MX363196B - Proceso para la reduccion quimoselectiva de esteres carboxilicos terminalmente saturados. - Google Patents

Proceso para la reduccion quimoselectiva de esteres carboxilicos terminalmente saturados.

Info

Publication number
MX363196B
MX363196B MX2014012447A MX2014012447A MX363196B MX 363196 B MX363196 B MX 363196B MX 2014012447 A MX2014012447 A MX 2014012447A MX 2014012447 A MX2014012447 A MX 2014012447A MX 363196 B MX363196 B MX 363196B
Authority
MX
Mexico
Prior art keywords
carboxylic esters
saturated carboxylic
chemoselective reduction
terminally saturated
terminally
Prior art date
Application number
MX2014012447A
Other languages
English (en)
Other versions
MX2014012447A (es
Inventor
Goeke Andreas
Wilhelm Geisser Roger
Schroeder Fridtjof
Original Assignee
Givaudan Sa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Givaudan Sa filed Critical Givaudan Sa
Publication of MX2014012447A publication Critical patent/MX2014012447A/es
Publication of MX363196B publication Critical patent/MX363196B/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
    • C07C29/149—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/189—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms containing both nitrogen and phosphorus as complexing atoms, including e.g. phosphino moieties, in one at least bidentate or bridging ligand
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
    • B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
    • B01J2531/0241—Rigid ligands, e.g. extended sp2-carbon frameworks or geminal di- or trisubstitution
    • B01J2531/0255—Ligands comprising the N2S2 or N2P2 donor atom set, e.g. diiminodithiolates or diiminodiphosphines with complete pi-conjugation between all donor centres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Se describe la reducción quimioselectiva de un éster carboxílico (I) a un alcohol por hidrogenación catalítica, particular en la presencia de un complejo de metal de transición, de manera más particular en la presencia de un complejo de rutenio (II).
MX2014012447A 2012-05-16 2013-05-16 Proceso para la reduccion quimoselectiva de esteres carboxilicos terminalmente saturados. MX363196B (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GBGB1208589.0A GB201208589D0 (en) 2012-05-16 2012-05-16 Improvements in or relating to organic compounds
PCT/EP2013/060150 WO2013171302A1 (en) 2012-05-16 2013-05-16 Process for the chemoselective reduction of terminally saturated carboxylic esters

Publications (2)

Publication Number Publication Date
MX2014012447A MX2014012447A (es) 2015-01-15
MX363196B true MX363196B (es) 2019-03-14

Family

ID=46458913

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2014012447A MX363196B (es) 2012-05-16 2013-05-16 Proceso para la reduccion quimoselectiva de esteres carboxilicos terminalmente saturados.

Country Status (10)

Country Link
US (1) US9193651B2 (es)
EP (1) EP2850050B1 (es)
JP (1) JP6279552B2 (es)
CN (1) CN104284875B (es)
BR (1) BR112014028156A2 (es)
GB (1) GB201208589D0 (es)
IN (1) IN2014DN08413A (es)
MX (1) MX363196B (es)
SG (1) SG11201406503VA (es)
WO (1) WO2013171302A1 (es)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3013047B1 (fr) * 2013-11-08 2016-01-01 Pivert Procede de synthese d'esters
EP3083647B1 (en) 2013-12-18 2018-07-04 Firmenich SA Hydrogenation of esters with fe/tridentate ligands complexes
US9416091B1 (en) * 2015-02-04 2016-08-16 Sirrus, Inc. Catalytic transesterification of ester compounds with groups reactive under transesterification conditions
CN105582961B (zh) * 2014-10-24 2018-04-06 中国石油化工股份有限公司 1,4‑环己烷二甲酸二甲酯氢化催化剂
US10501400B2 (en) 2015-02-04 2019-12-10 Sirrus, Inc. Heterogeneous catalytic transesterification of ester compounds with groups reactive under transesterification conditions
AU2016357756B2 (en) 2015-11-18 2021-09-30 Provivi, Inc. Production of fatty olefin derivatives via olefin metathesis
US10428177B2 (en) 2016-06-03 2019-10-01 Sirrus, Inc. Water absorbing or water soluble polymers, intermediate compounds, and methods thereof
CN110603240B (zh) 2017-02-17 2022-11-15 普罗维维公司 通过烯烃复分解合成信息素和相关物质
GB201800276D0 (en) 2018-01-08 2018-02-21 Univ Court Univ St Andrews Maganese-catalysed hydrogenation of esters
EP3994117A1 (de) 2019-07-03 2022-05-11 Basf Se Hydrierung von estern zu alkoholen in gegenwart eines ru-pnn-komplexes

