JP5735193B2 - シリコーンエラストマー及び非水性極性溶媒を含むヘアスタイリング組成物 - Google Patents
シリコーンエラストマー及び非水性極性溶媒を含むヘアスタイリング組成物 Download PDFInfo
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- JP5735193B2 JP5735193B2 JP2007053117A JP2007053117A JP5735193B2 JP 5735193 B2 JP5735193 B2 JP 5735193B2 JP 2007053117 A JP2007053117 A JP 2007053117A JP 2007053117 A JP2007053117 A JP 2007053117A JP 5735193 B2 JP5735193 B2 JP 5735193B2
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- 150000002193 fatty amides Chemical class 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000003349 gelling agent Substances 0.000 description 1
- 239000000174 gluconic acid Substances 0.000 description 1
- 235000012208 gluconic acid Nutrition 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 125000005456 glyceride group Chemical group 0.000 description 1
- 229940075529 glyceryl stearate Drugs 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- SFFVATKALSIZGN-UHFFFAOYSA-N hexadecan-7-ol Chemical compound CCCCCCCCCC(O)CCCCCC SFFVATKALSIZGN-UHFFFAOYSA-N 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 150000003949 imides Chemical group 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- CDAISMWEOUEBRE-GPIVLXJGSA-N inositol Chemical compound O[C@H]1[C@H](O)[C@@H](O)[C@H](O)[C@H](O)[C@@H]1O CDAISMWEOUEBRE-GPIVLXJGSA-N 0.000 description 1
- 229960000367 inositol Drugs 0.000 description 1
- 229940113096 isoceteth 20 Drugs 0.000 description 1
- VKPSKYDESGTTFR-UHFFFAOYSA-N isododecane Natural products CC(C)(C)CC(C)CC(C)(C)C VKPSKYDESGTTFR-UHFFFAOYSA-N 0.000 description 1
- GKQPCPXONLDCMU-CCEZHUSRSA-N lacidipine Chemical compound CCOC(=O)C1=C(C)NC(C)=C(C(=O)OCC)C1C1=CC=CC=C1\C=C\C(=O)OC(C)(C)C GKQPCPXONLDCMU-CCEZHUSRSA-N 0.000 description 1
- 239000008101 lactose Substances 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 239000000594 mannitol Substances 0.000 description 1
- 235000010355 mannitol Nutrition 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 description 1
- 229940044591 methyl glucose dioleate Drugs 0.000 description 1
- XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical compound COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 150000002762 monocarboxylic acid derivatives Chemical class 0.000 description 1
- PJUIMOJAAPLTRJ-UHFFFAOYSA-N monothioglycerol Chemical compound OCC(O)CS PJUIMOJAAPLTRJ-UHFFFAOYSA-N 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- SWVGZFQJXVPIKM-UHFFFAOYSA-N n,n-bis(methylamino)propan-1-amine Chemical compound CCCN(NC)NC SWVGZFQJXVPIKM-UHFFFAOYSA-N 0.000 description 1
- YRDNVESFWXDNSI-UHFFFAOYSA-N n-(2,4,4-trimethylpentan-2-yl)prop-2-enamide Chemical compound CC(C)(C)CC(C)(C)NC(=O)C=C YRDNVESFWXDNSI-UHFFFAOYSA-N 0.000 description 1
- AWDYCSUWSUENQK-UHFFFAOYSA-N n-decylprop-2-enamide Chemical compound CCCCCCCCCCNC(=O)C=C AWDYCSUWSUENQK-UHFFFAOYSA-N 0.000 description 1
- XQPVIMDDIXCFFS-UHFFFAOYSA-N n-dodecylprop-2-enamide Chemical compound CCCCCCCCCCCCNC(=O)C=C XQPVIMDDIXCFFS-UHFFFAOYSA-N 0.000 description 1
- SWPMNMYLORDLJE-UHFFFAOYSA-N n-ethylprop-2-enamide Chemical compound CCNC(=O)C=C SWPMNMYLORDLJE-UHFFFAOYSA-N 0.000 description 1
- AWGZKFQMWZYCHF-UHFFFAOYSA-N n-octylprop-2-enamide Chemical compound CCCCCCCCNC(=O)C=C AWGZKFQMWZYCHF-UHFFFAOYSA-N 0.000 description 1
- PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical compound C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- VVGIYYKRAMHVLU-UHFFFAOYSA-N newbouldiamide Natural products CCCCCCCCCCCCCCCCCCCC(O)C(O)C(O)C(CO)NC(=O)CCCCCCCCCCCCCCCCC VVGIYYKRAMHVLU-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229940049964 oleate Drugs 0.000 description 1
- 229940099570 oleth-2 Drugs 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 150000007530 organic bases Chemical class 0.000 description 1
- MHYFEEDKONKGEB-UHFFFAOYSA-N oxathiane 2,2-dioxide Chemical compound O=S1(=O)CCCCO1 MHYFEEDKONKGEB-UHFFFAOYSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 125000005702 oxyalkylene group Chemical group 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- UNNFEYPNQVSVJX-UHFFFAOYSA-N pentane-3-sulfonic acid Chemical compound CCC(CC)S(O)(=O)=O UNNFEYPNQVSVJX-UHFFFAOYSA-N 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 239000012169 petroleum derived wax Substances 0.000 description 1
- 235000019381 petroleum wax Nutrition 0.000 description 1
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 description 1
- 229940067107 phenylethyl alcohol Drugs 0.000 description 1
- CGIHFIDULQUVJG-UHFFFAOYSA-N phytantriol Chemical compound CC(C)CCCC(C)CCCC(C)CCCC(C)(O)C(O)CO CGIHFIDULQUVJG-UHFFFAOYSA-N 0.000 description 1
- CGIHFIDULQUVJG-VNTMZGSJSA-N phytantriol Natural products CC(C)CCC[C@H](C)CCC[C@H](C)CCC[C@@](C)(O)[C@H](O)CO CGIHFIDULQUVJG-VNTMZGSJSA-N 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920001467 poly(styrenesulfonates) Polymers 0.000 description 1
- 229920000172 poly(styrenesulfonic acid) Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920001515 polyalkylene glycol Polymers 0.000 description 1
- 229920000223 polyglycerol Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229950008882 polysorbate Drugs 0.000 description 1
- 229940068965 polysorbates Drugs 0.000 description 1
- 229940005642 polystyrene sulfonic acid Drugs 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 1
- 238000005956 quaternization reaction Methods 0.000 description 1
- NXLOLUFNDSBYTP-UHFFFAOYSA-N retene Chemical compound C1=CC=C2C3=CC=C(C(C)C)C=C3C=CC2=C1C NXLOLUFNDSBYTP-UHFFFAOYSA-N 0.000 description 1
- 229960002477 riboflavin Drugs 0.000 description 1
- 239000002151 riboflavin Substances 0.000 description 1
- 235000019192 riboflavin Nutrition 0.000 description 1
- 238000007665 sagging Methods 0.000 description 1
- CDAISMWEOUEBRE-UHFFFAOYSA-N scyllo-inosotol Natural products OC1C(O)C(O)C(O)C(O)C1O CDAISMWEOUEBRE-UHFFFAOYSA-N 0.000 description 1
- 210000002374 sebum Anatomy 0.000 description 1
- 150000003335 secondary amines Chemical group 0.000 description 1
- 230000035807 sensation Effects 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical class [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 description 1
- 229940006186 sodium polystyrene sulfonate Drugs 0.000 description 1
- 229950004959 sorbitan oleate Drugs 0.000 description 1
- 229950003429 sorbitan palmitate Drugs 0.000 description 1
- 229950011392 sorbitan stearate Drugs 0.000 description 1
- 235000019337 sorbitan trioleate Nutrition 0.000 description 1
- 229960000391 sorbitan trioleate Drugs 0.000 description 1
- 239000001589 sorbitan tristearate Substances 0.000 description 1
- 235000011078 sorbitan tristearate Nutrition 0.000 description 1
- 229960004129 sorbitan tristearate Drugs 0.000 description 1
- 229940098760 steareth-2 Drugs 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 229940117986 sulfobetaine Drugs 0.000 description 1
- 125000001273 sulfonato group Chemical class [O-]S(*)(=O)=O 0.000 description 1
- 150000003457 sulfones Chemical class 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-O sulfonium Chemical compound [SH3+] RWSOTUBLDIXVET-UHFFFAOYSA-O 0.000 description 1
- 150000003462 sulfoxides Chemical class 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 230000000475 sunscreen effect Effects 0.000 description 1
- 239000000516 sunscreening agent Substances 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- LADGBHLMCUINGV-UHFFFAOYSA-N tricaprin Chemical compound CCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCC)COC(=O)CCCCCCCCC LADGBHLMCUINGV-UHFFFAOYSA-N 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- VLPFTAMPNXLGLX-UHFFFAOYSA-N trioctanoin Chemical group CCCCCCCC(=O)OCC(OC(=O)CCCCCCC)COC(=O)CCCCCCC VLPFTAMPNXLGLX-UHFFFAOYSA-N 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N urethane group Chemical group NC(=O)OCC JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 239000012178 vegetable wax Substances 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- PTHBKNSHSCMKBV-ZETCQYMHSA-N versicol Natural products OCC[C@H]1COc2cc3C(=O)c4cc(O)cc(O)c4C(=O)c3c(O)c12 PTHBKNSHSCMKBV-ZETCQYMHSA-N 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 150000003722 vitamin derivatives Chemical class 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 239000000811 xylitol Substances 0.000 description 1
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 1
- 235000010447 xylitol Nutrition 0.000 description 1
- 229960002675 xylitol Drugs 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/345—Alcohols containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
- A61K8/8176—Homopolymers of N-vinyl-pyrrolidones. Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/895—Polysiloxanes containing silicon bound to unsaturated aliphatic groups, e.g. vinyl dimethicone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/594—Mixtures of polymers
Description
(a)i.少なくとも一つのシリコーンエラストマー;
ii.少なくとも一つの非水性極性溶媒;
iii.任意の、少なくとも一つのスタイリングポリマー;
iv.任意の、少なくとも一つの乳化剤;及び
v.化粧品として許容される(ii)以外の共溶媒;
を含む組成物を準備する工程;及び
(b)前記組成物をケラチン物質に適用する工程;
を含む、髪などのケラチン物質のスタイリング方法に関する。
(a)少なくとも一つのシリコーンエラストマー;
(b)少なくとも一つの非水性極性溶媒;
(c)少なくとも一つのスタイリングポリマー;
(d)任意の少なくとも一つの乳化剤;及び
(e)化粧品として許容される(b)以外の共溶媒;
を含む組成物であって、前記(b)が該組成物の重量に基づいて少なくとも約20重量%の量で存在し、適用後に髪に中程度から軽い保持を与えつつ髪に柔らかさ及び乾燥した感触を与えるヘアスタイリング化粧品組成物に関する。
本明細書中の「化粧品として許容される共溶媒」なる語は、当業者には知られるとおり、例えば水及び/または少なくとも一つの有機溶媒を含んで良い。
の一般構造を有してよい。こうしたポリマーエーテルの例には、PEG、PPG、PEG/PPGコポリマー、並びにこれらの誘導体が含まれる。別の例は、非常に高いHLB値を有するアルコキシル化アルコール、例えばステアレス-2、セテス-2、デセス-3、オレス-10、ラウレス-12である。
の一般構造を有するポリオキシプロピレンポリオキシエチレンブロックコポリマーが含まれる。こうした化合物は、Meroxapol 105、108、171、172、174、178、251、252、254、255、258、311、312、及び314のINCI名で市販されている。
A1は、不飽和基の炭素原子に、またはnが1より大なる場合には隣接メチレン基に、任意に酸素または硫黄などのヘテロ原子を介して結合したメチレン基を示し、
R10は、水素原子またはフェニルまたはベンジル基を示し、
R8は、水素原子または低級アルキル基またはカルボキシル基を示し、
R9は水素原子、低級アルキル基、または−CH2−COOH、フェニル、またはベンジル基を示す]
に相当するものによって提供される。
(a)i)一つ以上のマレイン酸、フマル酸、またはイタコン酸、あるいは無水物、及び
ii)ビニルエステル、ビニルエーテル、ビニルハライド、フェニルビニル誘導体、アクリル酸及びそのエステルから選択される少なくとも一つのモノマー、
を含むコポリマー(これらコポリマーの無水物官能基は任意にモノエステル化またはモノアミド化されている)。その購入可能な例には、以下に限定されるものではないが、ISP社によりGANTREZ ANもしくはES及びAVANTAGE CP及びAquaflex FX-64の名称で市販の製品が含まれる;
(b)i)一つ以上のマレイン酸、フマル酸、またはイタコン酸、あるいは無水物、及び
ii)アリルもしくはメタクリルエステルであって、任意に一つ以上のアクリルアミド、メタクリルアミド、α-オレフィン、アクリルもしくはメタクリルエステル、アクリルもしくはメタクリル酸、またはビニルピロリドン基をその鎖中に含むもの(これらコポリマーの無水物官能基は、任意にモノエステル化またはものアミド化されている);
から選択される、C4−C8一不飽和カルボン酸または無水物から誘導されるコポリマー。
(a)その窒素においてアルキル基で置換されたアクリルアミド及びメタクリルアミドから選択される少なくとも一つのモノマー、
(b)一つ以上の反応性カルボン酸基を含む少なくとも一つの酸性コモノマー、及び
(c)少なくとも一つの塩基性コモノマー、例えばアクリル酸及びメタクリル酸の第一級、第二級、第三級、及び第四級アミン置換基を含むエステル、及び字メチル網のエチルメタクリレートとジメチルもしくはジエチルサルフェートとの第四級化の生成物、
より誘導される単位を含むポリマー。
Zは、ビス(第一級)、モノ-もしくはビス(第二級)ポリアルキレン-ポリアミン基を示し、好ましくは下記:
(a)60乃至100mol%の割合は下式:
の基(この基はジエチレントリアミンから、トリエチレンテトラアミンから、またはジプロピレントリアミンから誘導される);
(b)0乃至40mol%の割合は上記式(IV)の基(式中、x=2であり、p=1である)であり、エチレンジアミンから誘導される基、あるいはピペラジン:
(c)0乃至20mol%の割合はヘキサメチレンジアミンから誘導される−NH−(CH2)6−NH−基;
を表す]
のポリアミノアミドから部分的もしくは全体的に誘導される架橋及びアルキル化ポリアミノアミド(これらのポリアミノアミンは、エピハロヒドリン、ジエポキシド、二無水物、及びビス不飽和誘導体から選択される二官能性架橋剤の添加によって、ポリアミノアミドのアミン基一つあたり0.025乃至0.35molの架橋剤を使用して架橋され、且つアクリル酸、クロロ酢酸、またはアルカンスルトン、あるいはその塩の作用によってアルキル化されている)。
y及びzは1乃至3の範囲の整数を表し、
R12及びR13は水素原子、メチル、エチル、またはプロピルを表し、
R14及びR15は水素原子またはアルキル基を表すが、R14とR15との炭素原子の合計が10を超えないこととする]
の双性イオン性単位を含むポリマー。
q=1であるならば、R17、R18、及びR19はそれぞれ水素原子、並びにこれら化合物と塩基または酸により形成される塩を表す)
の基を表す。
R20は、水素原子、CH3O、CH3CH2O、またはフェニル基を表し、
R21は、水素、または低級アルキル基、例えばメチルまたはエチルを示し、
R22は、水素、または低級アルキル基、例えばメチルまたはエチルを示し、
R23は、低級アルキル基、例えばメチルまたはエチルまたは次式−R24−N(R22)2(式中、R22は上記と同様の意味を有する)に相当する基を示し、ここでR24は、−CH2−CH2−、−CH2−CH2−CH2−、または-CH2−CH(CH3)−基、並びにこれらの基の上限6の炭素原子を含む高級相同物を表す]
に相当するポリマー。
(a)クロロ酢酸またはナトリウムクロロアセテートの下式:
−D−X−D−X−D− (VII)
[式中、
Dは下式:
Xは記号EまたはE’を示し、ここでEまたはE’は同一または相違してよく、主鎖中に上限7の炭素原子を含む直鎖または分枝鎖を含むアルキレン基である二価の基を示し、これは無置換であるかまたはヒドロキシル基で置換されており、さらに酸素、窒素、及び硫黄原子、1乃至3の芳香環及び/または複素環を含むことができ;酸素、窒素、及び硫黄原子が、エーテル、チオエーテル、スルホキシド、スルホン、スルホニウム、アルキルアミン、またはアルケニルアミン基、ヒドロキシル、ベンジルアミン、アミンオキシド、第四級アンモニア、アミド、イミド、アルコール、エステル、及び/またはウレタン基の形態で存在する]
の少なくとも一つの単位を含む化合物への作用により得られるポリマー;
(b)下式:
−D−X−D−X (VII’)
[式中、
Dは下式:
Xは記号EまたはE’を示し、ここでEまたはE’の少なくとも一つが上述の意味を有し、E’は主鎖中に上限7の炭素原子を含む直鎖または分枝鎖を含むアルキレン基である二価の基を示し、これは無置換であるかまたはヒドロキシル基で置換されており、一つ以上の窒素原子を含み、前記窒素原子はアルキル鎖(任意に酸素原子が介在し、且つ一つ以上のカルボキシル官能基または一つ以上のヒドロキシル官能基を必然的に含み、クロロ酢酸またはナトリウムクロロアセテートとの反応によってベタイン化されている)で置換されている]
のポリマー;
より選択される−D−X−D−X−タイプの両性ポリマー。
・ シリコーンオイル、揮発性及び不揮発性の、天然及び合成の油(使用可能なシリコーンオイルには、ジメチコーン、ジメチコノール、ポリジメチルシロキサン、例えばDow Corningから市販のDC fluidが含まれる)、
・ 天然オイル、例えばオリーブオイル、アーモンドオイル、アボカドオイル、ヴァイツェンカイムオイル、ヒマシ油、
・ 合成油、
・ 鉱物油、
等の化合物から選択される。
例示される全ての量は、特記のない限り、組成物全重量に対する重量による濃度である。
Claims (5)
- (a)i. 0.5乃至5重量%の、ジメチコーン/ビニルジメチコーンクロスポリマーである少なくとも一つの非乳化性シリコーンエラストマー;
ii.20乃至50重量%の、プロピレングリコール及びへキシレングリコールから選択される少なくとも一つの非水性極性溶媒;
iii.0.5乃至5重量%の、ポリビニルピロリドン、ビニルピロリドン/ビニルアセテートコポリマー、及びこれらの混合物から選択される、水溶性もしくは水分散性のポリマーである、少なくとも一つのスタイリングポリマー;
iv.0.1乃至10重量%の、オレス−2、ラウレス−4、及びラウレス−7から選択される少なくとも一つの非イオン性乳化剤;及び
v.水;
を含む組成物を準備する工程;及び
(b)前記組成物を髪に適用する工程;
を含む、髪のスタイリング方法。 - 少なくとも一つの前記乳化剤が、前記組成物の重量に基づいて0.5乃至6重量%の量で存在する、請求項1に記載の方法。
- (a)0.5乃至5重量%の、ジメチコーン/ビニルジメチコーンクロスポリマーである少なくとも一つの非乳化性シリコーンエラストマー;
(b)20乃至50重量%の、プロピレングリコール及びへキシレングリコールから選択される少なくとも一つの非水性極性溶媒;
(c)0.1乃至5重量%の、ポリビニルピロリドン、ビニルピロリドン/ビニルアセテートコポリマー、及びこれらの混合物から選択される、水溶性もしくは水分散性のポリマーである、少なくとも一つのスタイリングポリマー;
(d)0.1乃至10重量%の、オレス−2、ラウレス−4、及びラウレス−7から選択される少なくとも一つの非イオン性乳化剤;及び
(e)水;
を含む組成物であって、全ての重量は組成物の全重量に基づく、髪のスタイリングに使用される組成物。 - 少なくとも一つの前記乳化剤が、前記組成物の重量に基づいて0.5乃至6重量%の量で存在する、請求項3に記載の組成物。
- 髪のスタイリングまたは再成形のための、請求項3または4に記載の組成物の使用。
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-
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