JP6244078B2 - 生分解性ポリエステルの製造方法 - Google Patents
生分解性ポリエステルの製造方法 Download PDFInfo
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- JP6244078B2 JP6244078B2 JP2011501233A JP2011501233A JP6244078B2 JP 6244078 B2 JP6244078 B2 JP 6244078B2 JP 2011501233 A JP2011501233 A JP 2011501233A JP 2011501233 A JP2011501233 A JP 2011501233A JP 6244078 B2 JP6244078 B2 JP 6244078B2
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- acid
- aliphatic
- polyester
- polyesters
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/91—Polymers modified by chemical after-treatment
- C08G63/914—Polymers modified by chemical after-treatment derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/916—Dicarboxylic acids and dihydroxy compounds
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B32B23/00—Layered products comprising a layer of cellulosic plastic substances, i.e. substances obtained by chemical modification of cellulose, e.g. cellulose ethers, cellulose esters, viscose
- B32B23/04—Layered products comprising a layer of cellulosic plastic substances, i.e. substances obtained by chemical modification of cellulose, e.g. cellulose ethers, cellulose esters, viscose comprising such cellulosic plastic substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B23/08—Layered products comprising a layer of cellulosic plastic substances, i.e. substances obtained by chemical modification of cellulose, e.g. cellulose ethers, cellulose esters, viscose comprising such cellulosic plastic substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
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- B32B23/00—Layered products comprising a layer of cellulosic plastic substances, i.e. substances obtained by chemical modification of cellulose, e.g. cellulose ethers, cellulose esters, viscose
- B32B23/20—Layered products comprising a layer of cellulosic plastic substances, i.e. substances obtained by chemical modification of cellulose, e.g. cellulose ethers, cellulose esters, viscose comprising esters
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- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
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- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
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- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
- B32B27/20—Layered products comprising a layer of synthetic resin characterised by the use of special additives using fillers, pigments, thixotroping agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
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- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B32B29/00—Layered products comprising a layer of paper or cardboard
- B32B29/002—Layered products comprising a layer of paper or cardboard as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B29/005—Layered products comprising a layer of paper or cardboard as the main or only constituent of a layer, which is next to another layer of the same or of a different material next to another layer of paper or cardboard layer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/16—Dicarboxylic acids and dihydroxy compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
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- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2270/00—Resin or rubber layer containing a blend of at least two different polymers
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/31—Heat sealable
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B32B2307/412—Transparent
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- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/51—Elastic
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/54—Yield strength; Tensile strength
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B32B2307/70—Other properties
- B32B2307/716—Degradable
- B32B2307/7163—Biodegradable
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/724—Permeability to gases, adsorption
- B32B2307/7242—Non-permeable
- B32B2307/7244—Oxygen barrier
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/724—Permeability to gases, adsorption
- B32B2307/7242—Non-permeable
- B32B2307/7246—Water vapor barrier
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2439/00—Containers; Receptacles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2439/00—Containers; Receptacles
- B32B2439/70—Food packaging
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31786—Of polyester [e.g., alkyd, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31786—Of polyester [e.g., alkyd, etc.]
- Y10T428/3179—Next to cellulosic
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Polyesters Or Polycarbonates (AREA)
- Laminated Bodies (AREA)
- Biological Depolymerization Polymers (AREA)
- Wrappers (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
- Materials For Medical Uses (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ITMI2008A000507 | 2008-03-26 | ||
| IT000507A ITMI20080507A1 (it) | 2008-03-26 | 2008-03-26 | Poliestere biodegradabile, suo processo di preparazione e prodotti comprendenti detto poliestere. |
| PCT/EP2009/053586 WO2009118377A1 (en) | 2008-03-26 | 2009-03-26 | Biodegradable polyester, preparation process thereof and products comprising said polyester |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2011518235A JP2011518235A (ja) | 2011-06-23 |
| JP2011518235A5 JP2011518235A5 (https=) | 2017-10-12 |
| JP6244078B2 true JP6244078B2 (ja) | 2017-12-06 |
Family
ID=40292962
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2011501233A Active JP6244078B2 (ja) | 2008-03-26 | 2009-03-26 | 生分解性ポリエステルの製造方法 |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US8541109B2 (https=) |
| EP (1) | EP2268698B1 (https=) |
| JP (1) | JP6244078B2 (https=) |
| KR (1) | KR101600112B1 (https=) |
| CN (2) | CN104448281B (https=) |
| AU (1) | AU2009228938B2 (https=) |
| BR (1) | BRPI0906336B1 (https=) |
| CA (1) | CA2718212C (https=) |
| IT (1) | ITMI20080507A1 (https=) |
| RU (1) | RU2499007C2 (https=) |
| WO (1) | WO2009118377A1 (https=) |
Families Citing this family (54)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1399032B1 (it) * | 2009-11-06 | 2013-04-05 | Novamont Spa | Poliestere biodegradabile alifatico-aromatico |
| IT1402747B1 (it) * | 2010-10-27 | 2013-09-18 | Novamont Spa | Poliestere biodegradabile e pellicole aderenti per l'imballaggio con esso realizzate |
| IT1403611B1 (it) * | 2010-12-22 | 2013-10-31 | Novamont Spa | Composizione di poliesteri |
| JP2012229395A (ja) * | 2011-04-11 | 2012-11-22 | Canon Inc | プラスチックフィルム |
| EP2697321B1 (en) * | 2011-04-14 | 2015-07-15 | Universiteit van Amsterdam | Laminate comprising carrier and coating layer |
| CN103492280B (zh) * | 2011-04-20 | 2015-09-16 | 巴斯夫欧洲公司 | 纤维素防护包装材料 |
| KR101116668B1 (ko) * | 2011-05-16 | 2012-03-07 | (주)케이티에스 | 지방족 폴리에스테르 코팅지 및 그 제조방법 |
| EP2758465B1 (en) | 2011-09-19 | 2018-01-24 | Novamont S.p.A. | Stable aqueous dispersions comprising complexed starch |
| EP2572875A1 (de) * | 2011-09-26 | 2013-03-27 | Tscheulin-Rothal GmbH | Biologisch abbaubare Verpackungsmaterialien |
| US20130095269A1 (en) | 2011-10-14 | 2013-04-18 | Eastman Chemical Company | Polyester compositions containing furandicarboxylic acid or an ester thereof and ethylene glycol |
| FR2985260B1 (fr) | 2011-12-29 | 2014-06-27 | Natura Cosmeticos Sa | Procede pour la production de poly(2,5-furanedicarboxylate d'ethylene) a partir d'acide 2,5-furanedicarboxylique et son utilisation, compose polyester et melanges de celui-ci. |
| US8658810B2 (en) | 2012-06-22 | 2014-02-25 | Eastman Chemical Company | Method for producing purified dialkyl-furan-2,5-dicarboxylate vapor |
| US8859788B2 (en) | 2012-06-22 | 2014-10-14 | Eastman Chemical Company | Esterification of furan-2,5-dicarboxylic acid to a dialkyl-furan-2,5-dicarboxylate vapor with rectification |
| US8912349B2 (en) | 2012-06-22 | 2014-12-16 | Eastman Chemical Company | Method for producing purified dialkyl-furan-2,5-dicarboxylate separation and solid liquid separation |
| CN102786782B (zh) * | 2012-07-03 | 2014-03-12 | 广州碧嘉材料科技有限公司 | 一种生物降解材料及其制备方法和应用 |
| KR20140031011A (ko) * | 2012-09-04 | 2014-03-12 | 삼성정밀화학 주식회사 | 생분해성 지방족 폴리에스테르의 연속 제조방법 |
| BR112016025235B1 (pt) * | 2014-04-30 | 2021-07-27 | Stichting Wageningen Research | Copoliéster, método de produção de um copoliéster e utilização de um recipiente construído com o copoliéster |
| KR20160023973A (ko) * | 2014-08-21 | 2016-03-04 | 삼성정밀화학 주식회사 | 투명 생분해성 고분자 |
| HUP1400467A2 (en) * | 2014-10-03 | 2016-04-28 | Jozsef Sandor Borbely | Process for producing biodegradable packing material |
| ITUB20152688A1 (it) * | 2015-07-31 | 2017-01-31 | Novamont Spa | Composizione polimerica per la realizzazione di articoli stampati biodegradabili in compostaggio industriale. |
| EP3345953B1 (en) * | 2015-09-04 | 2024-11-20 | Mitsubishi Chemical Corporation | Polyester resin, production method for said polyester resin, and polyester resin composition |
| DE102016201498B4 (de) * | 2016-02-01 | 2017-08-17 | Norbert Kuhl | Sauerstoffdichter lebensmittelbehälter |
| CN107304285B (zh) * | 2016-04-21 | 2022-06-21 | 上海浦景化工技术股份有限公司 | 一种聚酯改性材料及其膜制品的制备方法 |
| ES2841823T3 (es) * | 2016-10-26 | 2021-07-09 | Danimer Bioplastics Inc | Composición de cera de marcaje renovable y biodegradable |
| CN107459783B (zh) | 2016-12-12 | 2018-07-27 | 金发科技股份有限公司 | 一种聚对苯二甲酸酯-共-癸二酸酯树脂组合物 |
| WO2018206352A1 (de) * | 2017-05-10 | 2018-11-15 | Basf Se | Biologisch abbaubare folie für lebensmittelverpackung |
| ES2895041T3 (es) * | 2017-06-19 | 2022-02-17 | Basf Se | Película de tres capas biodegradable |
| US20190023675A1 (en) | 2017-07-20 | 2019-01-24 | Eastman Chemical Company | Method for producing purified dialkyl-furan-2,5-dicarboxylate |
| JP7157069B2 (ja) | 2017-10-04 | 2022-10-19 | 日本製紙株式会社 | バリア素材 |
| US11260337B2 (en) * | 2018-03-29 | 2022-03-01 | Uop Llc | Process for the removal of carbon dioxide and heavy hydrocarbons |
| CN109467723A (zh) * | 2018-09-30 | 2019-03-15 | 江苏宏远新材料科技有限公司 | 一种水蒸气阻隔型抗菌环保聚酯薄膜的制备方法 |
| AU2020211687B2 (en) * | 2019-01-21 | 2026-02-05 | Plantics B.V. | Biodegradable container and plate material and method for the manufacture thereof |
| JP7271964B2 (ja) * | 2019-01-23 | 2023-05-12 | 東ソー株式会社 | 樹脂組成物およびその樹脂組成物を用いた積層体 |
| KR101992393B1 (ko) * | 2019-04-03 | 2019-06-24 | (주)새한폴리머 | 생분해성 지방족 폴리에스테르의 연속 제조방법 |
| KR102942424B1 (ko) * | 2019-04-11 | 2026-03-23 | 바스프 에스이 | 폴리부틸렌 테레프탈레이트 열성형 방법 |
| WO2021151892A1 (en) | 2020-01-27 | 2021-08-05 | Dsm Ip Assets B.V. | Layered material |
| IT202000012184A1 (it) * | 2020-05-25 | 2021-11-25 | Novamont Spa | Poliestere biodegradabile e pellicole aderenti per l’imballaggio con esso realizzate |
| CN114055877A (zh) * | 2020-07-29 | 2022-02-18 | 上海紫丹食品包装印刷有限公司 | 耐热、低水蒸气透过率且可生物降解的纸塑复合材料及其制备方法和应用 |
| CN112266473B (zh) * | 2020-10-09 | 2022-03-25 | 南方医科大学 | 一种光固化生物可降解弹性聚酯的制备方法 |
| KR102316790B1 (ko) * | 2020-12-11 | 2021-10-22 | 바이오플라스틱스 이노베이션스 리미티드 | 바이오매스로부터 유도된 반응속도조절제 및 분자량증가제를 첨가하여 제조된 생분해성 폴리에스터수지 및 그 제조방법 |
| IT202000032663A1 (it) * | 2020-12-29 | 2022-06-29 | Novamont Spa | Film biodegradabile multistrato ad alta disintegrazione |
| IT202100002135A1 (it) | 2021-02-02 | 2022-08-02 | Novamont Spa | Poliesteri ramificati per extrusion coating |
| CN113683763B (zh) * | 2021-10-26 | 2022-09-13 | 江苏金发科技新材料有限公司 | 一种半芳香族聚酯及其制备方法和应用 |
| CN113897043B (zh) * | 2021-11-24 | 2023-02-28 | 江苏科技大学 | 一种pla/pbat基弹性体共混物的制备方法 |
| EP4502008A4 (en) * | 2022-03-28 | 2025-07-09 | Mitsubishi Chem Corp | MODIFIED POLYESTER-BASED RESIN, ADHESIVE RESIN COMPOSITION AND LAMINATE |
| WO2024092296A1 (en) | 2022-10-27 | 2024-05-02 | Council For Scientific And Industrial Research | Multi-layered biodegradable polymer nanocomposite-based film |
| CN117304456B (zh) * | 2023-08-18 | 2025-11-21 | 美瑞新材料创新中心(山东)有限公司 | 低迁移pbs产品及其制备方法和系统 |
| IT202300024147A1 (it) * | 2023-11-14 | 2025-05-14 | Novamont Spa | Poliesteri per espansione in autoclave |
| SE2330603A1 (en) * | 2023-12-21 | 2025-06-22 | Stora Enso Oyj | Polymer coated paper and paperboard |
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| SE2330595A1 (en) * | 2023-12-21 | 2025-06-22 | Stora Enso Oyj | Polymer coated paper or paperboard |
| SE2330599A1 (en) * | 2023-12-21 | 2025-06-22 | Stora Enso Oyj | Corrugated board comprising a polymer coated liner |
| WO2025210220A1 (en) | 2024-04-04 | 2025-10-09 | Novamont S.P.A. | Aqueous dispersion comprising destructured starch |
| NL2037960B1 (en) | 2024-06-17 | 2026-01-12 | Wp Trading Alphen Aan Den Rijn B V | Biodegradable packaging material and polyester (pre)polymers for the making thereof |
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| JPS5565224A (en) * | 1978-11-10 | 1980-05-16 | Toagosei Chem Ind Co Ltd | Production of polyester di(meth)acrylate |
| JP2721945B2 (ja) * | 1992-05-13 | 1998-03-04 | 昭和高分子株式会社 | ラミネート |
| ID23491A (id) * | 1994-01-28 | 1995-09-07 | Procter & Gamble | Kopolimer-kopolimer yang dapat dibiodegradasi dan baha-bahan plastik yang terdiri dari kopolimer-kopolimer yang dapat dibiodegradasi |
| EP0747416B1 (en) * | 1994-12-21 | 2004-11-10 | Showa Denko Kabushiki Kaisha | Aliphatic polyester resin and process for producing the same |
| US5661193A (en) * | 1996-05-10 | 1997-08-26 | Eastman Chemical Company | Biodegradable foamable co-polyester compositions |
| ATE219782T1 (de) * | 1997-09-18 | 2002-07-15 | Monsanto Co | Modifizierte polyhydroxyalkanoate zur herstellung von überzügen und filmen |
| JP2003221423A (ja) | 2002-02-01 | 2003-08-05 | Aeba Toshiyuki | 複合樹脂組成物とその製造方法 |
| ITMI20020865A1 (it) * | 2002-04-22 | 2003-10-22 | Novamont Spa | Poliesteri biodegradabili ottenuti mediante estrusione reattiva |
| WO2004101666A2 (en) * | 2003-05-19 | 2004-11-25 | Polymers Australia Pty. Limited | Polyester masterbatch composition |
| JP2005036179A (ja) * | 2003-06-25 | 2005-02-10 | Mitsubishi Chemicals Corp | 脂肪族ポリエステル系樹脂組成物 |
| EP1721935B1 (en) | 2004-03-04 | 2010-09-08 | Unitika Ltd. | Biodegradable polyester resin composition, process for producing the same, and foam and molding obtained therefrom |
| TW200613134A (en) * | 2004-09-09 | 2006-05-01 | Int Paper Co | Biodegradable paper-based cup or package and production method |
| ITMI20050452A1 (it) | 2005-03-18 | 2006-09-19 | Novamont Spa | Poliestere biodegradabile alifatico-aromatico |
| US20070203261A1 (en) * | 2006-02-24 | 2007-08-30 | Board Of Trustees Of Michigan State University | Reactively blended polyester and filler composite compositions and process |
| JP5045035B2 (ja) * | 2006-09-01 | 2012-10-10 | 東洋製罐株式会社 | 脂肪族ポリエステル樹脂組成物及びその製造方法 |
| IT1395925B1 (it) * | 2009-09-25 | 2012-11-02 | Novamont Spa | Poliestere biodegradabile. |
| US8476652B2 (en) * | 2010-07-30 | 2013-07-02 | Invenlux Corporation | Three-dimensional light-emitting devices and method for fabricating the same |
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2008
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2009
- 2009-03-26 WO PCT/EP2009/053586 patent/WO2009118377A1/en not_active Ceased
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- 2009-03-26 US US12/934,011 patent/US8541109B2/en active Active
- 2009-03-26 JP JP2011501233A patent/JP6244078B2/ja active Active
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- 2009-03-26 CA CA2718212A patent/CA2718212C/en active Active
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|---|---|
| KR101600112B1 (ko) | 2016-03-04 |
| CA2718212C (en) | 2016-11-29 |
| US8541109B2 (en) | 2013-09-24 |
| ITMI20080507A1 (it) | 2009-09-27 |
| KR20110008054A (ko) | 2011-01-25 |
| RU2010142992A (ru) | 2012-05-10 |
| BRPI0906336A2 (pt) | 2016-07-26 |
| EP2268698A1 (en) | 2011-01-05 |
| AU2009228938A1 (en) | 2009-10-01 |
| CN101981081A (zh) | 2011-02-23 |
| AU2009228938B2 (en) | 2014-06-26 |
| JP2011518235A (ja) | 2011-06-23 |
| AU2009228938A2 (en) | 2011-03-31 |
| CN104448281A (zh) | 2015-03-25 |
| EP2268698B1 (en) | 2019-04-24 |
| RU2499007C2 (ru) | 2013-11-20 |
| WO2009118377A1 (en) | 2009-10-01 |
| CA2718212A1 (en) | 2009-10-01 |
| CN104448281B (zh) | 2018-03-27 |
| US20110020660A1 (en) | 2011-01-27 |
| BRPI0906336B1 (pt) | 2019-09-03 |
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