JP6506513B2 - リチウムイオン二次電池用電極の作製方法 - Google Patents

リチウムイオン二次電池用電極の作製方法 Download PDF

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Publication number
JP6506513B2
JP6506513B2 JP2014160438A JP2014160438A JP6506513B2 JP 6506513 B2 JP6506513 B2 JP 6506513B2 JP 2014160438 A JP2014160438 A JP 2014160438A JP 2014160438 A JP2014160438 A JP 2014160438A JP 6506513 B2 JP6506513 B2 JP 6506513B2
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active material
graphene
positive electrode
negative electrode
lithium ion
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JP2015057767A (ja
JP2015057767A5 (https=
Inventor
清文 荻野
清文 荻野
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Semiconductor Energy Laboratory Co Ltd
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Semiconductor Energy Laboratory Co Ltd
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/13Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/134Electrodes based on metals, Si or alloys
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • H01M10/0525Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/04Processes of manufacture in general
    • H01M4/0402Methods of deposition of the material
    • H01M4/0404Methods of deposition of the material by coating on electrode collectors
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/13Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139Processes of manufacture
    • H01M4/1395Processes of manufacture of electrodes based on metals, Si or alloys
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/38Selection of substances as active materials, active masses, active liquids of elements or alloys
    • H01M4/386Silicon or alloys based on silicon
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/62Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/621Binders
    • H01M4/622Binders being polymers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/62Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/624Electric conductive fillers
    • H01M4/625Carbon or graphite
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/64Carriers or collectors
    • H01M4/66Selection of materials
    • H01M4/661Metal or alloys, e.g. alloy coatings
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/64Carriers or collectors
    • H01M4/66Selection of materials
    • H01M4/665Composites
    • H01M4/667Composites in the form of layers, e.g. coatings
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02TCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00Road transport of goods or passengers
    • Y02T10/60Other road transportation technologies with climate change mitigation effect
    • Y02T10/70Energy storage systems for electromobility, e.g. batteries

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Composite Materials (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Cell Electrode Carriers And Collectors (AREA)
  • Secondary Cells (AREA)
JP2014160438A 2013-08-09 2014-08-06 リチウムイオン二次電池用電極の作製方法 Expired - Fee Related JP6506513B2 (ja)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2014160438A JP6506513B2 (ja) 2013-08-09 2014-08-06 リチウムイオン二次電池用電極の作製方法

Applications Claiming Priority (3)

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JP2013166869 2013-08-09
JP2013166869 2013-08-09
JP2014160438A JP6506513B2 (ja) 2013-08-09 2014-08-06 リチウムイオン二次電池用電極の作製方法

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JP2015057767A JP2015057767A (ja) 2015-03-26
JP2015057767A5 JP2015057767A5 (https=) 2017-09-14
JP6506513B2 true JP6506513B2 (ja) 2019-04-24

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Families Citing this family (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2794475B1 (en) 2011-12-21 2020-02-19 The Regents of The University of California Interconnected corrugated carbon-based network
WO2013134207A1 (en) 2012-03-05 2013-09-12 The Regents Of The University Of California Capacitor with electrodes made of an interconnected corrugated carbon-based network
EP3155688B1 (en) 2014-06-16 2025-04-16 The Regents of The University of California Hybrid electrochemical cell
CA2968139C (en) 2014-11-18 2023-01-10 The Regents Of The University Of California Porous interconnected corrugated carbon-based network (iccn) composite
US10818928B2 (en) * 2014-12-15 2020-10-27 Samsung Sdi Co., Ltd. Electrode for rechargeable lithium battery, rechargeable lithium battery, and method of fabricating electrode for rechargeable lithium battery
AU2015200886A1 (en) * 2015-02-20 2016-09-08 Monash University Carbon-based surface plasmon source and applications thereof
WO2016178117A1 (en) 2015-05-06 2016-11-10 Semiconductor Energy Laboratory Co., Ltd. Secondary battery and electronic device
DE102016208250A1 (de) * 2015-05-19 2016-11-24 Semiconductor Energy Laboratory Co., Ltd. Elektrode, Energiespeichervorrichtung und elektronische Vorrichtung
JP6027214B1 (ja) * 2015-06-11 2016-11-16 住友化学株式会社 フィルム製造方法
US10833325B2 (en) 2015-11-09 2020-11-10 Kabushiki Kaisha Toyota Jidoshokki Negative electrode active material
JP6869706B2 (ja) 2015-12-11 2021-05-12 株式会社半導体エネルギー研究所 蓄電装置用負極、蓄電装置、および電気機器
WO2017112575A1 (en) 2015-12-22 2017-06-29 The Regents Of The University Of California Cellular graphene films
CN105552333B (zh) * 2016-01-01 2018-03-13 三峡大学 一种石墨烯/硅/导电聚合物复合负极材料的制备方法
KR102645603B1 (ko) 2016-01-22 2024-03-07 더 리전트 오브 더 유니버시티 오브 캘리포니아 고-전압 장치
CN114784358A (zh) 2016-03-23 2022-07-22 加利福尼亚大学董事会 用于高电压和太阳能应用的装置和方法
EP3507846A4 (en) * 2016-08-31 2020-08-12 The Regents of the University of California DEVICES INCLUDING A CARBON-BASED MATERIAL AND ASSOCIATED MANUFACTURING
IL271731B2 (en) 2017-07-14 2024-10-01 Univ California A simple route to highly conductive porous graphene from carbon nanodots for supercapacitor applications
JP2019050108A (ja) * 2017-09-08 2019-03-28 日産自動車株式会社 電極活物質スラリー
JP6926873B2 (ja) 2017-09-14 2021-08-25 株式会社豊田自動織機 Al及びO含有シリコン材料
PL3582295T3 (pl) * 2017-10-25 2023-02-27 Lg Energy Solution, Ltd. Elektroda jednostronna o zmniejszonym skręcie do baterii akumulatorowej oraz sposób jej wytwarzania
JPWO2019193450A1 (ja) 2018-04-05 2021-04-01 株式会社半導体エネルギー研究所 負極活物質、二次電池、及び電子機器
JP7183707B2 (ja) 2018-08-10 2022-12-06 株式会社豊田自動織機 負極及び負極の製造方法並びに電極用結着剤
HUE064174T2 (hu) * 2019-10-22 2024-02-28 Samsung Electronics Co Ltd Szilárdtest-akkumulátor és eljárás szilárdtest-akkumulátor gyártására
CN111559739A (zh) * 2020-03-30 2020-08-21 桑顿新能源科技有限公司 高倍率磷酸铁锰锂复合材料及其制备方法、锂离子电池
CN112018369A (zh) * 2020-09-07 2020-12-01 杭州肄康新材料有限公司 一种锂离子电池负极材料的制备方法
CN112490416A (zh) * 2020-10-28 2021-03-12 浙江中科玖源新材料有限公司 一种硅碳复合薄膜及其制备方法和应用以及锂离子电池
DE112022001778T5 (de) 2021-03-26 2024-02-15 Gs Yuasa International Ltd. Schätzvorrichtung, Energiespeichers, ein Energiespeichermodul, ein Schätzverfahren und ein Computerprogramm
CN114497483B (zh) * 2021-12-31 2023-07-04 惠州锂威新能源科技有限公司 一种负极片及其制备方法以及锂离子电池
CN115282891B (zh) * 2022-08-01 2023-11-07 东莞澳中新材料科技股份有限公司 一种微米硅-石墨烯复合气凝胶的制备方法、电极及其制备方法
CN115282890B (zh) * 2022-08-01 2023-11-17 东莞澳中新材料科技股份有限公司 一种硅-石墨烯增强型复合气凝胶的制备方法及电极的制备方法
WO2025080002A1 (ko) * 2023-10-13 2025-04-17 주식회사 엘지에너지솔루션 리튬 이차 전지용 음극의 제조 방법, 이로부터 제조된 음극 및 음극을 포함하는 리튬 이차 전지

Family Cites Families (42)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0660870A (ja) 1992-08-05 1994-03-04 Toshiba Battery Co Ltd 乾電池の製造法
JP3913439B2 (ja) 2000-04-03 2007-05-09 三洋電機株式会社 リチウム二次電池
JP4765077B2 (ja) 2004-06-11 2011-09-07 国立大学法人東京農工大学 酸化ルテニウム内包ナノカーボン複合構造体
US7939218B2 (en) 2004-12-09 2011-05-10 Nanosys, Inc. Nanowire structures comprising carbon
WO2006062947A2 (en) 2004-12-09 2006-06-15 Nanosys, Inc. Nanowire-based membrane electrode assemblies for fuel cells
US7842432B2 (en) 2004-12-09 2010-11-30 Nanosys, Inc. Nanowire structures comprising carbon
US8278011B2 (en) 2004-12-09 2012-10-02 Nanosys, Inc. Nanostructured catalyst supports
KR100639889B1 (ko) 2004-12-30 2006-10-31 주식회사 소디프신소재 비탄소재료 함유 소구체 탄소분말 및 그 제조방법
JP3850427B2 (ja) 2005-03-22 2006-11-29 株式会社物産ナノテク研究所 炭素繊維結合体およびこれを用いた複合材料
US8003257B2 (en) 2005-07-04 2011-08-23 Showa Denko K.K. Method for producing anode for lithium secondary battery and anode composition, and lithium secondary battery
US20070009799A1 (en) 2005-07-07 2007-01-11 Eveready Battery Company, Inc. Electrochemical cell having a partially oxidized conductor
US7914844B2 (en) 2005-11-18 2011-03-29 Northwestern University Stable dispersions of polymer-coated graphitic nanoplatelets
EP1952467B9 (en) 2005-11-21 2012-03-14 Nanosys, Inc. Nanowire structures comprising carbon
KR20140083054A (ko) 2006-06-02 2014-07-03 미쓰비시 가가꾸 가부시키가이샤 비수계 전해액 및 비수계 전해액 전지
JP5314872B2 (ja) 2007-10-01 2013-10-16 株式会社オハラ 発熱機構を備える二次電池
KR100923304B1 (ko) 2007-10-29 2009-10-23 삼성전자주식회사 그라펜 시트 및 그의 제조방법
US7745047B2 (en) 2007-11-05 2010-06-29 Nanotek Instruments, Inc. Nano graphene platelet-base composite anode compositions for lithium ion batteries
JP5377946B2 (ja) 2007-12-25 2013-12-25 花王株式会社 リチウム電池正極用複合材料
US8426064B2 (en) 2007-12-25 2013-04-23 Kao Corporation Composite material for positive electrode of lithium battery
WO2009127901A1 (en) 2008-04-14 2009-10-22 High Power Lithium S.A. Lithium metal phosphate/carbon nanocomposites as cathode active materials for secondary lithium batteries
US8936874B2 (en) 2008-06-04 2015-01-20 Nanotek Instruments, Inc. Conductive nanocomposite-based electrodes for lithium batteries
US8257867B2 (en) 2008-07-28 2012-09-04 Battelle Memorial Institute Nanocomposite of graphene and metal oxide materials
US8580432B2 (en) 2008-12-04 2013-11-12 Nanotek Instruments, Inc. Nano graphene reinforced nanocomposite particles for lithium battery electrodes
US9093693B2 (en) 2009-01-13 2015-07-28 Samsung Electronics Co., Ltd. Process for producing nano graphene reinforced composite particles for lithium battery electrodes
EP2228854B1 (en) 2009-03-12 2014-03-05 Belenos Clean Power Holding AG Nitride and carbide anode materials
EP2237346B1 (en) 2009-04-01 2017-08-09 The Swatch Group Research and Development Ltd. Electrically conductive nanocomposite material comprising sacrificial nanoparticles and open porous nanocomposites produced thereof
US20140370380A9 (en) 2009-05-07 2014-12-18 Yi Cui Core-shell high capacity nanowires for battery electrodes
ES2910086T3 (es) * 2009-05-19 2022-05-11 Oned Mat Inc Materiales nanoestructurados para aplicaciones de batería
EP3865454A3 (en) 2009-05-26 2021-11-24 Belenos Clean Power Holding AG Stable dispersions of single and multiple graphene layers in solution
JP2011048992A (ja) 2009-08-26 2011-03-10 Sekisui Chem Co Ltd 炭素材料、電極材料及びリチウムイオン二次電池負極材料
US8778538B2 (en) 2009-11-06 2014-07-15 Northwestern University Electrode material comprising graphene-composite materials in a graphite network
US9431649B2 (en) 2009-11-23 2016-08-30 Uchicago Argonne, Llc Coated electroactive materials
US8652687B2 (en) 2009-12-24 2014-02-18 Nanotek Instruments, Inc. Conductive graphene polymer binder for electrochemical cell electrodes
CN103053055B (zh) 2010-08-19 2016-10-12 株式会社半导体能源研究所 电气设备
US8691441B2 (en) 2010-09-07 2014-04-08 Nanotek Instruments, Inc. Graphene-enhanced cathode materials for lithium batteries
US20120088151A1 (en) 2010-10-08 2012-04-12 Semiconductor Energy Laboratory Co., Ltd. Positive-electrode active material and power storage device
CN103140967B (zh) 2010-10-08 2016-08-31 株式会社半导体能源研究所 储能装置用正极活性材料的制造方法及储能装置
EP2698854B1 (en) 2010-10-22 2017-02-22 Belenos Clean Power Holding AG Method of an electrode (anode and cathode) performance enhancement by composite formation with graphene oxide
US9487880B2 (en) 2011-11-25 2016-11-08 Semiconductor Energy Laboratory Co., Ltd. Flexible substrate processing apparatus
EP2810322A1 (en) * 2012-01-30 2014-12-10 Nexeon Limited Composition of si/c electro active material
US9680272B2 (en) 2012-02-17 2017-06-13 Semiconductor Energy Laboratory Co., Ltd. Method for forming negative electrode and method for manufacturing lithium secondary battery
US20140004412A1 (en) 2012-06-29 2014-01-02 Semiconductor Energy Laboratory Co., Ltd. Secondary battery

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US11848439B2 (en) 2023-12-19
US20180248169A1 (en) 2018-08-30
US20150044560A1 (en) 2015-02-12
JP2015057767A (ja) 2015-03-26
US10873072B2 (en) 2020-12-22
US20210210744A1 (en) 2021-07-08

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