JP6069487B2 - 重合性液晶化合物、重合性液晶組成物および光学異方体 - Google Patents
重合性液晶化合物、重合性液晶組成物および光学異方体 Download PDFInfo
- Publication number
- JP6069487B2 JP6069487B2 JP2015506905A JP2015506905A JP6069487B2 JP 6069487 B2 JP6069487 B2 JP 6069487B2 JP 2015506905 A JP2015506905 A JP 2015506905A JP 2015506905 A JP2015506905 A JP 2015506905A JP 6069487 B2 JP6069487 B2 JP 6069487B2
- Authority
- JP
- Japan
- Prior art keywords
- liquid crystal
- group
- polymerizable
- wavelength
- polymerizable liquid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000004973 liquid crystal related substance Substances 0.000 title claims description 227
- 150000001875 compounds Chemical class 0.000 title claims description 136
- 230000003287 optical effect Effects 0.000 title claims description 60
- 239000000203 mixture Substances 0.000 title claims description 41
- 239000010408 film Substances 0.000 claims description 53
- 239000000126 substance Substances 0.000 claims description 38
- 125000004432 carbon atom Chemical group C* 0.000 claims description 32
- 125000005647 linker group Chemical group 0.000 claims description 28
- 125000000524 functional group Chemical group 0.000 claims description 20
- 229910052739 hydrogen Inorganic materials 0.000 claims description 19
- 125000000732 arylene group Chemical group 0.000 claims description 16
- 239000010409 thin film Substances 0.000 claims description 16
- 125000000217 alkyl group Chemical group 0.000 claims description 15
- 239000001257 hydrogen Substances 0.000 claims description 15
- 229910052799 carbon Inorganic materials 0.000 claims description 14
- 125000002947 alkylene group Chemical group 0.000 claims description 13
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 11
- 125000006574 non-aromatic ring group Chemical group 0.000 claims description 11
- 239000002904 solvent Substances 0.000 claims description 10
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 8
- 239000011230 binding agent Substances 0.000 claims description 8
- 229920000642 polymer Polymers 0.000 claims description 8
- 229910052736 halogen Inorganic materials 0.000 claims description 7
- 150000002367 halogens Chemical class 0.000 claims description 7
- 125000006850 spacer group Chemical group 0.000 claims description 7
- NIXOWILDQLNWCW-UHFFFAOYSA-M acrylate group Chemical group C(C=C)(=O)[O-] NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 6
- 125000002252 acyl group Chemical group 0.000 claims description 4
- 125000004453 alkoxycarbonyl group Chemical group 0.000 claims description 4
- 125000004956 cyclohexylene group Chemical group 0.000 claims description 4
- 125000003700 epoxy group Chemical group 0.000 claims description 4
- 150000002431 hydrogen Chemical class 0.000 claims description 4
- 239000003505 polymerization initiator Substances 0.000 claims description 4
- 125000003545 alkoxy group Chemical group 0.000 claims description 3
- 125000005907 alkyl ester group Chemical group 0.000 claims description 3
- 150000001721 carbon Chemical class 0.000 claims description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-M methacrylate group Chemical group C(C(=C)C)(=O)[O-] CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims description 3
- 125000003518 norbornenyl group Chemical group C12(C=CC(CC1)C2)* 0.000 claims description 3
- 229910052760 oxygen Inorganic materials 0.000 claims description 3
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 claims description 3
- 125000004448 alkyl carbonyl group Chemical group 0.000 claims description 2
- 229910052796 boron Inorganic materials 0.000 claims description 2
- 125000004093 cyano group Chemical group *C#N 0.000 claims description 2
- 125000002993 cycloalkylene group Chemical group 0.000 claims description 2
- 229910052757 nitrogen Inorganic materials 0.000 claims description 2
- 229910052698 phosphorus Inorganic materials 0.000 claims description 2
- 229910052717 sulfur Inorganic materials 0.000 claims description 2
- 229940126062 Compound A Drugs 0.000 claims 1
- NLDMNSXOCDLTTB-UHFFFAOYSA-N Heterophylliin A Natural products O1C2COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC2C(OC(=O)C=2C=C(O)C(O)=C(O)C=2)C(O)C1OC(=O)C1=CC(O)=C(O)C(O)=C1 NLDMNSXOCDLTTB-UHFFFAOYSA-N 0.000 claims 1
- 239000005264 High molar mass liquid crystal Substances 0.000 claims 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims 1
- 239000006185 dispersion Substances 0.000 description 59
- 238000004519 manufacturing process Methods 0.000 description 30
- 238000006243 chemical reaction Methods 0.000 description 29
- JGFZNNIVVJXRND-UHFFFAOYSA-N N,N-Diisopropylethylamine (DIPEA) Chemical compound CCN(C(C)C)C(C)C JGFZNNIVVJXRND-UHFFFAOYSA-N 0.000 description 24
