JP5907872B2 - ハイブリッド網状構造物に抗微生物剤を含有する水性分散液 - Google Patents

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Publication number

JP5907872B2

JP5907872B2 JP2012529205A JP2012529205A JP5907872B2 JP 5907872 B2 JP5907872 B2 JP 5907872B2 JP 2012529205 A JP2012529205 A JP 2012529205A JP 2012529205 A JP2012529205 A JP 2012529205A JP 5907872 B2 JP5907872 B2 JP 5907872B2

Authority

JP

Japan

Prior art keywords

acrylate

meth

tris

butyl

silylpropyl

Prior art date

2009-09-15

Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

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• 239000004599 antimicrobial Substances 0.000 title claims description 51
• 239000006185 dispersion Substances 0.000 title description 28
• -1 n-octyl Chemical group 0.000 claims description 160
• NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 124
• 239000000203 mixture Substances 0.000 claims description 99
• 239000000178 monomer Substances 0.000 claims description 82
• 238000000576 coating method Methods 0.000 claims description 74
• 230000000845 anti-microbial effect Effects 0.000 claims description 71
• 239000011248 coating agent Substances 0.000 claims description 62
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 42
• 229920000642 polymer Polymers 0.000 claims description 40
• 239000007983 Tris buffer Substances 0.000 claims description 36
• 238000000034 method Methods 0.000 claims description 34
• 239000013543 active substance Substances 0.000 claims description 31
• PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 28
• GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 23
• XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 23
• 125000000217 alkyl group Chemical group 0.000 claims description 21
• 239000004332 silver Substances 0.000 claims description 18
• 229910052709 silver Inorganic materials 0.000 claims description 18
• 229920002554 vinyl polymer Polymers 0.000 claims description 15
• 239000000017 hydrogel Substances 0.000 claims description 14
• 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 14
• 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 11
• 229910000077 silane Inorganic materials 0.000 claims description 11
• 239000004408 titanium dioxide Substances 0.000 claims description 11
• 239000011787 zinc oxide Substances 0.000 claims description 11
• BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 10
• 125000002947 alkylene group Chemical group 0.000 claims description 10
• CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 10
• 230000007062 hydrolysis Effects 0.000 claims description 10
• 238000006460 hydrolysis reaction Methods 0.000 claims description 10
• 230000008569 process Effects 0.000 claims description 10
• LENZDBCJOHFCAS-UHFFFAOYSA-N tris Chemical compound OCC(N)(CO)CO LENZDBCJOHFCAS-UHFFFAOYSA-N 0.000 claims description 10
• 239000002671 adjuvant Substances 0.000 claims description 9
• 239000012876 carrier material Substances 0.000 claims description 9
• 230000009477 glass transition Effects 0.000 claims description 8
• 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 8
• 238000006068 polycondensation reaction Methods 0.000 claims description 8
• 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 8
• 239000010457 zeolite Substances 0.000 claims description 8
• LVDKZNITIUWNER-UHFFFAOYSA-N Bronopol Chemical compound OCC(Br)(CO)[N+]([O-])=O LVDKZNITIUWNER-UHFFFAOYSA-N 0.000 claims description 7
• 229910052586 apatite Inorganic materials 0.000 claims description 7
• 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 7
• 238000004519 manufacturing process Methods 0.000 claims description 7
• 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 claims description 7
• 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 7
• 239000002245 particle Substances 0.000 claims description 7
• VSIIXMUUUJUKCM-UHFFFAOYSA-D pentacalcium;fluoride;triphosphate Chemical compound [F-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O VSIIXMUUUJUKCM-UHFFFAOYSA-D 0.000 claims description 7
• 150000003242 quaternary ammonium salts Chemical class 0.000 claims description 7
• 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 7
• ADZWSOLPGZMUMY-UHFFFAOYSA-M silver bromide Chemical compound [Ag]Br ADZWSOLPGZMUMY-UHFFFAOYSA-M 0.000 claims description 7
• 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 7
• 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 6
• 125000003136 n-heptyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 5
• NVZWEEGUWXZOKI-UHFFFAOYSA-N 1-ethenyl-2-methylbenzene Chemical compound CC1=CC=CC=C1C=C NVZWEEGUWXZOKI-UHFFFAOYSA-N 0.000 claims description 4
• GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 claims description 4
• BVTACSRUXCUEHT-UHFFFAOYSA-N 2-methyl-6-triethoxysilylhex-1-en-3-one Chemical compound CCO[Si](OCC)(OCC)CCCC(=O)C(C)=C BVTACSRUXCUEHT-UHFFFAOYSA-N 0.000 claims description 4
• XYPTZZQGMHILPQ-UHFFFAOYSA-N 2-methyl-6-trimethoxysilylhex-1-en-3-one Chemical compound CO[Si](OC)(OC)CCCC(=O)C(C)=C XYPTZZQGMHILPQ-UHFFFAOYSA-N 0.000 claims description 4
• GANRUNBROXMSEB-UHFFFAOYSA-N 6-[diethoxy(methyl)silyl]-2-methylhex-1-en-3-one Chemical compound CCO[Si](C)(OCC)CCCC(=O)C(C)=C GANRUNBROXMSEB-UHFFFAOYSA-N 0.000 claims description 4
• ALKCFGAAAKIGBJ-UHFFFAOYSA-N 6-[dimethoxy(methyl)silyl]-2-methylhex-1-en-3-one Chemical compound CO[Si](C)(OC)CCCC(=O)C(C)=C ALKCFGAAAKIGBJ-UHFFFAOYSA-N 0.000 claims description 4
• VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 4
• FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 claims description 4
• NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 claims description 4
• MBGQQKKTDDNCSG-UHFFFAOYSA-N ethenyl-diethoxy-methylsilane Chemical compound CCO[Si](C)(C=C)OCC MBGQQKKTDDNCSG-UHFFFAOYSA-N 0.000 claims description 4
• JEWCZPTVOYXPGG-UHFFFAOYSA-N ethenyl-ethoxy-dimethylsilane Chemical compound CCO[Si](C)(C)C=C JEWCZPTVOYXPGG-UHFFFAOYSA-N 0.000 claims description 4
• NUFVQEIPPHHQCK-UHFFFAOYSA-N ethenyl-methoxy-dimethylsilane Chemical compound CO[Si](C)(C)C=C NUFVQEIPPHHQCK-UHFFFAOYSA-N 0.000 claims description 4
• MABAWBWRUSBLKQ-UHFFFAOYSA-N ethenyl-tri(propan-2-yloxy)silane Chemical compound CC(C)O[Si](OC(C)C)(OC(C)C)C=C MABAWBWRUSBLKQ-UHFFFAOYSA-N 0.000 claims description 4
• 239000011256 inorganic filler Substances 0.000 claims description 4
• 229910003475 inorganic filler Inorganic materials 0.000 claims description 4
• 239000001023 inorganic pigment Substances 0.000 claims description 4
• ZLNAFSPCNATQPQ-UHFFFAOYSA-N ethenyl-dimethoxy-methylsilane Chemical compound CO[Si](C)(OC)C=C ZLNAFSPCNATQPQ-UHFFFAOYSA-N 0.000 claims description 2
• 239000000463 material Substances 0.000 description 55
• 239000004815 dispersion polymer Substances 0.000 description 44
• 239000000049 pigment Substances 0.000 description 44
• HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 39
• 150000001875 compounds Chemical class 0.000 description 37
• 238000006116 polymerization reaction Methods 0.000 description 35
• 239000003973 paint Substances 0.000 description 29
• 239000002253 acid Substances 0.000 description 24
• LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 21
• LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 20
• 150000002148 esters Chemical class 0.000 description 19
• 229910052751 metal Inorganic materials 0.000 description 19
• 239000002184 metal Substances 0.000 description 19
• VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 18
• 239000011230 binding agent Substances 0.000 description 17
• 238000006243 chemical reaction Methods 0.000 description 17
• MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 16
• XQDFIWLWXYFYOY-UHFFFAOYSA-N [SiH3]CCCOC(=O)C=C Chemical compound [SiH3]CCCOC(=O)C=C XQDFIWLWXYFYOY-UHFFFAOYSA-N 0.000 description 15
• 238000007720 emulsion polymerization reaction Methods 0.000 description 15
• 150000002763 monocarboxylic acids Chemical class 0.000 description 15
• 239000002904 solvent Substances 0.000 description 15
• 238000012360 testing method Methods 0.000 description 15
• PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 14
• CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 14
• CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical class CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 14
• 239000003431 cross linking reagent Substances 0.000 description 14
• 239000000945 filler Substances 0.000 description 14
• 150000007513 acids Chemical class 0.000 description 13
• 229920001577 copolymer Polymers 0.000 description 13
• 238000004132 cross linking Methods 0.000 description 13
• OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 12
• OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 12
• 150000001252 acrylic acid derivatives Chemical class 0.000 description 12
• 239000003995 emulsifying agent Substances 0.000 description 12
• 125000000524 functional group Chemical group 0.000 description 12
• 239000001257 hydrogen Substances 0.000 description 12
• 229910052739 hydrogen Inorganic materials 0.000 description 12
• 125000004435 hydrogen atom Chemical class [H]* 0.000 description 12
• 229910052757 nitrogen Inorganic materials 0.000 description 12
• 239000004417 polycarbonate Substances 0.000 description 12
• 229920005862 polyol Polymers 0.000 description 12
• 150000003077 polyols Chemical class 0.000 description 12
• BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 11
• 150000003839 salts Chemical group 0.000 description 11
• 239000000758 substrate Substances 0.000 description 11
• NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical class OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 10
• QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 10
• 150000001298 alcohols Chemical class 0.000 description 10
• 150000001991 dicarboxylic acids Chemical class 0.000 description 10
• 239000003999 initiator Substances 0.000 description 10
• DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 10
• VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 10
• XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 9
• XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 9
• 239000004721 Polyphenylene oxide Substances 0.000 description 9
• 230000000694 effects Effects 0.000 description 9
• 229920000570 polyether Polymers 0.000 description 9
• 150000003254 radicals Chemical class 0.000 description 9
• 239000000377 silicon dioxide Substances 0.000 description 9
• 239000000126 substance Substances 0.000 description 9
• 238000012546 transfer Methods 0.000 description 9
• SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 8
• 229910052783 alkali metal Inorganic materials 0.000 description 8
• 229940052303 ethers for general anesthesia Drugs 0.000 description 8
• 125000000468 ketone group Chemical group 0.000 description 8
• 150000002739 metals Chemical class 0.000 description 8
• 239000003607 modifier Substances 0.000 description 8
• 229920003229 poly(methyl methacrylate) Polymers 0.000 description 8
• 229920000515 polycarbonate Polymers 0.000 description 8
• 239000004926 polymethyl methacrylate Substances 0.000 description 8
• 239000002562 thickening agent Substances 0.000 description 8
• VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 7
• IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 7
• VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 7
• 125000003172 aldehyde group Chemical group 0.000 description 7
• 238000009835 boiling Methods 0.000 description 7
• DKPFZGUDAPQIHT-UHFFFAOYSA-N butyl acetate Chemical compound CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 7
• 239000003795 chemical substances by application Substances 0.000 description 7
• 238000001723 curing Methods 0.000 description 7
• 239000000839 emulsion Substances 0.000 description 7
• 229930195733 hydrocarbon Natural products 0.000 description 7
• 150000002430 hydrocarbons Chemical class 0.000 description 7
• 125000002768 hydroxyalkyl group Chemical group 0.000 description 7
• 229920001223 polyethylene glycol Polymers 0.000 description 7
• 239000007787 solid Substances 0.000 description 7
• TXDNPSYEJHXKMK-UHFFFAOYSA-N sulfanylsilane Chemical group S[SiH3] TXDNPSYEJHXKMK-UHFFFAOYSA-N 0.000 description 7
• CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
• OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
• 229910000831 Steel Inorganic materials 0.000 description 6
• YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
• 229920002877 acrylic styrene acrylonitrile Polymers 0.000 description 6
• 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 6
• 229910045601 alloy Inorganic materials 0.000 description 6
