JP6392195B2 - 二次元ナノ材料を形成するプロセス - Google Patents
二次元ナノ材料を形成するプロセス Download PDFInfo
- Publication number
- JP6392195B2 JP6392195B2 JP2015209700A JP2015209700A JP6392195B2 JP 6392195 B2 JP6392195 B2 JP 6392195B2 JP 2015209700 A JP2015209700 A JP 2015209700A JP 2015209700 A JP2015209700 A JP 2015209700A JP 6392195 B2 JP6392195 B2 JP 6392195B2
- Authority
- JP
- Japan
- Prior art keywords
- bulk
- lithiated
- dimensional material
- dimensional
- mos
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000000034 method Methods 0.000 title claims description 23
- 239000002086 nanomaterial Substances 0.000 title claims description 4
- 239000000463 material Substances 0.000 claims description 53
- HSZCZNFXUDYRKD-UHFFFAOYSA-M lithium iodide Chemical compound [Li+].[I-] HSZCZNFXUDYRKD-UHFFFAOYSA-M 0.000 claims description 33
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims description 18
- 238000004729 solvothermal method Methods 0.000 claims description 13
- 239000002904 solvent Substances 0.000 claims description 10
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 claims description 4
- 229910052982 molybdenum disulfide Inorganic materials 0.000 claims description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 2
- 238000001914 filtration Methods 0.000 claims description 2
- 229910052744 lithium Inorganic materials 0.000 claims description 2
- 238000001816 cooling Methods 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 description 13
- MZRVEZGGRBJDDB-UHFFFAOYSA-N N-Butyllithium Chemical compound [Li]CCCC MZRVEZGGRBJDDB-UHFFFAOYSA-N 0.000 description 8
- 239000002135 nanosheet Substances 0.000 description 7
- 238000006138 lithiation reaction Methods 0.000 description 5
- 238000003917 TEM image Methods 0.000 description 4
- 230000035484 reaction time Effects 0.000 description 4
- 230000000977 initiatory effect Effects 0.000 description 3
- 239000002105 nanoparticle Substances 0.000 description 3
- 229910052723 transition metal Inorganic materials 0.000 description 3
- 150000003624 transition metals Chemical class 0.000 description 3
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 2
- 238000001069 Raman spectroscopy Methods 0.000 description 2
- 238000002441 X-ray diffraction Methods 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 239000007772 electrode material Substances 0.000 description 2
- 238000004146 energy storage Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000009830 intercalation Methods 0.000 description 2
- 230000002687 intercalation Effects 0.000 description 2
- 239000011630 iodine Substances 0.000 description 2
- 229910052740 iodine Inorganic materials 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 238000004611 spectroscopical analysis Methods 0.000 description 2
- 239000011232 storage material Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 238000001237 Raman spectrum Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000004299 exfoliation Methods 0.000 description 1
- 229910021389 graphene Inorganic materials 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000010183 spectrum analysis Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G39/00—Compounds of molybdenum
- C01G39/06—Sulfides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
- C01B3/08—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents with metals
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
- C01D15/00—Lithium compounds
- C01D15/02—Oxides; Hydroxides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/08—Intercalated structures, i.e. with atoms or molecules intercalated in their structure
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/20—Two-dimensional structures
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
- C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/80—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70
- C01P2002/82—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70 by IR- or Raman-data
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/01—Particle morphology depicted by an image
- C01P2004/04—Particle morphology depicted by an image obtained by TEM, STEM, STM or AFM
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/20—Particle morphology extending in two dimensions, e.g. plate-like
- C01P2004/24—Nanoplates, i.e. plate-like particles with a thickness from 1-100 nanometer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Combustion & Propulsion (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Manufacture And Refinement Of Metals (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US14/526,929 | 2014-10-29 | ||
| US14/526,929 US9409792B2 (en) | 2014-10-29 | 2014-10-29 | Solventhermal synthesis of nanosized two dimensional materials |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2016088840A JP2016088840A (ja) | 2016-05-23 |
| JP2016088840A5 JP2016088840A5 (enExample) | 2017-04-27 |
| JP6392195B2 true JP6392195B2 (ja) | 2018-09-19 |
Family
ID=55851872
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2015209700A Expired - Fee Related JP6392195B2 (ja) | 2014-10-29 | 2015-10-26 | 二次元ナノ材料を形成するプロセス |
Country Status (3)
| Country | Link |
|---|---|
| US (1) | US9409792B2 (enExample) |
| JP (1) | JP6392195B2 (enExample) |
| CN (1) | CN105565383B (enExample) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20180072947A1 (en) * | 2016-09-12 | 2018-03-15 | Nanoco Technologies Ltd. | Solution-Phase Synthesis of Layered Transition Metal Dichalcogenide Nanoparticles |
| KR102526649B1 (ko) | 2016-11-30 | 2023-04-27 | 삼성전자주식회사 | 이차원 물질을 포함하는 반도체소자 및 그 제조방법 |
| CN108190960B (zh) * | 2018-01-23 | 2020-05-08 | 福州大学 | 一种基于电解液溶剂热插锂剥离制备单层二硫化钼的方法 |
| CN110776006B (zh) * | 2018-07-27 | 2023-07-21 | 香港科技大学 | 用作锂/钠离子电池负极材料的超薄硫化锑纳米片的制备方法 |
| WO2024047822A1 (ja) * | 2022-08-31 | 2024-03-07 | 国立大学法人東北大学 | 層状物質ナノシートの製造方法、層状ＭｏＳ２ナノシート及び層状グラファイトナノシート |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3933688A (en) | 1974-07-12 | 1976-01-20 | Exxon Research And Engineering Company | Method for lithiating metal chalcogenides and intercalated products thereof |
| US4822590A (en) * | 1986-04-23 | 1989-04-18 | Simon Fraser University | Forms of transition metal dichalcogenides |
| US7892514B2 (en) * | 2007-02-22 | 2011-02-22 | Nanotek Instruments, Inc. | Method of producing nano-scaled graphene and inorganic platelets and their nanocomposites |
| GB201101482D0 (en) * | 2011-01-28 | 2011-03-16 | Isis Innovation | Exfoiation of lyered material |
| CN103275355B (zh) * | 2013-05-20 | 2014-10-22 | 中国科学技术大学 | 一种有机改性二硫化钼纳米片层及其制备方法 |
| CN103833081B (zh) * | 2014-02-21 | 2016-04-06 | 桂林理工大学 | 一种表面含有反应性基团的二硫化钼纳米片的制备方法 |
| CN103803651B (zh) * | 2014-03-11 | 2015-06-03 | 新疆大学 | 一种制备二硫化钼纳米片的方法 |
| CN103937329A (zh) | 2014-05-09 | 2014-07-23 | 浙江大学 | 一种具有高稳定性的二硫化钼纳米片层分散液的制备方法 |
-
2014
- 2014-10-29 US US14/526,929 patent/US9409792B2/en not_active Expired - Fee Related
-
2015
- 2015-10-14 CN CN201510660846.2A patent/CN105565383B/zh not_active Expired - Fee Related
- 2015-10-26 JP JP2015209700A patent/JP6392195B2/ja not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN105565383A (zh) | 2016-05-11 |
| JP2016088840A (ja) | 2016-05-23 |
| CN105565383B (zh) | 2018-10-12 |
| US20160122198A1 (en) | 2016-05-05 |
| US9409792B2 (en) | 2016-08-09 |
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