JP6263548B2 - 室温硬化性シロキサン系ゲル - Google Patents
室温硬化性シロキサン系ゲル Download PDFInfo
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- JP6263548B2 JP6263548B2 JP2015547412A JP2015547412A JP6263548B2 JP 6263548 B2 JP6263548 B2 JP 6263548B2 JP 2015547412 A JP2015547412 A JP 2015547412A JP 2015547412 A JP2015547412 A JP 2015547412A JP 6263548 B2 JP6263548 B2 JP 6263548B2
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- gel
- curable
- adhesive
- condensation
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- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 title claims description 63
- 239000000203 mixture Substances 0.000 claims description 87
- 239000000853 adhesive Substances 0.000 claims description 71
- 230000001070 adhesive effect Effects 0.000 claims description 69
- 239000012530 fluid Substances 0.000 claims description 55
- 238000009833 condensation Methods 0.000 claims description 47
- 230000005494 condensation Effects 0.000 claims description 47
- 125000000217 alkyl group Chemical group 0.000 claims description 41
- 125000003118 aryl group Chemical group 0.000 claims description 38
- 239000000758 substrate Substances 0.000 claims description 33
- 229920002050 silicone resin Polymers 0.000 claims description 30
- 150000001875 compounds Chemical class 0.000 claims description 29
- 125000003277 amino group Chemical group 0.000 claims description 25
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 24
- 239000002243 precursor Substances 0.000 claims description 19
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 17
- 239000003054 catalyst Substances 0.000 claims description 17
- 125000001072 heteroaryl group Chemical group 0.000 claims description 17
- 125000004404 heteroalkyl group Chemical group 0.000 claims description 15
- 239000007795 chemical reaction product Substances 0.000 claims description 9
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 8
- 125000005647 linker group Chemical group 0.000 claims description 6
- 239000003999 initiator Substances 0.000 claims description 5
- 239000000499 gel Substances 0.000 description 111
- 239000000463 material Substances 0.000 description 33
- 229920001296 polysiloxane Polymers 0.000 description 31
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- -1 amine compound Chemical class 0.000 description 24
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- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 16
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- 125000002947 alkylene group Chemical group 0.000 description 10
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 10
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- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 6
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- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 6
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- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 4
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- 229910008051 Si-OH Inorganic materials 0.000 description 3
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- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
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- 125000005370 alkoxysilyl group Chemical group 0.000 description 3
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- SCPYDCQAZCOKTP-UHFFFAOYSA-N silanol Chemical compound [SiH3]O SCPYDCQAZCOKTP-UHFFFAOYSA-N 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
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- VSKJLJHPAFKHBX-UHFFFAOYSA-N 2-methylbuta-1,3-diene;styrene Chemical compound CC(=C)C=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 VSKJLJHPAFKHBX-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 2
