JP5963684B2 - 改善された色安定性を有する吸水性ポリマー粒子の製造方法 - Google Patents
改善された色安定性を有する吸水性ポリマー粒子の製造方法 Download PDFInfo
- Publication number
- JP5963684B2 JP5963684B2 JP2012557508A JP2012557508A JP5963684B2 JP 5963684 B2 JP5963684 B2 JP 5963684B2 JP 2012557508 A JP2012557508 A JP 2012557508A JP 2012557508 A JP2012557508 A JP 2012557508A JP 5963684 B2 JP5963684 B2 JP 5963684B2
- Authority
- JP
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- Prior art keywords
- acid
- water
- polymer particles
- absorbing polymer
- hydroxy
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/04—Acids; Metal salts or ammonium salts thereof
- C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
- A61L15/16—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
- A61L15/42—Use of materials characterised by their function or physical properties
- A61L15/60—Liquid-swellable gel-forming materials, e.g. super-absorbents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F6/00—Post-polymerisation treatments
- C08F6/008—Treatment of solid polymer wetted by water or organic solvents, e.g. coagulum, filter cakes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/24—Crosslinking, e.g. vulcanising, of macromolecules
- C08J3/245—Differential crosslinking of one polymer with one crosslinking type, e.g. surface crosslinking
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/41—Compounds containing sulfur bound to oxygen
- C08K5/42—Sulfonic acids; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
- C08F222/10—Esters
- C08F222/1006—Esters of polyhydric alcohols or polyhydric phenols
- C08F222/102—Esters of polyhydric alcohols or polyhydric phenols of dialcohols, e.g. ethylene glycol di(meth)acrylate or 1,4-butanediol dimethacrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
- C08F222/10—Esters
- C08F222/1006—Esters of polyhydric alcohols or polyhydric phenols
- C08F222/103—Esters of polyhydric alcohols or polyhydric phenols of trialcohols, e.g. trimethylolpropane tri(meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2333/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
- C08J2333/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0025—Crosslinking or vulcanising agents; including accelerators
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Epidemiology (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Dispersion Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Hematology (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polymerisation Methods In General (AREA)
- Absorbent Articles And Supports Therefor (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP10156480 | 2010-03-15 | ||
| EP10156480.5 | 2010-03-15 | ||
| PCT/EP2011/053764 WO2011113777A1 (de) | 2010-03-15 | 2011-03-14 | Verfahren zur herstellung wasserabsorbierender polymerpartikel mit verbesserter farbstabilität |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2013522406A JP2013522406A (ja) | 2013-06-13 |
| JP2013522406A5 JP2013522406A5 (enExample) | 2014-05-01 |
| JP5963684B2 true JP5963684B2 (ja) | 2016-08-03 |
Family
ID=43828317
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2012557508A Active JP5963684B2 (ja) | 2010-03-15 | 2011-03-14 | 改善された色安定性を有する吸水性ポリマー粒子の製造方法 |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US8703876B2 (enExample) |
| EP (1) | EP2547705B1 (enExample) |
| JP (1) | JP5963684B2 (enExample) |
| CN (1) | CN102892795B (enExample) |
| WO (1) | WO2011113777A1 (enExample) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2013144026A1 (de) * | 2012-03-30 | 2013-10-03 | Basf Se | Farbstabiler superabsorber |
| US11203005B2 (en) * | 2014-12-04 | 2021-12-21 | Basf Se | Method for producing water-absorbing polymer particles by suspension polymerization |
| JP6555832B2 (ja) * | 2015-03-10 | 2019-08-07 | Sdpグローバル株式会社 | 水性液体吸収性樹脂の製造方法 |
| JP6820862B2 (ja) * | 2015-04-07 | 2021-01-27 | ビーエイエスエフ・ソシエタス・エウロパエアBasf Se | 超吸収体粒子を凝集させる方法 |
| US11325990B2 (en) | 2016-08-10 | 2022-05-10 | Basf Se | Method for the production of superabsorbers |
| CN111278551B (zh) | 2017-11-10 | 2023-09-29 | 巴斯夫欧洲公司 | 超吸收剂 |
| CN111989074B (zh) * | 2018-04-20 | 2022-08-05 | 巴斯夫欧洲公司 | 制备超吸收剂的方法 |
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| JPS58180233A (ja) | 1982-04-19 | 1983-10-21 | Nippon Shokubai Kagaku Kogyo Co Ltd | 吸収剤 |
| US4734478A (en) | 1984-07-02 | 1988-03-29 | Nippon Shokubai Kagaku Kogyo Co., Ltd. | Water absorbing agent |
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| US5185413A (en) * | 1989-05-16 | 1993-02-09 | Mitsubishi Petrochemical Company Limited | Process for producing highly water-absortive polymers |
| WO1990015830A1 (en) | 1989-06-12 | 1990-12-27 | Weyerhaeuser Company | Hydrocolloid polymer |
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| JP3107873B2 (ja) * | 1991-09-26 | 2000-11-13 | ユニ・チャーム株式会社 | 高吸水性ポリマーの経時着色防止方法および経時着色防止剤 |
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| EP2114471B1 (de) | 2007-01-29 | 2013-10-16 | Basf Se | VERFAHREN ZUR HERSTELLUNG WEIßER UND FARBSTABILER WASSERABSORBIERENDER POLYMERPARTIKEL MIT HOHEM ABSORPTIONSVERMÖGEN UND HOHER FLÜSSIGKEITSLEITFÄHIGKEIT |
| JP5345554B2 (ja) | 2007-01-29 | 2013-11-20 | ビーエーエスエフ ソシエタス・ヨーロピア | 高吸収性および高食塩水流れ誘導性を有する白色かつ色安定性の吸水性ポリマー粒子を製造するための方法 |
| SA08290402B1 (ar) * | 2007-07-04 | 2014-05-22 | نيبون شوكوباي كو. ، ليمتد | عامل دقائقي ماص للماء وطريقة لتصنيعه |
| US7816426B2 (en) * | 2007-07-16 | 2010-10-19 | Evonik Stockhausen, Llc | Superabsorbent polymer compositions having color stability |
| DE102007053619A1 (de) * | 2007-11-08 | 2009-05-20 | Evonik Stockhausen Gmbh | Wasserabsorbierende Polymergebilde mit verbesserter Farbstabilität |
| EP2307486B2 (de) * | 2008-07-31 | 2019-10-23 | Basf Se | Farbstabiler superabsorber |
| EP2504368B1 (de) * | 2009-11-23 | 2014-01-08 | Basf Se | Verfahren zur herstellung wasserabsorbierender polymerpartikel mit verbesserter farbstabilität |
| US8852742B2 (en) * | 2010-03-15 | 2014-10-07 | Basf Se | Water absorbent polymer particles formed by polymerizing droplets of a monomer solution and coated with sulfinic acid, sulfonic acid, and/or salts thereof |
| RU2012143697A (ru) * | 2010-03-15 | 2014-04-20 | Басф Се | Способ получения водопоглощающих полимерных частиц путем полимеризации капель раствора мономеров |
-
2011
- 2011-03-04 US US13/041,033 patent/US8703876B2/en active Active
- 2011-03-14 JP JP2012557508A patent/JP5963684B2/ja active Active
- 2011-03-14 CN CN201180024054.6A patent/CN102892795B/zh active Active
- 2011-03-14 WO PCT/EP2011/053764 patent/WO2011113777A1/de not_active Ceased
- 2011-03-14 EP EP11707684.4A patent/EP2547705B1/de not_active Revoked
Also Published As
| Publication number | Publication date |
|---|---|
| US8703876B2 (en) | 2014-04-22 |
| CN102892795A (zh) | 2013-01-23 |
| WO2011113777A1 (de) | 2011-09-22 |
| US20110224381A1 (en) | 2011-09-15 |
| JP2013522406A (ja) | 2013-06-13 |
| EP2547705A1 (de) | 2013-01-23 |
| EP2547705B1 (de) | 2014-07-02 |
| CN102892795B (zh) | 2015-11-25 |
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