JP5883030B2 - シリコーン接着剤物品のための低粘着力バックサイズ及び方法 - Google Patents
シリコーン接着剤物品のための低粘着力バックサイズ及び方法 Download PDFInfo
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- JP5883030B2 JP5883030B2 JP2013547451A JP2013547451A JP5883030B2 JP 5883030 B2 JP5883030 B2 JP 5883030B2 JP 2013547451 A JP2013547451 A JP 2013547451A JP 2013547451 A JP2013547451 A JP 2013547451A JP 5883030 B2 JP5883030 B2 JP 5883030B2
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Description
本出願は、2010年12月29日に出願された米国特許仮出願第61/427,932号の利益を主張し、その開示内容の全体を参照として本明細書に組み込むものである。
本開示は、低粘着力バックサイズ組成物、及びLAB組成物を含む関連するシリコーン接着剤物品に関する。
X−(Y)nSiR(3−m)Zmを有するビニル官能性シリコーンマクロモノマーであり、
式中、
Xは、A及びBモノマーと共重合可能なビニル基であり、
Yは、nが0又は1の場合、二価の結合基であり、
mは、1〜3の整数であり、
Rは、水素、低級アルキル(例えば、メチル、エチル、又はプロピル)、アリール(例えば、フェニル又は置換フェニル)、又はアルコキシであり、
Zは、約1,000を超える数平均分子量を有し、かつ共重合条件下で本質的に非反応性である一価のシロキサンのポリマー部分である。
説明及び特許請求の範囲で特定の用語が使用されており、大部分は周知であるが、いくらか説明を必要とする場合がある。本明細書で使用される場合、
モノマーに対する用語「(メタ)アクリレート」とは、アルコールとアクリルの酸又はメタクリルの酸、例えばアクリル酸又はメタクリル酸との反応生成物として形成されたビニル官能性アルキルエステルを意味することが理解されるべきである。
本開示は、結晶性(メタ)アクリレートモノマーと共重合してコポリマーを形成するシリコーンマクロマーを含む低粘着力バックサイズ(LAB)組成物を説明する。このコポリマーは、約−15℃〜約55℃のガラス転移温度と、約25℃〜約80℃の結晶性融解転移とを呈する。
シリコーンマクロマーは、1つ以上のビニル官能性シリコーンマクロモノマー、メルカプト官能性シリコーンマクロモノマー、及びこれらの組み合わせから選択される。
一部の例示的実施形態では、シリコーンマクロマーは、一般式X−(Y)nSiR(3−m)Zmを有するビニル官能性シリコーンマクロモノマーであり、式中、
Xは、A及びBモノマーと共重合可能なビニル基であり、
Yは、nが0又は1の場合、二価の結合基であり、
mは、1〜3の整数であり、
Rは、水素、低級アルキル(例えば、メチル、エチル、又はプロピル)、アリール(例えば、フェニル又は置換フェニル)、又はアルコキシであり、
Zは、約1,000を超える数平均分子量を有し、かつ共重合条件下で本質的に非反応性である一価のシロキサンポリマー部分である。
一部の例示的実施形態では、シリコーンマクロマーは、メルカプト官能性シリコーンマクロモノマーである。好適なメルカプト官能性シリコーンマクロモノマーは、その全体の開示が参照により本明細書に組み込まれる米国特許第5,032,460号に開示されている。今般好ましいメルカプト官能性シリコーンマクロモノマーは、以下の一般式のうちの1つを有する。
好適な結晶性(メタ)アクリレートモノマーとしては、例えば、室温(22℃)を超える融解転移を有するモノマー、オリゴマー又はプレポリマーが挙げられる。概して、結晶性(メタ)アクリレートモノマーとしては、長鎖アルキル末端の一級アルコールのエステル(この末端アルキル鎖は、長さが少なくとも12個〜約24個の炭素原子である)、及び(メタ)アクリル酸、好ましくはアクリル酸又はメタクリル酸が挙げられる。結晶性(メタ)アクリレートモノマーは、一般的に、(メタ)アクリル酸のC12〜C24アルキルエステルであるよう選択される。
上述のLAB組成物のいずれかの追加の例示的実施形態では、このコポリマーは、シリコーンマクロマー及び結晶性(メタ)アクリレートモノマーと共重合される少なくとも1つの極性モノマーを任意に更に含む。この極性モノマーは、アクリロニトリル、アクリル酸、メタクリル酸、(メタ)アクリル酸のC1〜C4アルキルエステル、及び/又は(メタ)アクリル酸のヒドロキシル官能性C1〜C4アルキルエステルであるよう選択され得る。
一部の今般好ましい実施形態では、シリコーンマクロマーは、フリーラジカル反応開始剤の存在下で、結晶性(メタ)アクリレートモノマーと共重合される。本開示の重合方法において有用な反応開始剤は、当業者に周知であり、20 & 21章、Macromolecules、第2巻、第2版、H.G.Elias、Plenum Press、1984年、New Yorkに詳述されている。
4−4’−アゾービス−(4−シアノペンタン酸)、2,2’−アゾビス(2,4−ジメチルペンタンニトリル)、
2,2’−アゾビス(2−メチルプロパンニトリル)、2,2’−アゾビス(2−メチルブタンニトリル)、及び
2,2’−アゾビス(シクロへキサンカルボニトリル)が挙げられるが、これらに限定されない。
上述の実施形態のいずれかにおいて、1つ以上の添加剤がLAB組成物に必要に応じて添加されてもよい。そのような任意の添加剤としては、例えば、有機溶媒、非反応性希釈剤及び/又は充填剤が挙げられる。
先に指示されたように、有機溶媒の使用は、本開示の重合方法において任意である。一部の例示的実施形態では、有機溶媒は、効果的な攪拌及び伝熱を可能にするために反応中に粘度を低下させる理由で好都合に使用され得る。有機溶媒は、フリーラジカル重合で使用される場合、約−10℃〜約50℃の温度範囲で液体であり、約2.5を超える誘電定数を有し、反応開始剤を分離してフリーラジカルを形成するために用いられるエネルギー源又は触媒に干渉せず、反応体及び生成物に対して不活性であり、そうでなければ反応に悪影響を与えない任意の物質であり得る。
非反応性希釈剤は、反応の熱の一部を吸収することによって、反応工程中の断熱温度上昇を低減するために、一部の例示的実施形態において使用され得る。非反応性希釈剤はまた、LAB(コ)ポリマー生成物の粘度を低減し、及び/又はLAB(コ)ポリマー生成物の最終特性に有利に影響を及ぼすことができる。好都合なことに、非反応性希釈剤は、LAB(コ)ポリマーにおいてその使用可能な形態で留まることができる。
有用な充填剤は、これらが、ベース(コ)ポリマーのコモノマーと共反応が可能であるフリーラジカル反応性のエチレン性不飽和基、又はモノマーの重合中にモノマー重合を著しく阻害する若しくは連鎖移動する官能基を含有しないように、非反応性であることが好ましい。例えば、充填剤は、最終LAB(コ)ポリマー処方物のコストを削減するよう使用され得る。
重合分野で周知である連鎖移動剤もまた、分子量又はその他のポリマー特性を制御するために含まれてよい。本明細書で使用するとき、用語「連鎖移動剤」は、「休止剤」も含む。本発明のプロセスにおける使用に好適な連鎖移動剤としては、四臭化炭素、ヘキサンブロモエタン、ブロモトリクロロメタン、2−メルカプトエタノール、t−ドデシルメルカプタン、イソオクチルチオグリコレート、3−メルカプト−1,2−プロパンジオール、クメン、及びこれらの混合物からなる群から選択されるものが挙げられるが、これらに限定されない。具体的な連鎖移動剤の反応性、及び所望される連鎖移動の量に応じて、モノマー(単数又は複数)の総重量に基づいて、通常は0〜約5重量%、好ましくは0〜約0.5重量%の連鎖移動剤が使用される。
LAB組成物は、結晶性(メタ)アクリレートモノマーと共重合されてコポリマーを形成するシリコーンマクロマーを含み、このコポリマーは、約−15℃〜約55℃のガラス転移温度と、約25℃〜約80℃の結晶性融解転移とを呈する。
このような方法のいくつかの例示的実施形態では、シリコーンマクロマーは、溶液重合又はバルク重合において、結晶性(メタ)アクリレートモノマーと共重合されて、コポリマーを形成する。
本開示のLAB組成物は、巻き線型ロッド、ダイレクトグラビア、オフセットグラビア、リバースロール、エアーナイフ、及びトレイリングブレードコーティングなどの従来のコーティング技術によって、好適な基材に適用され得る。LAB剥離コーティング組成物におけるLAB(コ)ポリマーの所望の濃度は、コーティングの方法及び所望の最終コーティング厚さに依存する。典型的には、剥離コーティング組成物は、約1%〜約15%の固形分でコーティングされる。
本開示のLAB組成物は、剥離ライナー又はPSA物品のLABなどの多様な様式で使用され得る。一部の例示的実施形態では、本開示のLAB組成物は、シート、繊維、又は造形品であり得る固体基材のための剥離コーティングとして広く使用され得る。したがって、別の態様では、本開示は、基材の第1の主表面に適用される上述のLAB組成物のいずれかを含む物品を説明する。例示的な物品100を図1に図示する。LAB組成物110は、基材120の第1の主表面に適用される。
織物、不織布又は編物材料が、PSA医療用テープにおける裏材として通常使用される。好適な裏材の例としては、カード、スパンボンド、スパンレース、エアーレイド、及びステッチボンド布などの不織布;エラストマーの使用から利益を得るために十分な伸張を有する織布;並びに縦糸で編まれた及び横糸で編まれた材料などのニット織物が挙げられる。