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
MX2007012298A (es) * 2005-04-05 2007-10-16 Firmenich & Cie Hidrogenacion de esteres con complejos ligandos de ru/tetradentados.
CN101137601B (zh) * 2005-04-05 2011-08-10 弗门尼舍有限公司 通过钌/二齿配体的络合物进行的酯的氢化
ES2339073T3 (es) * 2006-11-27 2010-05-14 Firmenich Sa Hidrogenacion de esteres con complejos de ru/ligandos bidentados.
JP5849710B2 (ja) * 2011-02-03 2016-02-03 セントラル硝子株式会社 β−フルオロアルコール類の製造方法
JP2014524428A (ja) 2011-08-18 2014-09-22 ドミトリー・ゴッサブ 水素化および脱水素触媒、ならびにこれを作成する方法および用いる方法

Also Published As

Publication number Publication date
GB201208589D0 (en) 2012-06-27
US9193651B2 (en) 2015-11-24
JP2015520156A (ja) 2015-07-16
MX2014012447A (es) 2015-01-15
WO2013171302A1 (en) 2013-11-21
CN104284875B (zh) 2017-10-03
EP2850050A1 (en) 2015-03-25
BR112014028156A2 (pt) 2017-06-27
US20150152029A1 (en) 2015-06-04
JP6279552B2 (ja) 2018-02-14
IN2014DN08413A (es) 2015-05-08
CN104284875A (zh) 2015-01-14
EP2850050B1 (en) 2018-12-12
SG11201406503VA (en) 2014-11-27

Similar Documents

Publication Publication Date Title
MX363196B (es) Proceso para la reduccion quimoselectiva de esteres carboxilicos terminalmente saturados.
EA201590026A1 (ru) Выработка длинноцепочечных полиненасыщенных жирных кислот в растительных клетках
MY177225A (en) Process for purifying an acid composition comprising 2-formyl-furan-5-carboxylic acid and 2, 5-furandicarboxylic acid
MX2014015768A (es) Microorganismo recombinante para la produccion fermentativa de metionina.
SG11201601450UA (en) Catalyst for producing an unsaturated carboxylic acid by gas phase oxidation of an unsaturated aldehyde
PH12014501212A1 (en) Compositions comprising 20-carbon fatty acids and methods of making and using same
IN2015DN02292A (es)
MY175678A (en) Microorganisms and methods for enhancing the availability of reducing equivalents in the presence of methanol, and for producing 1,4-butanediol related thereto
IN2012DE00662A (es)
MY156726A (en) Process for producing fatty alcohols by hydrogenation of fatty acid triglycerides on a copper-containing heterogeneous catalyst
SG195111A1 (en) Process for preparing methacrylic acid
WO2013052971A3 (en) Process for producing ethanol using hydrogenation catalysts prepared from polyoxometalate precursors
MY170265A (en) Polythiols as cis/trans isomerization catalysts for unsaturated compounds
MX2015007904A (es) Productos de hidrogenacion obtenidos a partir de esteres de acidos carboxilicos derivados biologicamente.
PH12015501453A1 (en) Method for producing olefin
IN2015DN00531A (es)
MY171548A (en) Dual catalyst esterification
SG11201404923SA (en) Dehydration of water containing source of formaldehyde, and a method for producing an ethylenically unsaturated carboxylic ester
IN2014DN07933A (es)
MX342471B (es) Procedimiento de preparacion de un ester de acido carboxilico.
MY175343A (en) Efficient process of asymmetric hydrogenation of unsaturated ketones using additives
WO2013056268A3 (en) Preparation of hydrogenation catalysts from polyoxometalate precursors and process for using same to produce ethanol
PL2573064T3 (pl) Sposób wytwarzania estrów kwasu alkenowego z laktonów
MX2015000827A (es) Metodo catalizado por el complejo carbeno de metal de trasicion para producir esteres del acido carboxilico a partir de alcoholes bajo deshidratacion.
PL2675782T3 (pl) Sposób wytwarzania estrów kwasów alkenowych z laktonów