• 239000000956 alloy Substances 0.000 description 6
• XXROGKLTLUQVRX-UHFFFAOYSA-N allyl alcohol Chemical compound OCC=C XXROGKLTLUQVRX-UHFFFAOYSA-N 0.000 description 6
• 229910052782 aluminium Inorganic materials 0.000 description 6
• 230000015572 biosynthetic process Effects 0.000 description 6
• 150000001735 carboxylic acids Chemical class 0.000 description 6
• HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 6
• 239000004816 latex Substances 0.000 description 6
• 229920000126 latex Polymers 0.000 description 6
• VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 6
• 239000011976 maleic acid Substances 0.000 description 6
• 239000002105 nanoparticle Substances 0.000 description 6
• 229920000728 polyester Polymers 0.000 description 6
• BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 6
• SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 6
• 239000010959 steel Substances 0.000 description 6
• CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 6
• XSQUKJJJFZCRTK-UHFFFAOYSA-N urea group Chemical group NC(=O)N XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 6
• JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 5
• ATVJXMYDOSMEPO-UHFFFAOYSA-N 3-prop-2-enoxyprop-1-ene Chemical compound C=CCOCC=C ATVJXMYDOSMEPO-UHFFFAOYSA-N 0.000 description 5
• QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 5
• KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 5
• CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 5
• 239000002202 Polyethylene glycol Substances 0.000 description 5
• 239000004743 Polypropylene Substances 0.000 description 5
• GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 5
• XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 5
• 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 5
• 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 5
• 229910021529 ammonia Inorganic materials 0.000 description 5
• 125000003118 aryl group Chemical group 0.000 description 5
• 238000001035 drying Methods 0.000 description 5
• 235000011187 glycerol Nutrition 0.000 description 5
• 238000000265 homogenisation Methods 0.000 description 5
• 125000002887 hydroxy group Chemical group [H]O* 0.000 description 5
• WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 5
• YAMHXTCMCPHKLN-UHFFFAOYSA-N imidazolidin-2-one Chemical class O=C1NCCN1 YAMHXTCMCPHKLN-UHFFFAOYSA-N 0.000 description 5
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• LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 5
• IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 5
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• 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 5
• 150000003378 silver Chemical class 0.000 description 5
• HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 description 5
• 235000010262 sodium metabisulphite Nutrition 0.000 description 5
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• MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 4
• LCZVSXRMYJUNFX-UHFFFAOYSA-N 2-[2-(2-hydroxypropoxy)propoxy]propan-1-ol Chemical class CC(O)COC(C)COC(C)CO LCZVSXRMYJUNFX-UHFFFAOYSA-N 0.000 description 4
• YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 description 4
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• 229910000838 Al alloy Inorganic materials 0.000 description 4
• CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 4
• VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
• HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 4
• 239000004971 Cross linker Substances 0.000 description 4
• WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 4
• UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 4
• 229930194542 Keto Natural products 0.000 description 4
• LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 4
• 101710113246 Pectinesterase 3 Proteins 0.000 description 4
• WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
• 229910021536 Zeolite Inorganic materials 0.000 description 4
• 229910001297 Zn alloy Inorganic materials 0.000 description 4
• 150000001408 amides Chemical class 0.000 description 4
• 125000000129 anionic group Chemical group 0.000 description 4
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