JP5703023B2 - 低クリープ性の耐火セラミックおよび製造方法 - Google Patents
低クリープ性の耐火セラミックおよび製造方法 Download PDFInfo
- Publication number
- JP5703023B2 JP5703023B2 JP2010532057A JP2010532057A JP5703023B2 JP 5703023 B2 JP5703023 B2 JP 5703023B2 JP 2010532057 A JP2010532057 A JP 2010532057A JP 2010532057 A JP2010532057 A JP 2010532057A JP 5703023 B2 JP5703023 B2 JP 5703023B2
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- Prior art keywords
- sintering aid
- zircon
- ceramic
- sintering
- isopipe
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000004519 manufacturing process Methods 0.000 title claims description 18
- 239000011214 refractory ceramic Substances 0.000 title description 15
- 238000005245 sintering Methods 0.000 claims description 101
- 229910052845 zircon Inorganic materials 0.000 claims description 68
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 claims description 68
- 239000000203 mixture Substances 0.000 claims description 57
- 238000000034 method Methods 0.000 claims description 52
- 239000000919 ceramic Substances 0.000 claims description 47
- 239000002245 particle Substances 0.000 claims description 36
- 239000000843 powder Substances 0.000 claims description 35
- 239000007788 liquid Substances 0.000 claims description 29
- 239000002105 nanoparticle Substances 0.000 claims description 10
- 150000001875 compounds Chemical class 0.000 claims description 7
- 238000010304 firing Methods 0.000 claims description 7
- 238000000465 moulding Methods 0.000 claims description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 4
- 239000010936 titanium Substances 0.000 claims description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 3
- 238000001125 extrusion Methods 0.000 claims description 3
- 229910052719 titanium Inorganic materials 0.000 claims description 3
- 229910052742 iron Inorganic materials 0.000 claims description 2
- 238000007569 slipcasting Methods 0.000 claims description 2
- 239000000463 material Substances 0.000 description 39
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 21
- 239000011521 glass Substances 0.000 description 16
- 230000008569 process Effects 0.000 description 13
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 9
- 239000002243 precursor Substances 0.000 description 9
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 8
- 230000008901 benefit Effects 0.000 description 8
- 238000007499 fusion processing Methods 0.000 description 8
- 239000006060 molten glass Substances 0.000 description 8
- 239000011819 refractory material Substances 0.000 description 8
- 229910006501 ZrSiO Inorganic materials 0.000 description 7
- 239000005357 flat glass Substances 0.000 description 7
- 239000011148 porous material Substances 0.000 description 7
- 238000001694 spray drying Methods 0.000 description 7
- 238000009826 distribution Methods 0.000 description 6
- 229910010413 TiO 2 Inorganic materials 0.000 description 5
- 238000009770 conventional sintering Methods 0.000 description 4
- 239000006185 dispersion Substances 0.000 description 4
- 238000007500 overflow downdraw method Methods 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 239000004408 titanium dioxide Substances 0.000 description 4
- VXUYXOFXAQZZMF-UHFFFAOYSA-N titanium(IV) isopropoxide Chemical compound CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C VXUYXOFXAQZZMF-UHFFFAOYSA-N 0.000 description 4
- 239000011575 calcium Substances 0.000 description 3
- 229910010293 ceramic material Inorganic materials 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000000725 suspension Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 2
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 2
- 239000000292 calcium oxide Substances 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- -1 isopipes Substances 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 238000010079 rubber tapping Methods 0.000 description 2
- 238000007665 sagging Methods 0.000 description 2
- 238000006467 substitution reaction Methods 0.000 description 2
- 241000283690 Bos taurus Species 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 238000006124 Pilkington process Methods 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 238000000498 ball milling Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000013626 chemical specie Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 238000005056 compaction Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000000280 densification Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000007496 glass forming Methods 0.000 description 1
- 239000012761 high-performance material Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000004973 liquid crystal related substance Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000011234 nano-particulate material Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- SIWVEOZUMHYXCS-UHFFFAOYSA-N oxo(oxoyttriooxy)yttrium Chemical compound O=[Y]O[Y]=O SIWVEOZUMHYXCS-UHFFFAOYSA-N 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 230000008707 rearrangement Effects 0.000 description 1
- 238000001878 scanning electron micrograph Methods 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 238000003283 slot draw process Methods 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
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- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/48—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on zirconium or hafnium oxides, zirconates, zircon or hafnates
- C04B35/481—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on zirconium or hafnium oxides, zirconates, zircon or hafnates containing silicon, e.g. zircon
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B17/00—Forming molten glass by flowing-out, pushing-out, extruding or drawing downwardly or laterally from forming slits or by overflowing over lips
- C03B17/06—Forming glass sheets
- C03B17/064—Forming glass sheets by the overflow downdraw fusion process; Isopipes therefor
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- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
- C04B35/628—Coating the powders or the macroscopic reinforcing agents
- C04B35/62802—Powder coating materials
- C04B35/62805—Oxide ceramics
- C04B35/62818—Refractory metal oxides
- C04B35/62821—Titanium oxide
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- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
- C04B35/628—Coating the powders or the macroscopic reinforcing agents
- C04B35/62802—Powder coating materials
- C04B35/62805—Oxide ceramics
- C04B35/62826—Iron group metal oxides
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3231—Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
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- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/327—Iron group oxides, their mixed metal oxides, or oxide-forming salts thereof
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- C04B2235/50—Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
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- C04B2235/5418—Particle size related information expressed by the size of the particles or aggregates thereof
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- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/50—Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
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- C04B2235/5454—Particle size related information expressed by the size of the particles or aggregates thereof nanometer sized, i.e. below 100 nm
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/60—Aspects relating to the preparation, properties or mechanical treatment of green bodies or pre-forms
- C04B2235/604—Pressing at temperatures other than sintering temperatures
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
- C04B2235/72—Products characterised by the absence or the low content of specific components, e.g. alkali metal free alumina ceramics
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
- C04B2235/74—Physical characteristics
- C04B2235/77—Density
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
- C04B2235/95—Products characterised by their size, e.g. microceramics
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
- C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Structural Engineering (AREA)
- Inorganic Chemistry (AREA)
- Composite Materials (AREA)
- Nanotechnology (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Crystallography & Structural Chemistry (AREA)
- Compositions Of Oxide Ceramics (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/981,097 | 2007-10-31 | ||
| US11/981,097 US8986597B2 (en) | 2007-10-31 | 2007-10-31 | Low creep refractory ceramic and method of making |
| PCT/US2008/012337 WO2009058345A2 (en) | 2007-10-31 | 2008-10-30 | Low creep refractory ceramic and method of making |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2011502100A JP2011502100A (ja) | 2011-01-20 |
| JP2011502100A5 JP2011502100A5 (https=) | 2013-12-12 |
| JP5703023B2 true JP5703023B2 (ja) | 2015-04-15 |
Family
ID=40098942
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2010532057A Expired - Fee Related JP5703023B2 (ja) | 2007-10-31 | 2008-10-30 | 低クリープ性の耐火セラミックおよび製造方法 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US8986597B2 (https=) |
| EP (1) | EP2217546A2 (https=) |
| JP (1) | JP5703023B2 (https=) |
| KR (1) | KR101572281B1 (https=) |
| CN (1) | CN101910090A (https=) |
| TW (1) | TWI447090B (https=) |
| WO (1) | WO2009058345A2 (https=) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7988804B2 (en) * | 2008-05-02 | 2011-08-02 | Corning Incorporated | Material and method for bonding zircon blocks |
| TWI382572B (zh) * | 2010-02-12 | 2013-01-11 | Asia Vital Components Co Ltd | Used in the heating structure of the battery and the device and cooling auxiliary module |
| EP2539141A1 (en) | 2010-02-24 | 2013-01-02 | Corning Incorporated | Method of making a densified body by isostatically pressing in deep sea |
| TWI537231B (zh) * | 2010-07-12 | 2016-06-11 | 康寧公司 | 高靜態疲勞的氧化鋁隔離管 |
| US10421681B2 (en) | 2010-07-12 | 2019-09-24 | Corning Incorporated | Alumina isopipes for use with tin-containing glasses |
| DE102011111788A1 (de) * | 2011-09-01 | 2013-03-07 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Gesintertes flächiges Zirkonprodukt |
| US10308556B2 (en) | 2014-03-31 | 2019-06-04 | Saint-Gobain Ceramics & Plastics, Inc. | Sintered zircon material for forming block |
| WO2015153551A1 (en) | 2014-03-31 | 2015-10-08 | Saint-Gobain Ceramics & Plastics, Inc. | Sintered zircon material for forming block |
| US11465940B2 (en) | 2014-03-31 | 2022-10-11 | Saint-Gobain Ceramics & Plastics, Inc. | Sintered zircon material for forming block |
| CN105218121B (zh) * | 2015-10-30 | 2017-05-31 | 淄博工陶耐火材料有限公司 | 低蠕变、锆英石不分解的溢流砖及其制备方法 |
| KR102380180B1 (ko) * | 2020-01-14 | 2022-03-30 | 한양대학교 산학협력단 | 열 소결 및 광 소결을 이용한 세라믹 박막의 제조방법 |
Family Cites Families (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3338696A (en) | 1964-05-06 | 1967-08-29 | Corning Glass Works | Sheet forming apparatus |
| US3437470A (en) | 1966-06-17 | 1969-04-08 | Corning Glass Works | Constant force internal support for glass overflow wedge |
| BE757057A (fr) | 1969-10-06 | 1971-04-05 | Corning Glass Works | Procede et appareil de controle d'epaisseur d'une feuille de verre nouvellement etiree |
| US3899341A (en) | 1973-04-30 | 1975-08-12 | Didier Werke Ag | Refractory fired shaped element and process of its manufacture |
| JPS59164673A (ja) * | 1983-03-11 | 1984-09-17 | 三井造船株式会社 | セラミツク粉体と焼結助剤均一化方法 |
| CN85108307A (zh) * | 1985-11-24 | 1987-06-03 | 梅河口市砂轮厂 | 用氧化铝导熔合成高纯电熔莫来石 |
| AU597664B2 (en) * | 1986-05-28 | 1990-06-07 | Cookson Group Plc | An improved ceramic material |
| JPS6476976A (en) * | 1987-09-18 | 1989-03-23 | Toshiba Corp | Production of sintered material of complex ceramic |
| EP0447509B1 (en) | 1989-09-08 | 1998-01-07 | Corhart Refractories Corporation | Zircon refractories with improved thermal shock resistance |
| DE4243538C2 (de) | 1992-12-22 | 1995-05-11 | Dyko Industriekeramik Gmbh | Zirkonsilikatstein und Verfahren zu seiner Herstellung |
| CN1080709C (zh) * | 1998-01-23 | 2002-03-13 | 任建军 | 一种低蠕变耐火球 |
| JP3837729B2 (ja) | 1998-03-05 | 2006-10-25 | 日本電気硝子株式会社 | 板ガラス成形装置 |
| SE0002770D0 (sv) * | 2000-07-25 | 2000-07-25 | Biomat System Ab | a method of producing a body by adiabatic forming and the body produced |
| CN102992592A (zh) | 2000-12-01 | 2013-03-27 | 康宁股份有限公司 | 熔融法生产平板玻璃所用的等静压板的下沉控制 |
| JP2002293649A (ja) * | 2001-03-28 | 2002-10-09 | Kyocera Corp | セラミック焼結体の製造方法 |
| JP2003169431A (ja) | 2001-11-29 | 2003-06-13 | Hitachi Ltd | 電動機 |
| CA2488856A1 (en) * | 2002-06-20 | 2003-12-31 | Cytos Biotechnology Ag | Packaged virus-like particles for use as adjuvants: method of preparation and use |
| US7238635B2 (en) | 2003-12-16 | 2007-07-03 | Corning Incorporated | Creep resistant zircon refractory material used in a glass manufacturing system |
| FR2884510B1 (fr) | 2005-04-15 | 2007-06-22 | Saint Gobain Mat Constr Sas | Produit fritte a base de zircon |
| CN100488916C (zh) * | 2007-03-09 | 2009-05-20 | 西南科技大学 | 含立方氮化硅粉体的陶瓷及其制备方法 |
| US7704905B2 (en) | 2007-05-07 | 2010-04-27 | Corning Incorporated | Reduced strain refractory ceramic composite and method of making |
| WO2009054951A1 (en) | 2007-10-26 | 2009-04-30 | Corning Incorporated | Low-creep-zircon material with nano-additives and method of making same |
-
2007
- 2007-10-31 US US11/981,097 patent/US8986597B2/en not_active Expired - Fee Related
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2008
- 2008-10-30 KR KR1020107011996A patent/KR101572281B1/ko not_active Expired - Fee Related
- 2008-10-30 CN CN2008801239703A patent/CN101910090A/zh active Pending
- 2008-10-30 WO PCT/US2008/012337 patent/WO2009058345A2/en not_active Ceased
- 2008-10-30 EP EP08845949A patent/EP2217546A2/en not_active Withdrawn
- 2008-10-30 JP JP2010532057A patent/JP5703023B2/ja not_active Expired - Fee Related
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Also Published As
| Publication number | Publication date |
|---|---|
| JP2011502100A (ja) | 2011-01-20 |
| WO2009058345A2 (en) | 2009-05-07 |
| KR20100098616A (ko) | 2010-09-08 |
| KR101572281B1 (ko) | 2015-11-26 |
| US8986597B2 (en) | 2015-03-24 |
| US20090111679A1 (en) | 2009-04-30 |
| WO2009058345A3 (en) | 2009-12-23 |
| EP2217546A2 (en) | 2010-08-18 |
| TWI447090B (zh) | 2014-08-01 |
| CN101910090A (zh) | 2010-12-08 |
| TW200938512A (en) | 2009-09-16 |
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