JP5921104B2 - 多孔質ガラスおよび光学部材 - Google Patents
多孔質ガラスおよび光学部材 Download PDFInfo
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- JP5921104B2 JP5921104B2 JP2011161447A JP2011161447A JP5921104B2 JP 5921104 B2 JP5921104 B2 JP 5921104B2 JP 2011161447 A JP2011161447 A JP 2011161447A JP 2011161447 A JP2011161447 A JP 2011161447A JP 5921104 B2 JP5921104 B2 JP 5921104B2
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- phase separation
- porous glass
- spinodal
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- 239000005373 porous glass Substances 0.000 title claims description 78
- 230000003287 optical effect Effects 0.000 title claims description 14
- 238000005191 phase separation Methods 0.000 claims description 57
- 239000011148 porous material Substances 0.000 claims description 33
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 31
- 229910052814 silicon oxide Inorganic materials 0.000 claims description 20
- 239000000463 material Substances 0.000 claims description 14
- 229910000272 alkali metal oxide Inorganic materials 0.000 claims description 10
- 239000002585 base Substances 0.000 claims description 10
- 229910052810 boron oxide Inorganic materials 0.000 claims description 10
- 239000000758 substrate Substances 0.000 claims description 8
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 claims description 7
- 239000000377 silicon dioxide Substances 0.000 claims description 5
- 239000011159 matrix material Substances 0.000 claims description 4
- 239000011521 glass Substances 0.000 description 50
- 239000010410 layer Substances 0.000 description 39
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 34
- 229910001868 water Inorganic materials 0.000 description 34
- 239000006121 base glass Substances 0.000 description 31
- 239000000203 mixture Substances 0.000 description 27
- 239000002344 surface layer Substances 0.000 description 21
- 238000010438 heat treatment Methods 0.000 description 20
- 238000000034 method Methods 0.000 description 14
- 238000005530 etching Methods 0.000 description 11
- 239000005388 borosilicate glass Substances 0.000 description 10
- 230000008569 process Effects 0.000 description 10
- 238000010306 acid treatment Methods 0.000 description 9
- 230000015572 biosynthetic process Effects 0.000 description 9
- 239000002253 acid Substances 0.000 description 8
- 239000002994 raw material Substances 0.000 description 8
- 239000000243 solution Substances 0.000 description 8
- 238000007654 immersion Methods 0.000 description 6
- 238000005406 washing Methods 0.000 description 6
- 238000004833 X-ray photoelectron spectroscopy Methods 0.000 description 5
- 229910052783 alkali metal Inorganic materials 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- 239000000075 oxide glass Substances 0.000 description 5
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- 150000001340 alkali metals Chemical class 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- 239000005357 flat glass Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 229910017604 nitric acid Inorganic materials 0.000 description 4
- AOQZCUVGSOYNCB-UHFFFAOYSA-N [B].[Si]=O Chemical compound [B].[Si]=O AOQZCUVGSOYNCB-UHFFFAOYSA-N 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- 230000007935 neutral effect Effects 0.000 description 3
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 2
- 239000004327 boric acid Substances 0.000 description 2
- 229910052796 boron Inorganic materials 0.000 description 2
- 238000012790 confirmation Methods 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 238000000635 electron micrograph Methods 0.000 description 2
- 238000010828 elution Methods 0.000 description 2
- 238000003384 imaging method Methods 0.000 description 2
- 150000007522 mineralic acids Chemical class 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- 238000002791 soaking Methods 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- NZYCGFZUQASSNJ-UHFFFAOYSA-N O=[Si].OP(O)(O)=O Chemical compound O=[Si].OP(O)(O)=O NZYCGFZUQASSNJ-UHFFFAOYSA-N 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- BYYAEDYXYQAHAL-UHFFFAOYSA-N [O-2].[Ti+4].[O-2].[Al+3].[O-2].[Mg+2].[O-2].[Ca+2].[B+]=O.[Si+2]=O Chemical compound [O-2].[Ti+4].[O-2].[Al+3].[O-2].[Mg+2].[O-2].[Ca+2].[B+]=O.[Si+2]=O BYYAEDYXYQAHAL-UHFFFAOYSA-N 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 229910000287 alkaline earth metal oxide Inorganic materials 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 238000000445 field-emission scanning electron microscopy Methods 0.000 description 1
- 238000007429 general method Methods 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 230000008774 maternal effect Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 230000000877 morphologic effect Effects 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C11/00—Multi-cellular glass ; Porous or hollow glass or glass particles
- C03C11/005—Multi-cellular glass ; Porous or hollow glass or glass particles obtained by leaching after a phase separation step
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
- B32B3/26—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/006—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/089—Glass compositions containing silica with 40% to 90% silica, by weight containing boron
- C03C3/091—Glass compositions containing silica with 40% to 90% silica, by weight containing boron containing aluminium
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/40—Coatings comprising at least one inhomogeneous layer
- C03C2217/425—Coatings comprising at least one inhomogeneous layer consisting of a porous layer
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/70—Properties of coatings
- C03C2217/73—Anti-reflective coatings with specific characteristics
- C03C2217/732—Anti-reflective coatings with specific characteristics made of a single layer
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/90—Other aspects of coatings
- C03C2217/91—Coatings containing at least one layer having a composition gradient through its thickness
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24942—Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree
- Y10T428/2495—Thickness [relative or absolute]
- Y10T428/24967—Absolute thicknesses specified
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/249921—Web or sheet containing structurally defined element or component
- Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]
- Y10T428/249967—Inorganic matrix in void-containing component
- Y10T428/249969—Of silicon-containing material [e.g., glass, etc.]
Landscapes
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Composite Materials (AREA)
- Glass Compositions (AREA)
- Surface Treatment Of Glass (AREA)
- Surface Treatment Of Optical Elements (AREA)
- Re-Forming, After-Treatment, Cutting And Transporting Of Glass Products (AREA)
Description
(1)表面観察
走査電子顕微鏡(FE−SEM S−4800、日立製作所製)を用いて多孔質ガラスの表面観察(加速電圧;5kV、倍率;5万倍)を行った。
(2)ガラス組成の確認
ガラス組成の確認をX線光電子分光測定(XPS)により行った。XPS測定には、ESCA LAB220i−XLを用いた。
(3)反射率測定
レンズ反射率測定機(USPM−RU、オリンパス製)を用いて多孔質ガラスの反射率を測定した。
ガラス原料として、炭酸ナトリウム、ホウ酸及び二酸化ケイ素、アルミナを用いた。それらの原料をNa2O:B2O3:SiO2:Al2O3=4.5:19:75:1.5(重量%)組成比となるように均一に混合し、1350から1450℃で加熱溶融し、その後板状に成形した状態で自然冷却し厚み約1mmの板状ガラスを得た。
実施例1と同様に作製した板状ガラスを約1cm角に切断した、4.5Na2O・19B2O3・75SiO2・1.5Al2O3(重量%)組成の母体ガラスを80℃に温めたイオン交換水(中性pH、6.9)中に3時間浸漬した。その後600℃、50時間熱処理した。
上記組成ガラスを水浸漬後、600℃で熱処理したガラス表面のXPS測定を行った。その結果、ガラス表層のガラス組成はガラス内部に比べホウ素が約3分の1、ナトリウムが約2分の1になっており、ガラス表層において組成変化が起こっていることがわかった。
実施例1で得られた多孔質ガラスの反射率測定を行ったところ、光の波長550nmにおける反射率が1.86%、波長400nmにおける反射率が2.32%であった。実施例2で得られた多孔質ガラスの波長550nmにおける反射率は2.23%、波長400nmにおける反射率は2.66%であった。
実施例1と同様に作製した板状ガラスを約1cm角に切断した、4.5Na2O・19B2O3・75SiO2・1.5Al2O3(重量%)組成の母体ガラスを600℃、50時間熱処理した。その後、80℃に温めた1mol/L(1規定)の硝酸水溶液中に24時間浸漬した後、80℃のイオン交換水(中性、pH6.9)中に24時間浸漬した。
比較例1で得られた多孔質ガラスの反射率測定を行ったところ、光の波長550nmにおける反射率が1.90%、波長400nmにおける反射率が3.34%であった。実施例1に比べて、可視域の反射率は高く、波長依存性が悪いことがわかる。
2 多孔質層
3 母材層
Claims (9)
- シリカを主成分とし、スピノーダル型の相分離由来の孔およびバイノーダル型の相分離由来の孔が形成された多孔質層を有し、前記多孔質層は、表面から内部に向かってスピノーダル型の相分離由来の孔の割合がバイノーダル型の相分離由来の孔の割合に対して減少していることを特徴とする多孔質ガラス。
- 前記多孔質ガラスの膜厚が500μm乃至2000μmであり、
前記多孔質ガラスの膜厚のうち、前記多孔質層の厚みが0.01μm乃至100μmであることを特徴とする請求項1に記載の多孔質ガラス。 - 母材層をさらに有し、
前記多孔質層は前記母材層の上に形成され、
前記母材層は、酸化ケイ素、酸化ホウ素、アルカリ金属酸化物が含まれていることを特徴とする請求項1乃至2のいずれか1項に記載の多孔質ガラス。 - 基材をさらに有し、
前記多孔質層は前記基材の上に形成されていることを特徴とする請求項1乃至2のいずれか1項に記載の多孔質ガラス。 - 前記多孔質層の断面において、前記スピノーダル型の相分離由来の孔の形状は弓形であることを特徴とする請求項1乃至4のいずれか一項に記載の多孔質ガラス。
- 前記多孔質層の断面において、前記バイノーダル型の相分離由来の孔の形状は円形であることを特徴とする請求項1乃至5のいずれか一項に記載の多孔質ガラス。
- 前記バイノーダル型の相分離由来の孔どうしは、前記バイノーダル型の相分離由来の孔の孔径よりも小さい孔径を有する管状の孔でつながっていることを特徴とする請求項1乃至6のいずれか1項に記載の多孔質ガラス。
- 前記バイノーダル型の相分離由来の孔と前記スピノーダル型の相分離由来の孔は、前記バイノーダル型の相分離由来の孔の孔径と前記スピノーダル型の相分離由来の孔の孔径よりも小さい孔径を有する管状の孔でつながっていることを特徴とする請求項1乃至7のいずれか1項に記載の多孔質ガラス。
- 請求項1乃至8のいずれかに1項に記載の多孔質ガラスを用いたことを特徴とする光学部材。
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2011161447A JP5921104B2 (ja) | 2010-08-31 | 2011-07-23 | 多孔質ガラスおよび光学部材 |
PCT/JP2011/004725 WO2012029261A2 (en) | 2010-08-31 | 2011-08-25 | Porous glass and optical member |
US13/819,272 US8993107B2 (en) | 2010-08-31 | 2011-08-25 | Porous glass and optical member |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2010193215 | 2010-08-31 | ||
JP2010193215 | 2010-08-31 | ||
JP2011161447A JP5921104B2 (ja) | 2010-08-31 | 2011-07-23 | 多孔質ガラスおよび光学部材 |
Publications (3)
Publication Number | Publication Date |
---|---|
JP2012072048A JP2012072048A (ja) | 2012-04-12 |
JP2012072048A5 JP2012072048A5 (ja) | 2014-09-04 |
JP5921104B2 true JP5921104B2 (ja) | 2016-05-24 |
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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JP2011161447A Expired - Fee Related JP5921104B2 (ja) | 2010-08-31 | 2011-07-23 | 多孔質ガラスおよび光学部材 |
Country Status (3)
Country | Link |
---|---|
US (1) | US8993107B2 (ja) |
JP (1) | JP5921104B2 (ja) |
WO (1) | WO2012029261A2 (ja) |
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JP2013224249A (ja) * | 2012-03-23 | 2013-10-31 | Canon Inc | 光学部材の製造方法、光学部材及び撮像装置 |
CN104254501B (zh) * | 2012-04-27 | 2016-09-28 | 旭硝子株式会社 | 化学强化玻璃的制造方法 |
JP6080386B2 (ja) * | 2012-05-23 | 2017-02-15 | キヤノン株式会社 | 光学部材、撮像装置及び光学部材の製造方法 |
JP6103853B2 (ja) * | 2012-08-08 | 2017-03-29 | キヤノン株式会社 | 光学素子及びそれを有する光学装置 |
JP6071318B2 (ja) * | 2012-08-09 | 2017-02-01 | キヤノン株式会社 | 光学部材および光学部材の製造方法 |
US9393760B2 (en) | 2013-02-28 | 2016-07-19 | Corning Incorporated | Laminated glass articles with phase-separated claddings and methods for forming the same |
US10698136B2 (en) * | 2016-07-19 | 2020-06-30 | Panasonic Intellectual Property Management Co., Ltd. | Optical member and method for manufacturing the same |
US20200238797A1 (en) * | 2017-10-10 | 2020-07-30 | Central Glass Company, Limited | Improved anti-reflective functional coating for glazings |
US11422294B2 (en) | 2017-10-10 | 2022-08-23 | Central Glass Company, Limited | Durable functional coatings |
TW202248010A (zh) * | 2021-03-30 | 2022-12-16 | 美商康寧公司 | 具有多孔層之抗反射紅外線傳輸積層玻璃製品 |
US20220371939A1 (en) * | 2021-05-20 | 2022-11-24 | Corning Incorporated | Phase-separated glass compositions |
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US2480672A (en) * | 1944-08-12 | 1949-08-30 | Socony Vacuum Oil Co Inc | Process for forming porous glass and composition thereof |
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US20070184247A1 (en) * | 2006-02-03 | 2007-08-09 | Simpson John T | Transparent, super-hydrophobic, disordered composite material |
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WO2008106038A1 (en) * | 2007-02-28 | 2008-09-04 | Corning Incorporated | Extruded glass structures and methods for manufacturing the same |
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2011
- 2011-07-23 JP JP2011161447A patent/JP5921104B2/ja not_active Expired - Fee Related
- 2011-08-25 WO PCT/JP2011/004725 patent/WO2012029261A2/en active Application Filing
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US8993107B2 (en) | 2015-03-31 |
WO2012029261A3 (en) | 2012-07-12 |
JP2012072048A (ja) | 2012-04-12 |
US20130157026A1 (en) | 2013-06-20 |
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