JP6279552B2 - 末端飽和カルボン酸エステルの化学選択的還元のためのプロセス - Google Patents
末端飽和カルボン酸エステルの化学選択的還元のためのプロセス Download PDFInfo
- Publication number
- JP6279552B2 JP6279552B2 JP2015512059A JP2015512059A JP6279552B2 JP 6279552 B2 JP6279552 B2 JP 6279552B2 JP 2015512059 A JP2015512059 A JP 2015512059A JP 2015512059 A JP2015512059 A JP 2015512059A JP 6279552 B2 JP6279552 B2 JP 6279552B2
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- JP
- Japan
- Prior art keywords
- alkene
- group
- ester
- ruthenium
- complex
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
- C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
- C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
- C07C29/149—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/189—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms containing both nitrogen and phosphorus as complexing atoms, including e.g. phosphino moieties, in one at least bidentate or bridging ligand
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/60—Reduction reactions, e.g. hydrogenation
- B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
- B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
- B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
- B01J2531/0241—Rigid ligands, e.g. extended sp2-carbon frameworks or geminal di- or trisubstitution
- B01J2531/0255—Ligands comprising the N2S2 or N2P2 donor atom set, e.g. diiminodithiolates or diiminodiphosphines with complete pi-conjugation between all donor centres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/821—Ruthenium
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB1208589.0 | 2012-05-16 | ||
| GBGB1208589.0A GB201208589D0 (en) | 2012-05-16 | 2012-05-16 | Improvements in or relating to organic compounds |
| PCT/EP2013/060150 WO2013171302A1 (en) | 2012-05-16 | 2013-05-16 | Process for the chemoselective reduction of terminally saturated carboxylic esters |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2015520156A JP2015520156A (ja) | 2015-07-16 |
| JP2015520156A5 JP2015520156A5 (https=) | 2017-09-28 |
| JP6279552B2 true JP6279552B2 (ja) | 2018-02-14 |
Family
ID=46458913
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2015512059A Active JP6279552B2 (ja) | 2012-05-16 | 2013-05-16 | 末端飽和カルボン酸エステルの化学選択的還元のためのプロセス |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US9193651B2 (https=) |
| EP (1) | EP2850050B1 (https=) |
| JP (1) | JP6279552B2 (https=) |
| CN (1) | CN104284875B (https=) |
| BR (1) | BR112014028156A2 (https=) |
| GB (1) | GB201208589D0 (https=) |
| IN (1) | IN2014DN08413A (https=) |
| MX (1) | MX363196B (https=) |
| SG (1) | SG11201406503VA (https=) |
| WO (1) | WO2013171302A1 (https=) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR3013047B1 (fr) | 2013-11-08 | 2016-01-01 | Pivert | Procede de synthese d'esters |
| ES2686723T3 (es) | 2013-12-18 | 2018-10-19 | Firmenich Sa | Hidrogenación de ésteres con complejos de Fe/ligandos tridentados |
| US9416091B1 (en) | 2015-02-04 | 2016-08-16 | Sirrus, Inc. | Catalytic transesterification of ester compounds with groups reactive under transesterification conditions |
| CN105582961B (zh) * | 2014-10-24 | 2018-04-06 | 中国石油化工股份有限公司 | 1,4‑环己烷二甲酸二甲酯氢化催化剂 |
| US10501400B2 (en) | 2015-02-04 | 2019-12-10 | Sirrus, Inc. | Heterogeneous catalytic transesterification of ester compounds with groups reactive under transesterification conditions |
| WO2017087710A2 (en) | 2015-11-18 | 2017-05-26 | Provivi, Inc. | Production of fatty olefin derivatives via olefin metathesis |
| US10428177B2 (en) | 2016-06-03 | 2019-10-01 | Sirrus, Inc. | Water absorbing or water soluble polymers, intermediate compounds, and methods thereof |
| HUE073559T2 (hu) | 2017-02-17 | 2026-01-28 | Provivi Inc | Feromonok és kapcsolódó anyagok szintézise olefin-metatézisen keresztül |
| GB201800276D0 (en) | 2018-01-08 | 2018-02-21 | Univ Court Univ St Andrews | Maganese-catalysed hydrogenation of esters |
| JP7789566B2 (ja) | 2019-07-03 | 2025-12-22 | ビーエーエスエフ ソシエタス・ヨーロピア | Ru-PNN錯体存在下でのエステルのアルコールへの水素化 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1868964B1 (en) | 2005-04-05 | 2016-11-23 | Firmenich Sa | Hydrogenation of esters with ru/bidentate ligands complexes |
| RU2007140870A (ru) * | 2005-04-05 | 2009-05-20 | Фирмениш Са (Ch) | Гидрирование сложных эфиров в присутствии комплексов ru c тетрадентатными лигандами |
| DE602007005027D1 (de) * | 2006-11-27 | 2010-04-08 | Firmenich & Cie | Hydrierung von estern mit ru/bidentat-ligand-komplexen |
| JP5849710B2 (ja) * | 2011-02-03 | 2016-02-03 | セントラル硝子株式会社 | β−フルオロアルコール類の製造方法 |
| CN103857687B (zh) | 2011-08-18 | 2020-10-16 | 德米特里·顾塞维 | 氢化和脱氢催化剂、以及制备和使用它们的方法 |
-
2012
- 2012-05-16 GB GBGB1208589.0A patent/GB201208589D0/en not_active Ceased
-
2013
- 2013-05-16 IN IN8413DEN2014 patent/IN2014DN08413A/en unknown
- 2013-05-16 US US14/398,076 patent/US9193651B2/en active Active
- 2013-05-16 BR BR112014028156A patent/BR112014028156A2/pt not_active Application Discontinuation
- 2013-05-16 EP EP13724563.5A patent/EP2850050B1/en active Active
- 2013-05-16 JP JP2015512059A patent/JP6279552B2/ja active Active
- 2013-05-16 WO PCT/EP2013/060150 patent/WO2013171302A1/en not_active Ceased
- 2013-05-16 SG SG11201406503VA patent/SG11201406503VA/en unknown
- 2013-05-16 CN CN201380025207.8A patent/CN104284875B/zh active Active
- 2013-05-16 MX MX2014012447A patent/MX363196B/es unknown
Also Published As
| Publication number | Publication date |
|---|---|
| JP2015520156A (ja) | 2015-07-16 |
| EP2850050B1 (en) | 2018-12-12 |
| BR112014028156A2 (pt) | 2017-06-27 |
| EP2850050A1 (en) | 2015-03-25 |
| GB201208589D0 (en) | 2012-06-27 |
| MX363196B (es) | 2019-03-14 |
| US20150152029A1 (en) | 2015-06-04 |
| US9193651B2 (en) | 2015-11-24 |
| MX2014012447A (es) | 2015-01-15 |
| CN104284875B (zh) | 2017-10-03 |
| IN2014DN08413A (https=) | 2015-05-08 |
| CN104284875A (zh) | 2015-01-14 |
| WO2013171302A1 (en) | 2013-11-21 |
| SG11201406503VA (en) | 2014-11-27 |
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