JP5833744B2 - 織物積層発泡体製品の製造方法 - Google Patents
織物積層発泡体製品の製造方法 Download PDFInfo
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- JP5833744B2 JP5833744B2 JP2014509828A JP2014509828A JP5833744B2 JP 5833744 B2 JP5833744 B2 JP 5833744B2 JP 2014509828 A JP2014509828 A JP 2014509828A JP 2014509828 A JP2014509828 A JP 2014509828A JP 5833744 B2 JP5833744 B2 JP 5833744B2
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- Prior art keywords
- foam
- foam composition
- polyol
- mold
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000006260 foam Substances 0.000 title claims description 490
- 238000004519 manufacturing process Methods 0.000 title claims description 14
- 239000000203 mixture Substances 0.000 claims description 274
- 229920005862 polyol Polymers 0.000 claims description 163
- 150000003077 polyols Chemical class 0.000 claims description 161
- 239000004744 fabric Substances 0.000 claims description 86
- 238000000034 method Methods 0.000 claims description 75
- 239000003054 catalyst Substances 0.000 claims description 73
- 239000012948 isocyanate Substances 0.000 claims description 60
- 150000002513 isocyanates Chemical class 0.000 claims description 60
- 239000004094 surface-active agent Substances 0.000 claims description 57
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 26
- 238000005187 foaming Methods 0.000 claims description 17
- 238000007664 blowing Methods 0.000 claims description 12
- 230000008569 process Effects 0.000 claims description 8
- 239000004088 foaming agent Substances 0.000 claims 1
- 239000000047 product Substances 0.000 description 49
- 238000006243 chemical reaction Methods 0.000 description 27
- 210000004027 cell Anatomy 0.000 description 26
- 239000004604 Blowing Agent Substances 0.000 description 20
- -1 3-dimethylaminopropyl Chemical group 0.000 description 19
- 238000002156 mixing Methods 0.000 description 16
- 238000009472 formulation Methods 0.000 description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 15
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 12
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 12
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 11
- 229910052710 silicon Inorganic materials 0.000 description 11
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 11
- 230000035515 penetration Effects 0.000 description 10
- 239000010703 silicon Substances 0.000 description 10
- 229920000642 polymer Polymers 0.000 description 9
- 239000004814 polyurethane Substances 0.000 description 9
- 230000015572 biosynthetic process Effects 0.000 description 8
- 239000003795 chemical substances by application Substances 0.000 description 8
- 238000009826 distribution Methods 0.000 description 8
- 229920002635 polyurethane Polymers 0.000 description 8
- 239000000463 material Substances 0.000 description 7
- 238000002360 preparation method Methods 0.000 description 7
- 238000000926 separation method Methods 0.000 description 7
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 6
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 6
- 239000004721 Polyphenylene oxide Substances 0.000 description 6
- 229920005830 Polyurethane Foam Polymers 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 229920001577 copolymer Polymers 0.000 description 6
- 229920000570 polyether Polymers 0.000 description 6
- 229920001228 polyisocyanate Polymers 0.000 description 6
- 239000005056 polyisocyanate Substances 0.000 description 6
- 239000000758 substrate Substances 0.000 description 6
- 150000001412 amines Chemical class 0.000 description 5
- 230000004888 barrier function Effects 0.000 description 5
- 239000002131 composite material Substances 0.000 description 5
- 239000003431 cross linking reagent Substances 0.000 description 5
- 210000000497 foam cell Anatomy 0.000 description 5
- 238000001879 gelation Methods 0.000 description 5
- 150000008282 halocarbons Chemical class 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- 239000011496 polyurethane foam Substances 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 210000000481 breast Anatomy 0.000 description 4
- 239000013518 molded foam Substances 0.000 description 4
- 239000004753 textile Substances 0.000 description 4
- 239000004215 Carbon black (E152) Substances 0.000 description 3
- 239000004971 Cross linker Substances 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- 229920013701 VORANOL™ Polymers 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 125000001931 aliphatic group Chemical group 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
- 229920001400 block copolymer Polymers 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 239000001569 carbon dioxide Substances 0.000 description 3
- 229910002092 carbon dioxide Inorganic materials 0.000 description 3
- 238000005520 cutting process Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 238000002347 injection Methods 0.000 description 3
- 239000007924 injection Substances 0.000 description 3
- 229920001296 polysiloxane Polymers 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 239000011541 reaction mixture Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- MTZUIIAIAKMWLI-UHFFFAOYSA-N 1,2-diisocyanatobenzene Chemical compound O=C=NC1=CC=CC=C1N=C=O MTZUIIAIAKMWLI-UHFFFAOYSA-N 0.000 description 2
- GTEXIOINCJRBIO-UHFFFAOYSA-N 2-[2-(dimethylamino)ethoxy]-n,n-dimethylethanamine Chemical compound CN(C)CCOCCN(C)C GTEXIOINCJRBIO-UHFFFAOYSA-N 0.000 description 2
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 229920005863 Lupranol® Polymers 0.000 description 2
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 description 2
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000006071 cream Substances 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 239000012975 dibutyltin dilaurate Substances 0.000 description 2
- 229940043276 diisopropanolamine Drugs 0.000 description 2
- 230000009189 diving Effects 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920005903 polyol mixture Polymers 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- 230000035484 reaction time Effects 0.000 description 2
- 125000004469 siloxy group Chemical group [SiH3]O* 0.000 description 2
- 229920001169 thermoplastic Polymers 0.000 description 2
- 239000004416 thermosoftening plastic Substances 0.000 description 2
- KSBAEPSJVUENNK-UHFFFAOYSA-L tin(ii) 2-ethylhexanoate Chemical compound [Sn+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O KSBAEPSJVUENNK-UHFFFAOYSA-L 0.000 description 2
- RUELTTOHQODFPA-UHFFFAOYSA-N toluene 2,6-diisocyanate Chemical compound CC1=C(N=C=O)C=CC=C1N=C=O RUELTTOHQODFPA-UHFFFAOYSA-N 0.000 description 2
- IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 description 2
- RSJKGSCJYJTIGS-UHFFFAOYSA-N undecane Chemical compound CCCCCCCCCCC RSJKGSCJYJTIGS-UHFFFAOYSA-N 0.000 description 2
- DGLFZUBOMRZNQX-UHFFFAOYSA-N 1,1,2,2,3,3-hexafluorocyclobutane Chemical compound FC1(F)CC(F)(F)C1(F)F DGLFZUBOMRZNQX-UHFFFAOYSA-N 0.000 description 1
- AJDIZQLSFPQPEY-UHFFFAOYSA-N 1,1,2-Trichlorotrifluoroethane Chemical compound FC(F)(Cl)C(F)(Cl)Cl AJDIZQLSFPQPEY-UHFFFAOYSA-N 0.000 description 1
- FRCHKSNAZZFGCA-UHFFFAOYSA-N 1,1-dichloro-1-fluoroethane Chemical compound CC(F)(Cl)Cl FRCHKSNAZZFGCA-UHFFFAOYSA-N 0.000 description 1
- DCQWACSEFXBOCJ-UHFFFAOYSA-N 1-isocyanato-6-(6-isocyanatohexylsulfanyl)hexane Chemical compound O=C=NCCCCCCSCCCCCCN=C=O DCQWACSEFXBOCJ-UHFFFAOYSA-N 0.000 description 1
- BYACHAOCSIPLCM-UHFFFAOYSA-N 2-[2-[bis(2-hydroxyethyl)amino]ethyl-(2-hydroxyethyl)amino]ethanol Chemical compound OCCN(CCO)CCN(CCO)CCO BYACHAOCSIPLCM-UHFFFAOYSA-N 0.000 description 1
- KSSJBGNOJJETTC-UHFFFAOYSA-N COC1=C(C=CC=C1)N(C1=CC=2C3(C4=CC(=CC=C4C=2C=C1)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)C1=CC(=CC=C1C=1C=CC(=CC=13)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)C1=CC=C(C=C1)OC Chemical compound COC1=C(C=CC=C1)N(C1=CC=2C3(C4=CC(=CC=C4C=2C=C1)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)C1=CC(=CC=C1C=1C=CC(=CC=13)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)C1=CC=C(C=C1)OC KSSJBGNOJJETTC-UHFFFAOYSA-N 0.000 description 1
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 1
- 239000004338 Dichlorodifluoromethane Substances 0.000 description 1
- 229920013704 Dow VORANOL™ 4701 Polyether Polyol Polymers 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229920005875 Lupranol® 2090 Polymers 0.000 description 1
- 239000004341 Octafluorocyclobutane Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- ADKPKEZZYOUGBZ-UHFFFAOYSA-N [C].[O].[Si] Chemical compound [C].[O].[Si] ADKPKEZZYOUGBZ-UHFFFAOYSA-N 0.000 description 1
- HMDDXIMCDZRSNE-UHFFFAOYSA-N [C].[Si] Chemical compound [C].[Si] HMDDXIMCDZRSNE-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000005273 aeration Methods 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000001588 bifunctional effect Effects 0.000 description 1
