JP6412570B2 - アルカンおよび発煙硫酸からアルカンスルホン酸を製造するための新規な開始剤 - Google Patents
アルカンおよび発煙硫酸からアルカンスルホン酸を製造するための新規な開始剤 Download PDFInfo
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- JP6412570B2 JP6412570B2 JP2016528892A JP2016528892A JP6412570B2 JP 6412570 B2 JP6412570 B2 JP 6412570B2 JP 2016528892 A JP2016528892 A JP 2016528892A JP 2016528892 A JP2016528892 A JP 2016528892A JP 6412570 B2 JP6412570 B2 JP 6412570B2
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- JP
- Japan
- Prior art keywords
- reactor
- compound
- acid
- initiator
- sulfuric acid
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
- C07C309/63—Esters of sulfonic acids
- C07C309/64—Esters of sulfonic acids having sulfur atoms of esterified sulfo groups bound to acyclic carbon atoms
- C07C309/65—Esters of sulfonic acids having sulfur atoms of esterified sulfo groups bound to acyclic carbon atoms of a saturated carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C409/00—Peroxy compounds
- C07C409/42—Peroxy compounds containing sulfur atoms
- C07C409/44—Peroxy compounds containing sulfur atoms with sulfur atoms directly bound to the —O—O— groups, e.g. persulfonic acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C303/00—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides
- C07C303/02—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof
- C07C303/04—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof by substitution of hydrogen atoms by sulfo or halosulfonyl groups
- C07C303/06—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof by substitution of hydrogen atoms by sulfo or halosulfonyl groups by reaction with sulfuric acid or sulfur trioxide
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C303/00—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides
- C07C303/26—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of esters of sulfonic acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C303/00—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides
- C07C303/42—Separation; Purification; Stabilisation; Use of additives
- C07C303/44—Separation; Purification
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C407/00—Preparation of peroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic Table
- C07F3/06—Zinc compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/06—Aluminium compounds
- C07F5/069—Aluminium compounds without C-aluminium linkages
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP13193349 | 2013-11-18 | ||
| EP13193349.1 | 2013-11-18 | ||
| PCT/EP2014/074747 WO2015071455A1 (en) | 2013-11-18 | 2014-11-17 | Novel initiator for preparing alkanesulfonic acids from alkane and oleum |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2016540743A JP2016540743A (ja) | 2016-12-28 |
| JP2016540743A5 JP2016540743A5 (cg-RX-API-DMAC7.html) | 2017-10-12 |
| JP6412570B2 true JP6412570B2 (ja) | 2018-10-24 |
Family
ID=49674152
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2016528892A Active JP6412570B2 (ja) | 2013-11-18 | 2014-11-17 | アルカンおよび発煙硫酸からアルカンスルホン酸を製造するための新規な開始剤 |
Country Status (8)
| Country | Link |
|---|---|
| US (2) | US10329251B2 (cg-RX-API-DMAC7.html) |
| EP (1) | EP3071549B1 (cg-RX-API-DMAC7.html) |
| JP (1) | JP6412570B2 (cg-RX-API-DMAC7.html) |
| KR (1) | KR102106763B1 (cg-RX-API-DMAC7.html) |
| CN (1) | CN105705486B (cg-RX-API-DMAC7.html) |
| MY (1) | MY179376A (cg-RX-API-DMAC7.html) |
| SG (1) | SG11201607264XA (cg-RX-API-DMAC7.html) |
| WO (1) | WO2015071455A1 (cg-RX-API-DMAC7.html) |
Families Citing this family (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3068760B1 (en) | 2013-11-13 | 2023-06-07 | Grillo Chemie GmbH | Process for preparing alkanesulfonic acids from sulfur trioxide and an alkane |
