JP5829451B2 - 改良されたスポッティングおよびフィルミング性能を提供する、リン酸塩およびホスホン酸塩非含有自動食器洗浄機用ゲル状洗剤 - Google Patents
改良されたスポッティングおよびフィルミング性能を提供する、リン酸塩およびホスホン酸塩非含有自動食器洗浄機用ゲル状洗剤 Download PDFInfo
- Publication number
- JP5829451B2 JP5829451B2 JP2011170705A JP2011170705A JP5829451B2 JP 5829451 B2 JP5829451 B2 JP 5829451B2 JP 2011170705 A JP2011170705 A JP 2011170705A JP 2011170705 A JP2011170705 A JP 2011170705A JP 5829451 B2 JP5829451 B2 JP 5829451B2
- Authority
- JP
- Japan
- Prior art keywords
- carboxymethylinulin
- present
- polyacrylate
- detergent
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000003599 detergent Substances 0.000 title claims description 37
- 238000004851 dishwashing Methods 0.000 title description 3
- 239000000203 mixture Substances 0.000 claims description 65
- 229920000058 polyacrylate Polymers 0.000 claims description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 25
- 108091005804 Peptidases Proteins 0.000 claims description 19
- 239000004365 Protease Substances 0.000 claims description 18
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 15
- 239000002736 nonionic surfactant Substances 0.000 claims description 15
- 230000009467 reduction Effects 0.000 claims description 15
- 239000006254 rheological additive Substances 0.000 claims description 12
- 229910019142 PO4 Inorganic materials 0.000 claims description 10
- 235000021317 phosphate Nutrition 0.000 claims description 10
- 102000013142 Amylases Human genes 0.000 claims description 8
- 108010065511 Amylases Proteins 0.000 claims description 8
- 235000019418 amylase Nutrition 0.000 claims description 8
- 238000006467 substitution reaction Methods 0.000 claims description 7
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 6
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 claims description 6
- 150000003013 phosphoric acid derivatives Chemical class 0.000 claims description 6
- 229910052708 sodium Inorganic materials 0.000 claims description 6
- 239000011734 sodium Substances 0.000 claims description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 claims description 5
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 5
- 150000001860 citric acid derivatives Chemical class 0.000 claims description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 5
- 239000010452 phosphate Substances 0.000 claims description 5
- 239000004382 Amylase Substances 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 claims description 3
- 150000004760 silicates Chemical class 0.000 claims description 3
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 claims 3
- 102000004190 Enzymes Human genes 0.000 description 35
- 108090000790 Enzymes Proteins 0.000 description 35
- 229940088598 enzyme Drugs 0.000 description 35
- 239000000499 gel Substances 0.000 description 25
- 239000007844 bleaching agent Substances 0.000 description 17
- 102000035195 Peptidases Human genes 0.000 description 16
- -1 alkali metal salt Chemical class 0.000 description 13
- 238000009472 formulation Methods 0.000 description 13
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 12
- 239000004115 Sodium Silicate Substances 0.000 description 11
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 11
- 239000001301 oxygen Substances 0.000 description 11
- 229910052760 oxygen Inorganic materials 0.000 description 11
- 239000000843 powder Substances 0.000 description 11
- 239000002585 base Substances 0.000 description 9
- 229920000642 polymer Polymers 0.000 description 9
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 9
- 229910052911 sodium silicate Inorganic materials 0.000 description 9
- 229910052783 alkali metal Inorganic materials 0.000 description 8
- 108010003855 mesentericopeptidase Proteins 0.000 description 8
- 238000004140 cleaning Methods 0.000 description 7
- 235000019419 proteases Nutrition 0.000 description 7
- 239000012190 activator Substances 0.000 description 6
- 229910052910 alkali metal silicate Inorganic materials 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 229910000029 sodium carbonate Inorganic materials 0.000 description 6
- 235000017550 sodium carbonate Nutrition 0.000 description 6
- 235000019795 sodium metasilicate Nutrition 0.000 description 6
- 235000019351 sodium silicates Nutrition 0.000 description 6
- 239000004094 surface-active agent Substances 0.000 description 6
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 5
- 108090000787 Subtilisin Proteins 0.000 description 5
- 239000011521 glass Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 4
- 108010056079 Subtilisins Proteins 0.000 description 4
- 102000005158 Subtilisins Human genes 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 4
- 229940025131 amylases Drugs 0.000 description 4
- 239000003054 catalyst Substances 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 4
- 238000010998 test method Methods 0.000 description 4
- XSVSPKKXQGNHMD-UHFFFAOYSA-N 5-bromo-3-methyl-1,2-thiazole Chemical group CC=1C=C(Br)SN=1 XSVSPKKXQGNHMD-UHFFFAOYSA-N 0.000 description 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
- 150000001340 alkali metals Chemical class 0.000 description 3
- 108090000637 alpha-Amylases Proteins 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 235000013305 food Nutrition 0.000 description 3
- 239000001509 sodium citrate Substances 0.000 description 3
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 3
- 102000004400 Aminopeptidases Human genes 0.000 description 2
- 108090000915 Aminopeptidases Proteins 0.000 description 2
- 108010004032 Bromelains Proteins 0.000 description 2
- 108090000317 Chymotrypsin Proteins 0.000 description 2
- 108060005980 Collagenase Proteins 0.000 description 2
- 102000029816 Collagenase Human genes 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 229920002670 Fructan Polymers 0.000 description 2
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 2
- 102100026367 Pancreatic alpha-amylase Human genes 0.000 description 2
- 108010067372 Pancreatic elastase Proteins 0.000 description 2
- 102000016387 Pancreatic elastase Human genes 0.000 description 2
- 108090000526 Papain Proteins 0.000 description 2
- 108090000284 Pepsin A Proteins 0.000 description 2
- 102000057297 Pepsin A Human genes 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- 108090000631 Trypsin Proteins 0.000 description 2
- 102000004142 Trypsin Human genes 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 125000002947 alkylene group Chemical group 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 229960002376 chymotrypsin Drugs 0.000 description 2
- 229960002424 collagenase Drugs 0.000 description 2
- 239000013065 commercial product Substances 0.000 description 2
- 238000005530 etching Methods 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 108010059345 keratinase Proteins 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 229940055729 papain Drugs 0.000 description 2
- 235000019834 papain Nutrition 0.000 description 2
- 229940111202 pepsin Drugs 0.000 description 2
- 125000005342 perphosphate group Chemical group 0.000 description 2
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 2
- 235000019353 potassium silicate Nutrition 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 229940024999 proteolytic enzymes for treatment of wounds and ulcers Drugs 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- 239000003352 sequestering agent Substances 0.000 description 2
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 description 2