特定の今般好ましい実施形態では、物品は、感圧接着剤(PSA)物品である。感圧接着剤は、既知の多様な材料のいずれかであり得、一般的に裏材に適用される。一般的には、感圧接着剤はテープで用いられ、テープは裏材(又は基材)と感圧接着剤とを含む。感圧接着剤は、わずかな印加された指圧で接着し、永久的に粘着性であり得る。感圧接着剤は、下塗り剤、粘着付与剤、可塑剤などと一緒に使用され得る。感圧接着剤は、その通常の乾燥状態において十分に粘着性であることが好ましく、それらの目的とする用途のための接着、粘着、ストレッチネス、弾性及び強さの所望の平衡を有する。
一部の実施形態では、本開示のシリコーンゲル接着剤は、皮膚への接着に特に好適である。一般的に、本開示の接着剤は、皮膚よりも低い表面張力を有することから、この接着剤は素早く広い範囲をぬらす。ゲル接着剤はまた、弱い圧力により増強された場合に低い変形速度でも広がり、かつ強度及び持続時間の観点から所望される程度の接着を提供するような粘弾性特性を有する。
特に断らないかぎり、本実施例及び本明細書の残りの部分における部、百分率、比などは、全て重量に基づいたものである。加えて、表1は、以下の実施例において使用された全材料に関する略称及び供給元を提供する。
剥離及び再接着試験方法
剥離コーティングされた基材(不織布及びPET)を評価するために使用された試験方法は、PSAコーティングされた材料を評価するために使用される工業標準剥離接着試験の修正であった。修正された試験方法が以下に記載される。試験方法の基準源は、ASTM D3330−78 PSTC−1(1/75)である。
実施例1:SiMac/AN/MA/ODA/AA、36.3/20.75/34.75/6.64/1.56
750ミリリットルの琥珀色の広口瓶に42.0gのSiMac、24.0gのAN、40.2gのMA、12.0gのODA(酢酸エチル中64%の固形分)、1.80gのAA、180.0gの酢酸エチル及び0.60gのVAZO 67(2,2’−アゾビス(2−メチルブチロニトリル)を装填した。得られた溶液を、N2で1リットル/分(LPM)で5分間パージした。この広口瓶を密閉し、65℃の水浴中で約48時間回転させた。48時間後に、温水浴から広口瓶を取り出し、室温まで冷やした。コポリマーの固形分パーセントを測定すると、36.4%であった。得られたポリマー溶液を、酢酸エチルで5%の固形分に希釈した。ポリマーの変調DSCは、Tg=51℃及びTm=45℃を示した。
実施例1の手順が繰り返された。成分の装填は以下のようであった:42.0gのKF−2001、24.0gのAN、40.2gのMA、12.0gのODA(酢酸エチル中64%の固形分)、1.80gのAA、180gの酢酸エチル及び0.60gのVAZO 67。コポリマーの固形分パーセントを測定すると、36.9%であった。得られたポリマー溶液を、酢酸エチルで5%の固形分に希釈した。
実施例1の手順が繰り返された。成分の装填は以下のようであった:43.6gのSiMac、22.5gのAN、41.70gのMA、16.20gのODA(酢酸エチル中64%の固形分)、1.87gのAA、174.2gの酢酸エチル及び0.60gのVAZO 67。固形分パーセントを測定すると、38.6%であった。得られたポリマー溶液を、酢酸エチル中で5%の固形分まで希釈した。
実施例1の手順が繰り返された。成分の装填は以下のようであった:43.56gのSiMac、27.3gのAN、41.7gのMA、8.7gのODA(酢酸エチル中64%の固形分)、1.87gのAA、176.87gの酢酸エチル及び0.60gのVAZO 67。固形分パーセントを測定すると、38.6%であった。得られたポリマー溶液を、酢酸エチル中で5%の固形分まで希釈した。
実施例1の手順が繰り返された。成分の装填は以下のようであった:43.56gのSiMac、30.3gのAN、30.9gのMA、20.9gのODA(酢酸エチル中64%の固形分)、1.87gのAA、172.5gの酢酸エチル及び0.60gのVAZO 67。固形分パーセントを測定すると、39.1%であった。得られたポリマー溶液を、酢酸エチル中で5%の固形分まで希釈した。ポリマーの変調DSCは、Tg=56℃及びTm=50℃を示した。
実施例1の手順が繰り返された。成分の装填は以下のようであった:43.56gのSiMac、24.90gのAN、41.70gのMA、7.97gのODMA、1.87gのAA、180gの酢酸エチル及び0.60gのVAZO 67。固形分%が測定され、37.5%であった。得られたポリマー溶液を、酢酸エチル中で5%の固形分まで希釈した。
