JP6019034B2 - 多価不飽和化合物の金属触媒モノヒドロシリル化 - Google Patents

多価不飽和化合物の金属触媒モノヒドロシリル化 Download PDF

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JP6019034B2
JP6019034B2 JP2013541003A JP2013541003A JP6019034B2 JP 6019034 B2 JP6019034 B2 JP 6019034B2 JP 2013541003 A JP2013541003 A JP 2013541003A JP 2013541003 A JP2013541003 A JP 2013541003A JP 6019034 B2 JP6019034 B2 JP 6019034B2
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formula
trivinylcyclohexane
group
alkyl
independently
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JP2014502271A5 (enExample
JP2014502271A (ja
Inventor
ルイス，ケンリック，エム
トンドロー，アーロン，エム
クルーズ，リチャード，ダブリュー
ウェラー，キース，ジェイ
デリス，ヨハネス，ゲー．ペー．
ナイ，スーザン，エイ
チリク，ポール，ジェイ
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Cornell University
Momentive Performance Materials Inc
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Cornell University
Momentive Performance Materials Inc
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B61/00—Other general methods
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/02—Iron compounds
    • C07F15/025—Iron compounds without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/18—Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
JP2013541003A 2010-11-24 2011-11-22 多価不飽和化合物の金属触媒モノヒドロシリル化 Active JP6019034B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US41706110P 2010-11-24 2010-11-24
US61/417,061 2010-11-24
PCT/US2011/061752 WO2012071360A1 (en) 2010-11-24 2011-11-22 Metal - catalyzed mono - hydrosilylation of polyunsaturated compounds

Publications (3)

Publication Number Publication Date
JP2014502271A JP2014502271A (ja) 2014-01-30
JP2014502271A5 JP2014502271A5 (enExample) 2015-01-29
JP6019034B2 true JP6019034B2 (ja) 2016-11-02

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JP2013541003A Active JP6019034B2 (ja) 2010-11-24 2011-11-22 多価不飽和化合物の金属触媒モノヒドロシリル化

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Country Link
US (1) US8895770B2 (enExample)
EP (1) EP2643330B1 (enExample)
JP (1) JP6019034B2 (enExample)
KR (1) KR101896423B1 (enExample)
CN (1) CN103732599B (enExample)
BR (1) BR112013012734A2 (enExample)
TW (1) TWI457176B (enExample)
WO (1) WO2012071360A1 (enExample)

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JP6101695B2 (ja) 2011-09-20 2017-03-22 ダウ コーニング コーポレーションＤｏｗ Ｃｏｒｎｉｎｇ Ｃｏｒｐｏｒａｔｉｏｎ ニッケル含有ヒドロシリル化触媒及びその触媒を含有する組成物
WO2013081794A1 (en) 2011-12-01 2013-06-06 Dow Corning Corporation Hydrosilylation reaction catalysts and curable compositions and methods for their preparation and use
US9782763B2 (en) 2011-12-14 2017-10-10 Momentive Performance Materials Inc. Non-precious metal-based hyrdosilylation catalysts exhibiting improved selectivity
US9371340B2 (en) 2012-08-16 2016-06-21 Momentive Performance Materials Inc. Dehydrogenative silylation, hydrosilylation and crosslinking using cobalt catalysts
US9447125B2 (en) 2012-08-16 2016-09-20 Momentive Performance Materials Inc. Reusable homogeneous cobalt pyridine diimine catalysts for dehydrogenative silylation and tandem dehydrogenative-silylation-hydrogenation
US9890182B2 (en) 2013-05-06 2018-02-13 Momentive Performance Materials Inc. Selective 1,2-hydrosilylation of terminally unsaturated 1,3-dienes using iron catalysts
US9371339B2 (en) 2013-05-06 2016-06-21 Momentive Performance Materials Inc. Saturated and unsaturated silahydrocarbons via iron and cobalt pyridine diimine catalyzed olefin silylation
WO2014186513A1 (en) 2013-05-15 2014-11-20 Momentive Performance Materials Inc. Activation of metal salts with silylhydrides and their use in hydrosilylation reactions
JP6486925B2 (ja) 2013-11-19 2019-03-20 モメンティブ パフォーマンス マテリアルズ インコーポレイテッド コバルト触媒並びにヒドロシリル化及び脱水素シリル化のためのその使用
WO2015077344A1 (en) 2013-11-19 2015-05-28 The Trustees Of Princeton University Hydroboration and borylation with cobalt catalysts
JP6486924B2 (ja) * 2013-11-19 2019-03-20 モメンティブ パフォーマンス マテリアルズ インコーポレイテッド コバルト触媒並びにヒドロシリル化及び脱水素シリル化のためのその使用
WO2015171881A1 (en) * 2014-05-08 2015-11-12 Momentive Performance Materials Inc. Dialkyl cobalt catalysts and their use for hydrosilylation and dehydrogenative silylation
JP2015231965A (ja) * 2014-06-10 2015-12-24 国立研究開発法人産業技術総合研究所 有機ケイ素化合物の製造方法及び触媒組成物
EP3195932B1 (en) 2014-08-12 2024-08-21 Kyushu University, National University Corporation Hydrosilylation reaction catalyst
EP3181226B1 (en) 2014-08-12 2024-08-07 Kyushu University, National University Corporation Hydrosilylation reaction catalyst
JP6761997B2 (ja) 2014-08-19 2020-09-30 国立大学法人九州大学 ヒドロシリル化鉄触媒
US20180200703A1 (en) 2015-07-14 2018-07-19 Kyushu University, National University Corporation Hydrosilylation reaction catalyst
JP6846423B2 (ja) * 2015-07-24 2021-03-24 モメンティブ パフォーマンス マテリアルズ インコーポレイテッドＭｏｍｅｎｔｉｖｅ Ｐｅｒｆｏｒｍａｎｃｅ Ｍａｔｅｒｉａｌｓ Ｉｎｃ． ピリジンジイミンコバルトカルボキシレート触媒を用いた脱水素シリル化、ヒドロシリル化および架橋
KR101728308B1 (ko) 2015-09-14 2017-04-19 기초과학연구원 비전이금속 촉매법 수소규소화 반응을 이용한 규소 고분자 제조방법
CN108473514B (zh) 2016-01-22 2021-08-31 信越化学工业株式会社 新型异腈化合物和氢化硅烷化反应催化剂
WO2018159595A1 (ja) 2017-02-28 2018-09-07 国立大学法人九州大学 ヒドロシリル化反応、水素化反応およびヒドロシラン還元反応用触媒
JP2019064950A (ja) 2017-09-29 2019-04-25 国立大学法人九州大学 コバルト錯体、その製造方法およびヒドロシリル化反応用触媒

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FR2641785B1 (fr) 1989-01-19 1992-07-31 Essilor Int Composition de polymeres transparents pour lentilles de contact de type rigide, permeables a l'oxygene
US5691435A (en) * 1996-01-25 1997-11-25 Wacker-Chemie Gmbh Crosslinkable compositions
US5756795A (en) * 1996-12-30 1998-05-26 Dow Corning Corporation Unsaturated accelerators for hydrosilation
US5986022A (en) * 1998-04-01 1999-11-16 Witco Corporation Continuous manufacture of silicone coploymers
GB9819847D0 (en) 1998-09-12 1998-11-04 Bp Chem Int Ltd Novel compounds
DE19856115A1 (de) 1998-12-04 2000-06-21 Wacker Chemie Gmbh Alkenylgruppen aufweisende Siloxancopolymere
US6278011B1 (en) 1999-08-30 2001-08-21 The University Of Dayton Polysilahydrocarbons as lubricants for aerospace application
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US7696269B2 (en) 2006-12-28 2010-04-13 Momentive Performance Materials Inc. Silated core polysulfides, their preparation and use in filled elastomer compositions
US8236915B2 (en) 2009-07-10 2012-08-07 Momentive Performance Materials Inc. Hydrosilylation catalysts
US8415443B2 (en) * 2009-07-10 2013-04-09 Momentive Performance Materials Inc. Hydrosilylation catalysts
WO2012071358A2 (en) * 2010-11-24 2012-05-31 Momentive Performance Materials Inc. In-situ activation of metal complexes containing terdentate nitrogen ligands used as hydrosilylation catalysts

Also Published As

Publication number Publication date
CN103732599B (zh) 2016-09-14
CN103732599A (zh) 2014-04-16
BR112013012734A2 (pt) 2016-09-13
WO2012071360A1 (en) 2012-05-31
US20120130105A1 (en) 2012-05-24
TWI457176B (zh) 2014-10-21
KR101896423B1 (ko) 2018-10-04
US8895770B2 (en) 2014-11-25
KR20140035318A (ko) 2014-03-21
JP2014502271A (ja) 2014-01-30
EP2643330A1 (en) 2013-10-02
EP2643330B1 (en) 2017-01-04
TW201235102A (en) 2012-09-01

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