JP5535086B2 - 被覆ポリオキシメチレン - Google Patents
被覆ポリオキシメチレン Download PDFInfo
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- JP5535086B2 JP5535086B2 JP2010543472A JP2010543472A JP5535086B2 JP 5535086 B2 JP5535086 B2 JP 5535086B2 JP 2010543472 A JP2010543472 A JP 2010543472A JP 2010543472 A JP2010543472 A JP 2010543472A JP 5535086 B2 JP5535086 B2 JP 5535086B2
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- ULQISTXYYBZJSJ-UHFFFAOYSA-N 12-hydroxyoctadecanoic acid Chemical compound CCCCCCC(O)CCCCCCCCCCC(O)=O ULQISTXYYBZJSJ-UHFFFAOYSA-N 0.000 description 2
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Classifications
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- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/0427—Coating with only one layer of a composition containing a polymer binder
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/06—Coating with compositions not containing macromolecular substances
- C08J7/065—Low-molecular-weight organic substances, e.g. absorption of additives in the surface of the article
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2359/00—Characterised by the use of polyacetals containing polyoxymethylene sequences only
- C08J2359/02—Copolyoxymethylenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2433/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2471/00—Characterised by the use of polyethers obtained by reactions forming an ether link in the main chain; Derivatives of such polymers
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2991—Coated
- Y10T428/2998—Coated including synthetic resin or polymer
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31786—Of polyester [e.g., alkyd, etc.]
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)
Description
−ポリアミド、特にコポリアミド、
−アルカリ土類金属ケイ酸塩及びアルカリ土類金属グリセロリン酸塩、
−飽和脂肪族カルボン酸のエステル又はアミド、
−アルコールから及びエチレンオキシドから誘導されるエーテル、
−非極性ポリプロピレンワックス、
−核剤、
−好ましくは相乗剤としてホウ酸又はその誘導体を有する、ガラス繊維、ナノチューブ、珪灰石、チョークのような充填剤、
−衝撃改質ポリマー、特に、エチレン−プロピレンゴム(EPMゴム)に基づいた又はエチレン−プロピレン−ジエンゴム(EPDMゴム)に基づいた又は熱可塑性ポリウレタンに基づいたもの、
−難燃剤、
−可塑剤、
−カップリング剤、
−染料及び顔料、
−D)と異なる又はゼオライト若しくはポリエチレンイミン若しくはメラミン−ホルムアルデヒド縮合物である更なるホルムアルデヒド捕捉剤、
−酸化防止剤、特に、フェノール構造を有するもの、ベンゾフェノン誘導体、ベンゾトリアゾール誘導体、アクリル酸塩、安息香酸塩、オキサニリド及び立体障害アミン(HALS=ヒンダードアミン光安定剤)。
CH3O(CH2CH2O)nH (Pluriol(登録商標)A...E等級)
ブチルポリプロピレングリコール
R−O[CH2(CH3)CHO]nH (Pluriol(登録商標)A...P等級)
ブチルポリアルキレングリコールコポリマー
R−O[(CH2CH2O)n(CH2(CH3)CHO)]mH (Pluriol(登録商標)A...PE等級)
アリルジオール及びブチンジオールポリアルキレングリコール、
また、テトラメチルデシンジオール (Pluriol(登録商標)A...R等級)
アリルアルコールエトキシレート
CH2=CHCH2O(CH2CH2O)nH (Pluriol(登録商標)A 010 R)
アリルアルコールアルコキシレート
CH2=CHCH2O[(CH2CH2O)n(CH2(CH3)CHO)]mH (Pluriol(登録商標)A 23 R)
2,4,7,9−テトラメチル−5−デシン−4,7−ジオール (Pluriol(登録商標)A 104 R)
メチル末端基でキャップされているアリルアルコールアルコキシレート
CH2=CHCH2O[(CH2CH2O)n(CH2(CH3)CHO)]mCH3 (Pluriol(登録商標)A 111 R)
ブチン−1,4−ジオールポリエトキシレート
H(OCH2CH2)n−OCH2−C≡C−CH2O−(CH2CH2O)nH (Pluriol(登録商標)A 308 R)
トリメチロールプロパン又はグリセロールに基づいた多官能ポリアルキレングリコール (Pluriol(登録商標)A TE等級)
DIN53240によるヒドロキシ数は、好ましくは、3〜1000mgKOH/g未満であり、好ましいものは、3〜800mgKOH/g未満であり、平均モル質量は、200〜7000、好ましいものは、350〜5000g/molである。
A)20〜70質量%の水溶性ポリアルキレンオキシド、並びに
B)(B1)70〜100質量%の酢酸ビニル及び/又はプロピオン酸ビニル及び
(B2)0〜30質量%の更なるエチレン性不飽和モノマー、からなる30〜80質量%のビニルエステル成分、からなる構造を有する。
(A2)エチレンオキシド含有量が少なくとも50質量%であり、一端又は両端が同様に特にC1〜C25アルキル基で末端キャップされているが、好ましくはエーテル化されておらず、平均分子量Mnが好ましくは1000〜20000、特に好ましくは2500〜15000である、エチレンオキシド及びプロピレンオキシド及び/又はブチレンオキシドのコポリマー、
(A3)平均分子量が特に2500〜20000であり、平均分子量Mnが200〜5000のプロピレングリコール(A1)又は平均分子量Mnが200〜5000のコポリマー(A2)と、C2〜C12ジカルボン酸又はC2〜C12ジカルボン酸エステル又はC6〜C18ジイソシアネートとの反応を介して得られる、鎖延長生成物。
n=1又は2であり、
R1=H又は5〜6個の炭素原子を有する芳香族残基であり、
Y=2〜30個の炭素原子を有するアルキル残基又は5〜8個の炭素原子を有する芳香族残基又はアミノ若しくはヒドラジド基(−NH−NH2)であり、ここでアルキル残基又は芳香族残基は、場合により、酸素基、アミノ基、硫黄基、窒素基又はヒドラジド基を置換基として含むことができる]のヒドラジド化合物が一般に使用される。
7.5〜12質量%の炭素、
1.5質量%の水。
使用された成分は下記であった。
97.3質量%のトリオキサン及び2.7質量%のブタンジオールホルマールを含むポリオキシメチレンコポリマー。この生成物は、依然として、約3質量%の未反応トリオキサン及び5質量%の熱不安定画分を含んでいた。熱不安定画分を分解した後、コポリマーの融解容量速度は、7〜8cm3/10分であった(ISO1133により190℃、2.16kg)。
MVRが1.8〜2.6ml/10分であるPOMコポリマー(ISO1133により190℃、2.16kg)。
MVRが5.7〜8.3ml/10分であるPOMコポリマー(ISO1133により190℃、2.16kg)。
CognisからのLoxiol(登録商標)P 1206(グリセロールジステアレート)。
DE−A2540207の実施例1のメラミン−ホルムアルデヒド縮合物(MFK)。
US−A3,960,984の実施例(「PA−ジキャップ」)に基づいた方法により(モル質量調整剤として)カプロラクタム、ヘキサメチレンジアミン、アジピン酸及びプロピオン酸から調製した、モル質量が約3000g/molのポリアミドオリゴマー。
以下の特性を有する合成ケイ酸マグネシウム(PQ FranceからのAmbosol(登録商標))、
MgOの含有量 ≧14.8質量%
SiO2の含有量 ≧59質量%
SiO2:MgO比 2.7mol/mol
嵩密度 20〜30g/100ml
燃焼による損失 <25質量%
成分B/6
カーボンブラック(Degussa AGからのPrintex(登録商標)90)。
ショアA硬度が83である熱可塑性ポリウレタン(Elastogran GmbHからのElastollan(登録商標)B 85 A)。
C11:
メチルポリエチレングリコール、平均モル質量2000g/mol(BASF AGからのPluriol(登録商標)A 2000 E)
C12:
C11を参照すること、3000g/mol(BASF AGからのPluriol(登録商標)A 3010 E)
成分C2
C21:
粘度が1.9〜2.3mPa・s(10%酢酸エチル中20℃、DIN53015)、Wacker Polymer Systems GmbH & Co. KGからのVinnapas(登録商標)B 14 spのポリ酢酸ビニルホモポリマー
C22:
C21を参照すること、η=3.0〜3.5mPa・s(Wacker Polymer Systems GmbH & Co. KGからのVinnapas(登録商標)B 30 sp)
C23:
C21を参照すること、η=5.0〜6.5mPa・s(Wacker Polymer Systems GmbH & Co. KGからのVinnapas(登録商標)B 100)
C24:
C21を参照すること、η=8.0〜11.0mPa・s(Wacker Polymer Systems GmbH & Co. KGからのVinnapas(登録商標)UW 1)
C1+C2からなるグラフトポリマーC3(DE−A1077430によるフリーラジカル重合を介して得た)
C31:
40質量%のポリエチレングリコールPEG(モル質量:6000g/mol)及び
60質量%のPVA(ポリ酢酸ビニル)
C32:
モル質量が6000g/molの40質量%のPEG
60質量%のPVA、からなるグラフトポリマー
C33:
モル質量が6000g/molの20質量%のPEG
80質量%のPVA、からなるグラフトポリマー
C34:
モル質量が6000g/molの30質量%のPEG
70質量%のPVA、からなるグラフトポリマー
C35:
モル質量が4000g/molの30.8質量%のPEG
69.2質量%のPVA、からなるグラフトポリマー
成分D
アジピン酸ジヒドラジド
顔料E
BASF AGからのPaliogen(登録商標)Red 3911 HD(CAS No. 3049−71−6)。
10質量%の結合剤C1を水に溶解し、結合剤C2では、アセトンを溶媒として使用し、結合剤C3を水に60〜70℃で溶解した。
参考例1
ペレット1、C11、D、E
参考例2
ペレット1、C12、D、E
参考例3
ペレット1、C21、D、E
参考例4
ペレット1、C22、D、E
参考例5
ペレット1、C23、D、E
参考例6
ペレット1、C24、D、E
実施例7
ペレット1、C31、D、E
実施例8
ペレット1、C32、D、E
実施例9
ペレット1、C33、D、E
実施例10
ペレット1、C34、D、E
実施例11
ペレット1、C35、D、E
実施例12
ペレット2、C35、D
実施例13
ペレット2、C31、D
実施例14
ペレット3、C35、D
実施例15
ペレット4、C35、D、E。
Claims (10)
- 少なくとも1つの結合剤C)及び1つのホルムアルデヒド捕捉剤D)で表面が被覆されており、少なくとも1つのポリオキシメチレンホモポリマー又はコポリマーA)、並びに場合により更なる添加剤B)を含む、被覆ポリオキシメチレン成形品において、
結合剤C)として、ポリアルキレンオキシドC1及びポリビニルエステルC2からなるグラフトポリマーC3が使用され、かつホルムアルデヒド捕捉剤D)として、少なくとも1つのヒドラジド化合物が使用されることを特徴とする、被覆ポリオキシメチレン成形品。 - 前記成形品が、チップ、ペレット、粉末、微粉末、ビーズ、レンズ状顆粒又はこれらの混合物からなることを特徴とする、請求項1に記載の被覆POM成形品。
- 脂肪族若しくは芳香族ジヒドラジドD)又はこれらの混合物が使用されることを特徴とする、請求項1から3までのいずれか1項に記載の被覆POM成形品。
- 結合剤C3として、
A)20〜70質量%の水溶性ポリエチレンオキシドと、
B)B1)70〜100質量%の酢酸ビニル及び/又はプロピオン酸ビニル及び
B2)0〜30質量%の更なるエチレン性不飽和モノマー
からなる30〜80質量%のビニルエステル成分と
からなる構造を有する、C1とC2からなるグラフトポリマーが使用されることを特徴とする、請求項1から4までのいずれか1項に記載の被覆POM成形品。 - 前もって成分C)及びD)から溶液、エマルション又は分散液を調製し、次にこれをPOM成形品に適用し、乾燥させることを特徴とする、請求項1から5までのいずれか1項に記載の被覆POM成形品の製造方法。
- 水性又はアセトン性溶液がC)及びD)から調製されることを特徴とする、請求項6に記載の方法。
- 10質量%までの顔料E)が、C)及びD)からなる溶液に添加されることを特徴とする、請求項6又は7に記載の方法。
- C)及びD)からなる被覆が噴霧(スプレー)技術によって適用されることを特徴とする、請求項6から8までのいずれか1項に記載の方法。
- 被覆が室温から60℃で適用されることを特徴とする、請求項6から9までのいずれか1項に記載の方法。
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PCT/EP2009/050573 WO2009092698A1 (de) | 2008-01-22 | 2009-01-20 | Beschichtete polyoxymethylene |
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Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BRPI0908779A2 (pt) * | 2008-02-13 | 2015-07-28 | Basf Se | Peça moldada de polioximetileno revestido, e, processo para a produção da mesma |
CN103228728B (zh) * | 2010-10-14 | 2017-11-24 | 塞拉尼斯销售德国有限公司 | 增塑的聚甲醛 |
US9296896B2 (en) | 2010-11-23 | 2016-03-29 | Basf Se | Polyamides with nanoparticles on the surface |
KR101905206B1 (ko) | 2010-11-23 | 2018-10-05 | 바스프 에스이 | 표면 상에 나노입자를 갖는 폴리아미드 |
DE102011086516A1 (de) * | 2011-11-17 | 2013-05-23 | Evonik Degussa Gmbh | Superabsorbierende Polymere mit schnellen Absorptionseigenschaften sowieVerfahren zu dessen Herstellung |
CA2865249C (en) * | 2012-03-14 | 2021-09-07 | Valspar Sourcing, Inc. | Modified crush resistant latex topcoat composition for fiber cement substrates |
JP5890754B2 (ja) * | 2012-06-25 | 2016-03-22 | 三菱エンジニアリングプラスチックス株式会社 | ポリアセタール樹脂組成物 |
ES2688532T3 (es) | 2013-01-18 | 2018-11-05 | Basf Se | Composiciones de recubrimiento a base de dispersión acrílica |
US20150104635A1 (en) * | 2013-10-14 | 2015-04-16 | Ticona Llc | Coatings for polyoxymethylene polymer molded articles |
Family Cites Families (32)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1077430B (de) | 1958-04-15 | 1960-03-10 | Hoechst Ag | Verfahren zur Herstellung von Pfropfpolymerisaten von Polyvinylestern |
US3102106A (en) * | 1960-12-08 | 1963-08-27 | Du Pont | Stabilized polyoxymethylenes |
US3574786A (en) | 1967-12-25 | 1971-04-13 | Asahi Chemical Ind | Polyacetal compositions stabilized with a polymer from a dicarboxylic acid dihydrazide,diamine and urea |
US3960984A (en) | 1974-04-16 | 1976-06-01 | E. I. Du Pont De Nemours And Company | Composition of oxymethylene polymer and amide oligomers |
DE2540207B1 (de) | 1975-09-10 | 1976-11-18 | Degussa | Polyoxymethylen-Formmassen(I) |
JPS55145529A (en) | 1979-05-01 | 1980-11-13 | Otsuka Chem Co Ltd | Formalin adsorbent |
JPS56105905A (en) | 1980-01-29 | 1981-08-22 | Otsuka Kagaku Yakuhin | Formalin adsorbent |
US4351916A (en) * | 1980-09-09 | 1982-09-28 | E. I. Du Pont De Nemours And Company | Polyoxymethylene molding blends |
JPH0739524B2 (ja) * | 1982-05-21 | 1995-05-01 | 日本合成化学工業株式会社 | ポリビニルアルコール系樹脂組成物及びその用途 |
DE3536530A1 (de) | 1985-10-12 | 1987-04-23 | Basf Ag | Verwendung von pfropfcopolymerisaten aus polyalkylenoxiden und vinylacetat als vergrauungsinhibitoren beim waschen und nachbehandeln von synthesefasern enthaltendem textilgut |
US4652594A (en) * | 1985-10-16 | 1987-03-24 | Celanese Corporation | Glass fiber-reinforced oxymethylene polymer molding compositions having mechanical properties enhanced by amino-formaldehyde resin coupling agents |
JPH086003B2 (ja) * | 1987-09-01 | 1996-01-24 | コニシ株式会社 | 酢酸ビニル樹脂エマルジョン組成物 |
US4996253A (en) * | 1988-11-10 | 1991-02-26 | Hoechst Celanese Corporation | UV-light stabilized polyoxymethylene molding compositions |
JP3043344B2 (ja) * | 1989-09-25 | 2000-05-22 | ポリプラスチックス株式会社 | ポリアセタール樹脂組成物及び摺動部材 |
JPH04345648A (ja) | 1991-05-15 | 1992-12-01 | Du Pont Japan Ltd | ポリアセタール樹脂組成物 |
JP3053499B2 (ja) | 1992-08-31 | 2000-06-19 | 大塚化学株式会社 | 1,2,3,4−ブタンテトラカルボン酸ヒドラジド |
JPH1036524A (ja) * | 1996-07-30 | 1998-02-10 | Polyplastics Co | 梱包材及びその使用方法 |
JP3708693B2 (ja) | 1997-11-12 | 2005-10-19 | ポリプラスチックス株式会社 | ポリアセタール樹脂着色組成物 |
DE69903370T2 (de) * | 1998-05-14 | 2003-07-03 | Mitsubishi Gas Chemical Co | Polyoxymethylenharz-Zusammensetzung |
DE10005942A1 (de) * | 2000-02-09 | 2001-08-16 | Basf Ag | Verfahren zur Herstellung von wasserlöslichen oder wasserdispergierbaren polyetherhaltigen Polymerisaten sowie deren Verwendung als Überzugsmittel, Bindemittel und/oder filmbildende Hilfsstoffe in pharmazeutischen Darreichungsformen oder Verpackungsmaterialien oder als Zusatzstoffe in kosmetischen, dermatologischen oder hygienischen Zubereitungen |
WO2001005888A1 (fr) * | 1999-07-16 | 2001-01-25 | Polyplastics Co., Ltd. | Composition de resine polyacetal et procede de production correspondant |
JP3797852B2 (ja) | 2000-07-26 | 2006-07-19 | 大塚化学ホールディングス株式会社 | 消臭剤組成物、及び消臭性接着剤 |
KR100513868B1 (ko) * | 2002-02-25 | 2005-09-09 | 한국엔지니어링플라스틱 주식회사 | 우수한 내마모성 및 박리방지효과를 갖는 폴리아세탈 수지조성물 |
JP4357930B2 (ja) * | 2002-11-08 | 2009-11-04 | 旭化成ケミカルズ株式会社 | 添加剤を含有する熱可塑性樹脂ペレットの製造方法 |
JP5283822B2 (ja) * | 2003-10-01 | 2013-09-04 | ポリプラスチックス株式会社 | ポリアセタール樹脂組成物 |
JP2005112995A (ja) * | 2003-10-07 | 2005-04-28 | Polyplastics Co | ポリアセタール樹脂組成物及びその成形品 |
JP4516301B2 (ja) * | 2003-11-10 | 2010-08-04 | ポリプラスチックス株式会社 | ポリアセタール樹脂組成物 |
JP4568018B2 (ja) | 2004-04-30 | 2010-10-27 | ポリプラスチックス株式会社 | 消臭剤及び樹脂組成物 |
KR101177338B1 (ko) | 2004-09-17 | 2012-08-30 | 미츠비시 가스 가가쿠 가부시키가이샤 | 폴리아세탈 수지 조성물 |
WO2008066663A2 (en) * | 2006-11-22 | 2008-06-05 | E. I. Du Pont De Nemours And Company | Static dissipative polyacetal compositions |
EP2240537B1 (de) * | 2008-02-06 | 2012-04-25 | Basf Se | Beschichtete polyoxymethylene |
BRPI0908779A2 (pt) * | 2008-02-13 | 2015-07-28 | Basf Se | Peça moldada de polioximetileno revestido, e, processo para a produção da mesma |
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- 2009-01-20 JP JP2010543472A patent/JP5535086B2/ja active Active
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Publication number | Publication date |
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EP2235092B1 (de) | 2012-03-14 |
KR101722266B1 (ko) | 2017-03-31 |
BRPI0907432A2 (pt) | 2019-09-24 |
ATE549368T1 (de) | 2012-03-15 |
ES2381571T3 (es) | 2012-05-29 |
CN101925637B (zh) | 2012-11-21 |
US8440300B2 (en) | 2013-05-14 |
CN101925637A (zh) | 2010-12-22 |
EP2235092A1 (de) | 2010-10-06 |
KR20100105780A (ko) | 2010-09-29 |
WO2009092698A1 (de) | 2009-07-30 |
JP2011510145A (ja) | 2011-03-31 |
US20100291389A1 (en) | 2010-11-18 |
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