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 23
- 238000000034 method Methods 0.000 description 18
- VHYFNPMBLIVWCW-UHFFFAOYSA-N 4-Dimethylaminopyridine Chemical compound CN(C)C1=CC=NC=C1 VHYFNPMBLIVWCW-UHFFFAOYSA-N 0.000 description 16
- 125000005549 heteroarylene group Chemical group 0.000 description 11
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 10
- LMDZBCPBFSXMTL-UHFFFAOYSA-N 1-ethyl-3-(3-dimethylaminopropyl)carbodiimide Chemical compound CCN=C=NCCCN(C)C LMDZBCPBFSXMTL-UHFFFAOYSA-N 0.000 description 8
- 125000001931 aliphatic group Chemical group 0.000 description 7
- 230000001747 exhibiting effect Effects 0.000 description 7
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 125000003118 aryl group Chemical group 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 238000003786 synthesis reaction Methods 0.000 description 5
- FPQQSJJWHUJYPU-UHFFFAOYSA-N 3-(dimethylamino)propyliminomethylidene-ethylazanium;chloride Chemical compound Cl.CCN=C=NCCCN(C)C FPQQSJJWHUJYPU-UHFFFAOYSA-N 0.000 description 4
- 229960000549 4-dimethylaminophenol Drugs 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 230000010287 polarization Effects 0.000 description 4
- 238000006116 polymerization reaction Methods 0.000 description 4
- KWVGIHKZDCUPEU-UHFFFAOYSA-N 2,2-dimethoxy-2-phenylacetophenone Chemical compound C=1C=CC=CC=1C(OC)(OC)C(=O)C1=CC=CC=C1 KWVGIHKZDCUPEU-UHFFFAOYSA-N 0.000 description 3
- 238000004132 cross linking Methods 0.000 description 3
- 125000005843 halogen group Chemical group 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical group C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 description 2
- -1 5-norbornene-2-ethyl- (4-methylcinnamate) Chemical compound 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- ORILYTVJVMAKLC-UHFFFAOYSA-N adamantane Chemical group C1C(C2)CC3CC1CC2C3 ORILYTVJVMAKLC-UHFFFAOYSA-N 0.000 description 2
- 238000004873 anchoring Methods 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 239000002178 crystalline material Substances 0.000 description 2
- 125000005677 ethinylene group Chemical group [*:2]C#C[*:1] 0.000 description 2
- 125000001072 heteroaryl group Chemical group 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 2
- 229910052753 mercury Inorganic materials 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- GLGNXYJARSMNGJ-VKTIVEEGSA-N (1s,2s,3r,4r)-3-[[5-chloro-2-[(1-ethyl-6-methoxy-2-oxo-4,5-dihydro-3h-1-benzazepin-7-yl)amino]pyrimidin-4-yl]amino]bicyclo[2.2.1]hept-5-ene-2-carboxamide Chemical compound CCN1C(=O)CCCC2=C(OC)C(NC=3N=C(C(=CN=3)Cl)N[C@H]3[C@H]([C@@]4([H])C[C@@]3(C=C4)[H])C(N)=O)=CC=C21 GLGNXYJARSMNGJ-VKTIVEEGSA-N 0.000 description 1
- 125000000027 (C1-C10) alkoxy group Chemical group 0.000 description 1
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 description 1
- SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical compound CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 description 1
- 238000000018 DNA microarray Methods 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000003990 capacitor Substances 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 229940125758 compound 15 Drugs 0.000 description 1
- 238000001723 curing Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- 230000005669 field effect Effects 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 239000012788 optical film Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000005268 rod-like liquid crystal Substances 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K19/00—Liquid crystal materials
- C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
- C09K19/38—Polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K19/00—Liquid crystal materials
- C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
- C09K19/06—Non-steroidal liquid crystal compounds
- C09K19/08—Non-steroidal liquid crystal compounds containing at least two non-condensed rings
- C09K19/10—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings
- C09K19/20—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings linked by a chain containing carbon and oxygen atoms as chain links, e.g. esters or ethers
- C09K19/2007—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings linked by a chain containing carbon and oxygen atoms as chain links, e.g. esters or ethers the chain containing -COO- or -OCO- groups
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K19/00—Liquid crystal materials
- C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
- C09K19/42—Mixtures of liquid crystal compounds covered by two or more of the preceding groups C09K19/06 - C09K19/40
- C09K19/46—Mixtures of liquid crystal compounds covered by two or more of the preceding groups C09K19/06 - C09K19/40 containing esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F22/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides or nitriles thereof
- C08F22/10—Esters
- C08F22/12—Esters of phenols or saturated alcohols
- C08F22/20—Esters containing oxygen in addition to the carboxy oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F34/00—Homopolymers and copolymers of cyclic compounds having no unsaturated aliphatic radicals in a side chain and having one or more carbon-to-carbon double bonds in a heterocyclic ring
- C08F34/04—Homopolymers and copolymers of cyclic compounds having no unsaturated aliphatic radicals in a side chain and having one or more carbon-to-carbon double bonds in a heterocyclic ring in a ring containing sulfur
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K19/00—Liquid crystal materials
- C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
- C09K19/06—Non-steroidal liquid crystal compounds
- C09K19/08—Non-steroidal liquid crystal compounds containing at least two non-condensed rings
- C09K19/30—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing saturated or unsaturated non-aromatic rings, e.g. cyclohexane rings
- C09K19/3001—Cyclohexane rings
- C09K19/3066—Cyclohexane rings in which the rings are linked by a chain containing carbon and oxygen atoms, e.g. esters or ethers
- C09K19/3068—Cyclohexane rings in which the rings are linked by a chain containing carbon and oxygen atoms, e.g. esters or ethers chain containing -COO- or -OCO- groups
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K19/00—Liquid crystal materials
- C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
- C09K19/06—Non-steroidal liquid crystal compounds
- C09K19/32—Non-steroidal liquid crystal compounds containing condensed ring systems, i.e. fused, bridged or spiro ring systems
- C09K19/322—Compounds containing a naphthalene ring or a completely or partially hydrogenated naphthalene ring
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K19/00—Liquid crystal materials
- C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
- C09K19/06—Non-steroidal liquid crystal compounds
- C09K19/34—Non-steroidal liquid crystal compounds containing at least one heterocyclic ring
- C09K19/3491—Non-steroidal liquid crystal compounds containing at least one heterocyclic ring having sulfur as hetero atom
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K19/00—Liquid crystal materials
- C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
- C09K19/38—Polymers
- C09K19/3804—Polymers with mesogenic groups in the main chain
- C09K19/3809—Polyesters; Polyester derivatives, e.g. polyamides
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/30—Polarising elements
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/30—Polarising elements
- G02B5/3025—Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state
- G02B5/3033—Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state in the form of a thin sheet or foil, e.g. Polaroid
- G02B5/3041—Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state in the form of a thin sheet or foil, e.g. Polaroid comprising multiple thin layers, e.g. multilayer stacks
- G02B5/305—Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state in the form of a thin sheet or foil, e.g. Polaroid comprising multiple thin layers, e.g. multilayer stacks including organic materials, e.g. polymeric layers
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/133365—Cells in which the active layer comprises a liquid crystalline polymer
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/1335—Structural association of cells with optical devices, e.g. polarisers or reflectors
- G02F1/13363—Birefringent elements, e.g. for optical compensation
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/1337—Surface-induced orientation of the liquid crystal molecules, e.g. by alignment layers
- G02F1/13378—Surface-induced orientation of the liquid crystal molecules, e.g. by alignment layers by treatment of the surface, e.g. embossing, rubbing or light irradiation
- G02F1/133784—Surface-induced orientation of the liquid crystal molecules, e.g. by alignment layers by treatment of the surface, e.g. embossing, rubbing or light irradiation by rubbing
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/1337—Surface-induced orientation of the liquid crystal molecules, e.g. by alignment layers
- G02F1/13378—Surface-induced orientation of the liquid crystal molecules, e.g. by alignment layers by treatment of the surface, e.g. embossing, rubbing or light irradiation
