JP5547632B2 - 太陽光吸着冷凍システムの構成要素およびそのような構成要素の作製方法 - Google Patents
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- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/02—Materials undergoing a change of physical state when used
- C09K5/04—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa
- C09K5/047—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for absorption-type refrigeration systems
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- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B17/00—Sorption machines, plants or systems, operating intermittently, e.g. absorption or adsorption type
- F25B17/08—Sorption machines, plants or systems, operating intermittently, e.g. absorption or adsorption type the absorbent or adsorbent being a solid, e.g. salt
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
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- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
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- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B35/00—Boiler-absorbers, i.e. boilers usable for absorption or adsorption
- F25B35/04—Boiler-absorbers, i.e. boilers usable for absorption or adsorption using a solid as sorbent
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- B01J2220/40—Aspects relating to the composition of sorbent or filter aid materials
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- F25B2500/00—Problems to be solved
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Description
[0001] 米国特許法第119条の条項に基づき、2007年6月22日に出願された米国仮特許出願第60/936,876号の優先権の利益および2007年7月20日に出願された米国仮特許出願第60/951,137号の優先権の利益をここに(hereby)主張する。米国仮特許出願第60/936,876号および米国仮特許出願第60/951,137号の開示の全体を、あらゆる目的のために、参照によってそれぞれ本願にここに援用する。
Claims (15)
- 細孔構造を含む吸着材料から形成される少なくとも1つの吸着部材と、
前記吸着部材に吸着可能なガスが通過する少なくとも1つの多孔性部材であって、前記吸着部材の表面と接触して設けられる表面を有し、加熱又は冷却サイクルの間に、前記ガスを、前記少なくとも1つの多孔性部材に通過させて前記吸着部材の前記表面で出入りすることができるようにし、前記ガスの前記吸着材料の前記細孔構造への吸着速度と前記ガスの前記吸着材料の前記細孔構造からの脱着速度とを高める前記少なくとも1つの多孔性部材と、
を含む吸着構造。 - 前記吸着部材と接触して設けられ、前記吸着部材と熱移動流体との間で熱を移動するように構成された少なくとも1つの熱伝導性部材をさらに含む、請求項1に記載の吸着構造。
- 前記吸着材料が活性炭を含む、請求項1又は2に記載の吸着構造。
- 前記少なくとも1つの多孔性部材が多孔性金属を含み、前記少なくとも1つの熱伝導性部材が金属を含む、請求項1〜3のいずれか1項に記載の吸着構造。
- 前記吸着材料の熱移動特性を高めるために前記吸着材料内部に設けられた材料をさらに含み、前記吸着材料の熱移動特性を高めるための材料が、(i)前記吸着部材内部に設けられた金属、(ii)前記吸着材料内部の第2の相、(iii)ダイヤモンド様炭素、(iv)ダイヤモンドナノ結晶、(v)ダイヤモンドマイクロ結晶、(vi)炭素ナノチューブ及び(vii)複数の配列された繊維、からなる群から選択される高特性化材料である、請求項1〜4のいずれか1項に記載の吸着構造。
- 請求項2〜5のいずれか1項に記載の吸着構造を作製するための方法であって、
細孔構造を含む吸着材料から形成される吸着部材であって、前記吸着部材に吸着可能なガスを貯蔵および移動することができるように構成された前記吸着部材の表面と接触した表面を有する多孔性部材であって、前記ガスが通過する前記多孔性部材を設け、それにより、前記多孔性部材に前記ガスが通過し前記ガスが前記吸着部材の前記表面を横断することができるようにし、前記ガスの前記吸着材料の前記細孔構造への吸着速度と前記ガスの前記吸着材料の前記細孔構造からの脱着速度とを高める工程と、
前記吸着材料と熱移動流体との間で熱を移動するように構成されている少なくとも1つの熱伝導性部材を、前記吸着部材と接触して設ける工程と
を含む方法。 - (i)材料を吸着材料内部に設けて、前記吸着材料の熱移動特性を高める工程、及び、(ii)外部磁界を利用して前記吸着材料内部での熱移動特性を高める配列を行う工程、からなる群から選択される少なくとも1つの工程により、前記吸着材料の熱移動特性を高める工程をさらに含む、請求項6に記載の方法。
- 請求項1〜5のいずれか1項に記載の吸着構造を含み、前記多孔性部材は、冷媒流体が前記吸着材料を出入りすることができるように構成されている、吸着式冷凍システム。
- 冷媒流体によって冷却されるチャンバをさらに含む、請求項8に記載の吸着式冷凍システム。
- 前記吸着材料が、第1の密度を有する第1の活性炭前駆体を設ける工程と、第2の密度を有する第2の活性炭前駆体を、構造を形成するように前記第1の活性炭前駆体と接触して設ける工程と、前記構造を、複数の細孔を含む吸着材料を形成するように熱分解する工程とを含むプロセスによって形成され、前記吸着材料は前記第1の活性炭前駆体に対応する第1の領域および前記第2の活性炭前駆体に対応する第2の領域を含み、前記第1の領域と前記第2の領域では、細孔サイズおよび細孔分布のうちの少なくとも1つが異なる、請求項6又は7に記載の方法。
- (i)前記第1および第2の活性炭前駆体がポリマー材料であること、(ii)前記第1および第2の活性炭前駆体が、塩化ポリビニリデン、フェノール−ホルムアルデヒド樹脂、ポリフルフリルアルコール、ココナツ殻、ピーナツ殻、モモ種子、オリーブ種子、ポリアクリロニトリル、及びポリアクリルアミドからなる群から選択されること、(iii)前記第1の領域が第1のサイズの細孔を含み、前記第2の領域が前記第1のサイズより大きい第2のサイズの細孔を含むこと、(iv)前記第1の密度が前記第2の密度より大きいこと、(v)前記第1および第2の活性炭前駆体を設ける工程が、前記第1の活性炭前駆体を含む第1の層を設ける工程および前記第2の活性炭前駆体を含む第2の層を前記第1の層に積層する工程を含むこと、(vi)前記第1および第2の活性炭前駆体を設ける工程が、前記第1の活性炭前駆体内部に前記第2の活性炭前駆体を設ける工程を含むこと、及び、(vii)前記熱分解する工程の前に、前記第1の密度および前記第2の密度と異なる第3の密度の第3の活性炭前駆体を設ける工程をさらに含むこと、の少なくとも1つによって特徴付けられる、請求項10に記載の方法。
- 請求項6又は7に記載の方法であって、前記吸着部材は、ポリマーマトリックス内部に設けられた第1の材料を含む部材を設ける工程と、前記第1の材料を除去する工程と、前記ポリマーマトリックス内部に細孔を形成するように前記部材を熱分解する工程とを含むプロセスによって形成され、前記方法は、(i)前記第1の材料が犠牲材料であること、(ii)前記第1の材料を除去する工程が、前記第1の材料を灰化または溶解する工程を含むこと、(iii)前記第1の材料がアルミニウムを含み、前記第1の材料を除去する工程が、AlCl3ガスを形成するように塩化水素ガスをポリマー材料へと導入する工程を含むこと、(iv)前記第1の材料を除去する工程が前記熱分解する工程の間に実施されること、(v)前記第1の材料を除去する工程が前記熱分解する工程の後に実施されること、及び(vi)前記第1の材料を除去する工程が前記熱分解する工程の前に実施されること、のうち少なくとも1つを含む、方法。
- 前記吸着材料は、第1の細孔分布を有する第1の領域と、第2の細孔分布を有する第2の領域とを含み、前記第1の領域は第1の密度を有する第1のポリマー材料から形成され、前記第2の領域は第2の密度を有する第2のポリマー材料から形成される、請求項1〜5のいずれか1項に記載の吸着構造。
- 前記第1のポリマー材料および前記第2のポリマー材料が同じ組成を有し、および/または前記第1の領域が前記第2の領域より大きい細孔を含み、および/または前記第1の細孔分布が、単位体積あたり、前記第2の領域より少ない細孔を含む、請求項13に記載の吸着構造。
- 前記吸着材料への収着質ガスの負荷を増加するために十分な時間の間、前記収着質ガス環境で、前記吸着材料を高温および高圧条件に維持することにより、前記吸着材料の負荷容量を高める、請求項6、7、10〜12のいずれか1項に記載の方法。
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
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US93687607P | 2007-06-22 | 2007-06-22 | |
US60/936,876 | 2007-06-22 | ||
US95113707P | 2007-07-20 | 2007-07-20 | |
US60/951,137 | 2007-07-20 | ||
PCT/US2008/067824 WO2009002893A2 (en) | 2007-06-22 | 2008-06-22 | Component for solar adsorption refrigeration system and method of making such component |
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JP2010530953A JP2010530953A (ja) | 2010-09-16 |
JP2010530953A5 JP2010530953A5 (ja) | 2011-08-11 |
JP5547632B2 true JP5547632B2 (ja) | 2014-07-16 |
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US (2) | US8539781B2 (ja) |
EP (1) | EP2174076A4 (ja) |
JP (1) | JP5547632B2 (ja) |
KR (1) | KR101524324B1 (ja) |
CN (1) | CN101688705B (ja) |
AU (1) | AU2008268510B2 (ja) |
BR (1) | BRPI0814731A2 (ja) |
TW (1) | TWI439649B (ja) |
WO (1) | WO2009002893A2 (ja) |
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EP2174076A4 (en) | 2007-06-22 | 2011-04-13 | Advanced Tech Materials | COMPONENT FOR SOLAR ADSORPTION REFRIGERATION SYSTEM AND METHOD FOR MANUFACTURING THE SAME |
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US8067646B2 (en) | 2008-12-17 | 2011-11-29 | Uop Llc | Combined temperature controlled adsorption and heat pump process for fuel ethanol dehydration |
US7795479B1 (en) | 2009-12-15 | 2010-09-14 | Uop Llc | Temperature controlled adsorption multi-step regeneration cycle |
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DE112011103811B4 (de) * | 2010-12-22 | 2015-08-20 | International Business Machines Corporation | Festkörpersorptionskühlung |
US8679231B2 (en) | 2011-01-19 | 2014-03-25 | Advanced Technology Materials, Inc. | PVDF pyrolyzate adsorbent and gas storage and dispensing system utilizing same |
JP5482681B2 (ja) * | 2011-02-07 | 2014-05-07 | 株式会社豊田中央研究所 | 蓄熱装置 |
US8962520B2 (en) * | 2011-04-18 | 2015-02-24 | The Hong Kong University Of Science And Technology | Activated carbon/silica-gel/CaCl2 composite adsorbent material for air-conditioning applications and a method of preparing the same |
DE102011115018A1 (de) | 2011-06-21 | 2013-01-10 | Günter Kreitz | Sonnenkollektoren, Heizkörper, Kühlkörper |
US8544294B2 (en) * | 2011-07-11 | 2013-10-01 | Palo Alto Research Center Incorporated | Plate-based adsorption chiller subassembly |
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CN101688705A (zh) | 2010-03-31 |
AU2008268510A1 (en) | 2008-12-31 |
KR20100036322A (ko) | 2010-04-07 |
EP2174076A2 (en) | 2010-04-14 |
KR101524324B1 (ko) | 2015-06-04 |
US8539781B2 (en) | 2013-09-24 |
WO2009002893A3 (en) | 2009-02-19 |
CN101688705B (zh) | 2012-09-05 |
US20110048063A1 (en) | 2011-03-03 |
US9132412B2 (en) | 2015-09-15 |
WO2009002893A8 (en) | 2010-01-28 |
TW200921029A (en) | 2009-05-16 |
TWI439649B (zh) | 2014-06-01 |
JP2010530953A (ja) | 2010-09-16 |
AU2008268510B2 (en) | 2013-09-05 |
BRPI0814731A2 (pt) | 2015-02-24 |
WO2009002893A2 (en) | 2008-12-31 |
US20140020419A1 (en) | 2014-01-23 |
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