- OHJMTUPIZMNBFR-UHFFFAOYSA-N biuret Chemical group NC(=O)NC(N)=O OHJMTUPIZMNBFR-UHFFFAOYSA-N 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-N carbonic acid monoamide Natural products NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 210000000170 cell membrane Anatomy 0.000 description 1
- 229960001701 chloroform Drugs 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 230000009260 cross reactivity Effects 0.000 description 1
- ARUKYTASOALXFG-UHFFFAOYSA-N cycloheptylcycloheptane Chemical group C1CCCCCC1C1CCCCCC1 ARUKYTASOALXFG-UHFFFAOYSA-N 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- PXBRQCKWGAHEHS-UHFFFAOYSA-N dichlorodifluoromethane Chemical compound FC(F)(Cl)Cl PXBRQCKWGAHEHS-UHFFFAOYSA-N 0.000 description 1
- 235000019404 dichlorodifluoromethane Nutrition 0.000 description 1
- 229940042935 dichlorodifluoromethane Drugs 0.000 description 1
- UMNKXPULIDJLSU-UHFFFAOYSA-N dichlorofluoromethane Chemical compound FC(Cl)Cl UMNKXPULIDJLSU-UHFFFAOYSA-N 0.000 description 1
- 229940099364 dichlorofluoromethane Drugs 0.000 description 1
- KORSJDCBLAPZEQ-UHFFFAOYSA-N dicyclohexylmethane-4,4'-diisocyanate Chemical compound C1CC(N=C=O)CCC1CC1CCC(N=C=O)CC1 KORSJDCBLAPZEQ-UHFFFAOYSA-N 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- POLCUAVZOMRGSN-UHFFFAOYSA-N dipropyl ether Chemical compound CCCOCCC POLCUAVZOMRGSN-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000011953 free-radical catalyst Substances 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 229940052308 general anesthetics halogenated hydrocarbons Drugs 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 229910052736 halogen Chemical group 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 230000005802 health problem Effects 0.000 description 1
- 229920001903 high density polyethylene Polymers 0.000 description 1
- 239000004700 high-density polyethylene Substances 0.000 description 1
- 125000001183 hydrocarbyl group Chemical group 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 1
- 125000005647 linker group Chemical group 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- YTCQFLFGFXZUSN-BAQGIRSFSA-N microline Chemical compound OC12OC3(C)COC2(O)C(C(/Cl)=C/C)=CC(=O)C21C3C2 YTCQFLFGFXZUSN-BAQGIRSFSA-N 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- SKCNNQDRNPQEFU-UHFFFAOYSA-N n'-[3-(dimethylamino)propyl]-n,n,n'-trimethylpropane-1,3-diamine Chemical compound CN(C)CCCN(C)CCCN(C)C SKCNNQDRNPQEFU-UHFFFAOYSA-N 0.000 description 1
- 125000004971 nitroalkyl group Chemical group 0.000 description 1
- ZCYXXKJEDCHMGH-UHFFFAOYSA-N nonane Chemical compound CCCC[CH]CCCC ZCYXXKJEDCHMGH-UHFFFAOYSA-N 0.000 description 1
- BKIMMITUMNQMOS-UHFFFAOYSA-N normal nonane Natural products CCCCCCCCC BKIMMITUMNQMOS-UHFFFAOYSA-N 0.000 description 1
- 229940078552 o-xylene Drugs 0.000 description 1
- BCCOBQSFUDVTJQ-UHFFFAOYSA-N octafluorocyclobutane Chemical compound FC1(F)C(F)(F)C(F)(F)C1(F)F BCCOBQSFUDVTJQ-UHFFFAOYSA-N 0.000 description 1