- G02F1/133788—Surface-induced orientation of the liquid crystal molecules, e.g. by alignment layers by treatment of the surface, e.g. embossing, rubbing or light irradiation by light irradiation, e.g. linearly polarised light photo-polymerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G2261/10—Definition of the polymer structure
- C08G2261/22—Molecular weight
- C08G2261/226—Oligomers, i.e. up to 10 repeat units
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G2261/30—Monomer units or repeat units incorporating structural elements in the main chain
- C08G2261/34—Monomer units or repeat units incorporating structural elements in the main chain incorporating partially-aromatic structural elements in the main chain
- C08G2261/342—Monomer units or repeat units incorporating structural elements in the main chain incorporating partially-aromatic structural elements in the main chain containing only carbon atoms
- C08G2261/3422—Monomer units or repeat units incorporating structural elements in the main chain incorporating partially-aromatic structural elements in the main chain containing only carbon atoms conjugated, e.g. PPV-type
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G2261/40—Polymerisation processes
- C08G2261/41—Organometallic coupling reactions
- C08G2261/413—Heck reactions
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G2261/50—Physical properties
- C08G2261/53—Physical properties liquid-crystalline
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G2261/70—Post-treatment
- C08G2261/74—Further polymerisation of the obtained polymers, e.g. living polymerisation to obtain block-copolymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K19/00—Liquid crystal materials
- C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
- C09K2019/0444—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit characterized by a linking chain between rings or ring systems, a bridging chain between extensive mesogenic moieties or an end chain group
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K19/00—Liquid crystal materials
- C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
- C09K2019/0444—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit characterized by a linking chain between rings or ring systems, a bridging chain between extensive mesogenic moieties or an end chain group
- C09K2019/0448—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit characterized by a linking chain between rings or ring systems, a bridging chain between extensive mesogenic moieties or an end chain group the end chain group being a polymerizable end group, e.g. -Sp-P or acrylate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K19/00—Liquid crystal materials
- C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
- C09K19/06—Non-steroidal liquid crystal compounds
- C09K19/08—Non-steroidal liquid crystal compounds containing at least two non-condensed rings
- C09K19/10—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings
- C09K19/12—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings at least two benzene rings directly linked, e.g. biphenyls
- C09K2019/121—Compounds containing phenylene-1,4-diyl (-Ph-)
- C09K2019/122—Ph-Ph
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K19/00—Liquid crystal materials
- C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
- C09K19/06—Non-steroidal liquid crystal compounds
- C09K19/08—Non-steroidal liquid crystal compounds containing at least two non-condensed rings
- C09K19/10—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings
- C09K19/20—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings linked by a chain containing carbon and oxygen atoms as chain links, e.g. esters or ethers
- C09K19/2007—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings linked by a chain containing carbon and oxygen atoms as chain links, e.g. esters or ethers the chain containing -COO- or -OCO- groups
- C09K2019/2035—Ph-COO-Ph
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K19/00—Liquid crystal materials
- C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
- C09K19/06—Non-steroidal liquid crystal compounds
- C09K19/08—Non-steroidal liquid crystal compounds containing at least two non-condensed rings
- C09K19/30—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing saturated or unsaturated non-aromatic rings, e.g. cyclohexane rings
- C09K19/3001—Cyclohexane rings
- C09K19/3066—Cyclohexane rings in which the rings are linked by a chain containing carbon and oxygen atoms, e.g. esters or ethers
- C09K19/3068—Cyclohexane rings in which the rings are linked by a chain containing carbon and oxygen atoms, e.g. esters or ethers chain containing -COO- or -OCO- groups
- C09K2019/3075—Cy-COO-Ph
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K19/00—Liquid crystal materials
- C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
- C09K19/06—Non-steroidal liquid crystal compounds
- C09K19/08—Non-steroidal liquid crystal compounds containing at least two non-condensed rings
- C09K19/30—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing saturated or unsaturated non-aromatic rings, e.g. cyclohexane rings
- C09K19/3001—Cyclohexane rings
- C09K19/3066—Cyclohexane rings in which the rings are linked by a chain containing carbon and oxygen atoms, e.g. esters or ethers
- C09K19/3068—Cyclohexane rings in which the rings are linked by a chain containing carbon and oxygen atoms, e.g. esters or ethers chain containing -COO- or -OCO- groups
- C09K2019/3077—Cy-Cy-COO-Ph
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K19/00—Liquid crystal materials
- C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
- C09K19/06—Non-steroidal liquid crystal compounds
- C09K19/08—Non-steroidal liquid crystal compounds containing at least two non-condensed rings
- C09K19/30—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing saturated or unsaturated non-aromatic rings, e.g. cyclohexane rings
- C09K19/3001—Cyclohexane rings
- C09K19/3066—Cyclohexane rings in which the rings are linked by a chain containing carbon and oxygen atoms, e.g. esters or ethers
- C09K19/3068—Cyclohexane rings in which the rings are linked by a chain containing carbon and oxygen atoms, e.g. esters or ethers chain containing -COO- or -OCO- groups
- C09K2019/3083—Cy-Ph-COO-Ph
Description
pは、1乃至4の整数であり、1乃至4個含まれている各繰り返し単位は、独立して互いに同一でも異なっていてもよい。
前記非芳香族環を有するメソゲン基と異なる構造を有し、二重結合含有環を含むメソゲン基を有する第2液晶分子由来ラジカル;および
前記第1液晶分子由来ラジカルの非芳香族環内のsp3−混成化された炭素と、前記第2液晶分子由来ラジカルのメソゲン基内のsp2−混成化された炭素とを互いに連結し、下記一般式1で表されるリンカー;
を含み、
前記第1および第2液晶分子由来ラジカルのうちの少なくとも一つは、前記メソゲン基に直接的にまたはスペーサ基を介して連結された一つ以上の重合性基を有する、重合性液晶化合物が提供される:
M1およびM2は、それぞれ独立して、単結合、−C≡C−、−C≡C−C≡C−、アリーレン基またはヘテロアリーレン基であり、Qは、−C≡C−、−CR4=CR5−、アリーレン基、ヘテロアリーレン基またはこれらを2以上組み合わせた2価の作用基であり、M1、M2およびQの一つ以上は、−C≡C−、−C≡C−C≡C−、アリーレン基またはヘテロアリーレン基を含み、前記R4およびR5は、それぞれ独立して、H、F、Cl、CN、炭素数1乃至10のアルキル基、または炭素数1乃至10のアシル基であり、
pは、1乃至4の整数であり、1乃至4個含まれている各繰り返し単位は、独立して互いに同一でも異なっていてもよい。
(式III)
┃△n(λ1)┃/┃△n(550nm)┃≧1.0
(式IV)
┃△n(650nm)┃/┃△n(λ2)┃≦1.0
上記式IIIおよび式IV中、△n(λ)は、液晶相内の波長λでの複屈折率を意味し、λ1は、450nm以上550nm未満の波長を意味し、λ2は、550nm超過650nm以下の波長を意味する。
約1.0≦┃△n(550nm)┃/┃△n(450nm)┃≦約1.05
を満たす液晶分子から誘導されたものであり、前記リンカーは、
約1.1≦┃△n(550nm)┃/┃△n(450nm)┃≦約1.3(あるいは約1.2)
を満たす化合物から誘導されたものであり得る。
(式I)
┃△n(λ1)┃/┃△n(550nm)┃≦1.0
(式II)
┃△n(650nm)┃/┃△n(λ2)┃≧1.0
上記式Iおよび式II中、△n(λ)は、液晶相内の波長λでの複屈折率を意味し、λ1は、450nm以上550nm未満の波長を意味し、λ2は、550nm以上650nm未満の波長を意味する。
環Cは、一つ以上の酸素またはシリコン含有もしくは不含の脂肪族6員環、ノルボルネン環、樟脳(Camphor)環またはアダマンタン(adamantane)環の非芳香族環であり;
A1、A2、E1およびE2は、それぞれ独立して、単結合または2価の連結基であり;
D1およびD2は、それぞれ独立して、置換もしくは非置換の芳香族環、置換もしくは非置換の脂肪族環、置換もしくは非置換のヘテロ脂肪族環、および置換もしくは非置換のヘテロ芳香族環からなる群より選ばれた1種以上の環を含む2価の作用基であり;
G1およびG2は、それぞれ独立して、単結合またはアルキレン基であり;
J1およびJ2は、それぞれ独立して、水素または重合性基であり、ただし、J1およびJ2の少なくとも一つは重合性基であり;
m1、m2、n1およびn2は、それぞれ独立して、1乃至5の整数である。
A3、A4、E3およびE4は、それぞれ独立して、単結合または2価の連結基であり;
D3およびD4は、それぞれ独立して、置換もしくは非置換の芳香族環、置換もしくは非置換の脂肪族環、置換もしくは非置換のヘテロ脂肪族環、および置換もしくは非置換のヘテロ芳香族環からなる群より選ばれた1種以上の環を含む2価の作用基であり;
G3およびG4は、それぞれ独立して、単結合またはアルキレン基であり;
J3およびJ4は、それぞれ独立して、水素または重合性基であり、ただし、J3およびJ4の少なくとも一つは重合性基であり;
R1乃至R5は、それぞれ独立して、水素、ハロゲン、−CN、アルキル基またはアシル基であり;
B1は、NまたはPであり、B2は、OまたはSであり;
m3、m4、n3およびn4は、それぞれ独立して、1乃至5の整数である。
(式III)
┃△n(λ1)┃/┃△n(550nm)┃≧1.0
(式IV)
┃△n(650nm)┃/┃△n(λ2)┃≦1.0
上記式IIIおよび式IV中、△n(λ)は、液晶相内の波長λでの複屈折率を意味し、λ1は、450nm以上550nm未満の波長を意味し、λ2は、550nm以上650nm未満の波長を意味する。
F1およびF2は、それぞれ独立して、単結合、C(=O)−、−OC(=O)−、−C(=O)O−、または炭素数1乃至10のアルキレン基であり;
Y1乃至Y12は、それぞれ独立して、H、FまたはClなどのハロゲン、−CN、ハロゲンなどで置換もしくは非置換の炭素数1乃至10のアルキル、ハロゲンなどで置換もしくは非置換の炭素数1乃至10のアルコキシ、ハロゲンなどで置換もしくは非置換の炭素数1乃至10のアルキルカルボニル、ハロゲンなどで置換もしくは非置換の炭素数1乃至10のアルコキシカルボニルまたはハロゲンなどで置換もしくは非置換の炭素数1乃至10のアルキルエステルであり;
X1およびX2は、それぞれ独立して、水素または下記化学式10aの作用基であり;
JmおよびMmは、それぞれ独立して、単結合、炭素数1乃至10のアルキレン基または炭素数3乃至10のシクロアルキレン基であり;
Qmは、水素、炭素数1乃至10のアルキル基、またはアクリレート、メタクリレート、またはエポキシ基などの重合性基である。
(式V)
R(λ1)/R(550nm)≦1.0
(式VI)
R(650nm)/R(λ2)≧1.0
上記式Vおよび式VI中、R(λ)は、┃△n(λ)┃・dで定義される波長λでの光学軸上位相差であって、△n(λ)は、液晶相内の波長λでの複屈折率を意味し、dは、薄膜またはフィルムの厚さ(nm)を意味し、λ1は、450nm以上550nm未満の波長を意味し、λ2は、550nm以上650nm未満の波長を意味する。
TEA:トリエチルアミン;DCM:ジクロロメタン;R.T.:室温;DIPEA:N,N’−ジイソプロピルエチルアミン;EDC:1−エチル−3−[3−ジメチルアミノプロピル]カルボジイミドヒドロクロリド;DMAP:4−ジメチルアミノピリジン。
DCM:ジクロロメタン;DIPEA:N,N’−ジイソプロピルエチルアミン;R.T.:室温;EDC:1−エチル−3−[3−ジメチルアミノプロピル]カルボジイミドヒドロクロリド;DMAP:4−ジメチルアミノピリジン。
DMAP:4−ジメチルアミノピリジン;EDCI:1−エチル−3−[3−ジメチルアミノプロピル]カルボジイミド;DCM:ジクロロメタン;DIPEA:N,N’−ジイソプロピルエチルアミン;R.T.:室温;DCE:ジクロロエタン。
TEA:トリエチルアミン;DCM:ジクロロメタン;DIPEA:N,N’−ジイソプロピルエチルアミン;DMAP:4−ジメチルアミノピリジン;EDC:1−エチル−3−[3−ジメチルアミノプロピル]カルボジイミドヒドロクロリド;R.T.:室温。
