JP5552229B2 - 長寿命の改良型膜電極ユニット及び燃料電池 - Google Patents

長寿命の改良型膜電極ユニット及び燃料電池 Download PDF

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JP5552229B2
JP5552229B2 JP2008525450A JP2008525450A JP5552229B2 JP 5552229 B2 JP5552229 B2 JP 5552229B2 JP 2008525450 A JP2008525450 A JP 2008525450A JP 2008525450 A JP2008525450 A JP 2008525450A JP 5552229 B2 JP5552229 B2 JP 5552229B2
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acid
electrode unit
membrane
membrane electrode
group
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JP2009505341A (ja
Inventor
ウエンザル，エマー
シュミット，トーマス
パドベルク，クリストフ
オト，デトレフ
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ビーエーエスエフ、フューエル、セル、ゲゼルシャフト、ミット、ベシュレンクテル、ハフツング
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/08—Fuel cells with aqueous electrolytes
    • H01M8/086—Phosphoric acid fuel cells [PAFC]
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/88—Processes of manufacture
    • H01M4/8803—Supports for the deposition of the catalytic active composition
    • H01M4/881—Electrolytic membranes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90—Selection of catalytic material
    • H01M4/92—Metals of platinum group
    • H01M4/925—Metals of platinum group supported on carriers, e.g. powder carriers
    • H01M4/926—Metals of platinum group supported on carriers, e.g. powder carriers on carbon or graphite
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/02—Details
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/02—Details
    • H01M8/0271—Sealing or supporting means around electrodes, matrices or membranes
    • H01M8/0273—Sealing or supporting means around electrodes, matrices or membranes with sealing or supporting means in the form of a frame
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/02—Details
    • H01M8/0289—Means for holding the electrolyte
    • H01M8/0293—Matrices for immobilising electrolyte solutions
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1004—Fuel cells with solid electrolytes characterised by membrane-electrode assemblies [MEA]
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/103—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having nitrogen, e.g. sulfonated polybenzimidazoles [S-PBI], polybenzimidazoles with phosphoric acid, sulfonated polyamides [S-PA] or sulfonated polyphosphazenes [S-PPh]
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1041—Polymer electrolyte composites, mixtures or blends
    • H01M8/1053—Polymer electrolyte composites, mixtures or blends consisting of layers of polymers with at least one layer being ionically conductive
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1069—Polymeric electrolyte materials characterised by the manufacturing processes
    • H01M8/1086—After-treatment of the membrane other than by polymerisation
    • H01M8/109—After-treatment of the membrane other than by polymerisation thermal other than drying, e.g. sintering
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/8605—Porous electrodes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/88—Processes of manufacture
    • H01M4/8803—Supports for the deposition of the catalytic active composition
    • H01M4/8807—Gas diffusion layers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Energy (AREA)
  • Sustainable Development (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Composite Materials (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Inert Electrodes (AREA)
  • Fuel Cell (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
JP2008525450A 2005-08-12 2006-08-05 長寿命の改良型膜電極ユニット及び燃料電池 Expired - Fee Related JP5552229B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE102005038195A DE102005038195A1 (de) 2005-08-12 2005-08-12 Verbesserte Membran-Elektrodeneinheiten und Brennstoffzellen mit langer Lebensdauer
DE102005038195.2 2005-08-12
PCT/EP2006/007767 WO2007019978A1 (de) 2005-08-12 2006-08-05 Verbesserte membran-elektrodeneinheiten und brennstoffzellen mit langer lebensdauer

Publications (2)

Publication Number Publication Date
JP2009505341A JP2009505341A (ja) 2009-02-05
JP5552229B2 true JP5552229B2 (ja) 2014-07-16

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JP2008525450A Expired - Fee Related JP5552229B2 (ja) 2005-08-12 2006-08-05 長寿命の改良型膜電極ユニット及び燃料電池

Country Status (10)

Country Link
US (1) US20080268321A1 (de)
EP (1) EP1915795B1 (de)
JP (1) JP5552229B2 (de)
KR (1) KR101307010B1 (de)
CN (1) CN101238610B (de)
AT (1) ATE504098T1 (de)
CA (1) CA2615655A1 (de)
DE (2) DE102005038195A1 (de)
RU (1) RU2008108805A (de)
WO (1) WO2007019978A1 (de)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5105928B2 (ja) * 2007-03-28 2012-12-26 三洋電機株式会社 燃料電池用電極、燃料電池用電極の作製方法、および燃料電池
JP5481880B2 (ja) * 2008-03-10 2014-04-23 東レ株式会社 電解質膜の製造方法
EP2228857A1 (de) 2009-03-06 2010-09-15 Basf Se Verbesserte Membran-Elektrodeneinheiten
JP2010257669A (ja) * 2009-04-23 2010-11-11 Toppan Printing Co Ltd 膜電極接合体及びその製造方法並びに固体高分子形燃料電池
US9168567B2 (en) * 2010-03-05 2015-10-27 Basf Se Polymer membranes, processes for production thereof and use thereof
US8871385B2 (en) * 2012-01-27 2014-10-28 Battelle Energy Alliance, Llc Electrodes including a polyphosphazene cyclomatrix, methods of forming the electrodes, and related electrochemical cells
JP5907054B2 (ja) * 2012-12-14 2016-04-20 トヨタ自動車株式会社 燃料電池の製造方法
DK2869382T3 (en) 2013-10-30 2019-04-01 Basf Se Improved diaphragm electrode devices
DE102016125355A1 (de) * 2016-12-22 2018-06-28 Audi Ag Separatorplatte, Membran-Elektroden-Einheit und Brennstoffzelle
DE102018009747A1 (de) 2018-12-14 2020-06-18 Johns Manville Europe Gmbh Hybride Gasdiffusionslage für elektrochemische Zellen
DK180599B1 (en) * 2020-01-20 2021-10-14 Blue World Technologies Holding ApS Apparatus and process for making acid-doped proton exchange membranes

Family Cites Families (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4191618A (en) * 1977-12-23 1980-03-04 General Electric Company Production of halogens in an electrolysis cell with catalytic electrodes bonded to an ion transporting membrane and an oxygen depolarized cathode
US4212714A (en) * 1979-05-14 1980-07-15 General Electric Company Electrolysis of alkali metal halides in a three compartment cell with self-pressurized buffer compartment
US4333805A (en) * 1980-05-02 1982-06-08 General Electric Company Halogen evolution with improved anode catalyst
EP0586461B1 (de) * 1991-06-04 1995-09-13 Ballard Power Systems Inc. Gegliederte membranelektrodenanordnung für elektrochemische brennstoffzelle
JPH06333582A (ja) * 1993-05-25 1994-12-02 Fuji Electric Co Ltd 固体高分子電解質型燃料電池
DE19509749C2 (de) * 1995-03-17 1997-01-23 Deutsche Forsch Luft Raumfahrt Verfahren zur Herstellung eines Verbundes aus Elektrodenmaterial, Katalysatormaterial und einer Festelektrolytmembran
DE19509748C2 (de) * 1995-03-17 1997-01-23 Deutsche Forsch Luft Raumfahrt Verfahren zur Herstellung eines Verbundes aus Elektrodenmaterial, Katalysatormaterial und einer Festelektrolytmembran
US6054228A (en) * 1996-06-06 2000-04-25 Lynntech, Inc. Fuel cell system for low pressure operation
JP2000100456A (ja) * 1998-09-22 2000-04-07 Aisin Seiki Co Ltd 固体高分子電解質膜と電極の接合体の製造方法及び固体高分子電解質型燃料電池
JP2000243413A (ja) * 1999-02-23 2000-09-08 Sanyo Electric Co Ltd 固体高分子型燃料電池用電解質膜及びこれを用いた固体高分子型燃料電池
DE10052242A1 (de) * 2000-10-21 2002-05-02 Celanese Ventures Gmbh Mit Säure dotierte, ein- oder mehrschichtige Kunststoffmembran mit Schichten aufweisend Polymerblends umfassend Polymere mit wiederkehrenden Azoleinheiten, Verfahren zur Herstellung solche Kunststoffmembranen sowie deren Verwendung
WO2002061869A1 (fr) * 2001-01-31 2002-08-08 Matsushita Electric Industrial Co., Ltd. Pile a carburant electrolytique de haut polymere et ensemble joint a film electrolytique destine a la pile a carburant
DE10109829A1 (de) * 2001-03-01 2002-09-05 Celanese Ventures Gmbh Polymermembran, Verfahren zu deren Herstellung sowie deren Verwendung
DE10140147A1 (de) * 2001-08-16 2003-03-06 Celanese Ventures Gmbh Verfahren zur Herstellung einer Blend-Membran aus verbrücktem Polymer und Brennstoffzelle
CA2428131C (en) * 2001-09-11 2010-11-16 Sekisui Chemical Co., Ltd. Membrane-electrode assembly, method of manufacturing the same, and polymer electrolyte fuel cell using the same
JP2003282093A (ja) * 2002-03-25 2003-10-03 Matsushita Electric Ind Co Ltd 燃料電池用電解質膜−電極接合体およびその製造方法
EP1429408A4 (de) * 2002-03-25 2007-10-31 Matsushita Electric Ind Co Ltd Vereinigung einer elektrolytmembran/-elektrode für eine brennstoffzelle und prozess zu ihrer herstellung
DE10220818A1 (de) 2002-05-10 2003-11-20 Celanese Ventures Gmbh Verfahren zur Herstellung einer gepfropften Polymerelektrolytmembran und deren Anwendung in Brennstoffzellen
DE10235360A1 (de) * 2002-08-02 2004-02-19 Celanese Ventures Gmbh Membran-Elektrodeneinheiten mit langer Lebensdauer
DE102004035305A1 (de) * 2004-07-21 2006-02-16 Pemeas Gmbh Verbesserte Membran-Elektrodeneinheiten und Brennstoffzellen mit hoher Lebensdauer

Also Published As

Publication number Publication date
KR20080034926A (ko) 2008-04-22
DE502006009217D1 (de) 2011-05-12
US20080268321A1 (en) 2008-10-30
WO2007019978A1 (de) 2007-02-22
RU2008108805A (ru) 2009-09-20
CN101238610A (zh) 2008-08-06
JP2009505341A (ja) 2009-02-05
DE102005038195A1 (de) 2007-02-15
KR101307010B1 (ko) 2013-09-12
ATE504098T1 (de) 2011-04-15
CA2615655A1 (en) 2007-02-22
CN101238610B (zh) 2012-11-28
EP1915795B1 (de) 2011-03-30
EP1915795A1 (de) 2008-04-30

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