JP6228139B2 - TiおよびZnを含有するゼオライト材料を含有する微小粉末および成形物 - Google Patents

TiおよびZnを含有するゼオライト材料を含有する微小粉末および成形物 Download PDF

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JP6228139B2
JP6228139B2 JP2014556023A JP2014556023A JP6228139B2 JP 6228139 B2 JP6228139 B2 JP 6228139B2 JP 2014556023 A JP2014556023 A JP 2014556023A JP 2014556023 A JP2014556023 A JP 2014556023A JP 6228139 B2 JP6228139 B2 JP 6228139B2
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JP2015512845A5 (enExample
JP2015512845A (ja
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パルフレスク,アンドレイ−ニコラエ
ミュラー,ウルリヒ
ヘンリケ テレス,ヨアキム
ヘンリケ テレス,ヨアキム
ゼーリヒ,ビアンカ
カムペ,フィリップ
ヴェーバー,マルクス
バイアー,ロベルト
ザイデル,カルシュテン
レッシュ,ペーター
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    • B01J29/7049—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
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  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • General Life Sciences & Earth Sciences (AREA)
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  • Catalysts (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
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JP2014556023A 2012-02-07 2013-02-05 TiおよびZnを含有するゼオライト材料を含有する微小粉末および成形物 Active JP6228139B2 (ja)

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EP12154168.4 2012-02-07
EP12154168 2012-02-07
PCT/EP2013/052223 WO2013117536A2 (en) 2012-02-07 2013-02-05 Micropowder and molding containing a zeolitic material containing ti and zn

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JP2017197545A Active JP6570596B2 (ja) 2012-02-07 2017-10-11 TiおよびZnを含有するゼオライト材料を含有する微小粉末および成形物

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KR (1) KR102106405B1 (enExample)
CN (2) CN104271241B (enExample)
BR (2) BR122019019074B1 (enExample)
ES (2) ES2637839T3 (enExample)
HU (1) HUE068544T2 (enExample)
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MY (2) MY180180A (enExample)
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Cited By (1)

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JP2018048076A (ja) * 2012-02-07 2018-03-29 ビーエーエスエフ ソシエタス・ヨーロピアBasf Se TiおよびZnを含有するゼオライト材料を含有する微小粉末および成形物

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CN110002463B (zh) * 2013-02-05 2022-10-11 巴斯夫欧洲公司 制备具有mww骨架结构的含钛沸石材料的方法
CN105848781B (zh) 2013-10-23 2020-07-17 巴斯夫欧洲公司 疏水性沸石材料的模制品及其制备方法
DE102014008080A1 (de) 2014-05-30 2015-11-12 Basf Se Verfahren zur Herstellung von Acrylsäure unter Verwendung eines aluminiumfreien zeolithischen Materials
CN119456024A (zh) 2015-02-13 2025-02-18 巴斯夫欧洲公司 用于丙烯环氧化的钛沸石催化剂的再生方法
EP3322685A1 (en) 2015-07-15 2018-05-23 Basf Se Process for preparing an arylpropene
CN107848930A (zh) 2015-07-15 2018-03-27 巴斯夫欧洲公司 制备芳基丙烯的方法
RU2756603C2 (ru) * 2016-07-13 2021-10-04 Басф Се Способ получения этиленоксида
BR112019010134B1 (pt) 2016-12-13 2022-11-29 Basf Se Processo para preparar um material zeolítico, material zeolítico, e, uso do material
MY199977A (en) 2016-12-20 2023-12-01 Basf Se Use of an acid treatment to decrease the plasticity of a composition comprising a titanium-containing zeolitic material having framework type mww
EP3558516A1 (en) 2016-12-20 2019-10-30 Basf Se A process for preparing an extrudable composition comprising a titanium-containing zeolitic material having framework type mww
US10780432B2 (en) * 2017-01-18 2020-09-22 Basf Se Process for preparing a molding comprising zinc and a titanium-containing zeolite
US20220219154A1 (en) * 2019-04-29 2022-07-14 Basf Se Molding comprising a type mfi zeolitic titanosilicate and a silica binder, its preparation process and use as catalyst
WO2021123214A1 (en) 2019-12-20 2021-06-24 Basf Se A molding comprising a ti-mww zeolite and having a specific lewis acidity
BR112022018861A2 (pt) * 2020-03-23 2022-11-22 Basf Se Material zeolítico, composto contendo ti, uso de um composto contendo ti, processos para preparar um material zeolítico e para oxidar um composto orgânico, moldagem, uso de uma moldagem, e, óxido de propileno
JP7790704B2 (ja) * 2021-12-20 2025-12-23 国立研究開発法人物質・材料研究機構 ゼオライトバルク体およびその製造方法

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1298126B1 (it) * 1998-01-15 1999-12-20 Enichem Spa Procedimento per la preparazione di epossidi olefinici
US6114552A (en) 1999-09-28 2000-09-05 Arco Chemical Technology, L.P. Heterogeneous epoxidation catalyst
US6114551A (en) 1999-10-04 2000-09-05 Mobil Oil Corporation Olefin epoxidation catalysts
JP2002102709A (ja) 2000-09-29 2002-04-09 Showa Denko Kk 酸化化合物製造用結晶性mww型チタノシリケート触媒、該触媒の製造方法、及び該触媒を用いた酸化化合物の製造方法
DE10317519A1 (de) * 2003-04-16 2004-11-04 Basf Ag Verfahren zur Herstellung von Propylenoxid
DE10320635A1 (de) * 2003-05-08 2004-11-18 Basf Ag Verfahren zur Herstellung von Propylenoxid
US7182932B2 (en) * 2004-01-30 2007-02-27 Lyondell Chemical Technology, L.P. Catalyst preparation
US7273826B2 (en) 2005-07-26 2007-09-25 Lyondell Chemical Technology, L.P. Epoxidation catalyst
RU2388755C2 (ru) * 2005-12-27 2010-05-10 Басф Се Способ эпоксидирования пропена
JP2008200553A (ja) * 2007-02-16 2008-09-04 Sumitomo Chemical Co Ltd チタノシリケート触媒
JP2010173996A (ja) * 2009-02-02 2010-08-12 Sumitomo Chemical Co Ltd プロピレンオキサイドの製造方法
ES2596223T3 (es) * 2009-11-27 2017-01-05 Basf Se Proceso para la preparación de un catalizador de zeolita de titanio
EP3216520B1 (en) * 2012-02-07 2024-07-17 Basf Se Molding containing a zeolitic mww type material containing ti and zn and use thereof as a catalyst

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2018048076A (ja) * 2012-02-07 2018-03-29 ビーエーエスエフ ソシエタス・ヨーロピアBasf Se TiおよびZnを含有するゼオライト材料を含有する微小粉末および成形物

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