| KR102106763B1 (ko) | 2013-11-18 | 2020-05-06 | 바스프 에스이 | 알칸 및 올레움으로부터 알칸설폰산류를 제조하기 위한 신규 개시제 |
| AU2017365556A1 (en) | 2016-11-28 | 2019-05-02 | Basf Se | Solvent-free alkane sulfonation |
| US20200115332A1 (en) * | 2017-02-07 | 2020-04-16 | Grillo-Werke Ag | Method for the production of alkane sulfonic acids |
| US10995063B2 (en) | 2017-03-10 | 2021-05-04 | Veolia North America Regeneration Services, Llc | Integrated processing system with continuous acid loop for converting methane to methane-sulfonic acid |
| US10899703B2 (en) | 2017-03-10 | 2021-01-26 | Veolia North American Regeneration Services, LLC | Radical initiators and chain extenders for converting methane gas into methane-sulfonic acid |
| TW201841881A (zh) * | 2017-04-18 | 2018-12-01 | 德商巴斯夫歐洲公司 | 純化烷烴磺酸酐的方法及使用純化的烷烴磺酸酐製造烷烴磺酸的方法 |
| US10669232B2 (en) * | 2017-05-11 | 2020-06-02 | Arkema Inc. | Processes and systems for recovering methanesulfonic acid in purified form |
| CN110678443B (zh) * | 2017-05-30 | 2022-10-25 | 巴斯夫欧洲公司 | 制造甲磺酸的方法 |
| TW201904938A (zh) | 2017-06-30 | 2019-02-01 | 德商葛里洛沃克股份有限公司 | 用於生產烷磺酸的調節劑 |
| KR102771123B1 (ko) | 2018-02-07 | 2025-02-20 | 바스프 에스이 | 알칸설폰산의 제조방법 |
| FR3077817B1 (fr) * | 2018-02-14 | 2020-02-28 | Arkema France | Procede de synthese industrielle en continu d'acide alcane-sulfonique |
| TWI714964B (zh) | 2018-02-16 | 2021-01-01 | 巴斯夫歐洲公司 | 用於烷磺酸之合成的催化劑 |
| EP4159714A1 (en) * | 2018-03-10 | 2023-04-05 | Veolia North America Regeneration Services, LLC | Compounds, processes, and machinery for converting methane gas into methane sulfonic acid |
| EP3802485A1 (en) * | 2018-05-25 | 2021-04-14 | Grillo-Werke AG | Process for the preparation of haloalkanesulfonic acids from sulfur trioxide and a haloalkane |
| WO2020048965A1 (en) * | 2018-09-04 | 2020-03-12 | Basf Se | Method for the production of alkane sulfonic acids |
| WO2020064466A1 (en) | 2018-09-25 | 2020-04-02 | Basf Se | Catalyst for the synthesis of alkanesulfonic acids |
| WO2020064515A1 (en) | 2018-09-25 | 2020-04-02 | Basf Se | Cations as catalyst in the production of alkane sulfonic acids |
| WO2020064573A1 (en) | 2018-09-25 | 2020-04-02 | Basf Se | Catalysts for the synthesis of alkanesulfonic acids |
| WO2020126855A1 (en) | 2018-12-21 | 2020-06-25 | Basf Se | Mixture comprising methanesulfonic acid and sulfuric acid |
| MY204480A (en) * | 2019-03-21 | 2024-08-30 | Basf Se | Method for the purification of alkanes |
| CN113710650B (zh) | 2019-04-18 | 2023-12-01 | 巴斯夫欧洲公司 | 由甲烷和so3生产无水甲磺酸的方法 |
| EP3763701A1 (en) | 2019-07-10 | 2021-01-13 | Grillo-Werke AG | Improved process for the purification of methane sulfonic acid |
| MX2022000409A (es) | 2019-07-10 | 2022-04-25 | Basf Se | Metodo para reducir la concentracion de so3 en una mezcla de reaccion que comprende acido metanosulfonico y so3. |
| MX2022001602A (es) | 2019-08-07 | 2022-03-11 | Basf Se | Recuperacion de acido metansulfonico libre de agua del flujo de fondo de una columna de destilacion. |
| WO2021023583A1 (en) | 2019-08-07 | 2021-02-11 | Basf Se | Process for the production of alkanesulfonic acids |
| EP3782981A1 (en) | 2019-08-20 | 2021-02-24 | Basf Se | Catalysts for the synthesis of alkanesulfonic acids |
| MX2022003879A (es) * | 2019-10-01 | 2022-04-19 | Basf Se | Proceso para elaborar acidos alcansulfonicos. |
| MX2022004064A (es) | 2019-10-02 | 2022-05-02 | Basf Se | Proceso para elaborar acidos alcansulfonicos. |
| CN111302978A (zh) * | 2020-04-17 | 2020-06-19 | 凯瑞环保科技股份有限公司 | 一种烷基磺酸的合成装置及合成方法 |
| WO2022046543A1 (en) * | 2020-08-24 | 2022-03-03 | University Of Kansas | Alkane multi-sulfonic acids, compositions thereof, and related methods |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2493038A (en) | 1946-05-31 | 1950-01-03 | Houdry Process Corp | Reaction of methane with sulfur trioxide |
| US2619507A (en) | 1951-01-05 | 1952-11-25 | Dow Chemical Co | Di(methanesulfonyl) peroxide and its preparation |
| US4680095A (en) | 1986-11-03 | 1987-07-14 | Pennwalt Corporation | Continuous preparation of dialkanesulfonyl peroxide |
| FR2610320A1 (fr) | 1987-02-03 | 1988-08-05 | Atochem | Composes peroxydes renfermant l'isotope 17o |
| US4910335A (en) | 1989-08-01 | 1990-03-20 | Pennwalt Corporation | Decolorization of alkanesulfonic and arenesulfonic acids |
| GB9023433D0 (en) | 1990-10-27 | 1990-12-12 | Interox Chemicals Ltd | Peroxoacid manufacture |
| CN1318361C (zh) | 2002-11-05 | 2007-05-30 | 艾伦·K·理查兹 | 使用自由基路线和链反应,在最小废物的情况下,使甲烷和其它轻质烷烃无水转化成甲醇和其它衍生物 |
| MXPA05004957A (es) | 2002-11-05 | 2006-01-30 | Alan K Richards | Procesamiento de anhidro iniciado por radicales alcanos ligeros en acido metano-(sulfronico)-sulfonico, metanol y otros compuestos. |
| OA13183A (en) | 2003-06-21 | 2006-12-13 | Alan K Richards | Anhydrous processing of methane into methane-sulfonic acid, methanol, and other compounds. |
| US20080161591A1 (en) | 2003-06-21 | 2008-07-03 | Richards Alan K | Anhydrous processing of methane into methane-sulfonic acid, methanol, and other compounds |
| US7119226B2 (en) | 2004-04-20 | 2006-10-10 | The Penn State Research Foundation | Process for the conversion of methane |
| US20070282151A1 (en) * | 2006-05-19 | 2007-12-06 | Richards Alan K | Manufacture of higher hydrocarbons from methane, via methanesulfonic acid, sulfene, and other pathways |
| EA015910B1 (ru) | 2006-05-24 | 2011-12-30 | Ляйбниц Инститьют Фор Нэчерал Продакт Ресерч Энд Инфекшн Байолоджи Э. Ф. Ханс-Кнелль-Институт (Хки) | Производные бензотиазинона и их применение в качестве антибактериальных средств |
| EP3068760B1 (en) | 2013-11-13 | 2023-06-07 | Grillo Chemie GmbH | Process for preparing alkanesulfonic acids from sulfur trioxide and an alkane |
| WO2015071371A1 (en) | 2013-11-13 | 2015-05-21 | Grillo Chemie Gmbh | Process for preparing bis(alkanesulfonyl) peroxide by oxidation |
| WO2015071351A1 (en) | 2013-11-13 | 2015-05-21 | Grillo Chemie Gmbh | Process for preparing bis(alkanesulfonyl peroxide) |
| KR102106763B1 (ko) | 2013-11-18 | 2020-05-06 | 바스프 에스이 | 알칸 및 올레움으로부터 알칸설폰산류를 제조하기 위한 신규 개시제 |
-
2014
- 2014-11-17 KR KR1020167012178A patent/KR102106763B1/ko active Active
- 2014-11-17 EP EP14799443.8A patent/EP3071549B1/en active Active
- 2014-11-17 WO PCT/EP2014/074747 patent/WO2015071455A1/en not_active Ceased
- 2014-11-17 CN CN201480061403.5A patent/CN105705486B/zh active Active
- 2014-11-17 JP JP2016528892A patent/JP6412570B2/ja active Active
- 2014-11-17 MY MYPI2016704208A patent/MY179376A/en unknown
- 2014-11-17 SG SG11201607264XA patent/SG11201607264XA/en unknown
- 2014-11-17 US US15/035,865 patent/US10329251B2/en active Active
-
2019
- 2019-05-03 US US16/403,112 patent/US11180448B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| SG11201607264XA (en) | 2016-10-28 |
| MY179376A (en) | 2020-11-05 |
| EP3071549A1 (en) | 2016-09-28 |
| US11180448B2 (en) | 2021-11-23 |
| US20190256461A1 (en) | 2019-08-22 |
| CN105705486A (zh) | 2016-06-22 |
| JP2016540743A (ja) | 2016-12-28 |
| KR102106763B1 (ko) | 2020-05-06 |
| US10329251B2 (en) | 2019-06-25 |
| US20160289181A1 (en) | 2016-10-06 |
| CN105705486B (zh) | 2019-03-01 |
| KR20160086832A (ko) | 2016-07-20 |
| EP3071549B1 (en) | 2017-10-18 |
| WO2015071455A1 (en) | 2015-05-21 |
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