JP5862979B2 - 鉄空気再充電可能電池 - Google Patents
鉄空気再充電可能電池 Download PDFInfo
- Publication number
- JP5862979B2 JP5862979B2 JP2013520885A JP2013520885A JP5862979B2 JP 5862979 B2 JP5862979 B2 JP 5862979B2 JP 2013520885 A JP2013520885 A JP 2013520885A JP 2013520885 A JP2013520885 A JP 2013520885A JP 5862979 B2 JP5862979 B2 JP 5862979B2
- Authority
- JP
- Japan
- Prior art keywords
- electrode
- iron
- air
- hydrogen
- battery
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 title claims description 147
- 229910052742 iron Inorganic materials 0.000 title claims description 68
- 229910052739 hydrogen Inorganic materials 0.000 claims description 41
- 239000001257 hydrogen Substances 0.000 claims description 41
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 39
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 36
- 239000003792 electrolyte Substances 0.000 claims description 22
- 239000001569 carbon dioxide Substances 0.000 claims description 18
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 18
- 239000003054 catalyst Substances 0.000 claims description 17
- 238000000034 method Methods 0.000 claims description 17
- 230000002745 absorbent Effects 0.000 claims description 12
- 239000002250 absorbent Substances 0.000 claims description 12
- 239000002131 composite material Substances 0.000 claims description 11
- 238000009792 diffusion process Methods 0.000 claims description 10
- 239000007789 gas Substances 0.000 claims description 10
- 239000000758 substrate Substances 0.000 claims description 8
- 239000000654 additive Substances 0.000 claims description 6
- 229910052797 bismuth Inorganic materials 0.000 claims description 6
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims description 6
- 238000007599 discharging Methods 0.000 claims description 6
- 239000010409 thin film Substances 0.000 claims description 6
- 230000000996 additive effect Effects 0.000 claims description 5
- -1 alkyl disulfides Chemical class 0.000 claims description 5
- 229920002873 Polyethylenimine Polymers 0.000 claims description 4
- 229910052596 spinel Inorganic materials 0.000 claims description 4
- 239000011029 spinel Substances 0.000 claims description 4
- 239000002202 Polyethylene glycol Substances 0.000 claims description 2
- 150000001412 amines Chemical class 0.000 claims description 2
- 150000001504 aryl thiols Chemical class 0.000 claims description 2
- 238000003795 desorption Methods 0.000 claims description 2
- 239000007788 liquid Substances 0.000 claims description 2
- 239000000049 pigment Substances 0.000 claims description 2
- 229920001223 polyethylene glycol Polymers 0.000 claims description 2
- 239000013589 supplement Substances 0.000 claims description 2
- 125000001741 organic sulfur group Chemical group 0.000 claims 2
- 239000002086 nanomaterial Substances 0.000 claims 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 description 17
- 239000010410 layer Substances 0.000 description 16
- 229910052760 oxygen Inorganic materials 0.000 description 13
- 239000001301 oxygen Substances 0.000 description 13
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 8
- 229910052799 carbon Inorganic materials 0.000 description 8
- 230000008569 process Effects 0.000 description 7
- 230000001588 bifunctional effect Effects 0.000 description 6
- 230000003647 oxidation Effects 0.000 description 6
- 238000007254 oxidation reaction Methods 0.000 description 6
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 5
- 238000010521 absorption reaction Methods 0.000 description 5
- 230000008901 benefit Effects 0.000 description 5
- 230000015556 catabolic process Effects 0.000 description 5
- 238000006731 degradation reaction Methods 0.000 description 5
- 238000004146 energy storage Methods 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000011148 porous material Substances 0.000 description 4
- 230000008929 regeneration Effects 0.000 description 4
- 238000011069 regeneration method Methods 0.000 description 4
- 239000013545 self-assembled monolayer Substances 0.000 description 4
- 238000004544 sputter deposition Methods 0.000 description 4
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 238000013461 design Methods 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 239000000446 fuel Substances 0.000 description 3
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 3
- 229910052753 mercury Inorganic materials 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 231100000252 nontoxic Toxicity 0.000 description 3
- 230000003000 nontoxic effect Effects 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 239000000969 carrier Substances 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 238000000151 deposition Methods 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 238000003487 electrochemical reaction Methods 0.000 description 2
- 238000003411 electrode reaction Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 2
- 150000003949 imides Chemical class 0.000 description 2
- UGKDIUIOSMUOAW-UHFFFAOYSA-N iron nickel Chemical compound [Fe].[Ni] UGKDIUIOSMUOAW-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 150000008427 organic disulfides Chemical class 0.000 description 2
- ZZSIDSMUTXFKNS-UHFFFAOYSA-N perylene red Chemical compound CC(C)C1=CC=CC(C(C)C)=C1N(C(=O)C=1C2=C3C4=C(OC=5C=CC=CC=5)C=1)C(=O)C2=CC(OC=1C=CC=CC=1)=C3C(C(OC=1C=CC=CC=1)=CC1=C2C(C(N(C=3C(=CC=CC=3C(C)C)C(C)C)C1=O)=O)=C1)=C2C4=C1OC1=CC=CC=C1 ZZSIDSMUTXFKNS-UHFFFAOYSA-N 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 230000002441 reversible effect Effects 0.000 description 2
- 238000000682 scanning probe acoustic microscopy Methods 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 150000003573 thiols Chemical class 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- 101100325906 Bacillus subtilis (strain 168) ganA gene Proteins 0.000 description 1
- 229910018921 CoO 3 Inorganic materials 0.000 description 1
- 229910003266 NiCo Inorganic materials 0.000 description 1
- 101100111413 Thermoanaerobacter pseudethanolicus (strain ATCC 33223 / 39E) lacZ gene Proteins 0.000 description 1
- FSYNRRRTKKERNG-UHFFFAOYSA-N [Ir]=O.[Bi] Chemical compound [Ir]=O.[Bi] FSYNRRRTKKERNG-UHFFFAOYSA-N 0.000 description 1
- KSHLPUIIJIOBOQ-UHFFFAOYSA-N [O--].[O--].[O--].[O--].[Co++].[Ni++] Chemical compound [O--].[O--].[O--].[O--].[Co++].[Ni++] KSHLPUIIJIOBOQ-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000001335 aliphatic alkanes Chemical group 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- NNLOHLDVJGPUFR-UHFFFAOYSA-L calcium;3,4,5,6-tetrahydroxy-2-oxohexanoate Chemical compound [Ca+2].OCC(O)C(O)C(O)C(=O)C([O-])=O.OCC(O)C(O)C(O)C(=O)C([O-])=O NNLOHLDVJGPUFR-UHFFFAOYSA-L 0.000 description 1
- 150000005323 carbonate salts Chemical class 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 230000001351 cycling effect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 description 1
- 230000005518 electrochemistry Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 230000005661 hydrophobic surface Effects 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- NNLJGFCRHBKPPJ-UHFFFAOYSA-N iron lanthanum Chemical compound [Fe].[La] NNLJGFCRHBKPPJ-UHFFFAOYSA-N 0.000 description 1
- 229910021506 iron(II) hydroxide Inorganic materials 0.000 description 1
- NCNCGGDMXMBVIA-UHFFFAOYSA-L iron(ii) hydroxide Chemical compound [OH-].[OH-].[Fe+2] NCNCGGDMXMBVIA-UHFFFAOYSA-L 0.000 description 1
- 101150086432 lacA gene Proteins 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 1
- 239000011244 liquid electrolyte Substances 0.000 description 1
- 229910001416 lithium ion Inorganic materials 0.000 description 1
- 150000002678 macrocyclic compounds Chemical class 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 150000002898 organic sulfur compounds Chemical class 0.000 description 1
- 238000010525 oxidative degradation reaction Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 230000003071 parasitic effect Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 238000005546 reactive sputtering Methods 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 238000002207 thermal evaporation Methods 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
- H01M4/521—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of iron for aqueous cells
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/42—Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
- H01M10/4235—Safety or regulating additives or arrangements in electrodes, separators or electrolyte
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M12/00—Hybrid cells; Manufacture thereof
- H01M12/08—Hybrid cells; Manufacture thereof composed of a half-cell of a fuel-cell type and a half-cell of the secondary-cell type
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/8605—Porous electrodes
- H01M4/8626—Porous electrodes characterised by the form
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Chemistry (AREA)
- Hybrid Cells (AREA)
- Inert Electrodes (AREA)
Description
本出願は、2010年7月22日に出願された米国仮出願第61/366,696号(その開示内容がその全体において参考として本明細書に組み込まれる)の便益を主張する。
Fe+1/2 O2+H2O→Fe(OH)2 (1)
式1の逆反応は、充電の間に起こる。放電の間に、陰極上の鉄が水酸化鉄(II)に酸化され、陽極において酸素が還元されて水を形成する。これらのプロセスは電池の充電の間に逆になる。放電の間の個々の電極反応は以下の式によって示される。
(+)電極:1/2 O2+H2O+2e−→2OH− (1a)
(−)電極:Fe+2OH−→Fe(OH)2+2e− (1b)
Fe+2H2O→Fe(OH)2+H2 (式2)
発生した水素が利用されないまま残されている場合、効率および電解質のかなりの損失が生じる。水素発生の電極電位はほぼ鉄−電極反応の電極電位であり、したがって水素は同様に充電の間に鉄電極上に発生する。この水素は放電反応(式1b)に関与しないので、往復効率はさらに低減される。
Fe+2H2O→Fe(OH)2+H2 (2)
鉄電極12の表面から水を排除することによってこの反応を防ぐことができる。長鎖アルカンチオール、二硫化アルキル、非置換および置換アリールチオール、およびヒドロキシアルカンチオールは、電極上に撥水性単分子層を自己組織化することが知られている。適した置換基の例には、NO2、C1〜C6アルキル、ハロゲン(例えば、Cl、Br、F、I)、SO3H、OH、C1〜C6アルコキシド、フェニル等があるがそれらに限定されない。この実施形態はこの特性を利用して水を鉄電極12から排除し、それによって自己放電を抑える。
Fe+2OH−→Fe(OH)2+2e− (1b)
によって示される。
しかし、充電の間に以下の反応(式3)も鉄の表面上で起こり、これは主反応(式1b)と競合し、充電効率の低下をもたらす。
2H2O+2e−→H2+2OH− (3)
全反応:H2+1/2O2→H2O
アノード:H2+2OH−→2H2O+2e−
カソード:1/2O2+H2O+2e−→2OH−
Claims (17)
- 鉄電極とそれと統合された水素電極とを備える複合電極と、
前記複合電極から離隔された空気電極と、
前記複合電極および前記空気電極と接触している電解質とを含み、
前記鉄電極および前記水素電極が、前記鉄電極および前記水素電極間で挟持される絶縁層によって電気的に絶縁されており、
前記鉄電極および前記水素電極が別個の電気コンタクトを有し、それぞれの充電/放電制御装置と連通していることを特徴とする、鉄空気再充電可能電池。 - 請求項1に記載の電池において、自己組織化有機硫黄系添加剤を前記電解質中にさらに含むことを特徴とする電池。
- 請求項2に記載の電池において、前記有機硫黄系添加剤がアルカンチオール、二硫化アルキル、非置換および置換アリールチオール、およびヒドロキシアルカンチオールからなる群から選択されることを特徴とする電池。
- 請求項1に記載の電池において、前記鉄電極がビスマス添加剤を含むことを特徴とする電池。
- 請求項1に記載の電池において、前記鉄電極が、前記電解質の経路のための孔を有する多孔性導電構造物で被覆されることを特徴とする電池。
- 請求項1に記載の電池において、前記空気電極のための触媒担体としてナノ構造ホイスカー基材をさらに含んでおり、前記ホイスカー基材がカルボキシジイミド(Carboxidimide)顔料およびフタロシアニンの少なくとも1つから調製されることを特徴とする電池。
- 請求項6に記載の電池において、前記ナノ構造ホイスカー基材が薄い触媒活性酸化物層でコートされることを特徴とする電池。
- 請求項7に記載の電池において、前記酸化物層がペロブスカイト酸化物、パイロクロア酸化物、またはスピネル酸化物の少なくとも1つを含有することを特徴とする電池。
- 請求項1に記載の電池において、前記空気電極がガス拡散層上に担持された薄膜ナノ構造触媒層を含有することを特徴とする電池。
- 請求項1に記載の電池において、前記空気電極に供給される空気から二酸化炭素を急速に吸着する二酸化炭素管理システムをさらに含むことを特徴とする電池。
- 請求項10に記載の電池において、前記二酸化炭素管理システムが、前記電池上の充電および放電運転の間に再生される二酸化炭素吸収剤を備えることを特徴とする電池。
- 請求項11に記載の電池において、前記吸収剤が、入って来る空気が通過させられて二酸化炭素を弱く結合するナノ構造シリカ担持有機アミン吸収剤を含有することを特徴とする電池。
- 請求項12に記載の電池において、前記吸収剤が、ポリエチレンイミン、ポリエチレングリコール、およびポリ(イオン)液体からなる群から選択されることを特徴とする電池。
- 請求項11に記載の電池において、充電の間に前記電池から発生された熱が、前記吸収剤からの二酸化炭素の脱着のための熱エネルギーを提供するために使用されることを特徴とする電池。
- 鉄電極とそれと統合された水素電極とを備える複合電極と、前記鉄電極から離隔された空気電極と、前記鉄電極および前記空気電極と接触している電解質とを含む鉄空気電池を充電するための方法において、
前記水素電極を放電させる間に同時に前記鉄電極を充電する工程を含んでおり、
前記鉄電極および前記水素電極が、前記鉄電極および前記水素電極間で挟持される絶縁層によって電気的に絶縁されており、
前記鉄電極および前記水素電極が別個の電気コンタクトを有し、それぞれの充電/放電制御装置と連通している、ことを特徴とする方法。 - 請求項15に記載の方法において、前記水素電極から発生された電力を充電システムに供給して前記鉄電極を充電するために必要とされた電力の少なくとも一部を補う工程をさらに含むことを特徴とする方法。
- 請求項15に記載の方法において、運転していない間に発生された水素を使用して前記鉄空気電池を細流充電する工程をさらに含むことを特徴とする方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US36669610P | 2010-07-22 | 2010-07-22 | |
US61/366,696 | 2010-07-22 | ||
PCT/US2011/045030 WO2012012731A2 (en) | 2010-07-22 | 2011-07-22 | Iron-air rechargeable battery |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2013535775A JP2013535775A (ja) | 2013-09-12 |
JP5862979B2 true JP5862979B2 (ja) | 2016-02-16 |
Family
ID=45497488
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2013520885A Active JP5862979B2 (ja) | 2010-07-22 | 2011-07-22 | 鉄空気再充電可能電池 |
Country Status (5)
Country | Link |
---|---|
US (1) | US8758948B2 (ja) |
EP (2) | EP2596545B1 (ja) |
JP (1) | JP5862979B2 (ja) |
CN (1) | CN103098299B (ja) |
WO (1) | WO2012012731A2 (ja) |
Families Citing this family (24)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103597655B (zh) | 2011-06-15 | 2017-08-04 | 南加利福尼亚大学 | 高效率铁电极以及在可充电铁基电池中使用的添加剂 |
JP5910076B2 (ja) * | 2011-12-27 | 2016-04-27 | 住友化学株式会社 | 二酸化炭素の吸着脱離が可能な部位を備えたアルカリ型電池 |
WO2013169391A1 (en) * | 2012-05-08 | 2013-11-14 | Stc. Unm | Improved hydrothermal stability of oxides with carbon coatings |
EP3462531B8 (en) * | 2013-02-06 | 2020-04-29 | Encell Technology, Inc. | Battery comprising a coated iron anode and improved performance |
WO2014124123A1 (en) | 2013-02-06 | 2014-08-14 | Encell Technology, Inc. | Nickel iron battery employing untreated polyolefin separator with a surfactant in the electrolyte |
US10847843B2 (en) | 2013-02-06 | 2020-11-24 | Encell Technology, Inc. | Electrolyte for a nickel-iron battery |
US10854926B2 (en) | 2013-02-06 | 2020-12-01 | Encell Technology, Inc. | Nickel-iron battery with high cycle life |
US10804573B2 (en) | 2013-02-06 | 2020-10-13 | Encell Technology, Inc. | Electrolyte for battery containing an iron electrode |
US9450233B2 (en) | 2013-02-06 | 2016-09-20 | Encell Technology, Inc. | Battery comprising a coated iron anode |
US10868338B2 (en) | 2013-02-06 | 2020-12-15 | Encell Technology, Inc. | Nickel-iron battery with high power |
MX2015009647A (es) | 2013-02-06 | 2016-04-25 | Encell Technology Inc | Proceso para formar una bateria que contiene un electrodo de hierro. |
US9941548B2 (en) * | 2013-06-20 | 2018-04-10 | Landmark Battery Innovations, Inc. | Nickel iron battery |
EP3050152B1 (en) * | 2013-09-23 | 2018-11-07 | University of Southern California | A high efficiency nickel-iron battery |
JP2015079692A (ja) * | 2013-10-18 | 2015-04-23 | トヨタ自動車株式会社 | 金属空気電池 |
US10218017B2 (en) * | 2015-03-30 | 2019-02-26 | Nantenergy, Inc. | Water management system in electrochemical cells with vapor return comprising air electrodes |
CN105048024B (zh) * | 2015-08-04 | 2017-05-03 | 东北石油大学 | 一种可充熔盐铁‑空气电池以及制备方法 |
US11018387B2 (en) | 2016-07-22 | 2021-05-25 | Form Energy, Inc. | Moisture and carbon dioxide management system in electrochemical cells |
US11394035B2 (en) | 2017-04-06 | 2022-07-19 | Form Energy, Inc. | Refuelable battery for the electric grid and method of using thereof |
US11611115B2 (en) | 2017-12-29 | 2023-03-21 | Form Energy, Inc. | Long life sealed alkaline secondary batteries |
WO2020023912A1 (en) | 2018-07-27 | 2020-01-30 | Form Energy Inc. | Negative electrodes for electrochemical cells |
US11973254B2 (en) | 2018-06-29 | 2024-04-30 | Form Energy, Inc. | Aqueous polysulfide-based electrochemical cell |
US20220352527A1 (en) | 2019-10-04 | 2022-11-03 | Form Energy, Inc. | Refuelable battery for the electric grid and method of using thereof |
CN113823821B (zh) * | 2020-06-19 | 2024-01-30 | 中国科学院苏州纳米技术与纳米仿生研究所 | 一种铁-氢储能电池及其应用 |
KR20220063393A (ko) * | 2020-11-10 | 2022-05-17 | 주식회사 엘지에너지솔루션 | 가스 포집용 부재를 포함하는 이차 전지 |
Family Cites Families (26)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1242832A (en) * | 1969-02-11 | 1971-08-11 | Westinghouse Electric Corp | Metal-air battery containing an auxiliary electrode |
US3650835A (en) * | 1969-12-16 | 1972-03-21 | Westinghouse Electric Corp | Preparation of battery plates with iron oxides having a fused coating |
GB1359746A (en) * | 1971-02-18 | 1974-07-10 | Wenstingouse Electric Corp | Negative iron battery electrodes |
JPS564030B2 (ja) * | 1972-02-24 | 1981-01-28 | ||
DE2326070C3 (de) * | 1973-05-22 | 1979-10-25 | Siemens Ag, 1000 Berlin Und 8000 Muenchen | Vorrichtung zur Entfernung von Kohlendioxid aus zum Betrieb von elektrochemischen Zellen dienender Luft |
JPS5212374B2 (ja) * | 1974-06-04 | 1977-04-06 | ||
US3935027A (en) * | 1975-04-09 | 1976-01-27 | Westinghouse Electric Corporation | Oxygen-reduction electrocatalysts for electrodes |
US4032693A (en) | 1976-08-27 | 1977-06-28 | Ab Olle Lindstrom | Procedure to stabilize an iron air battery |
US5039561A (en) | 1986-08-25 | 1991-08-13 | Minnesota Mining And Manufacturing Company | Method for preparing an article having surface layer of uniformly oriented, crystalline, organic microstructures |
WO1993009573A1 (en) * | 1991-11-04 | 1993-05-13 | Battery Technologies International (C.H.O.) Ltd. | Metal-air storage battery, rechargeable by addition of hydrogen |
US5595949A (en) * | 1994-03-18 | 1997-01-21 | Electric Fuel (E.F.L.) Ltd., | Scrubber system for removing carbon dioxide from a metal-air or fuel cell battery |
JP2655810B2 (ja) * | 1994-04-08 | 1997-09-24 | 工業技術院長 | アルカリ二次電池及び触媒性電極体の製造法 |
JP3954793B2 (ja) | 2000-12-04 | 2007-08-08 | 三洋電機株式会社 | 燃料電池用ガス拡散層およびその製法 |
SE0100927D0 (sv) * | 2001-03-16 | 2001-03-16 | Kth Holding Ab | Oxygen reduction electrode |
US6706432B2 (en) | 2001-08-01 | 2004-03-16 | Magpower Systems, Inc. | Methods and products for improving performance of batteries/fuel cells |
US7020355B2 (en) * | 2001-11-02 | 2006-03-28 | Massachusetts Institute Of Technology | Switchable surfaces |
NO320029B1 (no) * | 2003-07-07 | 2005-10-10 | Revolt Technology As | Fremgangsmate for fremstilling av gassdiffusjonselektroder |
NO325620B1 (no) * | 2003-10-21 | 2008-06-30 | Revolt Technology Ltd | Elektrode, fremgangsmate for fremstilling derav, metall/luft-brenselcelle og metallhydrid-battericelle |
KR100552697B1 (ko) | 2003-11-13 | 2006-02-20 | 삼성에스디아이 주식회사 | 금속 산화물-탄소 복합체로 이루어진 촉매 담체 및 이를이용한연료전지 |
TWI258239B (en) * | 2004-06-02 | 2006-07-11 | High Tech Battery Inc | Air electrode constituting multilayer sintered structure and manufacturing method thereof |
WO2005119830A1 (ja) * | 2004-06-01 | 2005-12-15 | Matsushita Electric Industrial Co., Ltd. | アルカリ電池の外装体用薄膜およびそれを用いた薄型空気電池 |
US7638216B2 (en) * | 2005-12-21 | 2009-12-29 | General Electric Company | Fuel cell apparatus and associated method |
US7695840B2 (en) * | 2006-12-08 | 2010-04-13 | Eveready Battery Co., Inc. | Electrochemical cell having a deposited gas electrode |
JP2008293678A (ja) | 2007-05-22 | 2008-12-04 | Doshisha | 半電池および該半電池を用いた空気二次電池 |
JP2009129646A (ja) | 2007-11-21 | 2009-06-11 | Toyota Central R&D Labs Inc | 固体高分子型燃料電池 |
WO2011014818A1 (en) | 2009-07-31 | 2011-02-03 | Revolt Technology Ltd. | Air electrode with binder materials and manufacturing methods for air electrode |
-
2011
- 2011-07-22 JP JP2013520885A patent/JP5862979B2/ja active Active
- 2011-07-22 EP EP11810468.6A patent/EP2596545B1/en active Active
- 2011-07-22 CN CN201180042531.1A patent/CN103098299B/zh active Active
- 2011-07-22 US US13/189,038 patent/US8758948B2/en active Active
- 2011-07-22 WO PCT/US2011/045030 patent/WO2012012731A2/en active Application Filing
- 2011-07-22 EP EP18170691.2A patent/EP3386011B1/en active Active
Also Published As
Publication number | Publication date |
---|---|
EP3386011B1 (en) | 2023-02-15 |
CN103098299A (zh) | 2013-05-08 |
EP2596545A4 (en) | 2017-05-24 |
US8758948B2 (en) | 2014-06-24 |
EP2596545A2 (en) | 2013-05-29 |
EP3386011A1 (en) | 2018-10-10 |
WO2012012731A3 (en) | 2012-04-26 |
US20120187918A1 (en) | 2012-07-26 |
CN103098299B (zh) | 2016-03-16 |
EP2596545B1 (en) | 2018-06-13 |
WO2012012731A2 (en) | 2012-01-26 |
JP2013535775A (ja) | 2013-09-12 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP5862979B2 (ja) | 鉄空気再充電可能電池 | |
Selvakumaran et al. | A review on recent developments and challenges of cathode materials for rechargeable aqueous Zn-ion batteries | |
Wang et al. | Parametric study and optimization of a low-cost paper-based Al-air battery with corrosion inhibition ability | |
US10910674B2 (en) | Additive for increasing lifespan of rechargeable zinc-anode batteries | |
JP5777511B2 (ja) | リチウムメディエータを有する鉄−空気蓄電池 | |
US20200235385A1 (en) | Lithium secondary battery negative electrode including protection layer made of conductive fabric, and lithium secondary battery including same | |
KR20140039022A (ko) | 전지 | |
KR20140068850A (ko) | 충전식 철-기반 배터리에 사용되는 고효율 철 전극 및 첨가제 | |
KR20080083112A (ko) | 이기능성 공기 전극 | |
TW201421785A (zh) | 具有高密度之陽極活性材料及其製法 | |
CN111328435B (zh) | 具有改进安全性的锂金属二次电池和包含其的电池模块 | |
KR20150020227A (ko) | 탄소-담지 망간 산화물 촉매의 제조 방법 및 재충전가능한 리튬-에어 배터리에서의 그의 용도 | |
US10522869B2 (en) | Battery, battery pack, and uninterruptible power supply | |
JP5434062B2 (ja) | 空気電池 | |
CN114846645A (zh) | 包含氧化的集流体的锂二次电池用负极及其制造方法 | |
CN114141981B (zh) | 一种正极极片及其制备方法和应用 | |
WO2017177960A1 (zh) | 电解液、电池和电池组 | |
KR20120073757A (ko) | 신규한 양극 활물질 및 이를 포함하는 마그네슘 이차전지 | |
CN108780920A (zh) | 具有有机电极的高离子导电性可充电固态电池 | |
JP5557385B2 (ja) | プロトンを挿入種とする蓄電デバイス | |
Ghareghashi et al. | Anode Materials for Zinc‐Air Batteries | |
CN110088940B (zh) | 电池单元用隔膜和具有这种隔膜的电池单元 | |
WO2021148836A1 (en) | Naphthalene based lithium compounds, a process for their preparation, their use as solid organic catalyst, and their use in rechargeable non-aqueous lithium-air battery cells | |
Narayan et al. | Iron-air rechargeable battery | |
WO2016152055A1 (en) | Transition metal cyanometallate cathode battery with metal plating anode |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20140718 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20150318 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20150512 |
|
A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20150811 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20150909 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20151117 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20151216 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 5862979 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |