JP6476455B2 - 保護フィルム及び保護フィルムの製造方法 - Google Patents
保護フィルム及び保護フィルムの製造方法 Download PDFInfo
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- JP6476455B2 JP6476455B2 JP2015053526A JP2015053526A JP6476455B2 JP 6476455 B2 JP6476455 B2 JP 6476455B2 JP 2015053526 A JP2015053526 A JP 2015053526A JP 2015053526 A JP2015053526 A JP 2015053526A JP 6476455 B2 JP6476455 B2 JP 6476455B2
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- 230000001681 protective effect Effects 0.000 title claims description 59
- 238000004519 manufacturing process Methods 0.000 title claims description 15
- 239000010419 fine particle Substances 0.000 claims description 75
- 239000012790 adhesive layer Substances 0.000 claims description 67
- 239000011521 glass Substances 0.000 claims description 48
- 229920003002 synthetic resin Polymers 0.000 claims description 39
- 239000000057 synthetic resin Substances 0.000 claims description 39
- 238000000034 method Methods 0.000 claims description 25
- 239000010410 layer Substances 0.000 claims description 24
- 238000006116 polymerization reaction Methods 0.000 claims description 11
- 239000011148 porous material Substances 0.000 claims description 11
- 229920000642 polymer Polymers 0.000 claims description 10
- 238000002844 melting Methods 0.000 claims description 7
- 230000008018 melting Effects 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 7
- 125000000524 functional group Chemical group 0.000 claims description 6
- 238000010030 laminating Methods 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 5
- 239000002994 raw material Substances 0.000 claims description 5
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- 238000004381 surface treatment Methods 0.000 claims description 4
- 238000010557 suspension polymerization reaction Methods 0.000 claims description 2
- 239000000725 suspension Substances 0.000 claims 1
- 239000010408 film Substances 0.000 description 52
- 238000010586 diagram Methods 0.000 description 14
- 239000000853 adhesive Substances 0.000 description 10
- 238000011068 loading method Methods 0.000 description 9
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- 230000015572 biosynthetic process Effects 0.000 description 3
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- 238000000576 coating method Methods 0.000 description 2
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- 238000000926 separation method Methods 0.000 description 2
- 239000010409 thin film Substances 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 1
- 239000003522 acrylic cement Substances 0.000 description 1
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 1
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 1
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000003749 cleanliness Effects 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
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- 239000003431 cross linking reagent Substances 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 230000005660 hydrophilic surface Effects 0.000 description 1
- 239000012464 large buffer Substances 0.000 description 1
- 229920001684 low density polyethylene Polymers 0.000 description 1
- 239000004702 low-density polyethylene Substances 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
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- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
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- B29D7/01—Films or sheets
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
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- B32B27/205—Layered products comprising a layer of synthetic resin characterised by the use of special additives using fillers, pigments, thixotroping agents the fillers creating voids or cavities, e.g. by stretching
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- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
- B32B27/306—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl acetate or vinyl alcohol (co)polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
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- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
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- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/14—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
- B32B37/15—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer being manufactured and immediately laminated before reaching its stable state, e.g. in which a layer is extruded and laminated while in semi-molten state
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- B32B37/14—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
- B32B37/15—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer being manufactured and immediately laminated before reaching its stable state, e.g. in which a layer is extruded and laminated while in semi-molten state
- B32B37/153—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer being manufactured and immediately laminated before reaching its stable state, e.g. in which a layer is extruded and laminated while in semi-molten state at least one layer is extruded and immediately laminated while in semi-molten state
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- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/22—Plastics; Metallised plastics
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B32B2307/00—Properties of the layers or laminate
- B32B2307/40—Properties of the layers or laminate having particular optical properties
- B32B2307/412—Transparent
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- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/584—Scratch resistance
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/726—Permeability to liquids, absorption
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
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- B32B2307/728—Hydrophilic
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2457/00—Electrical equipment
- B32B2457/20—Displays, e.g. liquid crystal displays, plasma displays
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2571/00—Protective equipment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J201/00—Adhesives based on unspecified macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2203/00—Applications of adhesives in processes or use of adhesives in the form of films or foils
- C09J2203/318—Applications of adhesives in processes or use of adhesives in the form of films or foils for the production of liquid crystal displays
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
- C09J2301/302—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier the adhesive being pressure-sensitive, i.e. tacky at temperatures inferior to 30°C
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/40—Additional features of adhesives in the form of films or foils characterized by the presence of essential components
- C09J2301/41—Additional features of adhesives in the form of films or foils characterized by the presence of essential components additives as essential feature of the carrier layer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/249921—Web or sheet containing structurally defined element or component
- Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]
- Y10T428/249982—With component specified as adhesive or bonding agent
- Y10T428/249983—As outermost component
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Laminated Bodies (AREA)
- Adhesive Tapes (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
- Adhesives Or Adhesive Processes (AREA)
Description
b)前記微細粒子を合成樹脂と混合し、
c)前記微細粒子と前記合成樹脂との混合物を層状に成形する。
2 保護フィルム
3 間紙
4、140、240、340、440: 保護フィルム
141、241、341、441 粘着層
143、243、343、443 中間層
145、245、345、445 非粘着層
145a、245a、345a、445a 合成樹脂
145b、245b、345b、445b 微細粒子
445c 気孔
Claims (11)
- 粘着層と非粘着層とが積層されてなる保護フィルムを製造するための方法であって、
前記非粘着層は、
a)重合工程によって微細粒子を製造する段階と、
b)前記微細粒子を合成樹脂と混合する段階と、
c)前記微細粒子と前記合成樹脂との混合物を層状に成形する段階
とから得られ、
前記段階a)では、前記微細粒子に表面処理を施して該表面に親水性官能基または疎水性官能基を形成し、
前記段階c)では、層状に成形された前記非粘着層を結晶化してから延伸し、前記微細粒子の周囲に気孔を形成することを特徴とする、保護フィルムの製造方法。 - 前記重合工程は懸濁重合工程であることを特徴とする請求項1に記載の保護フィルムの製造方法。
- 前記段階b)では、前記微細粒子と前記合成樹脂の混合物を押出成形した後にマスターバッチを製造し、
前記段階c)では、前記マスターバッチを押出して層状に成形することを特徴とする請求項1に記載の保護フィルムの製造方法。 - 前記微細粒子の融点は前記合成樹脂の融点よりも高いことを特徴とする請求項1に記載の保護フィルムの製造方法。
- 前記粘着層と前記非粘着層との積層は、前記段階b)で得られた前記非粘着層の原料物質と前記粘着層の原料物質とを共押出して積層体に成形してから冷却して得られることを特徴とする請求項1に記載の保護フィルムの製造方法。
- 前記保護フィルムは、前記非粘着層及び前記粘着層を含む2層以上が積層されてなることを特徴とする請求項1に記載の保護フィルムの製造方法。
- 前記保護フィルムは、前記粘着層がガラスに粘着されて前記ガラスを保護するのに使用されるガラス保護フィルムであることを特徴とする請求項1に記載の保護フィルムの製造方法。
- 第1の合成樹脂と該第1の合成樹脂中に分散され重合体である微細粒子とを含む非粘着層と、
第2の合成樹脂を含む粘着層
とが積層されてなる保護フィルムであって、
前記微細粒子は、少なくともその表面に親水性官能基または疎水性官能基を有し、
前記非粘着層は、前記微細粒子の周囲に気孔を有し、
前記微細粒子の周囲の気孔は、前記非粘着層を結晶化してから延伸して形成されることを特徴とする、保護フィルム。 - 前記重合体は懸濁重合体であることを特徴とする請求項8に記載の保護フィルム。
- 前記微細粒子の融点は、前記第1の合成樹脂の融点よりも高いことを特徴とする請求項8に記載の保護フィルム。
- 前記保護フィルムは、前記粘着層がガラスに粘着されて前記ガラスを保護するのに使用されることを特徴とする請求項8に記載の保護フィルム。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020140033308A KR101606003B1 (ko) | 2014-03-21 | 2014-03-21 | 보호필름 및 보호필름 제조방법 |
KR10-2014-0033308 | 2014-03-21 |
Publications (2)
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JP (1) | JP6476455B2 (ja) |
KR (1) | KR101606003B1 (ja) |
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AT314844B (de) * | 1972-05-17 | 1974-04-25 | Color Service | Farbkörpergranulat zum Einfärben von Polystyrol |
US4578297A (en) * | 1985-07-11 | 1986-03-25 | Mobil Oil Corporation | Polymer film/polymer foam laminate and heat-resistant container fabricated therefrom |
US6093364A (en) * | 1989-03-08 | 2000-07-25 | Fortex, Inc. | Method for producing a biaxially oriented open-ended container |
US5223383A (en) * | 1989-12-27 | 1993-06-29 | Eastman Kodak Company | Photographic elements containing reflective or diffusely transmissive supports |
US5141685A (en) * | 1989-12-27 | 1992-08-25 | Eastman Kodak Company | Forming shaped articles from orientable polymers and polymer microbeads |
JPH06183164A (ja) * | 1992-11-10 | 1994-07-05 | Nippon Kakoh Seishi Kk | 軽平版印刷用紙版およびその製造方法 |
US6896928B2 (en) * | 2002-06-07 | 2005-05-24 | Corning Incorporated | Two-layer protective coating system for LCD glass |
JP2004034421A (ja) * | 2002-07-01 | 2004-02-05 | Sekisui Film Kk | 柔軟シート及び立て看板 |
JP2004300172A (ja) * | 2003-03-28 | 2004-10-28 | Dainippon Printing Co Ltd | コーティング組成物、その塗膜、反射防止膜、反射防止フィルム、及び、画像表示装置 |
KR100776197B1 (ko) * | 2006-06-20 | 2007-11-29 | 주식회사 한진피앤씨 | 유리 보호 필름 및 이를 제조하는 방법 |
KR100854562B1 (ko) * | 2006-11-16 | 2008-08-26 | 삼성코닝정밀유리 주식회사 | 유리 보호 필름 제조 방법 |
JP5452978B2 (ja) | 2009-05-29 | 2014-03-26 | アイカ工業株式会社 | 光拡散性有機微粒子の製造法及び光拡散フィルム又は成形体 |
JP5452208B2 (ja) * | 2009-12-18 | 2014-03-26 | 日本ポリプロ株式会社 | インモールドラミネーション用二軸延伸自己粘着性プロテクトフィルム |
JP2013202836A (ja) * | 2012-03-27 | 2013-10-07 | Obikawa Kk | 保護シート及び映像表示装置 |
CN103381616B (zh) * | 2013-05-23 | 2015-03-11 | 山东绿森塑木复合材料有限公司 | 一种木塑复合板、制备工艺及其设备 |
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US20150266281A1 (en) | 2015-09-24 |
KR20150111412A (ko) | 2015-10-06 |
TWI580573B (zh) | 2017-05-01 |
JP2015182466A (ja) | 2015-10-22 |
US20170129227A1 (en) | 2017-05-11 |
US20150266279A1 (en) | 2015-09-24 |
TW201601924A (zh) | 2016-01-16 |
KR101606003B1 (ko) | 2016-03-25 |
CN104924637A (zh) | 2015-09-23 |
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