JP5992764B2 - ルテニウム錯体からなる化学蒸着原料及びその製造方法並びに化学蒸着方法 - Google Patents
ルテニウム錯体からなる化学蒸着原料及びその製造方法並びに化学蒸着方法 Download PDFInfo
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- JP5992764B2 JP5992764B2 JP2012181329A JP2012181329A JP5992764B2 JP 5992764 B2 JP5992764 B2 JP 5992764B2 JP 2012181329 A JP2012181329 A JP 2012181329A JP 2012181329 A JP2012181329 A JP 2012181329A JP 5992764 B2 JP5992764 B2 JP 5992764B2
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- ruthenium
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- polyene
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- 239000012327 Ruthenium complex Substances 0.000 title claims description 48
- 238000005229 chemical vapour deposition Methods 0.000 title claims description 38
- 238000000034 method Methods 0.000 title claims description 25
- 238000004519 manufacturing process Methods 0.000 title claims description 15
- 239000000463 material Substances 0.000 title description 4
- 150000004291 polyenes Chemical class 0.000 claims description 42
- 239000002994 raw material Substances 0.000 claims description 39
- VMDTXBZDEOAFQF-UHFFFAOYSA-N formaldehyde;ruthenium Chemical compound [Ru].O=C VMDTXBZDEOAFQF-UHFFFAOYSA-N 0.000 claims description 34
- 125000003709 fluoroalkyl group Chemical group 0.000 claims description 24
- 239000010409 thin film Substances 0.000 claims description 22
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims description 17
- 229910052707 ruthenium Inorganic materials 0.000 claims description 17
- 125000001424 substituent group Chemical group 0.000 claims description 17
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims description 14
- 230000015572 biosynthetic process Effects 0.000 claims description 12
- 230000008569 process Effects 0.000 claims description 12
- 238000010438 heat treatment Methods 0.000 claims description 11
- 239000000758 substrate Substances 0.000 claims description 10
- 125000004432 carbon atom Chemical group C* 0.000 claims description 9
- 238000003786 synthesis reaction Methods 0.000 claims description 9
- 150000003304 ruthenium compounds Chemical class 0.000 claims description 6
- 239000012495 reaction gas Substances 0.000 claims description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 4
- 229910052799 carbon Inorganic materials 0.000 claims description 4
- 125000001153 fluoro group Chemical group F* 0.000 claims description 4
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 3
- 229910052731 fluorine Inorganic materials 0.000 claims description 3
- 239000011737 fluorine Substances 0.000 claims description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 63
- 238000006243 chemical reaction Methods 0.000 description 30
- 239000002904 solvent Substances 0.000 description 23
- 230000008018 melting Effects 0.000 description 18
- 238000002844 melting Methods 0.000 description 18
- -1 cyclic polyene Chemical class 0.000 description 16
- 238000000354 decomposition reaction Methods 0.000 description 13
- 239000010408 film Substances 0.000 description 12
- 239000003446 ligand Substances 0.000 description 12
- 150000003303 ruthenium Chemical class 0.000 description 11
- 238000010992 reflux Methods 0.000 description 10
- LDRWHISXIXVZOI-UHFFFAOYSA-N carbon monoxide;cyclohexa-1,3-diene;ruthenium Chemical compound [Ru].[O+]#[C-].[O+]#[C-].[O+]#[C-].C1CC=CC=C1 LDRWHISXIXVZOI-UHFFFAOYSA-N 0.000 description 9
- MGNZXYYWBUKAII-UHFFFAOYSA-N cyclohexa-1,3-diene Chemical compound C1CC=CC=C1 MGNZXYYWBUKAII-UHFFFAOYSA-N 0.000 description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
- 239000000741 silica gel Substances 0.000 description 8
- 229910002027 silica gel Inorganic materials 0.000 description 8
- 230000008020 evaporation Effects 0.000 description 7
- 238000001704 evaporation Methods 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- 150000001875 compounds Chemical class 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- KAKZBPTYRLMSJV-UHFFFAOYSA-N vinyl-ethylene Natural products C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 5
- LUOYEYALMNBTEO-UHFFFAOYSA-N C(=O)=[Ru](=C=O)=C=O.FC(C(F)(F)F)(F)C(=CC=C)C(F)(F)F Chemical compound C(=O)=[Ru](=C=O)=C=O.FC(C(F)(F)F)(F)C(=CC=C)C(F)(F)F LUOYEYALMNBTEO-UHFFFAOYSA-N 0.000 description 4
- KDUIUFJBNGTBMD-DLMDZQPMSA-N [8]annulene Chemical compound C/1=C/C=C\C=C/C=C\1 KDUIUFJBNGTBMD-DLMDZQPMSA-N 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 125000006340 pentafluoro ethyl group Chemical group FC(F)(F)C(F)(F)* 0.000 description 4
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 4
- GFRTUKRABHMLDS-UHFFFAOYSA-N 1-(trifluoromethyl)cyclohexa-1,3-diene Chemical compound FC(F)(F)C1=CC=CCC1 GFRTUKRABHMLDS-UHFFFAOYSA-N 0.000 description 3
- HLUSLWUSYXGYNR-UHFFFAOYSA-N 5,5,6,6,6-pentafluoro-4-(trifluoromethyl)hexa-1,3-diene Chemical compound FC(C(F)(F)F)(F)C(=CC=C)C(F)(F)F HLUSLWUSYXGYNR-UHFFFAOYSA-N 0.000 description 3
- VNQLFVHMTGBOHI-UHFFFAOYSA-N C(=O)=[Ru](=C=O)=C=O.FC(C(F)(F)F)(F)C1=CC=CC=CC=C1 Chemical compound C(=O)=[Ru](=C=O)=C=O.FC(C(F)(F)F)(F)C1=CC=CC=CC=C1 VNQLFVHMTGBOHI-UHFFFAOYSA-N 0.000 description 3
- XPGAEMCHWCTNHO-UHFFFAOYSA-N C(=O)=[Ru](=C=O)=C=O.FC(C(F)(F)F)(F)C1=CC=CCC1 Chemical compound C(=O)=[Ru](=C=O)=C=O.FC(C(F)(F)F)(F)C1=CC=CCC1 XPGAEMCHWCTNHO-UHFFFAOYSA-N 0.000 description 3
- OBPSUJWSQHYGAP-UHFFFAOYSA-N C(=O)=[Ru](=C=O)=C=O.FC(C(F)(F)F)(F)C=CC=C Chemical compound C(=O)=[Ru](=C=O)=C=O.FC(C(F)(F)F)(F)C=CC=C OBPSUJWSQHYGAP-UHFFFAOYSA-N 0.000 description 3
- XLYQSPNIHZPDQR-UHFFFAOYSA-N C(=O)=[Ru](=C=O)=C=O.FC(F)(F)C(C(=C)C(F)(F)F)=C Chemical compound C(=O)=[Ru](=C=O)=C=O.FC(F)(F)C(C(=C)C(F)(F)F)=C XLYQSPNIHZPDQR-UHFFFAOYSA-N 0.000 description 3
- OHJILEJFGRUYQA-UHFFFAOYSA-N C(=O)=[Ru](=C=O)=C=O.FC(F)(F)C1=C(CCC=C1)C(F)(F)F Chemical compound C(=O)=[Ru](=C=O)=C=O.FC(F)(F)C1=C(CCC=C1)C(F)(F)F OHJILEJFGRUYQA-UHFFFAOYSA-N 0.000 description 3
- LADLTIFFGCDDDQ-UHFFFAOYSA-N C(=O)=[Ru](=C=O)=C=O.FC(F)(F)C1=CC=CC=CC=C1 Chemical compound C(=O)=[Ru](=C=O)=C=O.FC(F)(F)C1=CC=CC=CC=C1 LADLTIFFGCDDDQ-UHFFFAOYSA-N 0.000 description 3
- DJIAZRBBWRRBLO-UHFFFAOYSA-N C(=O)=[Ru](=C=O)=C=O.FC(F)(F)C=CC=C Chemical compound C(=O)=[Ru](=C=O)=C=O.FC(F)(F)C=CC=C DJIAZRBBWRRBLO-UHFFFAOYSA-N 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- 238000009834 vaporization Methods 0.000 description 3
- 230000008016 vaporization Effects 0.000 description 3
- HDZWGQUKLSDYRP-UHFFFAOYSA-N 1,1,2,2,2-pentafluoroethylcyclooctatetraene Chemical compound FC(C(F)(F)F)(F)C1=CC=CC=CC=C1 HDZWGQUKLSDYRP-UHFFFAOYSA-N 0.000 description 2
- XRHMTKXTDMRDHA-UHFFFAOYSA-N 1-(1,1,2,2,2-pentafluoroethyl)cyclohexa-1,3-diene Chemical compound FC(C(F)(F)F)(F)C1=CC=CCC1 XRHMTKXTDMRDHA-UHFFFAOYSA-N 0.000 description 2
- QAKJJUWCWSVYHU-UHFFFAOYSA-N 5,5,5-trifluoropenta-1,3-diene Chemical compound FC(F)(F)C=CC=C QAKJJUWCWSVYHU-UHFFFAOYSA-N 0.000 description 2
- VVJKJZOULGBAJQ-UHFFFAOYSA-N 5,5,6,6,6-pentafluorohexa-1,3-diene Chemical compound FC(C(F)(F)F)(F)C=CC=C VVJKJZOULGBAJQ-UHFFFAOYSA-N 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- OZRSRAFAVRHYCN-UHFFFAOYSA-N C(=O)=[Ru](=C=O)=C=O.FC(C(F)(F)F)(F)C1=C(CCC=C1)C(F)(F)F Chemical compound C(=O)=[Ru](=C=O)=C=O.FC(C(F)(F)F)(F)C1=C(CCC=C1)C(F)(F)F OZRSRAFAVRHYCN-UHFFFAOYSA-N 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 239000012159 carrier gas Substances 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- IJMVUFLSZAIPNI-FXPPOMFJSA-N trifluoromethylcyclooctatetraene Chemical compound FC(F)(F)/C/1=C/C=C\C=C/C=C\1 IJMVUFLSZAIPNI-FXPPOMFJSA-N 0.000 description 2
- MBGSINXLCQJGRT-UHFFFAOYSA-N 2-(1,1,2,2,2-pentafluoroethyl)-1-(trifluoromethyl)cyclohexa-1,3-diene Chemical compound FC(C(F)(F)F)(F)C1=C(CCC=C1)C(F)(F)F MBGSINXLCQJGRT-UHFFFAOYSA-N 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 238000005411 Van der Waals force Methods 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000008033 biological extinction Effects 0.000 description 1
- 230000005587 bubbling Effects 0.000 description 1
- NQZFAUXPNWSLBI-UHFFFAOYSA-N carbon monoxide;ruthenium Chemical group [Ru].[Ru].[Ru].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-] NQZFAUXPNWSLBI-UHFFFAOYSA-N 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 125000006575 electron-withdrawing group Chemical group 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000000638 solvent extraction Methods 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 239000006200 vaporizer Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
- C07F15/0046—Ruthenium compounds
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/06—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of metallic material
- C23C16/18—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of metallic material from metallo-organic compounds
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/06—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of metallic material
- C23C16/16—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of metallic material from metal carbonyl compounds
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/44—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
- C23C16/46—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating characterised by the method used for heating the substrate
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Chemical Vapour Deposition (AREA)
- Electrodes Of Semiconductors (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
基板加熱温度:175℃
キャリアーガス(アルゴン)流量:10sccm
反応ガス(酸素)流量:2sccm
反応室圧力:50Pa
製膜時間:20分
Claims (6)
- ルテニウム錯体からなり、化学蒸着法によりルテニウム薄膜又はルテニウム化合物薄膜を製造するための原料において、
前記ルテニウム錯体は、次式で示される、ルテニウムに、カルボニル基及びポリエンのフルオロアルキル誘導体が配位したものである化学蒸着用原料。
- ポリエン(L)は、炭素数4〜6であり2個の二重結合を有する鎖状ポリエンである請求項1記載の化学蒸着用原料。
- 置換基であるフルオロアルキル基(R)は、炭素数1〜3、フッ素数1〜7であり、nが1〜2である請求項1記載の化学蒸着用原料。
- 請求項1〜請求項3のいずれかに記載の化学蒸着用原料の製造方法であって、
ドデカカルボニルトリルテニウムと、鎖状ポリエンのフルオロアルキル誘導体と加熱下で反応させる合成工程を含み、
前記合成工程は、ドデカカルボニルトリルテニウムに対してポリエンのフルオロアルキル誘導体をモル比で1〜3倍当量反応させるものである化学蒸着用原料の製造方法。 - 合成工程における加熱温度を、75〜85℃とする請求項4記載の化学蒸着用原料の製造方法。
- ルテニウム錯体からなる化学蒸着用原料を気化して反応ガスとし、前記反応ガスを基板表面に導入し、前記ルテニウム錯体を分解してルテニウムを析出させるルテニウム薄膜又はルテニウム化合物薄膜の化学蒸着法において、
前記化学蒸着用原料として請求項1〜請求項3のいずれかに記載の化学蒸着用原料を用いる方法。
Priority Applications (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2012181329A JP5992764B2 (ja) | 2012-08-20 | 2012-08-20 | ルテニウム錯体からなる化学蒸着原料及びその製造方法並びに化学蒸着方法 |
TW102129238A TWI532869B (zh) | 2012-08-20 | 2013-08-15 | 由釕錯合物所構成的化學蒸鍍原料及其製造方法和化學蒸鍍法 |
TW104105784A TW201522695A (zh) | 2012-08-20 | 2013-08-15 | 由釕錯合物所構成的化學蒸鍍原料及其製造方法和化學蒸鍍法 |
KR1020157005690A KR101657428B1 (ko) | 2012-08-20 | 2013-08-19 | 루테늄 착체로 이루어지는 화학 증착 원료 및 그 제조 방법 및 화학 증착 방법 |
US14/422,292 US9556212B2 (en) | 2012-08-20 | 2013-08-19 | Chemical deposition raw material formed of ruthenium complex and method for producing the same, and chemical deposition method |
EP13831394.5A EP2886679A4 (en) | 2012-08-20 | 2013-08-19 | CHEMICAL VAPOR DEPOSITION MATERIAL BASED ON RUTHENIUM COMPLEX, METHOD FOR PRODUCING THE SAME, AND CHEMICAL VAPOR DEPOSITION METHOD |
PCT/JP2013/072080 WO2014030609A1 (ja) | 2012-08-20 | 2013-08-19 | ルテニウム錯体からなる化学蒸着原料及びその製造方法並びに化学蒸着方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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JP2012181329A JP5992764B2 (ja) | 2012-08-20 | 2012-08-20 | ルテニウム錯体からなる化学蒸着原料及びその製造方法並びに化学蒸着方法 |
Publications (2)
Publication Number | Publication Date |
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JP2014037390A JP2014037390A (ja) | 2014-02-27 |
JP5992764B2 true JP5992764B2 (ja) | 2016-09-14 |
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JP2012181329A Active JP5992764B2 (ja) | 2012-08-20 | 2012-08-20 | ルテニウム錯体からなる化学蒸着原料及びその製造方法並びに化学蒸着方法 |
Country Status (6)
Country | Link |
---|---|
US (1) | US9556212B2 (ja) |
EP (1) | EP2886679A4 (ja) |
JP (1) | JP5992764B2 (ja) |
KR (1) | KR101657428B1 (ja) |
TW (2) | TW201522695A (ja) |
WO (1) | WO2014030609A1 (ja) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
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JP6321252B1 (ja) * | 2017-03-24 | 2018-05-09 | 田中貴金属工業株式会社 | イリジウム錯体からなる化学蒸着用原料及び該化学蒸着用原料を用いた化学蒸着法 |
US11371138B2 (en) * | 2018-11-08 | 2022-06-28 | Entegris, Inc. | Chemical vapor deposition processes using ruthenium precursor and reducing gas |
JP7148377B2 (ja) * | 2018-12-03 | 2022-10-05 | 田中貴金属工業株式会社 | ルテニウム錯体からなる化学蒸着用原料及び該化学蒸着用原料を用いた化学蒸着法 |
TW202342491A (zh) * | 2022-04-15 | 2023-11-01 | 日商東曹股份有限公司 | 釕錯合物、其製造方法、及含釕薄膜的製造方法 |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5962716A (en) * | 1998-08-27 | 1999-10-05 | Micron Technology, Inc. | Methods for preparing ruthenium and osmium compounds |
US6063705A (en) * | 1998-08-27 | 2000-05-16 | Micron Technology, Inc. | Precursor chemistries for chemical vapor deposition of ruthenium and ruthenium oxide |
JP2002212112A (ja) * | 2001-01-22 | 2002-07-31 | Tanaka Kikinzoku Kogyo Kk | 化学気相蒸着用のルテニウム化合物並びにルテニウム薄膜及びルテニウム化合物薄膜の化学気相蒸着方法。 |
KR100991299B1 (ko) * | 2002-12-03 | 2010-11-01 | 제이에스알 가부시끼가이샤 | 루테늄 화합물 및 금속 루테늄막의 제조 방법 |
JP4661130B2 (ja) | 2004-08-17 | 2011-03-30 | Jsr株式会社 | 化学気相成長方法 |
KR101344988B1 (ko) * | 2006-09-22 | 2013-12-24 | 레르 리키드 쏘시에떼 아노님 뿌르 레?드 에렉스뿔라따시옹 데 프로세데 조르즈 클로드 | 루테늄 함유 필름의 증착 방법 |
US8404306B2 (en) | 2006-09-22 | 2013-03-26 | L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés George Claude | Method for the deposition of a ruthenium containing film |
JP4674260B2 (ja) | 2009-01-30 | 2011-04-20 | 田中貴金属工業株式会社 | シクロオクタテトラエントリカルボニルルテニウム系錯体とその製造方法、ならびに、当該錯体を原料とする膜の製造方法 |
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EP2886679A4 (en) | 2016-04-06 |
EP2886679A1 (en) | 2015-06-24 |
KR101657428B1 (ko) | 2016-09-13 |
US20150225437A1 (en) | 2015-08-13 |
KR20150038596A (ko) | 2015-04-08 |
JP2014037390A (ja) | 2014-02-27 |
US9556212B2 (en) | 2017-01-31 |
TW201425630A (zh) | 2014-07-01 |
WO2014030609A1 (ja) | 2014-02-27 |
TW201522695A (zh) | 2015-06-16 |
TWI532869B (zh) | 2016-05-11 |
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