JP5661647B2 - 純粋なシクロドデカノンの製法 - Google Patents
純粋なシクロドデカノンの製法 Download PDFInfo
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- JP5661647B2 JP5661647B2 JP2011546824A JP2011546824A JP5661647B2 JP 5661647 B2 JP5661647 B2 JP 5661647B2 JP 2011546824 A JP2011546824 A JP 2011546824A JP 2011546824 A JP2011546824 A JP 2011546824A JP 5661647 B2 JP5661647 B2 JP 5661647B2
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- 238000004519 manufacturing process Methods 0.000 title claims description 9
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- 150000001923 cyclic compounds Chemical class 0.000 claims description 93
- 238000004821 distillation Methods 0.000 claims description 86
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- 125000003172 aldehyde group Chemical group 0.000 claims description 46
- 239000002253 acid Substances 0.000 claims description 44
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- 229910052723 transition metal Inorganic materials 0.000 claims description 27
- 150000003624 transition metals Chemical class 0.000 claims description 27
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- 239000001257 hydrogen Substances 0.000 description 8
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- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 8
- 239000011541 reaction mixture Substances 0.000 description 8
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- 239000002815 homogeneous catalyst Substances 0.000 description 7
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- 230000002829 reductive effect Effects 0.000 description 7
- 229910052707 ruthenium Inorganic materials 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 125000004429 atom Chemical group 0.000 description 6
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 6
- 239000003085 diluting agent Substances 0.000 description 6
- 239000000543 intermediate Substances 0.000 description 6
- 150000002739 metals Chemical class 0.000 description 6
- 229910052759 nickel Inorganic materials 0.000 description 6
- 238000012856 packing Methods 0.000 description 6
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- AYEKOFBPNLCAJY-UHFFFAOYSA-O thiamine pyrophosphate Chemical compound CC1=C(CCOP(O)(=O)OP(O)(O)=O)SC=[N+]1CC1=CN=C(C)N=C1N AYEKOFBPNLCAJY-UHFFFAOYSA-O 0.000 description 6
- 229910001928 zirconium oxide Inorganic materials 0.000 description 6
- DYLIWHYUXAJDOJ-OWOJBTEDSA-N (e)-4-(6-aminopurin-9-yl)but-2-en-1-ol Chemical compound NC1=NC=NC2=C1N=CN2C\C=C\CO DYLIWHYUXAJDOJ-OWOJBTEDSA-N 0.000 description 5
- 239000007868 Raney catalyst Substances 0.000 description 5
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- 239000003921 oil Substances 0.000 description 5
- 229910052763 palladium Inorganic materials 0.000 description 5
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Substances [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 5
- 238000001556 precipitation Methods 0.000 description 5
- 229920006395 saturated elastomer Polymers 0.000 description 5
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- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 4
- 150000001298 alcohols Chemical class 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 4
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- 125000004122 cyclic group Chemical group 0.000 description 4
- TVIDDXQYHWJXFK-UHFFFAOYSA-N dodecanedioic acid Chemical compound OC(=O)CCCCCCCCCCC(O)=O TVIDDXQYHWJXFK-UHFFFAOYSA-N 0.000 description 4
- 229910052742 iron Inorganic materials 0.000 description 4
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- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
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- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/78—Separation; Purification; Stabilisation; Use of additives
- C07C45/81—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
- C07C45/82—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation by distillation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/28—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of CHx-moieties
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
- C07C45/62—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by hydrogenation of carbon-to-carbon double or triple bonds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/18—Systems containing only non-condensed rings with a ring being at least seven-membered
- C07C2601/20—Systems containing only non-condensed rings with a ring being at least seven-membered the ring being twelve-membered
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Crystallography & Structural Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
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| EP09151525 | 2009-01-28 | ||
| EP09151525.4 | 2009-01-28 | ||
| PCT/EP2010/050888 WO2010086314A1 (de) | 2009-01-28 | 2010-01-27 | Verfahren zur herstellung von reinem cyclododecanon |
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| JP2012516301A JP2012516301A (ja) | 2012-07-19 |
| JP2012516301A5 JP2012516301A5 (enExample) | 2014-10-30 |
| JP5661647B2 true JP5661647B2 (ja) | 2015-01-28 |
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| ES (1) | ES2698849T3 (enExample) |
| WO (1) | WO2010086314A1 (enExample) |
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| US8188320B2 (en) | 2009-01-28 | 2012-05-29 | Basf Se | Process for preparing pure cyclododecanone |
| DE102009047196A1 (de) | 2009-11-26 | 2011-06-01 | Basf Se | Verfahren zur Herstellung von 1,6-Hexandiol |
| CN103864657A (zh) * | 2010-03-15 | 2014-06-18 | 宇部兴产株式会社 | 制备酰胺化合物的方法 |
| US9394212B2 (en) | 2010-06-15 | 2016-07-19 | Basf Se | Process for the cooligomerization of olefins |
| MX356142B (es) * | 2012-06-13 | 2018-05-16 | Basf Se | Metodo para producir cetonas macrociclicas. |
| DE102014212602A1 (de) | 2013-07-02 | 2015-01-08 | Basf Se | Verfahren zur Herstellung eines Ketons aus einem Olefin |
| EP2980069A1 (de) * | 2014-08-01 | 2016-02-03 | Evonik Degussa GmbH | Verfahren zur Herstellung von Cyclododecanon |
| EP3002003A1 (de) * | 2014-09-30 | 2016-04-06 | Basf Se | Verwendung neuartiger cyclischer Carbaldehyde als Aromastoff |
| EP3002058A1 (de) * | 2014-10-02 | 2016-04-06 | Evonik Degussa GmbH | Katalysatorsystem zur Herstellung von Ketonen aus Epoxiden |
| EP3206756B1 (de) | 2014-10-14 | 2018-09-19 | Basf Se | Verwendung von hexadeca-8,15-dienal als aromachemikalie |
| EP3050869B1 (de) * | 2015-01-30 | 2019-10-02 | Symrise AG | Verfahren zur Herstellung von substituierten Alkylcycloalkanonen |
| EP3153493A1 (de) * | 2015-10-08 | 2017-04-12 | Basf Se | Verfahren zur reinigung von cyclohexadec-8-en-1-on |
| CN108137460A (zh) * | 2015-10-08 | 2018-06-08 | 巴斯夫欧洲公司 | (e/z)-环十五碳烯酮异构体的新型混合物的用途、其制备和作为增香剂物质的用途 |
| MX2021011092A (es) * | 2019-03-15 | 2021-10-26 | Basf Se | Uso de 4,8,11-dodecatrienal para impartir una impresion de aroma limpio a una composicion. |
| CN114874085B (zh) * | 2022-07-12 | 2022-10-11 | 中国天辰工程有限公司 | 一种环十二酮提纯工艺 |
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| US316917A (en) | 1885-04-28 | Cord-spool and tension device for grain-binders | ||
| US2875256A (en) * | 1953-01-21 | 1959-02-24 | Shell Dev | Dienic hydrocarbons and derivatives thereof |
| DE1283836B (de) | 1959-12-22 | 1968-11-28 | Studiengesellschaft Kohle Mbh | Verfahren zur Herstellung von hauptsaechlich Cyclododekatrien-(1,5,9) enthaltenden Produkten durch Cyclooligomerisation von 1, 3-Diolefinen |
| US3182093A (en) | 1961-10-02 | 1965-05-04 | Exxon Research Engineering Co | Preparation of 1, 5-cyclododecadiene |
| BE646244A (enExample) | 1963-04-10 | 1900-01-01 | ||
| US3804914A (en) * | 1972-05-25 | 1974-04-16 | Phillips Petroleum Co | Ruthenium(ii)complexes as catalysts for selective hydrogenation of cyclic polyenes to cyclic monoenes |
| DD115480A2 (enExample) | 1974-08-19 | 1975-10-05 | ||
| DE2519817A1 (de) | 1975-05-03 | 1976-11-11 | Hoechst Ag | Verfahren zur herstellung von butandiol-(1.4) |
| EP0158229B1 (en) | 1984-03-28 | 1988-06-22 | Asahi Kasei Kogyo Kabushiki Kaisha | Process for producing polyether polyol, the produced polyether polyol and polyurethane |
| MX171769B (es) | 1987-02-16 | 1993-11-15 | Sumitomo Chemical Co | Base catalitica solida y procedimiento para obtenerla |
| GB8707595D0 (en) | 1987-03-31 | 1987-05-07 | British Petroleum Co Plc | Chemical process |
| US5210349A (en) * | 1991-07-01 | 1993-05-11 | Phillips Petroleum Company | Selective hydrogenation of cyclic polyenes |
| US5128296A (en) | 1991-07-01 | 1992-07-07 | Phillips Petroleum Company | Selective hydrogenation of cyclic polyenes |
| US5177278A (en) * | 1991-10-23 | 1993-01-05 | E. I. Du Pont De Nemours And Company | Preparation of cyclododecene |
| US5180870A (en) | 1991-10-23 | 1993-01-19 | E. I. Du Pont De Nemours And Company | Hydrogenation of polyenes |
| US5321176A (en) * | 1992-12-22 | 1994-06-14 | E. I. Du Pont De Nemours And Company | Hydrogenation of polyenes |
| DE19510993C1 (de) | 1995-03-24 | 1996-08-29 | Fhw Brenntechnik Gmbh | Vorrichtung zur thermischen Abgasbehandlung, insbesondere von oxidierbaren Schwelgasen |
| AU5137598A (en) | 1996-12-05 | 1998-06-29 | Kyowa Hakko Kogyo Co. Ltd. | Novel protein |
| DE10142033A1 (de) | 2001-08-28 | 2003-03-20 | Haarmann & Reimer Gmbh | Metathesekatalysatoren |
| DE10344595A1 (de) | 2003-09-25 | 2005-05-12 | Basf Ag | Verfahren zur Herstellung eines Ketons |
| DE102004046167A1 (de) | 2004-09-23 | 2006-04-06 | Basf Ag | Verfahren zur Reinigung und Aufkonzentrierung von Distickstoffmonoxid |
| DE102005048250A1 (de) * | 2005-10-07 | 2007-04-12 | Basf Ag | Verfahren zur Farbzahlverbesserung |
| DE102005055588A1 (de) | 2005-11-22 | 2007-05-24 | Basf Ag | Verfahren zur Isolierung von N2O |
| WO2007104650A1 (de) | 2006-03-10 | 2007-09-20 | Basf Se | Verfahren zur herstellung von benzophenoniminen |
| ES2337101T3 (es) | 2006-06-29 | 2010-04-20 | Basf Se | Procedimiento para la obtencion de cetonas ciclicas. |
| JP5108880B2 (ja) * | 2006-06-29 | 2012-12-26 | ビーエーエスエフ ソシエタス・ヨーロピア | 環状ケトンの製造方法 |
| EP2041061B1 (de) | 2006-06-29 | 2013-05-08 | Basf Se | Reinigung von Cyclododecanon durch thermisches Behandeln |
| CN101558009B (zh) | 2006-12-11 | 2012-03-28 | 巴斯夫欧洲公司 | 分离n2o的方法 |
| JP5733979B2 (ja) * | 2007-08-21 | 2015-06-10 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | 有機化合物を酸化するための方法および装置 |
| WO2009024549A2 (de) * | 2007-08-21 | 2009-02-26 | Basf Se | Verfahren und vorrichtung zur oxidation organischer verbindungen |
| EP2225220B1 (de) * | 2007-12-21 | 2013-05-22 | Basf Se | Verfahren zur Herstellung von epsilon-Caprolacton |
| WO2009092682A2 (de) | 2008-01-25 | 2009-07-30 | Basf Se | Verfahren und vorrichtung zur destillativen aufarbeitung von 1,5,9-cyclododecatrien und gewinnung von cdt mit hoher reinheit |
| WO2009092683A2 (de) | 2008-01-25 | 2009-07-30 | Basf Se | METHODE ZUR SELEKTIVEN GROßTECHNISCHEN HERSTELLUNG VON 1,5,9 CYCLODODECATRIEN |
| US8404901B2 (en) | 2008-04-02 | 2013-03-26 | Basf Se | Process for purifying dinitrogen monoxide |
| EP2271584B1 (de) | 2008-04-02 | 2013-05-15 | Basf Se | Verfahren zur reinigung von n2o |
| JP5579183B2 (ja) * | 2008-08-29 | 2014-08-27 | ビーエーエスエフ ソシエタス・ヨーロピア | 環式ケトンの製造方法 |
| WO2010076182A1 (de) * | 2008-12-30 | 2010-07-08 | Basf Se | Verfahren zur herstellung von ketonen durch umsetzung von 1,1-disubstituierten olefinen mit n2o |
| CN102361687B (zh) | 2009-01-21 | 2015-05-13 | 巴斯夫欧洲公司 | 用于非催化或均相催化反应的管束反应器 |
| JP5698152B2 (ja) * | 2009-01-28 | 2015-04-08 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | ドデカトリエナールの単離法、及びその香料としての使用 |
| US8188320B2 (en) | 2009-01-28 | 2012-05-29 | Basf Se | Process for preparing pure cyclododecanone |
-
2010
- 2010-01-27 US US12/694,815 patent/US8188320B2/en not_active Expired - Fee Related
- 2010-01-27 KR KR1020117019844A patent/KR20110110359A/ko not_active Abandoned
- 2010-01-27 JP JP2011546824A patent/JP5661647B2/ja not_active Expired - Fee Related
- 2010-01-27 EP EP10701244.5A patent/EP2391597B1/de active Active
- 2010-01-27 ES ES10701244T patent/ES2698849T3/es active Active
- 2010-01-27 CN CN2010800147909A patent/CN102365256A/zh active Pending
- 2010-01-27 WO PCT/EP2010/050888 patent/WO2010086314A1/de not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| US8188320B2 (en) | 2012-05-29 |
| CN102365256A (zh) | 2012-02-29 |
| KR20110110359A (ko) | 2011-10-06 |
| EP2391597A1 (de) | 2011-12-07 |
| WO2010086314A1 (de) | 2010-08-05 |
| EP2391597B1 (de) | 2018-08-22 |
| JP2012516301A (ja) | 2012-07-19 |
| US20100191018A1 (en) | 2010-07-29 |
| ES2698849T3 (es) | 2019-02-06 |
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