JP6002965B2 - 反射防止塗料組成物及び反射防止フィルム - Google Patents
反射防止塗料組成物及び反射防止フィルム Download PDFInfo
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- JP6002965B2 JP6002965B2 JP2012119631A JP2012119631A JP6002965B2 JP 6002965 B2 JP6002965 B2 JP 6002965B2 JP 2012119631 A JP2012119631 A JP 2012119631A JP 2012119631 A JP2012119631 A JP 2012119631A JP 6002965 B2 JP6002965 B2 JP 6002965B2
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- monomer
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- UZKWTJUDCOPSNM-UHFFFAOYSA-N methoxybenzene Substances CCCCOC=C UZKWTJUDCOPSNM-UHFFFAOYSA-N 0.000 description 1
- ACEONLNNWKIPTM-UHFFFAOYSA-N methyl 2-bromopropanoate Chemical compound COC(=O)C(C)Br ACEONLNNWKIPTM-UHFFFAOYSA-N 0.000 description 1
- JLEJCNOTNLZCHQ-UHFFFAOYSA-N methyl 2-chloropropanoate Chemical compound COC(=O)C(C)Cl JLEJCNOTNLZCHQ-UHFFFAOYSA-N 0.000 description 1
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 1
- PJUIMOJAAPLTRJ-UHFFFAOYSA-N monothioglycerol Chemical compound OCC(O)CS PJUIMOJAAPLTRJ-UHFFFAOYSA-N 0.000 description 1
- UUORTJUPDJJXST-UHFFFAOYSA-N n-(2-hydroxyethyl)prop-2-enamide Chemical compound OCCNC(=O)C=C UUORTJUPDJJXST-UHFFFAOYSA-N 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000003136 n-heptyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 229910017464 nitrogen compound Inorganic materials 0.000 description 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- JFNLZVQOOSMTJK-KNVOCYPGSA-N norbornene Chemical compound C1[C@@H]2CC[C@H]1C=C2 JFNLZVQOOSMTJK-KNVOCYPGSA-N 0.000 description 1
- 150000002848 norbornenes Chemical class 0.000 description 1
- ZMHZSHHZIKJFIR-UHFFFAOYSA-N octyltin Chemical compound CCCCCCCC[Sn] ZMHZSHHZIKJFIR-UHFFFAOYSA-N 0.000 description 1
- 150000002902 organometallic compounds Chemical class 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- UKODFQOELJFMII-UHFFFAOYSA-N pentamethyldiethylenetriamine Chemical compound CN(C)CCN(C)CCN(C)C UKODFQOELJFMII-UHFFFAOYSA-N 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 125000005496 phosphonium group Chemical group 0.000 description 1
- 125000004437 phosphorous atom Chemical group 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 239000003504 photosensitizing agent Substances 0.000 description 1
- DOIRQSBPFJWKBE-UHFFFAOYSA-N phthalic acid di-n-butyl ester Natural products CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 1
- 229920003207 poly(ethylene-2,6-naphthalate) Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920001748 polybutylene Polymers 0.000 description 1
- 229920001707 polybutylene terephthalate Polymers 0.000 description 1
- 229920006289 polycarbonate film Polymers 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920006267 polyester film Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 239000011112 polyethylene naphthalate Substances 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 239000002952 polymeric resin Substances 0.000 description 1
- 229920000193 polymethacrylate Chemical class 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 238000001226 reprecipitation Methods 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- YXDPTMVPGTZYAZ-UHFFFAOYSA-N ruthenium tributylphosphane Chemical compound [Ru].CCCCP(CCCC)CCCC YXDPTMVPGTZYAZ-UHFFFAOYSA-N 0.000 description 1
- VIHDTGHDWPVSMM-UHFFFAOYSA-N ruthenium;triphenylphosphane Chemical compound [Ru].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 VIHDTGHDWPVSMM-UHFFFAOYSA-N 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229910052717 sulfur Chemical group 0.000 description 1
- 125000004434 sulfur atom Chemical group 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 229910052714 tellurium Inorganic materials 0.000 description 1
- PORWMNRCUJJQNO-UHFFFAOYSA-N tellurium atom Chemical compound [Te] PORWMNRCUJJQNO-UHFFFAOYSA-N 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- IBWGNZVCJVLSHB-UHFFFAOYSA-M tetrabutylphosphanium;chloride Chemical compound [Cl-].CCCC[P+](CCCC)(CCCC)CCCC IBWGNZVCJVLSHB-UHFFFAOYSA-M 0.000 description 1
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 229940035024 thioglycerol Drugs 0.000 description 1
- YRHRIQCWCFGUEQ-UHFFFAOYSA-N thioxanthen-9-one Chemical compound C1=CC=C2C(=O)C3=CC=CC=C3SC2=C1 YRHRIQCWCFGUEQ-UHFFFAOYSA-N 0.000 description 1
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 150000005671 trienes Chemical class 0.000 description 1
- RXJKFRMDXUJTEX-UHFFFAOYSA-N triethylphosphine Chemical compound CCP(CC)CC RXJKFRMDXUJTEX-UHFFFAOYSA-N 0.000 description 1
- ITMCEJHCFYSIIV-UHFFFAOYSA-M triflate Chemical compound [O-]S(=O)(=O)C(F)(F)F ITMCEJHCFYSIIV-UHFFFAOYSA-M 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
- 239000003021 water soluble solvent Substances 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
- RUDFQVOCFDJEEF-UHFFFAOYSA-N yttrium(III) oxide Inorganic materials [O-2].[O-2].[O-2].[Y+3].[Y+3] RUDFQVOCFDJEEF-UHFFFAOYSA-N 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Laminated Bodies (AREA)
Description
測定装置:東ソー株式会社製「HLC−8220 GPC」、
カラム:東ソー株式会社製ガードカラム「HHR−H」(6.0mmI.D.×4cm)
+東ソー株式会社製「TSK−GEL GMHHR−N」(7.8mmI.D.×30cm)
+東ソー株式会社製「TSK−GEL GMHHR−N」(7.8mmI.D.×30cm)
+東ソー株式会社製「TSK−GEL GMHHR−N」(7.8mmI.D.×30cm)
+東ソー株式会社製「TSK−GEL GMHHR−N」(7.8mmI.D.×30cm)
検出器:ELSD(オルテックジャパン株式会社製「ELSD2000」)
データ処理:東ソー株式会社製「GPC−8020モデルIIデータ解析バージョン4.30」
測定条件:カラム温度 40℃
展開溶媒 テトラヒドロフラン(THF)
流速 1.0ml/分
試料:樹脂固形分換算で1.0質量%のテトラヒドロフラン溶液をマイクロフィルターでろ過したもの(5μl)。
標準試料:前記「GPC−8020モデルIIデータ解析バージョン4.30」の測定マニュアルに準拠して、分子量が既知の下記の単分散ポリスチレンを用いた。
東ソー株式会社製「A−500」
東ソー株式会社製「A−1000」
東ソー株式会社製「A−2500」
東ソー株式会社製「A−5000」
東ソー株式会社製「F−1」
東ソー株式会社製「F−2」
東ソー株式会社製「F−4」
東ソー株式会社製「F−10」
東ソー株式会社製「F−20」
東ソー株式会社製「F−40」
東ソー株式会社製「F−80」
東ソー株式会社製「F−128」
東ソー株式会社製「F−288」
東ソー株式会社製「F−550」
(1)まず基材にハードコート材を塗布・硬化してハードコート層の塗膜を形成する。
(2)上記のハードコート層に本発明の反射防止塗料組成物を塗布・硬化して低屈折率層の塗膜を形成する。この低屈折率層が反射防止フィルムの最表面となる。
なお、上記ハードコート層と低屈折率層との間に、中屈折率層及び/又は高屈折率層を設けても構わない。
測定装置:東ソー株式会社製「HLC−8220 GPC」、
カラム:東ソー株式会社製ガードカラム「HHR−H」(6.0mmI.D.×4cm)
+東ソー株式会社製「TSK−GEL GMHHR−N」(7.8mmI.D.×30cm)
+東ソー株式会社製「TSK−GEL GMHHR−N」(7.8mmI.D.×30cm)
+東ソー株式会社製「TSK−GEL GMHHR−N」(7.8mmI.D.×30cm)
+東ソー株式会社製「TSK−GEL GMHHR−N」(7.8mmI.D.×30cm)
検出器:ELSD(オルテックジャパン株式会社製「ELSD2000」)
データ処理:東ソー株式会社製「GPC−8020モデルIIデータ解析バージョン4.30」
測定条件:カラム温度 40℃
展開溶媒 テトラヒドロフラン(THF)
流速 1.0ml/分
試料:樹脂固形分換算で1.0質量%のテトラヒドロフラン溶液をマイクロフィルターでろ過したもの(5μl)。
標準試料:前記「GPC−8020モデルIIデータ解析バージョン4.30」の測定マニュアルに準拠して、分子量が既知の下記の単分散ポリスチレンを用いた。
東ソー株式会社製「A−500」
東ソー株式会社製「A−1000」
東ソー株式会社製「A−2500」
東ソー株式会社製「A−5000」
東ソー株式会社製「F−1」
東ソー株式会社製「F−2」
東ソー株式会社製「F−4」
東ソー株式会社製「F−10」
東ソー株式会社製「F−20」
東ソー株式会社製「F−40」
東ソー株式会社製「F−80」
東ソー株式会社製「F−128」
東ソー株式会社製「F−288」
東ソー株式会社製「F−550」
撹拌装置、温度計、冷却管、滴下装置を備えたガラスフラスコに、溶媒としてメチルイソブチルケトン50.4gを仕込み、窒素気流下にて攪拌しながら90℃に昇温した。次いで、2−(トリデカフルオロヘキシル)エチルメタクリレート44.1gと、3−ヒドロキシ−1−アダマンチルメタクリレート59.1gをメチルイソブチルケトン167.4gに溶解したモノマー溶液と、ラジカル重合開始剤としてt−ブチルペルオキシ−2−エチルヘキサノエート6.2gをメチルイソブチルケトン23.2gに溶解した重合開始剤溶液との2種類の滴下液をそれぞれ別々の滴下装置にセットし、フラスコ内を90℃に保ちながら同時に2時間かけて滴下した。滴下終了後、90℃で9時間攪拌後、減圧下で溶媒172.0部を留去することによって、重合体(P−1)溶液を得た。
窒素置換したフラスコに、溶剤として2−プロパノール30.3gと、3−ヒドロキシ−1−アダマンチルメタクリレート20.0gを仕込み、窒素気流下にて攪拌しながら40℃に昇温した。次いで、2,2’−ビピリジル2.5g、塩化第一銅0.79gを仕込み、フラスコ内を40℃に保ちながら30分撹拌した。その後、2−ブロモイソ酪酸エチル1.57gを加え、窒素気流下、40℃で5時間反応させた。次いで、2−プロパノール49.3g、2−(トリデカフルオロヘキシル)エチルメタクリレート14.6gと、3−ヒドロキシ−1−アダマンチルメタクリレート20.0gを加え、40℃で5時間反応させた後、60℃に昇温して8時間反応させた。この反応混合物をメタノールに溶かし、水/メタノールで再沈殿精製して共重合体を得た。この共重合体41.4gをメチルイソブチルケトン41.4gに溶解させ、オクチル酸錫0.02g、重合禁止剤(p−メトキシフェノール)0.1gを加えて60℃に昇温した。液中に乾燥空気を導入しながら、2−アクリロイルオキシエチルイソシアネート17.7gを滴下し、2時間反応し、80℃まで昇温した後にさらに4時間反応させ、メチルイソブチルケトンを加えることでフッ素含有率40質量%の重合性樹脂(III−2)の溶液を得た。重合性樹脂(III−2)の分子量をGPCで測定した結果、重量平均分子量8,500、数平均分子量6,400であった。また、原料仕込比から計算したフッ素原子含有量は11%、アダマンタン含有量は28%、ラジカル重合性不飽和基当量は472g/eq.であった。
撹拌装置、温度計、冷却管、滴下装置を備えたガラスフラスコに、溶媒としてメチルイソブチルケトン55gを仕込み、窒素気流下にて攪拌しながら90℃に昇温した。次いで、(2−トリデカフルオロヘキシル)エチルメタクリレート35gと、2−ヒドロキシエチルメタクリレート31.2gをメチルイソブチルケトン37.3gに溶解したモノマー溶液と、ラジカル重合開始剤としてt−ブチルペルオキシ−2−エチルヘキサノエート4gをメチルイソブチルケトン4gに溶解した重合開始剤溶液との2種類の滴下液をそれぞれ別々の滴下装置にセットし、フラスコ内を90℃に保ちながら同時に2時間かけて滴下した。滴下終了後、90℃で9時間攪拌して重合体(P´−1)溶液を得た。
<反射防止塗料組成物の調製>
中空シリカ微粒子(平均粒子径50nm)を20質量%含有するメチルイソブチルケトン分散液15質量部、ペンタエリスリトールトリアクリレート1.6質量部、光重合開始剤として2−ヒドロキシ−1−{4−[4−(2−ヒドロキシ−2−メチル−プロピオニル)−ベンジル]−フェニル}−2−メチル−プロパン−1−オン(チバ・ジャパン株式会社製「イルガキュア127」)0.1質量部、溶剤としてメチルイソブチルケトン81.8質量部を混合し溶解させて、反射防止塗料組成物のベース組成物を得た。
5官能無黄変型ウレタンアクリレート50質量部、ジペンタエリスリトールヘキサアクリレート50質量部、酢酸ブチル25質量部、光重合開始剤として1−ヒドロキシシクロヘキシルフェニルケトン(チバスペシャリティーケミカルズ社製「イルガキュア184」)5質量部、溶剤としてトルエン54質量部、2−プロパノール28質量部、酢酸エチル28質量部、プロピレングリコールモノメチルエーテル28質量部を混合し溶解させて、ハードコート層用塗料組成物を得た。
黒色の板上に上記で得た反射防止フィルムを置き、反射防止塗料組成物の硬化塗膜の白化の有無を目視で観察し、下記の基準で外観を評価した。評価結果を第1表に示す。
○:白化が生じていないもの。
×:白化が生じているもの。
トライボギア HEIDON 往復磨耗試験機 TYPE:30S(新東科学株式会社製)を用いて、直径27mmの円形の治具にボンスター No,0000(日本スチールウール株式会社製)を取り付けた磨耗試験機(500g/cm2荷重)にて、30往復磨耗させて試験を行った。試験後の塗膜表面に付いた傷の本数を数えて、下記の基準によって耐擦傷性を評価した。
◎:傷の本数が5本未満である。
○:傷の本数が5本以上10本未満である。
△:傷の本数が10本以上50本未満である。
×:傷の本数が50本以上である。
上記で得た反射防止フィルムの反射防止塗料組成物の硬化塗膜の表面に指で指紋を付着させ、ティッシュペーパーで10往復拭き取ったときの拭き取り具合を目視で観察し、下記の基準で指紋汚れ拭き取り性を評価した。
◎:指紋が完全に拭き取れるもの。
○:指紋の付着跡、又は、拭き取り方向に沿って線状の跡が、付着時に比べわずかに残ったもの。
×:指紋の付着跡、又は、拭き取り方向に沿って線状の跡が、付着時の半分以上の濃さで残ったもの。
5℃正反射測定装置を備えた分光光度計(株式会社島津製作所製「UV−3100PC」)を用いて反射率の測定を行った。なお、反射率は波長550nm付近で極小値(最低反射率)となったときの値とした。
上記で得られた反射防止フィルムを、70℃に加温した2.0mol/Lの水酸化カリウム水溶液に1分間浸漬させ、水洗後、100℃で3分間乾燥させて、強アルカリ処理を行った。
実施例1で用いた重合性樹脂(III−1)の40%含有溶液に代えて重合性樹脂(III−2)の20%含有溶液を樹脂分として0.4質量部となるように添加した以外は実施例1と同様に操作して、評価を行った。評価結果を第1表に示す。
実施例1で用いた重合性樹脂(III−1)の40%含有溶液に代えて、比較対照用重合性樹脂(III´)40質量%含有溶液を樹脂分として0.4質量部となるように添加した以外は実施例1と同様に操作して、評価を行った。評価結果を第1表に示す。
実施例1で用いた重合性樹脂(III−1)の40%含有溶液に代えて、シリコーンオイル(チッソ株式会社製「サイラプレーンFM−4421」、ポリジメチルシロキサン鎖の両末端に−C3H6OC2H4OHを有するもの)を50質量%含有するメチルイソブチルケトン溶液を0.8質量部(樹脂分として0.4質量部)添加した以外は実施例1と同様に操作して、評価を行った。評価結果を第1表に示す。
実施例1で用いた重合性樹脂(III−1)の40%含有溶液に代えて、ジメチルシロキサン鎖を有する4官能アクリレート(ビックケミー・ジャパン株式会社製「BYK−UV3570」)を50質量%含有するメチルイソブチルケトン溶液を0.8質量部(樹脂分として0.4質量部)添加した以外は実施例1と同様に操作して、評価を行った。評価結果を第1表に示す。
実施例1で調製した活性エネルギー線硬化性組成物のベース樹脂組成物に、何も添加せずに実施例1と同様に操作して、評価を行った。評価結果を第1表に示す。
Claims (7)
- 低屈折率剤(I)、活性エネルギー線硬化性化合物(II)、及び
下記式(Rf−1)〜(Rf−4)
の何れかの基を有する重合性不飽和単量体(A)と、反応性官能基(b1)を持つアダマンチル基を有する重合性不飽和単量体(B1)とを必須の単量体成分とする重合体(P1)と、前記官能基(b1)に対して反応性を有する官能基(c)及び重合性不飽和基を有する化合物(C)と、の反応物、または、
下記式(Rf−1)〜(Rf−4)
の何れかの基を有する重合性不飽和単量体(A)と、反応性官能基(b1)を持つアダマンチル基を有する重合性不飽和単量体(B1)又は反応性官能基(b1)を持たないアダマンチル基を有する重合性不飽和単量体(B2)と、前記(B1)以外の反応性官能基(b3)を有する重合性不飽和単量体(B3)と、を必須の単量体成分とする重合体(P2)と、
前記官能基(b1)又は前記官能基(b3)に対して反応性を有する官能基(c)及び重合性不飽和基を有する1種以上の化合物(C)との反応物である、
活性エネルギー線硬化性化合物(II)以外の重合性樹脂(III)、を含有することを特徴とする反射防止塗料組成物。 - 前記反応性官能基(b1)または反応性官能基(b3)が、水酸基、イソシアネート基、エポキシ基、カルボキシル基、カルボン酸ハライド基及び酸無水物基からなる群から選ばれる少なくとも1つの官能基であり、前記化合物(C)が有する官能基(c)が、前記反応性官能基(b1)又は反応性官能基(b3)と反応性を有し、かつ水酸基、イソシアネート基、エポキシ基、カルボキシル基、カルボン酸ハライド基及び酸無水物基からなる群から選ばれる少なくとも1つの官能基である請求項1記載の反射防止塗料組成物。
- 化合物(A)と単量体(B1)との質量比〔(A)/(B1)〕または化合物(A)と、単量体(B2)との質量比〔[(A)]/(B2)〕が8/92〜70/30の範囲である請求項1記載の反射防止塗料組成物。
- 前記低屈折率剤(I)が中空シリカ微粒子である請求項1記載の反射防止塗料組成物。
- 前記低屈折率剤(I)及び活性エネルギー線硬化性化合物(II)の合計100質量部に対して、前記重合性樹脂(III)を0.1〜20質量部含有する請求項1〜4のいずれか1項記載の反射防止塗料組成物。
- 請求項1〜5のいずれか1項記載の反射防止塗料組成物の硬化塗膜を有することを特徴とする反射防止フィルム。
- 前記硬化塗膜の膜厚が50〜300nmである請求項6記載の反射防止フィルム。
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