製造例1で得られた中間体1および製造例3で得られた中間体3を用いて、下記反応式5に示された反応条件および方法により、下記化学式5の重合性液晶化合物を製造した。このように製造された化学式5の重合性液晶化合物のNMRデータは図1に示されたとおりである:
製造例1で得られた中間体1を用いて、下記反応式6に示された反応条件および方法により、下記化学式6の重合性液晶化合物を製造した。このように製造された化学式6の重合性液晶化合物のNMRデータは図2に示されたとおりである:
製造例2で得られた中間体2および製造例4で得られた中間体4を用いて、下記反応式7に示された反応条件および方法により、下記化学式7の重合性液晶化合物を製造した。このように製造された化学式7の重合性液晶化合物の生成はNMRで確認した。
前記中間体4の代わりに公知の中間体5を用い、
製造例3で得られた中間体3および製造例5で得られた中間体6を用いて、下記反応式8に示された反応条件および方法により、下記化学式9の重合性液晶化合物を製造した。このように製造された化学式9の重合性液晶化合物の生成はNMRで確認した。
実施例1で得られた化学式5の重合性液晶化合物39.68重量%、下記化学式30の液晶化合物18.01重量%、下記化学式31の液晶化合物15.83重量%、下記化学式32の液晶化合物24.14重量%、イルガキュア(Irgacure)651の光開始剤1.39重量%および界面活性剤0.96重量%を混合して液晶組成物を製造した:
実施例1で得られた化学式5の重合性液晶化合物の代わりに、リンカーが各液晶分子由来ラジカルのsp3−混成化された炭素同志を連結する構造を有する対称構造の比較化学式1の重合性液晶化合物を用いたことを除き、実施例6と同様な方法で、重合性液晶組成物、光配向層、液晶層および光学異方体を製造した。
実施例2で得られた化学式6の重合性液晶化合物41.05重量%、化学式30の液晶化合物10.71重量%、化学式31の液晶化合物16.94重量%、化学式32の液晶化合物29.24重量%、イルガキュア(Irgacure)651の光開始剤0.99重量%および界面活性剤0.96重量%を混合して液晶組成物を製造した。
実施例3で得られた化学式7の重合性液晶化合物33.67重量%、化学式31の液晶化合物31.08重量%、化学式32の液晶化合物32.87重量%、イルガキュア(Irgacure)651の光開始剤0.99重量%および界面活性剤0.96重量%を混合して液晶組成物を製造した。
Claims (21)
- 非芳香族環を有するメソゲン基を含む第1液晶分子由来ラジカル;
前記非芳香族環を有するメソゲン基と異なる構造を有し、二重結合含有環を含むメソゲン基を有する第2液晶分子由来ラジカル;および
前記第1液晶分子由来ラジカルの非芳香族環内のsp3−混成化された炭素と、前記第2液晶分子由来ラジカルのメソゲン基内のsp2−混成化された炭素とを互いに連結する、リンカー;
を含み、
前記第1および第2液晶分子由来ラジカルのうちの少なくとも一つは、前記メソゲン基に直接的にまたはスペーサ基を介して連結された一つ以上の重合性基を有する、重合性液晶化合物であって、下記化学式1、2、3または4で表される重合性液晶化合物:
A 1 、A 2 、A 3 、A 4 、E 1 、E 2 、E 3 およびE 4 は、それぞれ独立して、単結合、−O−、−S−、−CO−、−COO−、−OCO−、−O−COO−、−CO−NR−、−NR−CO−、−NR−CO−NR−、−OCH 2 −、−CH 2 O−、−SCH−、−CH 2 S−、−CF 2 O−、−OCF 2 −、−CF 2 S−、−SCF 2 −、−CH 2 CH 2 −、−(CH 2 ) 3 −、−(CH 2 ) 4 −、−CF 2 CH 2 −、−CH 2 CF 2 −、−CF 2 CF 2 −、−C=C−または−C≡C−であり、前記Rは、それぞれ独立して、水素または炭素数1乃至10のアルキル基であり;
D 1 、D 2 、D 3 およびD 4 は、それぞれ独立して、シクロへキシレン基またはフェニレン基であるか、前記シクロへキシレン基またはフェニレン基が炭素数1乃至10のアルキレン、−COO−、−OCO−、−O−、および−O−(炭素数1乃至10のアルキレン)−からなる群より選ばれた連結基と連結された2価の作用基であり;
G 1 、G 2 、G 3 およびG 4 は、それぞれ独立して、単結合またはアルキレン基であり;
J 1 、J 2 、J 3 およびJ 4 は、それぞれ独立して、水素または重合性基であり、ただし、J 1 およびJ 2 の少なくとも一つと、J 3 およびJ 4 の少なくとも一つは重合性基であり、前記重合性基はアクリレート基、メタクリレート基またはエポキシ基であり;
M 1 およびM 2 は、それぞれ独立して、単結合、−C≡C−、−C≡C−C≡C−、またはアリーレン基であり、Qは、−C≡C−、アリーレン基またはこれらを2以上組み合わせた2価の作用基であり、M 1 、M 2 およびQの一つ以上は、−C≡C−、−C≡C−C≡C−、またはアリーレン基を含み;
pは、1乃至4の整数であり、p個含まれている各繰り返し単位は、独立して互いに同一でも異なっていてもよく、
R 1 乃至R 5 は、それぞれ独立して、水素、ハロゲン、−CN、アルキル基またはアシル基であり;
B 1 は、NまたはPであり、B 2 は、OまたはSであり;
m1、m2、m3、m4、n1、n2、n3およびn4は、それぞれ独立して、1乃至5の整数であり、m 1 、m 2 、m 3 、m 4 、n 1 、n 2 、n 3 またはn 4 個含まれている各繰り返し単位は、独立して互いに同一でも異なっていてもよい)。 - 第1および第2液晶分子由来ラジカルは、下記式IIIおよびIVを満たし、450nm乃至650nm波長の光に対して△n(λ)が正の値を示す液晶分子から誘導されたラジカルであり、
リンカーは、下記式IIIおよびIVを満たし、450nm乃至650nm波長の光に対して△n(λ)が負の値を示す化合物から誘導された2価ラジカルである、請求項1に記載の重合性液晶化合物:
(式III)
┃△n(λ1)┃/┃△n(550nm)┃≧1.0
(式IV)
┃△n(650nm)┃/┃△n(λ2)┃≦1.0
(上記式IIIおよび式IV中、△n(λ)は、液晶相内の波長λでの複屈折率を意味し、λ1は、450nm以上550nm未満の波長を意味し、λ2は、550nm以上650nm未満の波長を意味する)。 - 第1および第2液晶分子由来ラジカルは、
1.0≦┃△n(450nm)┃/┃△n(550nm)┃≦1.05
を満たす液晶分子から誘導されたラジカルであり、
前記リンカーは、
1.1≦┃△n(450nm)┃/┃△n(550nm)┃≦1.3を満たす化合物から誘導された2価ラジカルである、請求項2に記載の重合性液晶化合物。 - 前記第1および第2液晶分子由来ラジカルは、共に前記メソゲン基に直接的にまたはスペーサ基を介して連結された一つ以上の重合性基を有する、請求項1に記載の重合性液晶化合物。
- 下記式Iおよび式IIを満たす、請求項1に記載の重合性液晶化合物:
(式I)
┃△n(λ1)┃/┃△n(550nm)┃≦1.0
(式II)
┃△n(650nm)┃/┃△n(λ2)┃≧1.0
上記式Iおよび式II中、△n(λ)は、液晶相内の波長λでの複屈折率を意味し、λ1は、450nm以上550nm未満の波長を意味し、λ2は、550nm以上650nm未満の波長を意味する。 - 請求項1〜6のいずれか一項に記載の重合性液晶化合物を含む重合性液晶組成物。
- 前記重合性液晶化合物と異なる構造を有する追加的液晶化合物の1種以上をさらに含む、請求項7に記載の重合性液晶組成物。
- 前記追加的液晶化合物は、メソゲン基と、このようなメソゲン基に直接的にまたはスペーサ基を介して連結された両末端の重合性基とを有する重合性液晶化合物である、請求項8に記載の重合性液晶組成物。
- 前記追加的液晶化合物は、450nm乃至650nm波長の光に対して△n(λ)が負の値を示し、下記式IIIおよびIVを満たす、請求項8に記載の重合性液晶組成物:
(式III)
┃△n(λ1)┃/┃△n(550nm)┃≧1.0
(式IV)
┃△n(650nm)┃/┃△n(λ2)┃≦1.0
上記式IIIおよび式IV中、△n(λ)は、液晶相内の波長λでの複屈折率を意味し、λ1は、450nm以上550nm未満の波長を意味し、λ2は、550nm以上650nm未満の波長を意味する。 - 前記追加的液晶化合物は、下記化学式10乃至13の化合物からなる群より選ばれた1種以上の液晶化合物である、請求項8に記載の重合性液晶組成物:
F1およびF2は、それぞれ独立して、単結合、C(=O)−、−OC(=O)−、−C(=O)O−、または炭素数1乃至10のアルキレン基であり;
Y1乃至Y12は、それぞれ独立して、H、ハロゲン、−CN、置換もしくは非置換の炭素数1乃至10のアルキル、置換もしくは非置換の炭素数1乃至10のアルコキシ、置換もしくは非置換の炭素数1乃至10のアルキルカルボニル、置換もしくは非置換の炭素数1乃至10のアルコキシカルボニルまたは置換もしくは非置換の炭素数1乃至10のアルキルエステルであり;
X1およびX2は、それぞれ独立して、水素または下記化学式10aの作用基であり;
JmおよびMmは、それぞれ独立して、単結合、炭素数1乃至10のアルキレン基または炭素数3乃至10のシクロアルキレン基であり;
Qmは、水素、炭素数1乃至10のアルキル基、または重合性基である)。 - 重合性バインダーまたはモノアクリレート系化合物をさらに含む、請求項7に記載の重合性液晶組成物。
- 重合開始剤および溶媒をさらに含む、請求項7に記載の重合性液晶組成物。
- 請求項7〜14のいずれか一項に記載の重合性液晶組成物の硬化物または重合体を含む光学異方体。
- 前記重合性液晶化合物の重合性基のうちの少なくとも一部が付加重合または架橋されている重合体または硬化物を含む、請求項15に記載の光学異方体。
- 薄膜またはフィルム形態である、請求項15に記載の光学異方体。
- 下記式VおよびVIを満たす薄膜またはフィルム形態である、請求項17に記載の光学異方体:
(式V)
R(λ1)/R(550nm)≦1.0
(式VI)
R(650nm)/R(λ2)≧1.0
(上記式Vおよび式VI中、R(λ)は、┃△n(λ)┃・dで定義される波長λでの光学軸上位相差であって、△n(λ)は、液晶相内の波長λでの複屈折率を意味し、dは、薄膜またはフィルムの厚さ(nm)を意味し、λ1は、450nm以上550nm未満の波長を意味し、λ2は、550nm以上650nm未満の波長を意味する)。 - 前記硬化物または重合体下部に配向膜をさらに含む薄膜またはフィルム形態である、請求項17に記載の光学異方体。
- 前記配向膜は、ラビング配向膜または光配向膜である薄膜またはフィルム形態である、請求項19に記載の光学異方体。
- 請求項15〜20のいずれか一項に記載の光学異方体を含む光学または電子素子。
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR20120041780 | 2012-04-20 | ||
KR10-2012-0041780 | 2012-04-20 | ||
PCT/KR2013/003346 WO2013157888A1 (ko) | 2012-04-20 | 2013-04-19 | 중합성 액정 화합물, 중합성 액정 조성물 및 광학 이방체 |
KR20130043281A KR101363479B1 (ko) | 2012-04-20 | 2013-04-19 | 중합성 액정 화합물, 중합성 액정 조성물 및 광학 이방체 |
KR10-2013-0043281 | 2013-04-19 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2015516972A JP2015516972A (ja) | 2015-06-18 |
JP6069487B2 true JP6069487B2 (ja) | 2017-02-01 |
Family
ID=49636961
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2015506905A Active JP6069487B2 (ja) | 2012-04-20 | 2013-04-19 | 重合性液晶化合物、重合性液晶組成物および光学異方体 |
Country Status (6)
Country | Link |
---|---|
US (2) | US9206355B2 (ja) |
EP (1) | EP2824162B1 (ja) |
JP (1) | JP6069487B2 (ja) |
KR (1) | KR101363479B1 (ja) |
CN (1) | CN104245885B (ja) |
WO (1) | WO2013157888A1 (ja) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20150105826A (ko) * | 2014-03-10 | 2015-09-18 | 단국대학교 천안캠퍼스 산학협력단 | 내부에 미세구조의 채널을 가지는 생분해성 신경도관 및 이의 제조방법 |
Families Citing this family (25)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9206355B2 (en) * | 2012-04-20 | 2015-12-08 | Lg Chem, Ltd. | Polymerizable liquid crystal compound, polymerizable liquid crystal composition, and optically anisotropic body |
KR101623929B1 (ko) * | 2013-09-30 | 2016-05-24 | 주식회사 엘지화학 | 역 파장 분산성 화합물, 이를 포함하는 역 파장 분산성 조성물 및 광학 이방체 |
JP6648438B2 (ja) * | 2014-08-27 | 2020-02-14 | Jnc株式会社 | 液晶性化合物、液晶組成物およびその重合体 |
WO2016056542A1 (ja) | 2014-10-09 | 2016-04-14 | Dic株式会社 | 重合性化合物及び光学異方体 |
US10633353B2 (en) | 2014-12-04 | 2020-04-28 | Dic Corporation | Polymerizable compound, composition, polymer, optically anisotropic body, liquid crystal display element, and organic EL display |
KR101623086B1 (ko) | 2014-12-08 | 2016-05-20 | 삼성전자 주식회사 | 반사방지필름 및 이를 구비한 유기발광장치 |
CN105676318B (zh) | 2014-12-08 | 2018-06-05 | 三星电子株式会社 | 抗反射膜和包括其的有机发光器件 |
CN107108458B (zh) * | 2014-12-25 | 2021-07-30 | Dic株式会社 | 聚合性化合物和光学各向异性体 |
JP6255632B2 (ja) | 2015-01-16 | 2018-01-10 | Dic株式会社 | 重合性組成物及びそれを用いた光学異方体 |
CN107207676B (zh) * | 2015-01-16 | 2020-10-09 | Dic株式会社 | 聚合性组合物和光学各向异性体 |
CN107108775B (zh) | 2015-01-16 | 2019-12-13 | Dic株式会社 | 聚合性组合物和使用该聚合性组合物的光学各向异性体 |
KR20160106513A (ko) * | 2015-03-02 | 2016-09-12 | 제이엔씨 주식회사 | 중합성 액정 조성물 및 광학 이방성 필름 |
US10919870B2 (en) * | 2015-11-09 | 2021-02-16 | Dic Corporation | Polymerizable compound and optically anisotropic body |
JP6624696B2 (ja) | 2015-12-08 | 2019-12-25 | Dic株式会社 | 重合性化合物及び光学異方体 |
WO2017110638A1 (ja) * | 2015-12-22 | 2017-06-29 | 日本ゼオン株式会社 | 液晶性組成物、液晶硬化層及びその製造方法、並びに、光学フィルム |
JP7052718B2 (ja) * | 2016-03-08 | 2022-04-12 | 日本ゼオン株式会社 | 液晶性組成物、液晶硬化層及びその液晶硬化層の製造方法 |
KR102167466B1 (ko) * | 2016-03-29 | 2020-10-19 | 스미또모 가가꾸 가부시끼가이샤 | 액정 조성물 |
WO2019034592A1 (en) * | 2017-08-15 | 2019-02-21 | Merck Patent Gmbh | POLYMERIZABLE LC MEDIUM AND POLYMER FILM HAVING FLAT OPTICAL DISPERSION |
US11539002B2 (en) | 2017-12-22 | 2022-12-27 | Lg Chem, Ltd. | Liquid crystal composition and use thereof |
KR102442993B1 (ko) | 2018-02-14 | 2022-09-13 | 후지필름 가부시키가이샤 | 화상 표시 장치 및 감광성 접착제 포함 원 편광판 |
WO2019186912A1 (ja) * | 2018-03-29 | 2019-10-03 | シャープ株式会社 | 表示デバイスおよびその製造方法 |
JPWO2020137935A1 (ja) * | 2018-12-27 | 2021-11-11 | 三菱瓦斯化学株式会社 | 化合物、(共)重合体、組成物、パターン形成方法、及び化合物の製造方法 |
KR20200124556A (ko) | 2019-04-24 | 2020-11-03 | 삼성전자주식회사 | 펠리클 조립체의 제조 방법 및 포토마스크 조립체의 제조 방법 |
US11215743B2 (en) * | 2020-03-05 | 2022-01-04 | Facebook Technologies, Llc | Achromatic optical device based on birefringent materials having positive and negative birefringence dispersions |
WO2021230300A1 (ja) * | 2020-05-15 | 2021-11-18 | 三菱瓦斯化学株式会社 | 化合物、(共)重合体、組成物、レジストパターン形成方法、並びに化合物及び(共)重合体の製造方法 |
Family Cites Families (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6279724B1 (en) | 1997-12-19 | 2001-08-28 | Semitoll Inc. | Automated semiconductor processing system |
US6139771A (en) | 1997-04-04 | 2000-10-31 | Displaytech, Inc. | Mesogenic materials with anomalous birefringence dispersion and high second order susceptibility (X.sup.(2)). |
JPH1090521A (ja) | 1996-07-24 | 1998-04-10 | Sumitomo Chem Co Ltd | 偏光軸回転積層位相差板およびこれを用いた投射型液晶表示装置 |
JPH1068816A (ja) | 1996-08-29 | 1998-03-10 | Sharp Corp | 位相差板及び円偏光板 |
JPH1152131A (ja) | 1997-08-01 | 1999-02-26 | Sumitomo Bakelite Co Ltd | 位相差板及びそれを用いた偏光素子 |
US6097368A (en) | 1998-03-31 | 2000-08-01 | Matsushita Electric Industrial Company, Ltd. | Motion pixel distortion reduction for a digital display device using pulse number equalization |
GB9815269D0 (en) * | 1998-07-14 | 1998-09-09 | Rolic Ag | Compositions |
DE19855757A1 (de) * | 1998-12-03 | 2000-06-21 | Merck Patent Gmbh | Querverbrückte Cyclohexan-Derivate und flüssigkristallines Medium |
JP4320125B2 (ja) | 2001-03-06 | 2009-08-26 | 富士フイルム株式会社 | 位相差膜 |
JP4608852B2 (ja) | 2002-10-15 | 2011-01-12 | チッソ株式会社 | 液晶性ビニルケトン誘導体およびその重合体 |
JP4747257B2 (ja) | 2003-06-03 | 2011-08-17 | Jnc株式会社 | 不飽和結合を有する重合性液晶性化合物およびその重合体 |
ATE487777T1 (de) | 2007-03-30 | 2010-11-15 | Merck Patent Gmbh | Doppelbrechungs-polymerfolie mit negativer optischer dispersion |
WO2008119426A1 (en) * | 2007-03-30 | 2008-10-09 | Merck Patent Gmbh | Birefingent layer with negative optical dispersion |
US8697199B2 (en) * | 2007-09-03 | 2014-04-15 | Merck Patent Gmbh | Calamitic mesogenic compounds |
JP5474800B2 (ja) * | 2007-09-25 | 2014-04-16 | メルク パテント ゲゼルシャフト ミット ベシュレンクテル ハフツング | メソゲンダイマー |
KR101051746B1 (ko) * | 2008-11-25 | 2011-07-25 | 주식회사 포스코 | 전기강판의 자구미세화방법 및 자구미세화 처리된 전기강판 |
JP5676447B2 (ja) * | 2008-08-18 | 2015-02-25 | メルク パテント ゲゼルシャフト ミット ベシュレンクテル ハフツングMerck Patent Gesellschaft mit beschraenkter Haftung | ディスコチックおよびカラミチック基を含むメソゲン化合物 |
KR20100098036A (ko) * | 2009-02-27 | 2010-09-06 | 에스케이에너지 주식회사 | 2개 이상의 메소젠이 일정한 결합각을 갖는 네마틱 액정화합물의 두께 방향으로의 배열이 하이브리드 형태를 갖는 광학 보상 필름 및 이의 제조방법 |
KR101106528B1 (ko) | 2009-06-30 | 2012-01-20 | 금오공과대학교 산학협력단 | 이 메소젠 구조를 갖는 액정화합물 |
JP2011042606A (ja) | 2009-08-20 | 2011-03-03 | Sumitomo Chemical Co Ltd | 化合物、光学フィルム及び光学フィルムの製造方法 |
KR101779226B1 (ko) * | 2009-10-30 | 2017-09-18 | 메르크 파텐트 게엠베하 | 음성 광학 분산도를 갖는 중합성 lc 물질 및 중합체 필름 |
US9206355B2 (en) * | 2012-04-20 | 2015-12-08 | Lg Chem, Ltd. | Polymerizable liquid crystal compound, polymerizable liquid crystal composition, and optically anisotropic body |
-
2013
- 2013-04-19 US US14/391,326 patent/US9206355B2/en active Active
- 2013-04-19 CN CN201380020983.9A patent/CN104245885B/zh active Active
- 2013-04-19 EP EP13778326.2A patent/EP2824162B1/en active Active
- 2013-04-19 WO PCT/KR2013/003346 patent/WO2013157888A1/ko active Application Filing
- 2013-04-19 JP JP2015506905A patent/JP6069487B2/ja active Active
- 2013-04-19 KR KR20130043281A patent/KR101363479B1/ko active IP Right Grant
-
2015
- 2015-08-07 US US14/821,370 patent/US9416317B2/en active Active
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20150105826A (ko) * | 2014-03-10 | 2015-09-18 | 단국대학교 천안캠퍼스 산학협력단 | 내부에 미세구조의 채널을 가지는 생분해성 신경도관 및 이의 제조방법 |
KR101683336B1 (ko) | 2014-03-10 | 2016-12-06 | 단국대학교 천안캠퍼스 산학협력단 | 내부에 미세구조의 채널을 가지는 생분해성 신경도관 및 이의 제조방법 |
Also Published As
Publication number | Publication date |
---|---|
WO2013157888A1 (ko) | 2013-10-24 |
JP2015516972A (ja) | 2015-06-18 |
US20160024385A1 (en) | 2016-01-28 |
KR101363479B1 (ko) | 2014-02-17 |
EP2824162A1 (en) | 2015-01-14 |
US9206355B2 (en) | 2015-12-08 |
US9416317B2 (en) | 2016-08-16 |
CN104245885B (zh) | 2016-09-07 |
KR20130118805A (ko) | 2013-10-30 |
EP2824162B1 (en) | 2018-12-12 |
US20150115199A1 (en) | 2015-04-30 |
CN104245885A (zh) | 2014-12-24 |
EP2824162A4 (en) | 2015-11-25 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP6069487B2 (ja) | 重合性液晶化合物、重合性液晶組成物および光学異方体 | |
JP5531419B2 (ja) | 化合物および該化合物を含む光学フィルム | |
KR101727918B1 (ko) | 광학 디바이스 또는 전기광학 디바이스용 에스테르 그룹 함유 액정 | |
KR102290811B1 (ko) | 중합체, 중합체 조성물 및 횡전계 구동형 액정 표시 소자용 액정 배향막 | |
KR102311484B1 (ko) | 편광 자외선 이방성화 재료 | |
KR20220048487A (ko) | 액정 배향제, 액정 배향막 및 액정 표시 소자 | |
CN110720064B (zh) | 聚合性液晶组合物及相位差板 | |
KR102448661B1 (ko) | 횡전계 구동형 액정 표시 소자용 액정 배향막 제조용 조성물, 그 조성물을 사용한 액정 배향막 및 그 제조 방법, 그리고 액정 배향막을 갖는 액정 표시 소자 및 그 제조 방법 | |
JP6877698B2 (ja) | 液晶配向剤、液晶配向膜、及び液晶表示素子 | |
JP2007191442A (ja) | 重合性液晶化合物、重合性液晶組成物及びこれの重合体 | |
KR20160007636A (ko) | 횡전계 구동형 액정 표시 소자용 액정 배향막을 갖는 기판의 제조 방법 | |
TWI644931B (zh) | 具有橫向電場驅動型液晶顯示元件用液晶配向膜之基板之製造方法 | |
TW201520313A (zh) | 聚合物組成物以及橫向電場驅動型液晶顯示元件用之液晶配向膜 | |
TW201731891A (zh) | 光配向膜用聚合物、聚合物溶液、光配向膜、光學異向體、及液晶顯示元件 | |
JP6042538B2 (ja) | 重合性液晶化合物、これを含む液晶組成物及び光学異方体 | |
KR101657677B1 (ko) | 중합성 액정 화합물, 중합성 액정 조성물, 광학 이방체, 및 디스플레이 장치용 광학 소자 | |
CN107924092B (zh) | 液晶取向膜制造用组合物、使用该组合物的液晶取向膜及其制造方法、以及具有液晶取向膜的液晶表示元件及其制造方法 | |
TW202018338A (zh) | 偏光板及液晶顯示裝置 | |
KR101990057B1 (ko) | 역 파장 분산성 화합물, 이를 포함하는 역 파장 분산성 조성물 및 광학 이방체 | |
KR101659073B1 (ko) | 중합성 액정 화합물, 이를 포함하는 액정 조성물 및 광학 이방체 | |
JP2007017960A (ja) | 非線形光学材料用組成物、光学部材、非線形光学材料およびその製造方法 | |
KR101659071B1 (ko) | 중합성 액정 화합물, 이를 포함하는 액정 조성물 및 광학 이방체 | |
CN108369358B (zh) | 液晶取向膜制造用组合物、使用该组合物的液晶取向膜和其制造方法、以及具有液晶取向膜的液晶表示元件和其制造方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20160225 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20160328 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20160627 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20161205 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20161226 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 6069487 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |