CN103732599B - 多不饱和化合物的金属催化的单-氢化硅烷化 - Google Patents

多不饱和化合物的金属催化的单-氢化硅烷化 Download PDF

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Publication number
CN103732599B
CN103732599B CN201180065872.0A CN201180065872A CN103732599B CN 103732599 B CN103732599 B CN 103732599B CN 201180065872 A CN201180065872 A CN 201180065872A CN 103732599 B CN103732599 B CN 103732599B
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formula
sio
silyl hydride
alkyl
hydrosilylation
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Chinese (zh)
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CN103732599A (zh
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K.M.刘易斯
A.M.唐德里奥
R.W.克鲁斯
K.J.韦勒
J.G.P.德利斯
S.A.奈
P.J.奇里克
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Cornell University
General Electric Co
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Cornell University
General Electric Co
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B61/00—Other general methods
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/02—Iron compounds
    • C07F15/025—Iron compounds without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/18—Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
CN201180065872.0A 2010-11-24 2011-11-22 多不饱和化合物的金属催化的单-氢化硅烷化 Active CN103732599B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US41706110P 2010-11-24 2010-11-24
US61/417,061 2010-11-24
PCT/US2011/061752 WO2012071360A1 (en) 2010-11-24 2011-11-22 Metal - catalyzed mono - hydrosilylation of polyunsaturated compounds

Publications (2)

Publication Number Publication Date
CN103732599A CN103732599A (zh) 2014-04-16
CN103732599B true CN103732599B (zh) 2016-09-14

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US (1) US8895770B2 (enExample)
EP (1) EP2643330B1 (enExample)
JP (1) JP6019034B2 (enExample)
KR (1) KR101896423B1 (enExample)
CN (1) CN103732599B (enExample)
BR (1) BR112013012734A2 (enExample)
TW (1) TWI457176B (enExample)
WO (1) WO2012071360A1 (enExample)

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EP2758416B8 (en) 2011-09-20 2018-08-01 Dow Silicones Corporation Nickel containing hydrosilylation catalysts and compositions containing the catalysts
EP2785454B1 (en) 2011-12-01 2019-10-09 Dow Silicones Corporation Hydrosilylation reaction catalysts and curable compositions and methods for their preparation and use
US9782763B2 (en) 2011-12-14 2017-10-10 Momentive Performance Materials Inc. Non-precious metal-based hyrdosilylation catalysts exhibiting improved selectivity
US9371340B2 (en) 2012-08-16 2016-06-21 Momentive Performance Materials Inc. Dehydrogenative silylation, hydrosilylation and crosslinking using cobalt catalysts
US9447125B2 (en) 2012-08-16 2016-09-20 Momentive Performance Materials Inc. Reusable homogeneous cobalt pyridine diimine catalysts for dehydrogenative silylation and tandem dehydrogenative-silylation-hydrogenation
US9890182B2 (en) 2013-05-06 2018-02-13 Momentive Performance Materials Inc. Selective 1,2-hydrosilylation of terminally unsaturated 1,3-dienes using iron catalysts
US9371339B2 (en) 2013-05-06 2016-06-21 Momentive Performance Materials Inc. Saturated and unsaturated silahydrocarbons via iron and cobalt pyridine diimine catalyzed olefin silylation
CN105228744B (zh) 2013-05-15 2021-04-06 莫门蒂夫性能材料股份有限公司 用甲硅烷基氢化物活化金属盐及其在氢化硅烷化反应中的应用
WO2015077304A1 (en) * 2013-11-19 2015-05-28 Momentive Performance Materials Inc. Cobalt catalysts and their use for hydrosilylation and dehydrogenative silylation
JP2016540753A (ja) 2013-11-19 2016-12-28 モメンティブ パフォーマンス マテリアルズ インコーポレイテッド コバルト触媒並びにヒドロシリル化及び脱水素シリル化のためのそれらの使用
EP3071584B1 (en) 2013-11-19 2017-11-08 Momentive Performance Materials Inc. Cobalt catalysts and their use for hydrosilylation and dehydrogenative silylation
JP2017520519A (ja) * 2014-05-08 2017-07-27 モメンティブ パフォーマンス マテリアルズ インコーポレイテッド ジアルキルコバルト触媒並びにヒドロシリル化および脱水素シリル化のためのそれらの使用
JP2015231965A (ja) * 2014-06-10 2015-12-24 国立研究開発法人産業技術総合研究所 有機ケイ素化合物の製造方法及び触媒組成物
CN106660031A (zh) 2014-08-12 2017-05-10 国立大学法人九州大学 氢化硅烷化反应催化剂
EP3195932B1 (en) 2014-08-12 2024-08-21 Kyushu University, National University Corporation Hydrosilylation reaction catalyst
JP6761997B2 (ja) 2014-08-19 2020-09-30 国立大学法人九州大学 ヒドロシリル化鉄触媒
WO2017010366A1 (ja) 2015-07-14 2017-01-19 国立大学法人九州大学 ヒドロシリル化反応触媒
EP3325492B1 (en) * 2015-07-24 2019-09-18 Momentive Performance Materials Inc. Dehydrogenative silylation, hydrosilylation and crosslinking using pyridinediimine cobalt carboxylate catalysts
KR101728308B1 (ko) 2015-09-14 2017-04-19 기초과학연구원 비전이금속 촉매법 수소규소화 반응을 이용한 규소 고분자 제조방법
WO2017126562A1 (ja) 2016-01-22 2017-07-27 信越化学工業株式会社 新規イソシアニド化合物及びヒドロシリル化反応触媒
JP6786034B2 (ja) 2017-02-28 2020-11-18 国立大学法人九州大学 ヒドロシリル化反応、水素化反応およびヒドロシラン還元反応用触媒
JP2019064950A (ja) 2017-09-29 2019-04-25 国立大学法人九州大学 コバルト錯体、その製造方法およびヒドロシリル化反応用触媒

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US5691435A (en) * 1996-01-25 1997-11-25 Wacker-Chemie Gmbh Crosslinkable compositions
CN101668765A (zh) * 2006-12-28 2010-03-10 莫门蒂夫性能材料股份有限公司 硅烷化核多硫化物，其制备和在填充的弹性体组合物中的应用
WO2011006044A2 (en) * 2009-07-10 2011-01-13 Momentive Performance Materials Inc. Hydrosilylation catalysts
WO2011006049A1 (en) * 2009-07-10 2011-01-13 Momentive Performance Materials Inc. Hydrosilylation catalysts

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US5756795A (en) * 1996-12-30 1998-05-26 Dow Corning Corporation Unsaturated accelerators for hydrosilation
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US5691435A (en) * 1996-01-25 1997-11-25 Wacker-Chemie Gmbh Crosslinkable compositions
CN101668765A (zh) * 2006-12-28 2010-03-10 莫门蒂夫性能材料股份有限公司 硅烷化核多硫化物，其制备和在填充的弹性体组合物中的应用
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US20120130105A1 (en) 2012-05-24
BR112013012734A2 (pt) 2016-09-13
TWI457176B (zh) 2014-10-21
JP2014502271A (ja) 2014-01-30
WO2012071360A1 (en) 2012-05-31
TW201235102A (en) 2012-09-01
US8895770B2 (en) 2014-11-25
KR101896423B1 (ko) 2018-10-04
EP2643330B1 (en) 2017-01-04
EP2643330A1 (en) 2013-10-02
KR20140035318A (ko) 2014-03-21
JP6019034B2 (ja) 2016-11-02
CN103732599A (zh) 2014-04-16

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