- 235000019407 octafluorocyclobutane Nutrition 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 125000005474 octanoate group Chemical group 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 125000006353 oxyethylene group Chemical group 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 229920005906 polyester polyol Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- SCUZVMOVTVSBLE-UHFFFAOYSA-N prop-2-enenitrile;styrene Chemical compound C=CC#N.C=CC1=CC=CC=C1 SCUZVMOVTVSBLE-UHFFFAOYSA-N 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 125000005373 siloxane group Chemical group [SiH2](O*)* 0.000 description 1
- 150000003384 small molecules Chemical class 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 229920000638 styrene acrylonitrile Polymers 0.000 description 1
- 239000012970 tertiary amine catalyst Substances 0.000 description 1
- 239000012815 thermoplastic material Substances 0.000 description 1
- KJAMZCVTJDTESW-UHFFFAOYSA-N tiracizine Chemical compound C1CC2=CC=CC=C2N(C(=O)CN(C)C)C2=CC(NC(=O)OCC)=CC=C21 KJAMZCVTJDTESW-UHFFFAOYSA-N 0.000 description 1
- 125000005389 trialkylsiloxy group Chemical group 0.000 description 1
- CYRMSUTZVYGINF-UHFFFAOYSA-N trichlorofluoromethane Chemical compound FC(Cl)(Cl)Cl CYRMSUTZVYGINF-UHFFFAOYSA-N 0.000 description 1
- 229940029284 trichlorofluoromethane Drugs 0.000 description 1
- 238000009966 trimming Methods 0.000 description 1
- 150000004072 triols Chemical class 0.000 description 1
- AVWRKZWQTYIKIY-UHFFFAOYSA-N urea-1-carboxylic acid Chemical group NC(=O)NC(O)=O AVWRKZWQTYIKIY-UHFFFAOYSA-N 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/18—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by features of a layer of foamed material
- B32B5/20—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by features of a layer of foamed material foamed in situ
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C44/00—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
- B29C44/02—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles for articles of definite length, i.e. discrete articles
- B29C44/12—Incorporating or moulding on preformed parts, e.g. inserts or reinforcements
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/18—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by features of a layer of foamed material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
- B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
- B32B5/245—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it being a foam layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60N—SEATS SPECIALLY ADAPTED FOR VEHICLES; VEHICLE PASSENGER ACCOMMODATION NOT OTHERWISE PROVIDED FOR
- B60N2/00—Seats specially adapted for vehicles; Arrangement or mounting of seats in vehicles
- B60N2/58—Seat coverings
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- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
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- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
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Description
(a)少なくとも1つのポリオール、少なくとも1つのイソシアネート及び少なくとも1つの触媒を含む発泡体組成物をモールドアセンブリに提供するステップ;
(b)第1の所定時間の後に、モールドアセンブリから、発泡体組成物から形成される発泡体を得るステップ;
(c)織物を前記発泡体の表面に接触させるステップ;及び
(d)任意に、第2の所定時間、前記発泡体を硬化するステップ。
(a)ポリオール、イソシアネート及び触媒を含む発泡体組成物を第1モールドに提供するステップ;
(b)第2モールド及び第1モールドを互いに近付けて(bring)、第2モールドが発泡体組成物に接触するのを可能にするステップ;
(c)第1の所定時間後に第1モールドと第2モールドとを分離し、発泡体組成物から形成される発泡体を得るステップ;
(d)織物を第3モールドと接触させるステップであって、織物はさらに所定の衝突速度で発泡体の表面と接触する、ステップ;
(e)第2の所定時間、発泡体組成物を硬化し、発泡体製品を形成するステップ;及び
(f)発泡体製品を除去するステップ。
(a)少なくとも1つのポリオール、少なくとも1つのイソシアネート及び少なくとも1つの触媒を含む発泡体組成物をモールドアセンブリに提供するステップ;
(b)第1の所定時間の後に、モールドアセンブリから、発泡体組成物から形成される発泡体を得るステップ;
(c)織物を発泡体の少なくとも1つの表面に接触させるステップ;及び
(d)任意に、第2の所定時間、発泡体を硬化するステップ。
(a)少なくとも1つのポリオール、少なくとも1つのイソシアネート及び少なくとも1つの触媒を含む発泡体組成物を第1モールドに提供するステップ;
(b)第1モールド及び第2モールドを互いに近付け、第2モールドが発泡体組成物に接触するのを可能にするステップ;
(c)第1の所定時間の後に第1モールド及び第2モールドを分離し、発泡体組成物から形成される発泡体を得るステップ;
(d)織物を発泡体の少なくとも1つの表面に接触させるステップ;及び
(e)任意に、第2の所定時間、発泡体を硬化するステップ;
ここで、分離ステップ(c)の間、発泡体組成物は崩壊しない。
(a)少なくとも1つのポリオール、少なくとも1つのイソシアネート、及び少なくとも1つの触媒を含む発泡体組成物をクローズドモールドアセンブリに提供するステップ;
(b)第1の所定時間の後、クローズドモールドアセンブリを開いて、発泡体組成物から形成される発泡体を得るステップ;
(c)発泡体の少なくとも1つの表面に織物を接触させるステップ;及び
(d)任意に、第2の所定時間、発泡体を硬化するステップ;
ここで、発泡体組成物は、ステップ(b)の間にモールドアセンブリから得られるときに崩壊しない。
(a)少なくとも1つのポリオール、少なくとも1つのイソシアネート及び少なくとも1つの触媒を含む発泡体組成物を第1モールドに提供するステップ;
(b)第2モールド及び第1モールドを互いに近付けて、第2モールドが発泡体組成物に接触するのを可能にするステップ;
(c)第1の所定時間の後、第1モールド及び第2モールドを分離し、発泡体組成物から形成される発泡体を得るステップ;
(d)織物を第3モールドと接触させるステップであって、織物はさらに所定の衝突速度で発泡体の表面に接触する、ステップ;
(e)第2の所定時間、発泡体組成物を硬化し、発泡体製品を形成するステップ;及び
(f)発泡体製品を除去するステップ。
本実施例は、両側に織物が積層されたカーシートの製造を例示する。
4つの別個の処方が、表1においてそれぞれP1、P2、P3及びP4として示される通りに調製される:
織物が積層されたカーシートの調製に使用される装置及びプロセスは、図2から9に示される通りである。図2から5を参照すると、内蔵永久磁石6をそれぞれ含む第1の雄型モールド4及び第1の雌型モールド5が提供される。プレ成形雄型織物ライナー1及びプレ成形雌型織物ライナー2はそれぞれ、第1の雄型モールド4及び第1の雌型モールド5に適合する。プレ成形雄型織物ライナー1及びプレ成形雌型織物ライナー2のそれぞれは、1平方メートルあたり300グラム(gsm)の重量を有する100%ポリエステル連結(interlock)織物で形成される。プレ成形雄型織物ライナー1は、織物取り付けリング7によって、第1の雄型モールド4に機械的に取り付けられる(図2及び3参照)。同様に、プレ成形雌型織物ライナー2はまた、別の織物取り付けリング7によって、第1の雌型モールド5に機械的に取り付けられる(図4及び5参照)。特に、略3mmの直径を有するスチールワイヤリング7が、永久磁石6が埋め込まれているグルーブに挿入される。
4つの処方P1、P2、P3及びP4から形成された各最終製品への浸透が、UV蛍光発光の不在/存在により、254nmでのUV光下で試験された。積層の質は、スタンダードAATCC 124/143に対して測定されている。その結果が表2に示される。
2 プレ成形雌型織物ライナー
3 発泡体
4 第1の雄型モールド
5 第1の雌型モールド
6 永久磁石
7 織物取り付けリング
8 混合ヘッド
9 第2の雌型モールド
10 第2の雄型モールド
Claims (14)
- (a)少なくとも1つのポリオール、少なくとも1つのイソシアネート、及び少なくとも1つの触媒を含む発泡体組成物をモールドアセンブリに提供するステップ;
(b)第1の所定時間の後、前記モールドアセンブリから、前記発泡体組成物から形成される発泡体を得るステップであって、前記第1の所定時間は、前記発泡体組成物を完全に発泡するのに用いられる時間であるステップ;
(c)前記発泡体の少なくとも1つの表面に織物を接触させるステップ;及び
(d)任意に、第2の所定時間、前記発泡体を硬化するステップ;
を含み、前記ステップ(b)は前記モールドアセンブリから形成された前記発泡体を離型するステップを含み、前記ステップ(b)の間、前記発泡体は崩壊せず、前記ステップ(b)で得られた前記発泡体が粘着性である、織物積層発泡体製品の製造方法。 - 前記ステップ(b)で得られた前記発泡体は80%超の粘着度を有する、請求項1に記載の方法。
- 少なくとも1回、ステップ(c)を繰り返すことを含む、請求項1又は2に記載の方法。
- 前記ステップ(c)の前に、前記発泡体組成物から形成される発泡体の表面から層を除去するステップをさらに含む、請求項1から3の何れか1項に記載の方法。
- 前記少なくとも1つのポリオールは架橋ポリオールを含む、請求項1から4の何れか1項に記載の方法。
- 前記少なくとも1つのポリオールは、第1級水酸基末端ポリオールを含む、請求項1から5の何れか1項に記載の方法。
- 前記少なくとも1つのイソシアネートは、2.4−49%のイソシアネート含量を含む、請求項1から6の何れか1項に記載の方法。
- 前記発泡体組成物に含まれる前記少なくとも1つのイソシアネートは、ポリオール100部あたり20−100部(20−100pphp)の量である、請求項1から7の何れか1項に記載の方法。
- 前記少なくとも1つの触媒は、ゲル化触媒及び発泡触媒を含む、請求項1から8の何れか1項に記載の方法。
- 前記発泡体組成物に含まれる前記ゲル化触媒と前記発泡触媒との比率は、5:1から30:1である、請求項9に記載の方法。
- 前記発泡体組成物はさらに、少なくとも1つの界面活性剤を含む、請求項1から10の何れか1項に記載の方法。
- 前記発泡体組成物は、一次界面活性剤及び二次界面活性剤を含む、請求項11に記載の方法。
- 前記発泡体組成物はさらに、発泡剤を含む、請求項1から12の何れか1項に記載の方法。
- 前記方法は、
(i)少なくとも1つのポリオール、少なくとも1つのイソシアネート、及び少なくとも1つの触媒を含む発泡体組成物を第1モールドに提供するステップ;
(ii)第2モールド及び前記第1モールドを互いに近付けて、前記第2モールドが前記発泡体組成物に接触するのを可能にするステップ;
(iii)第1の所定時間の後、前記第1モールドと前記第2モールドとを分離して、前記発泡体組成物から形成される発泡体を得るステップであって、前記第1の所定時間は、前記発泡体組成物を完全に発泡するのに用いられる時間であるステップ;
(iv)織物を第3モールドに接触させるステップであって、前記織物はさらに所定の衝突速度で前記発泡体の表面に接触する、ステップ;
(v)第2の所定時間、前記発泡体組成物を硬化させ、発泡体製品を形成するステップ;及び
(vi)前記発泡体製品を除去するステップ;
を含み、前記ステップ(iii)の間、前記発泡体は崩壊せず、前記ステップ(iii)で得られた前記発泡体が粘着性である、請求項1に記載の方法。
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GB1108032.2A GB2490884A (en) | 2011-05-13 | 2011-05-13 | Method of manufacturing a fabric laminated foam pad |
GB1108033.0A GB2490885A (en) | 2011-05-13 | 2011-05-13 | Method of manufacturing a fabric laminated foam pad |
GB1108032.2 | 2011-05-13 | ||
PCT/GB2012/051035 WO2012156691A1 (en) | 2011-05-13 | 2012-05-11 | Method of manufacturing a fabric-laminated foam article |
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KR102151946B1 (ko) * | 2019-12-17 | 2020-09-04 | 송장섭 | 통기성이 우수한 브라컵 및 그 제조방법 |
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JP2883032B2 (ja) * | 1995-12-05 | 1999-04-19 | 難波プレス工業株式会社 | 表皮付き多層異硬度座席およびその製造方法 |
US5755901A (en) * | 1996-05-08 | 1998-05-26 | Lear Corporation | Method and apparatus for controlling an assembly for bonding a cover material to foam |
JP2840223B2 (ja) * | 1996-07-01 | 1998-12-24 | 難波プレス工業株式会社 | 表皮付き多層異硬度座席およびその製造方法 |
JP2905457B2 (ja) * | 1996-11-18 | 1999-06-14 | 難波プレス工業株式会社 | 立体形状を有する自動車用カーペットの一体成形方法 |
DE102005032025A1 (de) | 2005-07-08 | 2007-01-18 | Linde Ag | Verfahren zur adsorptiven Entfernung von Spurenkomponenten |
DE102006029026A1 (de) * | 2006-06-14 | 2007-12-20 | Sitech Sitztechnik Gmbh | Verkleben von Körpern aus einem Schaumstoffmaterial oder anderer Trägermaterialien mit Bezügen |
CN101289017B (zh) * | 2007-04-18 | 2012-09-05 | 上海磁浮交通工程技术研究中心 | 高速列车用复合材料结构及其制造方法 |
CN101220614A (zh) * | 2007-12-07 | 2008-07-16 | 厦门高特高新材料有限公司 | 聚氨酯复合保温板及其制造方法和应用 |
KR101263209B1 (ko) * | 2010-06-16 | 2013-05-10 | 박장원 | 직물 일체형 가교 발포 제품의 제조방법 |
-
2012
- 2012-05-11 EP EP12722807.0A patent/EP2707217B1/en active Active
- 2012-05-11 CN CN201280021195.7A patent/CN103635312B/zh active Active
- 2012-05-11 JP JP2014509828A patent/JP5833744B2/ja active Active
- 2012-05-11 WO PCT/GB2012/051035 patent/WO2012156691A1/en active Application Filing
- 2012-05-11 US US14/110,772 patent/US20140120337A1/en not_active Abandoned
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CN103635312A (zh) | 2014-03-12 |
JP2014518787A (ja) | 2014-08-07 |
WO2012156691A1 (en) | 2012-11-22 |
US20140120337A1 (en) | 2014-05-01 |
EP2707217A1 (en) | 2014-03-19 |
EP2707217B1 (en) | 2015-07-29 |
CN103635312B (zh) | 2015-11-25 |
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