JP5610669B2 - 噴霧重合によりポリマーを製造する方法 - Google Patents

噴霧重合によりポリマーを製造する方法 Download PDF

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Publication number
JP5610669B2
JP5610669B2 JP2007551591A JP2007551591A JP5610669B2 JP 5610669 B2 JP5610669 B2 JP 5610669B2 JP 2007551591 A JP2007551591 A JP 2007551591A JP 2007551591 A JP2007551591 A JP 2007551591A JP 5610669 B2 JP5610669 B2 JP 5610669B2
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water
same
polymer particles
monomer
different
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JP2008527155A5 (https=
JP2008527155A (ja
Inventor
レッシュ デニス
レッシュ デニス
ザイドル フォルカー
ザイドル フォルカー
ウーヴェ　シュテューフェン
シュテューフェン ウーヴェ
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BASF SE
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BASF SE
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
    • A61L15/16—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
    • A61L15/42—Use of materials characterised by their function or physical properties
    • A61L15/60—Liquid-swellable gel-forming materials, e.g. super-absorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B9/00—Making granules
    • B29B9/10—Making granules by moulding the material, i.e. treating it in the molten state
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/04—Acids; Metal salts or ammonium salts thereof
    • C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
    • C08F283/06—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polyethers, polyoxymethylenes or polyacetals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/14—Esterification
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/12—Powdering or granulating
    • C08J3/122—Pulverisation by spraying
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2810/00—Chemical modification of a polymer
    • C08F2810/20—Chemical modification of a polymer leading to a crosslinking, either explicitly or inherently
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2810/00—Chemical modification of a polymer
    • C08F2810/30—Chemical modification of a polymer leading to the formation or introduction of aliphatic or alicyclic unsaturated groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2810/00—Chemical modification of a polymer
    • C08F2810/40—Chemical modification of a polymer taking place solely at one end or both ends of the polymer backbone, i.e. not in the side or lateral chains

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Hematology (AREA)
  • Animal Behavior & Ethology (AREA)
  • Dispersion Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Epidemiology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Mechanical Engineering (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Absorbent Articles And Supports Therefor (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Polyesters Or Polycarbonates (AREA)
JP2007551591A 2005-01-18 2006-01-14 噴霧重合によりポリマーを製造する方法 Expired - Fee Related JP5610669B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE102005002412A DE102005002412A1 (de) 2005-01-18 2005-01-18 Verfahren zur Herstellung von Polymeren durch Sprühpolymerisation
DE102005002412.2 2005-01-18
PCT/EP2006/000289 WO2006077054A1 (de) 2005-01-18 2006-01-14 Verfahren zur herstellung von polymeren durch sprühpolymerisation

Publications (3)

Publication Number Publication Date
JP2008527155A JP2008527155A (ja) 2008-07-24
JP2008527155A5 JP2008527155A5 (https=) 2013-04-18
JP5610669B2 true JP5610669B2 (ja) 2014-10-22

Family

ID=36013644

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2007551591A Expired - Fee Related JP5610669B2 (ja) 2005-01-18 2006-01-14 噴霧重合によりポリマーを製造する方法

Country Status (8)

Country Link
US (1) US8268942B2 (https=)
EP (1) EP1841797B2 (https=)
JP (1) JP5610669B2 (https=)
CN (1) CN100584862C (https=)
AT (1) ATE507248T1 (https=)
DE (2) DE102005002412A1 (https=)
TW (1) TW200639185A (https=)
WO (1) WO2006077054A1 (https=)

Families Citing this family (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7727586B2 (en) * 2005-01-28 2010-06-01 Basf Aktiengesellschaft Production of water-absorbing polymeric particles by dropletization polymerization in the gas phase
WO2007093531A1 (de) * 2006-02-17 2007-08-23 Basf Se Verfahren zur herstellung wasserabsorbierender polymerpartikel durch polymerisation von tropfen einer monomerlösung
CN101490097B (zh) * 2006-07-19 2011-11-09 巴斯夫欧洲公司 通过聚合单体溶液液滴生产具有较高渗透性的吸水性聚合物颗粒的方法
RU2463310C2 (ru) 2006-07-19 2012-10-10 Басф Се Способ получения водопоглощающих полимерных частиц с высокой проницаемостью путем полимеризации капель мономерного раствора
WO2008009612A1 (de) 2006-07-19 2008-01-24 Basf Se Verfahren zur herstellung wasserabsorbierender polymerpartikel mit hoher permeabilität durch polymerisation von tropfen einer monomerlösung
JP5602428B2 (ja) 2006-07-19 2014-10-08 ビーエーエスエフ ソシエタス・ヨーロピア モノマー溶液の液滴の重合による、高い吸収性を有する後架橋された吸水性ポリマー粒子の製造方法
ATE491729T1 (de) 2006-10-05 2011-01-15 Basf Se Verfahren zur herstellung wasserabsorbierender polymerpartikel durch polymerisation von tropfen einer monomerlösung
US8529805B2 (en) * 2006-10-05 2013-09-10 Basf Se Method for the production of water absorbent polymer particles by polymerizing drops of a monomer solution
RU2467020C2 (ru) * 2006-10-31 2012-11-20 Басф Се Регулирование в способе получения абсорбирующих воду полимерных частиц в нагретой газовой фазе
CN101573386B (zh) † 2006-12-22 2012-06-20 巴斯夫欧洲公司 制备机械稳定的吸水性聚合物粒子的方法
US8419971B2 (en) 2006-12-22 2013-04-16 Basf Se Method for producing mechanically stable water-absorbent polymer particles
WO2008086976A1 (de) 2007-01-16 2008-07-24 Basf Se Verfahren zur herstellung von polymerpartikeln durch polymerisation von flüssigkeitstropfen in einer gasphase
WO2008095892A1 (de) * 2007-02-06 2008-08-14 Basf Se Verfahren zur herstellung wasserabsorbierender polymerpartikel durch polymerisation von tropfen einer monomerlösung
JP5419712B2 (ja) * 2007-02-06 2014-02-19 ビーエーエスエフ ソシエタス・ヨーロピア モノマー溶液の液滴の重合による吸水性ポリマー粒子を製造する方法
US8633285B2 (en) 2007-12-17 2014-01-21 Basf Se Method for producing water-absorbing polymer particles
EP2313042B1 (en) 2008-08-06 2013-07-10 Basf Se Fluid-absorbent articles
JP5496201B2 (ja) 2008-08-06 2014-05-21 ビーエーエスエフ ソシエタス・ヨーロピア 流体吸収性物品
EP2313040B1 (en) 2008-08-06 2013-06-19 Basf Se Fluid-absorbent articles
JP5322816B2 (ja) * 2009-07-15 2013-10-23 キヤノン株式会社 撮像装置およびその制御方法
US8481159B2 (en) 2009-09-04 2013-07-09 Basf Se Water-absorbent porous polymer particles having specific sphericity and high bulk density
CN102803302A (zh) 2010-03-15 2012-11-28 巴斯夫欧洲公司 通过聚合单体溶液的液滴生产吸水性聚合物颗粒的方法
US8852742B2 (en) 2010-03-15 2014-10-07 Basf Se Water absorbent polymer particles formed by polymerizing droplets of a monomer solution and coated with sulfinic acid, sulfonic acid, and/or salts thereof
JP5933520B2 (ja) 2010-03-24 2016-06-08 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ モノマー溶液の液滴を重合することによる吸水ポリマー粒子の製造方法
WO2011117187A1 (en) 2010-03-24 2011-09-29 Basf Se Ultrathin fluid-absorbent cores
WO2013045163A1 (en) 2011-08-12 2013-04-04 Basf Se A process for producing water-absorbent polymer particles by polymerizing droplets of a monomer solution
US11931928B2 (en) 2016-12-29 2024-03-19 Evonik Superabsorber Llc Continuous strand superabsorbent polymerization
CN111938918A (zh) * 2020-06-24 2020-11-17 杭州可靠护理用品股份有限公司 低回渗纸尿裤及其加工工艺
CN112920860A (zh) * 2021-01-21 2021-06-08 东南大学 生物质热解气在线联产含碳前驱物和高品质含氧燃料装置

Family Cites Families (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6024807B2 (ja) * 1979-02-19 1985-06-14 昭和電工株式会社 高吸水性ヒドロゲルの製造方法
JPS56147809A (en) * 1980-04-18 1981-11-17 Sumitomo Chem Co Ltd Highly water absorbing hydrogel and its preparation
JP2530668B2 (ja) * 1987-11-12 1996-09-04 株式会社日本触媒 改良された吸水性樹脂の製造法
WO1994019377A1 (en) * 1987-11-20 1994-09-01 The Dow Chemical Company Suspension polymerized aqueous absorbent polymer particles
JP2781208B2 (ja) * 1988-06-22 1998-07-30 三菱化学株式会社 吸水性樹脂の製造法
US5059664A (en) * 1988-06-22 1991-10-22 Mitsubishi Petrochemical Company Limited Process for the preparation of water absorptive resin
EP0348180A3 (en) 1988-06-22 1991-01-30 Mitsubishi Petrochemical Company Limited Process for the preparation of water absorptive resin
JP2642436B2 (ja) * 1988-08-30 1997-08-20 三菱化学株式会社 吸水性樹脂の製造法
DE3842184A1 (de) * 1988-12-15 1990-06-21 Basf Ag Verfahren zur steuerung der teilchengroesse bei der herstellung von pulverfoermigen polymerisaten
JP2982398B2 (ja) * 1991-07-05 1999-11-22 旭化成工業株式会社 新規な感光性樹脂組成物
JP3466222B2 (ja) * 1992-03-05 2003-11-10 株式会社日本触媒 吸水性樹脂の製造方法
EP0559476B1 (en) * 1992-03-05 1997-07-16 Nippon Shokubai Co., Ltd. Method for the production of absorbent resin
GB9208449D0 (en) 1992-04-16 1992-06-03 Dow Deutschland Inc Crosslinked hydrophilic resins and method of preparation
US5849816A (en) * 1994-08-01 1998-12-15 Leonard Pearlstein Method of making high performance superabsorbent material
IN1996KO01040A (https=) 1995-06-07 2005-03-04 Clarence S Freeman
DE19529348C2 (de) * 1995-08-09 1997-11-20 Stockhausen Chem Fab Gmbh Absorptionsmittel für Wasser und wäßrige Flüssigkeiten auf Polyacrylatbasis sowie Verfahren zu ihrer Herstellung und Verwendung
DE19543368C2 (de) † 1995-11-21 1998-11-26 Stockhausen Chem Fab Gmbh Wasserabsorbierende Polymere mit verbesserten Eigenschaften, Verfahren zu deren Herstellung und deren Verwendung
DE19646484C2 (de) * 1995-11-21 2000-10-19 Stockhausen Chem Fab Gmbh Flüssigkeitsabsorbierende Polymere, Verfahren zu deren Herstellung und deren Verwendung
DE19625143C1 (de) 1996-06-24 1997-08-21 Hoechst Ag Verfahren zur Herstellung von hydrophilen, hochquellfähigen Hydrogelen
CZ297784B6 (cs) * 2000-10-19 2007-03-28 Basf Aktiengesellschaft Zesítované vodou bobtnatelné polymery a zpusob jejich výroby
DE10358372A1 (de) * 2003-04-03 2004-10-14 Basf Ag Gemische von Verbindungen mit mindestens zwei Doppelbindungen und deren Verwendung
BRPI0410899A (pt) * 2003-06-06 2006-07-04 Basf Ag éster f, processos para preparar o mesmo e para preparar um hidrogel reticulado, polìmero, hidrogel reticulado, uso de um polìmero, composição de matéria, e, usos de uma mistura de reação e de um éster f
DE10340253A1 (de) 2003-08-29 2005-03-24 Basf Ag Sprühpolymerisationsverfahren
DE102004024437A1 (de) 2004-05-14 2005-12-08 Basf Ag Verfahren zur Herstellung wasserquellbarer, polymerer Partikel

Also Published As

Publication number Publication date
EP1841797B2 (de) 2015-04-15
CN100584862C (zh) 2010-01-27
US8268942B2 (en) 2012-09-18
TW200639185A (en) 2006-11-16
EP1841797B1 (de) 2011-04-27
ATE507248T1 (de) 2011-05-15
US20080188821A1 (en) 2008-08-07
EP1841797A1 (de) 2007-10-10
WO2006077054A1 (de) 2006-07-27
DE102005002412A1 (de) 2006-07-27
DE502006009389D1 (de) 2011-06-09
CN101107271A (zh) 2008-01-16
JP2008527155A (ja) 2008-07-24

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