JP5677311B2 - 改善された断熱能力を備えた発泡性ビニル芳香族ポリマーの組成物、それを製造するプロセス、及びそれから得られる発泡品 - Google Patents
改善された断熱能力を備えた発泡性ビニル芳香族ポリマーの組成物、それを製造するプロセス、及びそれから得られる発泡品 Download PDFInfo
- Publication number
- JP5677311B2 JP5677311B2 JP2011541220A JP2011541220A JP5677311B2 JP 5677311 B2 JP5677311 B2 JP 5677311B2 JP 2011541220 A JP2011541220 A JP 2011541220A JP 2011541220 A JP2011541220 A JP 2011541220A JP 5677311 B2 JP5677311 B2 JP 5677311B2
- Authority
- JP
- Japan
- Prior art keywords
- polymer
- range
- vinyl aromatic
- weight
- thermal barrier
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229920000642 polymer Polymers 0.000 title claims description 226
- 229920002554 vinyl polymer Polymers 0.000 title claims description 118
- 239000000203 mixture Substances 0.000 title claims description 115
- 238000000034 method Methods 0.000 title claims description 82
- 238000009413 insulation Methods 0.000 title description 10
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 69
- 239000002245 particle Substances 0.000 claims description 66
- 230000004888 barrier function Effects 0.000 claims description 60
- 239000000945 filler Substances 0.000 claims description 60
- 229910002804 graphite Inorganic materials 0.000 claims description 59
- 239000010439 graphite Substances 0.000 claims description 59
- 239000008187 granular material Substances 0.000 claims description 57
- 239000000571 coke Substances 0.000 claims description 53
- 239000000178 monomer Substances 0.000 claims description 46
- 239000011324 bead Substances 0.000 claims description 35
- 239000000654 additive Substances 0.000 claims description 33
- 239000006229 carbon black Substances 0.000 claims description 32
- 239000004594 Masterbatch (MB) Substances 0.000 claims description 29
- 238000002156 mixing Methods 0.000 claims description 29
- 239000004604 Blowing Agent Substances 0.000 claims description 27
- 238000006116 polymerization reaction Methods 0.000 claims description 27
- 239000008188 pellet Substances 0.000 claims description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 17
- 239000006260 foam Substances 0.000 claims description 16
- 230000000996 additive effect Effects 0.000 claims description 15
- 238000004519 manufacturing process Methods 0.000 claims description 15
- 238000006243 chemical reaction Methods 0.000 claims description 14
- 239000011159 matrix material Substances 0.000 claims description 13
- 230000003068 static effect Effects 0.000 claims description 10
- 239000007900 aqueous suspension Substances 0.000 claims description 9
- 238000005520 cutting process Methods 0.000 claims description 9
- 239000003795 chemical substances by application Substances 0.000 claims description 8
- 239000004088 foaming agent Substances 0.000 claims description 6
- 238000010528 free radical solution polymerization reaction Methods 0.000 claims description 6
- 230000000379 polymerizing effect Effects 0.000 claims description 6
- 238000005469 granulation Methods 0.000 claims description 5
- 230000003179 granulation Effects 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 5
- 239000003999 initiator Substances 0.000 claims description 5
- 238000002844 melting Methods 0.000 claims description 5
- 230000008018 melting Effects 0.000 claims description 5
- 229920002959 polymer blend Polymers 0.000 claims description 5
- OUUQCZGPVNCOIJ-UHFFFAOYSA-M Superoxide Chemical compound [O-][O] OUUQCZGPVNCOIJ-UHFFFAOYSA-M 0.000 claims description 4
- 238000012662 bulk polymerization Methods 0.000 claims description 4
- 238000000265 homogenisation Methods 0.000 claims description 4
- 239000011877 solvent mixture Substances 0.000 claims description 4
- 229920001577 copolymer Polymers 0.000 claims description 3
- 238000011049 filling Methods 0.000 claims description 2
- 238000005259 measurement Methods 0.000 claims 1
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 22
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 16
- 239000003063 flame retardant Substances 0.000 description 15
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 12
- 238000012360 testing method Methods 0.000 description 12
- 229910052799 carbon Inorganic materials 0.000 description 11
- 239000000243 solution Substances 0.000 description 11
- 239000004793 Polystyrene Substances 0.000 description 9
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 9
- 229920002223 polystyrene Polymers 0.000 description 9
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 8
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 7
- 239000011329 calcined coke Substances 0.000 description 7
- 239000011248 coating agent Substances 0.000 description 7
- 238000000576 coating method Methods 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- 229920006248 expandable polystyrene Polymers 0.000 description 6
- 238000005187 foaming Methods 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 6
- 239000000725 suspension Substances 0.000 description 6
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical class [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 6
- 235000019441 ethanol Nutrition 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 238000010557 suspension polymerization reaction Methods 0.000 description 5
- HGTUJZTUQFXBIH-UHFFFAOYSA-N (2,3-dimethyl-3-phenylbutan-2-yl)benzene Chemical compound C=1C=CC=CC=1C(C)(C)C(C)(C)C1=CC=CC=C1 HGTUJZTUQFXBIH-UHFFFAOYSA-N 0.000 description 4
- DEIGXXQKDWULML-UHFFFAOYSA-N 1,2,5,6,9,10-hexabromocyclododecane Chemical compound BrC1CCC(Br)C(Br)CCC(Br)C(Br)CCC1Br DEIGXXQKDWULML-UHFFFAOYSA-N 0.000 description 4
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 4
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 4
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 4
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 4
- 239000002216 antistatic agent Substances 0.000 description 4
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 4
- 229910052794 bromium Inorganic materials 0.000 description 4
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 4
- 239000004794 expanded polystyrene Substances 0.000 description 4
- 238000001125 extrusion Methods 0.000 description 4
- 229940075507 glyceryl monostearate Drugs 0.000 description 4
- 239000001788 mono and diglycerides of fatty acids Substances 0.000 description 4
- 239000002667 nucleating agent Substances 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 description 4
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 3
- 230000033228 biological regulation Effects 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 239000001569 carbon dioxide Substances 0.000 description 3
- 229910002092 carbon dioxide Inorganic materials 0.000 description 3
- 238000002485 combustion reaction Methods 0.000 description 3
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 3
- 230000009477 glass transition Effects 0.000 description 3
- 235000011187 glycerol Nutrition 0.000 description 3
- 239000000155 melt Substances 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- -1 pentane or hexane Chemical class 0.000 description 3
- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 description 3
- 229940001584 sodium metabisulfite Drugs 0.000 description 3
- 235000010262 sodium metabisulphite Nutrition 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- 230000002195 synergetic effect Effects 0.000 description 3
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 2
- CWLQIBNDJLDDOE-UHFFFAOYSA-K P(=O)([O-])([O-])[O-].[Ca+2].[Ca+2].[Ca+2].[Na+] Chemical compound P(=O)([O-])([O-])[O-].[Ca+2].[Ca+2].[Ca+2].[Na+] CWLQIBNDJLDDOE-UHFFFAOYSA-K 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 238000003763 carbonization Methods 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 239000003245 coal Substances 0.000 description 2
- 239000004020 conductor Substances 0.000 description 2
- GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 235000012438 extruded product Nutrition 0.000 description 2
- 230000009970 fire resistant effect Effects 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- 239000002006 petroleum coke Substances 0.000 description 2
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 2
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 2
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 2
- 229940048086 sodium pyrophosphate Drugs 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 2
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- WQJUBZMZVKITBU-UHFFFAOYSA-N (3,4-dimethyl-4-phenylhexan-3-yl)benzene Chemical compound C=1C=CC=CC=1C(C)(CC)C(C)(CC)C1=CC=CC=C1 WQJUBZMZVKITBU-UHFFFAOYSA-N 0.000 description 1
- VBHGWYJTOJBCPY-UHFFFAOYSA-N (3-methyl-2-phenylpentan-3-yl)benzene Chemical compound C=1C=CC=CC=1C(C)(CC)C(C)C1=CC=CC=C1 VBHGWYJTOJBCPY-UHFFFAOYSA-N 0.000 description 1
- UJPMYEOUBPIPHQ-UHFFFAOYSA-N 1,1,1-trifluoroethane Chemical compound CC(F)(F)F UJPMYEOUBPIPHQ-UHFFFAOYSA-N 0.000 description 1
- AUTSLLHNWAZVLE-UHFFFAOYSA-N 1,1,2,2,3-pentabromo-3-chlorocyclohexane Chemical compound ClC1(Br)CCCC(Br)(Br)C1(Br)Br AUTSLLHNWAZVLE-UHFFFAOYSA-N 0.000 description 1
- WGZYQOSEVSXDNI-UHFFFAOYSA-N 1,1,2-trifluoroethane Chemical compound FCC(F)F WGZYQOSEVSXDNI-UHFFFAOYSA-N 0.000 description 1
- SVHAMPNLOLKSFU-UHFFFAOYSA-N 1,2,2-trichloroethenylbenzene Chemical compound ClC(Cl)=C(Cl)C1=CC=CC=C1 SVHAMPNLOLKSFU-UHFFFAOYSA-N 0.000 description 1
- VCNJVIWFSMCZPE-UHFFFAOYSA-N 1,2,3,4,5-pentabromo-6-prop-2-enoxybenzene Chemical compound BrC1=C(Br)C(Br)=C(OCC=C)C(Br)=C1Br VCNJVIWFSMCZPE-UHFFFAOYSA-N 0.000 description 1
- AUHKVLIZXLBQSR-UHFFFAOYSA-N 1,2-dichloro-3-(1,2,2-trichloroethenyl)benzene Chemical compound ClC(Cl)=C(Cl)C1=CC=CC(Cl)=C1Cl AUHKVLIZXLBQSR-UHFFFAOYSA-N 0.000 description 1
- XPXMCUKPGZUFGR-UHFFFAOYSA-N 1-chloro-2-(1,2,2-trichloroethenyl)benzene Chemical compound ClC(Cl)=C(Cl)C1=CC=CC=C1Cl XPXMCUKPGZUFGR-UHFFFAOYSA-N 0.000 description 1
- CISIJYCKDJSTMX-UHFFFAOYSA-N 2,2-dichloroethenylbenzene Chemical compound ClC(Cl)=CC1=CC=CC=C1 CISIJYCKDJSTMX-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- SBYMUDUGTIKLCR-UHFFFAOYSA-N 2-chloroethenylbenzene Chemical compound ClC=CC1=CC=CC=C1 SBYMUDUGTIKLCR-UHFFFAOYSA-N 0.000 description 1
- CTHJQRHPNQEPAB-UHFFFAOYSA-N 2-methoxyethenylbenzene Chemical compound COC=CC1=CC=CC=C1 CTHJQRHPNQEPAB-UHFFFAOYSA-N 0.000 description 1
- BTOVVHWKPVSLBI-UHFFFAOYSA-N 2-methylprop-1-enylbenzene Chemical compound CC(C)=CC1=CC=CC=C1 BTOVVHWKPVSLBI-UHFFFAOYSA-N 0.000 description 1
- FMFHUEMLVAIBFI-UHFFFAOYSA-N 2-phenylethenyl acetate Chemical compound CC(=O)OC=CC1=CC=CC=C1 FMFHUEMLVAIBFI-UHFFFAOYSA-N 0.000 description 1
- VEORPZCZECFIRK-UHFFFAOYSA-N 3,3',5,5'-tetrabromobisphenol A Chemical compound C=1C(Br)=C(O)C(Br)=CC=1C(C)(C)C1=CC(Br)=C(O)C(Br)=C1 VEORPZCZECFIRK-UHFFFAOYSA-N 0.000 description 1
- FRIBMENBGGCKPD-UHFFFAOYSA-N 3-(2,3-dimethoxyphenyl)prop-2-enal Chemical compound COC1=CC=CC(C=CC=O)=C1OC FRIBMENBGGCKPD-UHFFFAOYSA-N 0.000 description 1
- ATVJXMYDOSMEPO-UHFFFAOYSA-N 3-prop-2-enoxyprop-1-ene Chemical compound C=CCOCC=C ATVJXMYDOSMEPO-UHFFFAOYSA-N 0.000 description 1
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 239000004338 Dichlorodifluoromethane Substances 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 229920013701 VORANOL™ Polymers 0.000 description 1
- YMOONIIMQBGTDU-VOTSOKGWSA-N [(e)-2-bromoethenyl]benzene Chemical compound Br\C=C\C1=CC=CC=C1 YMOONIIMQBGTDU-VOTSOKGWSA-N 0.000 description 1
- XQBCVRSTVUHIGH-UHFFFAOYSA-L [dodecanoyloxy(dioctyl)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCCCCCC)(CCCCCCCC)OC(=O)CCCCCCCCCCC XQBCVRSTVUHIGH-UHFFFAOYSA-L 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000007824 aliphatic compounds Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000003973 alkyl amines Chemical group 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 230000031709 bromination Effects 0.000 description 1
- 238000005893 bromination reaction Methods 0.000 description 1
- MPMBRWOOISTHJV-UHFFFAOYSA-N but-1-enylbenzene Chemical compound CCC=CC1=CC=CC=C1 MPMBRWOOISTHJV-UHFFFAOYSA-N 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 239000001506 calcium phosphate Substances 0.000 description 1
- 239000012159 carrier gas Substances 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 238000004939 coking Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- WCRDXYSYPCEIAK-UHFFFAOYSA-N dibutylstannane Chemical compound CCCC[SnH2]CCCC WCRDXYSYPCEIAK-UHFFFAOYSA-N 0.000 description 1
- PXBRQCKWGAHEHS-UHFFFAOYSA-N dichlorodifluoromethane Chemical compound FC(F)(Cl)Cl PXBRQCKWGAHEHS-UHFFFAOYSA-N 0.000 description 1
- 235000019404 dichlorodifluoromethane Nutrition 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- VVSMKOFFCAJOSC-UHFFFAOYSA-L disodium;dodecylbenzene;sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O.CCCCCCCCCCCCC1=CC=CC=C1 VVSMKOFFCAJOSC-UHFFFAOYSA-L 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 230000002431 foraging effect Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 1
- KETWBQOXTBGBBN-UHFFFAOYSA-N hex-1-enylbenzene Chemical compound CCCCC=CC1=CC=CC=C1 KETWBQOXTBGBBN-UHFFFAOYSA-N 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 229960001545 hydrotalcite Drugs 0.000 description 1
- 229910001701 hydrotalcite Inorganic materials 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- 239000006233 lamp black Substances 0.000 description 1
- 239000003077 lignite Substances 0.000 description 1
- 239000004973 liquid crystal related substance Substances 0.000 description 1
- GVALZJMUIHGIMD-UHFFFAOYSA-H magnesium phosphate Chemical compound [Mg+2].[Mg+2].[Mg+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O GVALZJMUIHGIMD-UHFFFAOYSA-H 0.000 description 1
- 239000004137 magnesium phosphate Substances 0.000 description 1
- 229960002261 magnesium phosphate Drugs 0.000 description 1
- 229910000157 magnesium phosphate Inorganic materials 0.000 description 1
- 235000010994 magnesium phosphates Nutrition 0.000 description 1
- 235000019359 magnesium stearate Nutrition 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000011331 needle coke Substances 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 238000011017 operating method Methods 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 238000004525 petroleum distillation Methods 0.000 description 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical class OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000006253 pitch coke Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920006327 polystyrene foam Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- LYBIZMNPXTXVMV-UHFFFAOYSA-N propan-2-yl prop-2-enoate Chemical compound CC(C)OC(=O)C=C LYBIZMNPXTXVMV-UHFFFAOYSA-N 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 230000002285 radioactive effect Effects 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 238000012552 review Methods 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 230000002226 simultaneous effect Effects 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000375 suspending agent Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
- 229940078499 tricalcium phosphate Drugs 0.000 description 1
- 229910000391 tricalcium phosphate Inorganic materials 0.000 description 1
- 235000019731 tricalcium phosphate Nutrition 0.000 description 1
- 150000005691 triesters Chemical class 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0066—Use of inorganic compounding ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2325/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
- C08J2325/02—Homopolymers or copolymers of hydrocarbons
- C08J2325/04—Homopolymers or copolymers of styrene
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ITMI2008A002278A IT1392391B1 (it) | 2008-12-19 | 2008-12-19 | Composizioni di polimeri vinilaromatici espansibili a migliorata capacita' di isolamento termico, procedimento per la loro preparazione ed articoli espansi da loro ottenuti |
| ITMI2008A002278 | 2008-12-19 | ||
| PCT/EP2009/009110 WO2010069584A1 (en) | 2008-12-19 | 2009-12-16 | Compositions of expandable vinyl aromatic polymers with an improved thermal insulation capacity, process for their production and expanded articles obtained therefrom |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2012512917A JP2012512917A (ja) | 2012-06-07 |
| JP2012512917A5 JP2012512917A5 (enExample) | 2013-02-07 |
| JP5677311B2 true JP5677311B2 (ja) | 2015-02-25 |
Family
ID=41138886
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2011541220A Expired - Fee Related JP5677311B2 (ja) | 2008-12-19 | 2009-12-16 | 改善された断熱能力を備えた発泡性ビニル芳香族ポリマーの組成物、それを製造するプロセス、及びそれから得られる発泡品 |
Country Status (12)
| Country | Link |
|---|---|
| US (2) | US20110284793A1 (enExample) |
| EP (1) | EP2358798B2 (enExample) |
| JP (1) | JP5677311B2 (enExample) |
| CN (1) | CN102307937B (enExample) |
| BR (1) | BRPI0923030B1 (enExample) |
| ES (1) | ES2536126T5 (enExample) |
| HU (1) | HUE025927T2 (enExample) |
| IT (1) | IT1392391B1 (enExample) |
| MX (1) | MX2011006635A (enExample) |
| PL (1) | PL2358798T5 (enExample) |
| RU (1) | RU2510406C2 (enExample) |
| WO (1) | WO2010069584A1 (enExample) |
Families Citing this family (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1393962B1 (it) | 2009-05-05 | 2012-05-17 | Polimeri Europa Spa | Articoli espansi con ottima resistenza allo irraggiamento solare e ottime proprieta' termoisolanti e meccaniche |
| IT1395379B1 (it) | 2009-09-07 | 2012-09-14 | Polimeri Europa Spa | Procedimento per la preparazione di polimeri vinilaromatici espansibili a ridotta conducibilita' termica mediante polimerizzazione in sospensione |
| IT1396193B1 (it) * | 2009-10-07 | 2012-11-16 | Polimeri Europa Spa | Composizioni polimeriche nanocomposite termoplastiche espansibili con migliorata capacita' di isolamento termico. |
| NL2004588C2 (nl) * | 2010-04-21 | 2011-10-24 | Synbra Tech Bv | Deeltjesvormig, expandeerbaar polymeer, werkwijze ter vervaardiging hiervan, alsmede de toepassing. |
| AT510312B1 (de) * | 2010-08-27 | 2013-02-15 | Sunpor Kunststoff Gmbh | Polymerschaumkörper oder teilchenförmige expandierbare polymerisatpartikel und verfahren zu deren herstellung |
| JP5685072B2 (ja) * | 2010-12-15 | 2015-03-18 | 積水化学工業株式会社 | 熱発泡性粒子及び発泡体の製造方法 |
| JP5885294B2 (ja) * | 2011-11-30 | 2016-03-15 | 株式会社ジェイエスピー | ポリスチレン系樹脂押出発泡板 |
| EP2794673A1 (de) * | 2011-12-21 | 2014-10-29 | Basf Se | Verfahren zur herstellung von expandierbaren, partikelförmige additive enthaltenden styrolpolymeren |
| ITMI20120571A1 (it) | 2012-04-06 | 2013-10-07 | Versalis Spa | "procedimento per l'adduzione e il trasporto di additivi labili in correnti di materiale fuso" |
| PL2872550T3 (pl) * | 2012-07-10 | 2017-03-31 | Ineos Europe Ag | Sposób otrzymywania spieniającego się polistyrenu |
| ITMI20121808A1 (it) | 2012-10-24 | 2014-04-25 | Versalis Spa | Composizioni polimeriche concentrate di polimeri e/o copolimeri vinilaromatici |
| ITMI20121973A1 (it) * | 2012-11-20 | 2014-05-21 | Versalis Spa | Composizione polimerica autoestinguente |
| HRP20170728T1 (hr) | 2012-12-28 | 2017-09-22 | Total Research & Technology Feluy | Rastezljivi vinil aromatski polimeri koji sadrže čestice igličastog koksa |
| HUE046210T2 (hu) | 2012-12-28 | 2020-02-28 | Total Res & Technology Feluy | Polimodális szemcseméret eloszlású grafit szemcséket tartalmazó expandálható vinilaromás polimerek |
| DE102014213685A1 (de) * | 2014-07-15 | 2016-01-21 | Sgl Carbon Se | Neuartige Polystyrolhartschaumstoffe |
| JP6735281B2 (ja) | 2015-01-14 | 2020-08-05 | シントス エス．アー．Ｓｙｎｔｈｏｓ Ｓ．Ａ． | ペロブスカイト構造を有する鉱物のビニル芳香族ポリマーフォームでの使用 |
| MA41344B1 (fr) | 2015-01-14 | 2019-01-31 | Synthos Sa | Combinaison de silice et de graphite et son utilisation pour réduire la conductivité thermique d'une mousse de polymère aromatique vinylique |
| CA2973630A1 (en) | 2015-01-14 | 2016-07-21 | Synthos S.A. | Geopolymer composite and expandable vinyl aromatic polymer granulate and expanded vinyl aromatic polymer foam comprising the same |
| MA41342A (fr) | 2015-01-14 | 2017-11-21 | Synthos Sa | Procédé pour la production de granulés de polymère vinylique aromatique expansible ayant une conductivité thermique réduite |
| CN109312108A (zh) | 2016-05-11 | 2019-02-05 | 欧文斯科宁知识产权资产有限公司 | 包含低水平溴化阻燃剂的聚合物泡沫及其制备方法 |
| US11834563B2 (en) | 2016-10-10 | 2023-12-05 | Totalenergies Onetech Belgium | Expandable vinyl aromatic polymers |
| KR102419948B1 (ko) | 2016-10-10 | 2022-07-12 | 토탈 리서치 앤드 테크놀로지 펠루이 | 개선된 팽창성 비닐 방향족 중합체 |
| EP3523361A1 (en) | 2016-10-10 | 2019-08-14 | Total Research & Technology Feluy | Improved expandable vinyl aromatic polymers |
| JP6844921B2 (ja) * | 2016-10-31 | 2021-03-17 | コスモ石油株式会社 | 遮熱材、遮熱組成物、遮熱膜および遮熱建材 |
| EP3352290B1 (en) * | 2017-01-19 | 2024-07-17 | 3M Innovative Properties Company | Aziridino-functional polyether thermally-conductive gap filler |
| EP3594276A4 (en) * | 2017-03-07 | 2020-11-04 | Kaneka Corporation | STYRENE RESIN EXTRUDED FOAM AND ITS PRODUCTION PROCESS |
| CN114341256A (zh) | 2019-09-04 | 2022-04-12 | 道达尔能源一技术比利时公司 | 具有改进的阻燃性的可膨胀乙烯基芳族聚合物 |
| IT202300001389A1 (it) | 2023-01-30 | 2024-07-30 | Versalis Spa | Granuli espandibili e manufatti da essi ottenuti. |
| WO2025006269A2 (en) * | 2023-06-28 | 2025-01-02 | Ticona Llc | Flame retardant and low viscosity liquid crystalline polymer composition |
Family Cites Families (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3631014A (en) | 1967-05-26 | 1971-12-28 | Sinclair Koppers Co | Suspension polymerization process |
| JPS6031536B2 (ja) | 1976-09-09 | 1985-07-23 | 財団法人電力中央研究所 | 液化ガスによる電気機器容器内の塵挨除去方法 |
| SU992542A1 (ru) * | 1981-04-29 | 1983-01-30 | Производственное объединение "ХЛОРВИНИЛ" им.60-летия Великой Октябрьской социалистической революции | Полимерна композици |
| JPS63183941A (ja) | 1987-01-27 | 1988-07-29 | Asahi Chem Ind Co Ltd | 断熱用熱可塑性樹脂発泡体 |
| US5041465A (en) | 1990-09-17 | 1991-08-20 | Arco Chemical Technology, Inc. | Reducing lustrous carbon in the lost foam process |
| DE9305431U1 (de) | 1993-04-13 | 1994-08-11 | AlgoStat GmbH & Co. KG, 29227 Celle | Formkörper aus Polystyrol-Hartschaum |
| EP0902804A1 (de) | 1996-05-28 | 1999-03-24 | Basf Aktiengesellschaft | Russpartikel enthaltende expandierbare styrolpolymerisate |
| DE59702327D1 (de) * | 1997-05-14 | 2000-10-12 | Basf Ag | Graphitpartikel enthaltende expandierbare styrolpolymerisate |
| ES2151270T3 (es) * | 1997-05-14 | 2000-12-16 | Basf Ag | Procedimiento para la obtencion de polimeros de estireno expandibles que contienen particulas de grafito. |
| DE19742910A1 (de) * | 1997-09-29 | 1999-04-01 | Basf Ag | Verfahren zur Herstellung von expandierbaren Styrolpolymerisaten |
| JP2002521543A (ja) * | 1998-07-27 | 2002-07-16 | ビーエーエスエフ アクチェンゲゼルシャフト | グラファイト粒子を含む発泡性スチレン重合体の製造法 |
| EP0987292A1 (en) * | 1998-09-16 | 2000-03-22 | Shell Internationale Researchmaatschappij B.V. | Process for the preparation of expanded polyvinylarene particles |
| DE19843327A1 (de) * | 1998-09-22 | 2000-03-23 | Basf Ag | Teilchenförmige, expandierbare Styrolpolymerisate |
| CN1135251C (zh) * | 1998-12-09 | 2004-01-21 | 巴斯福股份公司 | 发泡性聚苯乙烯粒子的制备工艺 |
| DE10101432A1 (de) * | 2001-01-13 | 2002-07-18 | Basf Ag | Kohlenstoffpartikel enthaltende expandierbare Styrolpolymerisate |
| ITMI20012706A1 (it) | 2001-12-20 | 2003-06-20 | Enichem Spa | Procedimento per la produzione di granuli di polimeri termoplastici espandibili ed apparecchiatura adatta allo scopo |
| ITMI20012708A1 (it) | 2001-12-20 | 2003-06-20 | Enichem Spa | Dispositivo per la granulazione a caldo di polimeri termolastici |
| ITMI20030627A1 (it) | 2003-03-31 | 2004-10-01 | Polimeri Europa Spa | Polimeri vinilaromatici espandibili e procedimento per la loro preparazione. |
| DE102004058583A1 (de) * | 2004-12-03 | 2006-06-14 | Basf Ag | Expandierbare Styrolpolymergranulate und Partikelschaumstoffe mit verringerter Wärmeleitfähigkeit |
| WO2006061571A1 (en) | 2004-12-06 | 2006-06-15 | Ineos Europe Limited | Expandable polystyrene composition |
| ITMI20050666A1 (it) * | 2005-04-15 | 2006-10-16 | Polimeri Europa Spa | Procedimento per il migoioramento del potere isolante di polimeri vinilaromatici espansi e prodotti cosi'ottenuti |
| ITMO20050135A1 (it) | 2005-06-03 | 2006-12-04 | Coopbox Europ S P A | Procedimento per la produzione di polistirolo espanso. |
| DE102005039976A1 (de) * | 2005-08-23 | 2007-03-08 | Basf Ag | Partikel aus expandierbarem Polystyrol und daraus erhältliche Formteile mit verbessertem Brandverhalten |
| IT1366567B (it) * | 2005-10-18 | 2009-10-06 | Polimeri Europa Spa | Granulati espandibili a basemdi polimeri vinilaromatici dotati di migliorata espansibilita'e procedimento per la loro preparazione |
| US20070105967A1 (en) † | 2005-11-08 | 2007-05-10 | Govind Rauniyar | Thermoplastic material |
| ITMI20062245A1 (it) * | 2006-11-23 | 2008-05-24 | Polimeri Europa Spa | Polimeri vinilaromatici espandibili a migliorata capacita' di isolamento termico e procedimento per la loro preparazione |
| ITMI20071005A1 (it) * | 2007-05-18 | 2008-11-19 | Polimeri Europa Spa | Procedimento per la preparazione di granuli a base di polimeri termoplastici espandibili e relativo prodotto |
| ITMI20071003A1 (it) † | 2007-05-18 | 2008-11-19 | Polimeri Europa Spa | Compositi a base di polimeri vinilaromatici aventi migliorate proprieta' di isolamento termico e procedimento per la loro preparazione |
| ITMI20080823A1 (it) | 2008-05-07 | 2009-11-08 | Polimeri Europa Spa | Composizioni di polimeri vinilaromatici espansibili a migliorata capacita' di isolamento termico, procedimento per la loro preparazione ed articoli espansi da esse ottenuti |
-
2008
- 2008-12-19 IT ITMI2008A002278A patent/IT1392391B1/it active
-
2009
- 2009-12-16 CN CN2009801560949A patent/CN102307937B/zh active Active
- 2009-12-16 ES ES09795928T patent/ES2536126T5/es active Active
- 2009-12-16 HU HUE09795928A patent/HUE025927T2/hu unknown
- 2009-12-16 BR BRPI0923030A patent/BRPI0923030B1/pt not_active IP Right Cessation
- 2009-12-16 US US13/140,500 patent/US20110284793A1/en not_active Abandoned
- 2009-12-16 EP EP09795928.2A patent/EP2358798B2/en active Active
- 2009-12-16 RU RU2011127677/04A patent/RU2510406C2/ru active
- 2009-12-16 WO PCT/EP2009/009110 patent/WO2010069584A1/en not_active Ceased
- 2009-12-16 MX MX2011006635A patent/MX2011006635A/es active IP Right Grant
- 2009-12-16 JP JP2011541220A patent/JP5677311B2/ja not_active Expired - Fee Related
- 2009-12-16 PL PL09795928T patent/PL2358798T5/pl unknown
-
2018
- 2018-06-04 US US15/996,683 patent/US10961365B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| RU2011127677A (ru) | 2013-01-27 |
| US20110284793A1 (en) | 2011-11-24 |
| PL2358798T3 (pl) | 2015-07-31 |
| MX2011006635A (es) | 2011-11-29 |
| BRPI0923030A2 (pt) | 2015-12-15 |
| CN102307937B (zh) | 2013-05-29 |
| US10961365B2 (en) | 2021-03-30 |
| HK1157369A1 (en) | 2012-06-29 |
| HUE025927T2 (hu) | 2016-05-30 |
| EP2358798A1 (en) | 2011-08-24 |
| US20180273717A1 (en) | 2018-09-27 |
| IT1392391B1 (it) | 2012-03-02 |
| RU2510406C2 (ru) | 2014-03-27 |
| CN102307937A (zh) | 2012-01-04 |
| EP2358798B2 (en) | 2021-08-18 |
| PL2358798T5 (pl) | 2021-11-29 |
| ES2536126T3 (es) | 2015-05-20 |
| BRPI0923030B1 (pt) | 2020-01-21 |
| ES2536126T5 (es) | 2022-02-23 |
| WO2010069584A1 (en) | 2010-06-24 |
| EP2358798B1 (en) | 2015-02-11 |
| ITMI20082278A1 (it) | 2010-06-20 |
| JP2012512917A (ja) | 2012-06-07 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP5677311B2 (ja) | 改善された断熱能力を備えた発泡性ビニル芳香族ポリマーの組成物、それを製造するプロセス、及びそれから得られる発泡品 | |
| JP5570501B2 (ja) | 改善された断熱性能を備えた発泡性ビニル芳香族ポリマー組成物、その調製方法及びその組成物から得られる発泡物品 | |
| EP2092002B1 (en) | Expandable vinyl aromatic polymers with enhanced heat insulation and process for the preparation thereof | |
| EP2427514B1 (en) | Expanded articles with excellent resistance to solar radiation and optimum thermoinsulating and mechanical properties | |
| JP5798554B2 (ja) | 断熱性発泡物品及びその調製のための組成物 | |
| EP3087127B1 (en) | Use of sterically hindered styrene comonomer for improving the thermal stability of expanded vinyl aromatic polymer | |
| HK1157369B (en) | Compositions of expandable vinyl aromatic polymers with an improved thermal insulation capacity, process for their production and expanded articles obtained therefrom | |
| HK1149940B (en) | Compositions of expandable vinyl aromatic polymers with an improved thermal insulation capacity, process for their preparation and expanded articles obtained therefrom | |
| HK1166814B (en) | Thermo-insulating expanded articles and compositions for the preparation thereof | |
| HK1166814A (en) | Thermo-insulating expanded articles and compositions for the preparation thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20121213 |
|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20121213 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20131218 |
|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20131218 |
|
| A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20140318 |
|
| A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20140326 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20140618 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20141126 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20141226 |
|
| R150 | Certificate of patent or registration of utility model |
Ref document number: 5677311 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| LAPS | Cancellation because of no payment of annual fees |