JP6153072B2 - 液式鉛蓄電池 - Google Patents
液式鉛蓄電池 Download PDFInfo
- Publication number
- JP6153072B2 JP6153072B2 JP2013161724A JP2013161724A JP6153072B2 JP 6153072 B2 JP6153072 B2 JP 6153072B2 JP 2013161724 A JP2013161724 A JP 2013161724A JP 2013161724 A JP2013161724 A JP 2013161724A JP 6153072 B2 JP6153072 B2 JP 6153072B2
- Authority
- JP
- Japan
- Prior art keywords
- mass
- negative electrode
- acid
- lead
- current collector
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000002253 acid Substances 0.000 title claims description 42
- 239000007788 liquid Substances 0.000 title claims description 27
- 239000007773 negative electrode material Substances 0.000 claims description 37
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 27
- 239000006229 carbon black Substances 0.000 claims description 26
- 229930185605 Bisphenol Natural products 0.000 claims description 23
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 23
- 150000003839 salts Chemical class 0.000 claims description 21
- 229910052799 carbon Inorganic materials 0.000 claims description 20
- 235000010443 alginic acid Nutrition 0.000 claims description 19
- 239000000783 alginic acid Substances 0.000 claims description 19
- 229960001126 alginic acid Drugs 0.000 claims description 19
- 229920000615 alginic acid Polymers 0.000 claims description 19
- 150000004781 alginic acids Chemical class 0.000 claims description 18
- -1 alkali metal salt Chemical class 0.000 claims description 16
- 238000004080 punching Methods 0.000 claims description 16
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 14
- 239000003792 electrolyte Substances 0.000 claims description 14
- 229920002125 Sokalan® Polymers 0.000 claims description 12
- 239000008151 electrolyte solution Substances 0.000 claims description 12
- 239000004584 polyacrylic acid Substances 0.000 claims description 12
- 229910052783 alkali metal Inorganic materials 0.000 claims description 8
- 229920002845 Poly(methacrylic acid) Polymers 0.000 claims description 7
- 239000000126 substance Substances 0.000 claims description 7
- 238000006243 chemical reaction Methods 0.000 claims description 6
- 108010020346 Polyglutamic Acid Proteins 0.000 claims description 3
- 229920002643 polyglutamic acid Polymers 0.000 claims description 3
- 238000003860 storage Methods 0.000 description 12
- 238000007600 charging Methods 0.000 description 11
- VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical compound C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 description 6
- 210000000988 bone and bone Anatomy 0.000 description 6
- PIJPYDMVFNTHIP-UHFFFAOYSA-L lead sulfate Chemical compound [PbH4+2].[O-]S([O-])(=O)=O PIJPYDMVFNTHIP-UHFFFAOYSA-L 0.000 description 6
- 230000001172 regenerating effect Effects 0.000 description 6
- 229910045601 alloy Inorganic materials 0.000 description 5
- 239000000956 alloy Substances 0.000 description 5
- WABPQHHGFIMREM-UHFFFAOYSA-N lead(0) Chemical compound [Pb] WABPQHHGFIMREM-UHFFFAOYSA-N 0.000 description 5
- 230000035515 penetration Effects 0.000 description 5
- 239000004698 Polyethylene Substances 0.000 description 4
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 230000005484 gravity Effects 0.000 description 4
- 229920000573 polyethylene Polymers 0.000 description 4
- 239000007774 positive electrode material Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 238000007599 discharging Methods 0.000 description 3
- 239000007772 electrode material Substances 0.000 description 3
- 239000011888 foil Substances 0.000 description 3
- 229920005610 lignin Polymers 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 3
- 239000000661 sodium alginate Substances 0.000 description 3
- 235000010413 sodium alginate Nutrition 0.000 description 3
- 229940005550 sodium alginate Drugs 0.000 description 3
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 3
- 125000000542 sulfonic acid group Chemical group 0.000 description 3
- 229910014474 Ca-Sn Inorganic materials 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- 238000009825 accumulation Methods 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 238000000498 ball milling Methods 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 238000005266 casting Methods 0.000 description 2
- YADSGOSSYOOKMP-UHFFFAOYSA-N dioxolead Chemical compound O=[Pb]=O YADSGOSSYOOKMP-UHFFFAOYSA-N 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 229910003002 lithium salt Inorganic materials 0.000 description 2
- 159000000002 lithium salts Chemical class 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 2
- 239000012779 reinforcing material Substances 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- 229920002994 synthetic fiber Polymers 0.000 description 2
- 239000012209 synthetic fiber Substances 0.000 description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- 229910020220 Pb—Sn Inorganic materials 0.000 description 1
- 229910001245 Sb alloy Inorganic materials 0.000 description 1
- 230000005856 abnormality Effects 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 239000006230 acetylene black Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 229910001413 alkali metal ion Inorganic materials 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 229910003481 amorphous carbon Inorganic materials 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 239000000648 calcium alginate Substances 0.000 description 1
- 235000010410 calcium alginate Nutrition 0.000 description 1
- 229960002681 calcium alginate Drugs 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- OKHHGHGGPDJQHR-YMOPUZKJSA-L calcium;(2s,3s,4s,5s,6r)-6-[(2r,3s,4r,5s,6r)-2-carboxy-6-[(2r,3s,4r,5s,6r)-2-carboxylato-4,5,6-trihydroxyoxan-3-yl]oxy-4,5-dihydroxyoxan-3-yl]oxy-3,4,5-trihydroxyoxane-2-carboxylate Chemical compound [Ca+2].O[C@@H]1[C@H](O)[C@H](O)O[C@@H](C([O-])=O)[C@H]1O[C@H]1[C@@H](O)[C@@H](O)[C@H](O[C@H]2[C@H]([C@@H](O)[C@H](O)[C@H](O2)C([O-])=O)O)[C@H](C(O)=O)O1 OKHHGHGGPDJQHR-YMOPUZKJSA-L 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 238000004737 colorimetric analysis Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010280 constant potential charging Methods 0.000 description 1
- 210000005069 ears Anatomy 0.000 description 1
- 125000001033 ether group Chemical group 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 239000003273 ketjen black Substances 0.000 description 1
- 229910000464 lead oxide Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 238000009783 overcharge test Methods 0.000 description 1
- YEXPOXQUZXUXJW-UHFFFAOYSA-N oxolead Chemical compound [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 description 1
- 229920005646 polycarboxylate Polymers 0.000 description 1
- 229920001444 polymaleic acid Polymers 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- 239000004071 soot Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Landscapes
- Cell Electrode Carriers And Collectors (AREA)
- Secondary Cells (AREA)
- Battery Electrode And Active Subsutance (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2013161724A JP6153072B2 (ja) | 2013-08-02 | 2013-08-02 | 液式鉛蓄電池 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2013161724A JP6153072B2 (ja) | 2013-08-02 | 2013-08-02 | 液式鉛蓄電池 |
Publications (3)
Publication Number | Publication Date |
---|---|
JP2015032480A JP2015032480A (ja) | 2015-02-16 |
JP2015032480A5 JP2015032480A5 (enrdf_load_stackoverflow) | 2015-11-05 |
JP6153072B2 true JP6153072B2 (ja) | 2017-06-28 |
Family
ID=52517639
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2013161724A Expired - Fee Related JP6153072B2 (ja) | 2013-08-02 | 2013-08-02 | 液式鉛蓄電池 |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP6153072B2 (enrdf_load_stackoverflow) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10622634B2 (en) | 2015-05-29 | 2020-04-14 | Gs Yuasa International Ltd. | Lead-acid battery and method for producing lead-acid battery |
JP6468163B2 (ja) * | 2015-10-21 | 2019-02-13 | 日立化成株式会社 | 鉛蓄電池 |
JP6750374B2 (ja) * | 2016-07-29 | 2020-09-02 | 株式会社Gsユアサ | 鉛蓄電池 |
JP6766504B2 (ja) * | 2016-07-29 | 2020-10-14 | 株式会社Gsユアサ | 鉛蓄電池 |
CN107068983B (zh) * | 2017-04-01 | 2020-01-31 | 安徽理士电源技术有限公司 | 一种铅炭电池、铅炭电池负极板及其制备方法 |
JP6950365B2 (ja) * | 2017-08-30 | 2021-10-13 | 昭和電工マテリアルズ株式会社 | 負極材ペースト、負極及び鉛蓄電池、並びにそれらの製造方法 |
JP2019053998A (ja) * | 2018-11-27 | 2019-04-04 | 株式会社Gsユアサ | 鉛蓄電池 |
JP6743919B2 (ja) * | 2019-01-15 | 2020-08-19 | 日立化成株式会社 | 鉛蓄電池、アイドリングストップシステム車及びマイクロハイブリッド車 |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS57103669U (enrdf_load_stackoverflow) * | 1980-12-15 | 1982-06-25 | ||
JPH02201872A (ja) * | 1989-01-31 | 1990-08-10 | Matsushita Electric Ind Co Ltd | 鉛蓄電池用極板 |
JP3992336B2 (ja) * | 1997-10-13 | 2007-10-17 | 株式会社ジーエス・ユアサコーポレーション | 鉛蓄電池用負極板 |
JP2001313064A (ja) * | 2000-04-28 | 2001-11-09 | Mase Shunzo | 鉛蓄電池およびその添加剤 |
JP4891474B2 (ja) * | 2000-10-20 | 2012-03-07 | 株式会社Gsユアサ | 鉛蓄電池 |
JP4492024B2 (ja) * | 2002-05-21 | 2010-06-30 | パナソニック株式会社 | 鉛蓄電池 |
JP2004022440A (ja) * | 2002-06-19 | 2004-01-22 | Hitachi Ltd | 鉛蓄電池 |
JP5531855B2 (ja) * | 2010-08-18 | 2014-06-25 | 新神戸電機株式会社 | 鉛蓄電池用負極板及びこの負極板を用いた鉛蓄電池 |
JP5195842B2 (ja) * | 2010-08-18 | 2013-05-15 | 株式会社デンソー | 減圧弁制御装置 |
EP2731189A4 (en) * | 2011-07-05 | 2015-04-08 | Gs Yuasa Int Ltd | LEAD-ACID BATTERY FLOODED |
-
2013
- 2013-08-02 JP JP2013161724A patent/JP6153072B2/ja not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
JP2015032480A (ja) | 2015-02-16 |
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