JP6503219B2 - 導電性インク組成物及びそれにより製造された導電性部材 - Google Patents
導電性インク組成物及びそれにより製造された導電性部材 Download PDFInfo
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- JP6503219B2 JP6503219B2 JP2015090112A JP2015090112A JP6503219B2 JP 6503219 B2 JP6503219 B2 JP 6503219B2 JP 2015090112 A JP2015090112 A JP 2015090112A JP 2015090112 A JP2015090112 A JP 2015090112A JP 6503219 B2 JP6503219 B2 JP 6503219B2
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- -1 nitrogen-containing compound Chemical class 0.000 claims description 27
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Description
前記(A)オキシカルボン酸が、グリコール酸、乳酸、リンゴ酸、クエン酸、及びこれらの酸無水物からなる群から選択される少なくとも一種であり、
前記(B)含窒素化合物が、下記一般式(1)で表される尿素結合を有する化合物、下記一般式(2)で表されるグアニジン又はその誘導体と酸との塩、塩化アンモニウム、硝酸アンモニウム、並びに炭酸アンモニウムからなる群から選択される少なくとも一種であることを特徴とするものである。
先ず、本発明の導電性インク組成物について説明する。すなわち、本発明の導電性インク組成物は、(A)オキシカルボン酸、(B)含窒素化合物、(C)銅粒子、及び(D)分散媒を含有し、前記(B)含窒素化合物が、尿素結合を有する化合物、グアニジン及びその誘導体、グアニジン塩、2個の窒素原子をヘテロ原子として含むヘテロ5員環化合物、1H−トリアゾール及びその誘導体、ヒドラジド化合物、ニトロソアミン化合物、ニトリル基を有する化合物、メラミン及びその誘導体、並びにアンモニウム塩からなる群から選択される少なくとも一種であることを特徴とするものである。
で表されるポリアミンアルキレンオキサイド付加物を更に含有することが好ましい。
(ii)グアニジン及びその誘導体としては、下記一般式(2)で表されるグアニジン及びその誘導体が挙げられる。
このようなグアニジンの誘導体としては、例えば、シアノグアニジン、1,1,3,3−テトラメチルグアニジン、1−メチル−3−ニトログアニジンが挙げられる。
次に、前述の本発明の導電性インク組成物を用いた本発明の導電性部材の製造方法について説明する。すなわち、本発明の導電性部材の製造方法は、前記本発明の導電性インク組成物を基材に塗布し、乾燥処理することによって導電性部材を得る方法である。
、アクリル樹脂、スチレン樹脂、塩化ビニル樹脂、ポリエステル樹脂(ポリエチレンテレフタレート、ポリトリメチレンテレフタレート、ポリブチレンテレフタレート、ポリエチレンナフタレート、ポリブチレンナフタレート)、ポリアセタール樹脂、セルロース誘導体等の樹脂基材;非塗工印刷用紙、微塗工印刷用紙、塗工印刷用紙(アート紙、コート紙)、特殊印刷用紙、コピー用紙(PPC用紙)、未晒包装紙(重袋用両更クラフト紙、両更クラフト紙)、晒包装紙(晒クラフト紙、純白ロール紙)、コートボール、チップボール段ボール等の紙基材;銅板、鉄板、アルミ板等の金属基材;ソーダガラス、ホウケイ酸ガラス、シリカガラス、石英ガラス等のガラス基材;アルミナ、サファイア、ジルコニア、チタニア、酸化イットリウム、ITO(インジウム錫オキサイド)等の金属酸化物基材が挙げられる。
実施例1〜18、20〜39及び比較例1〜8の導電性インク組成物は、それぞれ表1〜6に示す成分及び組成の通りとなるようにして以下の方法により製造した。すなわち、表1〜6に示す組成となるように、(D)成分に(A)成分、(B)成分(比較例1及び比較例5においては(B)成分のみ、比較例2及び比較例6においては(A)成分のみ)及び(E)成分((E)成分を加えるのは実施例26〜39及び比較例5〜7のみ)を加えて混合して均一溶液とし、さらに(C)成分を添加混合し、次に超音波処理(超音波工業株式会社製、ULTRASONIC CLEANER 「SONOQUICK C10」を使用)を30分間施して均一分散液として各導電性インク組成物を得た。
銅粒子*1:IOX社製「サブマイクロ銅粉 IOXCu750」、平均粒子径750nm、銅含有量99質量%以上
銅粒子*2:Aldrich社製「Copper powder(spheroidal)」、平均粒子径20μm、銅含有量99質量%。
エチレンジアミン−42PO−6EO:エチレンジアミンプロピレンオキサイド42モルエチレンオキサイド6モルランダム付加物
エチレンジアミン−4PO:エチレンジアミンプロピレンオキサイド4モル付加物
エチレンジアミン−16PO:エチレンジアミンプロピレンオキサイド16モル付加物
テトラメチレンジアミン−8PO:テトラメチレンジアミンプロピレンオキサイド8モル付加物。
Claims (7)
- (A)オキシカルボン酸、(B)含窒素化合物、(C)銅粒子、及び(D)分散媒を含有し、
前記(A)オキシカルボン酸が、グリコール酸、乳酸、リンゴ酸、クエン酸、及びこれらの酸無水物からなる群から選択される少なくとも一種であり、
前記(B)含窒素化合物が、下記一般式(1):
で表される尿素結合を有する化合物、下記一般式(2):
で表されるグアニジン又はその誘導体と酸との塩、塩化アンモニウム、硝酸アンモニウム、並びに炭酸アンモニウムからなる群から選択される少なくとも一種であることを特徴とする導電性インク組成物。 - (E)下記一般式(i):
で表されるポリアミンアルキレンオキサイド付加物を更に含有することを特徴とする請求項1に記載の導電性インク組成物。 - 前記(B)含窒素化合物が、尿素、ビウレット、グアニジン塩酸塩、グアニジンスルファミン酸塩、グアニジン炭酸塩、グアニジン硝酸塩、塩化アンモニウム、硝酸アンモニウム、及び炭酸アンモニウムからなる群から選択される少なくとも一種であることを特徴とする請求項1又は2に記載の導電性インク組成物。
- 前記(C)銅粒子の平均粒子径が0.01〜100μmの範囲内であることを特徴とする請求項1〜3のうちのいずれか一項に記載の導電性インク組成物。
- 前記(C)銅粒子の質量100質量部を基準に、前記(A)オキシカルボン酸の含有量が0.1〜100質量部の範囲内、前記(B)含窒素化合物の含有量が0.1〜100質量部の範囲内にあることを特徴とする請求項1〜4のうちのいずれか一項に記載の導電性インク組成物。
- 前記(C)銅粒子の質量100質量部を基準に、前記(E)ポリアミンアルキレンオキサイド付加物の含有量が0.1〜100質量部の範囲内にあることを特徴とする請求項2〜5のうちのいずれか一項に記載の導電性インク組成物。
- 請求項1〜6のうちのいずれか一項に記載の導電性インク組成物を基材に塗布し、乾燥処理して得られたものであることを特徴とする導電性部材。
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JP2014221745 | 2014-10-30 | ||
JP2014221745 | 2014-10-30 |
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JP6503219B2 true JP6503219B2 (ja) | 2019-04-17 |
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