JP5653430B2 - ケイ質ベースのポリウレア組成物 - Google Patents
ケイ質ベースのポリウレア組成物 Download PDFInfo
- Publication number
- JP5653430B2 JP5653430B2 JP2012522072A JP2012522072A JP5653430B2 JP 5653430 B2 JP5653430 B2 JP 5653430B2 JP 2012522072 A JP2012522072 A JP 2012522072A JP 2012522072 A JP2012522072 A JP 2012522072A JP 5653430 B2 JP5653430 B2 JP 5653430B2
- Authority
- JP
- Japan
- Prior art keywords
- polyisocyanate
- weight
- composition
- polyol
- composition according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000203 mixture Substances 0.000 title claims description 30
- 229920002396 Polyurea Polymers 0.000 title claims description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 title description 33
- 239000000377 silicon dioxide Substances 0.000 title description 12
- 239000005056 polyisocyanate Substances 0.000 claims description 37
- 229920001228 polyisocyanate Polymers 0.000 claims description 37
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 18
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 16
- 238000006243 chemical reaction Methods 0.000 claims description 15
- RLQWHDODQVOVKU-UHFFFAOYSA-N tetrapotassium;silicate Chemical compound [K+].[K+].[K+].[K+].[O-][Si]([O-])([O-])[O-] RLQWHDODQVOVKU-UHFFFAOYSA-N 0.000 claims description 15
- 229910000323 aluminium silicate Inorganic materials 0.000 claims description 14
- 229920005862 polyol Polymers 0.000 claims description 14
- 150000003077 polyols Chemical class 0.000 claims description 14
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 11
- 239000000945 filler Substances 0.000 claims description 11
- 239000000654 additive Substances 0.000 claims description 10
- 239000012948 isocyanate Substances 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 8
- -1 aliphatic isocyanate Chemical class 0.000 claims description 7
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 6
- 229910052910 alkali metal silicate Inorganic materials 0.000 claims description 6
- 239000003054 catalyst Substances 0.000 claims description 6
- 239000011574 phosphorus Substances 0.000 claims description 6
- 229910052698 phosphorus Inorganic materials 0.000 claims description 6
- 239000007787 solid Substances 0.000 claims description 6
- 150000002513 isocyanates Chemical class 0.000 claims description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 4
- 238000010276 construction Methods 0.000 claims description 4
- 239000006260 foam Substances 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- 230000008569 process Effects 0.000 claims description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 3
- 125000001931 aliphatic group Chemical group 0.000 claims description 3
- 230000004888 barrier function Effects 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 2
- 230000000996 additive effect Effects 0.000 claims description 2
- 125000003118 aryl group Chemical group 0.000 claims description 2
- 150000001768 cations Chemical class 0.000 claims description 2
- 229910052744 lithium Inorganic materials 0.000 claims description 2
- 150000004760 silicates Chemical class 0.000 claims description 2
- 239000004088 foaming agent Substances 0.000 claims 1
- 239000003381 stabilizer Substances 0.000 claims 1
- 239000000463 material Substances 0.000 description 24
- 238000003860 storage Methods 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 9
- 229920006329 Styropor Polymers 0.000 description 8
- 239000004576 sand Substances 0.000 description 8
- 235000012239 silicon dioxide Nutrition 0.000 description 7
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 6
- 229960004029 silicic acid Drugs 0.000 description 6
- 239000004604 Blowing Agent Substances 0.000 description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
- 230000006835 compression Effects 0.000 description 5
- 238000007906 compression Methods 0.000 description 5
- 239000012071 phase Substances 0.000 description 5
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 238000005259 measurement Methods 0.000 description 4
- 230000004044 response Effects 0.000 description 4
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 102220520989 Serine/threonine-protein phosphatase 2A regulatory subunit B'' subunit alpha_K42T_mutation Human genes 0.000 description 3
- 238000005452 bending Methods 0.000 description 3
- 239000001569 carbon dioxide Substances 0.000 description 3
- 229910002092 carbon dioxide Inorganic materials 0.000 description 3
- 239000004568 cement Substances 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 239000003995 emulsifying agent Substances 0.000 description 3
- 239000003063 flame retardant Substances 0.000 description 3
- 238000007706 flame test Methods 0.000 description 3
- 239000004872 foam stabilizing agent Substances 0.000 description 3
- 238000009413 insulation Methods 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 3
- 239000010457 zeolite Substances 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 2
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- 229910021536 Zeolite Inorganic materials 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229910001919 chlorite Inorganic materials 0.000 description 2
- 229910052619 chlorite group Inorganic materials 0.000 description 2
- QBWCMBCROVPCKQ-UHFFFAOYSA-N chlorous acid Chemical compound OCl=O QBWCMBCROVPCKQ-UHFFFAOYSA-N 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- GHLKSLMMWAKNBM-UHFFFAOYSA-N dodecane-1,12-diol Chemical compound OCCCCCCCCCCCCO GHLKSLMMWAKNBM-UHFFFAOYSA-N 0.000 description 2
- 239000006261 foam material Substances 0.000 description 2
- 239000010440 gypsum Substances 0.000 description 2
- 229910052602 gypsum Inorganic materials 0.000 description 2
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 2
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 2
- 229910052622 kaolinite Inorganic materials 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 235000010755 mineral Nutrition 0.000 description 2
- ZBJVLWIYKOAYQH-UHFFFAOYSA-N naphthalen-2-yl 2-hydroxybenzoate Chemical compound OC1=CC=CC=C1C(=O)OC1=CC=C(C=CC=C2)C2=C1 ZBJVLWIYKOAYQH-UHFFFAOYSA-N 0.000 description 2
- 229910052628 phlogopite Inorganic materials 0.000 description 2
- 229920001451 polypropylene glycol Polymers 0.000 description 2
- 235000019353 potassium silicate Nutrition 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- YPFDHNVEDLHUCE-UHFFFAOYSA-N propane-1,3-diol Chemical compound OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- RUELTTOHQODFPA-UHFFFAOYSA-N toluene 2,6-diisocyanate Chemical compound CC1=C(N=C=O)C=CC=C1N=C=O RUELTTOHQODFPA-UHFFFAOYSA-N 0.000 description 2
- 239000000080 wetting agent Substances 0.000 description 2
- GFNDFCFPJQPVQL-UHFFFAOYSA-N 1,12-diisocyanatododecane Chemical compound O=C=NCCCCCCCCCCCCN=C=O GFNDFCFPJQPVQL-UHFFFAOYSA-N 0.000 description 1
- ARXKVVRQIIOZGF-UHFFFAOYSA-N 1,2,4-butanetriol Substances OCCC(O)CO ARXKVVRQIIOZGF-UHFFFAOYSA-N 0.000 description 1
- ZWVMLYRJXORSEP-UHFFFAOYSA-N 1,2,6-Hexanetriol Chemical compound OCCCCC(O)CO ZWVMLYRJXORSEP-UHFFFAOYSA-N 0.000 description 1
- FKTHNVSLHLHISI-UHFFFAOYSA-N 1,2-bis(isocyanatomethyl)benzene Chemical compound O=C=NCC1=CC=CC=C1CN=C=O FKTHNVSLHLHISI-UHFFFAOYSA-N 0.000 description 1
- 239000005059 1,4-Cyclohexyldiisocyanate Substances 0.000 description 1
- ALQLPWJFHRMHIU-UHFFFAOYSA-N 1,4-diisocyanatobenzene Chemical compound O=C=NC1=CC=C(N=C=O)C=C1 ALQLPWJFHRMHIU-UHFFFAOYSA-N 0.000 description 1
- OVBFMUAFNIIQAL-UHFFFAOYSA-N 1,4-diisocyanatobutane Chemical compound O=C=NCCCCN=C=O OVBFMUAFNIIQAL-UHFFFAOYSA-N 0.000 description 1
- CDMDQYCEEKCBGR-UHFFFAOYSA-N 1,4-diisocyanatocyclohexane Chemical compound O=C=NC1CCC(N=C=O)CC1 CDMDQYCEEKCBGR-UHFFFAOYSA-N 0.000 description 1
- 229940043375 1,5-pentanediol Drugs 0.000 description 1
- QWGRWMMWNDWRQN-UHFFFAOYSA-N 2-methylpropane-1,3-diol Chemical compound OCC(C)CO QWGRWMMWNDWRQN-UHFFFAOYSA-N 0.000 description 1
- SXFJDZNJHVPHPH-UHFFFAOYSA-N 3-methylpentane-1,5-diol Chemical compound OCCC(C)CCO SXFJDZNJHVPHPH-UHFFFAOYSA-N 0.000 description 1
- JRQLZCFSWYQHPI-UHFFFAOYSA-N 4,5-dichloro-2-cyclohexyl-1,2-thiazol-3-one Chemical compound O=C1C(Cl)=C(Cl)SN1C1CCCCC1 JRQLZCFSWYQHPI-UHFFFAOYSA-N 0.000 description 1
- 229910021532 Calcite Inorganic materials 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- 241001595840 Margarites Species 0.000 description 1
- ALQSHHUCVQOPAS-UHFFFAOYSA-N Pentane-1,5-diol Chemical compound OCCCCCO ALQSHHUCVQOPAS-UHFFFAOYSA-N 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical class OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 1
- UWHCKJMYHZGTIT-UHFFFAOYSA-N Tetraethylene glycol, Natural products OCCOCCOCCOCCO UWHCKJMYHZGTIT-UHFFFAOYSA-N 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- ORLQHILJRHBSAY-UHFFFAOYSA-N [1-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1(CO)CCCCC1 ORLQHILJRHBSAY-UHFFFAOYSA-N 0.000 description 1
- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 description 1
- WNLRTRBMVRJNCN-UHFFFAOYSA-L adipate(2-) Chemical compound [O-]C(=O)CCCCC([O-])=O WNLRTRBMVRJNCN-UHFFFAOYSA-L 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 229910001579 aluminosilicate mineral Inorganic materials 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 230000000712 assembly Effects 0.000 description 1
- 238000000429 assembly Methods 0.000 description 1
- 239000010427 ball clay Substances 0.000 description 1
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- WEKDMIUZCXIQDG-UHFFFAOYSA-N benzylbenzene;isocyanic acid Chemical class N=C=O.C=1C=CC=CC=1CC1=CC=CC=C1 WEKDMIUZCXIQDG-UHFFFAOYSA-N 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 229910052626 biotite Inorganic materials 0.000 description 1
- OHJMTUPIZMNBFR-UHFFFAOYSA-N biuret Chemical group NC(=O)NC(N)=O OHJMTUPIZMNBFR-UHFFFAOYSA-N 0.000 description 1
- OWBTYPJTUOEWEK-UHFFFAOYSA-N butane-2,3-diol Chemical compound CC(O)C(C)O OWBTYPJTUOEWEK-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- 235000012255 calcium oxide Nutrition 0.000 description 1
- VPKDCDLSJZCGKE-UHFFFAOYSA-N carbodiimide group Chemical group N=C=N VPKDCDLSJZCGKE-UHFFFAOYSA-N 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-N carbonic acid monoamide Natural products NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- KYKAJFCTULSVSH-UHFFFAOYSA-N chloro(fluoro)methane Chemical compound F[C]Cl KYKAJFCTULSVSH-UHFFFAOYSA-N 0.000 description 1
- 229910052620 chrysotile Inorganic materials 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000006482 condensation reaction Methods 0.000 description 1
- 238000013270 controlled release Methods 0.000 description 1
- VKONPUDBRVKQLM-UHFFFAOYSA-N cyclohexane-1,4-diol Chemical compound OC1CCC(O)CC1 VKONPUDBRVKQLM-UHFFFAOYSA-N 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- 238000005906 dihydroxylation reaction Methods 0.000 description 1
- 125000005442 diisocyanate group Chemical group 0.000 description 1
- LRCFXGAMWKDGLA-UHFFFAOYSA-N dioxosilane;hydrate Chemical compound O.O=[Si]=O LRCFXGAMWKDGLA-UHFFFAOYSA-N 0.000 description 1
- YGANSGVIUGARFR-UHFFFAOYSA-N dipotassium dioxosilane oxo(oxoalumanyloxy)alumane oxygen(2-) Chemical compound [O--].[K+].[K+].O=[Si]=O.O=[Al]O[Al]=O YGANSGVIUGARFR-UHFFFAOYSA-N 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 239000010459 dolomite Substances 0.000 description 1
- 229910000514 dolomite Inorganic materials 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000010881 fly ash Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 229910052900 illite Inorganic materials 0.000 description 1
- 125000005462 imide group Chemical group 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 239000012774 insulation material Substances 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- XJRAOMZCVTUHFI-UHFFFAOYSA-N isocyanic acid;methane Chemical compound C.N=C=O.N=C=O XJRAOMZCVTUHFI-UHFFFAOYSA-N 0.000 description 1
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical group OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 1
- 239000003562 lightweight material Substances 0.000 description 1
- 229910052899 lizardite Inorganic materials 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 229910052630 margarite Inorganic materials 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- 229910052627 muscovite Inorganic materials 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- VGIBGUSAECPPNB-UHFFFAOYSA-L nonaaluminum;magnesium;tripotassium;1,3-dioxido-2,4,5-trioxa-1,3-disilabicyclo[1.1.1]pentane;iron(2+);oxygen(2-);fluoride;hydroxide Chemical compound [OH-].[O-2].[O-2].[O-2].[O-2].[O-2].[F-].[Mg+2].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[K+].[K+].[K+].[Fe+2].O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2 VGIBGUSAECPPNB-UHFFFAOYSA-L 0.000 description 1
- 239000007764 o/w emulsion Substances 0.000 description 1
- OEIJHBUUFURJLI-UHFFFAOYSA-N octane-1,8-diol Chemical compound OCCCCCCCCO OEIJHBUUFURJLI-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 229910052625 palygorskite Inorganic materials 0.000 description 1
- 239000011236 particulate material Substances 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- JLFNLZLINWHATN-UHFFFAOYSA-N pentaethylene glycol Chemical compound OCCOCCOCCOCCOCCO JLFNLZLINWHATN-UHFFFAOYSA-N 0.000 description 1
- 239000010451 perlite Substances 0.000 description 1
- 235000019362 perlite Nutrition 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920001610 polycaprolactone Polymers 0.000 description 1
- 239000004632 polycaprolactone Substances 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920005906 polyester polyol Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 239000008262 pumice Substances 0.000 description 1
- 229910052903 pyrophyllite Inorganic materials 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 239000003566 sealing material Substances 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 229960001866 silicon dioxide Drugs 0.000 description 1
- 229910021647 smectite Inorganic materials 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- KJAMZCVTJDTESW-UHFFFAOYSA-N tiracizine Chemical compound C1CC2=CC=CC=C2N(C(=O)CN(C)C)C2=CC(NC(=O)OCC)=CC=C21 KJAMZCVTJDTESW-UHFFFAOYSA-N 0.000 description 1
- 230000002110 toxicologic effect Effects 0.000 description 1
- 231100000027 toxicology Toxicity 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- IBPRKWGSNXMCOI-UHFFFAOYSA-N trimagnesium;disilicate;hydrate Chemical compound O.[Mg+2].[Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IBPRKWGSNXMCOI-UHFFFAOYSA-N 0.000 description 1
- CWBIFDGMOSWLRQ-UHFFFAOYSA-N trimagnesium;hydroxy(trioxido)silane;hydrate Chemical compound O.[Mg+2].[Mg+2].[Mg+2].O[Si]([O-])([O-])[O-].O[Si]([O-])([O-])[O-] CWBIFDGMOSWLRQ-UHFFFAOYSA-N 0.000 description 1
- 229940113165 trimethylolpropane Drugs 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N urea group Chemical group NC(=O)N XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- AVWRKZWQTYIKIY-UHFFFAOYSA-N urea-1-carboxylic acid Chemical group NC(=O)NC(O)=O AVWRKZWQTYIKIY-UHFFFAOYSA-N 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N urethane group Chemical group NC(=O)OCC JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 229910052902 vermiculite Inorganic materials 0.000 description 1
- 239000010455 vermiculite Substances 0.000 description 1
- 235000019354 vermiculite Nutrition 0.000 description 1
- 239000010456 wollastonite Substances 0.000 description 1
- 229910052882 wollastonite Inorganic materials 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/24—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing alkyl, ammonium or metal silicates; containing silica sols
- C04B28/26—Silicates of the alkali metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4825—Polyethers containing two hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/28—Fire resistance, i.e. materials resistant to accidental fires or high temperatures
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0041—Foam properties having specified density
- C08G2110/0066—≥ 150kg/m3
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Ceramic Engineering (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Polyurethanes Or Polyureas (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Description
10〜80質量%のポリイソシアネート、
2〜80質量%の水性ケイ酸塩、
2〜90質量%の水和性アルミノケイ酸塩、
0〜90質量%の不活性充填剤。
20〜65質量%のポリイソシアネート、
5〜55質量%の水性ケイ酸塩、
5〜20質量%の水和性アルミノケイ酸塩、
0〜40質量%のポリオール、
0〜40質量%の不活性充填剤。
材料を試験するための機械のセットアップはDIN196−1によるものであった。Lupranat(登録商標) MI(4,4’−ジフェニルメタンジイソシアネート)はElastogran GmbHから入手され、Desmophen(登録商標)3600z(プロピレングリコール)はBayer AGから入手され、Argical M 1000(メタカオリン)はAGS Minerauxから入手され、珪砂(0.06mm〜0.3mm)はCarlo Bernasconi AGから入手され、カリウム水ガラスK−45M(ケイ酸率 1.0、固体含有率 40.5質量%)およびBetol(登録商標)K42T(ケイ酸率 2.9、固体含有率 40.0質量%)はWoellner GmbHから入手され、ナトリウム水ガラスlnocot Na−4830(ケイ酸率 2.9、固体含有率 44.9質量%)およびカリウム水ガラスlnobond K−4250(ケイ酸率 3.2、固体含有率 41.3質量%)は、van Baerle GmbHから得られた。
プレポリマー1は、1000gの市販グレードの4,4’−ジフェニルメタンジイソシアネート(Lupranat(登録商標)MI)と、56.0mg/g KOHのOH値を有する863gの市販グレードのポリプロピレングリコール(Desmophen(登録商標) 3600 z)とを反応させることによって得られた。得られたプレポリマー1は、15.6質量%の−NCO含有率、および24℃で709mPa・sの粘度を有した。
A成分: メタカオリン、Argical M 1000 24.0g
珪砂 55.2g
カリウム水ガラス、K−45M 28.0g
B成分: プレポリマー1 133.91g
C成分: ナトリウム水ガラス、lnocot Na−4830 86.88g。
A成分: メタカオリン、Argical M 1000 4.19g
珪砂 4.41g
カリウム水ガラス、lnobond K−4250 9.65g
B成分: プレポリマー1 209.24g
C成分: カリウム水ガラス、lnobond K−4250 132.19g。
A成分: メタカオリン、Argical M 1000 16.78g
珪砂 38.59g
カリウム水ガラス、lnobond K−4250 19.63g
B成分: プレポリマー1 167.39g
C成分: カリウム水ガラス、lnobond K−4250 105.75g。
A成分: メタカオリン、Argical M 1000 13.43g
珪砂 30.87g
カリウム水ガラス、lnobond K−4250 15.70g
B成分: プレポリマー1 133.92g
C成分: カリウム水ガラス、lnobond K−4250 169.20g。
A成分: メタカオリン、Argical M 1000 46.98g
珪砂 108.05g
カリウム水ガラス、K−45M 54.97g
B成分: プレポリマー1 156.23g。
A成分: メタカオリン、Argical M 1000 44.74g
珪砂 102.91g
カリウム水ガラス、Betol K42T 52.35g
B成分: プレポリマー1 111.60g。
A成分: メタカオリン、Argical M 1000 40.27g
珪砂 92.62g
カリウム水ガラス、Betol K42T 47.11g
B成分: プレポリマー1 133.92g。
A成分: メタカオリン、Argical M 1000 35.85g
カリウム水ガラス、K−45 M 11.30g
B成分: プレポリマー1 45.40g。
Claims (11)
- a) ポリイソシアネート、
b) 水性ケイ酸塩、
c) 水和性のアルミノケイ酸塩としてのメタカオリン
を含む成分を反応させることによって得られる、ケイ質ベースのポリウレア組成物。 - 反応成分がさらに
d) ポリオール、および/または
e) 不活性充填剤
を含む、請求項1に記載の組成物。 - 反応成分が、
20〜65質量%のポリイソシアネート、
5〜55質量%の水性ケイ酸塩、
2〜20質量%の水和性のアルミノケイ酸塩、
0〜40質量%のポリオール、
0〜40質量%の不活性充填剤
を含む、請求項1に記載の組成物。 - ポリイソシアネートが、脂肪族のイソシアネート、芳香族のイソシアネート、または脂肪族/芳香族混合のイソシアネートであって、≧2の−NCO官能価を有する、請求項1から3までのいずれか1項に記載の組成物。
- 水性ケイ酸塩が、アルカリケイ酸塩またはアンモニウムケイ酸塩、好ましくはアンモニウム、リチウム、ナトリウムまたはカリウム水ガラスであって、そのSiO2:M2O(前記Mは一価のカチオンを表す)のモル比によって定義される率4.0〜0.2、好ましくは4.0〜1.0を有し、且つ、固体含有率10〜70質量%、好ましくは30〜55質量%を有する、請求項1から4までのいずれか1項に記載の組成物。
- ポリオールが、≧2の−OH官能価を有する多官能価のアルコールである、請求項1から5までのいずれか1項に記載の組成物。
- 少なくとも一部のポリイソシアネートおよびポリオールが、まず反応して≧2の−NCO官能価を有するポリイソシアネートプレポリマーを形成する、請求項1から6までのいずれか1項に記載の組成物。
- ハロゲン化および/またはリン含有添加剤が、反応成分に含まれていない、請求項1から7までのいずれか1項に記載の組成物。
- 泡安定剤、触媒および/または発泡剤が、反応成分に含まれていない、請求項1から8までのいずれか1項に記載の組成物。
- 請求項1から9までのいずれか1項において定義された組成物の製造方法であって、水和性のアルミノケイ酸塩としてのメタカオリンと水性ケイ酸塩とを混合する段階、および、この混合物を随意にポリオールの存在中および/または不活性充填剤を包含して、ポリイソシアネートおよび/またはポリイソシアネートプレポリマーと反応させる段階を含む、前記製造方法。
- 航空、自動車組み立て部品、建築、消費者製品、防火、家具部品、遮断、造船および/または風車建築の分野における、請求項1から9までのいずれか1項において定義された組成物の使用。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP09166854.1 | 2009-07-30 | ||
EP09166854 | 2009-07-30 | ||
PCT/EP2010/059733 WO2011012415A1 (en) | 2009-07-30 | 2010-07-07 | Siliceous-based polyurea compositions |
Publications (3)
Publication Number | Publication Date |
---|---|
JP2013500364A JP2013500364A (ja) | 2013-01-07 |
JP2013500364A5 JP2013500364A5 (ja) | 2013-08-22 |
JP5653430B2 true JP5653430B2 (ja) | 2015-01-14 |
Family
ID=42558196
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2012522072A Active JP5653430B2 (ja) | 2009-07-30 | 2010-07-07 | ケイ質ベースのポリウレア組成物 |
Country Status (11)
Country | Link |
---|---|
US (1) | US8785539B2 (ja) |
EP (1) | EP2459496B1 (ja) |
JP (1) | JP5653430B2 (ja) |
CN (1) | CN102548929B (ja) |
AU (1) | AU2010278150B2 (ja) |
BR (1) | BR112012002056B1 (ja) |
CA (1) | CA2769256C (ja) |
ES (1) | ES2508292T3 (ja) |
PL (1) | PL2459496T3 (ja) |
RU (1) | RU2547183C2 (ja) |
WO (1) | WO2011012415A1 (ja) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2746358A1 (en) * | 2012-12-21 | 2014-06-25 | Basf Se | Polyurea silicate resin for wellbore application |
CN109265645A (zh) * | 2016-07-12 | 2019-01-25 | 南京工业职业技术学院 | 一种汽车内饰用介孔改性聚氨酯树脂的制备方法 |
CN107053421B (zh) * | 2017-04-10 | 2020-06-02 | 温州企一家具有限公司 | 一种利用废料生产木地板的方法 |
CN109111726B (zh) * | 2017-06-22 | 2021-07-09 | 国家能源投资集团有限责任公司 | 复合材料及其制备方法 |
CN107619463A (zh) * | 2017-09-06 | 2018-01-23 | 台州市利仕达新材料科技有限公司 | 一种汽车内饰海绵 |
WO2020030828A1 (en) * | 2018-08-10 | 2020-02-13 | Heka Graphit.Technology Gmbh | Construction panel |
CN112143470B (zh) * | 2019-06-28 | 2023-02-03 | 中国石油化工股份有限公司 | 堵漏材料及其制备方法、堵漏剂 |
CN111690108A (zh) * | 2020-06-08 | 2020-09-22 | 合肥工业大学 | 一种涂抹在水位变幅带内红砂岩表面改性聚氨酯材料及其制备方法 |
FR3123679B1 (fr) * | 2021-06-07 | 2023-05-12 | Weber Mining & Tunnelling | Ensemble de préparation d’une composition injectable |
Family Cites Families (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1186771A (en) * | 1967-05-12 | 1970-04-02 | Conteki Dev Ltd | Silicious Products |
DE2310559C3 (de) | 1973-03-02 | 1975-09-11 | Bayer Ag, 5090 Leverkusen | Schaumbeton, ein Verfahren zu seiner Herstellung und seine Verwendung zur Herstellung von Bauelementen |
DE2227147C3 (de) | 1972-06-03 | 1979-10-18 | Bayer Ag, 5090 Leverkusen | Als kolloides Xerosol vorliegendes homogenes anorganisch-organisches Ionomer-Polykieselsäure-gel-Verbundmaterial |
DE2359610C3 (de) * | 1973-11-30 | 1981-09-17 | Bayer Ag, 5090 Leverkusen | Verfahren zur Herstellung flexibler, organisch-anorganischer Verbundkunststoffe mit niedrigem Heizwert und verbessertem Brandverhalten |
CA1029494A (en) | 1973-07-27 | 1978-04-11 | Fritz Ehrhard | Shaped polyurethane articles and a method for making them |
DE2359607C2 (de) | 1973-11-30 | 1982-12-09 | Bayer Ag, 5090 Leverkusen | Verfahren zur Herstellung eines anorganisch-organischen Verbundmaterials |
DE2512170C3 (de) | 1975-03-20 | 1981-06-11 | Bayer Ag, 5090 Leverkusen | Verfahren zur Herstellung von gegebenenfalls schaumförmigem, harten anorganisch-organischem Verbundmaterial |
GB1554857A (en) * | 1975-08-07 | 1979-10-31 | Ici Ltd | Quick setting silicious compositions |
DE2542279A1 (de) * | 1975-09-23 | 1977-04-28 | Joachim Dipl Chem Dr Steffens | Organo-mineralstoff-polymere und verfahren zu ihrer herstellung |
US5039711A (en) * | 1989-09-25 | 1991-08-13 | Blount David H | Production of flame-retardant polyol-oxidated silicon-acidic boron emulsion |
JPH1067839A (ja) * | 1996-08-28 | 1998-03-10 | Ig Tech Res Inc | アルカリ珪酸塩による変性ポリウレタン系発泡体及びその製造法 |
JP4108849B2 (ja) * | 1998-11-11 | 2008-06-25 | 三洋化成工業株式会社 | ポリウレタンフォームの製造方法 |
JP2004035378A (ja) * | 2002-07-08 | 2004-02-05 | Kawaguchi Makku Kogyo:Kk | 熱発泡性耐火材組成物 |
CN1948206A (zh) * | 2005-10-14 | 2007-04-18 | 建筑研究及技术有限责任公司 | 混凝土的加速混合物 |
RU2309922C2 (ru) * | 2005-11-21 | 2007-11-10 | ООО "Антикор" | Способ получения органосиликатной смеси |
CN100595246C (zh) * | 2007-06-28 | 2010-03-24 | 湖南湘江涂料集团有限公司 | 卡车车厢衬里用喷涂耐磨聚脲弹性体涂层及其施工方法 |
-
2010
- 2010-07-07 WO PCT/EP2010/059733 patent/WO2011012415A1/en active Application Filing
- 2010-07-07 ES ES10730784.5T patent/ES2508292T3/es active Active
- 2010-07-07 PL PL10730784T patent/PL2459496T3/pl unknown
- 2010-07-07 RU RU2012107221/03A patent/RU2547183C2/ru active
- 2010-07-07 AU AU2010278150A patent/AU2010278150B2/en active Active
- 2010-07-07 CA CA2769256A patent/CA2769256C/en active Active
- 2010-07-07 JP JP2012522072A patent/JP5653430B2/ja active Active
- 2010-07-07 BR BR112012002056A patent/BR112012002056B1/pt active IP Right Grant
- 2010-07-07 CN CN201080043685.8A patent/CN102548929B/zh active Active
- 2010-07-07 US US13/387,512 patent/US8785539B2/en active Active
- 2010-07-07 EP EP20100730784 patent/EP2459496B1/en active Active
Also Published As
Publication number | Publication date |
---|---|
US8785539B2 (en) | 2014-07-22 |
RU2547183C2 (ru) | 2015-04-10 |
US20120190792A1 (en) | 2012-07-26 |
CA2769256C (en) | 2017-02-28 |
AU2010278150B2 (en) | 2014-02-06 |
CN102548929A (zh) | 2012-07-04 |
WO2011012415A1 (en) | 2011-02-03 |
AU2010278150A1 (en) | 2012-03-01 |
JP2013500364A (ja) | 2013-01-07 |
PL2459496T3 (pl) | 2015-03-31 |
EP2459496A1 (en) | 2012-06-06 |
BR112012002056B1 (pt) | 2019-12-17 |
RU2012107221A (ru) | 2013-09-10 |
ES2508292T3 (es) | 2014-10-16 |
EP2459496B1 (en) | 2014-09-10 |
BR112012002056A2 (pt) | 2016-05-17 |
CA2769256A1 (en) | 2011-02-03 |
CN102548929B (zh) | 2015-07-08 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP5653430B2 (ja) | ケイ質ベースのポリウレア組成物 | |
CA1064200A (en) | Compositions based on polyisocyanates and alkali metals silicates | |
SU850009A3 (ru) | Способ получени пеноматериалов | |
FI58483B (fi) | Foerfarande foer framstaellning av skumaemne | |
US10017938B2 (en) | Concrete element comprising a sound-absorber | |
BRPI0707479A2 (pt) | processo para a produção de um compósito de poliisocianurato, e, compósito reativo | |
ES2913842T3 (es) | Elementos de material compuesto realizados a base de material de aislamiento térmico, adhesivo y capa de recubrimiento | |
ES2338612T3 (es) | Sistema de espuma de absorcion acustica. | |
CA2523469A1 (en) | Polyisocyanate-based adhesive formulation for use in sandwich panels | |
JP2013500364A5 (ja) | ||
TW200904869A (en) | Polymer foam and foam articles for fire protection | |
US20070000413A1 (en) | Inorganic lightweight insulator and process for preparing it | |
CN105377930A (zh) | 改进多异氰酸酯加聚反应产物韧度的方法 | |
KR101223679B1 (ko) | 알루미노 실리케이트계 경량 기포콘크리트 조성물 및 이를 이용한 경량 기포콘크리트 제품의 제조방법 | |
KR100700465B1 (ko) | 폴리이소시아네이트 중부가 생성물을 함유하는 복합재 | |
KR200390026Y1 (ko) | 난연성 및 강도강화 폴리우레탄 패널 | |
JP2003026460A (ja) | 水和硬化体用混和材料及び水和硬化体 | |
JP4303019B2 (ja) | サンドイッチ構造体用ハニカム芯材および遮音パネル | |
EP3371408B1 (en) | High fire-resistant polyisocyanurate, and use thereof to manufacture fire door or window frames and/or profiles therefor | |
JPH06157749A (ja) | バインダー、該バインダーを使用した樹脂成型品及びその製造方法 | |
JP4560414B2 (ja) | 軟質ポリウレタン発泡体 | |
Jamshidi | A process for recycling thermosetting foams and the incorporation of recycled foams into structural composite panels | |
WO1981002300A1 (en) | Production of poly(polyisocyanate silicate)solid or cellular solid utilizing alkali metal silicates | |
IT201600077120A1 (it) | Poliisocianurato compatto ad alta densita’ | |
IT201600076956A1 (it) | Uso di poliisocianurato compatto per la realizzazione di profili per telai di serramenti di sicurezza |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20130704 |
|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20130704 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20140124 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20140203 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20140319 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20140602 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20140819 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20141110 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20141118 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 5653430 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |