine Nachauflauf-Applikation erfolgen, oder nach einer frühen Nachauflaufanwendung kann eine Applikation im mittleren oder späten Nachauflauf erfolgen. Bevorzugt ist dabei die simultane oder zeitnahe Anwendung der Wirkstoffe der jeweiligen Kombination, gegebenenfalls in mehreren Portionen. Aber auch die zeitversetzte Anwendung der Einzelwirkstoffe einer Kombination ist möglich und kann im Einzelfall vorteilhaft sein. In das System der Anwendung
können auch andere Pflanzenschutzmittel, wie beispielsweise die erwähnten anderen Wirkstoffe (andere Herbizide, Fungizide, Insektizide, Akarizide etc.) und/oder verschiedene Hilfsstoffe, Adjuvantien und/oder Düngergaben, integriert werden. Unter Anwendung im Vorauflauf- oder Nachauflaufverfahren ist je nach dem Zusammenhang, in dem die Bezeichnungen verwendet werden, die Anwendung der Wirkstoffe vor dem bzw. nach dem obererdig sichtbaren Erscheinen der Schadpflanzen zu verstehen oder die Anwendung der Wirkstoffe gegen die Schadpflanzen vor Auflauf der Kulturpflanzen bzw. nach Auflauf der Kulturpflanzen zu verstehen. In der Formel (I) für Verbindungen der herbiziden Wirkstoffe (A) und allen nachfolgenden Formeln gelten folgende Definitionen: Die Verbindungen der Formel (I) können je nach Art und Verknüpfung der Substituenten als Stereoisomere vorliegen. Sind beispielsweise ein oder mehrere asymmetrisch substiuierte Kohlenstoff- atome und/oder Sulfoxide vorhanden, so können Enantiomere und Diastereomere auftreten. Stereoisomere lassen sich aus den bei der Herstellung anfallenden Gemischen nach üblichen Trennmethoden, beispielsweise durch chromatographische Trennverfahren, erhalten. Ebenso können Stereoisomere durch Einsatz stereoselektiver Reaktionen unter Verwendung optisch aktiver Ausgangs- und/oder Hilfsstoffe selektiv hergestellt werden. Die Erfindung betrifft auch alle Stereoisomeren und deren Gemische, die von der Formel (I) umfaßt, jedoch nicht spezifisch definiert sind. Im Folgenden wird der Einfachheit halber jedoch stets von Verbindungen der Formel (I) gesprochen, obwohl sowohl die reinen Verbindungen als gegebenenfalls auch Gemische mit unterschiedlichen Anteilen an isomeren Verbindungen gemeint sind. Je nach Art der oben definierten Substituenten weisen die Verbindungen der Formel (I) saure Eigenschaften auf und können mit anorganischen oder organischen Basen oder mit Metallionen Salze, gegebenenfalls auch innere Salze oder Addukte bilden. Tragen die Verbindungen der Formel (I) Hydroxy, Carboxy oder andere, saure Eigenschaften induzierende Gruppen, so können diese Verbindungen mit Basen zu Salzen umgesetzt werden.Geeignete Basen sind beispielsweise Hydroxide, Carbonate, Hydrogencarbonate der Alkali- und Erdalkalimetalle, insbesondere die von Natrium, Kalium, Magnesium und Calcium, weiterhin Ammoniak, primäre, sekundäre und teritäre Amine mit (C1-C4-)- Alkyl-Gruppen, Mono-, Di- und Trialkanolamine von (C1-C4)-Alkanolen, Cholin sowie Chlorcholin, sowie organische Amine, wie Trialkylamine, Morpholin, Piperidin oder Pyridin. Diese Salze sind Verbindungen, in denen der acide Wasserstoff durch ein für die Landwirtschaft geeignetes Kation ersetzt wird, beispielsweise Metallsalze, insbesondere Alkalimetallsalze oder Erdalkalimetallsalze,
insbesondere Natrium- und Kaliumsalze, oder auch Ammoniumsalze, Salze mit organischen Aminen oder quartäre (quaternäre) Ammoniumsalze, zum Beispiel mit Kationen der Formel [NRR´R´´R´´´]+, worin R bis R´´´ jeweils unabhängig voneinander einen organischen Rest, insbesondere Alkyl, Aryl, Aralkyl oder Alkylaryl darstellen. Infrage kommen auch Alkylsulfonium- und Alkylsulfoxoniumsalze, wie (C1-C4)-Trialkylsulfonium- und (C1-C4)-Trialkylsulfoxoniumsalze. Die Verbindungen der Formel (I) können durch Anlagerung einer geeigneten anorganischen oder organischen Säure, wie beispielsweise Mineralsäuren, wie beispielsweise HCl, HBr, H2SO4, H3PO4 oder HNO3, oder organische Säuren, z. B. Carbonsäuren, wie Ameisensäure, Essigsäure, Propionsäure, Oxalsäure, Milchsäure oder Salicylsäure oder Sulfonsäuren, wie zum Beispiel p-Toluolsulfonsäure, an eine basische Gruppe, wie z.B. Amino, Alkylamino, Dialkylamino, Piperidino, Morpholino oder Pyridino, Salze bilden. Diese Salze enthalten dann die konjugierte Base der Säure als Anion. Geeignete Substituenten, die in deprotonierter Form, wie z.B. Sulfonsäuren oder Carbonsäuren, vorliegen, können innere Salze mit ihrerseits protonierbaren Gruppen, wie Aminogruppen bilden. Ist eine Gruppe mehrfach durch Reste substituiert, so bedeutet dies, dass diese Gruppe durch einen oder mehrere gleiche oder verschiedene der genannten Reste substituiert ist. In allen nachfolgend genannten Formeln haben die Substituenten und Symbole, sofern nicht anders definiert, dieselbe Bedeutung wie unter der allgemeinen Formel (I) der Herbizide (A) beschrieben. Pfeile in einer chemischen Formel bedeuten die Verknüpfungsorte zum restlichen Molekül. Im Folgenden werden, jeweils für die einzelnen Substituenten der Herbizide (A) gemäß der allgemeinen Formel (I) wie oben dargestellt, bevorzugte, besonders bevorzugte und ganz besonders bevorzugte Bedeutungen beschrieben. Die übrigen Substituenten der Herbizide (A) gemäß der allgemeinen Formel (I), welche nachfolgend nicht genannt werden, weisen die oben genannte Bedeutung auf. In einer ersten Ausführungsform der vorliegenden Erfindung stehen für herbizid wirksame Substanzen (A) Verbindungen der Formel (I),
worin
R1 für Wasserstoff steht, R2 für Fluor steht, R3 für Fluor steht, R4 für Chlor, Brom, Cyano, NO2 steht, R5 für Wasserstoff steht, R6 für Wasserstoff, Fluor steht, R7 für Wasserstoff steht, G für Methylen steht, X für O (Sauerstoff) oder S (Schwefel) steht, Y für O (Sauerstoff) steht, und Q für eine der spezifisch genannten Gruppierungen
and (B) is one or more herbicides [component (B)] from the group of herbicidally active compounds (B1) to (B11), where (B1) is herbicidally active compounds from the group of the 1,3-diketo compounds mentioned below ( B1.1) Alloxydim, (CAS 55634-91-8), (CAS 55635-13-7) (B1.2) Bicyclopyrone, (CAS 352010-68-5) (B1.3) Butroxydim, (CAS 138164-12 -2) (B1.4) Clethodim, (CAS 99129-21-2) (B1.5) Cycloxydim, (CAS 101205-02-1) (B1.6) Fenquinotrione, (CAS 1342891-70-6) (B1 .7) Mesotrione, (CAS 104206-82-8) (B1.8) Pinoxaden, (CAS 243973-20-8) (B1.9) Profoxydim, (CAS 139001-49-3) (B1.10) Sethoxydim, (CAS 74051-80-2) (B1.11) Sulcotrione, (CAS 99105-77-8) (B1.12) SYP-9121 (CAS 1976053-87-8) (B1.13) Tefuryltrione, (CAS 473278- 76-1) (B1.14) Tembotrione, (CAS 335104-84-2) (B1.15) Tepraloxydim, (CAS 149979-41-9) (B1.16) Tralkoxydim, (CAS 87820-88-0) (B1.17) Y13161, (CAS 1639426-14-4) (B1.18) Y13287 (CAS 1639426-42-8) (B2) stands for herbicidal active ingredients from the group of (sulfone)amides mentioned below (B2.1) acetochlor, (CAS 34256-82-1) (B2.2) alachlor, (CAS 15972-60-8) (B2.3) Amidosulfuron, (CAS 120923-37-7) (B2.4) Asulam, (CAS 3337-71-1), (CAS 14089-43-1), (CAS 2302- 17-2) (B2.5) azimsulfuron, (CAS 120162-55-2) (B2.6) beflubutamide, (CAS 113614-08-7), (CAS 113614-09-8) (B2.7) bensulfuron, (CAS 83055-99-6), (CAS 83055-99-6) (B2.8) Butachlor, (CAS 23184-66-99) (B2.9) Carbetamide, (CAS 16118-49-3) (B2. 10) Chlorimuron, (CAS 99283-00-8), (CAS 90982-32-4) (B2.11) Chlorpropham, (CAS 101-21-3) (B2.12) Chlorsulfuron, (CAS 64902-72-3). ) (B2.13) Cinosulfuron, (CAS 94593-91-6) (B2.14) Cloransulam, (CAS159518-97-5), (CAS 147150-35-4) (B2.15) Cyclosulfamuron, (CAS 136849- 15-5) (B2.16) Desmedipham, (CAS 13684-56-5) (B2.17) Diclosulam, (CAS 145701-21-9) (B2.18) Diflu fenican, (CAS 83164-33-4) (B2.19) Dimethachlor, (CAS 50563-36-5) (B2.20) Dimethenamid, (CAS 87674-68-8), (CAS 163515-14-8) ( B2.21) Esprocarb (CAS 85785-20-2) (B2.22) Ethametsulfuron, (CAS 111353-84-5), (CAS 97780-06-8) (B2.23) Ethoxysulfuron, (CAS 126801-58-9) (B2.24) Flazasulfuron, (CAS 104040-78-0) (B2.25) Florasulam, (CAS 145701-23-1) (B2.26) Flucarbazone, (CAS 145026-88-6), (CAS 181274-17-9) (B2.27) Flucetosulfuron, (CAS 412928-75-7) (B2.28) Flufenacet, (CAS 142459-58-3) ( B2.29) Flumetsulam, (CAS 98967-40-9) (B2.30) Flupyrsulfuron, (CAS 150315-10-9), (CAS 144740-53-4), (CAS 144740-54-5) (B2. 31) Foramsulfuron, (CAS 173159-57-4) (B2.32) Halosulfuron, (CAS 135397-30-7), (CAS 100784-20-1) (B2.33) Imazosulfuron, (CAS 122548-33-8). ) (B2.34) Iodosulfuron, (CAS 185119-76-0), (CAS 144550-06-1), (CAS 144550-36-7) (B2.35) Pepper carbazones, (CAS 212201-70-2) ( B2.36) Mefenacet, (CAS 73250-68-7) (B2.37) Mesosulfuron, (CAS 400852-66-6), (CAS 208465-21-8) (B2.38) Metazachlor, (CAS 67129-08 -2) (B2.39) metazosulfuron, (CAS 868680-84-6) (B2.40) metolachlor, (CAS 51218-45-2) (B2.41) metosulam, (CAS 139528-85-1) (B2 .42) Metsulfuron, (CAS 79510-48-8), (CAS 74223-64-6) (B2.43) Nicosulfuron, (CAS 111991-09-4) (B2.44) Orthos ulfamuron, (CAS 213464-77-8) (B2.45) oxasulfuron, (CAS 144651-06-9) (B2.46) penoxsulam, (CAS 219714-96-2) (B2.47) pethoxamide, (CAS 106700 -29-2) (B2.48) phenmedipham, (CAS 13684-63-4) (B2.49) picolinafen, (CAS 137641-05-5) (B2.50) pretilachlor, (CAS 51218-49-6) (B2.51) Primisulfuron, (CAS 113036-87-6), (CAS 86209-51-0) (B2.52) Propachlor, (CAS 1918-16-7) (B2.53) Propanil, (CAS 709- 98-8) (B2.54) Propham, (CAS 122-42-9) (B2.55) Propisochlor, (CAS 86763-47-5) (B2.56) Propoxycarbazone, (CAS 145026-81-9), (CAS 181274-15-7) (B2.57) Propyrisulfuron, (CAS 570415-88-2) (B2.58) Propyzamide, (CAS 23950-58-5) (B2.59) Prosulfocarb, (CAS 52888-80 -9) (B2.60) prosulfuron, (CAS 94125-34-5) (B2.61) pyrazosulfuron, (CAS 98389-04-9), (CAS 93697-74-6) (B2.62) pyroxsulam, ( CAS 422556-08-9) (B2.63) rimsulfuron, (CAS 122931-48-0) (B2.64) S-metolachlor, (CAS 87392-12-9) (B2.65) sulfometuron, (CAS 74223- 56-6), (CAS 74222-97-2), (CAS 144651-06-9) (B2.66) Sulfosulfuron, (CAS 141776-32-1) (B2.67) Thenylchlor, (CAS 96491-05- 3) (B2.68) thiencarbazones, (CAS 936331-72-5), (CAS 317815-83-1) (B2.69) thifensulfuron, (CAS 79277-67-1), (CAS 79277-27-3) (B2.70) Tri-allate, (CAS 2303-17-5) (B2.71) Triasulfuron, (CAS 82097-50-5) (B2.72) Tribenuron, (CAS 106040-48-6), (CAS 101200-48-0 ) (B2.73) Trifloxysulfuron, (CAS 145099-21-4, (CAS 199119-58-9) (B2.74) Triflusulfuron, (CAS 135990-29-3), (CAS 126535-15-7) (B2 .75) Tritosulfuron, (CAS 142469-14-5) (B2.76) Esprocarb, (CAS 85785-20-2) (B2.77) profluazole, (CAS 190314-43-3) (B2.78) tri-allate, (CAS 2303-17-5) (B2.79) methyl rel-(2R,4R)-4-[[ 3-(3,5-dichlorophenyl)-5-methoxy-4H-isoxazol-5-carbonyl]amino]tetrahydrofuran-2-carboxylate, (B2.80) methyl rel-(2R,4R)-4-[[3- (3,5-dichlorophenyl)-5-vinyl-4H-isoxazole-5-carbonyl]amino]tetrahydrofuran-2-carboxylate, (B2.81) methyl -rel-(2R,4R)-4-[[(5S) -3-(3,5-difluorophenyl)-5-vinyl-4H-isoxazole-5-carbonyl]amino]tetrahydrofuran-2-carboxylate, (B2.82) isopropyl rel-(2R,4R)-4-[[3 -(3-fluorophenyl)-5-methyl-4H-isoxazol-5-carbonyl]amino]tetrahydrofuran-2-carboxylate, (B2.83) methyl (3R)-3-[[(5S)-3-(3, 5-difluorophenyl)-5-vinyl-4H-isoxazol-5-carbonyl]amino]-2,3-dihydrofuran-5-carboxylate, (B2.84) methyl (3R)-3-[[(5R)-3- (3,5-difluorophenyl)-5-methyl-4H-isoxazol-5-carbonyl]amino]-2,3-dihydrofuran-5-carboxylate, (B2.85) methyl (1S,4R)-4-[[[ (5S)-3-(3,5-difluorophenyl)-5-vinyl-4H-1,2-oxazol-5-yl]carbonyl]amino]cyclopent-2-en-1-carboxylate, (B2.86) Ethyl (1S,4R)-4-[[[3-(3,5-difluorophenyl)-5 - methoxy-4H-1,2-oxazol-5-yl]carbonyl]amino]cyclopent-2-ene-1-carboxylate, (B2.87) 2-Methoxyethyl (1S,4R)-4-[[[(5R )-3-(3-cyano-5-fluorophenyl)-5-(trifluoromethyl)-4H-1,2-oxazol-5-yl]carbonyl]amino]cyclopent-2-en-1-carboxylate, (B2.88 ) Methyl (4S)-4-[[[3-(3,5-difluorophenyl)-5-methyl-4H-1,2-oxazol-5-yl]carbonyl]amino]cyclopentene-1-carboxylate, (B2. 89) Methyl (3S)-3-[[[(5R)-3-(3,5-difluorophenyl)-5-methyl-4H-1,2-oxazol-5-yl]carbonyl]amino]cyclopentene-1 -carboxylate, (B2.90) 3-(3,5-Difluorophenyl)-N-[(1R,4S)-4-(oxazinan-2-ylcarbonyl)cyclopent-2-en-1-yl]-5-(trifluoromethyl)- 4H-1,2-oxazole-5-carboxamide, (B2.91) 3-(3,5-difluorophenyl)-N-[(1R,4S)-4-[(propylsulfonylamino)carbonyl]cyclopent-2-ene- 1-yl]-5-(trifluoromethyl)-4H-1,2-oxazole-5-carboxamide, (B2.92) (1S,4R)-4-[[(5R)-3-(3,5-difluorophenyl )-5-methyl- 4H-isoxazol-5-carbonyl]amino]cyclopent-2-ene-1-carboxylic acid (B3) stands for herbicidal active substances from the group of the aryl nitriles mentioned below (B3.1) bromoxynil, (CAS 1689- 84-5) (CAS 3861-41-4), (CAS 56634-95-8), (CAS 1689-99-2), (CAS 2961-68-4) (B3.2) Chlorothiamide, (CAS 1918- 13-4) (B3.3) Dichlobenil, (CAS 1194-65-6) (B3.4) Ioxynil, (CAS 1689-83-4), (CAS 2961-61-7), (CAS 3861-47- 0), (CAS 2961-62-8) (B3.5) Pyraclonil (CAS 158353-15-2) (B4) stands for herbicidal active substances from the group of the azoles mentioned below (B4.1) Amicarbazone, (CAS 129909- 90-6) (B4.2) Amitrols, (CAS 61-82-5) (B4.3) Azafenidin, (CAS 68049-83-2) (B4.4) Benzofenap, (CAS 82692 -44-2) (B4.5) Benzuofucaotong (CAS 1992017-55-6) (B4.6) Biscarfentrazone (CAS 1622908-18-2) (B4.7) Cafenstrole, (CAS 125306-83-4) (B4 .8) Carfentrazone, (CAS 128621-72-7), (CAS128639-02-1) (B4.9) Fentrazamide, (CAS 158237-07-1) (B4.10) Imazamethabenz, (CAS 100728-84-5). ), (CAS 81405-85-8) (B4.11) imazamox, (CAS 114311-32-9), (CAS 247057-22-3) (B4.12) imazapic, (CAS 104098-48-8), (CAS 115136-53-3) (B4.13) Imazapyr, (CAS 81334-34-1), (CAS 81510-83-0) (B4.14) Imazaquin, (CAS 81335-37-7), (CAS 81335-47-9), (CAS 81335-43-5), (CAS 81335-46-8) (B4.15) Imazethapyr, (CAS 81335-77-5), (CAS 101917-66-2) (B4.16) Isouron, (CAS 55861-78-4) (B4.17) Isoxaben, (CAS 82558- 50-7) (B4.18) Isoxaflutole, (CAS 141112-29-0) (B4.19) Oxadiargyl, (CAS 39807-15-3) (B4.20) Oxadiazon, (CAS 19666-30-9) ( B4.21) Pyraflufen, (CAS 129630-17-7), (CAS 129630-19-9) (B4.22) Pyrasulfotole, (CAS 365400-11-9) (B4.23) Pyrazolynate, (CAS 58011-68). -0) (B4.24) Pyrazoxyfen, (CAS 71561-11-0) (B4.25) Pyroxasulfones, (CAS 447399-55-5) (B4.26) Sulfentrazone, (CAS 122836-35-5) (B4 .27) Tolpyralate, (CAS 1101132-67-5) (B4.28) Topramezone, (CAS 210631-68-8) (B4.29) Triazolesulcotrione (CAS 1911613-97-2) (QYR-301), (B4 .30) QYM-201, (CAS 1855925-45-1) (B4.31) Bencarbazone, (CAS 173980-17-1) (B4.32) Fluazolate, (CAS 174514-07-9) (B4.33) Flupoxam, (CAS 119126-15-7) (B4.34) Isoxachlortole (CAS 141112-06-3) (B5) stands for other herbicidal active substances mentioned below, (B5.1) Aminocyclopyrachlor, (CAS 858956-08-8) , (CAS 858954-83-3), (CAS 858956-35-1) (B5.2) Aminopyralid, (CAS 150114-71-9), (CAS 566191-87-5), (CAS 566191-89-7) (B5.3) Benazoline-ethyl, (CAS 3813-05-6), (CAS 38561-76-1) , (CAS 25059-80-7), (CAS 67338-65-2) (B5.4) Benfluralin, (CAS 1861-40-1) (B5.5) Bentazone, (CAS 25057-89-0), ( CAS 50723-80-3) (B5.6) Benzobicyclone, (CAS 156963-66-5) (B5.7) Bixlozone (CAS 81777-95-9) (B5.8) Bromofenoxime, (CAS 13181-17-4 ) (B5.9) butraline, (CAS 33629-47-9) (B5.10) chloridazon/pyrazone, (CAS 1698-60-8) (B5.11) Chlorthal, (CAS 2136-79-0), (CAS 1861-32-1), (CAS 887-54-7) (B5.12) Cinidon-ethyl, (CAS 142891-20-1) (B5.13) cinmethyline, (CAS 87818-31-3) (B5.14) clomazone, (CAS 81777-89-1) (B5.15) cyclopyrimorate, (CAS 499231-24-2) (B5.16) Dinitramine, (CAS 29091-05-2) (B5.17) Diquat, (CAS 2764-72-9), (CAS 85-00-7), (CAS 4032-26-2) (B5.18) Dithiopyr, (CAS 97886-45-8) (B5.19) Acetic acid, (CAS 64-19-7) (B5.20) Ethalfluralin, (CAS 55283-68-6) (B5.21) Ethofumesate, (CAS 26225-79 -6) (B5.22) Flamprop, (CAS 58667-63-3, (CAS 90134-59-1), (CAS 63782-90-1), (CAS 63729-98-6) (B5.23) Florpyrauxifen , (CAS 943832-81-3), (CAS 1390661-72-9) (B5.24) Flufenpyr, (CAS 188490-07-5), (CAS 188489-07-8) (B5.25) Flumiclorac, ( CAS 87547-04-4), (CAS 87546-18-7) (B5.26) Flumioxazine, (CAS 103361-09-7) (B5.27) Fluridone, (CAS 59756-60-4) (B5.28 ) Flurochloridone, (CAS 61213-25-0) (B5.29) Flurtamone, (CAS 96525-23-4) (B5.30) Fluthiacet-methyl, (CAS 149253-65-6) (B5.31) Halauxifen, (CAS 943832-60-8), (CAS 943831-98-9) (B5.32 ) indanofan, (CAS 13320-30-1) (B5.33) norflurazon, (CAS 27314-13-2) (B5.34) oleic acid (CAS 112-80-1) (B5.35) oryzalin, (CAS 19044 -88-3) (B5.36) Oxaziclomefone, (CAS 153197-14-9) (B5.37) Paraquat, (CAS 4685-14-7), (CAS 1910-42-5), (CAS 2074-50 -2) (B5.38) Pelargonic acid, (CAS 112-05-0) (B5.39) Pendimethalin, (CAS 40487-42-1) (B5.40) Pentoxazone, (CAS 110956-75-7) (B5 .41) Pyridafol, (CAS 40020-01-7) (B5.42) Pyridate, (CAS 55512-33-9) (B5.43) Tetflupyrolimet, (CAS 2053901-33-8) (B5.44) Thiazopyr, (CAS 117718-60-2) (B5.45) Triafamone, (CAS 874195-61-6) (B5.46) Trifluralin, (CAS 1582-09-8) (B5.47) 4-amino-3-chloro-5-fluoro- 6-(7-fluoro-1H-indol-6- yl)pyridine-2-carboxylic acid (B5. 48) Cyclopyrimorate, (CAS 499231-24-2) (B5.49) Diquat, (CAS 2764-72-9), (CAS 85-00-7), (CAS4032-26-2) (B5.50) Oxaziclomefone , (CAS 153197-14-9) (B5.51) pentanochlor, (CAS 2307-68-8) (B5.52) tebutam, (CAS 35256-85-0) (B5.53) thidiazimine, (CAS 123249- 43-4) (B5.54) 4-Hydroxy-1-methyl-3-[4-(CAS 1708087-22-2) (trifluoromethyl)-2-pyridinyl]-2-imidazolidinone (B6) for herbicidal active substances from the The group of (het)arylcarboxylic acids mentioned below is (B6.1) chlorambene, (CAS 133-90-4), (CAS 1076-46-6), (CAS 53404-16-3), (CAS 7286-84-2). ), (CAS 25182-03-0), (1954-81-0) (B6.2) Clopyralid, (CAS 1702-17-6), (CAS 1532-24-7), (CAS 57754-85-5 ), (CAS 58509-83-4), (CAS 73455-09-1) (B6.3) Dicamba, (CAS 1918-00-9), (CAS 1286239-22-2), (CAS 104040-79- 1), (CAS 2300-66-5), (CAS 25059-78-3), (CAS 55871-02-8), (CAS 6597-78-0), (CAS 53404-28-7), (CAS 10007-85-9 ), (CAS 1982-69-0), (53404-29-8), (CAS 56141-00-5) (B6.4) Fluroxypyr, (CAS 69377-81-7), (CAS -27-8) , (CAS 81406-37-3) (B6.5) Picloram, (CAS 1918-02-1), (CAS 55870-98-9), (CAS 36374-99-9), (CAS 26952-20-5), (CAS 14143-55-6 ), (CAS 55871-00-6), (CAS 2545-60-0), (CAS 35832-11-2), (CAS 6753-47-5), (CAS 82683-78-1) (B6.6 ) Quinclorac, (CAS 84087-01-4), (CAS 84087-48-9), (CAS 84087-33-2) (B6.7) Quinmerac, (CAS 90717-03-6) (B6.8) TBA , (CAS 50-31-7), (CAS 3426-62-8), (CAS 71750-37-3), (CAS 4559-30-2), (CAS 2078-42-4) (B6.9) Triclopyr (CAS 55335-06-3), (CAS [64700-56-7), (CAS 1048373-85-8), (CAS 60825-27-6), (CAS 57213-69-1) (B7) for herbicidal active ingredients from the group of organic phosphorus compounds mentioned below (B7.1) Anilofos, (CAS 64249-01-0) (B7.2) Bialaphos, (CAS 35597-43-4), (CAS 71048-99-2) (B7.3) Butamifos, (CAS 36335-67-8) (B7.4) Glufosinate, (CAS 51276-47-2), (CAS 35597-44-5), (CAS 77182-82-2), ( CAS 70033-13-5) (B7.5) Glyphosate, (CAS 1071-83-6), (CAS 69254-40-6), (CAS 34494-04-7), (CAS 38641-94-0), (CAS 40465-66-5), (CAS 39600-42-5), (CAS 70393-85-0), (CAS 81591-81-3) (B7.6) Piper ophos, (CAS 24151-93-7) (B7.7) sulfosates, (CAS 1591-81-3) (B7.8) amiprofos (CAS 33857-23-7, (CAS 36001-88-4) (B8) (B8.1) 2,4-D, (CAS 94-75-7), (CAS 2307-55-3), (CAS 1929-73-3), ( CAS 1320-18-9), (CAS 1928-45-6), (CAS 94-80-4), (CAS 1048373-72-3), (CAS 20940-37-8), (CAS 2008-39- 1), (CAS 5742-19-8), (CAS 2212-54-6), (CAS 533-23-3), (CAS 1928-43-4), (CAS 37102-63-9), (CAS 713-15-1), (CAS 25168-26 -7), (CAS 94-11-1), (CAS 5742-17-6), (CAS 3766-27-6), (CAS 1917-97-1), (CAS 1928-38-7), ( CAS 1928-44-5), (CAS 1917-92-6), (CAS 1928-61-6), (CAS 2702-72-9), (CAS 15146-99-3), (CAS 28685-18- 9), (CAS 2646-78-8), (CAS 18584-79-7), (CAS 2569-01-9), (CAS 215655-76-8) (B8.2) 2,4-DB, ( CAS 94-82-6), (CAS 2758-42-1), (CAS 1320-15-6), (CAS 19480-40-1), (CAS 10433-59-7) (B8.3) 2, 4-DP, (CAS 120-36-5), (CAS 53404-31-2), (CAS 53404-32-3), (CAS 79270-78-3), (CAS 28631-35-8), ( CAS 57153-17-0), (CAS 5746-17-8), (CAS 39104-30-8) (B8.4) Acifluorfen, (CAS 50594-66-6), (CAS 50594-67-7), (CAS 62476-59-9) (B8.5) Aclonifen, (CAS 74070-46-5) (B8.6) Bifenox, (CAS 42576-02-3) (B8.7) Chloromethoxyfen, (CAS 32861-85 -1) (B8.8) clodinafop- (CAS 114420-56-3), (CAS 105512-06-9) propargyl, (B8.9) clomeprop, (CAS 84496-56-0) (B8.10) cyhalofop , (CAS 122008-78-0), (CAS 122008-85-9) (B8.11) Diclofop, (CAS 40843-25-2), (CAS 51338-2 7-3) (B8.12) Ethoxyfen, (CAS 188634-90-4), (CAS 131086-42-5) (B8.13) Fenoxaprop, (CAS 95617-09-7), (CAS 113158-40- 0), (CAS 71283-80-2) (B8.14) fluazifop, (CAS 69335-91-7), (CAS 83066-88-0), (CAS 79241-46-6) (B8.15) fluoroglycofen , (CAS 77501-60-1), (CAS 77501-90-7) (B8.16) fomesafen, (CAS 72178-02-0), (CAS 108731-70-0) (B8.17) halosafen, ( CAS 77227-69-1) (B8.18) Haloxyfop, (CAS 69806-34-4), (CAS 95977-29-0), (CAS 72619-32-0) (B8.19) Lactofen, (CAS 77501-63-4) (B8 .20) MCPA, (CAS 94-74-6), (CAS 19480-43-4), (CAS 1713-12-8), (CAS 2039-46-5), (CAS 20405-19-0), (CAS 2698-38-6), (CAS 29450-45-1), (CAS 1713-11-7), (CAS 26544-20-7), (CAS 2698-40-0), (CAS 2436-73 -9), (CAS 6365-62-4), (CAS 5221-16-9), (CAS 3653-48-3), (CAS 42459-68-7) (B8.21) MCPB, (CAS 94- 81-5), (CAS 10443-70-6), (CAS 57153-18-1), (CAS 6062-26-6) (B8.22) Mecoprop, (CAS 93-65-2), (CAS 32351 -70-5), (CAS 1432-14-0), (CAS 71526-69-7), (CAS 28473-03-2), (CAS 2786-19-8), (CAS 1929-86-8) , (CAS 19095-88-6), (CAS 53404-61-8), (CAS 16484-77-8) (B8.23) metamifop, (CAS 256412-89-2) (B8.24) oxyfluorfen, ( CAS 42874-03-3) (B8.25) Propaquizafop, (CAS 111479-05-1) (B8.26) Quizalofop, (CAS 76578-12-6), (CAS 76578-14-8), (B8. 27) Quizalofop-P, (CAS 94051-08-8), (CAS 100646-51-3), (CAS 200509-41-7) (B8.28) Benzfendizone (CAS 158755-95-4) (B9) for herbicidal active ingredients from the group below (B9.1) Bispyrac-sodium, (CAS 125401-92-5) (B9.2) Bromacil, (CAS 314-40-9), (CAS 53404-19-6), (CAS 69484-12). -4) (B9.3) Butafenacil, (CAS 134605-64-4) (B9.4) Lenacil, (CAS 2164-08-1) (B9.5) Pyribenzoxime, (CAS 168088-61-7) (B9 .6) Pyriftalid, (CAS 135186-78-6) (B9.7) Pyriminobac, (CAS 136191-56-5), (CAS 136191-64-5) (B9.8) Pyrimisulfan, (CAS 221205-90- 9) (B9.9) Pyrithiobac sodium, (CAS 123342-93-8), (CAS 123343-16-8) (B9.10) Saflufenacil, (CAS 372137-35-4) (B9.11) Terbacil, (CAS 5902-51-2) (B9.12) tiafenacil, (CAS 1220411-29-9) (B9.13) trifludimoxazine, (CAS 1258836-72-4) (B9.14) ethyl[3-[2-chloro- 4-fluoro-5-(CAS 353292-31-6) (1-methyl-6-trifluoromethyl- 2,4-dioxo-1,2,3,4- tetrahydropyrimidin-3-yl)phenoxy]-2-pyridyloxy] acetate (B10) stands for herbicidal active ingredients from the group of (thio)ureas mentioned below (B10.1) chlorobromuron, (CAS 13360-45-7) (B10.2) chlorotoluron, (CAS 15545-48-9) (B10 .3) Daimuron, (CAS 42609-52-9) (B10.4) Dimefuron, (CAS 34205-21-5) (B10.5) Diuron, (CAS 330-54-1) (B10.6) Diflufenzopyr ( CAS 1957168-02-3) (B10.7) Fluometuron, (CAS 2164-17-2) (B10.8) Isoproturon, (CAS 34123-59-6) (B10.9) Linuron, (CAS 330-55- 2) (B10.10) methabenzthiazuron, (CAS 18691-97-9) (B10.11) metobromuron, (CAS 3060-89-7) (B10.12) metoxuron, (CAS 19937-59-8) (B10. 13) monolinuron, (CAS 1746-81-2) (B10.14) neburone, (CAS 555-37-3) (B10.15) Siduron, (CAS 1982-49-6) (B10.16) Tebuthiuron, (CAS 34014-18-1) (B10.17) Fenuron, (CAS 101-42-8) (B10.18) Chloroxuron, (CAS 1982-47-4) (B10.19) Diflufenzopyr, (CAS 1957168-02-3, CAS 109293-98-3) (B10.20) Ethidimuron (CAS 30043-49-3) (B11) stands for herbicidal active substances from the group of triazines mentioned below (B11.1) Ametryne, (CAS 834-12-8) (B11.2) Atrazine, (CAS 1912-24-9) (B11.3) Cyanazine , (CAS 21725-46-2) (B11.4) Dimethametryn, (CAS 22936-75-0) (B11.5) Hexazinone, (CAS 51235-04-2) (B11.6) Indaziflam, (CAS 950782- 86-2) (B11.7) Metamitron, (CAS 41394-05-2) (B11.8) Metribuzin, (CAS 21087-64-9) (B11.9) Prometon, (CAS 1610-18-0) ( B11.10) Prometryn, (CAS 7287-19-6) (B11.11) Propazine, (CAS 139-40-2) (B11.12) Simazine, (CAS 122-34-9) (B11.13) Simetryn , (CAS 1014-70-6) (B11.14) Terbumetone, (CAS 33693-04-8) (B11.15) Terbuthylazine, (CAS 5915-41-3) (B11.16) Terbutryne, (CAS 886- 50-0) (B11.17) Triaziflam, (CAS 131475-57-5) (B11.18) Trietazine, (CAS 1912-26-1) (B11.19) Desmetryne (CAS 1014-69-3). The names of the herbicides listed above (common name) are supplemented by the “CAS RN” (Chemical Abstract Service Registry Number) (“CAS” for short) listed in brackets. The CAS RN is a commonly used reference number that enables the substances referred to to be clearly assigned, since the "CAS RN" distinguishes, among other things, between isomers, including stereoisomers, as well as salts and esters. For active ingredients that exist in different forms, the name of the neutral compound is given in the list above. The CAS given in brackets refer to these and all other known forms of the active ingredient, such as salts or adducts. The following may be mentioned here by way of example, but not by way of limitation: 2,4-D-ammonium; 2,4-D-choline (the choline salt of 2,4-D); 2,4-D-BAPMA (N,N-bis-(3-aminopropyl)methylamine salt of 2,4-D); 2,4-D-diethylammonium; 2,4-D-dimethylammonium; 2,4-D-dodecylammonium; 2,4-D-heptylammonium; 2,4-D-isopropylammonium; 2,4-D lithium; 2,4-D-potassium; 2,4-D sodium; 2,4-D-tetradecylammonium; 2,4-D-triethylammonium; 2,4-D-tris(2-hydroxypropyl)ammonium; 2,4-D-Monoethanolammonium (the monoethanolamine salt of 2,4-D); 2,4-D-diethanolammonium (the diethanolamine salt of 2,4-D or 2,4-D-diolamine); 2.4-D triethanolammonium (the triethanolamine salt of 2,4-D or 2,4-D-triolamine); the tetrabutylamine salt of dicamba; the dimethylamine salt of dicamba; the isopropylamine salt of dicamba; the diglycolamine salt of dicamba; the N,N-bis(3-aminopropyl)methylamine salt of dicamba; the choline salt of dicamba; the monoethanolamine salt of dicamba; the diethanolamine salt of dicamba; the triethanolamine salt of dicamba; The Potassium Salt of Dicamba; the sodium salt of dicamba; glyphosate diammonium; glyphosate dimethylammonium; glyphosate isopropylammonium; glyphosate monoammonium; glyphosate potassium; glyphosate dipotassium; glyphosate sesquisodium (N-(phosphonomethyl)glycine sodium salt (2:3)); the trimethylsulfonium salt of glyphosate (glyphosate-trimesium); the triethanolamine salt of glyphosate; the diethanolamine salt of glyphosate; and the monoethanolamine salt of glyphosate. In the following, only the neutral compound is always mentioned and thus includes all existing forms as listed, unless a specific form of the active ingredient is relevant in a specific context, such as in the table examples below for the biological effectiveness. The compositions according to the invention may contain other components, e.g. B. other active ingredients against harmful organisms such as harmful plants, phytotoxic animals or phytotoxic fungi, in particular active ingredients from the group of herbicides, fungicides, insecticides, acaricides, nematicides and miticides and related substances, or other types of pesticide active ingredients (e.g. resistance inducers), active ingredients that are gentle on crop plants (safeners, antidotes), plant growth regulators and/or additives customary in crop protection and/or formulation auxiliaries. The components can be formulated together (ready-to-use formulation) and used, or they can be formulated separately and used together, e.g. B. in the tank mix or in sequential application. The individual herbicidally active compounds of the general formula (I) present as component (A) are also referred to below as compounds (A), active compounds (A), components (A) or herbicides (A). Correspondingly, the individual herbicidally active ingredients present as component (B) are also referred to below as compounds (B), active ingredients (B), components (B) or herbicides (B). An advantageous property of the combination of herbicides (A) and (B) according to the invention is that active ingredients (A) and (B) are compatible with one another, ie they can be used together without significant chemical incompatibility of the active ingredients (A) and/or or (B) occur leading to degradation of one or more active ingredients. This avoids a reduction in the active ingredient content in formulations or spray mixtures. The favorable compatibility also extends to the biological properties of the active ingredients when used in combination. Thus, antagonistic effects are generally not observed when controlling harmful plants with the active compound combinations according to the invention. The active ingredients (A) and (B) are therefore particularly suitable for use together with or in addition to other crop protection active ingredients or agrochemicals. The combined application made possible allows the use of advantageous effects, such as the expansion of the spectrum of harmful plants to be controlled or combated in one application, the reduction in the application rate of the individual herbicides (A) or (B) compared to the respective application rate of the herbicide in question in the single application. In this way, the degradation behavior of the active ingredients can be influenced and more favorable conditions for the reproduction of crop plants can be achieved. A further advantage can be seen in the fact that the emergence of resistances in the harmful plants to the active substances can often be significantly reduced or avoided by combining active substances with different mechanisms of action. Surprisingly, in particular, when the active ingredients (A) and (B) are used in combination, superadditive (=synergistic) effects occur on a relatively large number of economically important harmful plants. The effect of the combination is stronger than the expected sum of the effects of the individual herbicides used. The synergistic effects allow a further reduction in the application rate, the control of a broader spectrum of weeds and weed grasses, faster use of the herbicidal effect, a longer duration of action, better control of harmful plants with just one or a few applications and an extension of the possible application period. In some cases, the amount of harmful ingredients, such as nitrogen or oleic acid, and their entry into the soil is reduced through the use of the agents. The properties and advantages mentioned are desirable in practical weed control, in order to keep agricultural crops free from unwanted competing plants and thus to ensure and/or increase the yields qualitatively and quantitatively. The technical standard is clearly exceeded by the new combinations with regard to the properties described. The synergistic effects are observed when the active ingredients (A) and (B) are applied together, but can also often occur when they are applied at different times (splitting). It is also possible to use the herbicides (A) or (B) or the herbicidal composition (A) and (B) in several portions (sequential application). For example, after one or more preemergence applications, a postemergence application can occur, or after an early postemergence application, a mid or late postemergence application can occur. Preference is given to the simultaneous or timely application of the active ingredients of the respective combination, optionally in several portions. However, the time-delayed use of the individual active ingredients in a combination is also possible and can be advantageous in individual cases. In the system of the application other crop protection agents, such as the other active ingredients mentioned (other herbicides, fungicides, insecticides, acaricides, etc.) and/or various auxiliaries, adjuvants and/or fertilizer additions, can also be integrated. Depending on the context in which the terms are used, pre-emergence or post-emergence application means application of the active ingredients before or after the harmful plants appear visible above ground, or application of the active ingredients against the harmful plants before the crop plants emerge or To understand after emergence of crops. The following definitions apply in the formula (I) for compounds of the herbicidally active compounds (A) and all subsequent formulas: Depending on the type and linkage of the substituents, the compounds of the formula (I) can be present as stereoisomers. If, for example, one or more asymmetrically substituted carbon atoms and/or sulfoxides are present, enantiomers and diastereomers can occur. Stereoisomers can be obtained from the mixtures obtained during production by customary separation methods, for example by chromatographic separation methods. Likewise, stereoisomers can be prepared selectively by using stereoselective reactions using optically active starting materials and/or auxiliaries. The invention also relates to all stereoisomers and mixtures thereof encompassed but not specifically defined by formula (I). For the sake of simplicity, however, reference is always made below to compounds of the formula (I), although both the pure compounds and, if appropriate, mixtures with different proportions of isomeric compounds are meant. Depending on the nature of the substituents defined above, the compounds of the formula (I) have acidic properties and can form salts, optionally also inner salts or adducts, with inorganic or organic bases or with metal ions. If the compounds of the formula (I) carry hydroxyl, carboxy or other groups which induce acidic properties, these compounds can be reacted with bases to form salts. Suitable bases are, for example, hydroxides, carbonates, hydrogen carbonates of the alkali and alkaline earth metals, in particular those of sodium, Potassium, magnesium and calcium, as well as ammonia, primary, secondary and tertiary amines with (C 1 -C 4 -)-alkyl groups, mono-, di- and trialkanolamines of (C 1 -C 4 -)-alkanols, choline and chlorocholine , and organic amines such as trialkylamines, morpholine, piperidine or pyridine. These salts are compounds in which the acidic hydrogen is replaced by an agriculturally suitable cation, for example metal salts, in particular alkali metal salts or alkaline earth metal salts, in particular sodium and potassium salts, or else ammonium salts, salts with organic amines or quaternary (quaternary) ammonium salts, for example with cations of the formula [NRR'R''R'''] + , in which R to R''' are each independently of the other represent an organic radical, in particular alkyl, aryl, aralkyl or alkylaryl. Also suitable are alkylsulfonium and alkylsulfoxonium salts, such as (C 1 -C 4 )-trialkylsulfonium and (C 1 -C 4 )-trialkylsulfoxonium salts. The compounds of formula (I) can be synthesized by addition of a suitable inorganic or organic acid, for example mineral acids such as HCl, HBr, H 2 SO 4 , H 3 PO 4 or HNO 3 , or organic acids, e.g. B. carboxylic acids such as formic acid, acetic acid, propionic acid, oxalic acid, lactic acid or salicylic acid or sulfonic acids such as p-toluenesulfonic acid to a basic group such as amino, alkylamino, dialkylamino, piperidino, morpholino or pyridino. These salts then contain the conjugate base of the acid as an anion. Suitable substituents which are in deprotonated form, such as sulfonic acids or carboxylic acids, can form inner salts with groups which can themselves be protonated, such as amino groups. If a group is multiply substituted by radicals, this means that this group is substituted by one or more of the radicals mentioned, which are identical or different. Unless otherwise defined, the substituents and symbols in all the formulas given below have the same meaning as described under the general formula (I) of the herbicides (A). Arrows in a chemical formula denote the sites of attachment to the rest of the molecule. Preferred, particularly preferred and very particularly preferred meanings are described below for the individual substituents of the herbicides (A) of the general formula (I) as shown above. The other substituents of the herbicides (A) of the general formula (I) which are not mentioned below have the meaning given above. In a first embodiment of the present invention, herbicidally active substances (A) are compounds of the formula (I), wherein R 1 is hydrogen, R 2 is fluorine, R 3 is fluorine, R 4 is chlorine, bromine, cyano, NO2, R 5 is hydrogen, R 6 is hydrogen, fluorine, R 7 is hydrogen, G is methylene, X is O (oxygen) or S (sulphur), Y is O (oxygen), and Q is any of the moieties specifically mentioned
steht. In einer zweiten Ausführungsform der vorliegenden Erfindung stehen für herbizid wirksame Substanzen (A) Verbindungen der Formel (I),
worin R1 für Wasserstoff steht, R2 für Fluor steht, R3 für Fluor steht, R4 für Chlor, Brom, oder Cyano steht, R5 für Wasserstoff steht,
R6 für Wasserstoff, Fluor steht, R7 für Wasserstoff steht, G für Methylen steht, X für O (Sauerstoff) steht, Y für O (Sauerstoff) steht, und Q für eine der spezifisch genannten Gruppierungen
steht. In einer dritten Ausführungsform der vorliegenden Erfindung enthält die herbizide Zusammensetzung neben mindestens einer Komponente (B) wie oben definiert bevorzugt eine oder mehrere Verbindungen [Komponente (A)] der allgemeinen Formel (I) oder deren agrochemisch verträglichen Salze [Herbizide (A)] gemäß Tabellen 1a und 1b. Tabelle 1a: Bevorzugte Verbindungen der Formel (I) als Herbizid (A)):
Alle diese bevorzugten Verbindungen sind in nachstehender Tabelle 1b nochmals durch ihre Strukturfomel und korrespondierendem IUPAC-Namen aufgeführt. Tabelle 1b: IUPAC Namen sowie die Strukturformeln der bevorzugten Verbindungen der Formel (I) (Herbizid (A))
Die Verbindungen der Formel (I) sind aus der internationalen Anmeldung mit der Anmeldnummer PCT/EP2020/070463 (veröffentlicht als WO2021/013799) bekannt und können nach den dort beschriebenen Verfahren hergestellt werden. Die Aufwandmengen der Herbizide (A) liegen im Bereich von 0,02 bis 750 g Aktivsubstanz pro Hektar (im folgenden g a.i./ha), vorzugsweise 0,05 bis 400 g a.i./ha, insbesondere 0,25 bis 300 g a.i./ha). In den erfindungsgemäßen Kombinationen werden im Rahmen der genannten Aufwandmengen im Vergleich zur Einzelapplikation meist niedrigere Aufwandmengen des jeweiligen Wirkstoffs benötigt, vorzugsweise 0,02 bis 250 g a.i./ha, insbesondere 0,05 bis 150 g a.i./ha, und am meisten bevorzugt 0,25 bis 120 g a.i./ha. Als Kombinationspartner (B) [= Komponente (B) bzw. Herbizide (B)] sind grundsätzliche alle Wirkstoffe der Untergruppen (B1) bis (B11) geeignet, wobei die Bezeichnung der herbiziden Wirkstoffe weitgehend mit dem “common name” (in der englischen Schreibweise) nach der Referenzstelle "The Pesticide Manual" 14th Ed., British Crop Protection Council 2006, abgekürzt “PM” bzw. dem chemischen Namen gemäß der üblichen Nomenklaturen (IUPAC oder Chemical Abstracts) erfolgt.
Einige Herbizide (B) haben sich jedoch überraschenderweise als besonders gute Kombinationspartner erwiesen. Im Folgenden sind die bevorzugten, besonders bevorzugten und am meisten bevorzugten Herbizide (B) als weitere Ausführungsformen der vorliegenden Erfindung aufgelistet. In einer vierten Ausführungsform der vorliegenden Erfindung sind die herbiziden Wirkstoffe (B1) bevorzugt: (B1.2) Bicyclopyrone, (B1.4) Clethodim, (B1.7) Mesotrione, (B1.8) Pinoxaden, (B1.10) Sethoxydim, (B1.11) Sulcotrione, (B1.14) Tembotrione, (B1.16) Tralkoxydim. Besonders bevorzugt aus der Gruppe B1 sind die herbiziden Wirkstoffe (B1.2) Bicyclopyrone, (B1.4) Clethodim, (B1.7) Mesotrione, (B1.8) Pinoxaden, (B1.14) Tembotrione In einer fünften Ausführungsform der vorliegenden Erfindung sind die herbiziden Wirkstoffe (B2) bevorzugt: (B2.1) Acetochlor, (B2.4) Asulam, (B2.6) Beflubutamid, (B2.10) Chlorimuron, (B2.12) Chlorsulfuron, (B2.14) Cloransulam, (B2.17) Diclosulam, (B2.18) Diflufenican, (B2.20) Dimethenamid, (B2.23) Ethoxysulfuron, (B2.24) Flazasulfuron, (B2.25) Florasulam,
(B2.26) Flucarbazone, (B2.28) Flufenacet, (B2.29) Flumetsulam, (B2.30) Flupyrsulfuron, (B2.31) Foramsulfuron, (B2.34) Iodosulfuron, (B2.37) Mesosulfuron, (B2.40) Metolachlor, (B2.41) Metosulam, (B2.42) Metsulfuron, (B2.43) Nicosulfuron, (B2.46) Penoxsulam, (B2.49) Picolinafen, (B2.56) Propoxycarbazone, (B2.59) Prosulfocarb, (B2.60) Prosulfuron, (B2.62) Pyroxsulam, (B2.63) Rimsulfuron, (B2.64) S-metolachlor, (B2.65) Sulfometuron, (B2.66) Sulfosulfuron, (B2.68) Thiencarbazone, (B2.69) Thifensulfuron, (B2.72) Tribenuron, (B2.76) Esprocarb, (B2.78) Tri-allate, (B2.79) Methyl rel-(2R,4R)-4-[[3-(3,5-dichlorophenyl)-5-methoxy-4H-isoxazol-5- carbonyl]amino]tetrahydrofuran-2-carboxylat, (B2.80) Methyl rel-(2R,4R)-4-[[3-(3,5-dichlorophenyl)-5-vinyl-4H-isoxazol-5- carbonyl]amino]tetrahydrofuran-2-carboxylat, (B2.81) Methyl –rel-(2R,4R)-4-[[(5S)-3-(3,5-difluorophenyl)-5-vinyl-4H-isoxazol-5- carbonyl]amino]tetrahydrofuran-2-carboxylat, (B2.82) Isopropyl rel-(2R,4R)-4-[[3-(3-fluorophenyl)-5-methyl-4H-isoxazol-5- carbonyl]amino]tetrahydrofuran-2-carboxylat, (B2.83) Methyl (3R)-3-[[(5S)-3-(3,5-difluorophenyl)-5-vinyl-4H-isoxazol-5- carbonyl]amino]-2,3-dihydrofuran-5-carboxylat,
(B2.84) Methyl (3R)-3-[[(5R)-3-(3,5-difluorophenyl)-5-methyl-4H-isoxazol-5- carbonyl]amino]-2,3-dihydrofuran-5-carboxylat, (B2.85) Methyl (1S,4R)-4-[[[(5S)-3-(3,5-difluorphenyl)-5-vinyl-4H-1,2-oxazol-5- yl]carbonyl]amino]-cyclopent-2-en-1-carboxylat, (B2.86) Ethyl (1S,4R)-4-[[[3-(3,5-difluorphenyl)-5-methoxy-4H-1,2-oxazol-5- yl]carbonyl]amino]cyclopent-2-en-1-carboxylat, (B2.87) 2-Methoxyethyl (1S,4R)-4-[[[(5R)-3-(3-cyano-5-fluorphenyl)-5- (trifluormethyl)-4H-1,2-oxazol-5-yl]carbonyl]amino]cyclopent-2-en-1- carboxylat, (B2.88) Methyl (4S)-4-[[[3-(3,5-difluorphenyl)-5-methyl-4H-1,2-oxazol-5- yl]carbonyl]amino]cyclopenten-1-carboxylat, (B2.89) Methyl (3S)-3-[[[(5R)-3-(3,5-difluorphenyl)-5-methyl-4H-1,2-oxazol-5- yl]carbonyl]amino]-cyclopenten-1-carboxylat, (B2.90) 3-(3,5-Difluorphenyl)-N-[(1R,4S)-4-(oxazinan-2-ylcarbonyl)cyclopent-2-en- 1-yl]-5-(trifluormethyl)-4H-1,2-oxazol-5-carboxamid, (B2.91) 3-(3,5-Difluorphenyl)-N-[(1R,4S)-4- [(propylsulfonylamino)carbonyl]cyclopent-2-en-1-yl]-5-(trifluormethyl)-4H- 1,2-oxazol-5-carboxamid, (B2.92) (1S,4R)-4-[[(5R)-3-(3,5-difluorophenyl)-5-methyl-4H-isoxazole-5- carbonyl]amino]cyclopent-2-ene-1-carbonsäure, Besonders bevorzugt aus der Gruppe B2 sind die herbiziden Wirkstoffe (B2.1) Acetochlor, (B2.18) Diflufenican, (B2.20) Dimethenamid, (B2.24) Flazasulfuron, (B2.28) Flufenacet, (B2.31) Foramsulfuron, (B2.34) Iodosulfuron, (B2.37) Mesosulfuron, (B2.40) Metolachlor, (B2.43) Nicosulfuron, (B2.63) Rimsulfuron, (B2.64) S-metolachlor, (B2.68) Thiencarbazone, (B2.79) Methyl rel-(2R,4R)-4-[[3-(3,5-dichlorophenyl)-5-methoxy-4H-isoxazol-5-
carbonyl]amino]tetrahydrofuran-2-carboxylat, (B2.80) Methyl rel-(2R,4R)-4-[[3-(3,5-dichlorophenyl)-5-vinyl-4H-isoxazol-5- carbonyl]amino]tetrahydrofuran-2-carboxylat, (B2.81) Methyl –rel-(2R,4R)-4-[[(5S)-3-(3,5-difluorophenyl)-5-vinyl-4H-isoxazol-5- carbonyl]amino]tetrahydrofuran-2-carboxylat, (B2.82) Isopropyl rel-(2R,4R)-4-[[3-(3-fluorophenyl)-5-methyl-4H-isoxazol-5- carbonyl]amino]tetrahydrofuran-2-carboxylat, (B2.83) Methyl (3R)-3-[[(5S)-3-(3,5-difluorophenyl)-5-vinyl-4H-isoxazol-5- carbonyl]amino]-2,3-dihydrofuran-5-carboxylat, (B2.84) Methyl (3R)-3-[[(5R)-3-(3,5-difluorophenyl)-5-methyl-4H-isoxazol-5- carbonyl]amino]-2,3-dihydrofuran-5-carboxylat, (B2.85) Methyl (1S,4R)-4-[[[(5S)-3-(3,5-difluorphenyl)-5-vinyl-4H-1,2-oxazol-5- yl]carbonyl]amino]-cyclopent-2-en-1-carboxylat, (B2.86) Ethyl (1S,4R)-4-[[[3-(3,5-difluorphenyl)-5-methoxy-4H-1,2-oxazol-5- yl]carbonyl]amino]cyclopent-2-en-1-carboxylat, (B2.87) 2-Methoxyethyl (1S,4R)-4-[[[(5R)-3-(3-cyano-5-fluorphenyl)-5- (trifluormethyl)-4H-1,2-oxazol-5-yl]carbonyl]amino]cyclopent-2-en-1- carboxylat, (B2.88) Methyl (4S)-4-[[[3-(3,5-difluorphenyl)-5-methyl-4H-1,2-oxazol-5- yl]carbonyl]amino]cyclopenten-1-carboxylat, (B2.89) Methyl (3S)-3-[[[(5R)-3-(3,5-difluorphenyl)-5-methyl-4H-1,2-oxazol-5- yl]carbonyl]amino]-cyclopenten-1-carboxylat, (B2.90) 3-(3,5-Difluorphenyl)-N-[(1R,4S)-4-(oxazinan-2-ylcarbonyl)cyclopent-2-en- 1-yl]-5-(trifluormethyl)-4H-1,2-oxazol-5-carboxamid, (B2.91) 3-(3,5-Difluorphenyl)-N-[(1R,4S)-4- [(propylsulfonylamino)carbonyl]cyclopent-2-en-1-yl]-5-(trifluormethyl)-4H- 1,2-oxazol-5-carboxamid, (B2.92) (1S,4R)-4-[[(5R)-3-(3,5-difluorophenyl)-5-methyl-4H-isoxazole-5- carbonyl]amino]cyclopent-2-ene-1-carbonsäure In einer sechsten Ausführungsform der vorliegenden Erfindung sind die herbiziden Wirkstoffe (B3) bevorzugt: (B3.1) Bromoxynil, (B3.4) Ioxynil
In einer siebten Ausführungsform der vorliegenden Erfindung sind die herbiziden Wirkstoffe (B4) bevorzugt: (B4.2) Amitrole, (B4.8) Carfentrazone, (B4.10) Imazamethabenz, (B4.11) Imazamox, (B4.12) Imazapic, (B4.13) Imazapyr, (B4.15) Imazethapyr, (B4.17) Isoxaben, (B4.18) Isoxaflutole, (B4.20) Oxadiazon, (B4.21) Pyraflufen, (B4.22) Pyrasulfotole, (B4.25) Pyroxasulfone, (B4.26) Sulfentrazone, (B4.27) Tolpyralate, (B4.28) Topramezone, (B4.33) Flupoxam Besonders bevorzugt aus der Gruppe B4 sind die herbiziden Wirkstoffe (B4.8) Carfentrazone, (B4.11) Imazamox, (B4.13) Imazapyr, (B4.15) Imazethapyr, (B4.18) Isoxaflutole, (B4.20) Oxadiazon, (B4.21) Pyraflufen, (B4.22) Pyrasulfotole, (B4.25) Pyroxasulfone, (B4.26) Sulfentrazone, (B4.27) Tolpyralate
In einer achten Ausführungsform der vorliegenden Erfindung sind die herbiziden Wirkstoffe (B5) bevorzugt: (B5.1) Aminocyclopyrachlor, (B5.2) Aminopyralid, (B5.3) Benazolin, (B5.5) Bentazone, (B5.7) Bixlozone, (B5.12) Cinidon, (B5.13) Cinmethylin, (B5.14) Clomazone, (B5.21) Ethofumesate, (B5.22) Flamprop, (B5.23) Florpyrauxifen, (B5.26) Flumioxazin, (B5.27) Fluridone, (B5.28) Flurochloridone, (B5.29) Flurtamone, (B5.30) Fluthiacet-methyl, (B5.31) Halauxifen, (B5.32) Indanofan, (B5.37) Paraquat, (B5.38) Pelargonsäure, (B5.39) Pendimethalin, (B5.45) Triafamone, (B5.46) Trifluralin, (B5.47) 4-Amino-3-chloro-5- fluoro-6-(7-fluoro-1H- indol-6-yl)pyridine-2- carbonsäure, (B5.48) Cyclopyrimorate, (B5.49) Diquat, (B5.50) Oxaziclomefone. (B5.54) 4-Hydroxy-1-methyl-3-[4- (trifluoromethyl)-2- pyridinyl]-2-imidazolidinon
Besonders bevorzugt aus der Gruppe B5 sind die herbiziden Wirkstoffe (B5.5) Bentazone, (B5.23) Florpyrauxifen, (B5.26) Flumioxazin, (B5.30) Fluthiacet-methyl, (B5.31) Halauxifen, (B5.37) Paraquat, (B5.38) Pelargonsäure. In einer neunten Ausführungsform der vorliegenden Erfindung sind die herbiziden Wirkstoffe (B6) bevorzugt: (B6.2) Clopyralid, (B6.3) Dicamba, (B6.4) Fluroxypyr, (B6.5) Picloram Besonders bevorzugt aus der Gruppe B6 ist der herbizide Wirkstoff (B6.3) Dicamba, In einer zehnten Ausführungsform der vorliegenden Erfindung sind die herbiziden Wirkstoffe (B7) bevorzugt: (B7.2) Bialaphos, (B7.4) Glufosinate, (B7.5) Glyphosate, (B7.7) Sulfosate Besonders bevorzugt aus der Gruppe B7 sind die herbiziden Wirkstoffe (B7.4) Glufosinate, (B7.5) Glyphosate, (B7.7) Sulfosate In einer elften Ausführungsform der vorliegenden Erfindung sind die herbiziden Wirkstoffe (B8) bevorzugt: (B8.1) 2,4-D, (B8.2) 2,4-DB, (B8.3) 2,4-DP,
(B8.4) Acifluorfen, (B8.5) Aclonifen, (B8.8) Clodinafop, (B8.11) Diclofop, (B8.13) Fenoxaprop, (B8.16) Fomesafen, (B8.19) Lactofen, (B8.20) MCPA, (B8.22) Mecoprop, (B8.24) Oxyfluorfen, (B8.26) Quizalofop, (B8.27) Quizalofop-P Besonders bevorzugt aus der Gruppe B8 sind die herbiziden Wirkstoffe (B8.1) 2,4-D, (B8.2) 2,4-DB, (B8.3) 2,4-DP, (B8.4) Acifluorfen, (B8.5) Aclonifen, (B8.16) Fomesafen, (B8.19) Lactofen, (B8.24) Oxyfluorfen In einer zwölften Ausführungsform der vorliegenden Erfindung sind die herbiziden Wirkstoffe (B9) bevorzugt: (B9.3) Butafenacil, (B9.10) Saflufenacil, (B9.11) Terbacil, (B9.12) Tiafenacil, (B9.13) Trifludimoxazin, (B9.14) Ethyl[3-[2-chloro-4-fluoro-5-(1- methyl-6-trifluoromethyl-2,4- dioxo-1,2,3,4- tetrahydropyrimidin-3- yl)phenoxy]-2-pyridyloxy]acetat
Besonders bevorzugt aus der Gruppe B9 sind die herbiziden Wirkstoffe (B9.3) Butafenacil, (B9.10) Saflufenacil, (B9.12) Tiafenacil, (B9.13) Trifludimoxazin, (B9.14) Ethyl[3-[2-chloro-4-fluoro-5-(1- methyl-6-trifluoromethyl-2,4- dioxo-1,2,3,4- tetrahydropyrimidin-3- yl)phenoxy]-2-pyridyloxy]acetat In einer dreizehnten Ausführungsform der vorliegenden Erfindung sind die herbiziden Wirkstoffe (B10) bevorzugt: (B10.1) Chlorobromuron, (B10.2) Chlorotoluron, (B10.5) Diuron, (B10.8) Isoproturon, (B10.9) Linuron, (B10.10) Methabenzthiazuron, (B10.11) Metobromuron, (B10.12) Metoxuron, (B10.13) Monolinuron Besonders bevorzugt aus der Gruppe B10 sind die herbiziden Wirkstoffe (B10.5) Diuron, (B10.8) Isoproturon In einer vierzehnten Ausführungsform der vorliegenden Erfindung sind die herbiziden Wirkstoffe (B11) bevorzugt: (B11.1) Ametryne, (B11.2) Atrazine, (B11.5) Hexazinone, (B11.6) Indaziflam, (B11.8) Metribuzin, (B11.12) Simazine, (B11.15) Terbuthylazine,
(B11.16) Terbutryne Besonders bevorzugt sind aus der Gruppe B11 sind die herbiziden Wirkstoffe (B11.2) Atrazine, (B11.6) Indaziflam, (B11.8) Metribuzin, (B11.15) Terbuthylazine Im Rahmen der vorliegenden Erfindung ist es möglich, die einzelnen bevorzugten, besonders bevorzugten und am meisten Ausführungsformen beliebig miteinander zu kombinieren. Das heißt, dass herbizide Zusammensetzungen enthaltend (A) eine oder mehrere Verbindungen der allgemeinen Formel (I) oder deren agrochemisch verträglichen Salze [Komponente (A)] sowie (B) ein oder mehrere Herbizide [Komponente (B)] ausgewählt aus der Gruppe der herbiziden Wirkstoffe (B1) bis (B11)von der vorliegenden Erfindung umfasst sind, in welchen beliebige offenbarte, bevorzugte, besonders bevorzugte und am meisten bevorzugte Ausführungsformen wie oben aufgeführt miteinander kombiniert werden können. Einige binäre Zusammensetzungen enthaltend (A) eine oder mehrere herbizid wirksame Verbindungen (A) der allgemeinen Formel (I) oder deren agrochemisch verträglichen Salze [Herbizide (A)], sowie ein Herbizid (B) haben sich überraschenderweise als besonders vorteilhaft erwiesen. Im Folgenden sind die bevorzugten, besonders bevorzugten und am meisten bevorzugten binären Systeme als weitere Ausführungsformen der vorliegenden Erfindung aufgelistet. In einer fünfzehnten Ausführungsform der vorliegenden Erfindung enthält die Zusammensetzung bevorzugt (A) eine Verbindung der allgemeinen Formel (I) oder deren agrochemisch verträglichen Salze [Herbizide (A)]
worin R1 für Wasserstoff steht,
R2 für Fluor steht, R3 für Fluor steht, R4 für Chlor, Brom oder Cyano steht, R5 für Wasserstoff steht, R6 für Wasserstoff, Fluor steht, R7 für Wasserstoff steht, G für Methylen steht, X für O (Sauerstoff) steht, Y für O (Sauerstoff) steht, und Q für eine der spezifisch genannten Gruppierungen
steht. und (B) ein Herbizid [Komponente (B)] aus der Gruppe, bestehend aus (B1.2) Bicyclopyrone, (B1.4) Clethodim, (B1.7) Mesotrione, (B1.8) Pinoxaden, (B1.14) Tembotrione, (B2.1) Acetochlor, (B2.18) Diflufenican, (B2.20) Dimethenamid, (B2.24) Flazasulfuron, (B2.28) Flufenacet, (B2.31) Foramsulfuron, (B2.34) Iodosulfuron, (B2.37) Mesosulfuron, (B2.40) Metolachlor, (B2.43) Nicosulfuron, (B2.63) Rimsulfuron, (B2.64) S-metolachlor, (B2.68) Thiencarbazone, (B2.79) Methyl rel-(2R,4R)-4-[[3-(3,5-dichlorophenyl)-5-methoxy-4H-isoxazol-5- carbonyl]amino]tetrahydrofuran-2-carboxylat, (B2.80) Methyl rel-(2R,4R)-4-[[3-(3,5-dichlorophenyl)-5-vinyl-4H-isoxazol-5- carbonyl]amino]tetrahydrofuran-2-carboxylat,
(B2.81) Methyl –rel-(2R,4R)-4-[[(5S)-3-(3,5-difluorophenyl)-5-vinyl-4H-isoxazol-5- carbonyl]amino]tetrahydrofuran-2-carboxylat, (B2.82) Isopropyl rel-(2R,4R)-4-[[3-(3-fluorophenyl)-5-methyl-4H-isoxazol-5- carbonyl]amino]tetrahydrofuran-2-carboxylat, (B2.83) Methyl (3R)-3-[[(5S)-3-(3,5-difluorophenyl)-5-vinyl-4H-isoxazol-5- carbonyl]amino]-2,3-dihydrofuran-5-carboxylat, (B2.84) Methyl (3R)-3-[[(5R)-3-(3,5-difluorophenyl)-5-methyl-4H-isoxazol-5- carbonyl]amino]-2,3-dihydrofuran-5-carboxylat, (B2.85) Methyl (1S,4R)-4-[[[(5S)-3-(3,5-difluorphenyl)-5-vinyl-4H-1,2-oxazol-5- yl]carbonyl]amino]-cyclopent-2-en-1-carboxylat, (B2.86) Ethyl (1S,4R)-4-[[[3-(3,5-difluorphenyl)-5-methoxy-4H-1,2-oxazol-5- yl]carbonyl]amino]cyclopent-2-en-1-carboxylat, (B2.87) 2-Methoxyethyl (1S,4R)-4-[[[(5R)-3-(3-cyano-5-fluorphenyl)-5-(trifluormethyl)-4H- 1,2-oxazol-5-yl]carbonyl]amino]cyclopent-2-en-1-carboxylat, (B2.88) Methyl (4S)-4-[[[3-(3,5-difluorphenyl)-5-methyl-4H-1,2-oxazol-5- yl]carbonyl]amino]cyclopenten-1-carboxylat, (B2.89) Methyl (3S)-3-[[[(5R)-3-(3,5-difluorphenyl)-5-methyl-4H-1,2-oxazol-5- yl]carbonyl]amino]-cyclopenten-1-carboxylat, (B2.90) 3-(3,5-Difluorphenyl)-N-[(1R,4S)-4-(oxazinan-2-ylcarbonyl)cyclopent-2-en-1-yl]-5- (trifluormethyl)-4H-1,2-oxazol-5-carboxamid, (B2.91) 3-(3,5-Difluorphenyl)-N-[(1R,4S)-4-[(propylsulfonylamino)carbonyl]cyclopent-2- en-1-yl]-5-(trifluormethyl)-4H-1,2-oxazol-5-carboxamid, (B2.92) (1S,4R)-4-[[(5R)-3-(3,5-difluorophenyl)-5-methyl-4H-isoxazole-5- carbonyl]amino]cyclopent-2-ene-1-carbonsäure (B3.1) Bromoxynil (B4.8) Carfentrazone, (B4.11) Imazamox, (B4.13) Imazapyr, (B4.15) Imazethapyr, (B4.18) Isoxaflutole, (B4.20) Oxadiazon, (B4.21) Pyraflufen, (B4.22) Pyrasulfotole, (B4.25) Pyroxasulfone,
(B4.26) Sulfentrazone, (B4.27) Tolpyralate (B5.5) Bentazone, (B5.14) Clomazone, (B5.23) Florpyrauxifen, (B5.26) Flumioxazin, (B5.30) Fluthiacet-methyl, (B5.31) Halauxifen, (B5.37) Paraquat, (B5.38) Pelargonsäure (B6.3) Dicamba (B7.2) Bialaphos, (B7.4) Glufosinate, (B7.5) Glyphosate, (B7.7) Sulfosate (B8.1) 2,4-D, (B8.2) 2,4-DB, (B8.3) 2,4-DP, (B8.4) Acifluorfen, (B8.5) Aclonifen, (B8.13) Fenoxaprop, (B8.16) Fomesafen, (B8.19) Lactofen, (B8.24) Oxyfluorfen (B9.3) Butafenacil, (B9.10) Saflufenacil, (B9.12) Tiafenacil, (B9.13) Trifludimoxazin, (B9.14) Ethyl[3-[2-chloro-4-fluoro-5-(1-methyl-6-trifluoromethyl-2,4-dioxo-1,2,3,4- tetrahydropyrimidin-3-yl)phenoxy]-2-pyridyloxy]acetat;
(B10.5) Diuron, (B10.8) Isoproturon (B11.2) Atrazine, (B11.6) Indaziflam, (B11.8) Metribuzin, (B11.15) Terbuthylazine In einer sechszehnten Ausführungsform der vorliegenden Erfindung enthält die Zusammensetzung bevorzugt (A) eine Verbindung der allgemeinen Formel (I) oder deren agrochemisch verträglichen Salze [Herbizide (A)] worin
R1 für Wasserstoff steht, R2 für Fluor steht, R3 für Fluor steht, R4 für Chlor, Brom oder Cyano steht, R5 für Wasserstoff steht, R6 für Wasserstoff, Fluor steht, R7 für Wasserstoff steht, G für Methylen steht,
X für O (Sauerstoff) steht, Y für O (Sauerstoff) steht, und Q für eine der spezifisch genannten Gruppierungen
steht. und (B) ein Herbizid [Komponente (B)] aus der Gruppe, bestehend aus (B1.2) Bicyclopyrone (CAS 352010-68-5),
(B1.4) Clethodim (CAS 99129-21-2), (B1.7) Mesotrione (CAS 104206-82-8), (B1.14) Tembotrione (CAS 335104-84-2) (B2.1) Acetochlor (CAS 34256-82-1), (B2.18) Diflufenican (CAS 83164-33-4), (B2.20) Dimethenamid (CAS 87674-68-8), (B2.24) Flazasulfuron (CAS 104040-78-0), (B2.28) Flufenacet (CAS 142459-58-3), (B2.31) Foramsulfuron (CAS 173159-57-4), (B2.34) Iodosulfuron (CAS 144550-36-7), (B2.37) Mesosulfuron (CAS 208465-21-8), (B2.63) Rimsulfuron (CAS 122931-48-0), (B2.64) S-metolachlor (CAS 87392-12-9), (B2.68) Thiencarbazone (CAS 317815-83-1), (B2.81) Methyl –rel-(2R,4R)-4-[[(5S)-3-(3,5-difluorophenyl)-5-vinyl-4H-isoxazol-5- carbonyl]amino]tetrahydrofuran-2-carboxylat (B3.1) Bromoxynil (CAS 1689-84-5) (B4.11) Imazamox (CAS 1143-11-32-9), (B4.15) Imazethapyr (CAS 81335-77-5), (B4.18) Isoxaflutole (CAS 141112-29-0), (B4.20) Oxadiazon (CAS 19666-30-9), (B4.21) Pyraflufen-ethyl (CAS 129630-19-9), (B4.25) Pyroxasulfone (CAS 365400-11-9), (B4.26) Sulfentrazone (CAS 122836-35-5) (B5.5) Bentazone (CAS 25057-89-0), (B5.14) Clomazone (CAS 81777-95-9), (B5.23) Florpyrauxifen (CAS 943832-81-3), (B5.26) Flumioxazin (CAS 103361-09-7), (B5.37) Paraquat (CAS 1910-42-5) (B6.3) Dicamba (CAS 1918-00-9)
(B7.4) Glufosinate (CAS 77182-82-2), (B7.5) Glyphosate (CAS 70901-12-1) (B8.1) 2,4-D (CAS 94-75-7), (B8.5) Aclonifen (CAS 74070-46-5), (B8.16) Fomesafen (CAS 72178-02-0), (B8.24) Oxyfluorfen (CAS 42874-03-3) (B9.3) Butafenacil (CAS 134605-64-4), (B9.10) Saflufenacil (CAS 372137-35-4), (B9.13) Trifludimoxazin (CAS 1258836-72-4) (B10.5) Diuron (CAS 330-54-1) (B11.2) Atrazine (CAS 1912-24-9), (B11.6) Indaziflam (CAS 950782-86-2) (B11.8) Metribuzin (CAS 21087-64-9), (B11.15) Terbuthylazine (CAS 5915-41-3) Besonders bevorzugte Zusammensetzungen im Sinne der vorliegenden Erfindung sind die Zusammensetzungen, wie in den folgenden Tabellen 2.1 – 2.4 aufgeführt: Tabelle 2.1: Besonders bevorzugte binäre Zusammensetzungen enthaltend (A1)
stands. In a second embodiment of the present invention, herbicidally active substances (A) are compounds of the formula (I), wherein R 1 is hydrogen, R 2 is fluoro, R 3 is fluoro, R 4 is chloro, bromo, or cyano, R 5 is hydrogen, R 6 is hydrogen, fluorine, R 7 is hydrogen, G is methylene, X is O (oxygen), Y is O (oxygen), and Q is any of the moieties specifically mentioned stands. In a third embodiment of the present invention, in addition to at least one component (B) as defined above, the herbicidal composition preferably contains one or more compounds [component (A)] of the general formula (I) or their agrochemically compatible salts [herbicides (A)]. Tables 1a and 1b. Table 1a: Preferred compounds of the formula (I) as herbicide (A)): All of these preferred compounds are listed again in Table 1b below by their structural formula and corresponding IUPAC name. Table 1b: IUPAC names and structural formulas of the preferred compounds of formula (I) (herbicide (A)) The compounds of the formula (I) are known from the international application with the application number PCT/EP2020/070463 (published as WO2021/013799) and can be prepared by the processes described there. The application rates of the herbicides (A) are in the range from 0.02 to 750 g of active substance per hectare (hereinafter g ai/ha), preferably 0.05 to 400 g ai/ha, in particular 0.25 to 300 g ai/ha ). In the combinations according to the invention, in the context of the application rates mentioned, lower application rates of the respective active ingredient are usually required compared to individual application, preferably 0.02 to 250 g ai/ha, in particular 0.05 to 150 g ai/ha, and most preferably 0. 25 to 120 g ai/ha. In principle, all active ingredients of subgroups (B1) to (B11) are suitable as combination partners (B) [= component (B) or herbicides (B)]. notation) according to the reference "The Pesticide Manual" 14th Ed., British Crop Protection Council 2006, abbreviated "PM" or the chemical name according to the usual nomenclature (IUPAC or Chemical Abstracts). Surprisingly, however, some herbicides (B) have proven to be particularly good combination partners. The preferred, particularly preferred and most preferred herbicides (B) are listed below as further embodiments of the present invention. In a fourth embodiment of the present invention, the herbicidal active ingredients (B1) are preferred: (B1.2) bicyclopyrone, (B1.4) clethodim, (B1.7) mesotrione, (B1.8) pinoxaden, (B1.10) sethoxydim , (B1.11) sulcotriones, (B1.14) tembotriones, (B1.16) tralkoxydim. Particularly preferred from group B1 are the herbicidal active ingredients (B1.2) bicyclopyrone, (B1.4) clethodim, (B1.7) mesotrione, (B1.8) pinoxaden, (B1.14) tembotrione In a fifth embodiment of the present invention Invention, the herbicidal active ingredients (B2) are preferred: (B2.1) acetochlor, (B2.4) asulam, (B2.6) beflubutamide, (B2.10) chlorimuron, (B2.12) chlorsulfuron, (B2.14) cloransulam, (B2.17) diclosulam, (B2.18) diflufenican, (B2.20) dimethenamid, (B2.23) ethoxysulfuron, (B2.24) flazasulfuron, (B2.25) florasulam, (B2.26) flucarbazone, (B2.28) flufenacet, (B2.29) flumetsulam, (B2.30) flupyrsulfuron, (B2.31) foramsulfuron, (B2.34) iodosulfuron, (B2.37) mesosulfuron, ( B2.40) metolachlor, (B2.41) metosulam, (B2.42) metsulfuron, (B2.43) nicosulfuron, (B2.46) penoxsulam, (B2.49) picolinafen, (B2.56) propoxycarbazone, (B2 .59) prosulfocarb, (B2.60) prosulfuron, (B2.62) pyroxsulam, (B2.63) rimsulfuron, (B2.64) S-metolachlor, (B2.65) sulfometuron, (B2.66) sulfosulfuron, ( B2.68) thiencarbazones, (B2.69) thifensulfuron, (B2.72) tribenuron, (B2.76) esprocarb, (B2.78) tri-allate, (B2.79) methyl rel-(2R,4R)- 4-[[3-(3,5-dichlorophenyl)-5-methoxy-4H-isoxazole-5-carbonyl]amino]tetrahydrofuran-2-carboxylate, (B2.80) methyl rel-(2R,4R)-4- [[3-(3,5-dichlorophenyl)-5-vinyl-4H-isoxazole-5-carbonyl]amino]tetrahydrofuran-2-carboxylate, (B2.81) methyl -rel-(2R,4R)-4-[ [(5S)-3-(3,5-difluorophenyl)-5-vinyl-4H-isoxazole-5-carbonyl]amino]tetrahydrofuran-2-carboxylate, (B2.82) isopropyl rel-(2R,4R)-4 -[[3-(3-fluorophenyl)-5-methyl-4 H-isoxazole-5-carbonyl]amino]tetrahydrofuran-2-carboxylate, (B2.83) methyl (3R)-3-[[(5S)-3-(3,5-difluorophenyl)-5-vinyl-4H- isoxazole-5-carbonyl]amino]-2,3-dihydrofuran-5-carboxylate, (B2.84) Methyl (3R)-3-[[(5R)-3-(3,5-difluorophenyl)-5-methyl-4H-isoxazole-5-carbonyl]amino]-2,3-dihydrofuran-5 -carboxylate, (B2.85) methyl (1S,4R)-4-[[[(5S)-3-(3,5-difluorophenyl)-5-vinyl-4H-1,2-oxazol-5-yl] carbonyl]amino]cyclopent-2-ene-1-carboxylate, (B2.86) ethyl (1S,4R)-4-[[[3-(3,5-difluorophenyl)-5-methoxy-4H-1, 2-oxazol-5-yl]carbonyl]amino]cyclopent-2-en-1-carboxylate, (B2.87) 2-Methoxyethyl (1S,4R)-4-[[[(5R)-3-(3- cyano-5-fluorophenyl)-5-(trifluoromethyl)-4H-1,2-oxazol-5-yl]carbonyl]amino]cyclopent-2-ene-1-carboxylate, (B2.88) methyl (4S)-4 -[[[3-(3,5-difluorophenyl)-5-methyl-4H-1,2-oxazol-5-yl]carbonyl]amino]cyclopentene-1-carboxylate, (B2.89) methyl (3S)- 3-[[[(5R)-3-(3,5-difluorophenyl)-5-methyl-4H-1,2-oxazol-5-yl]carbonyl]amino]cyclopentene-1-carboxylate, (B2.90 ) 3-(3,5-difluorophenyl)-N-[(1R,4S)-4-(oxazinan-2-ylcarbonyl)cyclopent-2-en-1-yl]-5-(trifluoromethyl)-4H-1, 2-oxazole-5-carboxamide, (B2.91) 3-(3,5-difluorophenyl)-N-[(1R,4S)-4-[(propylsulfonylamino)carbonyl]cyclopent-2-en-1-yl] -5-(t trifluoromethyl)-4H- 1,2-oxazole-5-carboxamide, (B2.92) (1S,4R)-4-[[(5R)-3-(3,5-difluorophenyl)-5-methyl-4H- isoxazole-5-carbonyl]amino]cyclopent-2-ene-1-carboxylic acid. The herbicidal active ingredients (B2.1) acetochlor, (B2.18) diflufenican, (B2.20) dimethenamid, (B2.20) dimethenamid, (B2.20) are particularly preferred from group B2. B2.24) Flazasulfuron, (B2.28) Flufenacet, (B2.31) Foramsulfuron, (B2.34) Iodosulfuron, (B2.37) Mesosulfuron, (B2.40) Metolachlor, (B2.43) Nicosulfuron, (B2 .63) rimsulfuron, (B2.64) S-metolachlor, (B2.68) thiencarbazone, (B2.79) methyl rel-(2R,4R)-4-[[3-(3,5-dichlorophenyl)-5 -methoxy-4H-isoxazole-5- carbonyl]amino]tetrahydrofuran-2-carboxylate, (B2.80) methyl rel-(2R,4R)-4-[[3-(3,5-dichlorophenyl)-5-vinyl-4H-isoxazole-5-carbonyl] amino]tetrahydrofuran-2-carboxylate, (B2.81) methyl -rel-(2R,4R)-4-[[(5S)-3-(3,5-difluorophenyl)-5-vinyl-4H-isoxazole-5 - carbonyl]amino]tetrahydrofuran-2-carboxylate, (B2.82) isopropyl rel-(2R,4R)-4-[[3-(3-fluorophenyl)-5-methyl-4H-isoxazole-5-carbonyl]amino ]tetrahydrofuran-2-carboxylate, (B2.83) methyl (3R)-3-[[(5S)-3-(3,5-difluorophenyl)-5-vinyl-4H-isoxazol-5-carbonyl]amino]- 2,3-dihydrofuran-5-carboxylate, (B2.84) methyl (3R)-3-[[(5R)-3-(3,5-difluorophenyl)-5-methyl-4H-isoxazole-5-carbonyl] amino]-2,3-dihydrofuran-5-carboxylate, (B2.85) methyl (1S,4R)-4-[[[(5S)-3-(3,5-difluorophenyl)-5-vinyl-4H- 1,2-oxazol-5-yl]carbonyl]amino]cyclopent-2-ene-1-carboxylate, (B2.86) ethyl (1S,4R)-4-[[[3-(3,5-difluorophenyl )-5-Methoxy-4H-1,2-oxazol-5-yl]carbonyl]amino]cyclopent-2-ene-1-carboxylate, (B2.87) 2-Methoxyethyl (1S,4R)-4-[[ [(5R)-3-(3-cyano-5-fluorophenyl)-5-(trifluoromethyl)- 4H-1,2-oxazol-5-yl]carbonyl]amino]cyclopent-2-en-1-carboxylate, (B2.88) methyl (4S)-4-[[[3-(3,5-difluorophenyl) -5-methyl-4H-1,2-oxazol-5-yl]carbonyl]amino]cyclopentene-1-carboxylate, (B2.89) methyl (3S)-3-[[[(5R)-3-(3 ,5-difluorophenyl)-5-methyl-4H-1,2-oxazol-5-yl]carbonyl]amino]cyclopentene-1-carboxylate, (B2.90) 3-(3,5-difluorophenyl)-N- [(1R,4S)-4-(oxazinan-2-ylcarbonyl)cyclopent-2-en-1-yl]-5-(trifluoromethyl)-4H-1,2-oxazole-5-carboxamide, (B2.91) 3-(3,5-Difluorophenyl)-N-[(1R,4S)-4-[(propylsulfonylamino)carbonyl]cyclopent-2-en-1-yl]-5-(trifluoromethyl)-4H-1,2- oxazole-5-carboxamide, (B2.92) (1S,4R)-4-[[(5R)-3-(3,5-difluorophenyl)-5-methyl-4H-isoxazole-5-carbonyl]amino]cyclopent -2-ene-1-carboxylic acid In a sixth embodiment of the present invention, the herbicidal active ingredients (B3) are preferred: (B3.1) bromoxynil, (B3.4) ioxynil In a seventh embodiment of the present invention, the herbicidal active ingredients (B4) are preferred: (B4.2) amitrols, (B4.8) carfentrazone, (B4.10) imazamethabenz, (B4.11) imazamox, (B4.12) imazapic , (B4.13) imazapyr, (B4.15) imazethapyr, (B4.17) isoxaben, (B4.18) isoxaflutole, (B4.20) oxadiazon, (B4.21) pyraflufen, (B4.22) pyrasulfotole, ( B4.25) pyroxasulfones, (B4.26) sulfentrazone, (B4.27) tolpyralate, (B4.28) topramezone, (B4.33) flupoxam The herbicidal active ingredients (B4.8) carfentrazone are particularly preferred from group B4 , (B4.11) imazamox, (B4.13) imazapyr, (B4.15) imazethapyr, (B4.18) isoxaflutole, (B4.20) oxadiazon, (B4.21) pyraflufen, (B4.22) pyrasulfotole, ( B4.25) pyroxasulfones, (B4.26) sulfentrazones, (B4.27) tolpyralates In an eighth embodiment of the present invention, the herbicidal active ingredients (B5) are preferred: (B5.1) aminocyclopyrachlor, (B5.2) aminopyralid, (B5.3) benazoline, (B5.5) bentazone, (B5.7) bixlozone , (B5.12) cinidone, (B5.13) cinmethyline, (B5.14) clomazone, (B5.21) ethofumesate, (B5.22) flamprop, (B5.23) florpyrauxifen, (B5.26) flumioxazine, (B5.27) fluridone, (B5.28) flurochloridone, (B5.29) flurtamone, (B5.30) fluthiacet-methyl, (B5.31) halauxifen, (B5.32) indanofan, (B5.37) paraquat , (B5.38) pelargonic acid, (B5.39) pendimethalin, (B5.45) triafamone, (B5.46) trifluralin, (B5.47) 4-amino-3-chloro-5-fluoro-6-(7 -fluoro-1H-indol-6-yl)pyridine-2-carboxylic acid, (B5.48) cyclopyrimorate, (B5.49) diquat, (B5.50) oxaziclomefone. (B5.54) 4-Hydroxy-1-methyl-3-[4-(trifluoromethyl)-2-pyridinyl]-2-imidazolidinone The herbicidal active ingredients (B5.5) bentazone, (B5.23) florpyrauxifen, (B5.26) flumioxazin, (B5.30) fluthiacet-methyl, (B5.31) halauxifen, (B5. 37) paraquat, (B5.38) pelargonic acid. In a ninth embodiment of the present invention, the herbicidal active ingredients (B6) are preferred: (B6.2) clopyralid, (B6.3) dicamba, (B6.4) fluroxypyr, (B6.5) picloram is particularly preferably from group B6 the herbicidal active ingredient (B6.3) dicamba, In a tenth embodiment of the present invention, the herbicidal active ingredients (B7) are preferred: (B7.2) bialaphos, (B7.4) glufosinate, (B7.5) glyphosate, (B7. 7) Sulphosates Particularly preferred from group B7 are the herbicidal active ingredients (B7.4) glufosinate, (B7.5) glyphosate, (B7.7) sulfosate. In an eleventh embodiment of the present invention, the herbicidal active ingredients (B8) are preferred: ( B8.1) 2.4-D, (B8.2) 2.4-DB, (B8.3) 2.4-DP, (B8.4) acifluorfen, (B8.5) aclonifen, (B8.8) clodinafop, (B8.11) diclofop, (B8.13) fenoxaprop, (B8.16) fomesafen, (B8.19) lactofen, ( B8.20) MCPA, (B8.22) mecoprop, (B8.24) oxyfluorfen, (B8.26) quizalofop, (B8.27) quizalofop-P The herbicidal active ingredients (B8.1) are particularly preferred from group B8 2,4-D, (B8.2) 2,4-DB, (B8.3) 2,4-DP, (B8.4) acifluorfen, (B8.5) aclonifen, (B8.16) fomesafen, ( B8.19) Lactofen, (B8.24) Oxyfluorfen In a twelfth embodiment of the present invention, the herbicidal active ingredients (B9) are preferred: (B9.3) butafenacil, (B9.10) saflufenacil, (B9.11) terbacil, ( B9.12) tiafenacil, (B9.13) trifludimoxazine, (B9.14) ethyl[3-[2-chloro-4-fluoro-5-(1-methyl-6-trifluoromethyl-2,4-dioxo-1), 2,3,4-tetrahydropyrimidin-3-yl)phenoxy]-2-pyridyloxy]acetate The herbicidal active ingredients (B9.3) butafenacil, (B9.10) saflufenacil, (B9.12) tiafenacil, (B9.13) trifludimoxazine, (B9.14) ethyl[3-[2- chloro-4-fluoro-5-(1-methyl-6-trifluoromethyl-2,4-dioxo-1,2,3,4-tetrahydropyrimidin-3-yl)phenoxy]-2-pyridyloxy]acetate In a thirteenth embodiment of the present invention, the herbicidal active ingredients (B10) are preferred: (B10.1) chlorobromuron, (B10.2) chlorotoluron, (B10.5) diuron, (B10.8) isoproturon, (B10.9) linuron, (B10.10 ) methabenzthiazuron, (B10.11) metobromuron, (B10.12) metoxuron, (B10.13) monolinuron Particularly preferred from group B10 are the herbicidal active ingredients (B10.5) diuron, (B10.8) isoproturon In a fourteenth embodiment According to the present invention, the herbicidal active ingredients (B11) are preferred: (B11.1) Ametryne, (B11.2) Atrazine, (B11.5) Hexazinone, (B11.6) Indaziflam, (B11.8) Metribuzin, (B11. 12) simazines, (B11.15) terbuthylazines, (B11.16) Terbutrynes The herbicidal active ingredients (B11.2) atrazines, (B11.6) indaziflam, (B11.8) metribuzin, (B11.15) terbuthylazines are particularly preferred from group B11 it is possible to combine the individual preferred, particularly preferred and most preferred embodiments with one another as desired. This means that herbicidal compositions containing (A) one or more compounds of the general formula (I) or their agrochemically acceptable salts [component (A)] and (B) one or more herbicides [component (B)] selected from the group of herbicidal active ingredients (B1) to (B11) are encompassed by the present invention, in which any disclosed, preferred, particularly preferred and most preferred embodiments as listed above can be combined with one another. Some binary compositions containing (A) one or more herbicidally active compounds (A) of the general formula (I) or their agrochemically acceptable salts [herbicides (A)], and a herbicide (B) have surprisingly proven to be particularly advantageous. The preferred, particularly preferred and most preferred binary systems are listed below as further embodiments of the present invention. In a fifteenth embodiment of the present invention, the composition preferably contains (A) a compound of the general formula (I) or its agrochemically compatible salts [herbicides (A)] where R 1 is hydrogen, R 2 is fluoro, R 3 is fluoro, R 4 is chloro, bromo or cyano, R 5 is hydrogen, R 6 is hydrogen, fluoro, R 7 is hydrogen, G is methylene, X is O (oxygen), Y is O (oxygen), and Q is one of the moieties specifically mentioned stands. and (B) a herbicide [component (B)] from the group consisting of (B1.2) bicyclopyrone, (B1.4) clethodim, (B1.7) mesotrione, (B1.8) pinoxaden, (B1.14 ) tembotrione, (B2.1) acetochlor, (B2.18) diflufenican, (B2.20) dimethenamid, (B2.24) flazasulfuron, (B2.28) flufenacet, (B2.31) foramsulfuron, (B2.34) iodosulfuron, (B2.37) mesosulfuron, (B2.40) metolachlor, (B2.43) nicosulfuron, (B2.63) rimsulfuron, (B2.64) S-metolachlor, (B2.68) thiencarbazone, (B2.79 ) methyl rel-(2R,4R)-4-[[3-(3,5-dichlorophenyl)-5-methoxy-4H-isoxazole-5-carbonyl]amino]tetrahydrofuran-2-carboxylate, (B2.80) methyl rel-(2R,4R)-4-[[3-(3,5-dichlorophenyl)-5-vinyl-4H-isoxazole-5-carbonyl]amino]tetrahydrofuran-2-carboxylate, (B2.81) Methyl -rel-(2R,4R)-4-[[(5S)-3-(3,5-difluorophenyl)-5-vinyl-4H-isoxazole-5-carbonyl]amino]tetrahydrofuran-2 -carboxylate, (B2.82) Isopropyl rel-(2R,4R)-4-[[3-(3-fluorophenyl)-5-methyl-4H-isoxazol-5-carbonyl]amino]tetrahydrofuran-2-carboxylate, ( B2.83) Methyl (3R)-3-[[(5S)-3-(3,5-difluorophenyl)-5-vinyl-4H-isoxazole-5-carbonyl]amino]-2,3-dihydrofuran-5- carboxylate, (B2.84) Methyl (3R)-3-[[(5R)-3-(3,5-difluorophenyl)-5-methyl-4H-isoxazole-5-carbonyl]amino]-2,3-dihydrofuran -5-carboxylate, (B2.85) methyl (1S,4R)-4-[[[(5S)-3-(3,5-difluorophenyl)-5-vinyl-4H-1,2-oxazole-5- yl]carbonyl]amino]cyclopent-2-ene-1-carboxylate, (B2.86) ethyl (1S,4R)-4-[[[3-(3,5-difluorophenyl)-5-methoxy-4H- 1,2-oxazol-5-yl]carbonyl]amino]cyclopent-2-en-1-carboxylate, (B2.87) 2-Methoxyethyl (1S,4R)-4-[[[(5R)-3-( 3-cyano-5-fluorophenyl)-5-(trifluoromethyl)-4H-1,2-oxazol-5-yl]carbonyl]amino]cyclopent-2-ene-1-carboxylate, (B2.88) methyl (4S) -4-[[[3-(3,5-difluorophenyl)-5-methyl-4H-1,2-oxazol-5-yl]carbonyl]amino]cyclopentene-1 -carboxylate, (B2.89) methyl (3S)-3-[[[(5R)-3-(3,5-difluorophenyl)-5-methyl-4H-1,2-oxazol-5-yl]carbonyl] amino]cyclopentene-1-carboxylate, (B2.90) 3-(3,5-Difluorophenyl)-N-[(1R,4S)-4-(oxazinan-2-ylcarbonyl)cyclopent-2-en-1- yl]-5-(trifluoromethyl)-4H-1,2-oxazole-5-carboxamide, (B2.91) 3-(3,5-difluorophenyl)-N-[(1R,4S)-4-[(propylsulfonylamino )carbonyl]cyclopent-2-en-1-yl]-5-(trifluoromethyl)-4H-1,2-oxazole-5-carboxamide, (B2.92) (1S,4R)-4-[[(5R) -3-(3,5-difluorophenyl)-5-methyl-4H-isoxazole-5-carbonyl]amino]cyclopent-2-ene-1-carboxylic acid (B3.1) bromoxynil (B4.8) carfentrazone, (B4. 11) imazamox, (B4.13) imazapyr, (B4.15) imazethapyr, (B4.18) isoxaflutole, (B4.20) oxadiazon, (B4.21) pyraflufen, (B4.22) pyrasulfotole, (B4.25 ) pyroxasulfones, (B4.26) sulfentrazone, (B4.27) tolpyralate, (B5.5) bentazone, (B5.14) clomazone, (B5.23) florpyrauxifen, (B5.26) flumioxazine, (B5.30) fluthiacet-methyl, (B5.31) halauxifen, (B5.37) paraquat, (B5.38) pelargonic acid, (B6.3) dicamba, (B7.2) bialaphos, (B7.4) glufosinate, (B7.5) glyphosate, (B7. 7) sulfosates (B8.1) 2,4-D, (B8.2) 2,4-DB, (B8.3) 2,4-DP, (B8.4) acifluorfen, (B8.5) aclonifen, (B8.13) fenoxaprop, (B8.16) fomesafen, (B8.19) lactofen, (B8.24) oxyfluorfen, (B9.3) butafenacil, (B9.10) saflufenacil, (B9.12) tiafenacil, (B9 .13) Trifludimoxazine, (B9.14) Ethyl[3-[2-chloro-4-fluoro-5-(1-methyl-6-trifluoromethyl-2,4-dioxo-1,2,3,4-tetrahydropyrimidine- 3-yl)phenoxy]-2-pyridyloxy]acetate; (B10.5) diuron, (B10.8) isoproturon (B11.2) atrazine, (B11.6) indaziflam, (B11.8) metribuzin, (B11.15) terbuthylazine In a sixteenth embodiment of the present invention, the composition contains preferably (A) a compound of the general formula (I) or its agrochemically acceptable salts [herbicides (A)] wherein R 1 is hydrogen, R 2 is fluoro, R 3 is fluoro, R 4 is chloro, bromo or cyano, R 5 is hydrogen, R 6 is hydrogen, fluoro, R 7 is hydrogen, G is methylene stands, X is O (oxygen), Y is O (oxygen), and Q is one of the moieties specifically mentioned stands. and (B) a herbicide [component (B)] from the group consisting of (B1.2) Bicyclopyrone (CAS 352010-68-5), (B1.4) Clethodim (CAS 99129-21-2), (B1.7) Mesotrione (CAS 104206-82-8), (B1.14) Tembotrione (CAS 335104-84-2) (B2.1) Acetochlor (CAS 34256-82-1), (B2.18) Diflufenican (CAS 83164-33-4), (B2.20) Dimethenamid (CAS 87674-68-8), (B2.24) Flazasulfuron (CAS 104040-78). -0), (B2.28) Flufenacet (CAS 142459-58-3), (B2.31) Foramsulfuron (CAS 173159-57-4), (B2.34) Iodosulfuron (CAS 144550-36-7), ( B2.37) Mesosulfuron (CAS 208465-21-8), (B2.63) Rimsulfuron (CAS 122931-48-0), (B2.64) S-metolachlor (CAS 87392-12-9), (B2.68 ) thiencarbazones (CAS 317815-83-1), (B2.81) methyl -rel-(2R,4R)-4-[[(5S)-3-(3,5-difluorophenyl)-5-vinyl-4H- isoxazol-5- carbonyl]amino]tetrahydrofuran-2-carboxylate (B3.1) bromoxynil (CAS 1689-84-5) (B4.11) imazamox (CAS 1143-11-32-9), (B4.15) imazethapyr (CAS 81335-77-5), (B4.18) Isoxaflutole (CAS 141112-29-0), (B4.20) Oxadiazon (CAS 19666-30-9), (B4.21) Pyraflufen-ethyl (CAS 129630 -19-9), (B4.25) Pyroxasulfones (CAS 365400-11-9), (B4.26) Sulfentrazone (CAS 122836-35-5) (B5.5) Bentazone ( CAS 25057-89-0), (B5.14) Clomazone (CAS 81777-95-9), (B5.23) Florpyrauxifen (CAS 943832-81-3), (B5.26) Flumioxazine (CAS 103361-09- 7), (B5.37) Paraquat (CAS 1910-42-5) (B6.3) Dicamba (CAS 1918-00-9) (B7.4) Glufosinate (CAS 77182-82-2), (B7.5) Glyphosate (CAS 70901-12-1) (B8.1) 2,4-D (CAS 94-75-7), (B8 .5) aclonifen (CAS 74070-46-5), (B8.16) fomesafen (CAS 72178-02-0), (B8.24) oxyfluorfen (CAS 42874-03-3) (B9.3) butafenacil (CAS 134605-64-4), (B9.10) Saflufenacil (CAS 372137-35-4), (B9.13) Trifludimoxazine (CAS 1258836-72-4) (B10.5) Diuron (CAS 330-54-1) (B11.2) Atrazine (CAS 1912-24-9), (B11.6) Indaziflam (CAS 950782-86-2) (B11.8) Metribuzin (CAS 21087-64-9), (B11.15) Terbuthylazine (CAS 5915-41-3) Particularly preferred compositions within the meaning of the present invention are the compositions as listed in Tables 2.1 - 2.4 below: Table 2.1: Particularly preferred binary compositions containing (A1)
Tabelle 2.2: Besonders bevorzugte binäre Zusammensetzungen enthaltend (A2)
Tabelle 2.3: Besonders bevorzugte binäre Zusammensetzungen enthaltend (A3)
Tabelle 2.4: Besonders bevorzugte binäre Zusammensetzungen enthaltend (A4)
Weiterhin können die erfindungsgemäßen Kombinationen zusammen mit anderen Wirkstoffen wie die erwähnten Wirkstoffe (Herbizide, Fungizide, Insektizide, Akarizide etc.) und/oder Pflanzenwachstumsregulatoren oder Hilfstoffe aus der Gruppe der im Pflanzenschutz üblichen Zusatzstoffe, wie Adjuvantien und Formulierungshilfsmittel, eingesetzt werden. Die Kombination der
Pflanzenschutzmittelwirkstoffe, welche die Wirkstoffe (A) und (B) und gegebenenfalls weitere Wirkstoffe enthalten, werden hier kurz als „Herbizid-Kombination“ bezeichnet. Deren Anwendungsformen wie Formulierungen oder Tankmischungen stellen herbizide Mittel (Zusammensetzungen) dar. Gegenstand der Erfindung sind deshalb auch die herbiziden Mittel, welche die erfindungsgemäßen Wirkstoffkombinationen mit im Pflanzenschutz üblichen Zusatzstoffen, wie Adjuvantien und Formulierungshilfsmitteln, und gegebenenfalls weiteren Pflanzenschutzmittelwirkstoffen enthalten. Gegenstand der Erfindung ist auch die Verwendung der bzw. das Anwendungsverfahren unter Verwendung der erfindungsgemäßen Wirkstoffkombinationen als Herbizide und Pflanzenwachstumsregulatoren, vorzugsweise als Herbizide und Pflanzenwachstumsregulatoren mit einem synergistisch wirksamen Gehalt an der jeweils enthaltenen Wirkstoffkombination. Die Aufwandmengen der Herbizide (B) sind im Prinzip bekannt und liegen in der Regel im Bereich von 0,01 bis 4000 g a.i./ha, vorzugsweise im Bereich von 0,02 bis 3000 g a.i./ha, insbesondere 0,1 bis 2500 g a.i./ha. Für den Wirkstoff Pelargonsäure (B5.38) aus der Gruppe (B5) liegt die Aufwandmenge im Bereich von 1 bis 100.000 g a.i./ha. In den erfindungsgemäßen Mischungen werden im Rahmen der genannten Aufwandmengen im Vergleich zur Einzelapplikation in der Regel niedrigere Aufwandmengen des jeweiligen Wirkstoffs benötigt. Für die Wirkstoffe aus der Gruppe (B1) ist die Aufwandmenge vorzugsweise im Bereich von 1 bis 250 g a.i./ha, insbesondere im Bereich von 1 bis 150 g/ha, und am meisten bevorzugt im Bereich von 5 bis 100 g a.i./ha. Für die Wirkstoffe aus der Gruppe (B2) ist die Aufwandmenge vorzugsweise im Bereich von 0,1 bis 3000 g a.i./ha, insbesondere im Bereich von 0,1 bis 2700 g a.i./ha, und am meisten bevorzugt im Bereich von 1 bis 2200 g a.i./ha. Für den Wirkstoff aus der Gruppe (B3) ist die Aufwandmenge vorzugsweise im Bereich von 10 bis 1000 g a.i. /ha, insbesondere im Bereich von 10 bis 500 g a.i./ha, und am meisten bevorzugt im Bereich von 10 bis 300 g a.i./ha.
Für den Wirkstoff aus der Gruppe (B4) ist die Aufwandmenge vorzugsweise im Bereich von 1 bis 1500 g a.i. /ha, insbesondere im Bereich von 1 bis 1200 g a.i./ha, und am meisten bevorzugt im Bereich von 1 bis 1000 g a.i./ha. Für den Wirkstoff aus der Gruppe (B5), ausgenommen Pelargonsäure (B5.38), ist die Aufwandmenge vorzugsweise im Bereich von 1 bis 1500 g a.i. /ha, insbesondere im Bereich von 1 bis 1000 g a.i./ha, und am meisten bevorzugt im Bereich von 1 bis 600 g a.i./ha. Für Pelargonsäure (B.5.38) ist die Aufwandmenge vorzugsweise 1 bis 100.000 g a.i/ha, weiter bevorzugt 1 bis 40.000 g a.i./ha und insbesondere im Bereich von 1 bis 30.000 g a.i./ha. Für den Wirkstoff aus der Gruppe (B6) ist die Aufwandmenge vorzugsweise im Bereich von 1 bis 1000 g a.i. /ha, insbesondere im Bereich von 1 bis 800 g a.i./ha, und am meisten bevorzugt im Bereich von 5 bis 600 g a.i./ha. Für den Wirkstoff aus der Gruppe (B7) ist die Aufwandmenge vorzugsweise im Bereich von 20 bis 3000 g a.i. /ha, insbesondere im Bereich von 20 bis 2000 g a.i./ha, und am meisten bevorzugt im Bereich von 30 bis 1300 g a.i./ha. Für den Wirkstoff aus der Gruppe (B8) ist die Aufwandmenge vorzugsweise im Bereich von 1 bis 1500 g a.i. /ha, insbesondere im Bereich von 1 bis 1000 g a.i./ha und am meisten bevorzugt im Bereich von 1 bis 800 g a.i./ha. Für den Wirkstoff aus der Gruppe (B9) ist die Aufwandmenge vorzugsweise im Bereich von 0,1 bis 500 g a.i. /ha, insbesondere im Bereich von 0,1 bis 250 g a.i./ha, und am meisten bevorzugt im Bereich von 0,2 bis 100 g a.i./ha. Für den Wirkstoff aus der Gruppe (B10) ist die Aufwandmenge vorzugsweise im Bereich von 20 bis 2500 g a.i. /ha, insbesondere im Bereich von 20 bis 2000 g a.i./ha, und am meisten bevorzugt im Bereich von 20 bis 1500 g a.i./ha. Für den Wirkstoff aus der Gruppe (B11) ist die Aufwandmenge vorzugsweise im Bereich von 5 bis 2000 g a.i. /ha, insbesondere im Bereich von 5 bis 1500 g a.i./ha, und am meisten bevorzugt im Bereich von 5 bis 1000 g a.i./ha. Die Mengenverhältnisse (A):(B) bezogen auf das Gewicht liegen in Abhängigkeit von den wirksamen Aufwandmengen in der Regel im Bereich von 1:100000 bis 3000:1, vorzugsweise 1:80000 bis 2000:1, insbesondere im Bereich von 1:15000 bis 1000:1.
Für die Wirkstoffe aus den Gruppen (B1) bis (B11) sind die bevorzugten Gewichtsverhältnisse (A):(B) wie folgt: (A):(B1) vorzugsweise im Bereich von 150:1 bis 1:2500, insbesondere 24:1 bis 1:400; (A):(B2) vorzugsweise im Bereich von 1500:1 bis 1:45000, insbesondere 120:1 bis 1:9000; (A):(B3) vorzugsweise im Bereich von 15:1 bis 1:8500, insbesondere 12:1 bis 1:1200; (A):(B4) vorzugsweise im Bereich von 150:1 bis 1:20000, insbesondere 120:1 bis 1:4000; (A):(B5) vorzugsweise im Bereich von 150:1 bis 1:17000, insbesondere 120:1 bis 1:2400; (A):(B6) vorzugsweise im Bereich von 150:1 bis 1:13500, insbesondere 24:1 bis 1:2400; (A):(B7) vorzugsweise im Bereich von 7:1 bis 1:13500, insbesondere 4:1 bis 1:5200; (A):(B8) vorzugsweise im Bereich von 150:1 bis 1:17000, insbesondere 120:1 bis 1:3200; (A):(B9) vorzugsweise im Bereich von 1500:1 bis 1:4200, insbesondere 600:1 bis 1:400; (A):(B10) vorzugsweise im Bereich von 7:1 bis 1:34000, insbesondere 6:1 bis 1: 6000; (A):(B11) vorzugsweise im Bereich von 1500:1 bis 1:4500, insbesondere 600:1 bis 1:400. Die erfindungsgemäßen herbiziden Zusammensetzungen können auch mit weiteren Herbiziden und Pflanzenwachstumsregulatoren (= Wirkstoffe (C*) kombiniert werden, um beispielsweise das Wirkungsspektrum zu ergänzen. Als Kombinationspartner für die erfindungsgemäßen Verbindungen in Mischungsformulierungen oder im Tank-Mix sind beispielsweise bekannte Wirkstoffe, die auf einer Inhibition von beispielsweise Acetolactat-Synthase, Acetyl-CoA-Carboxylase, Cellulose-Synthase, Enolpyruvylshikimat-3-phosphat-Synthase, Glutamin-Synthetase, p-Hydroxyphenylpyruvat- Dioxygenase, Phytoendesaturase, Photosystem I, Photosystem II, Protoporphyrinogen-Oxidase beruhen, einsetzbar, wie sie z.B. aus Weed Research 26 (1986) 441-445 oder "The Pesticide Manual", 14th edition, The British Crop Protection Council and the Royal Soc. of Chemistry, 2006, das korrespondierende "e-Pesticide Manual Version 4 (2006)" und dort zitierter Literatur bekannt sind.
Weitere Handelsnamen und "common names" sind im "Compendium of Pesticide Common Names" verzeichnet (abfragbar im Internet unter http://www.alanwood.net/pesticides). Als bekannte Herbizide, die mit den erfindungsgemäßen Verbindungen kombiniert werden können, sind z.B. folgende Wirkstoffe zu nennen (Anmerkung: Die Verbindungen sind entweder mit dem "common name" nach der International Organization for Standardization (ISO) oder mit dem chemischen Namen, ggf. zusammen mit einer üblichen Codenummer bezeichnet) und umfassen stets sämtliche Anwendungsformen wie Säuren, Salze, Ester und Isomere wie Stereoisomere und optische Isomere. Dabei sind eine und zum Teil auch mehrere Anwendungsformen genannt: acifluorfen, allidochlor, amidochlor, 4-amino-3-chloro-6-(4-chloro-2-fluoro-3-methylphenyl)-5- fluoropyridine-2-carboxylic acid, ammoniumsulfamate, benfuresate, bensulide, bipyrazone, bromobutide, busoxinone, butenachlor, butylate, cambendichlor, chlorfenac, chlrofenac-ammonium, chlorfenac-sodium, chlorfenprop, chlrofenprop-methyl, chlorflurenol, chlorflurenol-methyl, chlorophthalim, clacyfos, cumyluron, cyanamide, cycloate, cyprazine, dalapon, dalapon-calcium, dalapon-magnesium, dalapon-sodium, dazomet, dazomet-sodium, n-decanol, detosyl-pyrazolate (DTP), 2-(2,4-dichlorobenzyl)-4,4-dimethyl-1,2-oxazolidin-3-one, 2-(2,5-dichlorobenzyl)-4,4-dimethyl-1,2- oxazolidin-3-one, dichlorprop, dichlorprop-butotyl, dichlroprop-dimethylammonium, dichhlorprop- etexyl, dichlorprop-ethylammonium, dichlorprop-isoctyl, dichlorprop-methyl, dichlorprop-postassium, dichlorprop-sodium, dichlorprop-P, dichlorprop-P-dimethylammonium, dichlorprop-P-etexyl, dichlorprop-P-potassium, dichlorprop-sodium, difenzoquat, difenzoquat-metilsulfate, dimepiperate, dimesulfazet, dimetrasulfuron, dinoterb, dinoterb-acetate, diphenamid, DNOC, DNOC-ammonium, DNOC-potassium, DNOC-sodium, endothal, endothal-diammonium, endothal-dipotassium, endothal- disodium, Epyrifenacil, EPTC, ethiozin, etobenzanid, F-5231, i.e. N-[2-Chlor-4-fluor-5-[4-(3- fluorpropyl)-4,5-dihydro-5-oxo-1H-tetrazol-1-yl]-phenyl]-ethansulfonamid, F-7967, i.e.3-[7-Chlor-5- fluor-2-(trifluormethyl)-1H-benzimidazol-4-yl]-1-methyl-6-(trifluormethyl)pyrimidin-2,4(1H,3H)-dion, fenoxasulfone, fenpyrazone, fluchloralin, flurenol, flurenol-butyl, -dimethylammonium und -methyl, flupropanate, flupropanate-sdium, fosamine, fosamine-ammonium, H-9201, i.e. O-(2,4-Dimethyl-6- nitrophenyl)-O-ethyl-isopropylphosphoramidothioat, halosulfuron, HW-02, i.e.1- (Dimethoxyphosphoryl)-ethyl-(2,4-dichlorphenoxy)acetat, karbutilate, KUH-043, i.e.3-({[5- (Difluormethyl)-1-methyl-3-(trifluormethyl)-1H-pyrazol-4-yl]methyl}sulfonyl)-5,5-dimethyl-4,5- dihydro-1,2-oxazol, ketospiradox, ketospiradox-potassium, mefluidide, mefluidide-diolamine, mefluidide-potassium, methabenzthiazuron, metam, methiopyrsulfuron, methiozolin, methyl isothiocyanate, molinate, monosulfuron, monosulfuron-methyl, MT-5950, i.e. N-[3-chlor-4-(1- methylethyl)-phenyl]-2-methylpentanamid, NGGC-011, napropamide, NC-310, i.e.4-(2,4- Dichlorbenzoyl)-1-methyl-5-benzyloxypyrazol, orbencarb, pebulate, pentachlorphenol, petroleum oils, primisulfuron, prodiamine, pyribambenz, pyribambenz-isopropyl, pyribambenz-propyl, pyributicarb, quinoclamine, SL-261, SYP-249, i.e.1-Ethoxy-3-methyl-1-oxobut-3-en-2-yl-5-[2-chlor-4- (trifluormethyl)phenoxy]-2-nitrobenzoat, SYP-300, i.e.1-[7-Fluor-3-oxo-4-(prop-2-in-1-yl)-3,4-
dihydro-2H-1,4-benzoxazin-6-yl]-3-propyl-2-thioxoimidazolidin-4,5-dion, TCA (Trifluoressigsäure), TCA-ammonium, TCA-calcium, TCA-ethdyl, TCA-magnesium, TCA-sodium, terbucarb, thiobencarb, tolpyralate, urea sulfate, vernolate, XDE-848, ZJ-0862, i.e.3,4-Dichlor-N-{2-[(4,6-dimethoxypyrimidin- 2-yl)oxy]benzyl}anilin, 3-(2-chloro-4-fluoro-5-(3-methyl-2,6-dioxo-4-trifluoromethyl-3,6- dihydropyrimidin-1 (2H)-yl)phenyl)-5-methyl-4,5-dihydroisoxazole-5-carboxylic acid ethyl ester, 3- chloro-2-[3-(difluoromethyl)isoxazolyl-5-yl]phenyl-5-chloropyrimidin-2-yl ether, 2-(3,4- dimethoxyphenyl)-4-[(2-hydroxy-6-oxocyclohex-1-en-1-yl)carbonyl]-6-methylpyridazin-3(2H)-one, 2- ({2-[(2-methoxyethoxy)methyl]-6-methylpyridin-3-yl}carbonyl)cyclohexane-1,3-dione, (5-hydroxy-1- methyl-1H-pyrazol-4-yl)(3,3,4-trimethyl-1,1-dioxido-2,3-dihydro-1-benzothiophen-5-yl)methanone, 1- methyl-4-[(3,3,4-trimethyl-1,1-dioxido-2,3-dihydro-1-benzothiophen-5-yl)carbonyl]-1H-pyrazol-5-yl propane-1-sulfonate, 1-{2-chloro-3-[(3-cyclopropyl-5-hydroxy-1-methyl-1H-pyrazol-4-yl)carbonyl]-6- (trifluoromethyl)phenyl}piperidin-2-one, 4-{2-chloro-3-[(3,5-dimethyl-1H-pyrazol-1-yl)methyl]-4- (methylsulfonyl)benzoyl}-1-methyl-1H-pyrazol-5-yl 1,3-dimethyl-1H-pyrazole-4-carboxylate; cyanomethyl 4-amino-3-chloro-5-fluoro-6-(7-fluoro-1H-indol-6-yl)pyridine-2-carboxylate, prop-2-yn-1- yl 4-amino-3-chloro-5-fluoro-6-(7-fluoro-1H-indol-6-yl)pyridine-2-carboxylate, methyl 4-amino-3- chloro-5-fluoro-6-(7-fluoro-1H-indol-6-yl)pyridine-2-carboxylate, benzyl 4-amino-3-chloro-5-fluoro-6- (7-fluoro-1H-indol-6-yl)pyridine-2-carboxylate, ethyl 4-amino-3-chloro-5-fluoro-6-(7-fluoro-1H-indol- 6-yl)pyridine-2-carboxylate, methyl 4-amino-3-chloro-5-fluoro-6-(7-fluoro-1-isobutyryl-1H-indol-6- yl)pyridine-2-carboxylate, methyl 6-(1-acetyl-7-fluoro-1H-indol-6-yl)-4-amino-3-chloro-5- fluoropyridine-2-carboxylate, methyl 4-amino-3-chloro-6-[1-(2,2-dimethylpropanoyl)-7-fluoro-1H- indol-6-yl]-5-fluoropyridine-2-carboxylate, methyl 4-amino-3-chloro-5-fluoro-6-[7-fluoro-1- (methoxyacetyl)-1H-indol-6-yl]pyridine-2-carboxylate, potassium 4-amino-3-chloro-5-fluoro-6-(7- fluoro-1H-indol-6-yl)pyridine-2-carboxylate, sodium 4-amino-3-chloro-5-fluoro-6-(7-fluoro-1H-indol- 6-yl)pyridine-2-carboxylate, butyl 4-amino-3-chloro-5-fluoro-6-(7-fluoro-1H-indol-6-yl)pyridine-2- carboxylate, 4-hydroxy-1-methyl-3-[4-(trifluoromethyl)pyridin-2-yl]imidazolidin-2-one, 3-(5-tert-butyl- 1,2-oxazol-3-yl)-4-hydroxy-1-methylimidazolidin-2-one Wenn die jeweilige Bezeichnung (common name) mehrere Formen des Wirkstoffes umfasst, ist mit der Bezeichnung die kommerziell erhältliche Form bevorzugt definiert. Jeder der genannten weiteren Wirkstoffe (= Wirkstoffe (C*), (C1*), (C2*) etc.) kann dann vorzugsweise mit einer der Zweierkombinationen gemäß der vorliegenden Erfindung, nach dem Schema (A)+(B)+(C*) oder auch nach dem Schema (A)+(B)+(C1*)+(C2*) etc. kombiniert werden. Die Mengenangaben sind Aufwandmengen (g a.i./ha = Gramm Aktivsubstanz pro Hektar) und definieren somit auch die Mengenverhältnisse in einer Koformulierung, einem Pre-mix, einem Tank- mix oder einer sequenziellen Applikation der kombinierten Wirkstoffe.
Die Kombinationen können sowohl im Vorauflaufverfahren als auch Nachauflaufverfahren angewendet werden. Dies gilt sowohl für Vor- und Nachauflauf in Bezug auf die Schadpflanzen also auch bei der selektiven Bekämpfung der Schadpflanzen für den Vor- oder Nachauflauf der Kulturpflanzen. Es kommen dabei auch Mischformen in Frage, z. B. beim Nachauflauf der Kulturpflanzen die Bekämpfung der Schadpflanzen in deren Vor- oder Nachauflaufstadium. Von besonderem Interesse ist die selektive Bekämpfung von Schadpflanzen in Kulturen von Nutz- und Zierpflanzen. Obgleich die Herbizide (A) und (B), bereits in vielen Kulturen sehr gute bis ausreichende Selektivität aufweisen, können prinzipiell in einigen Kulturen und vor allem auch im Falle von Mischungen mit anderen Herbiziden, die weniger selektiv sind, Phytotoxizitäten an den Kulturpflanzen auftreten. Diesbezüglich sind Kombinationen von Herbiziden (A) und (B) von besonderem Interesse, welche die erfindungsgemäß kombinierten herbiziden Wirkstoffe und einen oder mehrere Safener enthalten. Die Safener, welche in einem antidotisch wirksamen Gehalt eingesetzt werden, reduzieren die phytotoxischen Nebenwirkungen der eingesetzten Herbizide/Pestizide, z. B. in wirtschaftlich bedeutenden Kulturen wie Getreide (Weizen, Gerste, Roggen, Mais, Reis, Hirse), Zuckerrübe, Zuckerrohr, Raps, Baumwolle und Soja, vorzugsweise Getreide. Als Kombinationspartner für die erfindungsgemäßen Herbizidkombiantionen kommen beispielsweise die folgenden Safener in Frage: S1) Verbindungen aus der Gruppe heterocyclischer Carbonsäurederivate: S1a) Verbindungen vom Typ der Dichlorphenylpyrazolin-3-carbonsäure (S1a), vorzugsweise Verbindungen wie 1-(2,4-Dichlorphenyl)-5-(ethoxycarbonyl)-5-methyl-2-pyrazolin-3-carbonsäure, 1-(2,4-Dichlorphenyl)-5-(ethoxycarbonyl)-5-methyl-2-pyrazolin-3-carbonsäureethylester (S1-1) ("Mefenpyr-diethyl"), und verwandte Verbindungen, wie sie in der WO-A-91/07874 beschrieben sind; S1b) Derivate der Dichlorphenylpyrazolcarbonsäure (S1b), vorzugsweise Verbindungen wie 1-(2,4-Dichlorphenyl)-5-methylpyrazol-3-carbonsäureethylester (S1-2), 1-(2,4-Dichlorphenyl)-5-isopropylpyrazol-3-carbonsäureethylester (S1-3), 1-(2,4-Dichlorphenyl)-5-(1,1-dimethyl-ethyl)pyrazol-3-carbonsäureethylester (S1-4) und verwandte Verbindungen, wie sie in EP-A-333131 und EP-A-269806 beschrieben sind; S1c) Derivate der 1,5-Diphenylpyrazol-3-carbonsäure (S1c), vorzugsweise Verbindungen wie 1-(2,4-Dichlorphenyl)-5-phenylpyrazol-3-carbonsäureethylester (S1-5),
1-(2-Chlorphenyl)-5-phenylpyrazol-3-carbonsäuremethylester (S1-6) und verwandte Verbindungen wie sie beispielsweise in der EP-A-268554 beschrieben sind; S1d) Verbindungen vom Typ der Triazolcarbonsäuren (S1d), vorzugsweise Verbindungen wie Fenchlorazol(-ethylester), d.h.1-(2,4-Dichlorphenyl)-5-trichlormethyl-(1H)-1,2,4-triazol-3- carbonsäureethylester (S1-7), und verwandte Verbindungen, wie sie in EP-A-174562 und EP-A-346620 beschrieben sind; S1e) Verbindungen vom Typ der 5-Benzyl- oder 5-Phenyl-2-isoxazolin-3- carbonsäure, oder der 5,5- Diphenyl-2-isoxazolin-3-carbonsäure(S1e), vorzugsweise Verbindungen wie 5-(2,4-Dichlorbenzyl)-2-isoxazolin-3-carbonsäureethylester (S1-8) oder 5-Phenyl-2-isoxazolin-3-carbonsäureethylester (S1-9) und verwandte Verbindungen, wie sie in WO-A-91/08202 beschrieben sind, bzw.5,5-Diphenyl-2-isoxazolin-carbonsäure (S1-10) oder 5,5-Diphenyl-2-isoxazolin-3-carbonsäureethylester (S1-11) ("Isoxadifen-ethyl") oder -n-propylester (S1-12) oder 5-(4-Fluorphenyl)-5-phenyl-2-isoxazolin-3-carbonsäureethylester (S1-13), wie sie in der Patentanmeldung WO-A-95/07897 beschrieben sind. S2) Verbindungen aus der Gruppe der 8-Chinolinoxyderivate (S2): S2a) Verbindungen vom Typ der 8-Chinolinoxyessigsäure (S2a), vorzugsweise (5-Chlor-8-chinolinoxy)essigsäure-(1-methylhexyl)-ester ("Cloquintocet-mexyl") (S2-1), (5-Chlor-8-chinolinoxy)essigsäure-(1,3-dimethyl-but-1-yl)-ester (S2-2), (5-Chlor-8-chinolinoxy)essigsäure-4-allyl-oxy-butylester (S2-3), (5-Chlor-8-chinolinoxy)essigsäure-1-allyloxy-prop-2-ylester (S2-4), (5-Chlor-8-chinolinoxy)essigsäureethylester (S2-5), (5-Chlor-8-chinolinoxy)essigsäuremethylester (S2-6), (5-Chlor-8-chinolinoxy)essigsäureallylester (S2-7), (5-Chlor-8-chinolinoxy)essigsäure-2-(2-propyliden-iminoxy)-1-ethylester (S2-8), (5-Chlor-8-chinolinoxy)essigsäure-2-oxo-prop-1-ylester (S2-9) und verwandte Verbindungen, wie sie in EP-A-86750, EP-A-94349 und EP-A-191736 oder EP-A-0492366 beschrieben sind, sowie (5-Chlor-8-chinolinoxy)essigsäure (S2-10), deren Hydrate und Salze, beispielsweise deren Lithium-, Natrium- Kalium-, Kalzium-, Magnesium-, Aluminium-, Eisen-, Ammonium-, quartäre Ammonium-, Sulfonium-, oder Phosphoniumsalze wie sie in der WO-A-2002/34048 beschrieben sind; S2b) Verbindungen vom Typ der (5-Chlor-8-chinolinoxy)malonsäure (S2b), vorzugsweise Verbindungen wie (5-Chlor-8-chinolinoxy)malonsäurediethylester, (5-Chlor-8-chinolinoxy)malonsäurediallylester,
(5-Chlor-8-chinolinoxy)malonsäure-methyl-ethylester und verwandte Verbindungen, wie sie in EP-A-0582198 beschrieben sind. S3) Wirkstoffe vom Typ der Dichloracetamide (S3), die häufig als Vorauflaufsafener (bodenwirksame Safener) angewendet werden, wie z. B. "Dichlormid" (N,N-Diallyl-2,2-dichloracetamid) (S3-1), "R-29148" (3-Dichloracetyl-2,2,5-trimethyl-1,3-oxazolidin) der Firma Stauffer (S3-2), "R-28725" (3-Dichloracetyl-2,2,-dimethyl-1,3-oxazolidin) der Firma Stauffer (S3-3), "Benoxacor" (4-Dichloracetyl-3,4-dihydro-3-methyl-2H-1,4-benzoxazin) (S3-4), "PPG-1292" (N-Allyl-N-[(1,3-dioxolan-2-yl)-methyl]-dichloracetamid) der Firma PPG Industries (S3-5), "DKA-24" (N-Allyl-N-[(allylaminocarbonyl)methyl]-dichloracetamid) der Firma Sagro-Chem (S3-6), "AD-67" oder "MON 4660" (3-Dichloracetyl-1-oxa-3-aza-spiro[4,5]decan) der Firma Nitrokemia bzw. Monsanto (S3-7), "TI-35" (1-Dichloracetyl-azepan) der Firma TRI-Chemical RT (S3-8), "Diclonon" (Dicyclonon) oder "BAS145138" oder "LAB145138" (S3-9) ((RS)-1-Dichloracetyl-3,3,8a-trimethylperhydropyrrolo[1,2-a]pyrimidin-6-on) der Firma BASF, "Furilazol" oder "MON 13900" ((RS)-3-Dichloracetyl-5-(2-furyl)-2,2-dimethyloxazolidin) (S3-10), sowie dessen (R)-Isomer (S3-11). S4) Verbindungen aus der Klasse der Acylsulfonamide (S4): S4a) N-Acylsulfonamide der Formel (S4a) und deren Salze wie sie in der WO-A-97/45016 beschrieben sind,
worin RA 1 (C1-C6)Alkyl, (C3-C6)Cycloalkyl, wobei die 2 letztgenannten Reste durch vA Substituenten aus der Gruppe Halogen, (C1-C4)Alkoxy, (C1-C6)Haloalkoxy und (C1- C4)Alkylthio und im Falle cyclischer Reste auch durch (C1-C4)Alkyl und (C1-C4)Haloalkyl substituiert sind; RA 2 Halogen, (C1-C4)Alkyl, (C1-C4)Alkoxy, CF3;
mA 1 oder 2; vA ist 0, 1, 2 oder 3 bedeuten; S4b) Verbindungen vom Typ der 4-(Benzoylsulfamoyl)benzamide der Formel (S4b) und deren Salze, wie sie in der WO-A-99/16744 beschrieben sind,
worin RB 1, RB 2 unabhängig voneinander Wasserstoff, (C1-C6)Alkyl, (C3-C6)Cycloalkyl, (C3- C6)Alkenyl, (C3-C6)Alkinyl, RB 3 Halogen, (C1-C4)Alkyl, (C1-C4)Haloalkyl oder (C1-C4)Alkoxy und mB 1 oder 2 bedeuten, z.B. solche worin RB 1 = Cyclopropyl, RB 2 = Wasserstoff und (RB 3) = 2-OMe ist ("Cyprosulfamide", S4-1), RB 1 = Cyclopropyl, RB 2 = Wasserstoff und (RB 3) = 5-Cl-2-OMe ist (S4-2), RB 1 = Ethyl, RB 2 = Wasserstoff und (RB 3) = 2-OMe ist (S4-3), RB 1 = Isopropyl, RB 2 = Wasserstoff und ( RB 3) = 5-Cl-2-OMe ist (S4-4) und RB 1 = Isopropyl, RB 2 = Wasserstoff und (RB 3) = 2-OMe ist (S4-5); S4c) Verbindungen aus der Klasse der Benzoylsulfamoylphenylharnstoffe der Formel (S4c), wie sie in der EP-A-365484 beschrieben sind,
worin RC 1, RC 2 unabhängig voneinander Wasserstoff, (C1-C8)Alkyl, (C3-C8)Cycloalkyl, (C3- C6)Alkenyl, (C3-C6)Alkinyl, RC3 Halogen, (C1-C4)Alkyl, (C1-C4)Alkoxy, CF3 und mC 1 oder 2 bedeuten; beispielsweise 1-[4-(N-2-Methoxybenzoylsulfamoyl)phenyl]-3-methylharnstoff, 1-[4-(N-2-Methoxybenzoylsulfamoyl)phenyl]-3,3-dimethylharnstoff, 1-[4-(N-4,5-Dimethylbenzoylsulfamoyl)phenyl]-3-methylharnstoff; S4d) Verbindungen vom Typ der N-Phenylsulfonylterephthalamide der Formel (S4d) und deren Salze, die z.B. bekannt sind aus CN 101838227,
worin RD 4 Halogen, (C1-C4)Alkyl, (C1-C4)Alkoxy, CF3; mD 1 oder 2; RD5 Wasserstoff, (C1-C6)Alkyl, (C3-C6)Cycloalkyl, (C2-C6)Alkenyl, (C2-C6)Alkinyl, (C5- C6)Cycloalkenyl bedeutet. S5) Wirkstoffe aus der Klasse der Hydroxyaromaten und der aromatisch-aliphatischen Carbonsäurederivate (S5), z.B. 3,4,5-Triacetoxybenzoesäureethylester, 3,5-Dimethoxy-4-hydroxybenzoesäure, 3,5- Dihydroxybenzoesäure, 4-Hydroxysalicylsäure, 4-Fluorsalicyclsäure, 2-Hydroxyzimtsäure, 2,4- Dichlorzimtsäure, wie sie in der WO-A-2004/084631, WO-A-2005/015994, WO-A- 2005/016001 beschrieben sind. S6) Wirkstoffe aus der Klasse der 1,2-Dihydrochinoxalin-2-one (S6), z.B. 1-Methyl-3-(2-thienyl)-1,2-dihydrochinoxalin-2-on, 1-Methyl-3-(2-thienyl)-1,2-dihydro-
chinoxalin-2-thion, 1-(2-Aminoethyl)-3-(2-thienyl)-1,2-dihydro-chinoxalin-2-on-hydrochlorid, 1-(2-Methylsulfonylaminoethyl)-3-(2-thienyl)-1,2-dihydro-chinoxalin-2-on, wie sie in der WO- A-2005/112630 beschrieben sind. S7) Verbindungen aus der Klasse der Diphenylmethoxyessigsäurederivate (S7), z.B. Diphenylmethoxyessigsäuremethylester (CAS-Reg.Nr.41858-19-9) (S7-1), Diphenylmethoxyessigsäureethylester oder Diphenylmethoxyessigsäure wie sie in der WO-A- 98/38856 beschrieben sind. S8) Verbindungen der Formel (S8), wie sie in der WO-A-98/27049 beschrieben sind,
worin die Symbole und Indizes folgende Bedeutungen haben: RD1 ist Halogen, (C1-C4)Alkyl, (C1-C4)Haloalkyl, (C1-C4)Alkoxy, (C1-C4)Haloalkoxy, RD2 ist Wasserstoff oder (C1-C4)Alkyl, RD3 ist Wasserstoff, (C1-C8)Alkyl, (C2-C4)Alkenyl, (C2-C4)Alkinyl, oder Aryl, wobei jeder der vorgenannten C-haltigen Reste unsubstituiert oder durch einen oder mehrere, vorzugsweise bis zu drei gleiche oder verschiedene Reste aus der Gruppe, bestehend aus Halogen und Alkoxy substituiert ist; oder deren Salze, nD ist eine ganze Zahl von 0 bis 2. S9) Wirkstoffe aus der Klasse der 3-(5-Tetrazolylcarbonyl)-2-chinolone (S9), z.B. 1,2-Dihydro-4-hydroxy-1-ethyl-3-(5-tetrazolylcarbonyl)-2-chinolon (CAS-Reg.Nr.: 219479-18- 2), 1,2-Dihydro-4-hydroxy-1-methyl-3-(5-tetrazolyl-carbonyl)-2-chinolon (CAS-Reg.Nr. 95855-00-8), wie sie in der WO-A-1999/000020 beschrieben sind. S10) Verbindungen der Formeln (S10a) oder (S10b), wie sie in der WO-A-2007/023719 und WO-A-2007/023764 beschrieben sind,
Table 2.2: Particularly preferred binary compositions containing (A2) Table 2.3: Particularly preferred binary compositions containing (A3) Table 2.4: Particularly preferred binary compositions containing (A4) Furthermore, the combinations according to the invention can be used together with other active ingredients such as the active ingredients mentioned (herbicides, fungicides, insecticides, acaricides, etc.) and/or plant growth regulators or auxiliaries from the group of additives customary in crop protection, such as adjuvants and formulation auxiliaries. The combination of Active substances in plant protection products which contain the active substances (A) and (B) and optionally other active substances are referred to here for short as a “herbicide combination”. Their application forms such as formulations or tank mixes are herbicidal agents (compositions). The invention therefore also relates to the herbicidal agents which contain the active compound combinations according to the invention with additives customary in crop protection, such as adjuvants and formulation auxiliaries, and optionally other active crop protection agents. The invention also relates to the use of or the application process using the active compound combinations according to the invention as herbicides and plant growth regulators, preferably as herbicides and plant growth regulators with a synergistically active content of the active compound combination present in each case. The application rates of the herbicides (B) are known in principle and are generally in the range from 0.01 to 4000 g ai/ha, preferably in the range from 0.02 to 3000 g ai/ha, in particular 0.1 to 2500 g hey/ha. For the active ingredient pelargonic acid (B5.38) from group (B5), the application rate is in the range from 1 to 100,000 g ai/ha. In the mixtures according to the invention, in the context of the application rates mentioned, lower application rates of the respective active ingredient are generally required in comparison to individual application. For the active compounds from group (B1), the application rate is preferably in the range from 1 to 250 g ai/ha, in particular in the range from 1 to 150 g/ha, and most preferably in the range from 5 to 100 g ai/ha. For the active ingredients from group (B2), the application rate is preferably in the range from 0.1 to 3000 g ai/ha, in particular in the range from 0.1 to 2700 g ai/ha, and most preferably in the range from 1 to 2200 g ai/ha. For the active compound from group (B3), the application rate is preferably in the range from 10 to 1000 g ai/ha, in particular in the range from 10 to 500 g ai/ha, and most preferably in the range from 10 to 300 g ai/ha . For the active compound from group (B4), the application rate is preferably in the range from 1 to 1500 g ai/ha, in particular in the range from 1 to 1200 g ai/ha, and most preferably in the range from 1 to 1000 g ai/ha . For the active ingredient from group (B5), with the exception of pelargonic acid (B5.38), the application rate is preferably in the range from 1 to 1500 g ai/ha, in particular in the range from 1 to 1000 g ai/ha, and most preferably im Range from 1 to 600 g ai/ha. For pelargonic acid (B.5.38) the application rate is preferably 1 to 100,000 g ai/ha, more preferably 1 to 40,000 g ai/ha and especially in the range of 1 to 30,000 g ai/ha. For the active ingredient from group (B6), the application rate is preferably in the range from 1 to 1000 g ai/ha, in particular in the range from 1 to 800 g ai/ha, and most preferably in the range from 5 to 600 g ai/ha . For the active ingredient from group (B7), the application rate is preferably in the range from 20 to 3000 g ai/ha, in particular in the range from 20 to 2000 g ai/ha, and most preferably in the range from 30 to 1300 g ai/ha . For the active compound from group (B8), the application rate is preferably in the range from 1 to 1500 g ai/ha, in particular in the range from 1 to 1000 g ai/ha and most preferably in the range from 1 to 800 g ai/ha. For the active ingredient from group (B9), the application rate is preferably in the range from 0.1 to 500 g ai/ha, in particular in the range from 0.1 to 250 g ai/ha, and most preferably in the range of 0.2 up to 100 g ai/ha. For the active ingredient from group (B10), the application rate is preferably in the range from 20 to 2500 g ai/ha, in particular in the range from 20 to 2000 g ai/ha, and most preferably in the range from 20 to 1500 g ai/ha . For the active compound from group (B11), the application rate is preferably in the range from 5 to 2000 g ai/ha, in particular in the range from 5 to 1500 g ai/ha, and most preferably in the range from 5 to 1000 g ai/ha . The weight ratios (A):(B) are generally in the range from 1:100,000 to 3000:1, preferably from 1:80,000 to 2000:1, in particular in the range from 1:15,000, depending on the effective application rates up to 1000:1. For the active ingredients from groups (B1) to (B11), the preferred weight ratios (A):(B) are as follows: (A):(B1) preferably in the range from 150:1 to 1:2500, in particular 24:1 up to 1:400; (A):(B2) preferably in the range from 1500:1 to 1:45000, in particular from 120:1 to 1:9000; (A):(B3) preferably in the range from 15:1 to 1:8500, especially from 12:1 to 1:1200; (A):(B4) preferably in the range from 150:1 to 1:20000, in particular from 120:1 to 1:4000; (A):(B5) preferably in the range from 150:1 to 1:17000, in particular from 120:1 to 1:2400; (A):(B6) preferably in the range from 150:1 to 1:13500, in particular from 24:1 to 1:2400; (A):(B7) preferably in the range from 7:1 to 1:13500, in particular from 4:1 to 1:5200; (A):(B8) preferably in the range from 150:1 to 1:17000, in particular from 120:1 to 1:3200; (A):(B9) preferably in the range from 1500:1 to 1:4200, in particular from 600:1 to 1:400; (A):(B10) preferably in the range from 7:1 to 1:34000, in particular from 6:1 to 1:6000; (A):(B11) preferably in the range from 1500:1 to 1:4500, in particular from 600:1 to 1:400. The herbicidal compositions according to the invention can also be combined with other herbicides and plant growth regulators (= active ingredients (C*), for example to supplement the spectrum of activity. Combination partners for the compounds according to the invention in mixture formulations or in tank mixes are, for example, known active ingredients that are based on inhibition based on, for example, acetolactate synthase, acetyl-CoA carboxylase, cellulose synthase, enolpyruvylshikimate-3-phosphate synthase, glutamine synthetase, p-hydroxyphenylpyruvate dioxygenase, phytoene desaturase, photosystem I, photosystem II, protoporphyrinogen oxidase, can be used, such as they, for example, from Weed Research 26 (1986) 441-445 or "The Pesticide Manual", 14th edition, The British Crop Protection Council and the Royal Soc. of Chemistry, 2006, the corresponding "e-Pesticide Manual Version 4 (2006)" and the literature cited there are known. Other trade names and "common names" are listed in the "Compendium of Pesticide Common Names" (available on the Internet at http://www.alanwood.net/pesticides). Known herbicides which can be combined with the compounds according to the invention are, for example, the following active ingredients (note: the compounds are either identified by the "common name" according to the International Organization for Standardization (ISO) or by the chemical name, possibly together designated with a common code number) and always include all application forms such as acids, salts, esters and isomers such as stereoisomers and optical isomers. One and sometimes several application forms are mentioned: acifluorfen, allidochlor, amidochlor, 4-amino-3-chloro-6-(4-chloro-2-fluoro-3-methylphenyl)-5-fluoropyridine-2-carboxylic acid, ammonium sulfamate, benfuresate, bensulide, bipyrazone, bromobutide, busoxinone, butenachlor, butylate, cambendichlor, chlorfenac, chlrfenac-ammonium, chlorfenac-sodium, chlorfenprop, chlrofenprop-methyl, chlorflurenol, chlorflurenol-methyl, chlorophthalim, clacyfos, cumyluron, cyanamide, cycloate, cyprazine, dalapon, dalapon-calcium, dalapon-magnesium, dalapon-sodium, dazomet, dazomet-sodium, n-decanol, detosyl-pyrazolate (DTP), 2-(2,4-dichlorobenzyl)-4,4-dimethyl-1 ,2-oxazolidin-3-one, 2-(2,5-dichlorobenzyl)-4,4-dimethyl-1,2-oxazolidin-3-one, dichlorprop, dichlorprop-butotyl, dichroprop-dimethylammonium, dichlorprop-etexyl, dichlorprop -ethylammonium, dichlorprop-isoctyl, dichlorprop-methyl, dichlorprop-postassium, dichlorprop-sodium, dichlorprop-P, dichlorprop-P-dimethylammonium, dichlor prop-P-etexyl, dichlorprop-P-potassium, dichlorprop-sodium, difenzoquat, difenzoquat-metilsulfate, dimepiperate, dimesulfazet, dimetrasulfuron, dinoterb, dinoterb-acetate, diphenamid, DNOC, DNOC-ammonium, DNOC-potassium, DNOC-sodium, endothal, endothal-diammonium, endothal-dipotassium, endothaldisodium, epyrifenacil, EPTC, ethiozine, etobenzanid, F-5231, ie N-[2-chloro-4-fluoro-5-[4-(3-fluoropropyl)-4 ,5-dihydro-5-oxo-1H-tetrazol-1-yl]-phenyl]-ethanesulfonamide, F-7967, ie3-[7-chloro-5-fluoro-2-(trifluoromethyl)-1H-benzimidazole-4- yl]-1-methyl-6-(trifluoromethyl)pyrimidine-2,4(1H,3H)-dione, fenoxasulfone, fenpyrazone, fluchloraline, flurenol, flurenol-butyl, -dimethylammonium and -methyl, flupropanate, flupropanate-sdium, fosamine , fosamine-ammonium, H-9201, ie O-(2,4-dimethyl-6-nitrophenyl)-O-ethyl-isopropylphosphoramidothioate, halosulfuron, HW-02, ie1-(Dimethoxyphosphoryl)-ethyl-(2,4-dichlorophenoxy )acetate, karbutilate, KUH-043, ie3-({[5-(Difluoromethyl)-1-methyl-3-(trifluoromethyl)-1H-pyrazol- 4-yl]methyl}sulfonyl)-5,5-dimethyl-4,5-dihydro-1,2-oxazole, ketospiradox, ketospiradox-potassium, mefluidide, mefluidide-diolamine, mefluidide-potassium, methabenzthiazuron, metam, methiopyrsulfuron, methiozoline , methyl isothiocyanate, molinate, monosulfuron, monosulfuron-methyl, MT-5950, ie N-[3-chloro-4-(1-methylethyl)-phenyl]-2-methylpentanamide, NGGC-011, napropamide, NC-310, ie4 -(2,4- Dichlorobenzoyl)-1-methyl-5-benzyloxypyrazole, orbencarb, pebulate, pentachlorophenol, petroleum oils, primisulfuron, prodiamine, pyribambenz, pyribambenz-isopropyl, pyribambenz-propyl, pyributicarb, quinoclamine, SL-261, SYP- 249, ie1-Ethoxy-3-methyl-1-oxobut-3-en-2-yl-5-[2-chloro-4-(trifluoromethyl)phenoxy]-2-nitrobenzoate, SYP-300, ie1-[7- Fluoro-3-oxo-4-(prop-2-yn-1-yl)-3,4- dihydro-2H-1,4-benzoxazin-6-yl]-3-propyl-2-thioxoimidazolidine-4,5-dione, TCA (trifluoroacetic acid), TCA-ammonium, TCA-calcium, TCA-ethdyl, TCA-magnesium, TCA-sodium, terbucarb, thiobencarb, tolpyralate, urea sulfate, vernolate, XDE-848, ZJ-0862, ie3,4-dichloro-N-{2-[(4,6-dimethoxypyrimidin-2-yl)oxy]benzyl} aniline, 3-(2-chloro-4-fluoro-5-(3-methyl-2,6-dioxo-4-trifluoromethyl-3,6-dihydropyrimidin-1(2H)-yl)phenyl)-5-methyl- 4,5-dihydroisoxazole-5-carboxylic acid ethyl ester, 3-chloro-2-[3-(difluoromethyl)isoxazolyl-5-yl]phenyl-5-chloropyrimidin-2-yl ether, 2-(3,4-dimethoxyphenyl )-4-[(2-hydroxy-6-oxocyclohex-1-en-1-yl)carbonyl]-6-methylpyridazin-3(2H)-one, 2-({2-[(2-methoxyethoxy)methyl] -6-methylpyridin-3-yl}carbonyl)cyclohexane-1,3-dione, (5-hydroxy-1-methyl-1H-pyrazol-4-yl)(3,3,4-trimethyl-1,1-dioxido -2,3-dihydro-1-benzothiophen-5-yl)methanone, 1-methyl-4-[(3,3,4-trimethyl-1,1-dioxido-2,3-dihydro-1-benzothiophene-5 -yl)carbonyl]-1H-pyrazol-5-ylpropane-1-sulfonate, 1-{2-chloro-3-[(3-cyc chloropropyl-5-hydroxy-1-methyl-1H-pyrazol-4-yl)carbonyl]-6-(trifluoromethyl)phenyl}piperidin-2-one, 4-{2-chloro-3-[(3,5-dimethyl -1H-pyrazol-1-yl)methyl]-4-(methylsulfonyl)benzoyl}-1-methyl-1H-pyrazol-5-yl 1,3-dimethyl-1H-pyrazole-4-carboxylates; cyanomethyl 4-amino-3-chloro-5-fluoro-6-(7-fluoro-1H-indol-6-yl)pyridine-2-carboxylate, prop-2-yn-1-yl 4-amino-3-chloro -5-fluoro-6-(7-fluoro-1H-indol-6-yl)pyridine-2-carboxylate, methyl 4-amino-3-chloro-5-fluoro-6-(7-fluoro-1H-indole- 6-yl)pyridine-2-carboxylate, benzyl 4-amino-3-chloro-5-fluoro-6-(7-fluoro-1H-indol-6-yl)pyridine-2-carboxylate, ethyl 4-amino-3 -chloro-5-fluoro-6-(7-fluoro-1H-indol- 6-yl)pyridine-2-carboxylate, methyl 4-amino-3-chloro-5-fluoro-6-(7-fluoro-1- isobutyryl-1H-indol-6-yl)pyridine-2-carboxylate, methyl 6-(1-acetyl-7-fluoro-1H-indol-6-yl)-4-amino-3-chloro-5-fluoropyridine-2 -carboxylate, methyl 4-amino-3-chloro-6-[1-(2,2-dimethylpropanoyl)-7-fluoro-1H-indol-6-yl]-5-fluoropyridine-2-carboxylate, methyl 4-amino -3-chloro-5-fluoro-6-[7-fluoro-1-(methoxyacetyl)-1H-indol-6-yl]pyridine-2-carboxylate, potassium 4-amino-3-chloro-5-fluoro-6 -(7-fluoro-1H-indol-6-yl)pyridine-2-carboxylate, sodium 4-amino-3-chloro-5-fluoro-6-(7-fluoro-1H-indol- 6-yl)pyridine- 2-carboxyla te,butyl 4-amino-3-chloro-5-fluoro-6-(7-fluoro-1H-indol-6-yl)pyridine-2-carboxylate, 4-hydroxy-1-methyl-3-[4-( trifluoromethyl)pyridin-2-yl]imidazolidin-2-one, 3-(5-tert-butyl-1,2-oxazol-3-yl)-4-hydroxy-1-methylimidazolidin-2-one If the respective designation ( common name) comprises several forms of the active ingredient, the commercially available form is preferably defined with the designation. Each of the other active ingredients mentioned (= active ingredients (C*), (C1*), (C2*), etc.) can then preferably be combined with one of the two-component combinations according to the present invention, according to the scheme (A)+(B)+(C *) or also according to the scheme (A)+(B)+(C1*)+(C2*) etc. The stated amounts are application rates (g ai/ha = grams of active ingredient per hectare) and thus also define the proportions in a co-formulation, a pre-mix, a tank mix or a sequential application of the combined active ingredients. The combinations can be used both pre-emergence and post-emergence. This applies both to pre- and post-emergence in relation to the harmful plants, ie also in the selective combating of the harmful plants for the pre- or post-emergence of the crop plants. Mixed forms are also possible, e.g. B. in the post-emergence of crops, the control of harmful plants in their pre- or post-emergence stage. Of particular interest is the selective control of harmful plants in crops of useful and ornamental plants. Although the herbicides (A) and (B) already have very good to sufficient selectivity in many crops, phytotoxicity can occur in the crop plants in principle in some crops and especially in the case of mixtures with other herbicides which are less selective. In this regard, combinations of herbicides (A) and (B) which contain the herbicidally active compounds combined according to the invention and one or more safeners are of particular interest. The safeners, which are used in an antidote-effective content, reduce the phytotoxic side effects of the herbicides/pesticides used, e.g. B. in economically important crops such as cereals (wheat, barley, rye, corn, rice, millet), sugar beet, sugar cane, rapeseed, cotton and soybeans, preferably cereals. Examples of possible combination partners for the herbicide combinations according to the invention are the following safeners: S1) Compounds from the group of heterocyclic carboxylic acid derivatives: S1a ) Compounds of the dichlorophenylpyrazoline-3-carboxylic acid ( S1a ) type, preferably compounds such as 1-(2,4- Dichlorophenyl)-5-(ethoxycarbonyl)-5-methyl-2-pyrazoline-3-carboxylic acid, ethyl 1-(2,4-dichlorophenyl)-5-(ethoxycarbonyl)-5-methyl-2-pyrazoline-3-carboxylate (S1 -1) ("Mefenpyr-diethyl"), and related compounds as described in WO-A-91/07874; S1b ) Derivatives of dichlorophenylpyrazolecarboxylic acid ( S1b ), preferably compounds such as ethyl 1-(2,4-dichlorophenyl)-5-methylpyrazole-3-carboxylate (S1-2), 1-(2,4-dichlorophenyl)-5-isopropylpyrazole Ethyl 3-carboxylate (S1-3), ethyl 1-(2,4-dichlorophenyl)-5-(1,1-dimethylethyl)pyrazole-3-carboxylate (S1-4) and related compounds as described in EP- A-333131 and EP-A-269806; S1c ) derivatives of 1,5-diphenylpyrazole-3-carboxylic acid ( S1c ), preferably compounds such as ethyl 1-(2,4-dichlorophenyl)-5-phenylpyrazole-3-carboxylate (S1-5), Methyl 1-(2-chlorophenyl)-5-phenylpyrazole-3-carboxylate (S1-6) and related compounds such as are described in EP-A-268554; S1 d ) Compounds of the triazole carboxylic acid type (S1 d ), preferably compounds such as fenchlorazole (ethyl ester), ie 1-(2,4-dichlorophenyl)-5-trichloromethyl-(1H)-1,2,4-triazole-3- ethyl carboxylate (S1-7), and related compounds as described in EP-A-174562 and EP-A-346620; S1 e ) Compounds of the 5-benzyl- or 5-phenyl-2-isoxazoline-3-carboxylic acid type, or 5,5-diphenyl-2-isoxazoline-3-carboxylic acid (S1 e ), preferably compounds such as 5-( 2,4-Dichlorobenzyl)-2-isoxazoline-3-carboxylic acid ethyl ester (S1-8) or 5-phenyl-2-isoxazoline-3-carboxylic acid ethyl ester (S1-9) and related compounds as described in WO-A-91/08202 are described, or 5,5-diphenyl-2-isoxazoline-carboxylic acid (S1-10) or 5,5-diphenyl-2-isoxazoline-3-carboxylic acid ethyl ester (S1-11) ("isoxadifen-ethyl") or -n -propyl ester (S1-12) or ethyl 5-(4-fluorophenyl)-5-phenyl-2-isoxazoline-3-carboxylate (S1-13) as described in patent application WO-A-95/07897. S2) Compounds from the group of 8-quinolinoxy derivatives (S2): S2 a ) Compounds of the 8-quinolinoxyacetic acid type (S2 a ), preferably (5-chloro-8-quinolinoxy)acetic acid (1-methylhexyl) ester ("Cloquintocet-mexyl") (S2-1), (5-Chloro-8-quinolinoxy)acetic acid (1,3-dimethylbut-1-yl) ester (S2-2), (5-Chloro-8- 4-allyloxy-butyl quinolinoxy)acetate (S2-3), 1-allyloxy-prop-2-yl (5-chloro-8-quinolinoxy)acetate (S2-4), (5-chloro-8- ethyl quinolinoxy)acetate (S2-5), methyl (5-chloro-8-quinolinoxy)acetate (S2-6), allyl (5-chloro-8-quinolinoxy)acetate (S2-7), (5-chloro-8-quinolinoxy) 2-(2-propylidene-iminoxy)-1-ethyl acetate (S2-8), 2-oxo-prop-1-yl (5-chloro-8-quinolinoxy)acetate (S2-9) and related compounds, as described in EP-A-86750, EP-A-94349 and EP-A-191736 or EP-A-0492366, and (5-chloro-8-quinolinoxy)acetic acid (S2-10), its hydrates and salts , For example, their lithium, sodium, potassium, calcium, magnesium, aluminum m-, iron, ammonium, quaternary ammonium, sulfonium or phosphonium salts as described in WO-A-2002/34048; S2 b ) Compounds of the (5-chloro-8-quinolinoxy)malonic acid (S2 b ) type, preferably compounds such as diethyl (5-chloro-8-quinolinoxy)malonate, diallyl (5-chloro-8-quinolinoxy)malonate, (5-Chloro-8-quinolinoxy)malonic acid methyl ethyl ester and related compounds as described in EP-A-0582198. S3) Active substances of the type of dichloroacetamide (S3), which are often used as pre-emergence safeners (soil-effective safeners), such as. B. "Dichlormide" (N,N-Diallyl-2,2-dichloroacetamide) (S3-1), "R-29148" (3-Dichloroacetyl-2,2,5-trimethyl-1,3-oxazolidine) from the company Stauffer (S3-2), "R-28725" (3-dichloroacetyl-2,2-dimethyl-1,3-oxazolidine) from Stauffer (S3-3), "Benoxacor" (4-dichloroacetyl-3,4 -dihydro-3-methyl-2H-1,4-benzoxazine) (S3-4), "PPG-1292" (N-allyl-N-[(1,3-dioxolan-2-yl)-methyl]-dichloroacetamide ) from PPG Industries (S3-5), "DKA-24" (N-allyl-N-[(allylaminocarbonyl)methyl]-dichloroacetamide) from Sagro-Chem (S3-6), "AD-67" or " MON 4660" (3-dichloroacetyl-1-oxa-3-aza-spiro[4,5]decane) from Nitrokemia or Monsanto (S3-7), "TI-35" (1-dichloroacetyl-azepan) from the company TRI-Chemical RT (S3-8), "Diclonon" (Dicyclonone) or "BAS145138" or "LAB145138" (S3-9) ((RS)-1-Dichloroacetyl-3,3,8a-trimethylperhydropyrrolo[1,2- a]pyrimidin-6-one) from BASF, "Furilazol" or "MON 13900" ((RS)-3-dichloroacetyl-5-(2-furyl)-2,2-dimethyloxazolidine) (S3-10), and its (R)-isomer (S3-11). S4) Compounds from the class of acylsulfonamides (S4): S4a ) N-acylsulfonamides of the formula ( S4a ) and salts thereof as described in WO-A-97/45016, in which R A 1 is (C 1 -C 6 )alkyl, (C 3 -C 6 )cycloalkyl, the last 2 radicals mentioned being replaced by v A substituents from the group consisting of halogen, (C 1 -C 4 )alkoxy, (C 1 -C 6 )haloalkoxy and (C 1 -C 4 )alkylthio and, in the case of cyclic radicals, also by (C 1 -C 4 )alkyl and (C 1 -C 4 )haloalkyl; R A 2 halo, (C 1 -C 4 )alkyl, (C 1 -C 4 )alkoxy, CF 3; mA 1 or 2; v A is 0, 1, 2 or 3; S4b ) compounds of the 4-(benzoylsulfamoyl)benzamide type of the formula ( S4b ) and their salts, as described in WO-A-99/16744, wherein R B 1 , R B 2 are independently hydrogen, (C 1 -C 6 )alkyl, (C 3 -C 6 )cycloalkyl, (C 3 -C 6 )alkenyl, (C 3 -C 6 )alkynyl, R B 3 halogen, (C 1 -C 4 )alkyl, (C 1 -C 4 )haloalkyl or (C 1 -C 4 )alkoxy and m B 1 or 2, for example those in which R B 1 = cyclopropyl, R B 2 = is hydrogen and (R B 3 ) = 2-OMe ("Cyprosulfamide", S4-1), R B 1 = cyclopropyl, R B 2 = hydrogen and (R B 3 ) = 5-Cl-2-OMe (S4 -2), R B 1 = ethyl, R B 2 = hydrogen and (R B 3 ) = 2-OMe is (S4-3), R B 1 = isopropyl, R B 2 = hydrogen and ( R B 3 ) = 5-Cl-2-OMe is (S4-4) and R B 1 = isopropyl, R B 2 = hydrogen and (R B 3 ) = 2-OMe (S4-5); S4 c ) compounds from the class of benzoylsulfamoylphenylureas of the formula (S4 c ), as described in EP-A-365484, wherein R C 1 , R C 2 are independently hydrogen, (C 1 -C 8 )alkyl, (C 3 -C 8 )cycloalkyl, (C 3 -C 6 )alkenyl, (C 3 -C 6 )alkynyl, RC 3 halogen, (C 1 -C 4 )alkyl, (C 1 -C 4 )alkoxy, CF 3 and mC 1 or 2; for example 1-[4-(N-2-methoxybenzoylsulfamoyl)phenyl]-3-methylurea, 1-[4-(N-2-methoxybenzoylsulfamoyl)phenyl]-3,3-dimethylurea, 1-[4-(N-4 ,5-dimethylbenzoylsulfamoyl)phenyl]-3-methylurea; S4 d ) compounds of the N-phenylsulfonylterephthalamide type of the formula (S4 d ) and their salts, which are known, for example, from CN 101838227, wherein R D 4 halogen, (C 1 -C 4 )alkyl, (C 1 -C 4 )alkoxy, CF 3; m D 1 or 2; RD 5 is hydrogen, (C 1 -C 6 )alkyl, (C 3 -C 6 )cycloalkyl, (C 2 -C 6 )alkenyl, (C 2 -C 6 )alkynyl, (C 5 -C 6 )cycloalkenyl. S5) Active ingredients from the class of hydroxyaromatics and aromatic-aliphatic carboxylic acid derivatives (S5), for example ethyl 3,4,5-triacetoxybenzoate, 3,5-dimethoxy-4-hydroxybenzoic acid, 3,5-dihydroxybenzoic acid, 4-hydroxysalicylic acid, 4-fluorosalicylic acid , 2-hydroxycinnamic acid, 2,4-dichlorocinnamic acid, as described in WO-A-2004/084631, WO-A-2005/015994, WO-A-2005/016001. S6) Active ingredients from the class of 1,2-dihydroquinoxalin-2-ones (S6), for example 1-methyl-3-(2-thienyl)-1,2-dihydroquinoxalin-2-one, 1-methyl-3-( 2-thienyl)-1,2-dihydro- quinoxaline-2-thione, 1-(2-aminoethyl)-3-(2-thienyl)-1,2-dihydro-quinoxalin-2-one hydrochloride, 1-(2-methylsulfonylaminoethyl)-3-(2-thienyl )-1,2-dihydroquinoxalin-2-one, as described in WO-A-2005/112630. S7) Compounds from the class of diphenylmethoxyacetic acid derivatives (S7), for example methyl diphenylmethoxyacetate (CAS Reg. No. 41858-19-9) (S7-1), ethyl diphenylmethoxyacetate or diphenylmethoxyacetic acid as described in WO-A-98/38856. S8) compounds of the formula (S8) as described in WO-A-98/27049, in which the symbols and indices have the following meanings: RD 1 is halogen, (C 1 -C 4 )alkyl, (C 1 -C 4 )haloalkyl, (C 1 -C 4 )alkoxy, (C 1 -C 4 )haloalkoxy, RD 2 is hydrogen or (C 1 -C 4 )alkyl, RD 3 is hydrogen, (C 1 -C 8 )alkyl, (C 2 -C 4 )alkenyl, (C 2 -C 4 )alkynyl, or aryl where each of the aforementioned C-containing radicals is unsubstituted or substituted by one or more, preferably up to three, identical or different radicals from the group consisting of halogen and alkoxy; or salts thereof, nD is an integer from 0 to 2. S9) active ingredients from the class of 3-(5-tetrazolylcarbonyl)-2-quinolones (S9), for example 1,2-dihydro-4-hydroxy-1-ethyl -3-(5-tetrazolylcarbonyl)-2-quinolone (CAS Reg. No.: 219479-18-2), 1,2-dihydro-4-hydroxy-1-methyl-3-(5-tetrazolyl-carbonyl) -2-quinolone (CAS Reg. No. 95855-00-8) as described in WO-A-1999/000020. S10) compounds of the formulas (S10 a ) or (S10 b ), as described in WO-A-2007/023719 and WO-A-2007/023764,
worin RE 1 Halogen, (C1-C4)Alkyl, Methoxy, Nitro, Cyano, CF3, OCF3 YE, ZE unabhängig voneinander O oder S, nE eine ganze Zahl von 0 bis 4, RE 2 (C1-C16)Alkyl, (C2-C6)Alkenyl, (C3-C6)Cycloalkyl, Aryl; Benzyl, Halogenbenzyl, RE 3 Wasserstoff oder (C1-C6)Alkyl bedeuten. S11) Wirkstoffe vom Typ der Oxyimino-Verbindungen (S11), die als Saatbeizmittel bekannt sind, wie z. B. "Oxabetrinil" ((Z)-1,3-Dioxolan-2-ylmethoxyimino(phenyl)acetonitril) (S11-1), das als Saatbeiz-Safener für Hirse gegen Schäden von Metolachlor bekannt ist, "Fluxofenim" (1-(4-Chlorphenyl)-2,2,2-trifluor-1-ethanon-O-(1,3-dioxolan-2-ylmethyl)-oxim) (S11-2), das als Saatbeiz-Safener für Hirse gegen Schäden von Metolachlor bekannt ist, und "Cyometrinil" oder "CGA-43089" ((Z)-Cyanomethoxyimino(phenyl)acetonitril) (S11-3), das als Saatbeiz-Safener für Hirse gegen Schäden von Metolachlor bekannt ist. S12) Wirkstoffe aus der Klasse der Isothiochromanone (S12), wie z.B. Methyl-[(3-oxo-1H-2- benzothiopyran-4(3H)-yliden)methoxy]acetat (CAS-Reg.Nr.205121-04-6) (S12-1) und verwandte Verbindungen aus WO-A-1998/13361. S13) Eine oder mehrere Verbindungen aus Gruppe (S13): "Naphthalic anhydrid" (1,8-Naphthalindicarbonsäureanhydrid) (S13-1), das als Saatbeiz-Safener für Mais gegen Schäden von Thiocarbamatherbiziden bekannt ist, "Fenclorim" (4,6-Dichlor-2-phenylpyrimidin) (S13-2), das als Safener für Pretilachlor in gesätem Reis bekannt ist,
"Flurazole" (Benzyl-2-chlor-4-trifluormethyl-1,3-thiazol-5-carboxylat) (S13-3), das als Saatbeiz-Safener für Hirse gegen Schäden von Alachlor und Metolachlor bekannt ist, "CL 304415" (CAS-Reg.Nr.31541-57-8) (4-Carboxy-3,4-dihydro-2H-1-benzopyran-4-essigsäure) (S13-4) der Firma American Cyanamid, das als Safener für Mais gegen Schäden von Imidazolinonen bekannt ist, "MG 191" (CAS-Reg.Nr.96420-72-3) (2-Dichlormethyl-2-methyl-1,3-dioxolan) (S13-5) der Firma Nitrokemia, das als Safener für Mais bekannt ist, "MG 838" (CAS-Reg.Nr.133993-74-5) (2-propenyl 1-oxa-4-azaspiro[4.5]decan-4-carbodithioat) (S13-6) der Firma Nitrokemia "Disulfoton" (O,O-Diethyl S-2-ethylthioethyl phosphordithioat) (S13-7), "Dietholate" (O,O-Diethyl-O-phenylphosphorothioat) (S13-8), "Mephenate" (4-Chlorphenyl-methylcarbamat) (S13-9). S14) Wirkstoffe, die neben einer herbiziden Wirkung gegen Schadpflanzen auch Safenerwirkung an Kulturpflanzen wie Reis aufweisen, wie z. B. "Dimepiperate" oder "MY-93" (S-1-Methyl-1-phenylethyl-piperidin-1-carbothioat), das als Safener für Reis gegen Schäden des Herbizids Molinate bekannt ist, "Daimuron" oder "SK 23" (1-(1-Methyl-1-phenylethyl)-3-p-tolyl-harnstoff), das als Safener für Reis gegen Schäden des Herbizids Imazosulfuron bekannt ist, "Cumyluron" = "JC-940" (3-(2-Chlorphenylmethyl)-1-(1-methyl-1-phenyl-ethyl)harnstoff, siehe JP-A-60087254), das als Safener für Reis gegen Schäden einiger Herbizide bekannt ist, "Methoxyphenon" oder "NK 049" (3,3'-Dimethyl-4-methoxy-benzophenon), das als Safener für Reis gegen Schäden einiger Herbizide bekannt ist, "CSB" (1-Brom-4-(chlormethylsulfonyl)benzol) von Kumiai, (CAS-Reg.Nr.54091-06-4), das als Safener gegen Schäden einiger Herbizide in Reis bekannt ist. S15) Verbindungen der Formel (S15) oder deren Tautomere,
wie sie in der WO-A-2008/131861 und WO-A-2008/131860 beschrieben sind, worin RH1 einen (C1-C6)Haloalkylrest bedeutet und RH 2 Wasserstoff oder Halogen bedeutet und RH 3, RH 4 unabhängig voneinander Wasserstoff, (C1-C16)Alkyl, (C2-C16)Alkenyl oder (C2-C16)Alkinyl, wobei jeder der letztgenannten 3 Reste unsubstituiert oder durch einen oder mehrere Reste aus der Gruppe Halogen, Hydroxy, Cyano, (C1-C4)Alkoxy, (C1-C4)Haloalkoxy, (C1-C4)Alkylthio, (C1-C4)Alkylamino, Di[(C1-C4)alkyl]-amino, [(C1-C4)Alkoxy]- carbonyl, [(C1-C4)Haloalkoxy]-carbonyl, (C3-C6)Cycloalkyl, das unsubstituiert oder substituiert ist, Phenyl, das unsubstituiert oder substituiert ist, und Heterocyclyl, das unsubstituiert oder substituiert ist, substituiert ist, oder (C3-C6)Cycloalkyl, (C4-C6)Cycloalkenyl, (C3-C6)Cycloalkyl, das an einer Seite des Rings mit einem 4 bis 6-gliedrigen gesättigten oder ungesättigten carbocyclischen Ring kondensiert ist, oder (C4-C6)Cycloalkenyl, das an einer Seite des Rings mit einem 4 bis 6-gliedrigen gesättigten oder ungesättigten carbocyclischen Ring kondensiert ist, wobei jeder der letztgenannten 4 Reste unsubstituiert oder durch einen oder mehrere Reste aus der Gruppe Halogen, Hydroxy, Cyano, (C1-C4)Alkyl, (C1-C4)Haloalkyl, (C1-C4)Alkoxy, (C1-C4)Haloalkoxy, (C1-C4)Alkylthio, (C1-C4)Alkylamino, Di[(C1- C4)alkyl]-amino, [(C1-C4)Alkoxy]-carbonyl, [(C1-C4)Haloalkoxy]-carbonyl, (C3-C6)Cycloalkyl, das unsubstituiert oder substituiert ist, Phenyl, das unsubstituiert oder substituiert ist, und Heterocyclyl, das unsubstituiert oder substituiert ist, substituiert ist,
bedeutet oder RH 3 (C1-C4)-Alkoxy, (C2-C4)Alkenyloxy, (C2-C6)Alkinyloxy oder (C2-C4)Haloalkoxy bedeutet und RH4 Wasserstoff oder (C1-C4)-Alkyl bedeutet oder RH3 und RH4 zusammen mit dem direkt gebundenen N-Atom einen vier- bis achtgliedrigen heterocyclischen Ring, der neben dem N-Atom auch weitere Heteroringatome, vorzugsweise bis zu zwei weitere Heteroringatome aus der Gruppe N, O und S enthalten kann und der unsubstituiert oder durch einen oder mehrere Reste aus der Gruppe Halogen, Cyano, Nitro, (C1- C4)Alkyl, (C1-C4)Haloalkyl, (C1-C4)Alkoxy, (C1-C4)Haloalkoxy und (C1-C4)Alkylthio substituiert ist, bedeutet. S16) Wirkstoffe, die vorrangig als Herbizide eingesetzt werden, jedoch auch Safenerwirkung auf Kulturpflanzen aufweisen, z. B. (2,4-Dichlorphenoxy)essigsäure (2,4-D), (4-Chlorphenoxy)essigsäure, (R,S)-2-(4-Chlor-o-tolyloxy)propionsäure (Mecoprop), 4-(2,4-Dichlorphenoxy)buttersäure (2,4-DB), (4-Chlor-o-tolyloxy)essigsäure (MCPA), 4-(4-Chlor-o-tolyloxy)buttersäure, 4-(4-Chlorphenoxy)buttersäure, 3,6-Dichlor-2-methoxybenzoesäure (Dicamba), 1-(Ethoxycarbonyl)ethyl-3,6-dichlor-2-methoxybenzoat (Lactidichlor-ethyl). Bevorzugte Safener in Kombination mit den erfindungsgemäßen Herbizidkombinationen sind: Cloquintocet-mexyl, Cyprosulfamid, Fenchlorazol-ethylester, Isoxadifen-ethyl, Mefenpyr-diethyl, Fenclorim, Cumyluron, S4-1 und S4-5, und besonders bevorzugte Safener sind: Cloquintocet-mexyl, Cyprosulfamid, Isoxadifen-ethyl und Mefenpyr-diethyl. Die erfindungsgemäßen Herbizidkombinationen können weitere Komponenten enthalten, z. B. Pflanzenwachstumsregulatoren oder andere Wirkstoffe gegen Schadorganismen wie Schadpflanzen, pflanzenschädliche Tiere oder pflanzenschädliche Pilze, insbesondere dabei Wirkstoffe aus der Gruppe Herbizide, Fungizide, Insektizide, Akarizide, Nematizide, Mitizide und verwandte Stoffe. Beispiele für Pflanzenwachstumsregulatoren als mögliche Mischungspartner sind: Acibenzolar, acibenzolar-S-methyl, 5-Aminolävulinsäure, ancymidol, 6-benzylaminopurine, Brassinolid, Catechin, chlormequat chloride, cloprop, cyclanilide, 3-(Cycloprop-1-enyl)propionsäure,
daminozide, dazomet, n-decanol, dikegulac, dikegulac-sodium, endothal, endothal-dipotassium, -disodium, und mono(N,N-dimethylalkylammonium), ethephon, flumetralin, flurenol, flurenol-butyl, flurprimidol, forchlorfenuron, gibberellic acid, inabenfide, indol-3-acetic acid (IAA), 4-indol-3-ylbutyric acid, isoprothiolane, probenazole, Jasmonsäure, Jasmonsäuremethylester, maleic hydrazide, mepiquat chloride, 1-methylcyclopropene, 2-(1-naphthyl)acetamide, 1-naphthylacetic acid, 2- naphthyloxyacetic acid, nitrophenolate-mixture, 4-Oxo-4[(2-phenylethyl)amino]buttersäure, paclobutrazol, N- phenylphthalamic acid, prohexadione, prohexadione-calcium, prohydrojasmone, Salicylsäure, Strigolacton, tecnazene, thidiazuron, triacontanol, trinexapac, trinexapac-ethyl, tsitodef, uniconazole, uniconazole-P. Fungizid wirksame Verbindungen, die in Kombination mit den erfindungsgemäßen Herbizidkombinationen eingesetzt werden können, sind bevorzugt handelsübliche Wirkstoffe, beispielsweise (analog zu den Herbiziden werden die Verbindungen generell mit ihren Common names bezeichnet, hier in der üblichen englischen Schreibweise): 1) Inhibitoren der Ergosterol-Biosynthese, beispielsweise (1.001) Cyproconazol, (1.002) Difenoconazol, (1.003) Epoxiconazol, (1.004) Fenhexamid, (1.005) Fenpropidin, (1.006) Fenpropimorph, (1.007) Fenpyrazamin, (1.008) Fluquinconazol, (1.009) Flutriafol, (1.010) Imazalil, (1.011) Imazalil Sulfat, (1.012) Ipconazol, (1.013) Metconazol, (1.014) Myclobutanil, (1.015) Paclobutrazol, (1.016) Prochloraz, (1.017) Propiconazol, (1.018) Prothioconazol, (1.019) Pyrisoxazol, (1.020) Spiroxamin, (1.021) Tebuconazol, (1.022) Tetraconazol, (1.023) Triadimenol, (1.024) Tridemorph, (1.025) Triticonazol, (1.026) (1R,2S,5S)-5-(4-Chlorbenzyl)-2-(chlormethyl)-2-methyl-1-(1H-1,2,4-triazol-1- ylmethyl)cyclopentanol, (1.027) (1S,2R,5R)-5-(4-Chlorbenzyl)-2-(chlormethyl)-2-methyl-1-(1H-1,2,4- triazol-1-ylmethyl)cyclopentanol, (1.028) (2R)-2-(1-Chlorcyclopropyl)-4-[(1R)-2,2-dichlorcyclopropyl]- 1-(1H-1,2,4-triazol-1-yl)butan-2-ol (1.029) (2R)-2-(1-Chlorcyclopropyl)-4-[(1S)-2,2- dichlorcyclopropyl]-1-(1H-1,2,4-triazol-1-yl)butan-2-ol, (1.030) (2R)-2-[4-(4-Chlorphenoxy)-2- (trifluormethyl)phenyl]-1-(1H-1,2,4-triazol-1-yl)propan-2-ol, (1.031) (2S)-2-(1-Chlorcyclopropyl)-4- [(1R)-2,2-dichlorcyclopropyl]-1-(1H-1,2,4-triazol-1-yl)butan-2-ol, (1.032) (2S)-2-(1-Chlorcyclopropyl)- 4-[(1S)-2,2-dichlorcyclopropyl]-1-(1H-1,2,4-triazol-1-yl)butan-2-ol, (1.033) (2S)-2-[4-(4- Chlorphenoxy)-2-(trifluormethyl)phenyl]-1-(1H-1,2,4-triazol-1-yl)propan-2-ol, (1.034) (R)-[3-(4-Chlor- 2-fluorphenyl)-5-(2,4-difluorphenyl)-1,2-oxazol-4-yl](pyridin-3-yl)methanol, (1.035) (S)-[3-(4-Chlor-2- fluorphenyl)-5-(2,4-difluorphenyl)-1,2-oxazol-4-yl](pyridin-3-yl)methanol, (1.036) [3-(4-Chlor-2- fluorphenyl)-5-(2,4-difluorphenyl)-1,2-oxazol-4-yl](pyridin-3-yl)methanol, (1.037) 1-({(2R,4S)-2-[2- Chlor-4-(4-chlorphenoxy)phenyl]-4-methyl-1,3-dioxolan-2-yl}methyl)-1H-1,2,4-triazol, (1.038) 1- ({(2S,4S)-2-[2-Chlor-4-(4-chlorphenoxy)phenyl]-4-methyl-1,3-dioxolan-2-yl}methyl)-1H-1,2,4-triazol, (1.039) 1-{[3-(2-Chlorphenyl)-2-(2,4-difluorphenyl)oxiran-2-yl]methyl}-1H-1,2,4-triazol-5-yl- thiocyanat, (1.040) 1-{[rel(2R,3R)-3-(2-Chlorphenyl)-2-(2,4-difluorphenyl)oxiran-2-yl]methyl}-1H- 1,2,4-triazol-5-yl-thiocyanat, (1.041) 1-{[rel(2R,3S)-3-(2-Chlorphenyl)-2-(2,4-difluorphenyl)oxiran-2-
yl]methyl}-1H-1,2,4-triazol-5-yl-thiocyanat, (1.042) 2-[(2R,4R,5R)-1-(2,4-Dichlorphenyl)-5-hydroxy- 2,6,6-trimethylheptan-4-yl]-2,4-dihydro-3H-1,2,4-triazol-3-thion, (1.043) 2-[(2R,4R,5S)-1-(2,4- Dichlorphenyl)-5-hydroxy-2,6,6-trimethylheptan-4-yl]-2,4-dihydro-3H-1,2,4-triazol-3-thion, (1.044) 2- [(2R,4S,5R)-1-(2,4-Dichlorophenyl)-5-hydroxy-2,6,6-trimethylheptan-4-yl]-2,4-dihydro-3H-1,2,4- triazol-3-thion, (1.045) 2-[(2R,4S,5S)-1-(2,4-Dichlorphenyl)-5-hydroxy-2,6,6-trimethylheptan-4-yl]-2,4- dihydro-3H-1,2,4-triazol-3-thion, (1.046) 2-[(2S,4R,5R)-1-(2,4-Dichlorphenyl)-5-hydroxy-2,6,6- trimethylheptan-4-yl]-2,4-dihydro-3H-1,2,4-triazol-3-thion, (1.047) 2-[(2S,4R,5S)-1-(2,4- Dichlorphenyl)-5-hydroxy-2,6,6-trimethylheptan-4-yl]-2,4-dihydro-3H-1,2,4-triazol-3-thion, (1.048) 2- [(2S,4S,5R)-1-(2,4-Dichlorphenyl)-5-hydroxy-2,6,6-trimethylheptan-4-yl]-2,4-dihydro-3H-1,2,4-triazol- 3-thion, (1.049) 2-[(2S,4S,5S)-1-(2,4-Dichlorphenyl)-5-hydroxy-2,6,6-trimethylheptan-4-yl]-2,4- dihydro-3H-1,2,4-triazol-3-thion, (1.050) 2-[1-(2,4-Dichlorphenyl)-5-hydroxy-2,6,6-trimethylheptan-4- yl]-2,4-dihydro-3H-1,2,4-triazol-3-thion, (1.051) 2-[2-Chlor-4-(2,4-dichlorophenoxy)phenyl]-1-(1H- 1,2,4-triazol-1-yl)propan-2-ol, (1.052) 2-[2-Chlor-4-(4-chlorphenoxy)phenyl]-1-(1H-1,2,4-triazol-1- yl)butan-2-ol, (1.053) 2-[4-(4-Chlorphenoxy)-2-(trifluormethyl)phenyl]-1-(1H-1,2,4-triazol-1-yl)butan- 2-ol, (1.054) 2-[4-(4-Chlorphenoxy)-2-(trifluormethyl)phenyl]-1-(1H-1,2,4-triazol-1-yl)pentan-2-ol, (1.055) 2-[4-(4-Chlorphenoxy)-2-(trifluormethyl)phenyl]-1-(1H-1,2,4-triazol-1-yl)propan-2-ol, (1.056) 2-{[3-(2-Chlorphenyl)-2-(2,4-difluorphenyl)oxiran-2-yl]methyl}-2,4-dihydro-3H-1,2,4-triazol-3-thion, (1.057) 2-{[rel(2R,3R)-3-(2-Chlorphenyl)-2-(2,4-difluorphenyl)oxiran-2-yl]methyl}-2,4-dihydro-3H- 1,2,4-triazol-3-thion, (1.058) 2-{[rel(2R,3S)-3-(2-Chlorphenyl)-2-(2,4-difluorphenyl)oxiran-2- yl]methyl}-2,4-dihydro-3H-1,2,4-triazol-3-thion, (1.059) 5-(4-Chlorbenzyl)-2-(chlormethyl)-2-methyl- 1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentanol, (1.060) 5-(Allylsulfanyl)-1-{[3-(2-chlorphenyl)-2-(2,4- difluorphenyl)oxiran-2-yl]methyl}-1H-1,2,4-triazol, (1.061) 5-(Allylsulfanyl)-1-{[rel(2R,3R)-3-(2- chlorphenyl)-2-(2,4-difluorphenyl)oxiran-2-yl]methyl}-1H-1,2,4-triazol, (1.062) 5-(Allylsulfanyl)-1- {[rel(2R,3S)-3-(2-chlorphenyl)-2-(2,4-difluorphenyl)oxiran-2-yl]methyl}-1H-1,2,4-triazol, (1.063) N'- (2,5-Dimethyl-4-{[3-(1,1,2,2-tetrafluorethoxy)phenyl]sulfanyl}phenyl)-N-ethyl-N- methylimidoformamid, (1.064) N'-(2,5-Dimethyl-4-{[3-(2,2,2-trifluorethoxy)phenyl]sulfanyl}phenyl)- N-ethyl-N-methylimidoformamid, (1.065) N'-(2,5-Dimethyl-4-{[3-(2,2,3,3- tetrafluorpropoxy)phenyl]sulfanyl}phenyl)-N-ethyl-N-methylimidoformamid, (1.066) N'-(2,5-Dimethyl- 4-{[3-(pentafluorethoxy)phenyl]sulfanyl}phenyl)-N-ethyl-N-methylimidoformamid, (1.067) N'-(2,5- Dimethyl-4-{3-[(1,1,2,2-tetrafluorethyl)sulfanyl]phenoxy}phenyl)-N-ethyl-N-methylimidoformamid, (1.068) N'-(2,5-Dimethyl-4-{3-[(2,2,2-trifluorethyl)sulfanyl]phenoxy}phenyl)-N-ethyl-N- methylimidoformamid, (1.069) N'-(2,5-Dimethyl-4-{3-[(2,2,3,3- tetrafluorpropyl)sulfanyl]phenoxy}phenyl)-N-ethyl-N-methylimidoformamid, (1.070) N'-(2,5-Dimethyl- 4-{3-[(pentafluorethyl)sulfanyl]phenoxy}phenyl)-N-ethyl-N-methylimidoformamid, (1.071) N'-(2,5- Dimethyl-4-phenoxyphenyl)-N-ethyl-N-methylimidoformamid, (1.072) N'-(4-{[3- (Difluormethoxy)phenyl]sulfanyl}-2,5-dimethylphenyl)-N-ethyl-N-methylimidoformamid, (1.073) N'- (4-{3-[(Difluormethyl)sulfanyl]phenoxy}-2,5-dimethylphenyl)-N-ethyl-N-methylimidoformamid,
(1.074) N'-[5-Brom-6-(2,3-dihydro-1H-inden-2-yloxy)-2-methylpyridin-3-yl]-N-ethyl-N- methylimidoformamid, (1.075) N'-{4-[(4,5-Dichlor-1,3-thiazol-2-yl)oxy]-2,5-dimethylphenyl}-N-ethyl- N-methylimidoformamid, (1.076) N'-{5-Brom-6-[(1R)-1-(3,5-difluorophenyl)ethoxy]-2-methylpyridin- 3-yl}-N-ethyl-N-methylimidoformamid, (1.077) N'-{5-Brom-6-[(1S)-1-(3,5-difluorphenyl)ethoxy]-2- methylpyridin-3-yl}-N-ethyl-N-methylimidoformamid, (1.078) N'-{5-Brom-6-[(cis-4- isopropylcyclohexyl)oxy]-2-methylpyridin-3-yl}-N-ethyl-N-methylimidoformamid, (1.079) N'-{5- Brom-6-[(trans-4-isopropylcyclohexyl)oxy]-2-methylpyridin-3-yl}-N-ethyl-N-methylimidoformamid, (1.080) N'-{5-Bromo-6-[1-(3,5-difluorphenyl)ethoxy]-2-methylpyridin-3-yl}-N-ethyl-N- methylimidoformamid, (1.081) Mefentrifluconazole, (1.082) Ipfentrifluconazole. 2) Inhibitoren der Atmungskette am Komplex I oder II beispielsweise (2.001) Benzovindiflupyr, (2.002) Bixafen, (2.003) Boscalid, (2.004) Carboxin, (2.005) Fluopyram, (2.006) Flutolanil, (2.007) Fluxapyroxad, (2.008) Furametpyr, (2.009) Isofetamid, (2.010) Isopyrazam (anti-epimeres Enantiomer 1R,4S,9S), (2.011) Isopyrazam (anti-epimeres Enantiomer 1S,4R,9R), (2.012) Isopyrazam (anti- epimeres Racemat 1RS,4SR,9SR), (2.013) Isopyrazam (Mischung des syn-epimeren Razemates 1RS,4SR,9RS und des anti-epimeren Razemates 1RS,4SR,9SR), (2.014) Isopyrazam (syn-epimeres Enantiomer 1R,4S,9R), (2.015) Isopyrazam (syn-epimeres Enantiomer 1S,4R,9S), (2.016) Isopyrazam (syn-epimeres Racemat 1RS,4SR,9RS), (2.017) Penflufen, (2.018) Penthiopyrad, (2.019) Pydiflumetofen, (2.020) Pyraziflumid, (2.021) Sedaxane, (2.022) 1,3-Dimethyl-N-(1,1,3-trimethyl-2,3- dihydro-1H-inden-4-yl)-1H-pyrazol-4-carboxamid, (2.023) 1,3-Dimethyl-N-[(3R)-1,1,3-trimethyl-2,3- dihydro-1H-inden-4-yl]-1H-pyrazol-4-carboxamid, (2.024) 1,3-Dimethyl-N-[(3S)-1,1,3-trimethyl-2,3- dihydro-1H-inden-4-yl]-1H-pyrazol-4-carboxamid, (2.025) 1-Methyl-3-(trifluormethyl)-N-[2'- (trifluormethyl)biphenyl-2-yl]-1H-pyrazol-4-carboxamid, (2.026) 2-Fluor-6-(trifluoromethyl)-N-(1,1,3- trimethyl-2,3-dihydro-1H-inden-4-yl)benzamid, (2.027) 3-(Difluormethyl)-1-methyl-N-(1,1,3-trimethyl- 2,3-dihydro-1H-inden-4-yl)-1H-pyrazol-4-carboxamid, (2.028) 3-(Difluormethyl)-1-methyl-N-[(3R)- 1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl]-1H-pyrazol-4-carboxamid, (2.029) 3-(Difluormethyl)-1- methyl-N-[(3S)-1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl]-1H-pyrazol-4-carboxamid, (2.030) 3- (Difluormethyl)-N-(7-fluor-1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl)-1-methyl-1H-pyrazol-4- carboxamid, (2.031) 3-(Difluormethyl)-N-[(3R)-7-fluor-1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl]-1- methyl-1H-pyrazol-4-carboxamid, (2.032) 3-(Difluoromethyl)-N-[(3S)-7-fluor-1,1,3-trimethyl-2,3- dihydro-1H-inden-4-yl]-1-methyl-1H-pyrazol-4-carboxamid, (2.033) 5,8-Difluor-N-[2-(2-fluor-4-{[4- (trifluormethyl)pyridin-2-yl]oxy}phenyl)ethyl]quinazolin-4-amin, (2.034) N-(2-Cyclopentyl-5- fluorbenzyl)-N-cyclopropyl-3-(difluormethyl)-5-fluor-1-methyl-1H-pyrazol-4-carboxamid, (2.035) N- (2-tert-Butyl-5-methylbenzyl)-N-cyclopropyl-3-(difluormethyl)-5-fluor-1-methyl-1H-pyrazol-4- carboxamid, (2.036) N-(2-tert-Butylbenzyl)-N-cyclopropyl-3-(difluormethyl)-5-fluor-1-methyl-1H- pyrazol-4-carboxamid, (2.037) N-(5-Chlor-2-ethylbenzyl)-N-cyclopropyl-3-(difluormethyl)-5-fluor-1- methyl-1H-pyrazol-4-carboxamid, (2.038) N-(5-Chlor-2-isopropylbenzyl)-N-cyclopropyl-3-
(difluormethyl)-5-fluor-1-methyl-1H-pyrazol-4-carboxamid, (2.039) N-[(1R,4S)-9-(Dichlormethylen)- 1,2,3,4-tetrahydro-1,4-methanonaphthalen-5-yl]-3-(difluormethyl)-1-methyl-1H-pyrazol-4-carboxamid, (2.040) N-[(1S,4R)-9-(Dichlormethylen)-1,2,3,4-tetrahydro-1,4-methanonaphthalen-5-yl]-3- (difluormethyl)-1-methyl-1H-pyrazol-4-carboxamid, (2.041) N-[1-(2,4-Dichlorphenyl)-1- methoxypropan-2-yl]-3-(difluormethyl)-1-methyl-1H-pyrazol-4-carboxamid, (2.042) N-[2-Chlor-6- (trifluormethyl)benzyl]-N-cyclopropyl-3-(difluormethyl)-5-fluor-1-methyl-1H-pyrazol-4-carboxamid, (2.043) N-[3-Chlor-2-fluor-6-(trifluormethyl)benzyl]-N-cyclopropyl-3-(difluormethyl)-5-fluor-1- methyl-1H-pyrazol-4-carboxamid, (2.044) N-[5-Chlor-2-(trifluormethyl)benzyl]-N-cyclopropyl-3- (difluormethyl)-5-fluor-1-methyl-1H-pyrazol-4-carboxamid, (2.045) N-Cyclopropyl-3-(difluormethyl)- 5-fluor-1-methyl-N-[5-methyl-2-(trifluormethyl)benzyl]-1H-pyrazol-4-carboxamid, (2.046) N- Cyclopropyl-3-(difluormethyl)-5-fluor-N-(2-fluor-6-isopropylbenzyl)-1-methyl-1H-pyrazol-4- carboxamid, (2.047) N-Cyclopropyl-3-(difluormethyl)-5-fluor-N-(2-isopropyl-5-methylbenzyl)-1- methyl-1H-pyrazol-4-carboxamid, (2.048) N-Cyclopropyl-3-(difluormethyl)-5-fluor-N-(2- isopropylbenzyl)-1-methyl-1H-pyrazol-4-carbothioamid, (2.049) N-Cyclopropyl-3-(difluoromethyl)-5- fluor-N-(2-isopropylbenzyl)-1-methyl-1H-pyrazol-4-carboxamid, (2.050) N-Cyclopropyl-3- (difluormethyl)-5-fluor-N-(5-fluor-2-isopropylbenzyl)-1-methyl-1H-pyrazol-4-carboxamid, (2.051) N- Cyclopropyl-3-(difluormethyl)-N-(2-ethyl-4,5-dimethylbenzyl)-5-fluor-1-methyl-1H-pyrazol-4- carboxamid, (2.052) N-Cyclopropyl-3-(difluormethyl)-N-(2-ethyl-5-fluorbenzyl)-5-fluor-1-methyl-1H- pyrazol-4-carboxamid, (2.053) N-Cyclopropyl-3-(difluormethyl)-N-(2-ethyl-5-methylbenzyl)-5-fluor-1- methyl-1H-pyrazole-4-carboxamid, (2.054) N-Cyclopropyl-N-(2-cyclopropyl-5-fluorbenzyl)-3- (difluormethyl)-5-fluor-1-methyl-1H-pyrazole-4-carboxamid, (2.055) N-Cyclopropyl-N-(2-cyclopropyl- 5-methylbenzyl)-3-(difluormethyl)-5-fluor-1-methyl-1H-pyrazole-4-carboxamid, (2.056) N- Cyclopropyl-N-(2-cyclopropylbenzyl)-3-(difluormethyl)-5-fluor-1-methyl-1H-pyrazole-4-carboxamid. 3) Inhibitoren der Atmungskette am Komplex III, beispielsweise (3.001) Ametoctradin, (3.002) Amisulbrom, (3.003) Azoxystrobin, (3.004) Coumethoxystrobin, (3.005) Coumoxystrobin, (3.006) Cyazofamid, (3.007) Dimoxystrobin, (3.008) Enoxastrobin, (3.009) Famoxadon, (3.010) Fenamidon, (3.011) Flufenoxystrobin, (3.012) Fluoxastrobin, (3.013) Kresoxim-Methyl, (3.014) Metominostrobin, (3.015) Orysastrobin, (3.016) Picoxystrobin, (3.017) Pyraclostrobin, (3.018) Pyrametostrobin, (3.019) Pyraoxystrobin, (3.020) Trifloxystrobin (3.021) (2E)-2-{2-[({[(1E)-1-(3-{[(E)-1-Fluor-2- phenylvinyl]oxy}phenyl)ethyliden]amino}oxy)methyl]phenyl}-2-(methoxyimino)-N-methylacetamid, (3.022) (2E,3Z)-5-{[1-(4-Chlorphenyl)-1H-pyrazol-3-yl]oxy}-2-(methoxyimino)-N,3-dimethylpent-3- enamid, (3.023) (2R)-2-{2-[(2,5-Dimethylphenoxy)methyl]phenyl}-2-methoxy-N-methylacetamid, (3.024) (2S)-2-{2-[(2,5-Dimethylphenoxy)methyl]phenyl}-2-methoxy-N-methylacetamid, (3.025) (3S,6S,7R,8R)-8-Benzyl-3-[({3-[(isobutyryloxy)methoxy]-4-methoxypyridin-2-yl}carbonyl)amino]-6- methyl-4,9-dioxo-1,5-dioxonan-7-yl-2-methylpropanoat, (3.026) 2-{2-[(2,5- Dimethylphenoxy)methyl]phenyl}-2-methoxy-N-methylacetamid, (3.027) N-(3-Ethyl-3,5,5-
trimethylcyclohexyl)-3-formamido-2-hydroxybenzamid, (3.028) (2E,3Z)-5-{[1-(4-Chlor-2-fluorphenyl)- 1H-pyrazol-3-yl]oxy}-2-(methoxyimino)-N,3-dimethylpent-3-enamid, (3.029) Methyl {5-[3-(2,4- dimethylphenyl)-1H-pyrazol-1-yl]-2-methylbenzyl}carbamate. 4) Inhibitoren der Mitose und Zellteilung, beispielsweise (4.001) Carbendazim, (4.002) Diethofencarb, (4.003) Ethaboxam, (4.004) Fluopicolid, (4.005) Pencycuron, (4.006) Thiabendazol, (4.007) Thiophanat-Methyl, (4.008) Zoxamid, , (4.009) 3-Chlor-4-(2,6-difluorphenyl)-6-methyl-5- phenylpyridazin, (4.010) 3-Chlor-5-(4-chlorphenyl)-4-(2,6-difluorphenyl)-6-methylpyridazin, (4.011) 3- Chlor-5-(6-chlorpyridin-3-yl)-6-methyl-4-(2,4,6-trifluorphenyl)pyridazin, (4.012) 4-(2-Brom-4- fluorphenyl)-N-(2,6-difluorphenyl)-1,3-dimethyl-1H-pyrazol-5-amin, (4.013) 4-(2-Brom-4- fluorphenyl)-N-(2-brom-6-fluorphenyl)-1,3-dimethyl-1H-pyrazol-5-amin, (4.014) 4-(2-Brom-4- fluorphenyl)-N-(2-bromphenyl)-1,3-dimethyl-1H-pyrazol-5-amin, (4.015) 4-(2-Brom-4-fluorphenyl)-N- (2-chlor-6-fluorphenyl)-1,3-dimethyl-1H-pyrazol-5-amin, (4.016) 4-(2-Brom-4-fluorphenyl)-N-(2- chlorphenyl)-1,3-dimethyl-1H-pyrazol-5-amin, (4.017) 4-(2-Brom-4-fluorphenyl)-N-(2-fluorphenyl)- 1,3-dimethyl-1H-pyrazol-5-amin, (4.018) 4-(2-Chlor-4-fluorphenyl)-N-(2,6-difluorphenyl)-1,3- dimethyl-1H-pyrazol-5-amin, (4.019) 4-(2-Chlor-4-fluorphenyl)-N-(2-chlor-6-fluorphenyl)-1,3- dimethyl-1H-pyrazol-5-amin, (4.020) 4-(2-Chlor-4-fluorphenyl)-N-(2-chlorphenyl)-1,3-dimethyl-1H- pyrazol-5-amin, (4.021) 4-(2-Chlor-4-fluorphenyl)-N-(2-fluorphenyl)-1,3-dimethyl-1H-pyrazol-5-amin, (4.022) 4-(4-Chlorphenyl)-5-(2,6-difluorphenyl)-3,6-dimethylpyridazin, (4.023) N-(2-Brom-6- fluorphenyl)-4-(2-chlor-4-fluorphenyl)-1,3-dimethyl-1H-pyrazol-5-amin, (4.024) N-(2-Bromphenyl)-4- (2-chlor-4-fluorphenyl)-1,3-dimethyl-1H-pyrazol-5-amin, (4.025) N-(4-Chlor-2,6-difluorphenyl)-4-(2- chlor-4-fluorphenyl)-1,3-dimethyl-1H-pyrazol-5-amin. 5) Verbindungen mit Befähigung zu Multisite-Aktivität, beispielsweise (5.001) Bordeauxmischung, (5.002) Captafol, (5.003) Captan, (5.004) Chlorthalonil, (5.005) Kupferhydroxid, (5.006) Kupfernaphthenat, (5.007) Kupferoxid, (5.008) Kupferoxychlorid, (5.009) Kupfer(2+)-sulfat, (5.010) Dithianon, (5.011) Dodin, (5.012) Folpet, (5.013) Mancozeb, (5.014) Maneb, (5.015) Metiram, (5.016) Zinkmetiram, (5.017) Kupfer-Oxin, (5.018) Propineb, (5.019) Schwefel und Schwefelzubereitungen einschließlich Calciumpolysulfid, (5.020) Thiram, (5.021) Zineb, (5.022) Ziram, (5.023) 6-Ethyl-5,7- dioxo-6,7-dihydro-5H-pyrrolo[3',4':5,6][1,4]dithiino[2,3-c][1,2]thiazole-3-carbonitrile. 6) Verbindungen, die zum Auslösen einer Wirtsabwehr befähigt sind, beispielsweise (6.001) Acibenzolar-S-Methyl, (6.002) Isotianil, (6.003) Probenazol, (6.004) Tiadinil. 7) Inhibitoren der Aminosäure- und/oder Protein-Biosynthese, beispielsweise (7.001) Cyprodinil, (7.002) Kasugamycin, (7.003) Kasugamycinhydrochlorid-hydrat, (7.004) Oxytetracyclin (7.005) Pyrimethanil, (7.006) 3-(5-Fluor-3,3,4,4-tetramethyl-3,4-dihydroisochinolin-1-yl)chinolin. (8) Inhibitoren der ATP-Produktion, beispielsweise (8.001) Silthiofam.
9) Inhibitoren der Zellwandsynthese, beispielsweise (9.001) Benthiavalicarb, (9.002) Dimethomorph, (9.003) Flumorph, (9.004) Iprovalicarb, (9.005) Mandipropamid, (9.006) Pyrimorph, (9.007) Valifenalat, (9.008) (2E)-3-(4-tert.-Butylphenyl)-3-(2-chlorpyridin-4-yl)-1-(morpholin-4-yl)prop-2-en- 1-on, (9.009) (2Z)-3-(4-tert.-Butylphenyl)-3-(2-chlorpyridin-4-yl)-1-(morpholin-4-yl)prop-2-en-1-on. 10) Inhibitoren der Lipid- und Membran-Synthese, beispielsweise (10.001) Propamocarb, (10.002) Propamocarbhydrochlorid, (10.003) Tolclofos-Methyl. 11) Inhibitoren der Melanin-Biosynthese, beispielsweise (11.001) Tricyclazol, (11.002) 2,2,2- Trifluorethyl-{3-methyl-1-[(4-methylbenzoyl)amino]butan-2-yl}carbamat. 12) Inhibitoren der Nukleinsäuresynthese, beispielsweise (12.001) Benalaxyl, (12.002) Benalaxyl-M (Kiralaxyl), (12.003) Metalaxyl, (12.004) Metalaxyl-M (Mefenoxam). 13) Inhibitoren der Signaltransduktion, beispielsweise (13.001) Fludioxonil, (13.002) Iprodion, (13.003) Procymidon, (13.004) Proquinazid, (13.005) Quinoxyfen, (13.006) Vinclozolin. 14) Verbindungen, die als Entkoppler wirken können, beispielsweise (14.001) Fluazinam, (14.002) Meptyldinocap. 15) Weitere Verbindungen, beispielsweise (15.001) Abscisinsäure, (15.002) Benthiazol, (15.003) Bethoxazin, (15.004) Capsimycin, (15.005) Carvon, (15.006) Chinomethionat, (15.007) Cufraneb, (15.008) Cyflufenamid, (15.009) Cymoxanil, (15.010) Cyprosulfamid, (15.011) Flutianil, (15.012) Fosetyl-Aluminium, (15.013) Fosetyl-Calcium, (15.014) Fosetyl-Natrium, (15.015) Methylisothiocyanat, (15.016) Metrafenon, (15.017) Mildiomycin, (15.018) Natamycin, (15.019) Nickel-Dimethyldithiocarbamat, (15.020) Nitrothal-Isopropyl, (15.021) Oxamocarb, (15.022) Oxathiapiprolin, (15.023) Oxyfenthiin, (15.024) Pentachlorphenol und Salze, (15.025) Phosphonsäure und deren Salze, (15.026) Propamocarb-fosetylat, (15.027) Pyriofenone (Chlazafenone) (15.028) Tebufloquin, (15.029) Tecloftalam, (15.030) Tolnifanide, (15.031) 1-(4-{4-[(5R)-5-(2,6-Difluorphenyl)- 4,5-dihydro-1,2-oxazol-3-yl]-1,3-thiazol-2-yl}piperidin-1-yl)-2-[5-methyl-3-(trifluormethyl)-1H- pyrazol-1-yl]ethanon, (15.032) 1-(4-{4-[(5S)-5-(2,6-Difluorphenyl)-4,5-dihydro-1,2-oxazol-3-yl]-1,3- thiazol-2-yl}piperidin-1-yl)-2-[5-methyl-3-(trifluormethyl)-1H-pyrazol-1-yl]ethanon, (15.033) 2-(6- Benzylpyridin-2-yl)quinazolin, (15.034) 2,6-Dimethyl-1H,5H-[1,4]dithiino[2,3-c:5,6-c']dipyrrol- 1,3,5,7(2H,6H)-tetron, (15.035) 2-[3,5-Bis(difluormethyl)-1H-pyrazol-1-yl]-1-[4-(4-{5-[2-(prop-2-in-1- yloxy)phenyl]-4,5-dihydro-1,2-oxazol-3-yl}-1,3-thiazol-2-yl)piperidin-1-yl]ethanon, (15.036) 2-[3,5- Bis(difluormethyl)-1H-pyrazol-1-yl]-1-[4-(4-{5-[2-chlor-6-(prop-2-in-1-yloxy)phenyl]-4,5-dihydro-1,2- oxazol-3-yl}-1,3-thiazol-2-yl)piperidin-1-yl]ethanon, (15.037) 2-[3,5-Bis(difluormethyl)-1H-pyrazol-1- yl]-1-[4-(4-{5-[2-fluor-6-(prop-2-in-1-yloxy)phenyl]-4,5-dihydro-1,2-oxazol-3-yl}-1,3-thiazol-2- yl)piperidin-1-yl]ethanon, (15.038) 2-[6-(3-Fluor-4-methoxyphenyl)-5-methylpyridin-2-yl]quinazolin,
(15.039) 2-{(5R)-3-[2-(1-{[3,5-Bis(difluormethyl)-1H-pyrazol-1-yl]acetyl}piperidin-4-yl)-1,3-thiazol-4- yl]-4,5-dihydro-1,2-oxazol-5-yl}-3-chlorphenyl methanesulfonat, (15.040) 2-{(5S)-3-[2-(1-{[3,5- Bis(difluormethyl)-1H-pyrazol-1-yl]acetyl}piperidin-4-yl)-1,3-thiazol-4-yl]-4,5-dihydro-1,2-oxazol-5- yl}-3-chlorphenyl methanesulfonat, (15.041) 2-{2-[(7,8-Difluor-2-methylquinolin-3-yl)oxy]-6- fluorphenyl}propan-2-ol, (15.042) 2-{2-Fluor-6-[(8-fluor-2-methylquinolin-3-yl)oxy]phenyl}propan-2- ol, (15.043) 2-{3-[2-(1-{[3,5-Bis(difluormethyl)-1H-pyrazol-1-yl]acetyl}piperidin-4-yl)-1,3-thiazol-4- yl]-4,5-dihydro-1,2-oxazol-5-yl}-3-chlorphenyl-methansulfonat, (15.044) 2-{3-[2-(1-{[3,5- Bis(difluormethyl)-1H-pyrazol-1-yl]acetyl}piperidin-4-yl)-1,3-thiazol-4-yl]-4,5-dihydro-1,2-oxazol-5- yl}phenyl methanesulfonat, (15.045) 2-Phenylphenol und deren Salze, (15.046) 3-(4,4,5-Trifluor-3,3- dimethyl-3,4-dihydroisoquinolin-1-yl)quinolin, (15.047) 3-(4,4-Difluor-3,3-dimethyl-3,4- dihydroisoquinolin-1-yl)quinolin, (15.048) 4-Amino-5-fluorpyrimidin-2-ol (Tautomere Form: 4-Amino- 5-fluorpyrimidin-2(1H)-on), (15.049) 4-Oxo-4-[(2-phenylethyl)amino]buttersäure, (15.050) 5-Amino- 1,3,4-thiadiazol-2-thiol, (15.051) 5-Chlor-N'-phenyl-N'-(prop-2-yn-1-yl)thiophen-2-sulfonohydrazid, (15.052) 5-Fluor-2-[(4-fluorbenzyl)oxy]pyrimidin-4-amin, (15.053) 5-Fluor-2-[(4- methylbenzyl)oxy]pyrimidin-4-amin, (15.054) 9-Fluor-2,2-dimethyl-5-(quinolin-3-yl)-2,3-dihydro-1,4- benzoxazepin, (15.055) But-3-yn-1-yl {6-[({[(Z)-(1-methyl-1H-tetrazol-5- yl)(phenyl)methylen]amino}oxy)methyl]pyridin-2-yl}carbamat, (15.056) Ethyl (2Z)-3-amino-2-cyano- 3-phenylacrylat, (15.057) Phenazin-1-carbonsäure, (15.058) Propyl 3,4,5-trihydroxybenzoat, (15.059) Quinolin-8-ol, (15.060) Quinolin-8-ol sulfat (2:1), (15.061) tert-Butyl {6-[({[(1-methyl-1H-tetrazol-5- yl)(phenyl)methylene]amino}oxy)methyl]pyridin-2-yl}carbamat, (15.062) 5-Fluor-4-imino-3-methyl- 1)sulfonyl]-3,4-dihydropyrimidin-2(1H)-one. Bevorzugte Fungizide sind ausgewählt aus der Gruppe bestehend aus Benalaxyl, Bitertanol, Bromuconazol, Captafol, Carbendazim, Carpropamid, Cyazofamid, Cyproconazol, Diethofencarb, Edifenphos, Fenpropimorph, Fentine, Fluquinconazol, Fosetyl, Fluoroimide, Folpet, Iminoctadine, Iprodionem, Iprovalicarb, Kasugamycin, Maneb, Nabam, Pencycuron, Prochloraz, Propamocarb, Propineb, Pyrimethanil, Sprioxamine, Quintozene, Tebuconazole, Tolylfluanid, Triadimefon, Triadimenol, Trifloxystrobin, Zineb. Insektizide, akarizide, nematizide, mitizide und verwandte Wirkstoffe sind, beispielsweise (analog zu den Herbiziden und Fungiziden werden die Verbindungen nach Möglichkeit mit ihren Common names bezeichnet, hier in der üblichen englischen Schreibweise): (1) Acetylcholinesterase(AChE)-Inhibitoren, vorzugsweise Carbamate ausgewählt aus Alanycarb, Aldicarb, Bendiocarb, Benfuracarb, Butocarboxim, Butoxycarboxim, Carbaryl, Carbofuran, Carbosulfan, Ethiofencarb, Fenobucarb, Formetanate, Furathiocarb, Isoprocarb, Methiocarb, Methomyl, Metolcarb, Oxamyl, Pirimicarb, Propoxur, Thiodicarb, Thiofanox, Triazamate, Trimethacarb, XMC und Xylylcarb, oder Organophosphate ausgewählt aus Acephat, Azamethiphos, Azinphos-ethyl, Azinphos-
methyl, Cadusafos, Chlorethoxyfos, Chlorfenvinphos, Chlormephos, Chlorpyrifos-methyl, Coumaphos, Cyanophos, Demeton-S-methyl, Diazinon, Dichlorvos/DDVP, Dicrotophos, Dimethoat, Dimethylvinphos, Disulfoton, EPN, Ethion, Ethoprophos, Famphur, Fenamiphos, Fenitrothion, Fenthion, Fosthiazat, Heptenophos, Imicyafos, Isofenphos, Isopropyl-O-(methoxyaminothio- phosphoryl)salicylat, Isoxathion, Malathion, Mecarbam, Methamidophos, Methidathion, Mevinphos, Monocrotophos, Naled, Omethoate, Oxydemeton-methyl, Parathion-methyl, Phenthoat, Phorat, Phosalon, Phosmet, Phosphamidon, Phoxim, Pirimiphos-methyl, Profenofos, Propetamphos, Prothiofos, Pyraclofos, Pyridaphenthion, Quinalphos, Sulfotep, Tebupirimfos, Temephos, Terbufos, Tetrachlorvinphos, Thiometon, Triazophos, Triclorfon und Vamidothion. (2) GABA-gesteuerte Chlorid-Kanal-Blocker, vorzugsweise Cyclodien-organochlorine ausgewählt aus Chlordan und Endosulfan, oder Phenylpyrazole (Fiprole) ausgewählt aus Ethiprol und Fipronil. (3) Natrium-Kanal-Modulatoren, vorzugsweise Pyrethroide ausgewählt aus Acrinathrin, Allethrin, d-cis- trans-Allethrin, d-trans-Allethrin, Bifenthrin, Bioallethrin, Bioallethrin-S-cyclopentenyl-Isomer, Bioresmethrin, Cycloprothrin, Cyfluthrin, beta-Cyfluthrin, Cyhalothrin, lambda-Cyhalothrin, gamma- Cyhalothrin, Cypermethrin, alpha-Cypermethrin, beta-Cypermethrin, theta-Cypermethrin, zeta- Cypermethrin, Cyphenothrin [(1R)-trans-Isomer], Deltamethrin, Empenthrin [(EZ)-(1R)-Isomer], Esfenvalerat, Etofenprox, Fenpropathrin, Fenvalerat, Flucythrinat, Flumethrin, tau-Fluvalinat, Halfenprox, Imiprothrin, Kadethrin, Momfluorothrin, Permethrin, Phenothrin [(1R)-trans-Isomer], Prallethrin, Pyrethrine (pyrethrum), Resmethrin, Silafluofen, Tefluthrin, Tetramethrin, Tetramethrin [(1R)-Isomer], Tralomethrin und Transfluthrin, oder DDT oder Methoxychlor. (4) Kompetitive Modulatoren des nicotinischen Acetylcholin-Rezeptors (nAChR), vorzugsweise Neonicotinoide ausgewählt aus Acetamiprid, Clothianidin, Dinotefuran, Imidacloprid, Nitenpyram, Thiacloprid und Thiamethoxam, oder Nicotin, oder Sufoximine ausgewählt aus Sulfoxaflor, oder Butenolide ausgewählt aus Flupyradifurone. (5) Allosterische Modulatoren des nicotinischen Acetylcholin-Rezeptors (nAChR), vorzugsweise Spinosyne ausgewählt aus Spinetoram und Spinosad. (6) Allosterische Modulatoren des Glutamat-abhängigen Chloridkanals (GluCl), vorzugsweise Avermectine/Milbemycine ausgewählt aus Abamectin, Emamectin-benzoat, Lepimectin und Milbemectin. (7) Juvenilhormon-Mimetika, vorzugsweise Juvenilhormon-Analoge ausgewählt aus Hydropren, Kinopren und Methopren, oder Fenoxycarb oder Pyriproxyfen.
(8) Verschiedene nicht spezifische (multi-site) Inhibitoren, vorzugsweise Alkylhalogenide ausgewählt aus Methylbromid und andere Alkylhalogenide, oder Chloropicrin oder Sulfurylfluorid oder Borax oder Brechweinstein oder Methylisocyanaterzeuger ausgewählt aus Diazomet und Metam. (9) TRPV-Kanal-Modulatoren chordotonaler Organe ausgewählt aus Pymetrozin und Pyrifluquinazon. (10) Milbenwachstumsinhibitoren ausgewählt aus Clofentezin, Hexythiazox, Diflovidazin und Etoxazol. (11) Mikrobielle Disruptoren der Insektendarmmembran ausgewählt aus Bacillus thuringiensis Subspezies israelensis, Bacillus sphaericus, Bacillus thuringiensis Subspezies aizawai, Bacillus thuringiensis Subspezies kurstaki, Bacillus thuringiensis Subspezies tenebrionis und B.t.- Pflanzenproteine ausgewählt aus Cry1Ab, Cry1Ac, Cry1Fa, Cry1A.105, Cry2Ab, VIP3A, mCry3A, Cry3Ab, Cry3Bb und Cry34Ab1/35Ab1. (12) Inhibitoren der mitochondrialen ATP-Synthase, vorzugsweise ATP-Disruptoren ausgewählt aus Diafenthiuron, oder Organozinnverbindungen ausgewählt aus Azocyclotin, Cyhexatin und Fenbutatin- oxid, oder Propargit oder Tetradifon. (13) Entkoppler der oxidativen Phoshorylierung durch Störung des Protonengradienten ausgewählt aus Chlorfenapyr, DNOC und Sulfluramid. (14) Blocker des nicotinischen Acetylcholinrezeptorkanals ausgewählt aus Bensultap, Cartap- hydrochlorid, Thiocyclam und Thiosultap-Natrium. (15) Inhibitoren der Chitinbiosynthese, Typ 0, ausgewählt aus Bistrifluron, Chlorfluazuron, Diflubenzuron, Flucycloxuron, Flufenoxuron, Hexaflumuron, Lufenuron, Novaluron, Noviflumuron, Teflubenzuron und Triflumuron. (16) Inhibitoren der Chitinbiosynthese, Typ 1 ausgewählt aus Buprofezin. (17) Häutungsdisruptor (insbesondere bei Dipteren, d. h. Zweiflüglern) ausgewählt aus Cyromazin. (18) Ecdyson-Rezeptor-Agonisten ausgewählt aus Chromafenozid, Halofenozid, Methoxyfenozid und Tebufenozid. (19) Oktopamin-Rezeptor-Agonisten ausgewählt aus Amitraz. (20) Mitochondriale Komplex-III-Elektronentransportinhibitoren ausgewählt aus Hydramethylnon, Acequinocyl und Fluacrypyrim. (21) Mitochondriale Komplex-I-Elektronentransportinhibitoren, vorzugsweise METI-Akarizide ausgewählt aus Fenazaquin, Fenpyroximat, Pyrimidifen, Pyridaben, Tebufenpyrad und Tolfenpyrad, oder Rotenon (Derris).
(22) Blocker des spannungsabhängigen Natriumkanals ausgewählt aus Indoxacarb und Metaflumizone. (23) Inhibitoren der Acetyl-CoA-Carboxylase, vorzugsweise Tetron- und Tetramsäurederivate ausgewählt aus Spirodiclofen, Spiromesifen und Spirotetramat. (24) Inhibitoren des mitochondrialen Komplex-IV-Elektronentransports, vorzugsweise Phosphine ausgewählt aus Aluminiumphosphid, Calciumphosphid, Phosphin und Zinkphosphid, oder Cyanide ausgewählt aus Calciumcyanid, Kaliumcyanid und Natriumcyanid. (25) Inhibitoren des mitochondrialen Komplex-II-Elektronentransports, vorzugsweise beta- Ketonitrilderivate ausgewählt aus Cyenopyrafen und Cyflumetofen, oder Carboxanilide ausgewählt aus Pyflubumid. (28) Ryanodinrezeptor-Modulatoren, vorzugsweise Diamide ausgewählt aus Chlorantraniliprol, Cyantraniliprol und Flubendiamid. (29) Modulatoren chordotonaler Organe (mit undefinierter Zielstruktur) ausgewählt aus Flonicamid. (30) weitere Wirkstoffe ausgewählt aus Acynonapyr, Afidopyropen, Afoxolaner, Azadirachtin, Benclothiaz, Benzoximat, Benzpyrimoxan, Bifenazat, Broflanilid, Bromopropylat, Chinomethionat, Chloroprallethrin, Cryolit, Cyclaniliprol, Cycloxaprid, Cyhalodiamid, Dicloromezotiaz, Dicofol, epsilon-Metofluthrin, epsilon-Momfluthrin, Flometoquin, Fluazaindolizin, Fluensulfon, Flufenerim, Flufenoxystrobin, Flufiprol, Fluhexafon, Fluopyram, Flupyrimin, Fluralaner, Fluxametamid, Fufenozid, Guadipyr, Heptafluthrin, Imidaclothiz, Iprodione, kappa-Bifenthrin, kappa-Tefluthrin, Lotilaner, Meperfluthrin, Oxazosulfyl, Paichongding, Pyridalyl, Pyrifluquinazon, Pyriminostrobin, Spirobudiclofen, Spiropidion, Tetramethylfluthrin, Tetraniliprol, Tetrachlorantraniliprol, Tigolaner, Tioxazafen, Thiofluoximat, Triflumezopyrim und Iodmethan; des Weiteren Präparate auf Basis von Bacillus firmus (I-1582, BioNeem, Votivo), sowie folgende Verbindungen: 1-{2-Fluor-4-methyl-5- [(2,2,2-trifluorethyl)sulfinyl]phenyl}-3-(trifluormethyl)-1H-1,2,4-triazol-5-amin (bekannt aus WO2006/043635) (CAS 885026-50-6), {1'-[(2E)-3-(4-Chlorphenyl)prop-2-en-1-yl]-5-fluorspiro[indol- 3,4'-piperidin]-1(2H)-yl}(2-chlorpyridin-4-yl)methanon (bekannt aus WO2003/106457) (CAS 637360- 23-7), 2-Chlor-N-[2-{1-[(2E)-3-(4-chlorphenyl)prop-2-en-1-yl]piperidin-4-yl}-4- (trifluormethyl)phenyl]isonicotinamid (bekannt aus WO2006/003494) (CAS 872999-66-1), 3-(4-Chlor- 2,6-dimethylphenyl)-4-hydroxy-8-methoxy-1,8-diazaspiro[4.5]dec-3-en-2-on (bekannt aus WO 2010052161) (CAS 1225292-17-0), 3-(4-Chlor-2, 6-dimethylphenyl)-8-methoxy-2-oxo-1,8- diazaspiro[4.5]dec-3-en-4-yl-ethylcarbonat (bekannt aus EP 2647626) (CAS-1440516-42-6), 4-(But-2- in-1-yloxy)-6-(3,5-dimethylpiperidin-1-yl)-5-fluorpyrimidin (bekannt aus WO2004/099160) (CAS 792914-58-0), PF1364 (bekannt aus JP2010/018586) (CAS-Reg.No.1204776-60-2), (3E)-3-[1-[(6- Chlor-3-pyridyl)methyl]-2-pyridyliden]-1,1,1-trifluorpropan-2-on (bekannt aus WO2013/144213) (CAS 1461743-15-6), N-[3-(Benzylcarbamoyl)-4-chlorphenyl]-1-methyl-3-(pentafluorethyl)-4-
(trifluormethyl)-1H-pyrazol-5-carboxamid (bekannt aus WO2010/051926) (CAS 1226889-14-0), 5- Brom-4-chlor-N-[4-chlor-2-methyl-6-(methylcarbamoyl)phenyl]-2-(3-chlor-2-pyridyl)pyrazol-3- carboxamid (bekannt aus CN103232431) (CAS 1449220-44-3), 4-[5-(3,5-Dichlorphenyl)-4,5-dihydro- 5-(trifluormethyl)-3-isoxazolyl]-2-methyl-N-(cis-1-oxido-3-thietanyl)benzamid, 4-[5-(3,5- Dichlorphenyl)-4,5-dihydro-5-(trifluormethyl)-3-isoxazolyl]-2-methyl-N-(trans-1-oxido-3- thietanyl)benzamid und 4-[(5S)-5-(3,5-Dichlorphenyl)-4,5-dihydro-5-(trifluormethyl)-3-isoxazolyl]-2- methyl-N-(cis-1-oxido-3-thietanyl)benzamid (bekannt aus WO 2013/050317 A1) (CAS 1332628-83-7), N-[3-Chlor-1-(3-pyridinyl)-1H-pyrazol-4-yl]-N-ethyl-3-[(3,3,3-trifluorpropyl)sulfinyl]propanamid, (+)- N-[3-Chlor-1-(3-pyridinyl)-1H-pyrazol-4-yl]-N-ethyl-3-[(3,3,3-trifluorpropyl)sulfinyl]propanamid und (-)-N-[3-Chlor-1-(3-pyridinyl)-1H-pyrazol-4-yl]-N-ethyl-3-[(3,3,3-trifluorpropyl)sulfinyl]propanamid (bekannt aus WO 2013/162715 A2, WO 2013/162716 A2, US 2014/0213448 A1) (CAS 1477923-37-7), 5-[[(2E)-3-Chlor-2-propen-1-yl]amino]-1-[2,6-dichlor-4-(trifluormethyl)phenyl]-4- [(trifluormethyl)sulfinyl]-1H-pyrazol-3-carbonitrile (bekannt aus CN 101337937 A) (CAS 1105672-77- 2), 3-Brom-N-[4-chlor-2-methyl-6-[(methylamino)thioxomethyl]phenyl]-1-(3-chlor-2-pyridinyl)-1H- pyrazol-5-carboxamid, (Liudaibenjiaxuanan, bekannt aus CN 103109816 A) (CAS 1232543-85-9); N- [4-Chlor-2-[[(1,1-dimethylethyl)amino]carbonyl]-6-methylphenyl]-1-(3-chlor-2-pyridinyl)-3- (fluormethoxy)-1H-pyrazol-5-carboxamid (bekannt aus WO 2012/034403 A1) (CAS 1268277-22-0), N- [2-(5-Amino-1,3,4-thiadiazol-2-yl)-4-chlor-6-methylphenyl]-3-brom-1-(3-chlor-2-pyridinyl)-1H- pyrazol-5-carboxamid (bekannt aus WO 2011/085575 A1) (CAS 1233882-22-8), 4-[3-[2,6-Dichlor-4- [(3,3-dichlor-2-propen-1-yl)oxy]phenoxy]propoxy]-2-methoxy-6-(trifluormethyl)pyrimidin (bekannt aus CN 101337940 A) (CAS 1108184-52-6); (2E)- und 2(Z)-2-[2-(4-Cyanophenyl)-1-[3- (trifluormethyl)phenyl]ethyliden]-N-[4-(difluormethoxy)phenyl]hydrazincarboxamid (bekannt aus CN 101715774 A) (CAS 1232543-85-9); Cyclopropancarbonsäure-3-(2,2-dichlorethenyl)-2,2-dimethyl-4- (1H-benzimidazol-2-yl)phenylester (bekannt aus CN 103524422 A) (CAS 1542271-46-4); (4aS)-7- Chlor-2,5-dihydro-2-[[(methoxycarbonyl)[4-[(trifluormethyl)thio]phenyl]amino]carbonyl]indeno[1,2- e][1,3,4]oxadiazin-4a(3H)-carbonsäuremethylester (bekannt aus CN 102391261 A) (CAS 1370358-69- 2); 6-Desoxy-3-O-ethyl-2,4-di-O-methyl-1-[N-[4-[1-[4-(1,1,2,2,2-pentafluorethoxy)phenyl]-1H-1,2,4- triazol-3-yl]phenyl]carbamat]-α-L-mannopyranose (bekannt aus US 2014/0275503 A1) (CAS 1181213- 14-8); 8-(2-Cyclopropylmethoxy-4-trifluormethylphenoxy)-3-(6-trifluormethylpyridazin-3-yl)-3- azabicyclo[3.2.1]octan (CAS 1253850-56-4), (8-anti)-8-(2-Cyclopropylmethoxy-4- trifluormethylphenoxy)-3-(6-trifluormethylpyridazin-3-yl)-3-azabicyclo[3.2.1]octan (CAS 933798-27- 7), (8-syn)-8-(2-Cyclopropylmethoxy-4-trifluormethylphenoxy)-3-(6-trifluormethylpyridazin-3-yl)-3- azabicyclo[3.2.1]octan (bekannt aus WO 2007040280 A1, WO 2007040282 A1) (CAS 934001-66-8), N-[3-Chlor-1-(3-pyridinyl)-1H-pyrazol-4-yl]-N-ethyl-3-[(3,3,3-trifluorpropyl)thio]-propanamid (bekannt aus WO 2015/058021 A1, WO 2015/058028 A1) (CAS 1477919-27-9) und N-[4- (Aminothioxomethyl)-2-methyl-6-[(methylamino)carbonyl]phenyl]-3-bromo-1-(3-chloro-2-pyridinyl)- 1H-pyrazol-5-carboxamid (bekannt aus CN 103265527 A) (CAS 1452877-50-7), 5-(1,3-Dioxan-2-yl)-4-
[[4-(trifluormethyl)phenyl]methoxy]-pyrimidin (bekannt aus WO 2013/115391 A1) (CAS 1449021-97- 9), 3-(4-Chlor-2,6-dimethylphenyl)-8-methoxy-1-methyl-1,8-diazaspiro[4.5]decane-2,4-dion (bekannt aus WO 2014/187846 A1) (CAS 1638765-58-8), 3-(4-Chlor-2,6-dimethylphenyl)-8-methoxy-1-methyl- 2-oxo-1,8-diazaspiro[4.5]dec-3-en-4-yl-carbonsäureethylester (bekannt aus WO 2010/066780 A1, WO 2011151146 A1) (CAS 1229023-00-0), 4-[(5S)-5-(3,5-Dichlor-4-fluorophenyl)-4,5-dihydro-5- (trifluoromethyl)-3-isoxazolyl]-N-[(4R)-2-ethyl-3-oxo-4-isoxazolidinyl]-2-methyl-benzamid (bekannt aus WO 2011/067272, WO2013/050302) (CAS 1309959-62-3). Insektizide, die bevorzugt gemeinsam mit den Herbiziden eingesetzt werden können, sind beispielsweise folgende: Acetamiprid, Acrinathrin, Aldicarb, Amitraz, Acinphos-methyl, Cyfluthrin, Carbaryl, Cypermethrin, Deltamethrin, Endosulfan, Ethoprophos, Fenamiphos, Fenthion, Fipronil, Imidacloprid, Methamidophos, Methiocarb, Niclosamide, Oxydemeton-methyl, Prothiophos, Silafluofen, Thiacloprid, Thiodicarb, Tralomethrin, Triazophos, Trichlorfon, Triflumuron, Terbufos, Fonofos, Phorate, Chlorpyriphos, Carbofuran, Tefluthrin. Die erfindungsgemäßen Wirkstoffkombinationen sind zur Bekämpfung eines breiten Unkrautspektrums im Nichtkulturland, auf Wegen, Gleisanlagen, Industrieflächen ("industrial weed control") oder in Plantagenkulturen wie gemäßigten, subtropischen und tropischen Klimaten oder Geographien geeignet. Beispiele für Plantagenkulturen sind Ölpalme, Nüsse (z. B. Mandeln, Haselnüsse, Walnüsse, Macademia), Kokosnuss, Beeren, Ölpalme, Gummibaum, Citrus (z. B. Orange, Zitrone, Mandarine), Bananen, Ananas, Baumwolle, Zuckerrohr, Tee, Kaffee, Kakao und Ähnliches. Ebenso sind sie für die Anwendung im Obstbau (z. B. Kernobst wie Apfel, Birne, Kirsche, Mango, Kiwi) und Weinbau geeignet. Die Mittel können auch zur Saatvorbereitung ("burn-down-" "no-till"- oder "zero-till"- Methode) oder zur Behandlung nach der Ernte ("chemical fallow") eingesetzt werden. Die Anwendungsmöglichkeiten der Wirkstoffkombinationen erstrecken sich auch zur Unkrautkontrolle in Baumkulturen, z. B. jungen Christbaumkulturen oder Eukalyptus-Anlagen, jeweils vor der Einpflanzung oder nach der Verpflanzung (auch mit Überkopfbehandlung, "over-top"). Auch können die Mittel in zur Bekämpfung von unerwünschtem Pflanzenwuchs in wirtschaftlich bedeutenden Kulturpflanzen wie Weizen (Hart- und Weichweizen), Mais, Soja, Zuckerrübe, Zuckerrohr, Baumwolle, Reis, Bohnen (wie beispielsweise Buschbohne und Pferdebohne), Flachs, Gerste, Hafer, Roggen, Triticale, Kartoffel und Hirse (Sorghum), Weideland und Grün-/Rasenflächen und Plantagenkulturen eingesetzt werden. Plantagenkulturen sind unteranderem Pomefruits (Apfel, Birne, Quitte), Ribes-Artige (Brombeere, Himbeere),Citrus, Prunus-Artige (Kirschen, Nektarinen, Mandeln), Nußfrüchte (Walnuß, Pecan, Haselnuß, Cashew, Macadamia), Mango, Kakao, Kaffee, Wein (Tafel-,
Weintrauben), Palmen (wie Ölpalme, Dattelpalme,Kokospalme,,) Eucalyptus, Kaki, Persimon, Kautschuk, Ananans, Banane, Avocado, Litschi, Forstkulturen (Eucalypteae, Piniaceae, Piceae, Meliaceae, etc. ) Die erfindungsgemäßen herbiziden Wirkstoffkombinationen in den jeweiligen Anwendungsformen (= herbiziden Mittel) weisen Synergien hinsichtlich der Herbizidwirkung und Selektivität und günstige Wirkung bezüglich des Unkrautspektums auf. Sie weisen eine ausgezeichnete herbizide Wirksamkeit gegen ein breites Spektrum wirtschaftlich wichtiger monokotyler und dikotyler annueller Schadpflanzen auf. Auch schwer bekämpfbare perennierende Schadpflanzen, die aus Rhizomen, Wurzelstöcken oder anderen Dauerorganen austreiben, werden durch die Wirkstoffe gut erfaßt. Zur Anwendung können die Wirkstoffkombinationen auf die Pflanzen (z.B. Schadpflanzen wie mono- oder dikotyle Unkräuter oder unerwünschte Kulturpflanzen), das Saatgut (z.B. Körner, Samen oder vegetative Vermehrungsorgane wie Knollen oder Sprossteile mit Knospen) oder die Fläche, auf der die Pflanzen wachsen (z.B. die Anbaufläche), ausgebracht werden. Dabei können die Substanzen im Vorsaat- (ggf. auch durch Einarbeitung in den Boden), Vorauflauf- oder Nachauflaufverfahren ausgebracht werden. Bevorzugt ist die Anwendung im frühen Nachsaat- Vorauflaufverfahren oder im Nachauflaufverfahren von Plantagenkulturen gegen noch nicht aufgelaufene oder bereits aufgelaufene Schadpflanzen. Die Anwendung kann auch in Unkrautmanagment-Systemen (weed-management) mit geteilten mehrfachen Anwendungen (Sequenzanwendungen, "sequentials") integriert werden. Im Einzelnen seien beispielhaft einige Vertreter der mono- und dikotylen Unkrautflora genannt, die durch die erfindungsgemäßen Wirkstoffkombinationen kontrolliert werden können, ohne dass durch die Nennung eine Beschränkung auf bestimmte Arten erfolgen soll. Auf der Seite der monokotylen Unkrautarten werden z.B. Aegilops, Agropyron, Agrostis, Alopecurus, Apera, Avena, Brachicaria, Bromus, Cynodon, Dactyloctenium, Digitaria, Echinochloa, Eleocharis, Eleusine, Eragrostis, Eriochloa, Festuca, Fimbristylis, Imperata, Ischaemum, Heteranthera, Imperata, Ischaemum, Leptochloa, Lolium, Monochoria, Panicum, Paspalum, Phalaris, Phleum, Poa, Rottboellia, Sagittaria, Scirpus, Setaria, Sorghum, Sphenoclea und Cyperus-arten von der annuellen Gruppe erfasst. Bei dikotylen Unkrautarten erstreckt sich das Wirkungsspektrum auf Arten wie z.B. Abutilon, Amaranthus, Ambrosia, Anoda, Anthemis, Aphanes, Artemisia, Atriplex, Bellis, Bidens, Capsella, Carduus, Cassia, Centaurea, Chenopodium, Cirsium, Convolvulus, Datura, Desmodium, Emex, Erodium, Erysimum, Euphorbia, Galeopsis, Galinsoga, Galium, Geranium, Hibiscus, Ipomoea, Kochia, Lamium, Lepidium, Lindernia, Matricaria, Mentha, Mercurialis, Mullugo, Myosotis, Papaver, Pharbitis,
Plantago, Polygonum, Portulaca, Ranunculus, Raphanus, Rorippa, Rotala, Rumex, Salsola, Senecio, Sesbania, Sida, Sinapis, Solanum, Sonchus, Sphenoclea, Stellaria, Taraxacum, Thlaspi, Trifolium, Urtica, Veronica, Viola, Xanthium. Werden die erfindungsgemäßen Wirkstoffkombinationen vor dem Keimen auf die Erdoberfläche appliziert, so wird entweder das Auflaufen der Unkrautkeimlinge vollständig verhindert oder die Unkräuter wachsen bis zum Keimblattstadium heran, stellen jedoch dann ihr Wachstum ein und sterben schließlich nach Ablauf von drei bis vier Wochen vollkommen ab. Bei Applikation der Wirkstoffe auf die grünen Pflanzenteile im Nachauflaufverfahren tritt nach der Behandlung ein Wachstumsstop ein und die Schadpflanzen bleiben in dem zum Applikationszeitpunkt vorhandenen Wachstumsstadium stehen oder sterben nach einer gewissen Zeit ganz ab, so dass auf diese Weise eine für die Kulturpflanzen schädliche Unkrautkonkurrenz sehr früh und nachhaltig beseitigt wird. Die erfindungsgemäßen herbiziden Mittel zeichnen sich durch eine schnell einsetzende und lang andauernde herbizide Wirkung aus. Die Regenfestigkeit der Wirkstoffe in den erfindungsgemäßen Kombinationen ist in der Regel günstig. Als besonderer Vorteil fällt ins Gewicht, dass die in den Kombinationen verwendeten und wirksamen Dosierungen von Verbindungen (A) und (B) so gering eingestellt werden können, dass ihre Bodenwirkung optimal niedrig ist. Somit wird deren Einsatz nicht nur in empfindlichen Kulturen erst möglich, sondern Grundwasser-Kontaminationen werden praktisch vermieden. Durch die erfindungsgemäße Kombination von Wirkstoffen wird eine erhebliche Reduzierung der nötigen Aufwandmenge der Wirkstoffe ermöglicht. Mit dem kombinierten Einsatz der Herbizide (A) und (B) werden anwendungstechnische Eigenschaften erreicht, die über das hinausgehen, was aufgrund der bekannten Eigenschaften der Einzelherbizide für deren Kombination zu erwarten war. Beispielsweise übertreffen die herbiziden Wirkungen bei einer bestimmten Schadpflanzenspezies den Erwartungswert, wie er nach Standardverfahren, z. B. gemäß Colby oder anderen Extrapolationsverfahren, abgeschätzt werden kann. Ein synergistischer Effekt liegt immer dann vor, wenn die Wirkung, hier die herbizide Wirkung der Wirkstoffkombination größer ist als die Summe der Wirkungen der einzeln applizierten Wirkstoffe. Die zu erwartende Wirkung für eine gegebene Kombination zweier Wirkstoffe kann nach S.R. Colby („Calculating Synergistic and Antagonistic Responses of Herbicide Combination“, Weeds 15 (1967), 20-22) berechnet werden (siehe unten).
Die synergistischen Effekte erlauben daher beispielsweise eine Reduktion der Aufwandmengen der Einzelwirkstoffe, eine höhere Wirkungsstärke bei gleicher Aufwandmenge, die Kontrolle bislang nicht erfasster Arten von Schadpflanzen (Lücken), eine erhöhte Residualwirkung, eine erhöhte Langzeitwirkung, eine erhöhte Wirkungsgeschwindigkeit, eine Ausdehnung des Anwendungszeitraums und/oder eine Reduzierung der Anzahl notwendiger Einzelanwendungen und - als Resultat für den Anwender - ökonomisch und ökologisch vorteilhaftere Unkrautbekämpfungssysteme. Obgleich die erfindungsgemäßen Kombinationen eine ausgezeichnete herbizide Aktivität gegenüber mono- und dikotylen Unkräutern aufweisen, werden viele wirtschaftlich bedeutende Kulturpflanzen abhängig von der Struktur der jeweiligen erfindungsgemäßen Wirkstoffkombinationen und deren Aufwandmenge nur unwesentlich oder gar nicht geschädigt. Wirtschaftlich bedeutende Kulturen sind dabei z.B. dikotyle Kulturen der Gattungen Arachis, Beta, Brassica, Cucumis, Cucurbita, Helianthus, Daucus, Glycine, Gossypium, Ipomoea, Lactuca, Linum, Lycopersicon, Nicotiana, Phaseolus, Pisum, Solanum, Vicia, oder monokotyle Kulturen der Gattungen Allium, Ananas, Asparagus, Avena, Hordeum, Oryza, Panicum, Saccharum, Secale, Sorghum, Triticale, Triticum und Zea. Darüberhinaus weisen die erfindungsgemäßen Mittel teilweise hervorragende wachstumsregulatorische Eigenschaften bei den Kulturpflanzen auf. Sie greifen regulierend in den pflanzeneigenen Stoffwechsel ein und können damit zur gezielten Beeinflussung von Pflanzeninhaltsstoffen und zur Ernteerleichterung wie z.B. durch Auslösen von Desikkation und Wuchsstauchung eingesetzt werden. Desweiteren eignen sie sich auch zur generellen Steuerung und Hemmung von unerwünschtem vegetativem Wachstum, ohne dabei die Pflanzen abzutöten. Eine Hemmung des vegetativen Wachstums spielt bei vielen mono- und dikotylen Kulturen eine große Rolle, da das Lagern hierdurch verringert oder völlig verhindert werden kann. Aufgrund ihrer herbiziden und pflanzenwachstumsregulatorischen Eigenschaften können die Mittel zur Bekämpfung von Schadpflanzen in bekannten Pflanzenkulturen oder noch zu entwickelnden, durch konventionelle Mutagenese veränderten oder gentechnisch veränderten, toleranten Kulturpflanzen eingesetzt werden. Die transgenen Pflanzen zeichnen sich in der Regel durch besondere vorteilhafte Eigenschaften aus, neben den Resistenzen gegenüber den erfindungsgemäßen Mitteln beispielsweise durch Resistenzen gegenüber Pflanzenkrankheiten oder Erregern von Pflanzenkrankheiten wie bestimmten Insekten oder Mikroorganismen wie Pilzen, Bakterien oder Viren. Andere besondere Eigenschaften betreffen z. B. das Erntegut hinsichtlich Menge, Qualität, Lagerfähigkeit, Zusammensetzung und spezieller Inhaltsstoffe. So sind transgene Pflanzen mit erhöhtem Stärkegehalt oder veränderter Qualität der Stärke oder solche mit anderer Fettsäurezusammensetzung des Ernteguts bekannt. Weitere besondere Eigenschaften können in einer Toleranz oder Resistenz gegen abiotische Stressoren z. B. Hitze, Kälte, Trockenheit, Salz und ultraviolette Strahlung liegen.
Vorzugsweise können die erfindungsgemäßen Wirkstoffkombinationen als Herbizide in Nutzpflanzenkulturen eingesetzt werden, welche gegenüber den phytotoxischen Wirkungen der Herbizide resistent sind bzw. gentechnisch resistent gemacht worden sind. Herkömmliche Wege zur Herstellung neuer Pflanzen, die im Vergleich zu bisher vorkommenden Pflanzen modifizierte Eigenschaften aufweisen, bestehen beispielsweise in klassischen Züchtungsverfahren und der Erzeugung von Mutanten. Alternativ können neue Pflanzen mit veränderten Eigenschaften mit Hilfe gentechnischer Verfahren erzeugt werden (siehe z. B. EP-A-0221044, EP-A- 0131624). Beschrieben wurden beispielsweise in mehreren Fällen - gentechnische Veränderungen von Kulturpflanzen zwecks Modifikation der in den Pflanzen synthetisierten Stärke (z. B. WO 92/11376, WO 92/14827, WO 91/19806), - transgene Kulturpflanzen, welche Resistenzen gegen andere Herbizide aufweisen, beispielsweise gegen Sulfonylharnstoffe (EP-A-0257993, US-A-5013659), - transgene Kulturpflanzen, mit der Fähigkeit Bacillus thuringiensis-Toxine (Bt-Toxine) zu produzieren, welche die Pflanzen gegen bestimmte Schädlinge resistent machen (EP-A-0142924, EP-A-0193259). - transgene Kulturpflanzen mit modifizierter Fettsäurezusammensetzung (WO 91/13972). - gentechnisch veränderte Kulturpflanzen mit neuen Inhalts- oder Sekundärstoffen z. B. neuen Phytoalexinen, die eine erhöhte Krankheitsresistenz verursachen (EPA 309862, EPA0464461) - gentechnisch veränderte Pflanzen mit reduzierter Photorespiration, die höhere Erträge und höhere Stresstoleranz aufweisen (EPA 0305398). - Transgene Kulturpflanzen, die pharmazeutisch oder diagnostisch wichtige Proteine produzieren („molecular pharming“) - transgene Kulturpflanzen, die sich durch höhere Erträge oder bessere Qualitat auszeichnen - transgene Kulturpflanzen die sich durch eine Kombinationen z. B. der o. g. neuen Eigenschaften auszeichnen („gene stacking“) Zahlreiche molekularbiologische Techniken, mit denen neue transgene Pflanzen mit veränderten Eigenschaften hergestellt werden können, sind im Prinzip bekannt; siehe z. B. I. Potrykus und G. Spangenberg (eds.) Gene Transfer to Plants, Springer Lab Manual (1995), Springer Verlag Berlin, Heidelberg. oder Christou, "Trends in Plant Science" 1 (1996) 423-431).
Für derartige gentechnische Manipulationen können Nucleinsäuremoleküle in Plasmide eingebracht werden, die eine Mutagenese oder eine Sequenzveränderung durch Rekombination von DNA- Sequenzen erlauben. Mit Hilfe von Standardverfahren können z. B. Basenaustausche vorgenommen, Teilsequenzen entfernt oder natürliche oder synthetische Sequenzen hinzugefügt werden. Für die Verbindung der DNA-Fragmente untereinander können an die Fragmente Adaptoren oder Linker angesetzt werden, siehe z. B. Sambrook et al., 1989, Molecular Cloning, A Laboratory Manual, 2. Aufl. Cold Spring Harbor Laboratory Press, Cold Spring Harbor, NY; oder Winnacker "Gene und Klone", VCH Weinheim 2. Auflage 1996. Die Herstellung von Pflanzenzellen mit einer verringerten Aktivität eines Genprodukts kann beispielsweise erzielt werden durch die Expression mindestens einer entsprechenden antisense-RNA, einer sense-RNA zur Erzielung eines Cosuppressionseffektes oder die Expression mindestens eines entsprechend konstruierten Ribozyms, das spezifisch Transkripte des obengenannten Genprodukts spaltet. Hierzu können zum einen DNA-Moleküle verwendet werden, die die gesamte codierende Sequenz eines Genprodukts einschließlich eventuell vorhandener flankierender Sequenzen umfassen, als auch DNA- Moleküle, die nur Teile der codierenden Sequenz umfassen, wobei diese Teile lang genug sein müssen, um in den Zellen einen antisense-Effekt zu bewirken. Möglich ist auch die Verwendung von DNA- Sequenzen, die einen hohen Grad an Homologie zu den codiereden Sequenzen eines Genprodukts aufweisen, aber nicht vollkommen identisch sind. Bei der Expression von Nucleinsäuremolekülen in Pflanzen kann das synthetisierte Protein in jedem beliebigen Kompartiment der pflanzlichen Zelle lokalisiert sein. Um aber die Lokalisation in einem bestimmten Kompartiment zu erreichen, kann z. B. die codierende Region mit DNA-Sequenzen verknüpft werden, die die Lokalisierung in einem bestimmten Kompartiment gewährleisten. Derartige Sequenzen sind dem Fachmann bekannt (siehe beispielsweise Braun et al., EMBO J.11 (1992), 3219- 3227; Wolter et al., Proc. Natl. Acad. Sci. USA 85 (1988), 846-850; Sonnewald et al., Plant J.1 (1991), 95-106). Die Expression der Nukleinsäuremoleküle kann auch in den Organellen der Pflanzenzellen stattfinden. Die transgenen Pflanzenzellen können nach bekannten Techniken zu ganzen Pflanzen regeneriert werden. Bei den transgenen Pflanzen kann es sich prinzipiell um Pflanzen jeder beliebigen Pflanzenspezies handeln, d.h. sowohl monokotyle als auch dikotyle Pflanzen. So sind transgene Pflanzen erhältlich, die veränderte Eigenschaften durch Überexpression, Suppression oder Inhibierung homologer (= natürlicher) Gene oder Gensequenzen oder Expression heterologer (= fremder) Gene oder Gensequenzen aufweisen.
Vorzugsweise können die erfindungsgemäßen Wirkstoffkombinationen in transgenen Kulturen eingesetzt werden, welche gegen die eingesetzten Wirkstoffe tolerant sind bzw. tolerant gemacht worden sind. Vorzugsweise können die erfindungsgemäßen Wirkstoffkombinationen auch in transgenen Kulturen eingesetzt werden, welche gegen Wuchsstoffe, wie z. B. Dicamba oder gegen Herbizide, die essentielle Pflanzenenzyme, z. B. Acetolactatsynthasen (ALS), EPSP Synthasen, Glutaminsynthasen (GS), Hydoxyphenylpyruvat Dioxygenasen (HPPD), oder Protoporphyrinogen Oxidase (PPO) hemmen, respektive gegen Herbizide aus der Gruppe der Sulfonylharnstoffe, der Glyphosate, Glufosinate oder Benzoylisoxazole und analogen Wirkstoffe, resistent sind. Gegenstand der Erfindung ist deshalb auch ein Verfahren zur Bekämpfung von unerwünschtem Pflanzenwuchs, gegebenenfalls in Nutzpflanzenkulturen, vorzugsweise im Nichtkulturland oder in Plantagenkulturen, dadurch gekennzeichnet, dass man ein oder mehrere Herbizide des Typs (A) mit einem oder mehreren Herbiziden des Typs (B) auf die Schadpflanzen, Pflanzenteile oder Pflanzensamen (Saatgut) davon oder die Anbaufläche appliziert. Gegenstand der Erfindung ist auch die Verwendung der neuen Kombinationen aus Verbindungen (A)+(B) zur Bekämpfung von Schadpflanzen, gegebenenfalls in Nutzpflanzenkulturen, vorzugsweise in Nichtkulturland und Plantagenkulturen, aber auch zur Bekämpfung von Schadpflanzen vor der Aussaat der folgenden Nutzpflanze, wie insbesondere zur Saatvorbereitung ("burn-down Anwendung“). Die erfindungsgemäßen Wirkstoffkombinationen können sowohl als Mischformulierungen der zwei Komponenten, gegebenenfalls mit weiteren Wirkstoffen, Zusatzstoffen und/oder üblichen Formulierungshilfsmitteln vorliegen, die dann in üblicher Weise mit Wasser verdünnt zur Anwendung gebracht werden, oder als sogenannte Tankmischungen durch gemeinsame Verdünnung der getrennt formulierten oder partiell getrennt formulierten Komponenten mit Wasser hergestellt werden. Die Verbindungen (A) und (B) oder deren Kombinationen können auf verschiedene Art formuliert werden, je nachdem welche biologischen und/oder chemisch-physikalischen Parameter vorgegeben sind. Als allgemeine Formulierungsmöglichkeiten kommen beispielsweise in Frage: Spritzpulver (WP), wasserlösliche Pulver (SP), emulgierbare Konzentrate (EC), wasserlösliche Konzentrate, wäßrige Lösungen (SL), Emulsionen (EW) wie Öl-in-Wasser- und Wasser-in-Öl-Emulsionen, versprühbare Lösungen oder Emulsionen, Dispersionen auf Öl- oder Wasserbasis, Öldispersionen (OD), Suspoemulsionen, Suspensionskonzentrate (SC), ölmischbare Lösungen, Kapselsuspensionen (CS), Stäubemittel (DP), Beizmittel, Granulate zur Boden- oder Streuapplikation, Granulate (GR) in Form von
Mikro-, Sprüh-, Aufzugs- und Adsorptionsgranulaten, wasserdispergierbare Granulate (WG), wasserlösliche Granulate (SG), ULV-Formulierungen, Mikrokapseln oder Wachse. Gegenstand der Erfindung sind deshalb auch herbizide und pflanzenwachstumsregulierende Mittel, welche die erfindungsgemäßen Wirkstoffkombinationen enthalten. Die einzelnen Formulierungstypen sind im Prinzip bekannt und werden beispielsweise beschrieben in: Winnacker-Küchler, "Chemische Technologie", Band 7, C. Hanser Verlag München, 4. Aufl.1986; van Valkenburg, "Pesticides Formulations", Marcel Dekker N.Y., 1973; K. Martens, "Spray Drying Handbook", 3rd Ed.1979, G. Goodwin Ltd. London. Die notwendigen Formulierungshilfsmittel wie Inertmaterialien, Tenside, Lösungsmittel und weitere Zusatzstoffe sind ebenfalls bekannt und werden beispielsweise beschrieben in: Watkins, "Handbook of Insecticide Dust Diluents and Carriers", 2nd Ed., Darland Books, Caldwell N.J.; H.v. Olphen, "Introduction to Clay Colloid Chemistry"; 2nd Ed., J. Wiley & Sons, N.Y. Marsden, "Solvents Guide", 2nd Ed., Interscience, N.Y.1963; McCutcheon's, "Detergents and Emulsifiers Annual", MC Publ. Corp., Ridegewood N.J.; Sisley and Wood, "Encyclopedia of Surface Active Egents", Chem. Publ. Co. Inc., N.Y.1964; Schönfeldt, "Grenzflächenaktive Äthylenoxidaddukte", Wiss. Verlagsgesellschaft, Stuttgart 1976, Winnacker-Küchler, "Chemische Technologie", Band 7, C. Hanser Verlag München, 4. Aufl. 1986. Auf der Basis dieser Formulierungen lassen sich auch Kombinationen mit anderen pestizid wirksamen Stoffen, wie anderen Herbiziden, Fungiziden, Insektiziden oder anderen Schädlingsbekämpfungsmitteln (z. B. Akarizide, Nematizide, Molluskizide, Rodentizide, Aphizide, Avizide, Larvizide, Ovizide, Bakterizide, Viruzide, etc.), sowie Safenern, Düngemitteln und/oder Wachstumsregulatoren herstellen, z.B. in Form einer Fertigformulierung oder als Tankmix. Spritzpulver sind in Wasser gleichmäßig dispergierbare Präparate, die neben dem Wirkstoff außer einem Verdünnungs- oder Inertstoff noch Tenside ionischer und/oder nichtionischer Art (Netzmittel, Dispergiermittel), z.B. polyoxethylierte Alkylphenole, polyoxethylierte Fettalkohole, polyoxethylierte Fettamine, Fettalkoholpolyglykolethersulfate, Alkansulfonate, Alkylbenzolsulfonate, ligninsulfonsaures Natrium, 2,2'-dinaphthylmethan-6,6'-disulfonsaures Natrium, dibutylnaphthalin-sulfonsaures Natrium oder auch oleoylmethyltaurinsaures Natrium enthalten. Zur Herstellung der Spritzpulver werden die herbiziden Wirkstoffe beispielsweise in üblichen Apparaturen wie Hammermühlen, Gebläsemühlen und Luftstrahlmühlen feingemahlen und gleichzeitig oder anschließend mit den Formulierungshilfsmitteln vermischt.
Emulgierbare Konzentrate werden durch Auflösen des Wirkstoffs in einem organischen Lösungsmittel, z.B. Butanol, Cyclohexanon, Dimethylformamid, Xylol oder auch höhersiedenden Aromaten oder Kohlenwasserstoffe oder Mischungen der organischen Lösungsmittel unter Zusatz von einem oder mehreren Tensiden ionischer und/oder nichtionischer Art (Emulgatoren) hergestellt. Als Emulgatoren können beispielsweise verwendet werden: Alkylarylsulfonsaure Calcium-Salze wie Ca- Dodecylbenzolsulfonat oder nichtionische Emulgatoren wie Fettsäurepolyglykolester, Alkylarylpolyglykolether, Fettalkoholpolyglykolether, Propylenoxid-Ethylenoxid- Kondensationsprodukte, Alkylpolyether, Sorbitanester wie z.B. Sorbitanfettsäureester oder wie z. B. Polyoxyethylensorbitanfettsäureester. Stäubemittel erhält man durch Vermahlen des Wirkstoffs mit fein verteilten festen Stoffen, z.B. Talkum, natürlichen Tonen, wie Kaolin, Bentonit und Pyrophyllit, oder Diatomeenerde. Suspensionskonzentrate können auf Wasser- oder Ölbasis sein. Sie können beispielsweise durch Naß-Vermahlung mittels handelsüblicher Perlmühlen und gegebenenfalls Zusatz von Tensiden, wie sie z.B. oben bei den anderen Formulierungstypen bereits aufgeführt sind, hergestellt werden. Emulsionen, z.B. Öl-in-Wasser-Emulsionen (EW), lassen sich beispielsweise mittels Rührern, Kolloidmühlen und/oder statischen Mischern unter Verwendung von wäßrigen organischen Lösungsmitteln und gegebenenfalls Tensiden, wie sie z.B. oben bei den anderen Formulierungstypen bereits aufgeführt sind, herstellen. Granulate können entweder durch Verdüsen des Wirkstoffes auf adsorptionsfähiges, granuliertes Inertmaterial hergestellt werden oder durch Aufbringen von Wirkstoffkonzentraten mittels Klebemitteln, z.B. Polyvinylalkohol, polyacrylsaurem Natrium oder auch Mineralölen, auf die Oberfläche von Trägerstoffen wie Sand, Kaolinite oder von granuliertem Inertmaterial. Auch können geeignete Wirkstoffe in der für die Herstellung von Düngemittelgranulaten üblichen Weise - gewünschtenfalls in Mischung mit Düngemitteln - granuliert werden. Wasserdispergierbare Granulate werden in der Regel nach Verfahren wie Sprühtrocknung, Wirbelbett- Granulierung, Teller-Granulierung, Mischung mit Hochgeschwindigkeitsmischern und Extrusion ohne festes Inertmaterial hergestellt. Die agrochemischen Zubereitungen enthalten in der Regel 0,1 bis 99 Gewichtsprozent, insbesondere 0,2 bis 95 Gew.-%, Wirkstoffe der Typen (A) und/oder (B), wobei je nach Formulierungsart folgende Konzentrationen üblich sind:
In Spritzpulvern beträgt die Wirkstoffkonzentration z.B. etwa 10 bis 95 Gew.-%, der Rest zu 100 Gew.- % besteht aus üblichen Formulierungsbestandteilen. Bei emulgierbaren Konzentraten kann die Wirkstoffkonzentration etwa 1 bis 90 Gew.-%, betragen, vorzugsweise 5 bis 80 Gewichtsprozent. Staubförmige Formulierungen enthalten meistens 5 bis 20 Gew.-% an Wirkstoff, versprühbare Lösungen enthalten etwa 0.05 bis 80, vorzugsweise 2 bis 50 Gewichtsprozent (Gew.-%) Wirkstoff. Bei Granulaten wie dispergierbaren Granulaten hängt der Wirkstoffgehalt zum Teil davon ab, ob die wirksame Verbindung flüssig oder fest vorliegt und welche Granulierhilsmittel und Füllstoffe verwendet werden. In der Regel liegt der Gehalt bei den in Wasser dispergierbaren Granulaten zwischen 1 und 95 Gew.-%, vorzugsweise zwischen 10 und 80 Gew.-%. Daneben enthalten die genannten Wirkstofformulierungen gegebenenfalls die jeweils üblichen Haft-, Netz-, Dispergier-, Emulgier-, Penetrations-, Konservierungs-, Frostschutz- und Lösungsmittel, Füll-, Farb- und Trägerstoffe, Entschäumer, Verdunstungshemmer und Mittel, die den pH-Wert oder die Viskosität beeinflussen. Zur Anwendung werden die in handelsüblicher Form vorliegenden Formulierungen gegebenenfalls in üblicher Weise verdünnt, z.B. bei Spritzpulvern, emulgierbaren Konzentraten, Dispersionen und wasserdispergierbaren Granulaten mittels Wasser. Staubförmige Zubereitungen, Boden- bzw. Streugranulate, sowie versprühbare Lösungen werden vor der Anwendung üblicherweise nicht mehr mit weiteren inerten Stoffen verdünnt. Die Wirkstoffe können auf die Pflanzen, Pflanzenteile, Pflanzensamen oder die Anbaufläche (Ackerboden) ausgebracht werden, vorzugsweise auf die grünen Pflanzen und Pflanzenteile und gegebenenfalls zusätzlich auf den Ackerboden. Eine Möglichkeit der Anwendung ist die gemeinsame Ausbringung der Wirkstoffe in Form von Tankmischungen, wobei die optimal formulierten konzentrierten Formulierungen der Einzelwirkstoffe gemeinsam im Tank mit Wasser gemischt und die erhaltene Spritzbrühe ausgebracht wird. Eine gemeinsame herbizide Formulierung der erfindungsgemäßen Kombination an Wirkstoffen (A) und (B) hat den Vorteil der leichteren Anwendbarkeit, weil die Mengen der Komponenten bereits im richtigen Verhältnis zueinander eingestellt sind. Außerdem können die Hilfsmittel in der Formulierung aufeinander optimal abgestimmt werden, während ein Tank-mix von unterschiedlichen Formulierungen unerwünschte Kombinationen von Hilfstoffen ergeben kann.
A. Formulierungsbeispiele allgemeiner Art a) Ein Stäubemittel wird erhalten, indem man 10 Gewichsteile (= Gew.-Teile) eines Wirkstoffs (A) oder (B) oder eines Wirkstoffgemischs (A) + (B) (und gegebenenfalls weiterer Wirkstoffkomponenten) und/oder deren Salze und 90 Gew.-Teile Talkum als Inertstoff mischt und in einer Schlagmühle zerkleinert. b) Ein in Wasser leicht dispergierbares, benetzbares Pulver wird erhalten, indem man 25 Gew.- Teile eines Wirkstoffs/Wirkstoffgemischs, 64 Gew.-Teile kaolinhaltigen Quarz als Inertstoff, 10 Gew.- Teile ligninsulfonsaures Kalium und 1 Gew.-Teil oleoylmethyltaurinsaures Natrium als Netz- und Dispergiermittel mischt und in einer Stiftmühle mahlt. c) Ein in Wasser leicht dispergierbares Dispersionskonzentrat wird erhalten, indem man 20 Gew.- Teile eines Wirkstoffs/Wirkstoffgemischs mit 6 Gew.-Teilen Alkylphenolpolyglykolether (®Triton X 207), 3 Gew.-Teilen Isotridecanolpolyglykolether (8 EO) und 71 Gew.-Teilen paraffinischem Mineralöl (Siedebereich z.B. ca.255 bis 277 °C) mischt und in einer Reibkugelmühle auf eine Feinheit von unter 5 Mikron vermahlt. d) Ein emulgierbares Konzentrat wird erhalten aus 15 Gew.-Teilen eines Wirkstoffs/Wirkstoffgemischs, 75 Gew.-Teilen Cyclohexanon als Lösemittel und 10 Gew.-Teilen oxethyliertem Nonylphenol als Emulgator. e) Ein in Wasser dispergierbares Granulat wird erhalten indem man 75 Gew.-Teile eines Wirkstoffs/Wirkstoffgemischs, 10 Gew.-Teile ligninsulfonsaures Calcium, 5 Gew.-Teile Natriumlaurylsulfat, 3 Gew.-Teile Polyvinylalkohol und 7 Gew.-Teile Kaolin mischt, auf einer Stiftmühle mahlt und das Pulver in einem Wirbelbett durch Aufsprühen von Wasser als Granulierflüssigkeit granuliert. f) Ein in Wasser dispergierbares Granulat wird auch erhalten, indem man 25 Gew.-Teile eines Wirkstoffs/Wirkstoffgemischs, 5 Gew.-Teile 2,2'-dinaphthylmethan-6,6'-disulfonsaures Natrium, 2 Gew.-Teile oleoylmethyltaurinsaures Natrium, 1 Gew.-Teil Polyvinylalkohol, 17 Gew.-Teile Calciumcarbonat und
50 Gew.-Teile Wasser auf einer Kolloidmühle homogenisiert und vorzerkleinert, anschließend auf einer Perlmühle mahlt und die so erhaltene Suspension in einem Sprühturm mittels einer Einstoffdüse zerstäubt und trocknet. B. Biologische Beispiele Bei der Anwendung der erfindungsgemäßen Kombinationen werden häufig herbizide Wirkungen an einer Schadpflanzenspezies beobachtet, die die formale Summe der Wirkungen der enthaltenen Herbizide bei alleiniger Applikation übertreffen. Alternativ kann in manchen Fällen beobachtet werden, dass eine geringere Aufwandmenge für die Herbizid-Kombination benötigt wird, um im Vergleich zu den Einzelpräparaten dieselbe Wirkung bei einer Schadpflanzenspezies zu erzielen. Derartige Wirkungssteigerungen bzw. Effektivitätssteigerungen oder Einsparungen an Aufwandmenge sind ein starker Hinweis auf synergistische Wirkung. Wenn die beobachteten Wirkungswerte bereits die formale Summe der Werte zu den Versuchen mit Einzelapplikationen übertreffen, dann übertreffen sie den Erwartungswert nach Colby ebenfalls, der sich nach folgender Formel errechnet und ebenfalls als Hinweis auf Synergismus angesehen wird (vgl. S. R. Colby; in Weeds 15 (1967) S.20 bis 22): EC = A+B - (A·B/100) Dabei bedeuten: A = Wirkung des Wirkstoffs (A) in % bei einer Aufwandmenge von a [g a.i./ha]; B = Wirkung des Wirkstoffs (B) in % bei einer Aufwandmenge von b [g a.i./ha]; EC = Erwartungswert der Wirkung der Kombination (A)+(B) in % bei der kombinierten Aufwandmenge a+b [g a.i./ha]. Die beobachteten Werte (EA) der Versuche zeigen bei geeigneten niedrigen Dosierungen eine Wirkung der Kombinationen, die über den Erwartungswerten nach Colby (EC)liegen (∆). Unkrautwirkung im Nachauflauf Samen von mono- und dikotylen Unkräutern wurden in Töpfen in sandigem Lehmboden ausgelegt, mit Erde abgedeckt und im Gewächshaus unter guten Wachstumsbedingungen (Temperatur, Luftfeuchtigkeit, Wasserversorgung) angezogen. Zwei bis drei Wochen nach der Aussaat wurden die Versuchspflanzen im Zweiblatt- bis Vierblatt-Stadium mit den erfindungsgemäßen Mitteln behandelt. Die als Spritzpulver bzw. als Emulsionskonzentrate formulierten erfindungsgemäßen Mittel wurden in
verschiedenen Dosierungen mit einer Wasseraufwandmenge von umgerechnet 300 l/ha auf die grünen Pflanzenteile gesprüht. Nach 3 Wochen Standzeit der Versuchspflanzen im Gewächshaus unter optimalen Wachstumsbedingungen wurde die Wirkung der Präparate optisch im Vergleich zu unbehandelten Kontrollen bonitiert. Dabei wurden häufig Wirkungen der erfindungsgemäßen Kombinationen beobachtet, die die formale Summe der Wirkungen bei Einzelapplikation der Herbizide übertreffen. 100 % Wirkung bedeutet eine vollständige Kontrolle des jeweilig getesteten Unkrauts. 0% Wirkung bedeutet gar keine Kontrolle des jeweilig getesteten Unkrauts. Die biologischen Ergebnisse der erfindungsgemäßen Zusammensetzungen sind in den nachfolgenden Tabellen 3.1 –3.12 zusammengefasst. Die Summe der Wirkungen der Einzelapplikationen ist unter EA angegeben; Erwartungswerte nach Colby sind jeweils unter EC angegeben; Der Boniturzeitraum ist in Tagen nach der Applikation (DAT) angegeben. Tabelle 3.1: Synergistischer Effekt (∆) für herbizide binäre Zusammensetzungen im Nachauflauf bei Applikation auf Amaranthus palmeri (AMAPA)
where R E 1 is halogen, (C 1 -C 4 )alkyl, methoxy, nitro, cyano, CF 3 , OCF 3 Y E , ZE is independently O or S, n E is an integer from 0 to 4, R E 2 (C 1 -C 16 )alkyl, (C 2 -C 6 )alkenyl, (C 3 -C 6 )cycloalkyl, aryl; benzyl, halobenzyl, R E 3 is hydrogen or (C 1 -C 6 )alkyl. S11) Active substances of the type of oxyimino compounds (S11), which are known as seed dressings, such as. B. "Oxabetrinil" ((Z)-1,3-dioxolan-2-ylmethoxyimino(phenyl)acetonitrile) (S11-1) known as a seed dressing safener for millet against damage from metolachlor, "Fluxofenim" (1- (4-Chlorophenyl)-2,2,2-trifluoro-1-ethanone-O-(1,3-dioxolan-2-ylmethyl)-oxime) (S11-2) used as a seed dressing safener for sorghum against damage from metolachlor, and "Cyometrinil" or "CGA-43089" ((Z)-cyanomethoxyimino(phenyl)acetonitrile) (S11-3), which is known as a seed dressing safener for sorghum against damage from metolachlor. S12) Active ingredients from the class of isothiochromanone (S12), such as methyl [(3-oxo-1H-2-benzothiopyran-4(3H)-ylidene)methoxy]acetate (CAS Reg. No. 205121-04-6 ) (S12-1) and related compounds from WO-A-1998/13361. S13) One or more compounds from group (S13): "Naphthalic anhydride" (1,8-naphthalenedicarboxylic acid anhydride) (S13-1), known as a seed dressing safener for corn against damage from thiocarbamate herbicides, "Fenclorim" (4.6 -dichloro-2-phenylpyrimidine) (S13-2), known as a safener for pretilachlor in seeded rice, "Flurazole" (Benzyl 2-chloro-4-trifluoromethyl-1,3-thiazole-5-carboxylate) (S13-3) known as a seed dressing safener for sorghum against damage from alachlor and metolachlor, "CL 304415" (CAS-Reg.Nr.31541-57-8) (4-carboxy-3,4-dihydro-2H-1-benzopyran-4-acetic acid) (S13-4) from American Cyanamid, used as a safener for corn against Damage caused by imidazolinones is known, "MG 191" (CAS Reg. No. 96420-72-3) (2-dichloromethyl-2-methyl-1,3-dioxolane) (S13-5) from Nitrokemia, which is used as a safener known for corn, "MG 838" (CAS Reg. No. 133993-74-5) (2-propenyl 1-oxa-4-azaspiro[4.5]decane-4-carbodithioate) (S13-6) from Nitrokemia "Disulfoton" (O,O-Diethyl S-2-ethylthioethyl phosphorodithioate) (S13-7), "Dietholate" (O,O-Diethyl-O-phenyl phosphorothioate) (S13-8), "Mephenate" (4-chlorophenyl- methyl carbamate) (S13-9). S14) active ingredients which, in addition to having a herbicidal action against harmful plants, also have a safener effect on crop plants such as rice, such as, for. B. "Dimepiperate" or "MY-93" (S-1-methyl-1-phenylethyl-piperidine-1-carbothioate), which is known as a safener for rice against damage from the herbicide Molinate, "Daimuron" or "SK 23" (1-(1-Methyl-1-phenylethyl)-3-p-tolyl-urea), known as a safener for rice against damage from the herbicide imazosulfuron, "Cumyluron" = "JC-940" (3-(2- chlorophenylmethyl)-1-(1-methyl-1-phenylethyl)urea, see JP-A-60087254) known as a safener for rice against damage from some herbicides, "methoxyphenone" or "NK 049" (3.3 '-dimethyl-4-methoxy-benzophenone) known as a safener for rice against damage from some herbicides, "CSB" (1-bromo-4-(chloromethylsulfonyl)benzene) from Kumiai, (CAS Reg.No.54091- 06-4), which is known as a safener against damage from some herbicides in rice. S15) compounds of the formula (S15) or their tautomers, as described in WO-A-2008/131861 and WO-A-2008/131860, in which RH 1 is a (C 1 -C 6 )haloalkyl radical and R H 2 is hydrogen or halogen and R H 3 , R H 4 independently of one another hydrogen, (C 1 -C 16 )alkyl, (C 2 -C 16 )alkenyl or (C 2 -C 16 )alkynyl, each of the latter 3 radicals being unsubstituted or substituted by one or more radicals from the group halogen, Hydroxy, cyano, (C 1 -C 4 )alkoxy, (C 1 -C 4 )haloalkoxy, (C 1 -C 4 )alkylthio, (C 1 -C 4 )alkylamino, di[(C 1 -C 4 )alkyl ]-amino, [(C 1 -C 4 )alkoxy]-carbonyl, [(C 1 -C 4 )haloalkoxy]-carbonyl, (C 3 -C 6 )cycloalkyl which is unsubstituted or substituted, phenyl which is unsubstituted or is substituted, and heterocyclyl which is unsubstituted or substituted, or (C 3 -C 6 )cycloalkyl, (C 4 -C 6 )cycloalkenyl, (C 3 -C 6 )cycloalkyl substituted on one side of the ring with is fused to a 4 to 6-membered saturated or unsaturated carbocyclic ring, or (C 4 -C 6 )cycloalkenyl fused on one side of the ring with a 4 to 6-membered saturated or unsaturated carbocyclic ring, each of the latter 4 radicals being unsubstituted or substituted by one or more radicals from the group halogen, hydroxy, cyano, ( C 1 -C 4 )alkyl, (C 1 -C 4 )haloalkyl, (C 1 -C 4 )alkoxy, (C 1 -C 4 )haloalkoxy, (C 1 -C 4 )alkylthio, (C 1 -C 4 ) . )alkylamino, di[(C 1 -C 4 )alkyl]amino, [(C 1 -C 4 )alkoxy]carbonyl, [(C 1 -C 4 )haloalkoxy]carbonyl, (C 3 -C 6 ) cycloalkyl that is unsubstituted or substituted, phenyl that is unsubstituted or substituted, and heterocyclyl that is unsubstituted or substituted, substituted, or R H 3 is (C 1 -C 4 )alkoxy, (C 2 -C 4 )alkenyloxy, (C 2 -C 6 )alkynyloxy or (C 2 -C 4 )haloalkoxy and RH 4 is hydrogen or (C 1 -C 4 )-alkyl or RH 3 and RH 4 together with the directly bonded N atom form a four- to eight-membered heterocyclic ring which, in addition to the N atom, also has further hetero ring atoms, preferably up to two further hetero ring atoms from the group N, O and S may contain and which is unsubstituted or by one or more radicals from the group consisting of halogen, cyano, nitro, (C 1 -C 4 )alkyl, (C 1 -C 4 )haloalkyl, (C 1 -C 4 )alkoxy, (C 1 -C 4 )haloalkoxy and (C 1 -C 4 )alkylthio is substituted. S16) active substances which are primarily used as herbicides but also have a safener effect on crop plants, e.g. B. (2,4-Dichlorophenoxy)acetic acid (2,4-D), (4-Chlorophenoxy)acetic acid, (R,S)-2-(4-Chloro-o-tolyloxy)propionic acid (Mecoprop), 4-( 2,4-dichlorophenoxy)butyric acid (2,4-DB), (4-chloro-o-tolyloxy)acetic acid (MCPA), 4-(4-chloro-o-tolyloxy)butyric acid, 4-(4-chlorophenoxy)butyric acid , 3,6-dichloro-2-methoxybenzoic acid (dicamba), 1-(ethoxycarbonyl)ethyl 3,6-dichloro-2-methoxybenzoate (lactidichloro-ethyl). Preferred safeners in combination with the herbicide combinations according to the invention are: cloquintocet-mexyl, cyprosulfamide, fenchlorazol-ethyl ester, isoxadifen-ethyl, mefenpyr-diethyl, fenclorim, cumyluron, S4-1 and S4-5, and particularly preferred safeners are: cloquintocet-mexyl, cyprosulfamide, isoxadifen-ethyl and mefenpyr-diethyl. The herbicide combinations according to the invention may contain other components, e.g. B. plant growth regulators or other active ingredients against harmful organisms such as harmful plants, phytotoxic animals or phytotoxic fungi, in particular active ingredients from the group of herbicides, fungicides, insecticides, acaricides, nematicides, miticides and related substances. Examples of plant growth regulators as possible mixing partners are: Acibenzolar, acibenzolar-S-methyl, 5-aminolevulinic acid, ancymidol, 6-benzylaminopurine, brassinolide, catechin, chlormequat chloride, cloprop, cyclanilide, 3-(cycloprop-1-enyl)propionic acid, daminozide, dazomet, n-decanol, dikegulac, dikegulac-sodium, endothal, endothal-dipotassium, -disodium, and mono(N,N-dimethylalkylammonium), ethephon, flumetralin, flurenol, flurenol-butyl, flurprimidol, forchlorfenuron, gibberellic acid, inabenfide, indol-3-acetic acid (IAA), 4-indol-3-ylbutyric acid, isoprothiolane, probenazole, jasmonic acid, jasmonic acid methyl ester, maleic hydrazide, mepiquat chloride, 1-methylcyclopropene, 2-(1-naphthyl)acetamide, 1- naphthylacetic acid, 2- naphthyloxyacetic acid, nitrophenolate-mixture, 4-oxo-4[(2-phenylethyl)amino]butyric acid, paclobutrazol, N- phenylphthalamic acid, prohexadione, prohexadione-calcium, prohydrojasmone, salicylic acid, strigolactone, tecnazene, thidiazuron, triacontanol, trinexapac, trinexapac-ethyl, tsitodef, uniconazole, uniconazole-P. Fungicidally active compounds which can be used in combination with the herbicide combinations according to the invention are preferably commercially available active compounds, for example (analogously to the herbicides, the compounds are generally referred to by their common names, here in the usual English notation): 1) Inhibitors of ergosterol Biosynthesis, for example (1.001) cyproconazole, (1.002) difenoconazole, (1.003) epoxiconazole, (1.004) fenhexamide, (1.005) fenpropidin, (1.006) fenpropimorph, (1.007) fenpyrazamine, (1.008) fluquinconazole, (1.009) flutriafol, (1.010 ) imazalil, (1.011) imazalil sulfate, (1.012) ipconazole, (1.013) metconazole, (1.014) myclobutanil, (1.015) paclobutrazole, (1.016) prochloraz, (1.017) propiconazole, (1.018) prothioconazole, (1.019) pyrisoxazole, ( 1.020) Spiroxamine, (1.021) Tebuconazole, (1.022) Tetraconazole, (1.023) Triadimenol, (1.024) Tridemorph, (1.025) Triticonazole, (1.026) (1R,2S,5S)-5-(4-Chlorobenzyl)-2- (chloromethyl)-2-methyl-1-(1H-1,2,4-triazole- 1-ylmethyl)cyclopentanol, (1,027) (1S,2R,5R)-5-(4-Chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triazole-1- ylmethyl)cyclopentanol, (1,028) (2R)-2-(1-Chlorocyclopropyl)-4-[(1R)-2,2-dichlorocyclopropyl]-1-(1H-1,2,4-triazol-1-yl) butan-2-ol (1.029) (2R)-2-(1-Chlorocyclopropyl)-4-[(1S)-2,2-dichlorocyclopropyl]-1-(1H-1,2,4-triazol-1-yl )butan-2-ol, (1,030) (2R)-2-[4-(4-chlorophenoxy)-2-(trifluoromethyl)phenyl]-1-(1H-1,2,4-triazol-1-yl) propan-2-ol, (1.031) (2S)-2-(1-Chlorocyclopropyl)-4-[(1R)-2,2-dichlorocyclopropyl]-1-(1H-1,2,4-triazole-1- yl)butan-2-ol, (1,032) (2S)-2-(1-Chlorocyclopropyl)-4-[(1S)-2,2-dichlorocyclopropyl]-1-(1H-1,2,4-triazole- 1-yl)butan-2-ol, (1.033)(2S)-2-[4-(4-chlorophenoxy)-2-(trifluoromethyl)phenyl]-1-(1H-1,2,4-triazole-1 -yl)propan-2-ol, (1.034) (R)-[3-(4-Chloro-2-fluorophenyl)-5-(2,4-difluorophenyl)-1,2-oxazol-4-yl]( pyridin-3-yl)methanol, (1.035) (S)-[3-(4-Chloro-2-fluorophenyl)-5-(2,4-difluorophenyl)-1,2-oxazol-4-yl](pyridine -3-yl)methanol, (1.036) [3-(4-Chloro-2-fluorophenyl)-5 -(2,4-difluorophenyl)-1,2-oxazol-4-yl](pyridin-3-yl)methanol, (1.037) 1-({(2R,4S)-2-[2-chloro-4- (4-chlorophenoxy)phenyl]-4-methyl-1,3-dioxolan-2-yl}methyl)-1H-1,2,4-triazole, (1.038) 1-({(2S,4S)-2- [2-Chloro-4-(4-chlorophenoxy)phenyl]-4-methyl-1,3-dioxolan-2-yl}methyl)-1H-1,2,4-triazole, (1.039) 1-{[3 -(2-Chlorophenyl)-2-(2,4-difluorophenyl)oxiran-2-yl]methyl}-1H-1,2,4-triazol-5-yl-thiocyanate, (1.040) 1-{[rel( 2R,3R)-3-(2-Chlorophenyl)-2-(2,4-difluorophenyl)oxiran-2-yl]methyl}-1H-1,2,4-triazol-5-yl thiocyanate, (1.041) 1-{[rel(2R,3S)-3-(2-chlorophenyl)-2-(2,4-difluorophenyl)oxirane-2- yl]methyl}-1H-1,2,4-triazol-5-yl thiocyanate, (1.042) 2-[(2R,4R,5R)-1-(2,4-dichlorophenyl)-5-hydroxy- 2 ,6,6-trimethylheptan-4-yl]-2,4-dihydro-3H-1,2,4-triazole-3-thione, (1,043) 2-[(2R,4R,5S)-1-(2 ,4-Dichlorophenyl)-5-hydroxy-2,6,6-trimethylheptan-4-yl]-2,4-dihydro-3H-1,2,4-triazole-3-thione, (1.044) 2-[( 2R,4S,5R)-1-(2,4-Dichlorophenyl)-5-hydroxy-2,6,6-trimethylheptan-4-yl]-2,4-dihydro-3H-1,2,4-triazole- 3-thione, (1,045) 2-[(2R,4S,5S)-1-(2,4-dichlorophenyl)-5-hydroxy-2,6,6-trimethylheptan-4-yl]-2,4-dihydro -3H-1,2,4-triazole-3-thione, (1,046) 2-[(2S,4R,5R)-1-(2,4-dichlorophenyl)-5-hydroxy-2,6,6-trimethylheptane -4-yl]-2,4-dihydro-3H-1,2,4-triazole-3-thione, (1,047) 2-[(2S,4R,5S)-1-(2,4-dichlorophenyl)- 5-hydroxy-2,6,6-trimethylheptan-4-yl]-2,4-dihydro-3H-1,2,4-triazole-3-thione, (1,048) 2-[(2S,4S,5R) -1-(2,4-Dichlorophenyl)-5-hydroxy-2,6,6-trimethylheptan-4-yl]-2,4-dihydro-3H-1,2,4-triazole-3-thione, (1.049 ) 2-[(2S,4S,5S)-1-(2,4-dichlorophenyl)-5-hydroxy-2,6,6-trimethylheptan-4-yl]-2,4-dihydro-3H-1,2 ,4-t riazole-3-thione, (1,050) 2-[1-(2,4-dichlorophenyl)-5-hydroxy-2,6,6-trimethylheptan-4-yl]-2,4-dihydro-3H-1,2 ,4-triazole-3-thione, (1.051) 2-[2-Chloro-4-(2,4-dichlorophenoxy)phenyl]-1-(1H-1,2,4-triazol-1-yl)propan- 2-ol, (1.052) 2-[2-Chloro-4-(4-chlorophenoxy)phenyl]-1-(1H-1,2,4-triazol-1-yl)butan-2-ol, (1.053) 2-[4-(4-Chlorophenoxy)-2-(trifluoromethyl)phenyl]-1-(1H-1,2,4-triazol-1-yl)butan-2-ol, (1.054) 2-[4- (4-Chlorophenoxy)-2-(trifluoromethyl)phenyl]-1-(1H-1,2,4-triazol-1-yl)pentan-2-ol, (1.055) 2-[4-(4-Chlorophenoxy) -2-(trifluoromethyl)phenyl]-1-(1H-1,2,4-triazol-1-yl)propan-2-ol, (1,056) 2-{[3-(2-chlorophenyl)-2-( 2,4-difluorophenyl)oxiran-2-yl]methyl}-2,4-dihydro-3H-1,2,4-triazole-3-thione, (1.057) 2-{[rel(2R,3R)-3 -(2-Chlorophenyl)-2-(2,4-difluorophenyl)oxiran-2-yl]methyl}-2,4-dihydro-3H-1,2,4-triazole-3-thione, (1.058) 2- {[rel(2R,3S)-3-(2-Chlorophenyl)-2-(2,4-difluorophenyl)oxiran-2-yl]methyl}-2,4-dihydro-3H-1,2,4-triazole -3-thione, (1.059) 5-(4-Chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triaz ol-1-ylmethyl)cyclopentanol, (1,060) 5-(allylsulfanyl)-1-{[3-(2-chlorophenyl)-2-(2,4-difluorophenyl)oxiran-2-yl]methyl}-1H-1 ,2,4-triazole, (1.061) 5-(Allylsulfanyl)-1-{[rel(2R,3R)-3-(2-chlorophenyl)-2-(2,4-difluorophenyl)oxiran-2-yl] methyl}-1H-1,2,4-triazole, (1.062) 5-(Allylsulfanyl)-1-{[rel(2R,3S)-3-(2-chlorophenyl)-2-(2,4-difluorophenyl) oxiran-2-yl]methyl}-1H-1,2,4-triazole, (1.063) N'-(2,5-dimethyl-4-{[3-(1,1,2,2-tetrafluoroethoxy)phenyl ]sulfanyl}phenyl)-N-ethyl-N-methylimidoformamide, (1.064) N'-(2,5-dimethyl-4-{[3-(2,2,2-trifluoroethoxy)phenyl]sulfanyl}phenyl)-N -ethyl-N-methylimidoformamide, (1.065) N'-(2,5-dimethyl-4-{[3-(2,2,3,3-tetrafluoropropoxy)phenyl]sulfanyl}phenyl)-N-ethyl-N- methylimidoformamide, (1.066) N'-(2,5-dimethyl-4-{[3-(pentafluoroethoxy)phenyl]sulfanyl}phenyl)-N-ethyl-N-methylimidoformamide, (1.067) N'-(2,5- dimethyl-4-{3-[(1,1,2,2-tetrafluoroethyl)sulfanyl]phenoxy}phenyl)-N-ethyl-N-methylimidoformamide, (1,068) N'-(2,5-dimethyl-4-{ 3-[(2,2,2-trifluoroethyl)sulfanyl]phenoxy}p phenyl)-N-ethyl-N-methylimidoformamide, (1.069) N'-(2,5-dimethyl-4-{3-[(2,2,3,3- tetrafluoropropyl)sulfanyl]phenoxy}phenyl)-N- ethyl-N-methylimidoformamide, (1.070) N'-(2,5-dimethyl-4-{3-[(pentafluoroethyl)sulfanyl]phenoxy}phenyl)-N-ethyl-N-methylimidoformamide, (1.071) N'-( 2,5-dimethyl-4-phenoxyphenyl)-N-ethyl-N-methylimidoformamide, (1.072) N'-(4-{[3-(Difluoromethoxy)phenyl]sulfanyl}-2,5-dimethylphenyl)-N-ethyl -N-methylimidoformamide, (1.073) N'-(4-{3-[(Difluoromethyl)sulfanyl]phenoxy}-2,5-dimethylphenyl)-N-ethyl-N-methylimidoformamide, (1.074) N'-[5-Bromo-6-(2,3-dihydro-1H-inden-2-yloxy)-2-methylpyridin-3-yl]-N-ethyl-N-methylimidoformamide, (1.075) N '-{4-[(4,5-Dichloro-1,3-thiazol-2-yl)oxy]-2,5-dimethylphenyl}-N-ethyl-N-methylimidoformamide, (1.076) N'-{5- Bromo-6-[(1R)-1-(3,5-difluorophenyl)ethoxy]-2-methylpyridin-3-yl}-N-ethyl-N-methylimidoformamide, (1.077) N'-{5-Bromo-6 -[(1S)-1-(3,5-difluorophenyl)ethoxy]-2-methylpyridin-3-yl}-N-ethyl-N-methylimidoformamide, (1.078) N'-{5-Bromo-6-[( cis-4-isopropylcyclohexyl)oxy]-2-methylpyridin-3-yl}-N-ethyl-N-methylimidoformamide, (1.079) N'-{5-Bromo-6-[(trans-4-isopropylcyclohexyl)oxy]- 2-methylpyridin-3-yl}-N-ethyl-N-methylimidoformamide, (1,080) N'-{5-Bromo-6-[1-(3,5-difluorophenyl)ethoxy]-2-methylpyridin-3-yl }-N-ethyl-N-methylimidoformamide, (1.081) mefentrifluconazole, (1.082) ipfentrifluconazole. 2) Respiratory chain inhibitors at complex I or II, for example (2.001) benzovindiflupyr, (2.002) bixafen, (2.003) boscalid, (2.004) carboxine, (2.005) fluopyram, (2.006) flutolanil, (2.007) fluxapyroxad, (2.008) furametpyr , (2.009) ISOFEMID, (2,010) ISOPYRAZAM (anti-epimer enantiomer 1r, 4S, 9S), (2.011) ISOPYRAZAM (anti-epimer enantiomer 1S, 4R, 9R), (2nd012) ISOPYRAZAM (anti- epimer racemat 1rs, 4SR ,9SR), (2.013) isopyrazam (mixture of syn-epimeric racemate 1RS,4SR,9RS and anti-epimeric racemate 1RS,4SR,9SR), (2.014) isopyrazam (syn-epimeric enantiomer 1R,4S,9R), ( 2.015) isopyrazam (syn-epimeric enantiomer 1S,4R,9S), (2.016) isopyrazam (syn-epimeric racemate 1RS,4SR,9RS), (2.017) penflufen, (2.018) penthiopyrad, (2.019) pydiflumetofen, (2.020) pyraziflumide , (2.021) Sedaxanes, (2.022) 1,3-dimethyl-N-(1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl)-1H-pyrazole-4-carboxamide, ( 2.023) 1,3-dimethyl-N-[(3R)-1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl]-1H-pyrazole-4-carboxamide, (2.024) 1,3-dimethyl-N-[(3S)-1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl]-1H-pyrazole-4-carboxamide, (2.025) 1-methyl -3-(trifluoromethyl)-N-[2'-(trifluoromethyl)biphenyl-2-yl]-1H-pyrazole-4-carboxamide, (2.026) 2-Fluoro-6-(trifluoromethyl)-N-(1,1 ,3-trimethyl-2,3-dihydro-1H-inden-4-yl)benzamide, (2.027) 3-(Difluoromethyl)-1-methyl-N-(1,1,3-trimethyl-2,3-dihydro -1H-inden-4-yl)-1H-pyrazole-4-carboxamide, (2.028) 3-(Difluoromethyl)-1-methyl-N-[(3R)-1,1,3-trimethyl-2,3- dihydro-1H-inden-4-yl]-1H-pyrazole-4-carboxamide, (2.029) 3-(Difluoromethyl)-1-methyl-N-[(3S)-1,1,3-trimethyl-2,3 -dihydro-1H-inden-4-yl]-1H-pyrazole-4-carboxamide, (2,030) 3-(Difluoromethyl)-N-(7-fluoro-1,1,3-trimethyl-2,3-dihydro- 1H-inden-4-yl)-1-methyl-1H-pyrazole-4-carboxamide, (2.031) 3-(Difluoromethyl)-N-[(3R)-7-fluoro-1,1,3-trimethyl-2 ,3-dihydro-1H-inden-4-yl]-1-methyl-1H-pyrazole-4-carboxamide, (2.032) 3-(Difluoromethyl)-N-[(3S)-7-fluoro-1,1, 3-trimethyl-2,3-dihydro-1H-inden-4-yl]-1-methyl-1H-pyrazole-4-carboxamide, (2.033) 5,8-difluoro-N-[2-(2-flu or-4-{[4-(trifluoromethyl)pyridin-2-yl]oxy}phenyl)ethyl]quinazolin-4-amine, (2.034) N-(2-cyclopentyl-5-fluorobenzyl)-N-cyclopropyl-3- (difluoromethyl)-5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.035) N-(2-tert-Butyl-5-methylbenzyl)-N-cyclopropyl-3-(difluoromethyl)-5-fluoro -1-methyl-1H-pyrazole-4-carboxamide, (2.036) N-(2-tert-butylbenzyl)-N-cyclopropyl-3-(difluoromethyl)-5-fluoro-1-methyl-1H-pyrazole-4- carboxamide, (2.037) N-(5-Chloro-2-ethylbenzyl)-N-cyclopropyl-3-(difluoromethyl)-5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.038) N-(5 -Chloro-2-isopropylbenzyl)-N-cyclopropyl-3- (difluoromethyl)-5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.039) N -[(1R,4S)-9-(dichloromethylene)-1,2,3,4-tetrahydro-1, 4-methanonaphthalen-5-yl]-3-(difluoromethyl)-1-methyl-1H-pyrazole-4-carboxamide, (2,040) N -[(1S,4R)-9-(dichloromethylene)-1,2,3 ,4-Tetrahydro-1,4-methanonaphthalene-5-yl]-3-(difluoromethyl)-1-methyl-1H-pyrazole-4-carboxamide, (2.041) N -[1-(2,4-Dichlorophenyl)- 1-methoxypropan-2-yl]-3-(difluoromethyl)-1-methyl-1H-pyrazole-4-carboxamide, (2.042) N -[2-Chloro-6-(trifluoromethyl)benzyl]-N-cyclopropyl-3 -(difluoromethyl)-5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.043) N -[3-Chloro-2-fluoro-6-(trifluoromethyl)benzyl]-N-cyclopropyl-3-( difluoromethyl)-5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.044) N -[5-Chloro-2-(trifluoromethyl)benzyl]-N-cyclopropyl-3-(difluoromethyl)-5-fluoro -1-methyl-1H-pyrazole-4-carboxamide, (2.045) N -Cyclopropyl-3-(difluoromethyl)-5-fluoro-1-methyl-N-[5-methyl-2-(trifluoromethyl)benzyl]-1H -pyrazole-4-carboxamide, (2.046) N-cyclopropyl-3-(difluoromethyl)-5-fluoro-N-(2-fluoro-6-isopr opylbenzyl)-1-methyl-1H-pyrazole-4-carboxamide, (2.047) N -Cyclopropyl-3-(difluoromethyl)-5-fluoro-N-(2-isopropyl-5-methylbenzyl)-1-methyl-1H- pyrazole-4-carboxamide, (2.048) N -Cyclopropyl-3-(difluoromethyl)-5-fluoro-N-(2-isopropylbenzyl)-1-methyl-1H-pyrazole-4-carbothioamide, (2.049) N -cyclopropyl- 3-(difluoromethyl)-5-fluoro-N-(2-isopropylbenzyl)-1-methyl-1H-pyrazole-4-carboxamide, (2,050) N-cyclopropyl-3-(difluoromethyl)-5-fluoro-N-( 5-fluoro-2-isopropylbenzyl)-1-methyl-1H-pyrazole-4-carboxamide, (2.051) N-cyclopropyl-3-(difluoromethyl)-N-(2-ethyl-4,5-dimethylbenzyl)-5- fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.052) N -Cyclopropyl-3-(difluoromethyl)-N-(2-ethyl-5-fluorobenzyl)-5-fluoro-1-methyl-1H-pyrazole -4-carboxamide, (2.053) N -Cyclopropyl-3-(difluoromethyl)-N-(2-ethyl-5-methylbenzyl)-5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.054) N -cyclopropyl-N-(2-cyclopropyl-5-fluorobenzyl)-3-(difluoromethyl)-5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.055) N -cyclopropyl-N-(2-cyclopropyl - 5-methylbenzyl)-3-(di fluoromethyl)-5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.056) N-cyclopropyl-N-(2-cyclopropylbenzyl)-3-(difluoromethyl)-5-fluoro-1-methyl-1H- pyrazole-4-carboxamide. 3) Inhibitors of the respiratory chain at complex III, e.g. (3.001) ametoctradine, (3.002) amisulbromine, (3.003) azoxystrobin, (3.004) coumethoxystrobin, (3.005) coumoxystrobin, (3.006) cyazofamide, (3.007) dimoxystrobin, (3.008) enoxastrobin, (3009) famoxadone, (3010) fenamidone, (3011) flufenoxystrobin, (3012) fluoxastrobin, (3013) kresoxim-methyl, (3014) metominostrobin, (3015) orysastrobin, (3016) picoxystrobin, (3017) pyraclostrobin, (3018) Pyrametostrobin, (3.019) Pyraoxystrobin, (3.020) Trifloxystrobin (3.021) (2E)-2-{2-[({[(1E)-1-(3-{[(E)-1-Fluoro-2-phenylvinyl] oxy}phenyl)ethylidene]amino}oxy)methyl]phenyl}-2-(methoxyimino)-N-methylacetamide, (3.022)(2E,3Z)-5-{[1-(4-Chlorophenyl)-1H-pyrazol- 3-yl]oxy}-2-(methoxyimino)-N,3-dimethylpent-3-enamide, (3.023)(2R)-2-{2-[(2,5-dimethylphenoxy)methyl]phenyl}-2- methoxy-N-methylacetamide, (3.024) (2S)-2-{2-[(2,5-dimethylphenoxy)methyl]phenyl}-2-methoxy-N-methylacetamide, (3.025) (3S,6S,7R,8R )-8-Benzyl-3-[({3-[(isobutyryloxy)methoxy]-4-m ethoxypyridin-2-yl}carbonyl)amino]-6-methyl-4,9-dioxo-1,5-dioxonan-7-yl 2-methylpropanoate, (3,026) 2-{2-[(2,5-dimethylphenoxy )methyl]phenyl}-2-methoxy-N-methylacetamide, (3.027) N-(3-Ethyl-3,5,5- trimethylcyclohexyl)-3-formamido-2-hydroxybenzamide, (3.028)(2E,3Z)-5-{[1-(4-chloro-2-fluorophenyl)-1H-pyrazol-3-yl]oxy}-2-( methoxyimino)-N,3-dimethylpent-3-enamide, (3.029) Methyl {5-[3-(2,4-dimethylphenyl)-1H-pyrazol-1-yl]-2-methylbenzyl}carbamates. 4) Inhibitors of mitosis and cell division, for example (4.001) carbendazim, (4.002) diethofencarb, (4.003) ethaboxam, (4.004) fluopicolide, (4.005) pencycuron, (4.006) thiabendazole, (4.007) thiophanate-methyl, (4.008) zoxamide , , (4.009) 3-Chloro-4-(2,6-difluorophenyl)-6-methyl-5-phenylpyridazine, (4.010) 3-Chloro-5-(4-chlorophenyl)-4-(2,6-difluorophenyl )-6-methylpyridazine, (4.011) 3-Chloro-5-(6-chloropyridin-3-yl)-6-methyl-4-(2,4,6-trifluorophenyl)pyridazine, (4.012) 4-(2- bromo-4-fluorophenyl)-N-(2,6-difluorophenyl)-1,3-dimethyl-1H-pyrazol-5-amine, (4.013) 4-(2-bromo-4-fluorophenyl)-N-(2 -bromo-6-fluorophenyl)-1,3-dimethyl-1H-pyrazol-5-amine, (4.014) 4-(2-bromo-4-fluorophenyl)-N-(2-bromophenyl)-1,3-dimethyl -1H-pyrazol-5-amine, (4.015) 4-(2-bromo-4-fluorophenyl)-N-(2-chloro-6-fluorophenyl)-1,3-dimethyl-1H-pyrazol-5-amine, (4.016) 4-(2-Bromo-4-fluorophenyl)-N-(2-chlorophenyl)-1,3-dimethyl-1H-pyrazol-5-amine, (4.017) 4-(2-bromo-4-fluorophenyl). )-N-(2-fluorophenyl)-1,3-dimethyl-1H-pyrazol-5-amine, (4.018) 4-(2-chloro-4- fluorophenyl)-N-(2,6-difluorophenyl)-1,3-dimethyl-1H-pyrazol-5-amine, (4.019) 4-(2-Chloro-4-fluorophenyl)-N-(2-chloro-6 -fluorophenyl)-1,3-dimethyl-1H-pyrazole-5-amine, (4,020) 4-(2-Chloro-4-fluorophenyl)-N-(2-chlorophenyl)-1,3-dimethyl-1H-pyrazole -5-amine, (4.021) 4-(2-Chloro-4-fluorophenyl)-N-(2-fluorophenyl)-1,3-dimethyl-1H-pyrazole-5-amine, (4.022) 4-(4- Chlorophenyl)-5-(2,6-difluorophenyl)-3,6-dimethylpyridazine, (4.023) N-(2-Bromo-6-fluorophenyl)-4-(2-chloro-4-fluorophenyl)-1,3- dimethyl-1H-pyrazole-5-amine, (4.024) N-(2-Bromophenyl)-4-(2-chloro-4-fluorophenyl)-1,3-dimethyl-1H-pyrazole-5-amine, (4.025) N-(4-Chloro-2,6-difluorophenyl)-4-(2-chloro-4-fluorophenyl)-1,3-dimethyl-1H-pyrazole-5-amine. 5) Compounds capable of multisite activity, e.g. (5.001) Bordeaux mixture, (5.002) captafol, (5.003) captan, (5.004) chlorothalonil, (5.005) copper hydroxide, (5.006) copper naphthenate, (5.007) copper oxide, (5.008) copper oxychloride , (5.009) copper(2+) sulfate, (5.010) dithianon, (5.011) dodine, (5.012) folpet, (5.013) mancozeb, (5.014) maneb, (5.015) metiram, (5.016) zinc metiram, (5.017) copper oxine, (5.018) propineb, (5.019) sulfur and sulfur preparations including calcium polysulphide, (5.020) thiram, (5.021) zineb, (5.022) ziram, (5.023) 6-ethyl-5,7-dioxo-6,7- dihydro-5H-pyrrolo[3',4':5,6][1,4]dithiino[2,3-c][1,2]thiazole-3-carbonitrile. 6) Compounds capable of eliciting host defenses, e.g. (6.001) acibenzolar-S-methyl, (6.002) isotianil, (6.003) probenazole, (6.004) tiadinil. 7) Inhibitors of amino acid and/or protein biosynthesis, for example (7.001) cyprodinil, (7.002) kasugamycin, (7.003) kasugamycin hydrochloride hydrate, (7.004) oxytetracycline, (7.005) pyrimethanil, (7.006) 3-(5-fluoro- 3,3,4,4-tetramethyl-3,4-dihydroisoquinolin-1-yl)quinoline. (8) Inhibitors of ATP production, e.g. (8.001) silthiofam. 9) Inhibitors of cell wall synthesis, for example (9.001) benthiavalicarb, (9.002) dimethomorph, (9.003) flumorph, (9.004) iprovalicarb, (9.005) mandipropamide, (9.006) pyrimorph, (9.007) valifenalate, (9.008) (2E)-3 -(4-tert-Butylphenyl)-3-(2-chloropyridin-4-yl)-1-(morpholin-4-yl)prop-2-en-1-one, (9.009)(2Z)-3- (4-tert-butylphenyl)-3-(2-chloropyridin-4-yl)-1-(morpholin-4-yl)prop-2-en-1-one. 10) Inhibitors of lipid and membrane synthesis, e.g. (10.001) propamocarb, (10.002) propamocarb hydrochloride, (10.003) tolclofos-methyl. 11) Inhibitors of melanin biosynthesis, e.g. (11.001) tricyclazole, (11.002) 2,2,2-trifluoroethyl {3-methyl-1-[(4-methylbenzoyl)amino]butan-2-yl}carbamate. 12) Inhibitors of nucleic acid synthesis, for example (12.001) benalaxyl, (12.002) benalaxyl-M (kiralaxyl), (12.003) metalaxyl, (12.004) metalaxyl-M (mefenoxam). 13) Inhibitors of signal transduction, e.g. (13.001) fludioxonil, (13.002) iprodione, (13.003) procymidone, (13.004) proquinazide, (13.005) quinoxyfen, (13.006) vinclozoline. 14) Compounds which can act as uncouplers, e.g. (14.001) fluazinam, (14.002) meptyldinocap. 15) Other compounds, e.g. (15.001) abscisic acid, (15.002) benthiazole, (15.003) bethoxazine, (15.004) capsimycin, (15.005) carvone, (15.006) quinomethionate, (15.007) cufraneb, (15.008) cyflufenamide, (15.009) cymoxanil , (15.010) cyprosulfamide, (15.011) flutianil, (15.012) fosetyl aluminum, (15.013) fosetyl calcium, (15.014) fosetyl sodium, (15.015) methyl isothiocyanate, (15.016) metrafenone, (15.017) mildiomycin, (15.018) Natamycin, (15.019) nickel dimethyldithiocarbamate, (15.020) nitrothal-isopropyl, (15.021) oxamocarb, (15.022) oxathiapiproline, (15.023) oxyfenthiin, (15.024) pentachlorophenol and salts, (15.025) phosphonic acid and its salts, (15.026) propamocarb -fosetylate, (15.027) pyriofenone (chlazafenone) (15.028) tebufloquine, (15.029) tecloftalam, (15.030) tolnifanide, (15.031) 1-(4-{4-[(5R)-5-(2,6-difluorophenyl) - 4,5-dihydro-1,2-oxazol-3-yl]-1,3-thiazol-2-yl}piperidin-1-yl)-2-[5-methyl-3-(trifluoromethyl)-1H- pyrazol-1-yl]ethanone, (15,032) 1-(4-{4-[(5S)-5-(2,6-difluoro phenyl)-4,5-dihydro-1,2-oxazol-3-yl]-1,3-thiazol-2-yl}piperidin-1-yl)-2-[5-methyl-3-(trifluoromethyl)- 1H-pyrazol-1-yl]ethanone, (15.033) 2-(6-Benzylpyridin-2-yl)quinazoline, (15.034) 2,6-dimethyl-1H,5H-[1,4]dithiino[2,3- c:5,6-c']dipyrrol-1,3,5,7(2H,6H)-tetrone, (15,035) 2-[3,5-bis(difluoromethyl)-1H-pyrazol-1-yl]- 1-[4-(4-{5-[2-(prop-2-yn-1-yloxy)phenyl]-4,5-dihydro-1,2-oxazol-3-yl}-1,3-thiazole -2-yl)piperidin-1-yl]ethanone, (15,036) 2-[3,5-bis(difluoromethyl)-1H-pyrazol-1-yl]-1-[4-(4-{5-[2 -chloro-6-(prop-2-yn-1-yloxy)phenyl]-4,5-dihydro-1,2-oxazol-3-yl}-1,3-thiazol-2-yl)piperidin-1- yl]ethanone, (15.037) 2-[3,5-bis(difluoromethyl)-1H-pyrazol-1-yl]-1-[4-(4-{5-[2-fluoro-6-(prop-2 -yn-1-yloxy)phenyl]-4,5-dihydro-1,2-oxazol-3-yl}-1,3-thiazol-2-yl)piperidin-1-yl]ethanone, (15,038) 2- [6-(3-Fluoro-4-methoxyphenyl)-5-methylpyridin-2-yl]quinazoline, (15.039) 2-{(5R)-3-[2-(1-{[3,5-Bis(difluoromethyl)-1H-pyrazol-1-yl]acetyl}piperidin-4-yl)-1,3- thiazol-4-yl]-4,5-dihydro-1,2-oxazol-5-yl}-3-chlorophenyl methanesulfonate, (15,040) 2-{(5S)-3-[2-(1-{[3 ,5-bis(difluoromethyl)-1H-pyrazol-1-yl]acetyl}piperidin-4-yl)-1,3-thiazol-4-yl]-4,5-dihydro-1,2-oxazol-5- yl}-3-chlorophenyl methanesulfonate, (15.041) 2-{2-[(7,8-Difluoro-2-methylquinolin-3-yl)oxy]-6-fluorophenyl}propan-2-ol, (15.042) 2- {2-Fluoro-6-[(8-fluoro-2-methylquinolin-3-yl)oxy]phenyl}propan-2-ol, (15,043) 2-{3-[2-(1-{[3,5 -bis(difluoromethyl)-1H-pyrazol-1-yl]acetyl}piperidin-4-yl)-1,3-thiazol-4-yl]-4,5-dihydro-1,2-oxazol-5-yl} -3-chlorophenyl methanesulfonate, (15.044) 2-{3-[2-(1-{[3,5-bis(difluoromethyl)-1H-pyrazol-1-yl]acetyl}piperidin-4-yl)-1 ,3-thiazol-4-yl]-4,5-dihydro-1,2-oxazol-5-yl}phenyl methanesulfonate, (15,045) 2-phenylphenol and its salts, (15,046) 3-(4,4,5 -Trifluoro-3,3-dimethyl-3,4-dihydroisoquinolin-1-yl)quinoline, (15,047) 3-(4,4-Difluoro-3,3-dimethyl-3,4-dihydroisoquinoline-1- yl)quinoline, (15.048) 4-amino-5-fluoropyrimidin-2-ol (tautomeric form: 4-amino-5-fluoropyrimidin-2(1H)-one), (15.049) 4-oxo-4-[(2 -phenylethyl)amino]butyric acid, (15,050) 5-amino-1,3,4-thiadiazole-2-thiol, (15,051) 5-chloro-N'-phenyl-N'-(prop-2-yn-1- yl)thiophene-2-sulfonohydrazide, (15.052) 5-Fluoro-2-[(4-fluorobenzyl)oxy]pyrimidin-4-amine, (15.053) 5-Fluoro-2-[(4-methylbenzyl)oxy]pyrimidin- 4-amine, (15.054) 9-Fluoro-2,2-dimethyl-5-(quinolin-3-yl)-2,3-dihydro-1,4-benzoxazepine, (15.055) but-3-yn-1- yl {6-[({[(Z)-(1-methyl-1H-tetrazol-5-yl)(phenyl)methylene]amino}oxy)methyl]pyridin-2-yl}carbamate, (15.056) ethyl (2Z )-3-amino-2-cyano-3-phenyl acrylate, (15.057) phenazine-1-carboxylic acid, (15.058) propyl 3,4,5-trihydroxybenzoate, (15.059) quinolin-8-ol, (15.060) quinoline-8 -ol sulfate (2:1), (15.061) tert -butyl {6-[({[(1-methyl-1H-tetrazol-5-yl)(phenyl)methylene]amino}oxy)methyl]pyridine-2- yl}carbamate, (15,062) 5-Fluoro-4-imino-3-methyl-1)sulfonyl]-3,4-dihydropyrimidin-2(1H)-one. Preferred fungicides are selected from the group consisting of benalaxyl, bitertanol, bromuconazole, captafol, carbendazim, carpropamid, cyazofamid, cyproconazole, diethofencarb, edifenphos, fenpropimorph, fentine, fluquinconazole, fosetyl, fluoroimide, folpet, iminoctadine, iprodionem, iprovalicarb, kasugamycin, maneb , Nabam, Pencycuron, Prochloraz, Propamocarb, Propineb, Pyrimethanil, Sprioxamine, Quintozene, Tebuconazole, Tolylfluanid, Triadimefon, Triadimenol, Trifloxystrobin, Zineb. Insecticides, acaricides, nematicides, miticides and related active ingredients are, for example (in analogy to the herbicides and fungicides, the compounds are referred to by their common names where possible, here in the usual English notation): (1) acetylcholinesterase (AChE) inhibitors, preferably Carbamates selected from alanycarb, aldicarb, bendiocarb, benfuracarb, butocarboxime, butoxycarboxime, carbaryl, carbofuran, carbosulfan, ethiofencarb, fenobucarb, formetanate, furathiocarb, isoprocarb, methiocarb, methomyl, metolcarb, oxamyl, pirimicarb, propoxur, thiodicarb, thiofanox, triazamate, trimethacarb , XMC and xylylcarb, or organophosphates selected from acephate, azamethiphos, azinphos-ethyl, azinphos- methyl, cadusafos, chlorethoxyfos, chlorfenvinphos, chlormephos, chlorpyrifos-methyl, coumaphos, cyanophos, demeton-S-methyl, diazinon, dichlorvos/DDVP, dicrotophos, dimethoate, dimethylvinphos, disulfoton, EPN, ethion, ethoprophos, famphur, fenamiphos, fenitrothion, Fenthion, Fosthiazate, Heptenophos, Imicyafos, Isofenphos, Isopropyl O-(methoxyaminothiophosphoryl)salicylate, Isoxathion, Malathion, Mecarbam, Methamidophos, Methidathion, Mevinphos, Monocrotophos, Naled, Omethoate, Oxydemeton-methyl, Parathion-methyl, Phenthoate, Phorate , Phosalon, Phosmet, Phosphamidon, Phoxim, Pirimiphos-methyl, Profenofos, Propetamphos, Prothiofos, Pyraclofos, Pyridaphenthion, Quinalphos, Sulfotep, Tebupirimfos, Temephos, Terbufos, Tetrachlorvinphos, Thiometon, Triazophos, Triclorfon and Vamidothion. (2) GABA-gated chloride channel blockers, preferably cyclodiene-organochlorines selected from chlordane and endosulfan, or phenylpyrazoles (fiprole) selected from ethiprole and fipronil. (3) Sodium channel modulators, preferably pyrethroids selected from acrinathrin, allethrin, d-cis-trans-allethrin, d-trans-allethrin, bifenthrin, bioallethrin, bioallethrin-S-cyclopentenyl isomer, bioresmethrin, cycloprothrin, cyfluthrin, beta -cyfluthrin, cyhalothrin, lambda-cyhalothrin, gamma-cyhalothrin, cypermethrin, alpha-cypermethrin, beta-cypermethrin, theta-cypermethrin, zeta-cypermethrin, cyphenothrin [(1R)-trans isomer], deltamethrin, empenthrin [(EZ)- (1R) isomer], esfenvalerate, etofenprox, fenpropathrin, fenvalerate, flucythrinate, flumethrin, tau-fluvalinate, halfenprox, imiprothrin, kadethrin, momfluorothrin, permethrin, phenothrin [(1R)-trans isomer], prallethrin, pyrethrins (pyrethrum) , resmethrin, silafluofen, tefluthrin, tetramethrin, tetramethrin [(1R) isomer], tralomethrin and transfluthrin, or DDT or methoxychlor. (4) Competitive modulators of the nicotinic acetylcholine receptor (nAChR), preferably neonicotinoids selected from acetamiprid, clothianidin, dinotefuran, imidacloprid, nitenpyram, thiacloprid and thiamethoxam, or nicotine, or sufoximine selected from sulfoxaflor, or butenolide selected from flupyradifurone. (5) Allosteric modulators of the nicotinic acetylcholine receptor (nAChR), preferably spinosyns selected from spinetoram and spinosad. (6) Allosteric modulators of the glutamate-gated chloride channel (GluCl), preferably avermectins/milbemycins selected from abamectin, emamectin benzoate, lepimectin and milbemectin. (7) juvenile hormone mimetics, preferably juvenile hormone analogs selected from hydroprene, kinoprene and methoprene, or fenoxycarb or pyriproxyfen. (8) Various non-specific (multi-site) inhibitors, preferably alkyl halides selected from methyl bromide and other alkyl halides, or chloropicrin, or sulfuryl fluoride, or borax, or tartar emetic, or methyl isocyanate generators selected from diazomet and metam. (9) TRPV channel modulators of chordotonal organs selected from pymetrozine and pyrifluquinazone. (10) Mite growth inhibitors selected from Clofentezine, Hexythiazox, Diflovidazine and Etoxazole. (11) Insect intestinal membrane microbial disruptors selected from Bacillus thuringiensis subsp. israelensis, Bacillus sphaericus, Bacillus thuringiensis subsp. aizawai, Bacillus thuringiensis subsp. kurstaki, Bacillus thuringiensis subsp. tenebrionis and Bt plant proteins selected from Cry1Ab, Cry1Ac, Cry1Fa, Cry1A.105, Cry2Ab, VIP3A.105 , mCry3A, Cry3Ab, Cry3Bb and Cry34Ab1/35Ab1. (12) Inhibitors of mitochondrial ATP synthase, preferably ATP disruptors selected from diafenthiuron, or organotin compounds selected from azocyclotin, cyhexatin and fenbutatin oxide, or propargit or tetradifon. (13) Oxidative phosphorylation decouplers by perturbation of the proton gradient selected from chlorfenapyr, DNOC and sulfluramide. (14) Nicotinic acetylcholine receptor channel blockers selected from Bensultap, Cartap hydrochloride, Thiocyclam and Thiosultap sodium. (15) Inhibitors of chitin biosynthesis type 0 selected from bistrifluron, chlorfluazuron, diflubenzuron, flucycloxuron, flufenoxuron, hexaflumuron, lufenuron, novaluron, noviflumuron, teflubenzuron and triflumuron. (16) Inhibitors of chitin biosynthesis type 1 selected from buprofezin. (17) Moult disruptor (particularly in Diptera) selected from cyromazine. (18) Ecdysone receptor agonists selected from chromafenozide, halofenozide, methoxyfenozide and tebufenozide. (19) Octopamine receptor agonists selected from amitraz. (20) Mitochondrial complex III electron transport inhibitors selected from hydramethylnon, acequinocyl and fluacrypyrim. (21) Mitochondrial complex I electron transport inhibitors, preferably METI acaricides selected from fenazaquin, fenpyroximate, pyrimidifen, pyridaben, tebufenpyrad and tolfenpyrad, or rotenone (Derris). (22) Voltage-gated sodium channel blocker selected from indoxacarb and metaflumizone. (23) Inhibitors of acetyl-CoA carboxylase, preferably tetronic and tetramic acid derivatives selected from spirodiclofen, spiromesifen and spirotetramat. (24) Inhibitors of mitochondrial complex IV electron transport, preferably phosphines selected from aluminum phosphide, calcium phosphide, phosphine and zinc phosphide, or cyanides selected from calcium cyanide, potassium cyanide and sodium cyanide. (25) Inhibitors of mitochondrial complex II electron transport, preferably beta-ketonitrile derivatives selected from cyenopyrafen and cyflumetofen, or carboxanilides selected from pyflubumide. (28) Ryanodine receptor modulators, preferably diamides selected from chlorantraniliprole, cyantraniliprole and flubendiamide. (29) Modulators of chordotonal organs (with undefined target structure) selected from flonicamid. (30) other active ingredients selected from acynonapyr, afidopyropene, afoxolaner, azadirachtin, benclothiaz, benzoximate, benzpyrimoxane, bifenazate, broflanilide, bromopropylate, quinomethionate, chloroballethrin, cryolite, cyclaniliprole, cycloxapride, cyhalodiamide, dicloromezotiaz, dicofol, epsilon-metofluthrin, epsilon-momfluthrin , Flometoquine, Fluazaindolizine, Fluensulfone, Flufenerime, Flufenoxystrobin, Flufiprole, Fluhexafone, Fluopyram, Flupyrimine, Fluralaner, Fluxametamide, Fufenozide, Guadipyr, Heptafluthrin, Imidaclothiz, Iprodione, kappa-Bifenthrin, kappa-Tefluthrin, Lotilaner, Meperfluthrin, Oxazosulfyl, Pyridal Paichongding, , pyrifluquinazone, pyriminostrobin, spirobudiclofen, spiropidione, tetramethylfluthrin, tetraniliprole, tetrachlorantraniliprole, tigolaner, tioxazafen, thiofluoximate, triflumezopyrim and iodomethane; also preparations based on Bacillus firmus (I-1582, BioNeem, Votivo), as well as the following compounds: 1-{2-Fluoro-4-methyl-5-[(2,2,2-trifluoroethyl)sulfinyl]phenyl}- 3-(trifluoromethyl)-1H-1,2,4-triazole-5-amine (known from WO2006/043635) (CAS 885026-50-6), {1'-[(2E)-3-(4-chlorophenyl )prop-2-en-1-yl]-5-fluorospiro[indole-3,4'-piperidine]-1(2H)-yl}(2-chloropyridin-4-yl)methanone (known from WO2003/106457) (CAS 637360-23-7), 2-Chloro-N-[2-{1-[(2E)-3-(4-chlorophenyl)prop-2-en-1-yl]piperidin-4-yl}- 4-(trifluoromethyl)phenyl]isonicotinamide (known from WO2006/003494) (CAS 872999-66-1), 3-(4-chloro-2,6-dimethylphenyl)-4-hydroxy-8-methoxy-1,8- diazaspiro[4.5]dec-3-en-2-one (known from WO 2010052161) (CAS 1225292-17-0), 3-(4-chloro-2,6-dimethylphenyl)-8-methoxy-2-oxo- 1,8-diazaspiro[4.5]dec-3-en-4-yl ethyl carbonate (known from EP 2647626) (CAS-1440516-42-6), 4-(but-2-yn-1-yloxy)-6 -(3,5-dimethylpiperidin-1-yl)-5-fluoropyrimidine (known from WO2004/099160) (CAS 792914-58-0), PF1364 (known from JP20 10/018586) (CAS Reg.No.1204776-60-2), (3E)-3-[1-[(6-chloro-3-pyridyl)methyl]-2-pyridylidene]-1,1,1 -trifluoropropan-2-one (known from WO2013/144213) (CAS 1461743-15-6), N-[3-(benzylcarbamoyl)-4-chlorophenyl]-1-methyl-3-(pentafluoroethyl)-4- (trifluoromethyl)-1H-pyrazole-5-carboxamide (known from WO2010/051926) (CAS 1226889-14-0), 5-bromo-4-chloro-N-[4-chloro-2-methyl-6-(methylcarbamoyl )phenyl]-2-(3-chloro-2-pyridyl)pyrazole-3-carboxamide (known from CN103232431) (CAS 1449220-44-3), 4-[5-(3,5-dichlorophenyl)-4,5 -dihydro-5-(trifluoromethyl)-3-isoxazolyl]-2-methyl-N-(cis-1-oxido-3-thietanyl)benzamide, 4-[5-(3,5-dichlorophenyl)-4,5- dihydro-5-(trifluoromethyl)-3-isoxazolyl]-2-methyl-N-(trans-1-oxido-3-thietanyl)benzamide and 4-[(5S)-5-(3,5-dichlorophenyl)-4 ,5-dihydro-5-(trifluoromethyl)-3-isoxazolyl]-2-methyl-N-(cis-1-oxido-3-thietanyl)benzamide (known from WO 2013/050317 A1) (CAS 1332628-83-7 ), N -[3-Chloro-1-(3-pyridinyl)-1H-pyrazol-4-yl]-N-ethyl-3-[(3,3,3-trifluoropropyl)sulfinyl]propanamide, (+)- N -[3-Chloro-1-(3-pyridinyl)-1H-pyrazol-4-yl]-N-ethyl-3-[(3,3,3-trifluoropropyl)sulfinyl]propanamide and (-)-N- [3-Chloro-1-(3-pyridinyl)-1H-pyrazol-4-yl]-N-ethyl-3-[(3,3,3-trifluoropropyl)sulfinyl]propanamide (known from WO 2013/162715 A2, WO 2013/1 62716 A2, US 2014/0213448 A1) (CAS 1477923-37-7), 5-[[(2E)-3-chloro-2-propen-1-yl]amino]-1-[2,6-dichloro- 4-(trifluoromethyl)phenyl]-4-[(trifluoromethyl)sulfinyl]-1H-pyrazole-3-carbonitrile (known from CN 101337937 A) (CAS 1105672-77-2), 3-bromo-N-[4-chloro -2-methyl-6-[(methylamino)thioxomethyl]phenyl]-1-(3-chloro-2-pyridinyl)-1H-pyrazole-5-carboxamide, (Liudaibenjiaxuanan, known from CN 103109816 A) (CAS 1232543-85 -9); N-[4-Chloro-2-[[(1,1-dimethylethyl)amino]carbonyl]-6-methylphenyl]-1-(3-chloro-2-pyridinyl)-3-(fluoromethoxy)-1H-pyrazole- 5-carboxamide (known from WO 2012/034403 A1) (CAS 1268277-22-0), N-[2-(5-amino-1,3,4-thiadiazol-2-yl)-4-chloro-6- methylphenyl]-3-bromo-1-(3-chloro-2-pyridinyl)-1H-pyrazole-5-carboxamide (known from WO 2011/085575 A1) (CAS 1233882-22-8), 4-[3-[ 2,6-Dichloro-4-[(3,3-dichloro-2-propen-1-yl)oxy]phenoxy]propoxy]-2-methoxy-6-(trifluoromethyl)pyrimidine (known from CN 101337940 A) (CAS 1108184-52-6); (2E)- and 2(Z)-2-[2-(4-cyanophenyl)-1-[3-(trifluoromethyl)phenyl]ethylidene]-N-[4-(difluoromethoxy)phenyl]hydrazinecarboxamide (known from CN 101715774 A) (CAS 1232543-85-9); Cyclopropanecarboxylic acid 3-(2,2-dichloroethenyl)-2,2-dimethyl-4-(1H-benzimidazol-2-yl)phenyl ester (known from CN 103524422 A) (CAS 1542271-46-4); (4aS)-7-Chloro-2,5-dihydro-2-[[(methoxycarbonyl)[4-[(trifluoromethyl)thio]phenyl]amino]carbonyl]indeno[1,2-e][1,3,4 ]oxadiazine-4a(3H)-carboxylic acid methyl ester (known from CN 102391261 A) (CAS 1370358-69-2); 6-Deoxy-3-O-ethyl-2,4-di-O-methyl-1-[N-[4-[1-[4-(1,1,2,2,2-pentafluoroethoxy)phenyl]- 1H-1,2,4-triazol-3-yl]phenyl]carbamate]-α-L-mannopyranose (known from US 2014/0275503 A1) (CAS 1181213-14-8); 8-(2-Cyclopropylmethoxy-4-trifluoromethylphenoxy)-3-(6-trifluoromethylpyridazin-3-yl)-3-azabicyclo[3.2.1]octane (CAS 1253850-56-4), (8-anti)-8- (2-Cyclopropylmethoxy-4-trifluoromethylphenoxy)-3-(6-trifluoromethylpyridazin-3-yl)-3-azabicyclo[3.2.1]octane (CAS 933798-27-7), (8-syn)-8-(2 -Cyclopropylmethoxy-4-trifluoromethylphenoxy)-3-(6-trifluoromethylpyridazin-3-yl)-3-azabicyclo[3.2.1]octane (known from WO 2007040280 A1, WO 2007040282 A1) (CAS 934001-66-8), N -[3-Chloro-1-(3-pyridinyl)-1H-pyrazol-4-yl]-N-ethyl-3-[(3,3,3-trifluoropropyl)thio]-propanamide (known from WO 2015/058021 A1, WO 2015/058028 A1) (CAS 1477919-27-9) and N-[4-(aminothioxomethyl)-2-methyl-6-[(methylamino)carbonyl]phenyl]-3-bromo-1-(3- chloro-2-pyridinyl)- 1H-pyrazole-5-carboxamide (known from CN 103265527 A) (CAS 1452877-50-7), 5-(1,3-dioxan-2-yl)-4- [[4-(trifluoromethyl)phenyl]methoxy]pyrimidine (known from WO 2013/115391 A1) (CAS 1449021-97-9), 3-(4-chloro-2,6-dimethylphenyl)-8-methoxy-1 -methyl-1,8-diazaspiro[4.5]decane-2,4-dione (known from WO 2014/187846 A1) (CAS 1638765-58-8), 3-(4-chloro-2,6-dimethylphenyl)- Ethyl 8-methoxy-1-methyl-2-oxo-1,8-diazaspiro[4.5]dec-3-en-4-ylester (known from WO 2010/066780 A1, WO 2011151146 A1) (CAS 1229023-00- 0), 4-[(5S)-5-(3,5-dichloro-4-fluorophenyl)-4,5-dihydro-5-(trifluoromethyl)-3-isoxazolyl]-N-[(4R)-2- ethyl-3-oxo-4-isoxazolidinyl]-2-methylbenzamide (known from WO 2011/067272, WO2013/050302) (CAS 1309959-62-3). Examples of insecticides that can preferably be used together with the herbicides are the following: acetamiprid, acrinathrin, aldicarb, amitraz, acinphos-methyl, cyfluthrin, carbaryl, cypermethrin, deltamethrin, endosulfan, ethoprophos, fenamiphos, fenthion, fipronil, imidacloprid, methamidophos, Methiocarb, Niclosamide, Oxydemeton-methyl, Prothiophos, Silafluofen, Thiacloprid, Thiodicarb, Tralomethrin, Triazophos, Trichlorfon, Triflumuron, Terbufos, Fonofos, Phorate, Chlorpyriphos, Carbofuran, Tefluthrin. The active compound combinations according to the invention are suitable for controlling a broad spectrum of weeds in non-crop land, on paths, railway tracks, industrial areas ("industrial weed control") or in plantation crops such as moderate, subtropical and tropical climates or geographies. Examples of plantation crops are oil palm, nuts (e.g. almonds, hazelnuts, walnuts, macademia), coconut, berries, oil palm, rubber tree, citrus (e.g. orange, lemon, tangerine), banana, pineapple, cotton, sugarcane, Tea, coffee, cocoa and the like. They are also suitable for use in fruit growing (e.g. pome fruit such as apples, pears, cherries, mangoes, kiwis) and viticulture. The compositions can also be used for seed preparation ("burn-down""no-till" or "zero-till" method) or for post-harvest treatment ("chemical fallow"). The possible uses of the active ingredient combinations also extend to weed control in tree crops, e.g. B. young Christmas tree cultures or eucalyptus plants, in each case before the planting or after the planting (also with overhead treatment, "over-top"). The agents can also be used to control undesired plant growth in economically important crops such as wheat (durum and soft wheat), corn, soybeans, sugar beet, sugar cane, cotton, rice, beans (such as bush beans and horse beans), flax, barley, oats, Rye, triticale, potato and millet (sorghum), pasture and green/lawn areas and plantation crops. Plantation crops include pomefruit (apple, pear, quince), ribes (blackberry, raspberry), citrus, prunus (cherry, nectarine, almond), nut (walnut, pecan, hazelnut, cashew, macadamia), mango, cocoa , coffee, wine (table, Grapes), palms (such as oil palm, date palm, coconut palm,,) eucalyptus, persimmon, rubber, pineapple, banana, avocado, lychee, forest crops (Eucalypteae, Piniaceae, Piceae, Meliaceae, etc.) The herbicidal active ingredient combinations according to the invention in the respective Application forms (= herbicidal agents) have synergies with regard to herbicidal action and selectivity and favorable action with regard to the weed spectrum. They have excellent herbicidal activity against a broad spectrum of economically important monocotyledonous and dicotyledonous annual weeds. Perennial harmful plants which are difficult to control and which sprout from rhizomes, rootstocks or other permanent organs are also well affected by the active compounds. The active ingredient combinations can be applied to the plants (e.g. harmful plants such as monocotyledonous or dicotyledonous weeds or unwanted crop plants), the seeds (e.g. grains, seeds or vegetative propagation organs such as tubers or shoot parts with buds) or the area on which the plants grow (e.g the cultivated area), are applied. The substances can be applied before sowing (possibly also by incorporation into the soil), pre-emergence or post-emergence. Preference is given to use in the early reseeding pre-emergence process or in the post-emergence process of plantation crops against harmful plants that have not yet emerged or have already emerged. The application can also be integrated into weed management systems with shared multiple applications (sequential applications). In detail, some representatives of the monocotyledon and dicotyledonous weed flora may be mentioned by way of example, which can be controlled by the active compound combinations according to the invention, without the naming of a restriction to specific species. On the side of monocotyledonous weed species, for example, Aegilops, Agropyron, Agrostis, Alopecurus, Apera, Avena, Brachicaria, Bromus, Cynodon, Dactyloctenium, Digitaria, Echinochloa, Eleocharis, Eleusine, Eragrostis, Eriochloa, Festuca, Fimbristylis, Imperata, Ischaemum, Heteranthera, Imperata, Ischaemum, Leptochloa, Lolium, Monochoria, Panicum, Paspalum, Phalaris, Phleum, Poa, Rottboellia, Sagittaria, Scirpus, Setaria, Sorghum, Sphenoclea and Cyperus species covered by the annual group. In the case of dicotyledonous weed species, the spectrum of activity extends to species such as Abutilon, Amaranthus, Ambrosia, Anoda, Anthemis, Aphanes, Artemisia, Atriplex, Bellis, Bidens, Capsella, Carduus, Cassia, Centaurea, Chenopodium, Cirsium, Convolvulus, Datura, Desmodium, Emex , Erodium, Erysimum, Euphorbia, Galeopsis, Galinsoga, Galium, Geranium, Hibiscus, Ipomoea, Kochia, Lamium, Lepidium, Lindernia, Matricaria, Mentha, Mercurialis, Mullugo, Myosotis, Papaver, Pharbitis, Plantago, Polygonum, Portulaca, Ranunculus, Raphanus, Rorippa, Rotala, Rumex, Salsola, Senecio, Sesbania, Sida, Sinapis, Solanum, Sonchus, Sphenoclea, Stellaria, Taraxacum, Thlaspi, Trifolium, Urtica, Veronica, Viola, Xanthium. If the active compound combinations according to the invention are applied to the surface of the soil before germination, either the emergence of the weed seedlings is completely prevented or the weeds grow to the cotyledon stage, but then stop growing and finally die off completely after three to four weeks. When the active ingredients are applied to the green parts of the plant post-emergence, growth stops after the treatment and the harmful plants remain in the growth stage present at the time of application or die off completely after a certain time, so that in this way weed competition that is harmful to the crop plants occurs very early and permanently eliminated. The herbicidal compositions according to the invention are distinguished by a rapidly onset and long-lasting herbicidal action. The rainfastness of the active ingredients in the combinations according to the invention is generally favorable. A particular advantage is that the effective doses of compounds (A) and (B) used in the combinations can be set so low that their effect on the soil is optimally low. This not only makes it possible to use them in sensitive crops, but also practically avoids groundwater contamination. The combination of active substances according to the invention enables a considerable reduction in the required application rate of the active substances. With the combined use of the herbicides (A) and (B), performance properties are achieved which go beyond what was to be expected on the basis of the known properties of the individual herbicides for their combination. For example, the herbicidal effects on a certain harmful plant species exceed the expected value as determined by standard methods, e.g. B. according to Colby or other extrapolation methods can be estimated. A synergistic effect is always present when the action, in this case the herbicidal action of the combination of active ingredients, is greater than the sum of the actions of the active ingredients applied individually. The effect to be expected for a given combination of two active substances can be calculated according to SR Colby (“Calculating Synergistic and Antagonistic Responses of Herbicide Combination”, Weeds 15 (1967), 20-22) (see below). The synergistic effects therefore allow, for example, a reduction in the application rates of the individual active ingredients, a higher level of effectiveness with the same application rate, the control of previously undetected types of harmful plants (gaps), an increased residual effect, an increased long-term effect, an increased speed of action, an extension of the application period and/ or a reduction in the number of individual applications required and - as a result for the user - economically and ecologically more advantageous weed control systems. Although the combinations according to the invention have excellent herbicidal activity against monocotyledon and dicotyledonous weeds, many economically important crop plants are only slightly damaged or not damaged at all, depending on the structure of the particular active compound combination according to the invention and the amount applied. Economically important cultures are, for example, dicotyledonous cultures of the genera Arachis, Beta, Brassica, Cucumis, Cucurbita, Helianthus, Daucus, Glycine, Gossypium, Ipomoea, Lactuca, Linum, Lycopersicon, Nicotiana, Phaseolus, Pisum, Solanum, Vicia, or monocotyledonous cultures Genera Allium, Ananas, Asparagus, Avena, Hordeum, Oryza, Panicum, Saccharum, Secale, Sorghum, Triticale, Triticum and Zea. In addition, some of the compositions according to the invention have outstanding growth-regulatory properties in the crop plants. They intervene to regulate the plant's own metabolism and can therefore be used to specifically influence plant constituents and to facilitate harvesting, for example by triggering desiccation and growth stunted growth. Furthermore, they are also suitable for the general control and inhibition of undesired vegetative growth without killing the plants. Inhibition of vegetative growth plays an important role in many monocotyledonous and dicotyledonous crops, since lodging can be reduced or completely prevented as a result. Because of their herbicidal and plant growth-regulating properties, the compositions can be used for controlling harmful plants in known crops or in tolerant crops that are yet to be developed and have been modified by conventional mutagenesis or genetically modified. The transgenic plants are generally distinguished by particularly advantageous properties, in addition to resistance to the agents according to the invention, for example resistance to plant diseases or pathogens of plant diseases such as certain insects or microorganisms such as fungi, bacteria or viruses. Other special properties concern e.g. B. the crop in terms of quantity, quality, shelf life, composition and special ingredients. Thus, transgenic plants with an increased starch content or altered starch quality or those with a different fatty acid composition in the harvested crop are known. Other special properties can be found in tolerance or resistance to abiotic stressors, e.g. B. heat, cold, drought, salt and ultraviolet radiation. The active compound combinations according to the invention can preferably be used as herbicides in crops of useful plants which are resistant to the phytotoxic effects of the herbicides or have been made resistant by genetic engineering. Conventional ways of producing new plants that have modified properties compared to previously existing plants include, for example, classical breeding methods and the generation of mutants. Alternatively, new plants with modified properties can be produced using genetic engineering methods (see, for example, EP-A-0221044, EP-A-0131624). For example, in several cases it has been described - genetic engineering modifications of crop plants for the purpose of modifying the starch synthesized in the plants (eg WO 92/11376, WO 92/14827, WO 91/19806), - transgenic crop plants which are resistant to other herbicides , for example against sulfonylureas (EP-A-0257993, US-A-5013659), - transgenic crop plants with the ability to produce Bacillus thuringiensis toxins (Bt toxins), which make the plants resistant to certain pests (EP-A- 0142924, EP-A-0193259). - Transgenic crop plants with modified fatty acid composition (WO 91/13972). - Genetically modified crops with new ingredients or secondary substances, e.g. B. new phytoalexins that cause increased disease resistance (EPA 309862, EPA0464461) - genetically modified plants with reduced photorespiration that show higher yields and higher stress tolerance (EPA 0305398). - Transgenic crops that produce pharmaceutically or diagnostically important proteins ("molecular pharming") - Transgenic crops that are characterized by higher yields or better quality - Transgenic crops that are distinguished by a combination of e.g. B. distinguish the above-mentioned new properties ("gene stacking") Numerous molecular biological techniques with which new transgenic plants with modified properties can be produced are known in principle; see e.g. BI Potrykus and G. Spangenberg (eds.) Gene Transfer to Plants, Springer Lab Manual (1995), Springer Verlag Berlin, Heidelberg. or Christou, "Trends in Plant Science" 1 (1996) 423-431). For such genetic engineering manipulations, nucleic acid molecules can be introduced into plasmids, which allow mutagenesis or sequence modification by recombination of DNA sequences. Using standard procedures, e.g. B. base exchanges are made, partial sequences are removed or natural or synthetic sequences are added. To connect the DNA fragments to one another, adapters or linkers can be attached to the fragments, see e.g. B. Sambrook et al., 1989, Molecular Cloning, A Laboratory Manual, 2nd ed. Cold Spring Harbor Laboratory Press, Cold Spring Harbor, NY; or Winnacker "Gene und Klone", VCH Weinheim 2nd edition 1996. The production of plant cells with a reduced activity of a gene product can be achieved, for example, by expressing at least one corresponding antisense RNA, a sense RNA to achieve a cosuppression effect or expression at least one appropriately constructed ribozyme which specifically cleaves transcripts of the above gene product. For this purpose, on the one hand, DNA molecules can be used which include the entire coding sequence of a gene product, including any flanking sequences present, as well as DNA molecules which only include parts of the coding sequence, these parts having to be long enough to enter the cells produce an antisense effect. It is also possible to use DNA sequences which have a high degree of homology to the coding sequences of a gene product but are not completely identical. When nucleic acid molecules are expressed in plants, the synthesized protein can be located in any compartment of the plant cell. However, in order to achieve localization in a specific compartment, e.g. B. the coding region can be linked to DNA sequences that ensure localization in a specific compartment. Such sequences are known to those skilled in the art (see, for example, Braun et al., EMBO J.11 (1992), 3219-3227; Wolter et al., Proc. Natl. Acad. Sci. USA 85 (1988), 846-850; Sonnewald et al., Plant J.1 (1991), 95-106). The expression of the nucleic acid molecules can also take place in the organelles of the plant cells. The transgenic plant cells can be regenerated into whole plants using known techniques. In principle, the transgenic plants can be plants of any desired plant species, ie both monocotyledonous and dicotyledonous plants. It is thus possible to obtain transgenic plants which have modified properties as a result of overexpression, suppression or inhibition of homologous (=natural) genes or gene sequences or expression of heterologous (=foreign) genes or gene sequences. The active substance combinations according to the invention can preferably be used in transgenic cultures which are tolerant or have been made tolerant to the active substances used. The active substance combinations according to the invention can preferably also be used in transgenic cultures which are active against growth substances, such as e.g. B. dicamba or against herbicides that destroy essential plant enzymes, e.g. B. acetolactate synthases (ALS), EPSP synthases, glutamine synthases (GS), hydroxyphenylpyruvate dioxygenases (HPPD), or protoporphyrinogen oxidase (PPO) inhibit, or against herbicides from the group of sulfonylureas, glyphosate, glufosinate or benzoylisoxazoles and analogous active ingredients are resistant . The invention therefore also provides a method for controlling undesired plant growth, if appropriate in crops of useful plants, preferably in non-crop land or in plantation crops, characterized in that one or more herbicides of type (A) are used with one or more herbicides of type (B). applied to the harmful plants, parts of plants or plant seeds (seeds) thereof or the cultivated area. The invention also relates to the use of the new combinations of compounds (A)+(B) for controlling harmful plants, if appropriate in crops of useful plants, preferably in non-crop land and plantation crops, but also for controlling harmful plants before sowing the following useful plant, such as in particular for Seed preparation ("burn-down application"). The active ingredient combinations according to the invention can be present both as mixed formulations of the two components, optionally with other active ingredients, additives and / or customary formulation auxiliaries, which are then diluted with water in the usual way for use, or as so-called Tank mixes can be prepared by diluting together the separately formulated or partially separately formulated components with water Compounds (A) and (B) or combinations thereof can be formulated in various ways, depending on the biological and/or chemico-physical ones n parameters are specified. Examples of general formulation options are: wettable powder (WP), water-soluble powder (SP), emulsifiable concentrates (EC), water-soluble concentrates, aqueous solutions (SL), emulsions (EW) such as oil-in-water and water-in- Oil emulsions, sprayable solutions or emulsions, oil or water-based dispersions, oil dispersions (OD), suspoemulsions, suspension concentrates (SC), oil-miscible solutions, capsule suspensions (CS), dusts (DP), dressings, granules for floor or scatter application, Granules (GR) in the form of Micro, spray, elevator and adsorption granules, water dispersible granules (WG), water soluble granules (SG), ULV formulations, microcapsules or waxes. The invention therefore also relates to herbicidal and plant growth-regulating compositions which contain the active compound combinations according to the invention. The individual formulation types are known in principle and are described, for example, in: Winnacker-Küchler, "Chemical Technology", Volume 7, C. Hanser Verlag Munich, 4th edition 1986; van Valkenburg, "Pesticides Formulations", Marcel Dekker NY, 1973; K. Martens, "Spray Drying Handbook", 3rd Ed. 1979, G. Goodwin Ltd. London. The necessary formulation aids such as inert materials, surfactants, solvents and other additives are also known and are described, for example, in: Watkins, "Handbook of Insecticide Dust Diluents and Carriers", 2nd Ed., Darland Books, Caldwell NJ; Hv Olphen, "Introduction to Clay Colloid Chemistry"; 2nd Ed., J. Wiley & Sons, NY Marsden, "Solvents Guide", 2nd Ed., Interscience, NY 1963; McCutcheon's, "Detergents and Emulsifiers Annual", MC Publ. Corp., Ridegewood NJ; Sisley and Wood, "Encyclopedia of Surface Active Agents", Chem. Publ. Co. Inc., NY1964; Schönfeldt, "Interface-active ethylene oxide adducts", Wiss. Verlagsgesellschaft, Stuttgart 1976, Winnacker-Küchler, "Chemical Technology", Volume 7, C. Hanser Verlag Munich, 4th edition 1986. On the basis of these formulations, combinations with other pesticidally active substances, such as other herbicides, fungicides, Insecticides or other pesticides (e.g. acaricides, nematicides, molluscicides, rodenticides, aphicides, avicides, larvicides, ovicides, bactericides, virucides, etc.), as well as safeners, fertilizers and/or growth regulators, for example in the form of a finished formulation or as tank mix. Wettable powders are evenly water-dispersible preparations which, in addition to the active ingredient and a diluent or inert substance, also contain ionic and/or nonionic surfactants (wetting agents, dispersing agents), e.g , 2,2'-dinaphthylmethane-6,6'-sodium disulfonate, sodium dibutylnaphthalenesulfonate or sodium oleoylmethyltaurine. To prepare the wettable powders, the herbicidal active ingredients are finely ground, for example in conventional apparatus such as hammer mills, blower mills and air jet mills, and mixed simultaneously or subsequently with the formulation auxiliaries. Emulsifiable concentrates are prepared by dissolving the active ingredient in an organic solvent, for example butanol, cyclohexanone, dimethylformamide, xylene or higher-boiling aromatics or hydrocarbons or mixtures of organic solvents, with the addition of one or more ionic and/or nonionic surfactants (emulsifiers). Examples of emulsifiers that can be used are: alkylarylsulfonic acid calcium salts such as calcium dodecylbenzenesulfonate or nonionic emulsifiers such as fatty acid polyglycol esters, alkylaryl polyglycol ethers, fatty alcohol polyglycol ethers, propylene oxide-ethylene oxide condensation products, alkyl polyethers, sorbitan esters such as sorbitan fatty acid esters or such. B. Polyoxyethylene sorbitan fatty acid esters. Dusts are obtained by grinding the active ingredient with finely divided solid substances, for example talc, natural clays such as kaolin, bentonite and pyrophyllite, or diatomaceous earth. Suspension concentrates can be water or oil based. They can be prepared, for example, by wet grinding using commercially available bead mills and optionally adding surfactants, such as those already listed above for the other types of formulation. Emulsions, for example oil-in-water emulsions (EW), can be prepared, for example, using stirrers, colloid mills and/or static mixers using aqueous organic solvents and, if appropriate, surfactants, such as those already listed above for the other types of formulation. Granules can be produced either by spraying the active ingredient onto adsorptive, granulated inert material or by applying active ingredient concentrates using adhesives, eg polyvinyl alcohol, sodium polyacrylic acid or mineral oils, to the surface of carriers such as sand, kaolinite or granulated inert material. Suitable active ingredients can also be granulated in the manner customary for the production of fertilizer granules--if desired in a mixture with fertilizers. Water dispersible granules are typically produced by methods such as spray drying, fluidized bed granulation, pan granulation, mixing with high speed mixers and extrusion without solid inert material. The agrochemical preparations usually contain 0.1 to 99% by weight, in particular 0.2 to 95% by weight, of active ingredients of types (A) and/or (B), the following concentrations being usual depending on the type of formulation: In wettable powders, the active substance concentration is, for example, about 10 to 95% by weight, the remainder to 100% by weight consists of customary formulation components. In the case of emulsifiable concentrates, the active substance concentration can be about 1 to 90% by weight, preferably 5 to 80% by weight. Formulations in dust form usually contain 5 to 20% by weight of active ingredient, and sprayable solutions contain about 0.05 to 80, preferably 2 to 50 percent by weight (% by weight) of active ingredient. In the case of granules, such as dispersible granules, the active ingredient content depends in part on whether the active compound is in liquid or solid form and on the granulation aids and fillers used. In general, the content in the water-dispersible granules is between 1 and 95% by weight, preferably between 10 and 80% by weight. In addition, the active ingredient formulations mentioned may contain the customary adhesives, wetting agents, dispersants, emulsifiers, penetration agents, preservatives, antifreeze agents and solvents, fillers, colorants and carriers, defoamers, evaporation inhibitors and agents that lower the pH affect value or viscosity. For use, the formulations, which are in commercially available form, are diluted, if appropriate, in a customary manner, for example using water in the case of wettable powders, emulsifiable concentrates, dispersions and water-dispersible granules. Preparations in the form of dust, ground or scattered granules, and sprayable solutions are usually not diluted with other inert substances before use. The active compounds can be applied to the plants, parts of plants, plant seeds or the area under cultivation (arable land), preferably to the green plants and plant parts and optionally also to the arable land. One possible application is the joint application of the active ingredients in the form of tank mixes, with the optimally formulated, concentrated formulations of the individual active ingredients being mixed together with water in the tank and the spray mixture obtained being applied. A joint herbicidal formulation of the combination of active ingredients (A) and (B) according to the invention has the advantage of being easier to use because the amounts of the components are already set in the correct ratio to one another. In addition, the auxiliaries in the formulation can be optimally matched to one another, while a tank mix of different formulations can result in undesirable combinations of auxiliaries. A. Formulation examples of a general nature a) A dust is obtained by mixing 10 parts by weight (=parts by weight) of an active ingredient (A) or (B) or of an active ingredient mixture (A)+(B) (and optionally other active ingredient components) and/or or their salts and 90 parts by weight of talc as an inert substance and comminuted in a hammer mill. b) A water-dispersible, wettable powder is obtained by mixing 25 parts by weight of an active ingredient/active ingredient mixture, 64 parts by weight of kaolin-containing quartz as the inert substance, 10 parts by weight of potassium lignosulfonate and 1 part by weight of sodium oleoylmethyltaurine mixed as a wetting and dispersing agent and ground in a pin mill. c) A dispersion concentrate that is easily dispersible in water is obtained by mixing 20 parts by weight of an active ingredient/active ingredient mixture with 6 parts by weight of alkylphenol polyglycol ether (®Triton X 207), 3 parts by weight of isotridecanol polyglycol ether (8 EO) and 71 parts by weight -Parts of paraffinic mineral oil (boiling range, for example, approx. 255 to 277 °C) and ground in a ball mill to a fineness of less than 5 microns. d) An emulsifiable concentrate is obtained from 15 parts by weight of an active substance/active substance mixture, 75 parts by weight of cyclohexanone as solvent and 10 parts by weight of ethoxylated nonylphenol as emulsifier. e) Water-dispersible granules are obtained by mixing 75 parts by weight of an active ingredient/active ingredient mixture, 10 parts by weight of calcium lignosulfonate, 5 parts by weight of sodium lauryl sulfate, 3 parts by weight of polyvinyl alcohol and 7 parts by weight of kaolin , ground on a pin mill and the powder granulated in a fluidized bed by spraying on water as the granulating liquid. f) A water-dispersible granulate is also obtained by mixing 25 parts by weight of an active ingredient/active ingredient mixture, 5 parts by weight of sodium 2,2'-dinaphthylmethane-6,6'-disulphonate, 2 parts by weight of sodium oleoylmethyltaurine , 1 part by weight polyvinyl alcohol, 17 parts by weight calcium carbonate and 50 parts by weight of water are homogenized and precomminuted in a colloid mill, then ground in a bead mill and the suspension thus obtained is atomized in a spray tower using a single-component nozzle and dried. B. Biological Examples When the combinations according to the invention are used, herbicidal effects on a harmful plant species are frequently observed which exceed the formal sum of the effects of the herbicides present when they are applied alone. Alternatively, it can be observed in some cases that a lower application rate for the herbicide combination is required to achieve the same effect on a harmful plant species as compared to the individual preparations. Such increases in action or increases in effectiveness or savings in the amount applied are a strong indication of a synergistic effect. If the observed effect values already exceed the formal sum of the values for the tests with individual applications, then they also exceed the expected value according to Colby, which is calculated using the following formula and is also regarded as an indication of synergism (cf. SR Colby; in Weeds 15 ( 1967) p.20 to 22): E C = A+B - (A·B/100) where: A = effect of the active ingredient (A) in % at an application rate of a [g ai/ha]; B=effect of the active ingredient (B) in % at an application rate of b [g ai/ha]; E C = Expected value of the effect of the combination (A)+(B) in % at the combined application rate a+b [g ai/ha]. The observed values ( EA ) of the experiments show, at suitable low doses, an effect of the combinations that is above the expected values according to Colby ( EC ) (∆). Post-emergence weed action Seeds of monocotyledonous and dicotyledonous weeds were placed in sandy loam soil in pots, covered with soil and grown in the greenhouse under good growth conditions (temperature, humidity, water supply). Two to three weeks after sowing, the test plants in the two-leaf to four-leaf stage were treated with the agents according to the invention. The agents according to the invention, formulated as a wettable powder or as an emulsion concentrate, were different dosages with a water application rate of the equivalent of 300 l/ha on the green parts of the plant. After the test plants had been left in the greenhouse under optimal growth conditions for 3 weeks, the effect of the preparations was scored visually in comparison with untreated controls. In this context, effects of the combinations according to the invention were frequently observed which exceed the formal sum of the effects when the herbicides are applied individually. 100% effectiveness means complete control of the weed tested. 0% effectiveness means no control of the respective tested weed. The biological results of the compositions according to the invention are summarized in Tables 3.1 - 3.12 below. The sum of the effects of the individual applications is given under E A ; Expected values according to Colby are given under E C ; The scoring period is given in days after application (DAT). Table 3.1: Synergistic effect (∆) for post-emergence herbicidal binary compositions when applied to Amaranthus palmeri (AMAPA)
Tabelle 3.2: Synergistischer Effekt (∆) für herbizide binäre Zusammensetzungen im Nachauflauf bei Applikation auf Amaranthus palmeri (AMAPA_R = resistenter Biotyp)
Tabelle 3.3: Synergistischer Effekt (∆) für herbizide binäre Zusammensetzungen im Nachauflauf bei Applikation auf Avena fatua (AVEFA)
Tabelle 3.4: Synergistischer Effekt (∆) für herbizide binäre Zusammensetzungen im Nachauflauf bei Applikation auf Bidens pilosa (BIDPI)
Table 3.2: Synergistic effect (∆) for post-emergence herbicidal binary compositions when applied to Amaranthus palmeri (AMAPA_R = resistant biotype) Table 3.3: Synergistic effect (∆) for post-emergence herbicidal binary compositions when applied to Avena fatua (AVEFA) Table 3.4: Post-emergence synergistic effect (∆) for binary herbicidal compositions when applied to Bidens pilosa (BIDPI)
Tabelle 3.5: Synergistischer Effekt (∆) für herbizide binäre Zusammensetzungen im Nachauflauf bei Applikation auf Brachiaria platyphylla (BRAPP)
Table 3.5: Post-emergence synergistic effect (∆) for binary herbicidal compositions when applied to Brachiaria platyphylla (BRAPP)
Tabelle 3.6: Synergistischer Effekt (∆) für herbizide binäre Zusammensetzungen im Nachauflauf bei Applikation auf Centaurea cyanus (CENCY)
Table 3.6: Synergistic effect (∆) for post-emergence herbicidal binary compositions when applied to Centaurea cyanus (CENCY)
Tabelle 3.7: Synergistischer Effekt (∆) für herbizide binäre Zusammensetzungen im Nachauflauf bei Applikation auf Echinochloa crus-galli (ECHCG)
Table 3.7: Post-emergence synergistic effect (∆) for binary herbicidal compositions when applied to Echinochloa crus-galli (ECCHG)
Tabelle 3.8: Synergistischer Effekt (∆) für herbizide binäre Zusammensetzungen im Nachauflauf bei Applikation auf Eleusine inidca (ELEIN)
Tabelle 3.9: Synergistischer Effekt (∆) für herbizide binäre Zusammensetzungen im Nachauflauf bei Applikation auf Brassia scoparia (KCHSC)
Table 3.8: Synergistic effect (∆) for post-emergence herbicidal binary compositions when applied to Eleusine inidca (ELEIN) Table 3.9: Synergistic effect (∆) for post-emergence herbicidal binary compositions when applied to Brassia scoparia (KCHSC)
Tabelle 3.10: Synergistischer Effekt (∆) für herbizide binäre Zusammensetzungen im Nachauflauf bei Applikation auf Lolium rigidum (LOLRI)
Table 3.10: Synergistic effect (∆) for post-emergence herbicidal binary compositions when applied to Lolium rigidum (LOLRI)
Tabelle 3.11: Synergistischer Effekt (∆) für herbizide binäre Zusammensetzungen im Nachauflauf bei Applikation auf Ipomoea purpurea (PHBPU)
Table 3.11: Post-emergence synergistic effect (∆) for binary herbicidal compositions when applied to Ipomoea purpurea (PHBPU)
Tabelle 3.12: Synergistischer Effekt (∆) für herbizide binäre Zusammensetzungen im Nachauflauf bei Applikation auf Sorghum halepense (SORHA)
Table 3.12: Post-emergence synergistic effect (∆) for binary herbicidal compositions when applied to Sorghum halepense (SORHA)
Die beobachteten Werte der Versuche, wie sei in den vorstehend aufgeführten Tabellen B3.1-B3.12 dargestellt sind, zeigten bei geeigneten niedrigen Dosierungen eine Wirkung der erfindungsgemäßen Kombinationen auf verschiedenste Unkräuter Amaranthus palmeri (AMAPA bzw. AMAPA_R = sensitiver (AMAPA) bzw. resistenter (AMAPA_R) Biotyp), Avena fatua (AVEFA), Bidens pilosa (BIDPI), Centaurea cyanus (CENCY), Brachiaria platyphylla (BRAPP), Echinochloa crus-galli (ECHCG), Eleusine inidca (ELEIN), Kochia scoparia (KCHSC), Lolium rigidum (LOLRI), Ipomoea purpurea (PHBPU), Sorghum halepense (SORHA), die über den Erwartungswerten nach Colby liegen.
The values observed in the experiments, as shown in Tables B3.1-B3.12 above, showed an effect of the combinations according to the invention on a wide variety of weeds Amaranthus palmeri (AMAPA or AMAPA_R = more sensitive (AMAPA) or resistant (AMAPA_R) biotype), Avena fatua (AVEFA), Bidens pilosa (BIDPI), Centaurea cyanus (CENCY), Brachiaria platyphylla (BRAPP), Echinochloa crus-galli (ECHCG), Eleusine inidca (ELEIN), Kochia scoparia (KCHSC) , Lolium rigidum (LOLRI), Ipomoea purpurea (PHBPU), Sorghum halepense (SORHA), which are above the expected values according to Colby.
Claims
Patentansprüche 1. Zusammensetzungen enthaltend herbizid wirksame Verbindungen (A) und (B) wobei (A) für eine oder mehrere Verbindungen der allgemeinen Formel (I) oder deren agrochemisch verträglichen Salze [Komponente (A)] steht,
worin R1 für Wasserstoff steht, R2 für Wasserstoff, Fluor, Chlor, Brom, Trifluormethyl, Methoxy, Ethoxy, Prop-1-yloxy, But-1-yloxy steht, R3 für Wasserstoff, Fluor, Chlor, Brom, Methoxy, Ethoxy, Prop-1-yloxy, Prop-2-yloxy, But-1-yloxy, But-2-yloxy, 2-Methylprop-1-yloxy, 1,1-Dimethyleth-1-yloxy steht, R4 für Fluor, Chlor, Brom, Cyano, NO2, C(O)NH2, C(S)NH2, Trifluormethyl, Difluormethyl, Pentafluorethyl, Ethinyl, Propin-1-yl, 1-Butin-1-yl, Pentin-1-yl, Hexin-1-yl steht, R5, R6 und R7 unabhängig voneinander für Wasserstoff, Fluor, Chlor, Brom, Iod, Cyano, Methyl, Ethyl, Prop-1-yl, 1-Methylethyl, But-1-yl, 1-Methylpropyl, 2-Methylpropyl, 1,1-Dimethylethyl, n-Pentyl, 1-Methylbutyl, 2-Methylbutyl, 3-Methylbutyl, 1,1-Dimethylpropyl, 1,2-Dimethylpropyl, 2,2-Dimethylpropyl, 1-Ethylpropyl, n-Hexyl, 1-Methylpentyl, 2-Methylpentyl, 3-Methylpentyl, 4-Methylpentyl, 1,1-Dimethylbutyl, 1,2-Dimethylbutyl, 1,3-Di-methylbutyl, 2,2-Dimethylbutyl, 2,3-Dimethylbutyl, 3,3-Dimethylbutyl, 1-Ethylbutyl, 2-Ethylbutyl, 1,1,2-Trimethylpropyl, 1,2,2-Trimethylpropyl, 1-Ethyl-1-methylpropyl, 1-Ethyl-2-methylpropyl, Trifluormethyl, Difluormethyl, Pentafluorethyl, 2,2-Difluorethyl, 2,2,2-Trifluorethyl, Methoxy, Ethoxy, Prop-1-yloxy, Prop-2-yloxy, But-1-yloxy, But-2-yloxy,
2-Methylprop-1-yloxy, 1,1-Dimethyleth-1-yloxy, Difluormethoxy, Trifluormethoxy, Pentafluorethoxy, 2,2-Difluorethoxy, 2,2,2-Trifluorethoxy stehen, G für Methylen, (Methyl)methylen, (Ethyl)methylen, (Prop-1-yl)methylen, (Prop-2- yl)methylen, (But-1-yl)methylen, (But-2-yl)methylen, (Pent-1-yl)methylen, (Pent-2- yl)methylen, (Pent-3-yl)methylen, (Dimethyl)methylen, (Diethyl)methylen, Ethylen, n-Propylen, (1-Methyl)ethyl-1-en, (2-Methyl)ethyl-1-en, n-Butylen, 1-Methylpropyl-1- en, 2-Methylpropyl-1-en, 3-Methylpropyl-1-en, 1,1-Dimethylethyl-1-en, 2,2-Dimethylethyl-1-en, 1-Ethylethyl-1-en, 2-Ethylethyl-1-en, 1-(Prop-1-yl)ethyl-1-en, 2-(Prop-1-yl)ethyl-1-en, 1-(Prop-2-yl)ethyl-1-en, 2-(Prop-2-yl)ethyl-1-en, 1,1,2-Trimethylethyl-1-en, 1,2,2-Trimethylethyl-1-en, 1,1,2,2-Tetramethylethyl-1-en, n-Pentylen, 1-Methylbutyl-1-en, 2-Methylbutyl-1-en, 3-Methylbutyl-1-en, 4-Methylbutyl-1-en, 1,1-Dimethylpropyl-1-en, 2,2-Dimethylpropyl-1-en, 3,3-Dimethylpropyl-1-en, 1,2-Dimethylpropyl-1-en, 1,3-Dimethylpropyl-1-en, 1-Ethylpropyl-1-en, n-Hexylen, 1-Methylpentyl-1-en, 2-Methylpentyl-1-en, 3-Methylpentyl-1-en, 4-Methylpentyl-1-en, 1,1-Dimethylbutyl-1-en, 1,2-Dimethylbutyl- 1-en, 1,3-Di-methylbutyl-1-en, 2,2-Dimethylbutyl-1-en, 2,3-Dimethylbutyl-1-en, 3,3-Dimethylbutyl-1-en, 1-Ethylbutyl-1-en, 2-Ethylbutyl-1-en, 1,1,2-Trimethylpropyl-1- en, 1,2,2-Trimethylpropyl-1-en, 1-Ethyl-1-methylpropyl-1-en, 1-Ethyl-2-methylpropyl- 1-en steht, X und Y unabhängig voneinander für O (Sauerstoff) oder S (Schwefel) stehen und Q für eine der nachfolgend spezifisch genannten Gruppierungen Q-1 bis Q-54, Q-56 bis Q-57, Q-60 bis Q-89, Q-91 bis Q-129, Q-131 bis Q-139, Q-141 bis Q-144, Q-146 bis Q-180, Q-182 bis Q-185, Q-193 bis Q-195, Q-200 bis Q-208, Q-210 bis Q-370, Q-395 bis Q-440 steht:
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Claims 1. Compositions containing herbicidally active compounds (A) and (B), where (A) represents one or more compounds of the general formula (I) or their agrochemically compatible salts [component (A)], wherein R 1 is hydrogen, R 2 is hydrogen, fluoro, chloro, bromo, trifluoromethyl, methoxy, ethoxy, prop-1-yloxy, but-1-yloxy, R 3 is hydrogen, fluoro, chloro, bromo, methoxy, ethoxy, prop-1-yloxy, prop-2-yloxy, but-1-yloxy, but-2-yloxy, 2-methylprop-1-yloxy, 1,1-dimethyleth-1-yloxy, R 4 is fluoro, Chlorine, bromine, cyano, NO 2 , C(O)NH 2 , C(S)NH 2 , trifluoromethyl, difluoromethyl, pentafluoroethyl, ethynyl, propyn-1-yl, 1-butyn-1-yl, pentyn-1-yl , hexyn-1-yl, R 5 , R 6 and R 7 are independently hydrogen, fluoro, chloro, bromo, iodo, cyano, methyl, ethyl, prop-1-yl, 1-methylethyl, but-1-yl , 1-methylpropyl, 2-methylpropyl, 1,1-dimethylethyl, n-pentyl, 1-methylbutyl, 2-methylbutyl, 3-methylbutyl, 1,1-dimethylpropyl, 1,2-dimethylpropyl, 2,2-dimethylpropyl, 1 -ethylpropyl, n-hexyl, 1-methylpentyl, 2-methylpentyl, 3-methylpentyl, 4-methylpentyl, 1,1-dimethylbutyl, 1,2-dimethylbutyl, 1,3-dimethylbutyl, 2,2-dimethylbutyl, 2 ,3-dimethylbutyl, 3,3-dimethylbutyl, 1-ethyl lbutyl, 2-ethylbutyl, 1,1,2-trimethylpropyl, 1,2,2-trimethylpropyl, 1-ethyl-1-methylpropyl, 1-ethyl-2-methylpropyl, trifluoromethyl, difluoromethyl, pentafluoroethyl, 2,2-difluoroethyl, 2,2,2-trifluoroethyl, methoxy, ethoxy, prop-1-yloxy, prop-2-yloxy, but-1-yloxy, but-2-yloxy, 2-methylprop-1-yloxy, 1,1-dimethyleth-1-yloxy, difluoromethoxy, trifluoromethoxy, pentafluoroethoxy, 2,2-difluoroethoxy, 2,2,2-trifluoroethoxy, G is methylene, (methyl)methylene, (ethyl )methylene, (prop-1-yl)methylene, (prop-2-yl)methylene, (but-1-yl)methylene, (but-2-yl)methylene, (pent-1-yl)methylene, (Pent -2-yl)methylene, (pent-3-yl)methylene, (dimethyl)methylene, (diethyl)methylene, ethylene, n-propylene, (1-methyl)ethyl-1-ene, (2-methyl)ethyl- 1-ene, n-butylene, 1-methylpropyl-1-ene, 2-methylpropyl-1-ene, 3-methylpropyl-1-ene, 1,1-dimethylethyl-1-ene, 2,2-dimethylethyl-1- en, 1-ethylethyl-1-ene, 2-ethylethyl-1-ene, 1-(prop-1-yl)ethyl-1-ene, 2-(prop-1-yl)ethyl-1-ene, 1- (Prop-2-yl)ethyl-1-ene, 2-(Prop-2-yl)ethyl-1-ene, 1,1,2-Trimethylethyl-1-ene, 1,2,2-Trimethylethyl-1- en, 1,1,2,2-tetramethylethyl-1-ene, n-pentylene, 1-methylbutyl-1-ene, 2-methylbutyl-1-ene, 3-methylbutyl-1-ene, 4-methylbutyl-1- en, 1,1-dimethylpropyl-1-ene, 2,2-dimethylpropyl-1-ene, 3,3-dimethylpropyl-1-ene, 1,2-dimethylpropyl-1-ene, 1,3-dimethylpr opyl-1-ene, 1-ethylpropyl-1-ene, n-hexylene, 1-methylpentyl-1-ene, 2-methylpentyl-1-ene, 3-methylpentyl-1-ene, 4-methylpentyl-1-ene, 1,1-dimethylbutyl-1-ene, 1,2-dimethylbutyl-1-ene, 1,3-dimethylbutyl-1-ene, 2,2-dimethylbutyl-1-ene, 2,3-dimethylbutyl-1- en, 3,3-dimethylbutyl-1-ene, 1-ethylbutyl-1-ene, 2-ethylbutyl-1-ene, 1,1,2-trimethylpropyl-1-ene, 1,2,2-trimethylpropyl-1-ene en, 1-ethyl-1-methylpropyl-1-ene, 1-ethyl-2-methylpropyl-1-ene, X and Y independently represent O (oxygen) or S (sulphur) and Q represents one of the following specifically mentioned groups Q-1 to Q-54, Q-56 to Q-57, Q-60 to Q-89, Q-91 to Q-129, Q-131 to Q-139, Q-141 to Q-144, Q-146 to Q-180, Q-182 to Q-185, Q-193 to Q-195, Q-200 to Q-208, Q-210 to Q-370, Q-395 to Q-440 says: '' '
und (B) für ein oder mehrere Herbizide [Komponente (B)] aus der Gruppe der herbiziden Wirkstoffe (B1) bis (B11) steht, worin
(B1) für herbizide Wirkstoffe aus der Gruppe der nachstehend genannten 1,3-Diketoverbindungen steht (B1.1) Alloxydim, (CAS 55634-91-8), (CAS 55635-13-7) (B1.2) Bicyclopyrone, (CAS 352010-68-5) (B1.3) Butroxydim, (CAS 138164-12-2) (B1.4) Clethodim, (CAS 99129-21-2) (B1.5) Cycloxydim, (CAS 101205-02-1) (B1.6) Fenquinotrione, (CAS 1342891-70-6) (B1.7) Mesotrione, (CAS 104206-82-8) (B1.8) Pinoxaden, (CAS 243973-20-8) (B1.9) Profoxydim, (CAS 139001-49-3) (B1.10) Sethoxydim, (CAS 74051-80-2) (B1.11) Sulcotrione, (CAS 99105-77-8) (B1.12) SYP-9121 (CAS 1976053-87-8) (B1.13) Tefuryltrione, (CAS 473278-76-1) (B1.14) Tembotrione, (CAS 335104-84-2) (B1.15) Tepraloxydim, (CAS 149979-41-9) (B1.16) Tralkoxydim, (CAS 87820-88-0) (B1.17) Y13161, (CAS 1639426-14-4) (B1.18) Y13287 (CAS 1639426-42-8) (B2) für herbizide Wirkstoffe aus der Gruppe der nachstehend genannten (Sulfon)Amide steht (B2.1) Acetochlor, (CAS 34256-82-1) (B2.2) Alachlor, (CAS 15972-60-8) (B2.3) Amidosulfuron, (CAS 120923-37-7) (B2.4) Asulam, (CAS 3337-71-1), (CAS 14089-43-1), (CAS 2302-17-2) (B2.5) Azimsulfuron, (CAS 120162-55-2) (B2.6) Beflubutamid, (CAS 113614-08-7), (CAS 113614-09-8) (B2.7) Bensulfuron, (CAS 83055-99-6), (CAS 83055-99-6) (B2.8) Butachlor, (CAS 23184-66-99) (B2.9) Carbetamide, (CAS 16118-49-3) (B2.10) Chlorimuron, (CAS 99283-00-8), (CAS 90982-32-4) (B2.11) Chlorpropham, (CAS 101-21-3) (B2.12) Chlorsulfuron, (CAS 64902-72-3)
(B2.13) Cinosulfuron, (CAS 94593-91-6) (B2.14) Cloransulam, (CAS159518-97-5), (CAS 147150-35-4) (B2.15) Cyclosulfamuron, (CAS 136849-15-5) (B2.16) Desmedipham, (CAS 13684-56-5) (B2.17) Diclosulam, (CAS 145701-21-9) (B2.18) Diflufenican, (CAS 83164-33-4) (B2.19) Dimethachlor, (CAS 50563-36-5) (B2.20) Dimethenamid, (CAS 87674-68-8), (CAS 163515-14-8) (B2.21) Esprocarb (CAS 85785-20-2) (B2.22) Ethametsulfuron, (CAS 111353-84-5), (CAS 97780-06-8) (B2.23) Ethoxysulfuron, (CAS 126801-58-9) (B2.24) Flazasulfuron, (CAS 104040-78-0) (B2.25) Florasulam, (CAS 145701-23-1) (B2.26) Flucarbazone, (CAS 145026-88-6), (CAS 181274-17-9) (B2.27) Flucetosulfuron, (CAS 412928-75-7) (B2.28) Flufenacet, (CAS 142459-58-3) (B2.29) Flumetsulam, (CAS 98967-40-9) (B2.30) Flupyrsulfuron, (CAS 150315-10-9), (CAS 144740-53-4), (CAS 144740-54-5) (B2.31) Foramsulfuron, (CAS 173159-57-4) (B2.32) Halosulfuron, (CAS 135397-30-7), (CAS 100784-20-1) (B2.33) Imazosulfuron, (CAS 122548-33-8) (B2.34) Iodosulfuron, (CAS 185119-76-0), (CAS 144550-06-1), (CAS 144550-36-7) (B2.35) Ipfencarbazone, (CAS 212201-70-2) (B2.36) Mefenacet, (CAS 73250-68-7) (B2.37) Mesosulfuron, (CAS 400852-66-6), (CAS 208465-21-8) (B2.38) Metazachlor, (CAS 67129-08-2) (B2.39) Metazosulfuron, (CAS 868680-84-6) (B2.40) Metolachlor, (CAS 51218-45-2) (B2.41) Metosulam, (CAS 139528-85-1) (B2.42) Metsulfuron, (CAS 79510-48-8), (CAS 74223-64-6) (B2.43) Nicosulfuron, (CAS 111991-09-4) (B2.44) Orthosulfamuron, (CAS 213464-77-8) (B2.45) Oxasulfuron, (CAS 144651-06-9) (B2.46) Penoxsulam, (CAS 219714-96-2)
(B2.47) Pethoxamide, (CAS 106700-29-2) (B2.48) Phenmedipham, (CAS 13684-63-4) (B2.49) Picolinafen, (CAS 137641-05-5) (B2.50) Pretilachlor, (CAS 51218-49-6) (B2.51) Primisulfuron, (CAS 113036-87-6), (CAS 86209-51-0) (B2.52) Propachlor, (CAS 1918-16-7) (B2.53) Propanil, (CAS 709-98-8) (B2.54) Propham, (CAS 122-42-9) (B2.55) Propisochlor, (CAS 86763-47-5) (B2.56) Propoxycarbazone, (CAS 145026-81-9), (CAS 181274-15-7) (B2.57) Propyrisulfuron, (CAS 570415-88-2) (B2.58) Propyzamide, (CAS 23950-58-5) (B2.59) Prosulfocarb, (CAS 52888-80-9) (B2.60) Prosulfuron, (CAS 94125-34-5) (B2.61) Pyrazosulfuron, (CAS 98389-04-9), (CAS 93697-74-6) (B2.62) Pyroxsulam, (CAS 422556-08-9) (B2.63) Rimsulfuron, (CAS 122931-48-0) (B2.64) S-metolachlor, (CAS 87392-12-9) (B2.65) Sulfometuron, (CAS 74223-56-6), (CAS 74222-97-2), (CAS 144651-06-9) (B2.66) Sulfosulfuron, (CAS 141776-32-1) (B2.67) Thenylchlor, (CAS 96491-05-3) (B2.68) Thiencarbazone, (CAS 936331-72-5), (CAS 317815-83-1) (B2.69) Thifensulfuron, (CAS 79277-67-1), (CAS 79277-27-3) (B2.70) Tri-allat, (CAS 2303-17-5) (B2.71) Triasulfuron, (CAS 82097-50-5) (B2.72) Tribenuron, (CAS 106040-48-6), (CAS 101200-48-0) (B2.73) Trifloxysulfuron, (CAS 145099-21-4, (CAS 199119-58-9) (B2.74) Triflusulfuron, (CAS 135990-29-3), (CAS 126535-15-7) (B2.75) Tritosulfuron, (CAS 142469-14-5) (B2.76) Esprocarb, (CAS 85785-20-2) (B2.77) Profluazol, (CAS 190314-43-3) (B2.78) Tri-allate, (CAS 2303-17-5) (B2.79) Methyl rel-(2R,4R)-4-[[3-(3,5-dichlorophenyl)-5-methoxy-4H-isoxazol-5- carbonyl]amino]tetrahydrofuran-2-carboxylat, (B2.80) Methyl rel-(2R,4R)-4-[[3-(3,5-dichlorophenyl)-5-vinyl-4H-isoxazol-5-
carbonyl]amino]tetrahydrofuran-2-carboxylat, (B2.81) Methyl –rel-(2R,4R)-4-[[(5S)-3-(3,5-difluorophenyl)-5-vinyl-4H-isoxazol-5- carbonyl]amino]tetrahydrofuran-2-carboxylat, (B2.82) Isopropyl rel-(2R,4R)-4-[[3-(3-fluorophenyl)-5-methyl-4H-isoxazol-5- carbonyl]amino]tetrahydrofuran-2-carboxylat, (B2.83) Methyl (3R)-3-[[(5S)-3-(3,5-difluorophenyl)-5-vinyl-4H-isoxazol-5- carbonyl]amino]-2,3-dihydrofuran-5-carboxylat, (B2.84) Methyl (3R)-3-[[(5R)-3-(3,5-difluorophenyl)-5-methyl-4H-isoxazol-5- carbonyl]amino]-2,3-dihydrofuran-5-carboxylat, (B2.85) Methyl (1S,4R)-4-[[[(5S)-3-(3,5-difluorphenyl)-5-vinyl-4H-1,2-oxazol-5- yl]carbonyl]amino]-cyclopent-2-en-1-carboxylat, (B2.86) Ethyl (1S,4R)-4-[[[3-(3,5-difluorphenyl)-5-methoxy-4H-1,2-oxazol-5- yl]carbonyl]amino]cyclopent-2-en-1-carboxylat, (B2.87) 2-Methoxyethyl (1S,4R)-4-[[[(5R)-3-(3-cyano-5-fluorphenyl)-5- (trifluormethyl)-4H-1,2-oxazol-5-yl]carbonyl]amino]cyclopent-2-en-1- carboxylat, (B2.88) Methyl (4S)-4-[[[3-(3,5-difluorphenyl)-5-methyl-4H-1,2-oxazol-5- yl]carbonyl]amino]cyclopenten-1-carboxylat, (B2.89) Methyl (3S)-3-[[[(5R)-3-(3,5-difluorphenyl)-5-methyl-4H-1,2-oxazol-5- yl]carbonyl]amino]-cyclopenten-1-carboxylat, (B2.90) 3-(3,5-Difluorphenyl)-N-[(1R,4S)-4-(oxazinan-2-ylcarbonyl)cyclopent-2-en-1- yl]-5-(trifluormethyl)-4H-1,2-oxazol-5-carboxamid, (B2.91) 3-(3,5-Difluorphenyl)-N-[(1R,4S)-4- [(propylsulfonylamino)carbonyl]cyclopent-2-en-1-yl]-5-(trifluormethyl)-4H- 1,2-oxazol-5-carboxamid, (B2.92) (1S,4R)-4-[[(5R)-3-(3,5-difluorophenyl)-5-methyl-4H-isoxazol-5- carbonyl]amino]cyclopent-2-ene-1-carbonsäure (B3) für herbizide Wirkstoffe aus der Gruppe der nachstehend geannten Arylnitrile steht (B3.1) Bromoxynil, (CAS 1689-84-5), (CAS 3861-41-4), (CAS 56634-95-8), (CAS 1689-99-2), (CAS 2961-68-4) (B3.2) Chlorthiamid, (CAS 1918-13-4) (B3.3) Dichlobenil, (CAS 1194-65-6) (B3.4) Ioxynil, (CAS 1689-83-4), (CAS 2961-61-7), (CAS 3861-47-0), (CAS 2961-62-8)
(B3.5) Pyraclonil (CAS 158353-15-2) (B4) für herbizide Wirkstoffe aus der Gruppe der nachstehend genannten Azole steht (B4.1) Amicarbazone, (CAS 129909-90-6) (B4.2) Amitrole, (CAS 61-82-5) (B4.3) Azafenidin, (CAS 68049-83-2) (B4.4) Benzofenap, (CAS 82692-44-2) (B4.5) Benzuofucaotong (CAS 1992017-55-6) (B4.6) Biscarfentrazone (CAS 1622908-18-2) (B4.7) Cafenstrole, (CAS 125306-83-4) (B4.8) Carfentrazone, (CAS 128621-72-7), (CAS128639-02-1) (B4.9) Fentrazamide, (CAS 158237-07-1) (B4.10) Imazamethabenz, (CAS 100728-84-5), (CAS 81405-85-8) (B4.11) Imazamox, (CAS 114311-32-9), (CAS 247057-22-3) (B4.12) Imazapic, (CAS 104098-48-8), (CAS 115136-53-3) (B4.13) Imazapyr, (CAS 81334-34-1), (CAS 81510-83-0) (B4.14) Imazaquin, (CAS 81335-37-7), (CAS 81335-47-9), (CAS 81335-43-5), (CAS 81335-46-8) (B4.15) Imazethapyr, (CAS 81335-77-5), (CAS 101917-66-2) (B4.16) Isouron, (CAS 55861-78-4) (B4.17) Isoxaben, (CAS 82558-50-7) (B4.18) Isoxaflutole, (CAS 141112-29-0) (B4.19) Oxadiargyl, (CAS 39807-15-3) (B4.20) Oxadiazon, (CAS 19666-30-9) (B4.21) Pyraflufen, (CAS 129630-17-7), (CAS 129630-19-9) (B4.22) Pyrasulfotole, (CAS 365400-11-9) (B4.23) Pyrazolynate, (CAS 58011-68-0) (B4.24) Pyrazoxyfen, (CAS 71561-11-0) (B4.25) Pyroxasulfone, (CAS 447399-55-5) (B4.26) Sulfentrazone, (CAS 122836-35-5) (B4.27) Tolpyralate, (CAS 1101132-67-5) (B4.28) Topramezone, (CAS 210631-68-8) (B4.29) Triazolesulcotrione (QYR- (CAS 1911613-97-2) 301), (B4.30) QYM-201, (CAS 1855925-45-1) (B4.31) Bencarbazone, (CAS 173980-17-1)
(B4.32) Fluazolate, (CAS 174514-07-9) (B4.33) Flupoxam, (CAS 119126-15-7) (B4.34) Isoxachlortole; (CAS 141112-06-3) (B5) für weitere herbizide Wirkstoffe steht, ausgewählt aus (B5.1) Aminocyclopyrachlor, (CAS 858956-08-8), (CAS 858954-83-3), (CAS 858956-35-1) (B5.2) Aminopyralid, (CAS 150114-71-9), (CAS 566191-87-5), (CAS 566191-89-7) (B5.3) Benazolin-ethyl, (CAS 3813-05-6), (CAS 38561-76-1), (CAS 25059-80-7), (CAS 67338-65-2) (B5.4) Benfluralin, (CAS 1861-40-1) (B5.5) Bentazone, (CAS 25057-89-0), (CAS 50723-80-3) (B5.6) Benzobicyclon, (CAS 156963-66-5) (B5.8) Bromofenoxim, (CAS 13181-17-4) (B5.9) Butralin, (CAS 33629-47-9) (B5.10) Chloridazon/Pyrazon, (CAS 1698-60-8) (B5.11) Chlorthal, (CAS 2136-79-0), (CAS 1861-32-1), (CAS 887-54-7) (B5.12) Cinidon-ethyl, (CAS 142891-20-1) (B5.13) Cinmethylin, (CAS 87818-31-3) (B5.14) Clomazone, (CAS 81777-89-1) (B5.15) Cyclopyrimorat, (CAS 499231-24-2) (B5.16) Dinitramine, (CAS 29091-05-2) (B5.17) Diquat, (CAS 2764-72-9), (CAS 85-00-7), (CAS 4032-26-2) (B5.18) Dithiopyr, (CAS 97886-45-8) (B5.19) Essigsäure, (CAS 64-19-7) (B5.20) Ethalfluralin, (CAS 55283-68-6) (B5.21) Ethofumesate, (CAS 26225-79-6) (B5.22) Flamprop, (CAS 58667-63-3, (CAS 90134-59-1), (CAS 63782-90-1), (CAS 63729-98-6) (B5.23) Florpyrauxifen, (CAS 943832-81-3), (CAS 1390661-72-9) (B5.24) Flufenpyr, (CAS 188490-07-5), (CAS 188489-07-8)
(B5.25) Flumiclorac, (CAS 87547-04-4), (CAS 87546-18-7) (B5.26) Flumioxazin, (CAS 103361-09-7) (B5.27) Fluridone, (CAS 59756-60-4) (B5.28) Flurochloridone, (CAS 61213-25-0) (B5.29) Flurtamone, (CAS 96525-23-4) (B5.30) Fluthiacet-methyl, (CAS 149253-65-6) (B5.31) Halauxifen, (CAS 943832-60-8), (CAS 943831-98-9) (B5.32) Indanofan, (CAS 13320-30-1) (B5.33) Norflurazon, (CAS 27314-13-2) (B5.34) Oleinsäure (CAS 112-80-1) (B5.35) Oryzalin, (CAS 19044-88-3) (B5.36) Oxaziclomefone, (CAS 153197-14-9) (B5.37) Paraquat, (CAS 4685-14-7), (CAS 1910-42-5), (CAS 2074-50-2) (B5.38) Pelargonsäure, (CAS 112-05-0) (B5.39) Pendimethalin, (CAS 40487-42-1) (B5.40) Pentoxazone, (CAS 110956-75-7) (B5.41) Pyridafol, (CAS 40020-01-7) (B5.42) Pyridate, (CAS 55512-33-9) (B5.43) Tetflupyrolimet, (CAS 2053901-33-8) (B5.44) Thiazopyr, (CAS 117718-60-2) (B5.45) Triafamone, (CAS 874195-61-6) (B5.46) Trifluralin, (CAS 1582-09-8) (B5.47) 4-Amino-3-chloro-5-fluoro- 6-(7-fluoro-1H-indol-6- yl)pyridine-2-carbonsäure, (B5.48) Cyclopyrimorate, (CAS 499231-24-2) (B5.49) Diquat, (CAS 2764-72-9), (CAS 85-00-7), (CAS4032-26-2) (B5.50) Oxaziclomefone, (CAS 153197-14-9) (B5.51) Pentanochlor, (CAS 2307-68-8) (B5.52) Tebutam, (CAS 35256-85-0) (B5.53) Thidiazimin, (CAS 123249-43-4) (B5.54) 4-Hydroxy-1-methyl-3-[4- (CAS 1708087-22-2) (trifluoromethyl)-2- pyridinyl]-2-imidazolidinon
(B6) für herbizide Wirkstoffe aus der Gruppe der nachstehend genannten (Het)Arylcarbonsäuren steht (B6.1) Chloramben, (CAS 133-90-4), (CAS 1076-46-6), (CAS 53404-16-3), (CAS 7286-84-2), (CAS 25182-03-0), (CAS 1954-81-0) (B6.2) Clopyralid, (CAS 1702-17-6), (CAS 1532-24-7), (CAS 57754-85-5), (CAS 58509-83-4), (CAS 73455-09-1) (B6.3) Dicamba, (CAS 1918-00-9), (CAS 1286239-22-2), (CAS 104040-79-1), (CAS 2300-66-5), (CAS 25059-78-3), (CAS 55871-02-8), (CAS 6597-78-0), (CAS 53404-28-7), (CAS 10007-85-9), (CAS 1982-69-0), (53404-29-8), (CAS 56141-00-5) (B6.4) Fluroxypyr, (CAS 69377-81-7), (CAS -27-8), (CAS 81406-37-3) (B6.5) Picloram, (CAS 1918-02-1), (CAS 55870-98-9), (CAS 36374-99-9), (CAS 26952-20-5), (CAS 14143-55-6), (CAS 55871-00-6), (CAS 2545-60-0), (CAS 35832-11-2), (CAS 6753-47-5), (CAS 82683-78-1) (B6.6) Quinclorac, (CAS 84087-01-4), (CAS 84087-48-9), (CAS 84087-33-2) (B6.7) Quinmerac, (CAS 90717-03-6) (B6.8) TBA, (CAS 50-31-7), (CAS 3426-62-8), (CAS 71750-37-3), (CAS 4559-30-2), (CAS 2078-42-4) (B6.9) Triclopyr (CAS 55335-06-3), (CAS [64700-56-7), (CAS 1048373-85-8), (CAS 60825-27-6), (CAS 57213-69-1) (B7) für herbizide Wirkstoffe aus der Gruppe der nachstehend genannten organischen Phosphorverbindungen steht (B7.1) Anilofos, (CAS 64249-01-0) (B7.2) Bialaphos, (CAS 35597-43-4), (CAS 71048-99-2) (B7.3) Butamifos, (CAS 36335-67-8) (B7.4) Glufosinate, (CAS 51276-47-2), (CAS 35597-44-5),
(CAS 77182-82-2), (CAS 70033-13-5) (B7.5) Glyphosate, (CAS 1071-83-6), (CAS 69254-40-6), (CAS 34494-04-7), (CAS 38641-94-0), (CAS 40465-66-5), (CAS 39600-42-5), (CAS 70393-85-0), (CAS 81591-81-3) (B7.6) Piperophos, (CAS 24151-93-7) (B7.7) Sulfosate, (CAS 1591-81-3) (B7.8) Amiprofos (CAS 33857-23-7), (CAS 36001-88-4) (B8) für herbizide Wirkstoffe aus der Gruppe der nachstehend genannten Phenylether steht (B8.1) 2,4-D, (CAS 94-75-7), (CAS 2307-55-3), (CAS 1929-73-3), (CAS 1320-18-9), (CAS 1928-45-6), (CAS 94-80-4), (CAS 1048373-72-3), (CAS 20940-37-8), (CAS 2008-39-1), (CAS 5742-19-8), (CAS 2212-54-6), (CAS 533-23-3), (CAS 1928-43-4), (CAS 37102-63-9), (CAS 713-15-1), (CAS 25168-26-7), (CAS 94-11-1), (CAS 5742-17-6), (CAS 3766-27-6), (CAS 1917-97-1), (CAS 1928-38-7), (CAS 1928-44-5), (CAS 1917-92-6), (CAS 1928-61-6), (CAS 2702-72-9), (CAS 15146-99-3), (CAS 28685-18-9), (CAS 2646-78-8), (CAS 18584-79-7), (CAS 2569-01-9), (CAS 215655-76-8) (B8.2) 2,4-DB, (CAS 94-82-6), (CAS 2758-42-1), (CAS 1320-15-6), (CAS 19480-40-1), (CAS 10433-59-7) (B8.3) 2,4-DP, (CAS 120-36-5), (CAS 53404-31-2), (CAS 53404-32-3), (CAS 79270-78-3), (CAS 28631-35-8), (CAS 57153-17-0), (CAS 5746-17-8), (CAS 39104-30-8) (B8.4) Acifluorfen, (CAS 50594-66-6), (CAS 50594-67-7), (CAS 62476-59-9) (B8.5) Aclonifen, (CAS 74070-46-5)
(B8.6) Bifenox, (CAS 42576-02-3) (B8.7) Chlomethoxyfen, (CAS 32861-85-1) (B8.8) Clodinafop- (CAS 114420-56-3), (CAS 105512-06-9) propargyl, (B8.9) Clomeprop, (CAS 84496-56-0) (B8.10) Cyhalofop, (CAS 122008-78-0), (CAS 122008-85-9) (B8.11) Diclofop, (CAS 40843-25-2), (CAS 51338-27-3) (B8.12) Ethoxyfen, (CAS 188634-90-4), (CAS 131086-42-5) (B8.13) Fenoxaprop, (CAS 95617-09-7), (CAS 113158-40-0), (CAS 71283-80-2) (B8.14) Fluazifop, (CAS 69335-91-7), (CAS 83066-88-0), (CAS 79241-46-6) (B8.15) Fluoroglycofen, (CAS 77501-60-1), (CAS 77501-90-7) (B8.16) Fomesafen, (CAS 72178-02-0), (CAS 108731-70-0) (B8.17) Halosafen, (CAS 77227-69-1) (B8.18) Haloxyfop, (CAS 69806-34-4), (CAS 95977-29-0), (CAS 72619-32-0) (B8.19) Lactofen, (CAS 77501-63-4) (B8.20) MCPA, (CAS 94-74-6), (CAS 19480-43-4), (CAS 1713-12-8), (CAS 2039-46-5), (CAS 20405-19-0), (CAS 2698-38-6), (CAS 29450-45-1), (CAS 1713-11-7), (CAS 26544-20-7), (CAS 2698-40-0), (CAS 2436-73-9), (CAS 6365-62-4), (CAS 5221-16-9), (CAS 3653-48-3), (CAS 42459-68-7) (B8.21) MCPB, (CAS 94-81-5), (CAS 10443-70-6), (CAS 57153-18-1), (CAS 6062-26-6) (B8.22) Mecoprop, (CAS 93-65-2), (CAS 32351-70-5), (CAS 1432-14-0), (CAS 71526-69-7), (CAS 28473-03-2), (CAS 2786-19-8), (CAS 1929-86-8), (CAS 19095-88-6), (CAS 53404-61-8), (CAS 16484-77-8) (B8.23) Metamifop, (CAS 256412-89-2) (B8.24) Oxyfluorfen, (CAS 42874-03-3) (B8.25) Propaquizafop, (CAS 111479-05-1)
(B8.26) Quizalofop, (CAS 76578-12-6), (CAS 76578-14-8), (B8.27) Quizalofop-P, (CAS 94051-08-8), (CAS 100646-51-3), (CAS 200509-41-7) (B8.28) Benzfendizone (CAS 158755-95-4) (B9) für herbizide Wirkstoffe aus der Gruppe der nachstehend genannten Pyrimidine steht (B9.1) Bispyrac-sodium, (CAS 125401-92-5) (B9.2) Bromacil, (CAS 314-40-9), (CAS 53404-19-6), (CAS 69484-12-4) (B9.3) Butafenacil, (CAS 134605-64-4) (B9.4) Lenacil, (CAS 2164-08-1) (B9.5) Pyribenzoxim, (CAS 168088-61-7) (B9.6) Pyriftalid, (CAS 135186-78-6) (B9.7) Pyriminobac, (CAS 136191-56-5), (CAS 136191-64-5) (B9.8) Pyrimisulfan, (CAS 221205-90-9) (B9.9) Pyrithiobac-sodium, (CAS 123342-93-8), (CAS 123343-16-8) (B9.10) Saflufenacil, (CAS 372137-35-4) (B9.11) Terbacil, (CAS 5902-51-2) (B9.12) Tiafenacil, (CAS 1220411-29-9) (B9.13) Trifludimoxazin, (CAS 1258836-72-4) (B9.14) Ethyl[3-[2-chloro-4-fluoro-5- (CAS 353292-31-6) (1-methyl-6-trifluoromethyl- 2,4-dioxo-1,2,3,4- tetrahydropyrimidin-3- yl)phenoxy]-2- pyridyloxy]acetat (B10) für herbizide Wirkstoffe aus der Gruppe der nachstehend genannten (Thio)harnstoffe steht (B10.1) Chlorobromuron, (CAS 13360-45-7) (B10.2) Chlorotoluron, (CAS 15545-48-9) (B10.3) Daimuron, (CAS 42609-52-9) (B10.4) Dimefuron, (CAS 34205-21-5) (B10.5) Diuron, (CAS 330-54-1) (B10.6) Diflufenzopyr (CAS 1957168-02-3) (B10.7) Fluometuron, (CAS 2164-17-2) (B10.8) Isoproturon, (CAS 34123-59-6)
(B10.9) Linuron, (CAS 330-55-2) (B10.10) Methabenzthiazuron, (CAS 18691-97-9) (B10.11) Metobromuron, (CAS 3060-89-7) (B10.12) Metoxuron, (CAS 19937-59-8) (B10.13) Monolinuron, (CAS 1746-81-2) (B10.14) Neburon, (CAS 555-37-3) (B10.15) Siduron, (CAS 1982-49-6) (B10.16) Tebuthiuron, (CAS 34014-18-1) (B10.17) Fenuron, (CAS 101-42-8) (B10.18) Chloroxuron, (CAS 1982-47-4) (B10.19) Diflufenzopyr, (CAS 1957168-02-3), (CAS 109293-98-3) (B10.20) Ethidimuron (CAS 30043-49-3) (B11) für herbizide Wirkstoffe aus der Gruppe der nachstehend genannten Triazine steht (B11.1) Ametryne, (CAS 834-12-8) (B11.2) Atrazine, (CAS 1912-24-9) (B11.3) Cyanazine, (CAS 21725-46-2) (B11.4) Dimethametryn, (CAS 22936-75-0) (B11.5) Hexazinone, (CAS 51235-04-2) (B11.6) Indaziflam, (CAS 950782-86-2) (B11.7) Metamitron, (CAS 41394-05-2) (B11.8) Metribuzin, (CAS 21087-64-9) (B11.9) Prometon, (CAS 1610-18-0) (B11.10) Prometryne, (CAS 7287-19-6) (B11.11) Propazine, (CAS 139-40-2) (B11.12) Simazine, (CAS 122-34-9) (B11.13) Simetryne, (CAS 1014-70-6) (B11.14) Terbumeton, (CAS 33693-04-8) (B11.15) Terbuthylazine, (CAS 5915-41-3) (B11.16) Terbutryne, (CAS 886-50-0) (B11.17) Triaziflam, (CAS 131475-57-5) (B11.18) Trietazine, (CAS 1912-26-1) (B11.19) Desmetryne (CAS 1014-69-3) 2. Zusammensetzung gemäß Anspruch 1, wobei die Komponente (A) der allgemeinen Formel (I) dadurch definiert ist, dass
R1 für Wasserstoff steht, R2 für Fluor steht, R3 für Fluor steht, R4 für Chlor, Brom, oder Cyano steht, R5 für Wasserstoff steht, R6 für Wasserstoff, Fluor steht, R7 für Wasserstoff steht, G für Methylen steht, X für O (Sauerstoff) steht, Y für O (Sauerstoff) steht, und Q für eine der spezifisch genannten Gruppierungen
and (B) represents one or more herbicides [component (B)] from the group of the herbicidally active compounds (B1) to (B11), in which (B1) stands for herbicidal active ingredients from the group of 1,3-diketo compounds mentioned below (B1.1) Alloxydim, (CAS 55634-91-8), (CAS 55635-13-7) (B1.2) Bicyclopyrone, ( CAS 352010-68-5) (B1.3) Butroxydim, (CAS 138164-12-2) (B1.4) Clethodime, (CAS 99129-21-2) (B1.5) Cycloxydim, (CAS 101205-02- 1) (B1.6) Fenquinotrione, (CAS 1342891-70-6) (B1.7) Mesotrione, (CAS 104206-82-8) (B1.8) Pinoxaden, (CAS 243973-20-8) (B1. 9) Profoxydim, (CAS 139001-49-3) (B1.10) Sethoxydim, (CAS 74051-80-2) (B1.11) Sulcotrione, (CAS 99105-77-8) (B1.12) SYP-9121 (CAS 1976053-87-8) (B1.13) Tefuryltrione, (CAS 473278-76-1) (B1.14) Tembotrione, (CAS 335104-84-2) (B1.15) Tepraloxydim, (CAS 149979-41 -9) (B1.16) Tralkoxydim, (CAS 87820-88-0) (B1.17) Y13161, (CAS 1639426-14-4) (B1.18) Y13287 (CAS 1639426-42-8) (B2) (B2.1) acetochlor, (CAS 34256-82-1) (B2.2) alachlor, (CAS 15972-60-8) (B2.3) amidosulfuron stands for herbicidal active ingredients from the group of (sulfone)amides mentioned below , (CAS 120923-37-7) (B2.4) Asulam, (CAS 3337-71-1), (CAS 14089-43-1), (CAS 2302-17-2) (B2.5) Azimsulfuron, (CAS 120162-55-2) (B2.6) Beflubutamide, (CAS 113614-08-7), (CAS 113614-09-8) (B2.7) Bensulfuron, (CAS 83055-99-6), (CAS 83055-99-6) (B2.8) Butachlor, (CAS 23184-66-99) (B2.9) Carbetamide, (CAS 16118-49-3) (B2.10) Chlorimuron, (CAS 99283-00-8), (CAS 90982-32-4) (B2.11) Chlorpropham, (CAS 101-21-3) (B2.12) Chlorsulfuron, (CAS 64902-72-3) (B2.13) Cinosulfuron, (CAS 94593-91-6) (B2.14) Cloransulam, (CAS159518-97-5), (CAS 147150-35-4) (B2.15) Cyclosulfamuron, (CAS 136849-15). -5) (B2.16) Desmedipham, (CAS 13684-56-5) (B2.17) Diclosulam, (CAS 145701-21-9) (B2.18) Diflufenican, (CAS 83164-33-4) (B2 .19) Dimethachlor, (CAS 50563-36-5) (B2.20) Dimethenamid, (CAS 87674-68-8), (CAS 163515-14-8) (B2.21) Esprocarb (CAS 85785-20-2). ) (B2.22) ethametsulfuron, (CAS 111353-84-5), (CAS 97780-06-8) (B2.23) ethoxysulfuron, (CAS 126801-58-9) (B2.24) flazasulfuron, (CAS 104040 -78-0) (B2.25) Florasulam, (CAS 145701-23-1) (B2.26) Flucarbazone, (CAS 145026-88-6), (CAS 181274-17-9) (B2.27) Flucetosulfuron , (CAS 412928-75-7) (B2.28) Flufenacet, (CAS 142459-58-3) (B2.29) Flumetsulam, (CAS 98967-40-9) (B2.30) Flupyrsulfuron, (CAS 150315- 10-9), (CAS 144740-53-4), (CAS 144740-54-5) (B2.31) Foramsulfuron, (CAS 173159-57-4) (B2.32) Halosulfuron, (CAS 135397-30- 7), (CAS 100784-20-1) (B2.33) imazosulfuron, (CAS 122548-33-8) (B2.34) iodosulfuron, (CAS 185119 -76-0), (CAS 144550-06-1), (CAS 144550-36-7) (B2.35) Ipfencarbazone, (CAS 212201-70-2) (B2.36) Mefenacet, (CAS 73250-68 -7) (B2.37) mesosulfuron, (CAS 400852-66-6), (CAS 208465-21-8) (B2.38) metazachlor, (CAS 67129-08-2) (B2.39) metazosulfuron, ( CAS 868680-84-6) (B2.40) metolachlor, (CAS 51218-45-2) (B2.41) metosulam, (CAS 139528-85-1) (B2.42) metsulfuron, (CAS 79510-48- 8), (CAS 74223-64-6) (B2.43) Nicosulfuron, (CAS 111991-09-4) (B2.44) Orthosulfamuron, (CAS 213464-77-8) (B2.45) Oxasulfuron, (CAS 144651-06-9) (B2.46) Penoxsulam, (CAS 219714-96-2) (B2.47) Pethoxamide, (CAS 106700-29-2) (B2.48) Phenmedipham, (CAS 13684-63-4) (B2.49) Picolinafen, (CAS 137641-05-5) (B2.50) Pretilachlor, (CAS 51218-49-6) (B2.51) Primisulfuron, (CAS 113036-87-6), (CAS 86209-51-0) (B2.52) Propachlor, (CAS 1918-16-7) ( B2.53) Propanil, (CAS 709-98-8) (B2.54) Propham, (CAS 122-42-9) (B2.55) Propisochlor, (CAS 86763-47-5) (B2.56) Propoxycarbazone , (CAS 145026-81-9), (CAS 181274-15-7) (B2.57) Propyrisulfuron, (CAS 570415-88-2) (B2.58) Propyzamide, (CAS 23950-58-5) (B2 .59) Prosulfocarb, (CAS 52888-80-9) (B2.60) Prosulfuron, (CAS 94125-34-5) (B2.61) Pyrazosulfuron, (CAS 98389-04-9), (CAS 93697-74- 6) (B2.62) Pyroxsulam, (CAS 422556-08-9) (B2.63) Rimsulfuron, (CAS 122931-48-0) (B2.64) S-metolachlor, (CAS 87392-12-9) ( B2.65) Sulfometuron, (CAS 74223-56-6), (CAS 74222-97-2), (CAS 144651-06-9) (B2.66) Sulfosulfuron, (CAS 141776-32-1) (B2. 67) Thenylchlor, (CAS 96491-05-3) (B2.68) Thiencarbazone, (CAS 936331-72-5), (CAS 317815-83-1) (B2.69) Thifensulfuron, (CAS 792 77-67-1), (CAS 79277-27-3) (B2.70) Tri-allate, (CAS 2303-17-5) (B2.71) Triasulfuron, (CAS 82097-50-5) (B2. 72) tribenuron, (CAS 106040-48-6), (CAS 101200-48-0) (B2.73) trifloxysulfuron, (CAS 145099-21-4, (CAS 199119-58-9) (B2.74) triflusulfuron , (CAS 135990-29-3), (CAS 126535-15-7) (B2.75) Tritosulfuron, (CAS 142469-14-5) (B2.76) Esprocarb, (CAS 85785-20-2) (B2 .77) profluazole, (CAS 190314-43-3) (B2.78) tri-allate, (CAS 2303-17-5) (B2.79) methyl rel-(2R,4R)-4-[[3- (3,5-dichlorophenyl)-5-methoxy-4H-isoxazole-5-carbonyl]amino]tetrahydrofuran-2-carboxylate, (B2.80) methyl rel-(2R,4R)-4-[[3-(3 ,5-dichlorophenyl)-5-vinyl-4H-isoxazole-5- carbonyl]amino]tetrahydrofuran-2-carboxylate, (B2.81) methyl -rel-(2R,4R)-4-[[(5S)-3-(3,5-difluorophenyl)-5-vinyl-4H-isoxazole -5-carbonyl]amino]tetrahydrofuran-2-carboxylate, (B2.82) isopropyl rel-(2R,4R)-4-[[3-(3-fluorophenyl)-5-methyl-4H-isoxazole-5-carbonyl ]amino]tetrahydrofuran-2-carboxylate, (B2.83) methyl (3R)-3-[[(5S)-3-(3,5-difluorophenyl)-5-vinyl-4H-isoxazole-5-carbonyl]amino ]-2,3-dihydrofuran-5-carboxylate, (B2.84) methyl (3R)-3-[[(5R)-3-(3,5-difluorophenyl)-5-methyl-4H-isoxazole-5- carbonyl]amino]-2,3-dihydrofuran-5-carboxylate, (B2.85) methyl (1S,4R)-4-[[[(5S)-3-(3,5-difluorophenyl)-5-vinyl- 4H-1,2-oxazol-5-yl]carbonyl]amino]cyclopent-2-ene-1-carboxylate, (B2.86) ethyl (1S,4R)-4-[[[3-(3,5 -difluorophenyl)-5-methoxy-4H-1,2-oxazol-5-yl]carbonyl]amino]cyclopent-2-ene-1-carboxylate, (B2.87) 2-Methoxyethyl (1S,4R)-4- [[[(5R)-3-(3-cyano-5-fluorophenyl)-5-(trifluoromethyl)-4H-1,2-oxazol-5-yl]carbonyl]amino]cyclopent-2-en-1-carboxylate , (B2.88) methyl (4S)-4-[[[3-(3,5-difluorophenyl)-5-methyl-4H -1,2-oxazol-5-yl]carbonyl]amino]cyclopentene-1-carboxylate, (B2.89) methyl (3S)-3-[[[(5R)-3-(3,5-difluorophenyl)- 5-methyl-4H-1,2-oxazol-5-yl]carbonyl]amino]cyclopentene-1-carboxylate, (B2.90) 3-(3,5-difluorophenyl)-N-[(1R,4S) -4-(oxazinan-2-ylcarbonyl)cyclopent-2-en-1-yl]-5-(trifluoromethyl)-4H-1,2-oxazole-5-carboxamide, (B2.91) 3-(3,5 -difluorophenyl)-N-[(1R,4S)-4-[(propylsulfonylamino)carbonyl]cyclopent-2-en-1-yl]-5-(trifluoromethyl)-4H-1,2-oxazole-5-carboxamide, (B2.92) (1S,4R)-4-[[(5R)-3-(3,5-difluorophenyl)-5-methyl-4H-isoxazol-5-carbonyl]amino]cyclopent-2-ene-1 -carboxylic acid (B3) stands for herbicidal active substances from the group of the aryl nitriles mentioned below (B3.1) bromoxynil, (CAS 1689-84-5), (CAS 3861-41-4), (CAS 56634-95-8), (CAS 1689-99-2), (CAS 2961-68-4) (B3.2) Chlorothiamide, (CAS 1918-13-4) (B3.3) Dichlobenil, (CAS 1194-65-6) (B3. 4) Ioxynil, (CAS 1689-83-4), (CAS 2961-61-7), (CAS 3861-47-0), (CAS 2961-62-8) (B3.5) Pyraclonil (CAS 158353-15-2) (B4) stands for herbicidal active substances from the group of the azoles mentioned below (B4.1) Amicarbazone, (CAS 129909-90-6) (B4.2) Amitrole, (CAS 61-82-5) (B4.3) azafenidin, (CAS 68049-83-2) (B4.4) benzofenap, (CAS 82692-44-2) (B4.5) benzuofucaotong (CAS 1992017-55- 6) (B4.6) Biscarfentrazone (CAS 1622908-18-2) (B4.7) Cafenstrole, (CAS 125306-83-4) (B4.8) Carfentrazone, (CAS 128621-72-7), (CAS128639- 02-1) (B4.9) fentrazamide, (CAS 158237-07-1) (B4.10) imazamethabenz, (CAS 100728-84-5), (CAS 81405-85-8) (B4.11) imazamox, (CAS 114311-32-9), (CAS 247057-22-3) (B4.12) imazapic, (CAS 104098-48-8), (CAS 115136-53-3) (B4.13) imazapyr, (CAS 81334-34-1), (CAS 81510-83-0) (B4.14) Imazaquin, (CAS 81335-37-7), (CAS 81335-47-9), (CAS 81335-43-5), ( CAS 81335-46-8) (B4.15) Imazethapyr, (CAS 81335-77-5), (CAS 101917-66-2) (B4.16) Isouron, (CAS 55861-78-4) (B4.17 ) Isoxaben, (CAS 82558-50-7) (B4.18) Isoxaflutole, (CAS 141112-29-0) (B4.19) Oxadiargyl, (CAS 39807-15-3) (B4 .20) Oxadiazon, (CAS 19666-30-9) (B4.21) Pyraflufen, (CAS 129630-17-7), (CAS 129630-19-9) (B4.22) Pyrasulfotole, (CAS 365400-11- 9) (B4.23) Pyrazolynates, (CAS 58011-68-0) (B4.24) Pyrazoxyfen, (CAS 71561-11-0) (B4.25) Pyroxasulfones, (CAS 447399-55-5) (B4. 26) Sulfentrazone, (CAS 122836-35-5) (B4.27) Tolpyralate, (CAS 1101132-67-5) (B4.28) Topramezone, (CAS 210631-68-8) (B4.29) Triazolesulcotrione (QYR - (CAS 1911613-97-2) 301), (B4.30) QYM-201, (CAS 1855925-45-1) (B4.31) Bencarbazone, (CAS 173980-17-1) (B4.32) Fluazolates, (CAS 174514-07-9) (B4.33) Flupoxam, (CAS 119126-15-7) (B4.34) Isoxachlortols; (CAS 141112-06-3) (B5) stands for other herbicidal active ingredients selected from (B5.1) aminocyclopyrachlor, (CAS 858956-08-8), (CAS 858954-83-3), (CAS 858956-35- 1) (B5.2) Aminopyralid, (CAS 150114-71-9), (CAS 566191-87-5), (CAS 566191-89-7) (B5.3) Benazoline-ethyl, (CAS 3813-05- 6), (CAS 38561-76-1), (CAS 25059-80-7), (CAS 67338-65-2) (B5.4) Benfluralin, (CAS 1861-40-1) (B5.5) Bentazone , (CAS 25057-89-0), (CAS 50723-80-3) (B5.6) Benzobicyclone, (CAS 156963-66-5) (B5.8) Bromofenoxime, (CAS 13181-17-4) (B5 .9) Butralin, (CAS 33629-47-9) (B5.10) Chloridazone/Pyrazon, (CAS 1698-60-8) (B5.11) Chlorthal, (CAS 2136-79-0), (CAS 1861- 32-1), (CAS 887-54-7) (B5.12) cinidone-ethyl, (CAS 142891-20-1) (B5.13) cinmethyline, (CAS 87818-31-3) (B5.14) Clomazone, (CAS 81777-89-1) (B5.15) Cyclopyrimorate, (CAS 499231-24-2) (B5.16) Dinitramine, (CAS 29091-05-2) (B5.17) Diquat, (CAS 2764 -72-9), (CAS 85-00-7), (CAS 4032-26-2) (B5.18) dithiopyr, (CAS 97886-45-8) (B5.19) acetic acid, (CAS 64-19 -7) (B5.20) ethalfluralin, ( CAS 55283-68-6) (B5.21) Ethofumesate, (CAS 26225-79-6) (B5.22) Flamprop, (CAS 58667-63-3, (CAS 90134-59-1), (CAS 63782- 90-1), (CAS 63729-98-6) (B5.23) Florpyrauxifen, (CAS 943832-81-3), (CAS 1390661-72-9) (B5.24) Flufenpyr, (CAS 188490-07- 5), (CAS 188489-07-8) (B5.25) Flumiclorac, (CAS 87547-04-4), (CAS 87546-18-7) (B5.26) Flumioxazine, (CAS 103361-09-7) (B5.27) Fluridone, (CAS 59756- 60-4) (B5.28) Flurochloridone, (CAS 61213-25-0) (B5.29) Flurtamone, (CAS 96525-23-4) (B5.30) Fluthiacet-methyl, (CAS 149253-65-6 ) (B5.31) Halauxifen, (CAS 943832-60-8), (CAS 943831-98-9) (B5.32) Indanofan, (CAS 13320-30-1) (B5.33) Norflurazon, (CAS 27314 -13-2) (B5.34) Oleic acid (CAS 112-80-1) (B5.35) Oryzalin, (CAS 19044-88-3) (B5.36) Oxaziclomefone, (CAS 153197-14-9) ( B5.37) Paraquat, (CAS 4685-14-7), (CAS 1910-42-5), (CAS 2074-50-2) (B5.38) Pelargonic acid, (CAS 112-05-0) (B5. 39) pendimethalin, (CAS 40487-42-1) (B5.40) pentoxazone, (CAS 110956-75-7) (B5.41) pyridafol, (CAS 40020-01-7) (B5.42) pyridate, ( CAS 55512-33-9) (B5.43) Tetflupyrolimet, (CAS 2053901-33-8) (B5.44) Thiazopyr, (CAS 117718-60-2) (B5.45) Triafamone, (CAS 874195-61- 6) (B5.46) Trifluralin, (CAS 1582-09-8) (B5.47) 4-amino-3-chloro-5-fluoro- 6-(7-fluoro-1H-indol-6-yl)pyridine -2-carboxylic acid, (B5.4 8) Cyclopyrimorate, (CAS 499231-24-2) (B5.49) Diquat, (CAS 2764-72-9), (CAS 85-00-7), (CAS4032-26-2) (B5.50) Oxaziclomefone , (CAS 153197-14-9) (B5.51) pentanochlor, (CAS 2307-68-8) (B5.52) tebutam, (CAS 35256-85-0) (B5.53) thidiazimine, (CAS 123249- 43-4) (B5.54) 4-Hydroxy-1-methyl-3-[4-(CAS 1708087-22-2)(trifluoromethyl)-2-pyridinyl]-2-imidazolidinone (B6) stands for herbicidal active ingredients from the group of (het)arylcarboxylic acids mentioned below (B6.1) chloramben, (CAS 133-90-4), (CAS 1076-46-6), (CAS 53404-16-3) , (CAS 7286-84-2), (CAS 25182-03-0), (CAS 1954-81-0) (B6.2) Clopyralid, (CAS 1702-17-6), (CAS 1532-24-7 ), (CAS 57754-85-5), (CAS 58509-83-4), (CAS 73455-09-1) (B6.3) Dicamba, (CAS 1918-00-9), (CAS 1286239-22- 2), (CAS 104040-79-1), (CAS 2300-66-5), (CAS 25059-78-3), (CAS 55871-02-8), (CAS 6597-78-0), (CAS 53404-28-7), (CAS 10007-85-9), (CAS 1982-69-0), (53404-29-8), (CAS 56141-00-5) (B6.4) Fluroxypyr, (CAS 69377-81-7), (CAS -27-8), (CAS 81406-37-3) (B6.5) Picloram, (CAS 1918-02-1), (CAS 55870-98-9), (CAS 36374-99-9), (CAS 26952-20-5), (CAS 14143-55-6), (CAS 55871-00-6), (CAS 2545-60-0), (CAS 35832-11-2 ), (CAS 6753-47-5), (CAS 82683-78-1) (B6.6) Quinclorac, (CAS 84087-01-4), (CAS 84087-48-9), (CAS 84087-33- 2) (B6.7) Quinmerac, (CAS 90717-03-6) (B6.8) TBA, (CAS 50-31-7), (CAS 3426-62-8), (CAS 71750-37-3) , (CAS 4559-30-2), (C AS 2078-42-4) (B6.9) Triclopyr (CAS 55335-06-3), (CAS [64700-56-7), (CAS 1048373-85-8), (CAS 60825-27-6), (CAS 57213-69-1) (B7) stands for herbicidal active ingredients from the group of organic phosphorus compounds mentioned below (B7.1) Anilofos, (CAS 64249-01-0) (B7.2) Bialaphos, (CAS 35597-43 -4), (CAS 71048-99-2) (B7.3) Butamifos, (CAS 36335-67-8) (B7.4) Glufosinate, (CAS 51276-47-2), (CAS 35597-44-5 ), (CAS 77182-82-2), (CAS 70033-13-5) (B7.5) Glyphosate, (CAS 1071-83-6), (CAS 69254-40-6), (CAS 34494-04-7) , (CAS 38641-94-0), (CAS 40465-66-5), (CAS 39600-42-5), (CAS 70393-85-0), (CAS 81591-81-3) (B7.6) Piperophos, (CAS 24151-93-7) (B7.7) Sulphosate, (CAS 1591-81-3) (B7.8) Amiprofos (CAS 33857-23-7), (CAS 36001-88-4) (B8 ) stands for herbicidal active ingredients from the group of phenyl ethers mentioned below (B8.1) 2,4-D, (CAS 94-75-7), (CAS 2307-55-3), (CAS 1929-73-3), (CAS 1320-18-9), (CAS 1928-45-6), (CAS 94-80-4), (CAS 1048373-72-3), (CAS 20940-37-8), (CAS 2008-39 -1), (CAS 5742-19-8), (CAS 2212-54-6), (CAS 533-23-3), (CAS 1928-43-4), (CAS 37102-63-9), ( CAS 713-15-1), (CAS 25168-26-7), (CAS 94-11-1), (CAS 5742-17-6), (CAS 3766-27-6), (CAS 1917-97- 1), (CAS 1928-38-7), (CAS 1928-44-5), (CAS 1917-92-6), (CAS 1928-61-6), (CAS 2702-72-9), (CAS 15146-99-3), (CAS 28685-18-9), (CAS 2646-78-8), (CAS 18584-79-7), (CAS 2569-01-9), (CAS 215655-76-8 ) (B8.2) 2,4-DB, (CAS 94-82-6), (CAS 2758-42-1), (CA S 1320-15-6), (CAS 19480-40-1), (CAS 10433-59-7) (B8.3) 2,4-DP, (CAS 120-36-5), (CAS 53404-31 -2), (CAS 53404-32-3), (CAS 79270-78-3), (CAS 28631-35-8), (CAS 57153-17-0), (CAS 5746-17-8), ( CAS 39104-30-8) (B8.4) Acifluorfen, (CAS 50594-66-6), (CAS 50594-67-7), (CAS 62476-59-9) (B8.5) Aclonifen, (CAS 74070 -46-5) (B8.6) Bifenox, (CAS 42576-02-3) (B8.7) Chloromethoxyfen, (CAS 32861-85-1) (B8.8) Clodinafop- (CAS 114420-56-3), (CAS 105512- 06-9) propargyl, (B8.9) clomeprop, (CAS 84496-56-0) (B8.10) cyhalofop, (CAS 122008-78-0), (CAS 122008-85-9) (B8.11) diclofop, (CAS 40843-25-2), (CAS 51338-27-3) (B8.12) ethoxyfen, (CAS 188634-90-4), (CAS 131086-42-5) (B8.13) fenoxaprop, (CAS 95617-09-7), (CAS 113158-40-0), (CAS 71283-80-2) (B8.14) Fluazifop, (CAS 69335-91-7), (CAS 83066-88-0) , (CAS 79241-46-6) (B8.15) Fluoroglycofen, (CAS 77501-60-1), (CAS 77501-90-7) (B8.16) Fomesafen, (CAS 72178-02-0), ( CAS 108731-70-0) (B8.17) Halosafe, (CAS 77227-69-1) (B8.18) Haloxyfop, (CAS 69806-34-4), (CAS 95977-29-0), (CAS 72619 -32-0) (B8.19) Lactofen, (CAS 77501-63-4) (B8.20) MCPA, (CAS 94-74-6), (CAS 19480-43-4), (CAS 1713-12 -8), (CAS 2039-46-5), (CAS 20405-19-0), (CAS 2698-38-6), (CAS 29450-45-1), (CAS 1713-11-7), ( CAS 26544-20-7), (CAS 2698-40-0), (CAS 2436-73-9), (CAS 6365-62-4), (CAS 5221-16-9), (CAS 3653-48- 3), (approx S 42459-68-7) (B8.21) MCPB, (CAS 94-81-5), (CAS 10443-70-6), (CAS 57153-18-1), (CAS 6062-26-6) ( B8.22) Mecoprop, (CAS 93-65-2), (CAS 32351-70-5), (CAS 1432-14-0), (CAS 71526-69-7), (CAS 28473-03-2) , (CAS 2786-19-8), (CAS 1929-86-8), (CAS 19095-88-6), (CAS 53404-61-8), (CAS 16484-77-8) (B8.23) metamifop, (CAS 256412-89-2) (B8.24) oxyfluorfen, (CAS 42874-03-3) (B8.25) propaquizafop, (CAS 111479-05-1) (B8.26) Quizalofop, (CAS 76578-12-6), (CAS 76578-14-8), (B8.27) Quizalofop-P, (CAS 94051-08-8), (CAS 100646-51-3 ), (CAS 200509-41-7) (B8.28) Benzfendizone (CAS 158755-95-4) (B9) stands for herbicidal active ingredients from the group of pyrimidines mentioned below (B9.1) bispyrac-sodium, (CAS 125401 -92-5) (B9.2) bromacil, (CAS 314-40-9), (CAS 53404-19-6), (CAS 69484-12-4) (B9.3) butafenacil, (CAS 134605-64). -4) (B9.4) Lenacil, (CAS 2164-08-1) (B9.5) Pyribenzoxime, (CAS 168088-61-7) (B9.6) Pyriftalide, (CAS 135186-78-6) (B9 .7) Pyriminobac, (CAS 136191-56-5), (CAS 136191-64-5) (B9.8) Pyrimisulfan, (CAS 221205-90-9) (B9.9) Pyrithiobac sodium, (CAS 123342- 93-8), (CAS 123343-16-8) (B9.10) saflufenacil, (CAS 372137-35-4) (B9.11) terbacil, (CAS 5902-51-2) (B9.12) tiafenacil, (CAS 1220411-29-9) (B9.13) Trifludimoxazine, (CAS 1258836-72-4) (B9.14) Ethyl[3-[2-chloro-4-fluoro-5- (CAS 353292-31-6 ) (1-methyl-6-trifluoromethyl- 2,4-dioxo-1,2,3,4- tetrahydropyrimidin-3- yl)phenoxy]-2- pyridyloxy]acetate (B10) (B10.1) chlorobromuron, (CAS 13360-45-7) (B10.2) chlorotoluron, (CAS 15545-48-9) (B10.3) daimuron stands for herbicidal active substances from the group of (thio)ureas mentioned below , (CAS 42609-52-9) (B10.4) Dimefuron, (CAS 34205-21-5) (B10.5) Diuron, (CAS 330-54-1) (B10.6) Diflufenzopyr (CAS 1957168-02 -3) (B10.7) Fluometuron, (CAS 2164-17-2) (B10.8) Isoproturon, (CAS 34123-59-6) (B10.9) linuron, (CAS 330-55-2) (B10.10) methabenzthiazuron, (CAS 18691-97-9) (B10.11) metobromuron, (CAS 3060-89-7) (B10.12) Metoxuron, (CAS 19937-59-8) (B10.13) Monolinuron, (CAS 1746-81-2) (B10.14) Neburon, (CAS 555-37-3) (B10.15) Siduron, (CAS 1982 -49-6) (B10.16) tebuthiuron, (CAS 34014-18-1) (B10.17) fenuron, (CAS 101-42-8) (B10.18) chloroxuron, (CAS 1982-47-4) (B10.19) Diflufenzopyr, (CAS 1957168-02-3), (CAS 109293-98-3) (B10.20) Ethidimuron (CAS 30043-49-3) (B11) for herbicidal active substances from the group of the following Triazine is available (B11.1) Ametryne, (CAS 834-12-8) (B11.2) Atrazine, (CAS 1912-24-9) (B11.3) Cyanazine, (CAS 21725-46-2) (B11. 4) Dimethametryn, (CAS 22936-75-0) (B11.5) Hexazinone, (CAS 51235-04-2) (B11.6) Indaziflam, (CAS 950782-86-2) (B11.7) Metamitron, ( CAS 41394-05-2) (B11.8) Metribuzin, (CAS 21087-64-9) (B11.9) Prometon, (CAS 1610-18-0) (B11.10) Prometryne, (CAS 7287-19- 6) (B11.11) Propazine, (CAS 139-40-2) (B11.12) Simazine, (CAS 122-34-9) (B11.13) Sim etryne, (CAS 1014-70-6) (B11.14) terbumetone, (CAS 33693-04-8) (B11.15) terbuthylazine, (CAS 5915-41-3) (B11.16) terbutryne, (CAS 886 -50-0) (B11.17) Triaziflam, (CAS 131475-57-5) (B11.18) Trietazine, (CAS 1912-26-1) (B11.19) Desmetryne (CAS 1014-69-3) 2 Composition according to claim 1, wherein the component (A) of the general formula (I) is defined in that R 1 is hydrogen, R 2 is fluoro, R 3 is fluoro, R 4 is chloro, bromo, or cyano, R 5 is hydrogen, R 6 is hydrogen, fluoro, R 7 is hydrogen, G is methylene, X is O (oxygen), Y is O (oxygen), and Q is one of the moieties specifically mentioned
steht. 3. Zusammensetzung gemäß Anspruch 1, wobei die Komponente (A) der Verbindung (a) Pyridin-2-ylmethyl-[(3-{2-chlor-4-fluor-5-[3-methyl-2,6-dioxo-4-(trifluormethyl)-3,6- dihydropyrimidin-1(2H)-yl]phenoxy}pyridin-2-yl)oxy]acetat, (b) 2-Methoxyethyl-[(3-{2-chlor-4-fluor-5-[3-methyl-2,6-dioxo-4-(trifluormethyl)-3,6- dihydropyrimidin-1(2H)-yl]phenoxy}pyridin-2-yl)oxy]acetat, (c) 2-Methoxyethyl-[(3-{2-cyan-4-fluor-5-[3-methyl-2,6-dioxo-4-(trifluormethyl)-3,6- dihydropyrimidin-1(2H)-yl]phenoxy}pyridin-2-yl)oxy]acetat, oder (d) Cyanmethyl-[(3-{2-brom-4-fluor-5-[3-methyl-2,6-dioxo-4-(trifluormethyl)-3,6- dihydropyrimidin-1(2H)-yl]phenoxy}pyridin-2-yl)oxy]acetat entspricht. 4. Zusammensetzung gemäß einem der Ansprüche 1 bis 3, wobei die Komponente (B) einem oder mehreren Wirkstoffen, ausgewählt aus der Gruppe (B1.2) Bicyclopyrone, (B1.4) Clethodim, (B1.7) Mesotrione,
(B1.8) Pinoxaden, (B1.14) Tembotrione (B2.1) Acetochlor, (B2.18) Diflufenican, (B2.20) Dimethenamid, (B2.24) Flazasulfuron, (B2.28) Flufenacet, (B2.31) Foramsulfuron, (B2.34) Iodosulfuron, (B2.37) Mesosulfuron, (B2.40) Metolachlor, (B2.43) Nicosulfuron, (B2.63) Rimsulfuron, (B2.64) S-metolachlor, (B2.68) Thiencarbazone, (B2.79) Methyl rel-(2R,4R)-4-[[3-(3,5-dichlorophenyl)-5-methoxy-4H-isoxazol-5- carbonyl]amino]tetrahydrofuran-2-carboxylat, (B2.80) Methyl rel-(2R,4R)-4-[[3-(3,5-dichlorophenyl)-5-vinyl-4H-isoxazol-5- carbonyl]amino]tetrahydrofuran-2-carboxylat, (B2.81) Methyl –rel-(2R,4R)-4-[[(5S)-3-(3,5-difluorophenyl)-5-vinyl-4H-isoxazol-5- carbonyl]amino]tetrahydrofuran-2-carboxylat, (B2.82) Isopropyl rel-(2R,4R)-4-[[3-(3-fluorophenyl)-5-methyl-4H-isoxazol-5- carbonyl]amino]tetrahydrofuran-2-carboxylat, (B2.83) Methyl (3R)-3-[[(5S)-3-(3,5-difluorophenyl)-5-vinyl-4H-isoxazol-5- carbonyl]amino]-2,3-dihydrofuran-5-carboxylat, (B2.84) Methyl (3R)-3-[[(5R)-3-(3,5-difluorophenyl)-5-methyl-4H-isoxazol-5- carbonyl]amino]-2,3-dihydrofuran-5-carboxylat, (B2.85) Methyl (1S,4R)-4-[[[(5S)-3-(3,5-difluorphenyl)-5-vinyl-4H-1,2-oxazol-5- yl]carbonyl]amino]-cyclopent-2-en-1-carboxylat, (B2.86) Ethyl (1S,4R)-4-[[[3-(3,5-difluorphenyl)-5-methoxy-4H-1,2-oxazol-5- yl]carbonyl]amino]cyclopent-2-en-1-carboxylat, (B2.87) 2-Methoxyethyl (1S,4R)-4-[[[(5R)-3-(3-cyano-5-fluorphenyl)-5-(trifluormethyl)-4H- 1,2-oxazol-5-yl]carbonyl]amino]cyclopent-2-en-1-carboxylat, (B2.88) Methyl (4S)-4-[[[3-(3,5-difluorphenyl)-5-methyl-4H-1,2-oxazol-5- yl]carbonyl]amino]cyclopenten-1-carboxylat,
(B2.89) Methyl (3S)-3-[[[(5R)-3-(3,5-difluorphenyl)-5-methyl-4H-1,2-oxazol-5- yl]carbonyl]amino]-cyclopenten-1-carboxylat, (B2.90) 3-(3,5-Difluorphenyl)-N-[(1R,4S)-4-(oxazinan-2-ylcarbonyl)cyclopent-2-en-1-yl]-5- (trifluormethyl)-4H-1,2-oxazol-5-carboxamid, (B2.91) 3-(3,5-Difluorphenyl)-N-[(1R,4S)-4-[(propylsulfonylamino)carbonyl]cyclopent-2- en-1-yl]-5-(trifluormethyl)-4H-1,2-oxazol-5-carboxamid, (B2.92) (1S,4R)-4-[[(5R)-3-(3,5-difluorophenyl)-5-methyl-4H-isoxazole-5- carbonyl]amino]cyclopent-2-ene-1-carbonsäure (B3.1) Bromoxynil (B4.8) Carfentrazone, (B4.11) Imazamox, (B4.13) Imazapyr, (B4.15) Imazethapyr, (B4.18) Isoxaflutole, (B4.20) Oxadiazon, (B4.21) Pyraflufen, (B4.22) Pyrasulfotole, (B4.25) Pyroxasulfone, (B4.26) Sulfentrazone, (B4.27) Tolpyralate (B5.5) Bentazone, (B5.14) Clomazone (B5.23) Florpyrauxifen, (B5.26) Flumioxazin, (B5.30) Fluthiacet-methyl, (B5.31) Halauxifen, (B5.37) Paraquat, (B5.38) Pelargonsäure (B6.3) Dicamba (B7.2) Bialaphos, (B7.4) Glufosinate,
(B7.5) Glyphosate, (B7.7) Sulfosate (B8.1) 2,4-D, (B8.2) 2,4-DB, (B8.3) 2,4-DP, (B8.4) Acifluorfen, (B8.5) Aclonifen, (B8.13) Fenoxaprop, (B8.16) Fomesafen, (B8.19) Lactofen, (B8.24) Oxyfluorfen (B9.3) Butafenacil, (B9.10) Saflufenacil, (B9.12) Tiafenacil, (B9.13) Trifludimoxazin, (B9.14) Ethyl[3-[2-chloro-4-fluoro-5-(1-methyl-6-trifluoromethyl-2,4-dioxo-1,2,3,4- tetrahydropyrimidin-3-yl)phenoxy]-2-pyridyloxy]acetat (B10.5) Diuron, (B10.8) Isoproturon (B11.2) Atrazine, (B11.6) Indaziflam, (B11.8) Metribuzin, (B11.15) Terbuthylazine entspricht. 5. Zusammensetzung gemäß einem der Ansprüche 1 bis 3, wobei die Komponente (B) einem oder mehreren Wirkstoffen ausgewählt aus der Gruppe (B1.2) Bicyclopyrone (CAS 352010-68-5), (B1.4) Clethodim (CAS 99129-21-2), (B1.7) Mesotrione (CAS 104206-82-8),
(B1.14) Tembotrione (CAS 335104-84-2) (B2.1) Acetochlor (CAS 34256-82-1), (B2.18) Diflufenican (CAS 83164-33-4), (B2.20) Dimethenamid (CAS 87674-68-8), (B2.24) Flazasulfuron (CAS 104040-78-0), (B2.28) Flufenacet (CAS 142459-58-3), (B2.31) Foramsulfuron (CAS 173159-57-4), (B2.34) Iodosulfuron (CAS 144550-36-7), (B2.37) Mesosulfuron (CAS 208465-21-8), (B2.63) Rimsulfuron (CAS 122931-48-0), (B2.64) S-metolachlor (CAS 87392-12-9), (B2.68) Thiencarbazone (CAS 317815-83-1), (B2.81) Methyl –rel-(2R,4R)-4-[[(5S)-3-(3,5-difluorophenyl)-5-vinyl-4H-isoxazol-5- carbonyl]amino]tetrahydrofuran-2-carboxylat (B3.1) Bromoxynil (CAS 1689-84-5) (B4.11) Imazamox (CAS 1143-11-32-9), (B4.15) Imazethapyr (CAS 81335-77-5), (B4.18) Isoxaflutole (CAS 141112-29-0), (B4.20) Oxadiazon (CAS 19666-30-9), (B4.21) Pyraflufen-ethyl (CAS 129630-19-9), (B4.25) Pyroxasulfone (CAS 365400-11-9), (B4.26) Sulfentrazone (CAS 122836-35-5) (B5.5) Bentazone (CAS 25057-89-0), (B5.14) Clomazone (CAS 81777-95-9), (B5.23) Florpyrauxifen (CAS 943832-81-3), (B5.26) Flumioxazin (CAS 103361-09-7), (B5.37) Paraquat (CAS 1910-42-5) (B6.3) Dicamba (CAS 1918-00-9) (B7.4) Glufosinate (CAS 77182-82-2), (B7.5) Glyphosate (CAS 70901-12-1)
(B8.1) 2,4-D (CAS 94-75-7), (B8.5) Aclonifen (CAS 74070-46-5), (B8.16) Fomesafen (CAS 72178-02-0), (B8.24) Oxyfluorfen (CAS 42874-03-3) (B9.3) Butafenacil (CAS 134605-64-4), (B9.10) Saflufenacil (CAS 372137-35-4), (B9.13) Trifludimoxazin (CAS 1258836-72-4) (B10.5) Diuron (CAS 330-54-1) (B11.2) Atrazine (CAS 1912-24-9), (B11.6) Indaziflam (CAS 950782-86-2) (B11.8) Metribuzin (CAS 21087-64-9), (B11.15) Terbuthylazine (CAS 5915-41-3) entspricht. 6. Herbizide Zusammensetzung gemäß einem der Ansprüche 1 bis 5, wobei die Wirkstoffkomponenten (A) und (B) in einem Gewichtsverhältnis von 1:100000 bis 3000:1 enthalten sind. 7. Herbizide Zusammensetzung gemäß einem der Ansprüche 1 bis 6, wobei die Wirkstoffkomponenten (A) und (B) in einem Gewichtsverhältnis von 1:15000 bis 1000:1 enthalten sind. 8. Herbizide Zusammensetzung gemäß einem der Ansprüche 1 bis 7, wobei ein oder mehrere weitere Komponenten aus der Gruppe enthaltend Pflanzenschutzmittelwirkstoffe anderer Art enthalten sind. 9. Herbizide Zusammensetzung gemäß einem der Ansprüche 1 bis 8, enthaltend ein oder mehrere im Pflanzenschutz übliche Zusatzstoffe. 10. Verfahren zur Bekämpfung von Schadpflanzen oder zur Wachstumsregulierung von Pflanzen, wobei die Wirkstoffkomponenten der herbiziden Zusammensetzung gemäß einem der
Ansprüche 1 bis 9 auf die Pflanzen, Pflanzenteile, Pflanzensamen oder die Anbaufläche appliziert werden. 11. Verfahren gemäß Anspruch 10, wobei die Wirkstoffkomponenten der herbiziden Zusammensetzung gemeinsam oder getrennt im Vorauflauf, Nachauflauf oder im Vor- und Nachauflauf auf die Pflanzen, Pflanzenteile, Pflanzensamen oder die Anbaufläche appliziert werden. 12. Verfahren gemäß Anspruch 11, wobei die Herbizidkomponente (A) in einer Aufwandmenge von 0,02 bis 250 g a.i./ha appliziert wird. 13. Verfahren gemäß Anspruch 11, wobei die Herbizidkomponente (B) in einer Aufwandmenge von 0,01 bis 4000 g a.i./ha appliziert wird, ausgenommen Pelargonsäure, die in einer Aufwandmenge von 1 bis 100.000 g a.i./ha appliziert wird. 14. Verfahren nach einem der Ansprüche 11 bis 13 zur Bekämpfung von Schadpflanzen durch Behandlung vor Aussaat der Kulturpflanzen und in Plantagenkulturen, sowie Nichtkulturland. 15. Verfahren nach einem der Ansprüche 11 bis 14, wobei die Wirkstoffe der herbizide Zusammensetzung in Form eines herbiziden Mittels, welches ein oder mehrere im Pflanzenschutz übliche Zusatzstoffe enthält, gegebenenfalls nach Verdünnen mit Wasser, appliziert werden. 16. Verwendung der herbiziden Zusammensetzung gemäß einem der Ansprüche 1 bis 9 zur Bekämpfung von Schadpflanzen oder zur Wachstumsregulierung von Pflanzen.
stands. 3. The composition of claim 1 wherein component (A) of compound (a) is pyridin-2-ylmethyl-[(3-{2-chloro-4-fluoro-5-[3-methyl-2,6-dioxo- 4-(trifluoromethyl)-3,6-dihydropyrimidin-1(2H)-yl]phenoxy}pyridin-2-yl)oxy]acetate, (b) 2-Methoxyethyl-[(3-{2-chloro-4-fluoro -5-[3-methyl-2,6-dioxo-4-(trifluoromethyl)-3,6-dihydropyrimidin-1(2H)-yl]phenoxy}pyridin-2-yl)oxy]acetate, (c) 2- Methoxyethyl[(3-{2-cyano-4-fluoro-5-[3-methyl-2,6-dioxo-4-(trifluoromethyl)-3,6-dihydropyrimidin-1(2H)-yl]phenoxy}pyridine -2-yl)oxy]acetate, or (d) cyanomethyl-[(3-{2-bromo-4-fluoro-5-[3-methyl-2,6-dioxo-4-(trifluoromethyl)-3,6 - corresponds to dihydropyrimidin-1(2H)-yl]phenoxy}pyridin-2-yl)oxy]acetate. 4. The composition according to any one of claims 1 to 3, wherein component (B) one or more active ingredients selected from the group (B1.2) bicyclopyrone, (B1.4) clethodim, (B1.7) mesotrione, (B1.8) pinoxaden, (B1.14) tembotrione, (B2.1) acetochlor, (B2.18) diflufenican, (B2.20) dimethenamid, (B2.24) flazasulfuron, (B2.28) flufenacet, (B2 .31) foramsulfuron, (B2.34) iodosulfuron, (B2.37) mesosulfuron, (B2.40) metolachlor, (B2.43) nicosulfuron, (B2.63) rimsulfuron, (B2.64) S-metolachlor, ( B2.68) Thienecarbazones, (B2.79) methyl rel-(2R,4R)-4-[[3-(3,5-dichlorophenyl)-5-methoxy-4H-isoxazole-5-carbonyl]amino]tetrahydrofuran- 2-carboxylate, (B2.80) methyl rel-(2R,4R)-4-[[3-(3,5-dichlorophenyl)-5-vinyl-4H-isoxazole-5-carbonyl]amino]tetrahydrofuran-2- carboxylate, (B2.81) methyl -rel-(2R,4R)-4-[[(5S)-3-(3,5-difluorophenyl)-5-vinyl-4H-isoxazole-5-carbonyl]amino]tetrahydrofuran -2-carboxylate, (B2.82) Isopropyl rel-(2R,4R)-4-[[3-(3-fluorophenyl)-5-methyl-4H-isoxazole-5-carbonyl]amino]tetrahydrofuran-2-carboxylate , (B2.83) Methyl (3R)-3-[[(5S)-3-(3,5-difluorophenyl)-5-vinyl-4H-isoxazole-5-carbonyl]amino]-2,3-dihydrofuran- 5-carboxylate, (B2.84) methyl (3R)-3-[[(5R)-3-(3,5-difluorophenyl)-5-methyl -4H-isoxazol-5-carbonyl]amino]-2,3-dihydrofuran-5-carboxylate, (B2.85) methyl (1S,4R)-4-[[[(5S)-3-(3,5- difluorophenyl)-5-vinyl-4H-1,2-oxazol-5-yl]carbonyl]amino]cyclopent-2-ene-1-carboxylate, (B2.86) ethyl (1S,4R)-4-[[ [3-(3,5-difluorophenyl)-5-methoxy-4H-1,2-oxazol-5-yl]carbonyl]amino]cyclopent-2-en-1-carboxylate, (B2.87) 2-methoxyethyl ( 1S,4R)-4-[[[(5R)-3-(3-cyano-5-fluorophenyl)-5-(trifluoromethyl)-4H-1,2-oxazol-5-yl]carbonyl]amino]cyclopent- 2-ene-1-carboxylate, (B2.88) methyl (4S)-4-[[[3-(3,5-difluorophenyl)-5-methyl-4H-1,2-oxazol-5-yl]carbonyl ]amino]cyclopentene-1-carboxylate, (B2.89) Methyl (3S)-3-[[[(5R)-3-(3,5-difluorophenyl)-5-methyl-4H-1,2-oxazol-5-yl]carbonyl]amino]- cyclopentene-1-carboxylate, (B2.90) 3-(3,5-Difluorophenyl)-N-[(1R,4S)-4-(oxazinan-2-ylcarbonyl)cyclopent-2-en-1-yl]- 5-(trifluoromethyl)-4H-1,2-oxazole-5-carboxamide, (B2.91) 3-(3,5-difluorophenyl)-N-[(1R,4S)-4-[(propylsulfonylamino)carbonyl] cyclopent-2-en-1-yl]-5-(trifluoromethyl)-4H-1,2-oxazole-5-carboxamide, (B2.92) (1S,4R)-4-[[(5R)-3- (3,5-difluorophenyl)-5-methyl-4H-isoxazole-5-carbonyl]amino]cyclopent-2-ene-1-carboxylic acid (B3.1) bromoxynil (B4.8) carfentrazone, (B4.11) imazamox , (B4.13) imazapyr, (B4.15) imazethapyr, (B4.18) isoxaflutole, (B4.20) oxadiazon, (B4.21) pyraflufen, (B4.22) pyrasulfotole, (B4.25) pyroxasulfone, (B4.26) sulfentrazone, (B4.27) tolpyralate (B5.5) bentazone, (B5.14) clomazone (B5.23) florpyrauxifen, (B5.26) flumioxazine, (B5.30) fluthiacet-methyl, ( B5.31) halauxifen, (B5.37) paraquat, (B5.38) pelargonic acid, (B6.3) dicamba (B7.2) bialaphos, (B7.4) glufosinate, (B7.5) glyphosate, (B7.7) sulfosate (B8.1) 2,4-D, (B8.2) 2,4-DB, (B8.3) 2,4-DP, (B8.4 ) acifluorfen, (B8.5) aclonifen, (B8.13) fenoxaprop, (B8.16) fomesafen, (B8.19) lactofen, (B8.24) oxyfluorfen, (B9.3) butafenacil, (B9.10) saflufenacil , (B9.12) tiafenacil, (B9.13) trifludimoxazine, (B9.14) ethyl[3-[2-chloro-4-fluoro-5-(1-methyl-6-trifluoromethyl-2,4-dioxo- 1,2,3,4-tetrahydropyrimidin-3-yl)phenoxy]-2-pyridyloxy]acetate (B10.5) diuron, (B10.8) isoproturon (B11.2) atrazine, (B11.6) indaziflam, ( B11.8) metribuzin, (B11.15) terbuthylazine. 5. The composition according to any one of claims 1 to 3, wherein component (B) is one or more active substances selected from the group (B1.2) bicyclopyrone (CAS 352010-68-5), (B1.4) clethodim (CAS 99129- 21-2), (B1.7) mesotriones (CAS 104206-82-8), (B1.14) Tembotrione (CAS 335104-84-2) (B2.1) Acetochlor (CAS 34256-82-1), (B2.18) Diflufenican (CAS 83164-33-4), (B2.20) Dimethenamid (CAS 87674-68-8), (B2.24) Flazasulfuron (CAS 104040-78-0), (B2.28) Flufenacet (CAS 142459-58-3), (B2.31) Foramsulfuron (CAS 173159-57). -4), (B2.34) Iodosulfuron (CAS 144550-36-7), (B2.37) Mesosulfuron (CAS 208465-21-8), (B2.63) Rimsulfuron (CAS 122931-48-0), ( B2.64) S-metolachlor (CAS 87392-12-9), (B2.68) Thienecarbazone (CAS 317815-83-1), (B2.81) Methyl -rel-(2R,4R)-4-[[ (5S)-3-(3,5-difluorophenyl)-5-vinyl-4H-isoxazol-5-carbonyl]amino]tetrahydrofuran-2-carboxylate (B3.1) Bromoxynil (CAS 1689-84-5) (B4. 11) Imazamox (CAS 1143-11-32-9), (B4.15) Imazethapyr (CAS 81335-77-5), (B4.18) Isoxaflutole (CAS 141112-29-0), (B4.20) Oxadiazon (CAS 19666-30-9), (B4.21) Pyraflufen-ethyl (CAS 129630-19-9), (B4.25) Pyroxasulfone (CAS 365400-11-9), (B4.26) Sulfentrazone (CAS 122836). -35-5) (B5.5) Bentazone (CAS 25057-89-0), (B5.14) Clomazone (CAS 81777-95-9), (B5.23) Florpyrauxi fen (CAS 943832-81-3), (B5.26) Flumioxazine (CAS 103361-09-7), (B5.37) Paraquat (CAS 1910-42-5) (B6.3) Dicamba (CAS 1918-00 -9) (B7.4) Glufosinate (CAS 77182-82-2), (B7.5) Glyphosate (CAS 70901-12-1) (B8.1) 2,4-D (CAS 94-75-7), (B8.5) Aclonifen (CAS 74070-46-5), (B8.16) Fomesafen (CAS 72178-02-0), ( B8.24) Oxyfluorfen (CAS 42874-03-3) (B9.3) Butafenacil (CAS 134605-64-4), (B9.10) Saflufenacil (CAS 372137-35-4), (B9.13) Trifludimoxazine ( CAS 1258836-72-4) (B10.5) Diuron (CAS 330-54-1) (B11.2) Atrazine (CAS 1912-24-9), (B11.6) Indaziflam (CAS 950782-86-2) (B11.8) Metribuzin (CAS 21087-64-9), (B11.15) Terbuthylazine (CAS 5915-41-3). 6. The herbicidal composition according to any one of claims 1 to 5, wherein the active ingredient components (A) and (B) are contained in a weight ratio of 1:100,000 to 3000:1. 7. The herbicidal composition according to any one of claims 1 to 6, wherein the active ingredient components (A) and (B) are contained in a weight ratio of 1:15000 to 1000:1. 8. The herbicidal composition as claimed in any of claims 1 to 7, containing one or more further components from the group containing active ingredients in crop protection agents of a different type. 9. The herbicidal composition as claimed in any of claims 1 to 8, containing one or more additives customary in crop protection. 10. A method for controlling harmful plants or for regulating the growth of plants, wherein the active components of the herbicidal composition according to any one of Claims 1 to 9 are applied to the plants, parts of plants, plant seeds or the area under cultivation. 11. The method according to claim 10, wherein the active ingredient components of the herbicidal composition are applied together or separately pre-emergence, post-emergence or pre- and post-emergence on the plants, parts of plants, plant seeds or the area under cultivation. 12. The method according to claim 11, wherein the herbicide component (A) is applied at an application rate of 0.02 to 250 g ai/ha. 13. The method according to claim 11, wherein the herbicide component (B) is applied at an application rate of 0.01 to 4000 g ai/ha, with the exception of pelargonic acid, which is applied at an application rate of 1 to 100,000 g ai/ha. 14. The method according to any one of claims 11 to 13 for controlling harmful plants by treatment before sowing the crop plants and in plantation crops, and non-crop land. 15. The method according to any one of claims 11 to 14, wherein the active ingredients of the herbicidal composition in the form of a herbicidal composition containing one or more additives customary in crop protection, optionally after dilution with water, are applied. 16. Use of the herbicidal composition according to any one of claims 1 to 9 for controlling harmful plants or for regulating the growth of plants.
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CN116602296B (en) * | 2023-07-20 | 2023-09-15 | 成武县晨晖环保科技有限公司 | Weeding composition containing propyzamide |
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