- 241001465754 Metazoa Species 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- 229910004298 SiO 2 Inorganic materials 0.000 description 2
- DTQVDTLACAAQTR-UHFFFAOYSA-N Trifluoroacetic acid Chemical compound OC(=O)C(F)(F)F DTQVDTLACAAQTR-UHFFFAOYSA-N 0.000 description 2
- 239000002390 adhesive tape Substances 0.000 description 2
- 150000001335 aliphatic alkanes Chemical class 0.000 description 2
- 125000002490 anilino group Chemical group [H]N(*)C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 2
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- IJOOHPMOJXWVHK-UHFFFAOYSA-N chlorotrimethylsilane Chemical compound C[Si](C)(C)Cl IJOOHPMOJXWVHK-UHFFFAOYSA-N 0.000 description 2
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- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 2
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- FFUAGWLWBBFQJT-UHFFFAOYSA-N hexamethyldisilazane Chemical compound C[Si](C)(C)N[Si](C)(C)C FFUAGWLWBBFQJT-UHFFFAOYSA-N 0.000 description 2
- 238000006459 hydrosilylation reaction Methods 0.000 description 2
- 125000000250 methylamino group Chemical group [H]N(*)C([H])([H])[H] 0.000 description 2
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
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- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 description 1
- YJTKZCDBKVTVBY-UHFFFAOYSA-N 1,3-Diphenylbenzene Chemical group C1=CC=CC=C1C1=CC=CC(C=2C=CC=CC=2)=C1 YJTKZCDBKVTVBY-UHFFFAOYSA-N 0.000 description 1
- GOCRPOKWZIVUQG-UHFFFAOYSA-N 3-(diethoxymethylsilyl)propan-1-amine Chemical compound CCOC(OCC)[SiH2]CCCN GOCRPOKWZIVUQG-UHFFFAOYSA-N 0.000 description 1
- 241001247482 Amsonia Species 0.000 description 1
- 229910001369 Brass Inorganic materials 0.000 description 1
- 102000008186 Collagen Human genes 0.000 description 1
- 108010035532 Collagen Proteins 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 229920001875 Ebonite Polymers 0.000 description 1
- 244000043261 Hevea brasiliensis Species 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- 229920002614 Polyether block amide Polymers 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 229910004283 SiO 4 Inorganic materials 0.000 description 1
- 229910020175 SiOH Inorganic materials 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 229910002808 Si–O–Si Inorganic materials 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
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- 239000000654 additive Substances 0.000 description 1
- 239000002313 adhesive film Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 125000005103 alkyl silyl group Chemical group 0.000 description 1
- 125000001118 alkylidene group Chemical group 0.000 description 1
- 125000002178 anthracenyl group Chemical group C1(=CC=CC2=CC3=CC=CC=C3C=C12)* 0.000 description 1
- 125000005428 anthryl group Chemical group [H]C1=C([H])C([H])=C2C([H])=C3C(*)=C([H])C([H])=C([H])C3=C([H])C2=C1[H] 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 239000003139 biocide Substances 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 239000010951 brass Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
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- 239000007799 cork Substances 0.000 description 1
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- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 125000001664 diethylamino group Chemical group [H]C([H])([H])C([H])([H])N(*)C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000002147 dimethylamino group Chemical group [H]C([H])([H])N(*)C([H])([H])[H] 0.000 description 1
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- LWIGVRDDANOFTD-UHFFFAOYSA-N hydroxy(dimethyl)silane Chemical group C[SiH](C)O LWIGVRDDANOFTD-UHFFFAOYSA-N 0.000 description 1
- 230000001969 hypertrophic effect Effects 0.000 description 1
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- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
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- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000003136 n-heptyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- LWFWUJCJKPUZLV-UHFFFAOYSA-N n-trimethylsilylacetamide Chemical compound CC(=O)N[Si](C)(C)C LWFWUJCJKPUZLV-UHFFFAOYSA-N 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
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- 150000001451 organic peroxides Chemical group 0.000 description 1
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- 125000002080 perylenyl group Chemical group C1(=CC=C2C=CC=C3C4=CC=CC5=CC=CC(C1=C23)=C45)* 0.000 description 1
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- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
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- 229940124597 therapeutic agent Drugs 0.000 description 1
- 239000005051 trimethylchlorosilane Substances 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/42—Block-or graft-polymers containing polysiloxane sequences
- C08G77/44—Block-or graft-polymers containing polysiloxane sequences containing only polysiloxane sequences
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
- C08K5/544—Silicon-containing compounds containing nitrogen
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L24/00—Surgical adhesives or cements; Adhesives for colostomy devices
- A61L24/04—Surgical adhesives or cements; Adhesives for colostomy devices containing macromolecular materials
- A61L24/046—Surgical adhesives or cements; Adhesives for colostomy devices containing macromolecular materials obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/28—Treatment by wave energy or particle radiation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J183/00—Adhesives based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Adhesives based on derivatives of such polymers
- C09J183/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J183/00—Adhesives based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Adhesives based on derivatives of such polymers
- C09J183/10—Block or graft copolymers containing polysiloxane sequences
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/40—Adhesives in the form of films or foils characterised by release liners
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/10—Materials in mouldable or extrudable form for sealing or packing joints or covers
- C09K3/1006—Materials in mouldable or extrudable form for sealing or packing joints or covers characterised by the chemical nature of one of its constituents
- C09K3/1018—Macromolecular compounds having one or more carbon-to-silicon linkages
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2220/00—Compositions for preparing gels other than hydrogels, aerogels and xerogels
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/14—Polysiloxanes containing silicon bound to oxygen-containing groups
- C08G77/16—Polysiloxanes containing silicon bound to oxygen-containing groups to hydroxyl groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
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- Surgery (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Sealing Material Composition (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Adhesive Tapes (AREA)
- Materials For Medical Uses (AREA)
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| US201261736107P | 2012-12-12 | 2012-12-12 | |
| US61/736,107 | 2012-12-12 | ||
| PCT/US2013/073070 WO2014093093A1 (en) | 2012-12-12 | 2013-12-04 | Room temperature curable siloxane-based gels |
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| JP2016501942A JP2016501942A (ja) | 2016-01-21 |
| JP2016501942A5 JP2016501942A5 (enExample) | 2017-01-26 |
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| WO (1) | WO2014093093A1 (enExample) |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| US9980737B2 (en) | 2014-08-04 | 2018-05-29 | Medos International Sarl | Flexible transport auger |
| EP3201283A2 (en) * | 2014-10-02 | 2017-08-09 | Zephyros Inc. | Repositionable adhesive |
| JP2018513895A (ja) | 2015-04-06 | 2018-05-31 | スリーエム イノベイティブ プロパティズ カンパニー | 取り外し可能なフィルムを形成するゲル組成物及びこれらの適用方法 |
| TWI730984B (zh) | 2015-09-18 | 2021-06-21 | 德商漢高智慧財產控股公司 | 可固化且光學透明之壓敏黏著劑及其用途 |
| EP3352715B1 (en) * | 2015-09-24 | 2019-06-26 | Coloplast A/S | An ostomy appliance with a release liner with an enclosure |
| CN108430453B (zh) * | 2015-12-21 | 2023-03-17 | 拜耳股份有限公司 | 制造药物递送装置的方法和根据该方法制成的药物递送装置 |
| EP3547970A4 (en) | 2016-12-02 | 2020-11-25 | 3M Innovative Properties Company | MUSCLE OR JOINT SUPPORT ARTICLE EQUIPPED WITH A STRAP |
| EP3547971A4 (en) | 2016-12-02 | 2020-07-15 | 3M Innovative Properties Company | MUSCLE OR JOINT SUPPORTS |
| WO2018102322A1 (en) | 2016-12-02 | 2018-06-07 | 3M Innovative Properties Company | Muscle or joint support article with bump |
| CN109957111A (zh) * | 2017-12-25 | 2019-07-02 | 中国科学院上海硅酸盐研究所 | 一种自固化金属防腐蚀杂化硅溶胶及其制备方法与应用 |
| EP3775086B1 (en) | 2018-04-05 | 2022-09-14 | 3M Innovative Properties Company | Gel adhesive comprising crosslinked blend of polydiorganosiloxane and acrylic polymer |
| BR112020020291A2 (pt) * | 2018-04-05 | 2021-01-12 | 3M Innovative Properties Company | Composição adesiva em gel e artigo adesivo em gel |
| JP7420471B2 (ja) * | 2018-11-15 | 2024-01-23 | スリーエム イノベイティブ プロパティズ カンパニー | シリコーン感圧接着剤及びシリコーン感圧接着剤組成物 |
| CN110563366B (zh) * | 2019-10-17 | 2021-10-12 | 上海大学 | 一种双相有机-无机杂化硅溶胶及其制备方法与应用 |
| CN110776664B (zh) * | 2019-10-25 | 2022-06-24 | 航天特种材料及工艺技术研究所 | 一种缩合型有机硅树脂气凝胶及其制备方法 |
| CN110591638B (zh) * | 2019-11-04 | 2021-10-19 | 镇江博慎新材料有限公司 | 一种低比例双组分脱醇型有机硅密封胶及其制备方法和应用 |
| CN111925482B (zh) * | 2020-07-09 | 2021-11-16 | 北京航空航天大学 | 一种聚合物流体凝胶材料、其制备方法和用途 |
| US20240124720A1 (en) | 2022-10-13 | 2024-04-18 | Devil's Cask, LLC | Liquid silicone coating for barrels used for aging alcoholic beverages |
| WO2024209307A1 (en) * | 2023-04-07 | 2024-10-10 | Solventum Intellectual Properties Company | Pressure activated adhesives |
Family Cites Families (38)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA711756A (en) | 1965-06-15 | R. Pail Daniel | Organosiloxane pressure-sensitive adhesive composition | |
| NO134790C (no) | 1968-07-09 | 1984-03-22 | Smith & Nephew | Klebende,; trykkfoelsomt, vanndamp-permeabelt produkt for bruk paa hud hos mennesker. |
| FR2228814B1 (enExample) * | 1973-05-11 | 1975-11-21 | Rhone Poulenc Ind | |
| WO1983003549A1 (en) | 1982-04-08 | 1983-10-27 | Smith And Nephew Associated Companies P.L.C. | Surgical adhesive dressing |
| JPS62225580A (ja) * | 1986-03-26 | 1987-10-03 | Toray Silicone Co Ltd | ロ−ル巻き接着剤 |
| US4831070A (en) * | 1987-11-02 | 1989-05-16 | Dow Corning Corporation | Moldable elastomeric pressure sensitive adhesives |
| US4865920A (en) * | 1988-09-20 | 1989-09-12 | Dow Corning Corporation | Hot-melt pressure sensitive adhesive article and method of making |
| US5088483A (en) | 1988-11-04 | 1992-02-18 | Minnesota Mining And Manufacturing Co. | Adhesive frame bandage |
| CA2038902A1 (en) * | 1990-04-13 | 1991-10-14 | Randall Paul Sweet | Hot-melt silicone pressure sensitive adhesives with phenyl-containing siloxane fluid additive and related methods and articles |
| US5160315A (en) | 1991-04-05 | 1992-11-03 | Minnesota Mining And Manufacturing Company | Combined adhesive strip and transparent dressing delivery system |
| JPH05239433A (ja) * | 1992-02-25 | 1993-09-17 | Toray Dow Corning Silicone Co Ltd | 湿気硬化性シリコーン粘着剤組成物 |
| US5482988A (en) * | 1994-01-14 | 1996-01-09 | Dow Corning Corporation | Hot-melt silicone pressure sensitive adhesive with siloxylated polyether waxes as additives |
| SE503384C2 (sv) | 1994-09-20 | 1996-06-03 | Moelnlycke Ab | Förband innefattande en silikongel i vilken ett bärarmaterial är inneslutet |
| DE19733168A1 (de) * | 1997-07-31 | 1999-02-04 | Wacker Chemie Gmbh | Unter Abspaltung von Alkoholen zu Elastomeren vernetzbare Organopolysiloxanmassen |
| JP3419273B2 (ja) * | 1997-09-09 | 2003-06-23 | 信越化学工業株式会社 | 室温硬化性オルガノポリシロキサン組成物 |
| US6828355B1 (en) * | 1999-07-19 | 2004-12-07 | Henkel Corporation | Resin-reinforced UV, moisture and UV/moisture dual curable silicone compositions |
| JP4875251B2 (ja) | 2001-04-26 | 2012-02-15 | 東レ・ダウコーニング株式会社 | シリコーンゲル組成物 |
| US6730397B2 (en) * | 2001-12-18 | 2004-05-04 | 3M Innovative Properties Company | Silicone pressure sensitive adhesives, articles and methods |
| JP4777591B2 (ja) * | 2002-10-25 | 2011-09-21 | 信越化学工業株式会社 | 室温硬化性オルガノポリシロキサン組成物 |
| WO2005102403A1 (en) | 2004-04-08 | 2005-11-03 | Dow Corning Corporation | Silicone skin adhesive gels |
| US20050282977A1 (en) | 2004-06-17 | 2005-12-22 | Emil Stempel | Cross-linked gel and pressure sensitive adhesive blend, and skin-attachable products using the same |
| GB0606661D0 (en) | 2006-04-03 | 2006-05-10 | Brightwake Ltd | Improvements relating to dressings |
| WO2008057155A1 (en) | 2006-11-07 | 2008-05-15 | Dow Corning Corporation | Silicone skin adhesive gels |
| JP4840602B2 (ja) * | 2007-09-21 | 2011-12-21 | 信越化学工業株式会社 | 室温硬化性オルガノポリシロキサン組成物の硬化方法 |
| SE532495C2 (sv) | 2007-12-13 | 2010-02-09 | Moelnlycke Health Care Ab | Förband för att skydda huden kring föremål som skjuter ut därifrån |
| JP2011516170A (ja) | 2008-04-04 | 2011-05-26 | スリーエム イノベイティブ プロパティズ カンパニー | バルブを備える医療用手当て用品及びこれを含むキット |
| CN102203204B (zh) | 2008-10-29 | 2016-01-20 | 3M创新有限公司 | 对皮肤温和的粘合剂 |
| KR101656897B1 (ko) | 2008-10-29 | 2016-09-12 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 전자빔 경화된, 비작용화된 실리콘 감압 접착제 |
| WO2010056541A1 (en) | 2008-10-29 | 2010-05-20 | 3M Innovative Properties Company | Electron beam cured silicone materials |
| US20120029455A1 (en) | 2009-02-02 | 2012-02-02 | Bsn Medical Gmbh | Wound dressing, method for the production thereof, and use thereof for dressing wounds |
| IN2012DN00942A (enExample) | 2009-07-03 | 2015-04-03 | Dow Corning | |
| DE102009028142A1 (de) | 2009-07-31 | 2011-02-03 | Wacker Chemie Ag | Bei Raumtemperatur durch Kondensation vernetzende Siliconmassen |
| CN102548545A (zh) | 2009-08-18 | 2012-07-04 | 道康宁公司 | 多层透皮贴剂 |
| CN102596560B (zh) | 2009-11-09 | 2015-11-25 | 3M创新有限公司 | 医疗制品及使用可混溶组合物进行制备的方法 |
| JP6195518B2 (ja) | 2010-04-29 | 2017-09-13 | スリーエム イノベイティブ プロパティズ カンパニー | 電子ビームで硬化されるシリコーン処理された繊維状ウェブ |
| BR112013012785A2 (pt) | 2010-11-25 | 2020-10-20 | Bluestar Silicones France Sas | composição i - ii e produtos e usos das mesmas |
| JP5742421B2 (ja) * | 2011-04-21 | 2015-07-01 | 公立大学法人首都大学東京 | 室温硬化性オルガノポリシロキサン組成物及び気体分離膜 |
| CN102424742B (zh) * | 2011-11-21 | 2013-09-18 | 绵阳惠利电子材料有限公司 | 一种耐湿热老化的双组分缩合型室温固化硅橡胶 |
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- 2013-12-04 WO PCT/US2013/073070 patent/WO2014093093A1/en not_active Ceased
- 2013-12-04 JP JP2015547412A patent/JP6263548B2/ja not_active Expired - Fee Related
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| CN104937035A (zh) | 2015-09-23 |
| EP2931813A1 (en) | 2015-10-21 |
| CN104937035B (zh) | 2018-11-16 |
| US20150376345A1 (en) | 2015-12-31 |
| EP2931813B1 (en) | 2020-08-05 |
| WO2014093093A1 (en) | 2014-06-19 |
| JP2016501942A (ja) | 2016-01-21 |
| US10294333B2 (en) | 2019-05-21 |
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