実施例1の手順が繰り返された。成分の装填は以下のようであった:43.56gのSiMac、30.30gのAN、30.90gのMA、13.37gのODMA、1.87gのAA、180gの酢酸エチル及び0.60gのVAZO 67。固形分%が測定され、37.2%であった。得られたポリマー溶液を、酢酸エチル中で5%の固形分まで希釈した。
本開示は以下も包含する。
[1]
結晶性(メタ)アクリレートモノマーと共重合されてコポリマーを形成するシリコーンマクロマーを含むLAB組成物であって、前記コポリマーが、約−15℃〜約55℃のガラス転移温度と、約25℃〜約80℃の結晶性融解転移とを呈する、LAB組成物。
[2]
前記ガラス転移温度が、少なくとも約25℃である、[1]に記載のLAB組成物。
[3]
前記結晶性融解転移が、少なくとも約50℃であり、任意に、前記ガラス転移温度が、少なくとも約50℃である、[1]又は[2]に記載のLAB組成物。
[4]
前記シリコーンマクロマーが、
一般式:
一般式:
一般式:
一般式:
又はこれらの組み合わせから選択される、[1]〜[3]のいずれか一項に記載のLAB組成物。
[5]
前記結晶性(メタ)アクリレートモノマーが、(メタ)アクリル酸のC12〜C24アルキルエステルである、[1]〜[4]のいずれか一項に記載のLAB組成物。
[6]
前記結晶性(メタ)アクリレートモノマーが、オクタデシルアクリレート、オクタデシルメタクリレート、ベヘニルアクリレート、ベヘニルメタクリレート、及びこれらの組み合わせから選択される、[5]に記載のLAB組成物。
[7]
有機溶媒を更に含み、必要に応じて、前記有機溶媒が酢酸エチルを含む、[1]〜[6]のいずれか一項に記載のLAB組成物。
[8]
前記有機溶媒が、前記組成物の約40重量%〜約80重量%の量で存在する、[7]に記載のLAB組成物。
[9]
いかなる有機溶媒も実質的に含まない、[1]〜[6]のいずれか一項に記載のLAB組成物。
[10]
前記コポリマーが、前記シリコーンマクロマー及び前記結晶性(メタ)アクリレートモノマーと共重合される少なくとも1つの極性モノマーを更に含み、前記少なくとも1つの極性モノマーが、アクリロニトリル、メチルアクリレート、アクリル酸、メタクリル酸、ヒドロキシエチルメタクリレート、ヒドロキシプロピルアクリレート、及びこれらの組み合わせから選択される、[1]〜[9]のいずれか一項に記載のLAB組成物。
[11]
前記少なくとも1つの極性モノマーが、アクリロニトリル、メチルアクリレート、及びアクリル酸の混合物を含む、[10]に記載のLAB組成物。
[12]
前記シリコーンマクロマーが、フリーラジカル反応開始剤の存在下で、結晶性(メタ)アクリレートモノマーと共重合される、[1]〜[11]のいずれか一項に記載のLAB組成物。
[13]
前記コポリマーの重量平均分子量が、少なくとも約15kDaである、[1]〜[12]のいずれか一項に記載のLAB組成物。
[14]
基材の第1の主表面に適用される[1]〜[13]のいずれか一項に記載の前記LAB組成物を含む、物品。
[15]
前記LAB組成物の反対側で前記基材の第2の主表面に適用されたシリコーン接着剤を更に含む、[14]に記載の物品。
[16]
前記基材が、高分子フィルム、紙、織布、不織布、及び不織布高分子繊維からなるウェブから選択される、[14]又は[15]に記載の物品。
[17]
前記基材が、高分子フィルムである、[16]に記載の物品。
[18]
前記基材がポリエチレンテレフタレート(PET)フィルムであり、更に、前記LAB組成物が第2のPETフィルムに接触する場合、前記物品が約6g/cm(0.059N/cm)未満の剥離力を呈し、前記LAB組成物が引き続いてガラスと接触する場合、約73g/cm(0.72N/cm)未満の再接着を呈する、[17]に記載の物品。
[19]
前記基材が紙であり、更に前記LAB組成物が紙に接触する場合、前記物品が約28g/cm(0.27N/cm)未満の剥離力を呈し、前記LAB組成物が引き続いてガラスと接触する場合、約64g/cm(0.63N/cm)未満の再接着を呈する、[16]に記載の物品。
[20]
前記物品が、ライナーレス接着テープである、[14]〜[19]のいずれか一項に記載の物品。
[21]
前記シリコーン接着剤が、放射線硬化シリコーンゲルを含み、更に前記シリコーンゲルが、架橋されたポリジオルガノシロキサン材料を含む、[14]〜[20]のいずれか一項に記載の物品。
[22]
前記シリコーン接着剤が、ポリジオルガノシロキサン材料を含む組成物を、電子ビーム放射及びガンマ放射のうちの少なくとも1つに、前記ポリジオルガノシロキサン材料を架橋するのに十分な線量で曝露することによって形成される、[21]に記載の物品。
[23]
前記ポリジオルガノシロキサン材料が、ポリジメチルシロキサンを含む、[21]又は[22]に記載の物品。
[24]
前記ポリジメチルシロキサンが、1つ以上のシラノール末端ポリジメチルシロキサン、1つ以上の非官能性ポリジメチルシロキサン、及びこれらの組み合わせからなる群から選択される、[23]に記載の物品。
[25]
前記ポリジメチルシロキサンが、1つ以上の非官能性ポリジメチルシロキサンからなる、[24]に記載の物品。
[26]
前記シリコーン接着剤が、シリケート樹脂粘着付与剤を更に含む、[21]〜[25]のいずれか一項に記載の物品。
[27]
前記シリコーン接着剤が、ポリ(ジメチルシロキサン−オキサミド)線状コポリマーを更に含む、[21]〜[26]のいずれか一項に記載の物品。
[28]
前記ポリジオルガノシロキサン材料が、25℃で1,000,000mPa・秒以下の動的粘度を有するポリジオルガノシロキサン流体を含む、[21]〜[27]のいずれか一項に記載の物品。
[29]
前記ポリジオルガノシロキサン材料が、25℃で100,000センチストーク(0.1m2/s)以下の運動粘度を有するポリジオルガノシロキサン流体からなる、[21]〜[28]のいずれか一項に記載の物品。
[30]
前記シリコーン接着剤が、皮膚剥離接着手順に従って測定されるものとして、2.54センチメートル当たり200グラム(1.96N/2.54cm)以下の、ヒト皮膚からの180度の剥離接着力を有する、[21]〜[29]のいずれか一項に記載の物品。
[31]
前記シリコーン接着剤が、20〜200マイクロメートルの厚さを有する、[21]〜[30]のいずれか一項に記載の物品。
[32]
接着剤物品を作製する方法であって、
LAB組成物が、結晶性(メタ)アクリレートモノマーと共重合されてコポリマーを形成するシリコーンマクロマーを含み、前記コポリマーが、約−15℃〜約55℃のガラス転移温度と、約25℃〜約80℃の結晶性融解転移とを呈する、[1]〜[13]のいずれか一項に記載の前記LAB組成物を、基材の第1の主表面に適用することと、
前記LAB組成物の反対側でシリコーン接着剤を前記基材の第2の主表面に適用することと、
を含む、方法。
[33]
前記シリコーンマクロマーが、溶液重合又はバルク重合において、結晶性(メタ)アクリレートモノマーと共重合されてコポリマーを形成する、[1]〜[13]のいずれか一項によるLAB組成物を作製する方法。
Claims (5)
- 結晶性(メタ)アクリレートモノマーと共重合されてコポリマーを形成するシリコーンマクロマーを含むLAB組成物であって、前記コポリマーが、−15℃〜55℃のガラス転移温度と、25℃〜80℃の結晶性融解転移とを呈する、LAB組成物。
- 前記結晶性(メタ)アクリレートモノマーが、(メタ)アクリル酸のC12〜C24アルキルエステルである、請求項1に記載のLAB組成物。
- 基材の第1の主表面に適用される請求項1に記載の前記LAB組成物を含む、物品。
- 前記LAB組成物の反対側で前記基材の第2の主表面に適用されたシリコーン接着剤を更に含む、請求項4に記載の物品。
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Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9663684B2 (en) * | 2011-07-27 | 2017-05-30 | 3M Innovative Properties Company | Hand-tearable masking tape with silicone-containing low adhesion backsize |
JP5946290B2 (ja) * | 2012-02-28 | 2016-07-06 | 日東電工株式会社 | 粘着テープ用フィルムおよび粘着テープ |
EP2850145A4 (en) * | 2012-05-18 | 2016-02-10 | 3M Innovative Properties Co | ADHESIVE PRODUCTS FOR MEDICAL APPLICATIONS |
US9550921B2 (en) * | 2012-08-13 | 2017-01-24 | 3M Innovative Properties Company | Masking tape with multi-directional hand tear |
JP5942725B2 (ja) * | 2012-09-18 | 2016-06-29 | デクセリアルズ株式会社 | 導電性シート |
WO2014073840A1 (ko) * | 2012-11-06 | 2014-05-15 | 주식회사 엘지화학 | 아크릴-실리콘계 하이브리드 에멀젼 점착제 조성물 및 이의 제조방법 |
EP2745851B1 (en) * | 2012-12-21 | 2017-04-12 | Mölnlycke Health Care AB | Method for attachment of medical devices to surfaces |
KR20160132903A (ko) * | 2014-03-10 | 2016-11-21 | 쓰리엠 이노베이티브 프로퍼티즈 캄파니 | 티올-치환된 실리콘을 포함하는 복합 나노입자 |
US9962461B2 (en) * | 2014-03-10 | 2018-05-08 | 3M Innovative Properties Company | Conformable coating composition |
WO2015141551A1 (ja) * | 2014-03-19 | 2015-09-24 | リンテック株式会社 | 剥離剤組成物、剥離フィルム、剥離フィルムの巻取体および当該巻取体の製造方法 |
EP3234052B1 (en) * | 2014-12-19 | 2020-09-16 | 3M Innovative Properties Company | Adhesive article comprising a poly(meth)acrylate-based primer layer and methods of making same |
CN107109145A (zh) * | 2014-12-23 | 2017-08-29 | 3M创新有限公司 | 双面多层粘合剂 |
JP6529318B2 (ja) * | 2015-04-13 | 2019-06-12 | 日華化学株式会社 | 非フッ素系ポリマー、撥水剤組成物、撥水性繊維製品及び撥水性繊維製品の製造方法 |
CA2983029C (en) * | 2015-04-29 | 2023-04-04 | Adrian J. Hulme | Non-silicone additives in release coating materials |
KR102314734B1 (ko) * | 2015-06-12 | 2021-10-20 | 삼성디스플레이 주식회사 | 점착제 조성물 및 표시장치 |
CN107922739A (zh) * | 2015-08-31 | 2018-04-17 | 毕克化学有限公司 | 包含聚硅氧烷大分子单体单元的共聚物,其制备方法及其在涂料组合物和聚合模塑化合物中的用途 |
CN108699388B (zh) * | 2016-03-07 | 2020-09-25 | 美国陶氏有机硅公司 | 可光固化的有机硅组合物及其固化产物 |
CN109415590B (zh) * | 2016-06-29 | 2020-03-27 | 3M创新有限公司 | 化合物、粘合剂制品及其制备方法 |
US11285702B2 (en) | 2016-07-22 | 2022-03-29 | 3M Innovative Properties Company | Siloxane-based adhesive layers as ceramic precursors |
US11078385B2 (en) * | 2017-04-13 | 2021-08-03 | Shin-Etsu Chemical Co., Ltd. | Removable radiation-curable silicone composition and release sheet |
KR102542235B1 (ko) * | 2017-06-06 | 2023-06-12 | 신에쓰 가가꾸 고교 가부시끼가이샤 | 자외선 경화형 실리콘 점착제 조성물 및 그 경화물 |
US20210163802A1 (en) * | 2017-12-14 | 2021-06-03 | 3M Innovative Properties Company | Siloxane-based dual-cure transparent transfer film |
WO2019193514A1 (en) * | 2018-04-05 | 2019-10-10 | 3M Innovative Properties Company | Gel adhesive comprising crosslinked blend of polydiorganosiloxane and acrylic polymer |
US20210095172A1 (en) * | 2018-04-05 | 2021-04-01 | 3M Innovative Properties Company | Siloxane-Based Gel Adhesives |
WO2019224769A1 (en) * | 2018-05-25 | 2019-11-28 | 3M Innovative Properties Company | Phase separated articles |
CN110628351A (zh) * | 2018-06-25 | 2019-12-31 | 上海海优威新材料股份有限公司 | 用于处于加工状态的工件的防护的保护膜及其应用 |
CN110628350A (zh) * | 2018-06-25 | 2019-12-31 | 上海海优威新材料股份有限公司 | 用于保护处于加工状态的工件的保护膜及其应用 |
WO2020054335A1 (ja) * | 2018-09-11 | 2020-03-19 | 信越化学工業株式会社 | シリコーン樹脂とポリオレフィン系樹脂との接着用プライマー組成物、及びシリコーン樹脂とポリオレフィン系樹脂との接着方法 |
CN109321153A (zh) * | 2018-09-19 | 2019-02-12 | 广东星宇耐力新材料股份有限公司 | 一种超低粘保护膜用水性压敏胶、超低粘保护膜及其制备方法 |
WO2020188438A1 (en) | 2019-03-15 | 2020-09-24 | 3M Innovative Properties Company | Tie layer chemistry to promote bonding with silicone adhesive |
EP3976723A1 (en) | 2019-06-03 | 2022-04-06 | 3M Innovative Properties Company | Release coating compositions for pressure sensitive adhesive articles and methods |
WO2022043786A1 (en) | 2020-08-24 | 2022-03-03 | 3M Innovative Properties Company | Release coating compositions for pressure sensitive adhesive articles and methods |
CN112322253B (zh) * | 2020-11-11 | 2022-09-16 | 南京清尚新材料科技有限公司 | 低表面粘性的压敏胶黏剂及其和功能胶带的制备方法 |
CN112940261B (zh) * | 2021-02-01 | 2022-10-11 | 浙江新安化工集团股份有限公司 | 一种增粘剂及其合成方法和应用 |
CN113402681A (zh) * | 2021-06-24 | 2021-09-17 | 中科院广州化学有限公司 | 一种含巯基有机硅改性苯丙乳液及其制备方法与应用 |
TW202406994A (zh) * | 2022-08-08 | 2024-02-16 | 美商陶氏全球科技公司 | 聚矽氧烷填料處理劑及由其製備之組成物 |
Family Cites Families (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4728571A (en) * | 1985-07-19 | 1988-03-01 | Minnesota Mining And Manufacturing Company | Polysiloxane-grafted copolymer release coating sheets and adhesive tapes |
US5202190A (en) * | 1989-08-14 | 1993-04-13 | Minnesota Mining And Manufacturing Company | Method of making vinyl-silicone copolymers using mercapto functional silicone chain-transfer agents and release coatings made therewith |
US5308887A (en) * | 1991-05-23 | 1994-05-03 | Minnesota Mining & Manufacturing Company | Pressure-sensitive adhesives |
CA2115329A1 (en) * | 1993-03-31 | 1994-10-01 | Joseph Thomas Bartusiak | Electrophotographic toner receptive release coatings |
US5635331A (en) * | 1994-10-13 | 1997-06-03 | Minnesota Mining And Manufacturing Company | Substrate and a color proofing article having release agent/adhesive mixture coated thereon |
US5874144A (en) * | 1996-10-23 | 1999-02-23 | Minnesota Mining And Manufacturing Company | Silicon-free copolymer and bleed-through resistant, ink receptive, and adhesive receptive coatings and coated substrates prepared therefrom |
US6337086B1 (en) * | 1999-02-06 | 2002-01-08 | Dow Corning Corporation | Pressure sensitive adhesive compositions for transdermal drug delivery devices |
US6699351B2 (en) | 2000-03-24 | 2004-03-02 | 3M Innovative Properties Company | Anisotropically conductive adhesive composition and anisotropically conductive adhesive film formed from it |
US6486267B1 (en) * | 2000-08-03 | 2002-11-26 | Avery Dennison Corporation | Release composition |
US7524545B2 (en) * | 2002-05-16 | 2009-04-28 | 3M Innovative Properties Company | Release coating containing thermoplastic silicone-containing polymer |
US6919405B2 (en) * | 2002-12-31 | 2005-07-19 | 3M Innovative Properties Company | Release compositions and articles made therefrom |
US20090000727A1 (en) * | 2007-06-29 | 2009-01-01 | Kanta Kumar | Hardcoat layers on release liners |
EP2235079B1 (en) * | 2007-12-28 | 2012-08-01 | 3M Innovative Properties Company | Copolymers of nanoparticles, vinyl monomers and silicone |
US8822559B2 (en) * | 2008-10-29 | 2014-09-02 | 3D Innovative Properties Company | Electron beam cured silicone release materials |
US20110300296A1 (en) * | 2008-12-17 | 2011-12-08 | Sherman Audrey A | Bulk polymerization of silicone-containing copolymers |
US9493643B2 (en) * | 2011-05-06 | 2016-11-15 | Board Of Supervisors Of Louisiana State University And Agricultural And Mechanical College | Thermosetting shape memory polymers with ability to perform repeated molecular scale healing |
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CN103261356B (zh) | 2016-01-13 |
EP2658941A1 (en) | 2013-11-06 |
CN103261356A (zh) | 2013-08-21 |
BR112013014112A2 (pt) | 2016-09-20 |
US20140287642A1 (en) | 2014-09-25 |
TW201233752A (en) | 2012-08-16 |
EP2658941A4 (en) | 2014-09-17 |
WO2012091742A1 (en) | 2012-07-05 |
KR20130131420A (ko) | 2013-12-03 |
TWI588230B (zh) | 2017-06-21 |
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