- 235000011152 sodium sulphate Nutrition 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- 239000012588 trypsin Substances 0.000 description 2
- 229960001322 trypsin Drugs 0.000 description 2
- VPTUPAVOBUEXMZ-UHFFFAOYSA-N (1-hydroxy-2-phosphonoethyl)phosphonic acid Chemical class OP(=O)(O)C(O)CP(O)(O)=O VPTUPAVOBUEXMZ-UHFFFAOYSA-N 0.000 description 1
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- GLULCKCBVYGUDD-UHFFFAOYSA-N 2-phosphonobutane-1,1,1-tricarboxylic acid Chemical class CCC(P(O)(O)=O)C(C(O)=O)(C(O)=O)C(O)=O GLULCKCBVYGUDD-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 244000063299 Bacillus subtilis Species 0.000 description 1
- 235000014469 Bacillus subtilis Nutrition 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 102000002322 Egg Proteins Human genes 0.000 description 1
- 108010000912 Egg Proteins Proteins 0.000 description 1
- 229920001202 Inulin Polymers 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- 229920002252 Plurafac® SLF 180 Polymers 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910000288 alkali metal carbonate Inorganic materials 0.000 description 1
- 150000008041 alkali metal carbonates Chemical class 0.000 description 1
- 229910052936 alkali metal sulfate Inorganic materials 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 102000004139 alpha-Amylases Human genes 0.000 description 1
- 229940024171 alpha-amylase Drugs 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010411 cooking Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- 235000013345 egg yolk Nutrition 0.000 description 1
- 210000002969 egg yolk Anatomy 0.000 description 1
- 235000013601 eggs Nutrition 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 230000009969 flowable effect Effects 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 229940029339 inulin Drugs 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 235000013372 meat Nutrition 0.000 description 1
- 108010020132 microbial serine proteinases Proteins 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 150000004967 organic peroxy acids Chemical class 0.000 description 1
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 150000003138 primary alcohols Chemical class 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 235000011083 sodium citrates Nutrition 0.000 description 1
- 229960001922 sodium perborate Drugs 0.000 description 1
- 239000012418 sodium perborate tetrahydrate Substances 0.000 description 1
- 235000019794 sodium silicate Nutrition 0.000 description 1
- IBDSNZLUHYKHQP-UHFFFAOYSA-N sodium;3-oxidodioxaborirane;tetrahydrate Chemical compound O.O.O.O.[Na+].[O-]B1OO1 IBDSNZLUHYKHQP-UHFFFAOYSA-N 0.000 description 1
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 1
- 239000008234 soft water Substances 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 210000000225 synapse Anatomy 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
- C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/08—Silicates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
- C11D3/3761—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in solid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38609—Protease or amylase in solid compositions only
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
- Emergency Medicine (AREA)
- Molecular Biology (AREA)
- Detergent Compositions (AREA)
Description
クエン酸塩はビルダーおよび金属イオン封鎖剤の両方として機能できる。
Claims (10)
- a.珪酸塩およびクエン酸塩の1以上を含む塩基を7%から35%;
b.非イオン性界面活性剤を0.1%から10%;
c.(i)ポリアクリレートおよび(ii)カルボキシメチルイヌリンを含み、ポリアクリレートのカルボキシメチルイヌリンに対する比率が2:1から3:1であるスポット低減システムを0.55%から4%;
d.0.1%から3%のアルカリ安定プロテアーゼ、および0.1%から1%のアミラーゼ、
e.0.1%から2%のレオロジー改良剤、および残部の水を含み、
aからeに記載の成分の合計は100%であり、
FサイズのT形バーを使用して、12rpmでブルックフィールドLVT粘度計で測定されたゲルの粘度が、10,000から30,000センチポイズの範囲内であるような量で水とレオロジー改良剤が存在する、
燐酸塩およびホスホン酸塩を含まない、注入可能なゲルである自動食器洗浄機用洗剤。 - 該ポリアクリレートが500から200,000の分子量を有する、請求項1記載の洗剤。
- 該ポリアクリレートが0.5%から1.5%の量で存在する、請求項2記載の洗剤。
- 該カルボキシメチルイヌリンが0.15から3の置換度を有する、請求項1記載の洗剤。
- 該カルボキシメチルイヌリンが1.5から3の置換度を有するカルボキシメチルイヌリンナトリウムであり、該カルボキシメチルイヌリンは0.05%から2.5%の範囲で存在する、請求項1記載の洗剤。
- 該珪酸塩が5%から20%の量で存在し、該クエン酸塩が2%から15%の量で存在する、請求項1記載の洗剤。
- さらにクエン酸を0.5%から5%の量で含む、請求項1記載の洗剤。
- a.5%から20%の珪酸塩;
b.2%から15%のクエン酸塩;
c.0.5%から5%のクエン酸;
d.0.1%から10%の非イオン性界面活性剤;
e.(i)ポリアクリレートおよび(ii)カルボキシメチルイヌリンを含み、ポリアクリレートのカルボキシメチルイヌリンに対する比率が2:1から3:1であるスポット低減システムを0.55%から4%;
f.0.1%から3%のアルカリ安定プロテアーゼ、および0.1%から1%のアミラーゼ、
g.0.1%から2%のレオロジー改良剤、および残部の水を含み、
aからgに記載の成分の合計は100%であり、
FサイズのT形バーを使用して、12rpmでブルックフィールドLVT粘度計で測定されたゲルの粘度が、10,000から30,000センチポイズの範囲内であるような量で水とレオロジー改良剤が存在する、燐酸塩およびホスホン酸塩を含まない、注入可能なゲルである自動食器洗浄機用洗剤。 - a.珪酸塩およびクエン酸塩の1以上を含む塩基を7%から35%;
b.非イオン性界面活性剤を0.1%から10%;
c.(i)ポリアクリレートおよび(ii)カルボキシメチルイヌリン、を含み、ポリアクリレートのカルボキシメチルイヌリンに対する比率が2:1から3:1であるスポット低減システムを0.55%から4%;
d.0.1%から3%のアルカリ安定プロテアーゼ、および0.1%から1%のアミラーゼ、
e.0.1%から2%のレオロジー改良剤、および残部の水を含み、
aからeに記載の成分の合計は100%であり、
FサイズのT形バーを使用して、12rpmでブルックフィールドLVT粘度計で測定されたゲルの粘度が、10,000から30,000センチポイズの範囲内であるような量で水とレオロジー改良剤が存在する、
燐酸塩およびホスホン酸塩を含まない、注入可能なゲルである自動食器洗浄機用洗剤で食器を処理することを含む、自動食器洗浄機中で洗浄された食器の水スポッティングを低減する方法。 - 該組成物が15グレイン以上の硬度を有する水とさらに混合される、請求項9記載の方法。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US12/851,056 | 2010-08-05 | ||
US12/851,056 US8343904B2 (en) | 2008-01-22 | 2010-08-05 | Phosphate and phosphonate-free automatic gel dishwashing detergent providing improved spotting and filming performance |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2012036390A JP2012036390A (ja) | 2012-02-23 |
JP5829451B2 true JP5829451B2 (ja) | 2015-12-09 |
Family
ID=44533856
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2011170705A Active JP5829451B2 (ja) | 2010-08-05 | 2011-08-04 | 改良されたスポッティングおよびフィルミング性能を提供する、リン酸塩およびホスホン酸塩非含有自動食器洗浄機用ゲル状洗剤 |
Country Status (4)
Country | Link |
---|---|
US (2) | US8343904B2 (ja) |
EP (1) | EP2415854A1 (ja) |
JP (1) | JP5829451B2 (ja) |
RU (1) | RU2564033C2 (ja) |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AU2008322438B2 (en) | 2007-11-15 | 2014-06-19 | The University Of Montana | Hydroxypolyamide gel forming agents |
US8343904B2 (en) | 2008-01-22 | 2013-01-01 | Access Business Group International Llc | Phosphate and phosphonate-free automatic gel dishwashing detergent providing improved spotting and filming performance |
JP5968898B2 (ja) | 2010-11-11 | 2016-08-10 | リバートツプ・リニユーワブルズ | 腐食抑制組成物 |
US8822403B2 (en) * | 2011-01-20 | 2014-09-02 | Ecolab Usa Inc. | Detergent composition including a saccharide or sugar alcohol |
AU2012245234B2 (en) | 2011-04-21 | 2015-10-29 | Rivertop Renewables, Inc. | Calcium sequestering composition |
US9670124B2 (en) | 2013-03-13 | 2017-06-06 | Rivertop Renewables, Inc. | Nitric acid oxidation process |
US9346736B2 (en) | 2013-03-13 | 2016-05-24 | Rivertop Renewables, Inc. | Oxidation process |
BR112015022284A2 (pt) | 2013-03-13 | 2017-07-18 | Rivertop Renewables Inc | processos de oxidação de ácido nítrico melhorados |
US9260679B2 (en) * | 2013-05-17 | 2016-02-16 | Madison Chemcial Co., Inc. | Cleaning composition for the food and beverage industry |
US20160102274A1 (en) * | 2014-10-08 | 2016-04-14 | Rivertop Renewables, Inc. | Detergent builder and dispersant synergy in calcium carbonate scale prevention |
EP3241891B1 (en) * | 2016-05-03 | 2019-04-03 | The Procter and Gamble Company | Automatic dishwashing detergent composition |
EP4234668A3 (en) | 2018-04-27 | 2023-10-04 | The Procter & Gamble Company | Hard surface cleaners comprising carboxylated fructan |
CN111575121B (zh) * | 2020-05-15 | 2021-06-04 | 珠海格力电器股份有限公司 | 一种水溶性浓缩凝胶清洁剂、制备方法及冲洗清洁方法 |
Family Cites Families (34)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4545917A (en) | 1984-02-09 | 1985-10-08 | Creative Products Resource Associates Ltd. | Automatic dishwasher product in solid form |
US5084198A (en) * | 1987-11-05 | 1992-01-28 | Colgate-Palmolove Co. | Thixotropic aqueous liquid automatic dishwashing detergent composition |
US5256327A (en) | 1991-08-01 | 1993-10-26 | Shaklee Corporation | Method of preparing a sequestering agent for a non-phosphate cleaning composition |
NL9302163A (nl) * | 1993-12-10 | 1995-07-03 | Univ Delft Tech | Gecarboxymethyleerde oligo- en polysacchariden als kristallisatie inhibitors. |
CA2206852A1 (en) * | 1994-12-07 | 1996-06-13 | Novo Nordisk A/S | Polypeptide with reduced allergenicity |
ATE193320T1 (de) | 1995-02-02 | 2000-06-15 | Procter & Gamble | Maschinengeschirrspülmittel zusammensetzungen mit kobalt chelatkatalysatoren |
GB2307914A (en) | 1995-12-06 | 1997-06-11 | Procter & Gamble | Detergent compositions |
NL1009379C2 (nl) | 1998-06-11 | 1999-12-15 | Cooperatie Cosun U A | Dispergeermiddel. |
CA2362841A1 (en) * | 1999-02-22 | 2000-08-31 | The Procter & Gamble Company | Automatic dishwashing compositions comprising mixed surfactants systems |
US6844305B1 (en) | 1999-08-27 | 2005-01-18 | The Proctor & Gamble Company | Aqueous liquid detergent compositions comprising a polymeric stabilization system |
US6331512B1 (en) * | 1999-09-29 | 2001-12-18 | Amway Corporation | Phosphate-free automatic dishwashing detergent |
SE515806C2 (sv) * | 2000-01-19 | 2001-10-08 | Avesta Polarit Ab Publ | Långtidsstabilt betmedel innehållande urea samt sätt att tillverka detta |
GB0028268D0 (en) | 2000-11-20 | 2001-01-03 | Norske Stats Oljeselskap | Well treatment |
US6723687B2 (en) * | 2001-05-01 | 2004-04-20 | The Procter & Gamble Company | Automatic dishwashing compositions comprising diacyl peroxide bleach and blooming perfume |
US6921743B2 (en) * | 2001-04-02 | 2005-07-26 | The Procter & Gamble Company | Automatic dishwashing compositions containing a halogen dioxide salt and methods for use with electrochemical cells and/or electrolytic devices |
ATE309318T1 (de) | 2001-07-20 | 2005-11-15 | Unilever Nv | Verwendung von verbindungen in waschmitteln |
JP2005535766A (ja) * | 2002-08-20 | 2005-11-24 | ザ プロクター アンド ギャンブル カンパニー | 無水溶媒を含む液体ゲル自動食器洗浄洗剤組成物 |
EP1408103A1 (en) * | 2002-10-10 | 2004-04-14 | N.V. Solutia Europe S.A. | Detergent composition exhibiting enhanced stain removal |
WO2006119162A1 (en) * | 2005-05-04 | 2006-11-09 | Johnsondiversey, Inc. | Warewashing system containing low levels of surfactant |
US20070203323A1 (en) * | 2006-02-10 | 2007-08-30 | Gyorgyi Fenyvesi | Food compositions comprising biologically-based biodegradable 1,3-propanediol esters |
JP2007320927A (ja) | 2006-06-02 | 2007-12-13 | Dai Ichi Kogyo Seiyaku Co Ltd | 農薬顆粒水和剤用結合剤および農薬顆粒水和剤 |
JP5199614B2 (ja) * | 2006-12-06 | 2013-05-15 | 花王株式会社 | 増粘された液状洗浄剤組成物及びその製造方法 |
DE102007044417A1 (de) | 2007-09-17 | 2009-03-19 | Henkel Ag & Co. Kgaa | Reinigungsmittel |
DE102007044418A1 (de) | 2007-09-17 | 2009-03-19 | Henkel Ag & Co. Kgaa | Reinigungsmittel |
US7838485B2 (en) | 2007-03-08 | 2010-11-23 | American Sterilizer Company | Biodegradable alkaline disinfectant cleaner with analyzable surfactant |
KR20100014954A (ko) * | 2007-03-09 | 2010-02-11 | 다니스코 유에스 인크. | 호알칼리성 바실러스 종 α-아밀라아제 변이체, α-아밀라아제 변이체를 함유하는 조성물 및 사용 방법 |
EP1972361A1 (en) * | 2007-03-21 | 2008-09-24 | Cognis IP Management GmbH | Mild cleansing compositions with an encapsultated dye |
US7597766B2 (en) | 2007-08-03 | 2009-10-06 | American Sterilizer Company | Biodegradable detergent concentrate for medical instruments and equipment |
MX2010003825A (es) * | 2007-10-18 | 2010-04-27 | Ecolab Inc | Composiciones de limpieza solidas, auto-solidificables, comprimidas, y metodos para hacerlas. |
US7781387B2 (en) | 2008-01-22 | 2010-08-24 | Access Business Group International, Llc. | Automatic phosphate-free dishwashing detergent providing improved spotting and filming performance |
US8343904B2 (en) | 2008-01-22 | 2013-01-01 | Access Business Group International Llc | Phosphate and phosphonate-free automatic gel dishwashing detergent providing improved spotting and filming performance |
US20090209447A1 (en) * | 2008-02-15 | 2009-08-20 | Michelle Meek | Cleaning compositions |
US7902137B2 (en) * | 2008-05-30 | 2011-03-08 | American Sterilizer Company | Biodegradable scale control composition for use in highly concentrated alkaline hard surface detergents |
GB0917740D0 (en) * | 2009-10-09 | 2009-11-25 | Reckitt Benckiser Nv | Detergent composition |
-
2010
- 2010-08-05 US US12/851,056 patent/US8343904B2/en active Active
-
2011
- 2011-07-12 RU RU2011128596/04A patent/RU2564033C2/ru active
- 2011-07-13 EP EP20110173786 patent/EP2415854A1/en not_active Ceased
- 2011-08-04 JP JP2011170705A patent/JP5829451B2/ja active Active
-
2012
- 2012-11-29 US US13/688,482 patent/US8454757B2/en active Active
Also Published As
Publication number | Publication date |
---|---|
RU2011128596A (ru) | 2013-01-20 |
US20100298192A1 (en) | 2010-11-25 |
JP2012036390A (ja) | 2012-02-23 |
US20130090281A1 (en) | 2013-04-11 |
RU2564033C2 (ru) | 2015-09-27 |
EP2415854A1 (en) | 2012-02-08 |
US8343904B2 (en) | 2013-01-01 |
US8454757B2 (en) | 2013-06-04 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP5829451B2 (ja) | 改良されたスポッティングおよびフィルミング性能を提供する、リン酸塩およびホスホン酸塩非含有自動食器洗浄機用ゲル状洗剤 | |
JP5372958B2 (ja) | 改良されたスポッティングおよびフィルミング性能を提供する、リン酸塩非含有自動食器洗浄機用洗剤 | |
ES2444922T3 (es) | Composición detergente para lavado de vajilla en lavavajillas | |
NZ202897A (en) | Detergent dishwashing composition | |
ES2794938T3 (es) | Detergente enzimático, de múltiples usos y métodos de estabilización de una solución de uso | |
US5240632A (en) | Machine dishwasher water spot control composition | |
KR20170061687A (ko) | 세제 조성물 | |
JP2008127490A (ja) | 自動食器洗浄機用中性液体洗浄剤組成物 | |
CA1334389C (en) | Machine dishwasher water spot control composition | |
PT100537A (pt) | Composicao melhorada para maquina de lavar louca automatica, liquida naao aquosa, isenta de fosfatos, contendo enzimas protease e amilase | |
JPH02504649A (ja) | 皿を洗いすすぐための酵素組成物 | |
US6331512B1 (en) | Phosphate-free automatic dishwashing detergent | |
JP2004511277A (ja) | 洗剤組成物および器物洗浄方法 | |
ES2954295T3 (es) | Composición detergente libre de fosfatos para lavavajillas automático | |
JP4015779B2 (ja) | 食器洗浄機用洗浄剤組成物 | |
JP2004203990A (ja) | スプレー式容器入り自動食器洗浄機用液体洗浄剤製品及び洗浄方法 | |
Tomlinson et al. | A review of key ingredients used in past and present autodishwashing formulations and the physic-chemical processes they facilitate | |
EP4286500A1 (en) | Use of xylanase in a dishwashing process | |
US20230416650A1 (en) | Dishwashing detergent composition comprising xylanase and block co-polymer | |
US20230416649A1 (en) | Dishwashing detergent composition comprising xylanase and sulphonated carboxylate polymer | |
US20220039629A1 (en) | Automatic dishwashing method | |
JPH0749594B2 (ja) | 洗浄剤組成物 | |
JPH0749595B2 (ja) | 洗浄剤組成物 | |
JPH1171596A (ja) | 自動食器洗浄機用洗浄剤組成物 | |
JP2010275472A (ja) | 自動食器洗浄機用洗浄剤組成物 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20140724 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20150518 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20150526 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20150824 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20151006 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20151022 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 5829451 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |