JP5523556B2 - フラッシュ火災およびアーク防護を改善するためのアンチモン含有量を限定したモダクリル/アラミド混紡品およびアンチモン無含有のモダクリル/アラミド混紡品 - Google Patents
フラッシュ火災およびアーク防護を改善するためのアンチモン含有量を限定したモダクリル/アラミド混紡品およびアンチモン無含有のモダクリル/アラミド混紡品 Download PDFInfo
- Publication number
- JP5523556B2 JP5523556B2 JP2012514071A JP2012514071A JP5523556B2 JP 5523556 B2 JP5523556 B2 JP 5523556B2 JP 2012514071 A JP2012514071 A JP 2012514071A JP 2012514071 A JP2012514071 A JP 2012514071A JP 5523556 B2 JP5523556 B2 JP 5523556B2
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- Prior art keywords
- fabric
- modacrylic
- fibers
- fiber
- antimony
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 229920002821 Modacrylic Polymers 0.000 title claims description 69
- 239000004760 aramid Substances 0.000 title claims description 54
- 229910052787 antimony Inorganic materials 0.000 title claims description 41
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 title claims description 41
- 229920003235 aromatic polyamide Polymers 0.000 title description 39
- 239000000203 mixture Substances 0.000 title description 19
- 239000004744 fabric Substances 0.000 claims description 149
- 239000000835 fiber Substances 0.000 claims description 145
- 229920006231 aramid fiber Polymers 0.000 claims description 47
- 238000000034 method Methods 0.000 description 16
- 230000001681 protective effect Effects 0.000 description 13
- 238000012360 testing method Methods 0.000 description 11
- 229920001778 nylon Polymers 0.000 description 9
- 238000003763 carbonization Methods 0.000 description 6
- 229920001577 copolymer Polymers 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 229920000642 polymer Polymers 0.000 description 6
- 239000002356 single layer Substances 0.000 description 6
- 229920000784 Nomex Polymers 0.000 description 5
- 150000001463 antimony compounds Chemical class 0.000 description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 5
- 230000006872 improvement Effects 0.000 description 5
- 239000004763 nomex Substances 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- 239000001301 oxygen Substances 0.000 description 5
- 238000009987 spinning Methods 0.000 description 5
- 238000007655 standard test method Methods 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 230000007613 environmental effect Effects 0.000 description 4
- 239000000178 monomer Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 3
- 229920003368 Kevlar® 29 Polymers 0.000 description 3
- 239000004677 Nylon Substances 0.000 description 3
- 238000001069 Raman spectroscopy Methods 0.000 description 3
- CZBZUDVBLSSABA-UHFFFAOYSA-N butylated hydroxyanisole Chemical compound COC1=CC=C(O)C(C(C)(C)C)=C1.COC1=CC=C(O)C=C1C(C)(C)C CZBZUDVBLSSABA-UHFFFAOYSA-N 0.000 description 3
- 239000000975 dye Substances 0.000 description 3
- 238000004043 dyeing Methods 0.000 description 3
- 238000010891 electric arc Methods 0.000 description 3
- 230000004907 flux Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000010998 test method Methods 0.000 description 3
- 239000004753 textile Substances 0.000 description 3
- 238000012546 transfer Methods 0.000 description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 3
- 229920002554 vinyl polymer Polymers 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- 238000009941 weaving Methods 0.000 description 3
- -1 yarns Substances 0.000 description 3
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 2
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 229940058905 antimony compound for treatment of leishmaniasis and trypanosomiasis Drugs 0.000 description 2
- 229910000410 antimony oxide Inorganic materials 0.000 description 2
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 238000009954 braiding Methods 0.000 description 2
- 238000011088 calibration curve Methods 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 2
- 239000000969 carrier Substances 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 150000004985 diamines Chemical class 0.000 description 2
- 239000003063 flame retardant Substances 0.000 description 2
- 230000009477 glass transition Effects 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- 238000009940 knitting Methods 0.000 description 2
- 239000010410 layer Substances 0.000 description 2
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical class [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000011241 protective layer Substances 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 239000002759 woven fabric Substances 0.000 description 2
- SXZSFWHOSHAKMN-UHFFFAOYSA-N 2,3,4,4',5-Pentachlorobiphenyl Chemical compound C1=CC(Cl)=CC=C1C1=CC(Cl)=C(Cl)C(Cl)=C1Cl SXZSFWHOSHAKMN-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical compound CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- 239000004953 Aliphatic polyamide Substances 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 238000005079 FT-Raman Methods 0.000 description 1
- 241000282412 Homo Species 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 229920001328 Polyvinylidene chloride Polymers 0.000 description 1
- 238000003841 Raman measurement Methods 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 238000000333 X-ray scattering Methods 0.000 description 1
- 238000002679 ablation Methods 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 229920003231 aliphatic polyamide Polymers 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000008378 aryl ethers Chemical class 0.000 description 1
- 239000000981 basic dye Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- QGGZBXOADPVUPN-UHFFFAOYSA-N beta-phenylpropiophenone Natural products C=1C=CC=CC=1C(=O)CCC1=CC=CC=C1 QGGZBXOADPVUPN-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- INLLPKCGLOXCIV-UHFFFAOYSA-N bromoethene Chemical compound BrC=C INLLPKCGLOXCIV-UHFFFAOYSA-N 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 238000012993 chemical processing Methods 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010411 cooking Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000001739 density measurement Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000004993 emission spectroscopy Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- QZUPTXGVPYNUIT-UHFFFAOYSA-N isophthalamide Chemical compound NC(=O)C1=CC=CC(C(N)=O)=C1 QZUPTXGVPYNUIT-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000011344 liquid material Substances 0.000 description 1
- 231100000647 material safety data sheet Toxicity 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920000889 poly(m-phenylene isophthalamide) Polymers 0.000 description 1
- 229920003366 poly(p-phenylene terephthalamide) Polymers 0.000 description 1
- 239000005033 polyvinylidene chloride Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 238000007378 ring spinning Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000000790 scattering method Methods 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- MHSKRLJMQQNJNC-UHFFFAOYSA-N terephthalamide Chemical compound NC(=O)C1=CC=C(C(N)=O)C=C1 MHSKRLJMQQNJNC-UHFFFAOYSA-N 0.000 description 1
- 230000008646 thermal stress Effects 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- AYEKOFBPNLCAJY-UHFFFAOYSA-O thiamine pyrophosphate Chemical compound CC1=C(CCOP(O)(=O)OP(O)(O)=O)SC=[N+]1CC1=CN=C(C)N=C1N AYEKOFBPNLCAJY-UHFFFAOYSA-O 0.000 description 1
- 229910021642 ultra pure water Inorganic materials 0.000 description 1
- 239000012498 ultrapure water Substances 0.000 description 1
- 239000011800 void material Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/44—Yarns or threads characterised by the purpose for which they are designed
- D02G3/443—Heat-resistant, fireproof or flame-retardant yarns or threads
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D13/00—Professional, industrial or sporting protective garments, e.g. surgeons' gowns or garments protecting against blows or punches
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D31/00—Materials specially adapted for outerwear
- A41D31/04—Materials specially adapted for outerwear characterised by special function or use
- A41D31/08—Heat resistant; Fire retardant
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/07—Addition of substances to the spinning solution or to the melt for making fire- or flame-proof filaments
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/09—Addition of substances to the spinning solution or to the melt for making electroconductive or anti-static filaments
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/12—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyamide as constituent
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
- D02G3/04—Blended or other yarns or threads containing components made from different materials
- D02G3/047—Blended or other yarns or threads containing components made from different materials including aramid fibres
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/20—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
- D03D15/283—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads synthetic polymer-based, e.g. polyamide or polyester fibres
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/40—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads
- D03D15/47—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads multicomponent, e.g. blended yarns or threads
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/50—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
- D03D15/513—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads heat-resistant or fireproof
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/50—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
- D03D15/533—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads antistatic; electrically conductive
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2321/00—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D10B2321/10—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polymers of unsaturated nitriles, e.g. polyacrylonitrile, polyvinylidene cyanide
- D10B2321/101—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polymers of unsaturated nitriles, e.g. polyacrylonitrile, polyvinylidene cyanide modacrylic
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/02—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
- D10B2331/021—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides aromatic polyamides, e.g. aramides
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/16—Physical properties antistatic; conductive
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2501/00—Wearing apparel
- D10B2501/04—Outerwear; Protective garments
Description
布帛の摩耗性能は、ASTM D−3884−01「Standard Guide for Abrasion Resistance of Textile Fabrics(Rotary Platform,Double Head Method)」に従い測定する。
本実施例は、アンチモン無含有のモダクリル繊維を使用することで布帛のアーク等級が驚くほど増大することを例示する。経糸および緯糸の両方にNomex(登録商標)type300繊維、Kevlar(登録商標)29繊維、およびアンチモン無含有のモダクリル繊維の緊密な混紡品の空気紡績糸を有する耐久性アークおよび熱防護布帛(品目1)を製造する。Nomex(登録商標)type300は、33〜37%の結晶化度を有するポリ(m−フェニレンイソフタルアミド)(MPD−I)である。モダクリル繊維は、アンチモンが全く測定されないACN/ポリ塩化ビニリデンコポリマー繊維(Kenekaにより作製されるModacrylic SEとして市販されていることが周知)である。Kevlar(登録商標)29繊維は、ポリ(p−フェニレンテレフタルアミド)(PPD−T)繊維である。
3種の異なるモダクリル繊維を使用し糸の混紡品にナイロン繊維も含んだことを除いて、実施例1の全体的な手順を繰り返し、3種の異なる布帛および衣服を作製し、試験する。品目2は、1.2%という低いアンチモン含有量のモダクリル繊維(Fushun Rayva Fiber Company,Wanghua District,Fushun,Chinaが製造)を含有する。品目Bは、9.9%のアンチモン含有量を有するモダクリル繊維(Protex(登録商標)Cとして市販されていることが周知)を含有する。品目Cは、4.1%のアンチモン含有量を有するモダクリル繊維(Protex(登録商標)Mとして市販されていることが周知)を含有する。繊維構成およびアーク試験性能を表2に示す。
2重量パーセントのNomex(登録商標)メタ系アラミド繊維をP140として市販されていることが周知の炭素芯/ナイロン鞘繊維である帯電防止繊維に置き換えることを除いて、実施例1および2を繰り返す。結果として得られる布帛を実施例1および2と同様な予測される性能を有する単層防護カバーオールに変換する。
次に、本発明の好ましい態様を示す。
1. アラミド繊維およびモダクリル繊維を含むアークおよび火炎防護に使用するための糸であって、前記モダクリル繊維が1.5パーセント未満のアンチモンを有する糸。
2. 前記モダクリル繊維が、1パーセント未満のアンチモンを有する上記1に記載の糸。
3. 前記モダクリル繊維がアンチモン無含有である上記2に記載の糸。
4. さらに帯電防止繊維を含む上記3に記載の糸。
5. (a)少なくとも20%の結晶化度を有するメタ系アラミド繊維50〜80重量パーセント
(b)モダクリル繊維10〜40重量パーセント、
(c)パラ系アラミド繊維5〜20重量パーセント、および
(d)帯電防止繊維1〜3重量パーセント、
から基本的になり、前記百分率が、成分(a)、(b)、(c)、および(d)を基準とする上記3に記載の糸。
6. アラミド繊維とモダクリル繊維を含むアークおよび火炎防護に使用するのに適した布帛であって、前記モダクリル繊維が、1.5パーセント未満のアンチモンを有し、前記布帛が、135〜407グラム毎平方メートル(4.0〜12オンス毎平方ヤード)の目付を有する布帛。
7. 前記モダクリル繊維が、1パーセント未満のアンチモンを有する上記6に記載の布帛。
8. 前記モダクリル繊維が、アンチモン無含有である上記6に記載の布帛。
9. 帯電防止繊維をさらに含む上記8に記載の布帛。
10. (a)少なくとも20%の結晶化度を有するメタ系アラミド繊維50〜80重量パーセント、
(b)モダクリル繊維10〜40重量パーセント、
(c)パラ系アラミド繊維5〜20重量パーセント、および
(d)帯電防止繊維1〜3重量パーセント、
から基本的になる糸を含み、前記百分率が、成分(a)、(b)、(c)、および(d)を基準とし、150〜290グラム毎平方メートル(4.5〜8.5オンス毎平方ヤード)の目付を有する上記8に記載の布帛。
11. 布帛の平方ヤード当り少なくとも1.5カロリー毎平方センチメートル毎オンスのASTM F−1959−99に準拠する耐アーク性を有する上記8に記載の布帛。
12. ナイロン繊維をさらに含む上記8に記載の布帛。
13. 布帛の平方ヤード当り少なくとも1.7カロリー毎平方センチメートル毎オンスのASTM F−1959−99に準拠する耐アーク性を有する上記12に記載の布帛。
14. ASTM F1930に準拠する4秒間の火炎暴露による体の火傷が65%未満に相当する熱防護を提供すると同時に、ASTM F1959およびNFPA 70Eに準拠するカテゴリー2のアーク等級を維持する上記11に記載の布帛を含む衣服。
15. ASTM F1930に準拠する4秒間の火炎暴露による体の火傷が65%未満に相当する熱防護を提供すると同時に、ASTM F1959およびNFPA 70Eに準拠するカテゴリー2のアーク等級を維持する上記13に記載の布帛を含む衣服。
Claims (5)
- アラミド繊維およびモダクリル繊維を含むアークおよび火炎防護に使用するための糸であって、前記モダクリル繊維が1.5パーセント未満のアンチモンを有する糸。
- アラミド繊維とモダクリル繊維を含むアークおよび火炎防護に使用するのに適した布帛であって、前記モダクリル繊維が、1.5パーセント未満のアンチモンを有し、前記布帛が、135〜407グラム毎平方メートル(4.0〜12オンス毎平方ヤード)の目付を有する布帛。
- 前記モダクリル繊維が、アンチモン無含有である請求項2に記載の布帛。
- 布帛の平方ヤード当り少なくとも1.5カロリー毎平方センチメートル毎オンスのASTM F−1959−99に準拠する耐アーク性を有する請求項3に記載の布帛。
- ASTM F1930に準拠する4秒間の火炎暴露による体の火傷が65%未満に相当する熱防護を提供すると同時に、ASTM F1959およびNFPA 70Eに準拠するカテゴリー2のアーク等級を維持する請求項4に記載の布帛を含む衣服。
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US12/476,595 | 2009-06-02 | ||
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Families Citing this family (27)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8069642B2 (en) * | 2009-06-02 | 2011-12-06 | E.I. Du Pont De Nemours And Company | Crystallized meta-aramid blends for improved flash fire and superior arc protection |
US20130118635A1 (en) * | 2009-12-14 | 2013-05-16 | International Global Trading Usa, Inc. | Flame, Heat and Electric Arc Protective Yarn and Fabric |
US20110138523A1 (en) * | 2009-12-14 | 2011-06-16 | Layson Jr Hoyt M | Flame, Heat and Electric Arc Protective Yarn and Fabric |
US9885128B2 (en) | 2011-05-13 | 2018-02-06 | Milliken & Company | Energy-absorbing textile material |
EP2762618B1 (en) * | 2011-09-26 | 2016-08-31 | Kaneka Corporation | Flameproof spun yarn, fabric, clothes and flameproof work clothes |
US8695319B2 (en) * | 2011-12-05 | 2014-04-15 | E I Du Pont De Nemours And Company | Yarns of polyoxadiazole and modacrylic fibers and fabrics and garments made therefrom and methods for making same |
US20140026303A1 (en) * | 2012-07-27 | 2014-01-30 | E I Du Pont De Nemours And Company | Fiber blends, yarns, fabrics, and garments for arc and flame protection |
CN104736750B (zh) * | 2012-07-27 | 2017-08-08 | 德里菲尔有限公司 | 具有洗涤持久的热性能和舒适性的纤维共混物 |
CN103352284B (zh) * | 2013-07-30 | 2015-07-29 | 上海特安纶纤维有限公司 | 一种具有多功能防护效用的纱线和由其制得的织物和成衣 |
US9926663B2 (en) | 2013-08-19 | 2018-03-27 | Milliken & Company | Treated textile material and process for producing the same |
US9732446B2 (en) * | 2013-11-04 | 2017-08-15 | E I Du Pont De Nemours And Company | Heat resistant outershell fabric |
AU2015224518B2 (en) * | 2014-07-15 | 2017-03-09 | Drifire, Llc | Lightweight, dual hazard fabrics |
BR112017013647B1 (pt) | 2015-01-06 | 2021-10-26 | Kaneka Corporation | Fibra acrílica resistente a arco, tecido para roupa protetora de arco, e roupa protetora de arco |
EP3385418B1 (en) | 2015-12-02 | 2021-07-14 | Teijin Limited | Fabric and protective product |
EP3425093B1 (en) | 2016-03-04 | 2023-04-26 | Kaneka Corporation | Fabric for electric-arc protective clothing, and electric-arc protective clothing |
CA2964708A1 (en) * | 2016-04-22 | 2017-10-22 | General Recycled | Protective fabric and process of manufacturing same |
AU2017281348C1 (en) | 2016-06-23 | 2021-07-01 | Southern Mills, Inc. | Flame resistant fabrics having fibers containing energy absorbing and/or reflecting additives |
US10253437B2 (en) * | 2016-09-01 | 2019-04-09 | E I Du Pont De Nemours And Company | Lightweight fabrics containing carbon-containing aramid fiber blend including modacrylic fiber |
CA3039312A1 (en) * | 2016-11-01 | 2018-05-11 | Teijin Limited | Fabric, method for manufacturing same, and fiber product |
US10612166B1 (en) | 2017-05-03 | 2020-04-07 | Waubridge Specialty Fabrics, Llc | Fire resistant fabric with stitchbonding |
JP6945082B2 (ja) * | 2018-02-08 | 2021-10-06 | サザンミルズ インコーポレイテッドSouthern Mills,Inc. | 溶融金属飛沫に対する防護用難燃性布地 |
JP7268056B2 (ja) | 2018-12-17 | 2023-05-02 | 帝人株式会社 | 布帛および防護製品 |
WO2020198668A1 (en) | 2019-03-28 | 2020-10-01 | Southern Mills, Inc. | Flame resistant fabrics |
KR102654523B1 (ko) * | 2019-09-10 | 2024-04-05 | 가부시키가이샤 가네카 | 난연성 섬유 복합체 및 난연성 작업복 |
US11946173B2 (en) * | 2020-05-20 | 2024-04-02 | Glen Raven, Inc. | Yarns and fabrics including modacrylic fibers |
US11773515B2 (en) * | 2021-02-19 | 2023-10-03 | New York Knitworks, Llc | Single, multi-effect, energy harvesting and heat managing spun yarn and manufacturing method thereof |
US11891731B2 (en) | 2021-08-10 | 2024-02-06 | Southern Mills, Inc. | Flame resistant fabrics |
Family Cites Families (32)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3094511A (en) | 1958-11-17 | 1963-06-18 | Du Pont | Wholly aromatic polyamides |
US3193602A (en) * | 1962-08-13 | 1965-07-06 | Monsanto Co | Process for the production of flame retarded acrylic fibers |
US3354127A (en) * | 1966-04-18 | 1967-11-21 | Du Pont | Aromatic copolyamides |
US3819587A (en) * | 1969-05-23 | 1974-06-25 | Du Pont | Wholly aromatic carbocyclic polycarbonamide fiber having orientation angle of less than about 45{20 |
US3673143A (en) * | 1970-06-24 | 1972-06-27 | Du Pont | Optically anisotropic spinning dopes of polycarbonamides |
US3869429A (en) * | 1971-08-17 | 1975-03-04 | Du Pont | High strength polyamide fibers and films |
US3748302A (en) | 1971-11-17 | 1973-07-24 | Du Pont | Flame-retarded acrylonitrile fibers |
US3803453A (en) * | 1972-07-21 | 1974-04-09 | Du Pont | Synthetic filament having antistatic properties |
JPS53294A (en) * | 1976-06-23 | 1978-01-05 | Teijin Ltd | Preparation of aromatic polyamide with high degree of polymerization |
DE3140274A1 (de) * | 1981-10-10 | 1983-04-28 | Bayer Ag, 5090 Leverkusen | Verfahren zur herstellung flammbestaendiger formkoerper aus polymeren |
US4612150A (en) * | 1983-11-28 | 1986-09-16 | E. I. Du Pont De Nemours And Company | Process for combining and codrawing antistatic filaments with undrawn nylon filaments |
US5208105A (en) * | 1984-10-05 | 1993-05-04 | Kanegafuchi Kagaku Kogyo Kabushiki Kaisha | Flame-retarded composite fiber |
DE3587745T2 (de) * | 1984-10-05 | 1994-05-19 | Kanegafuchi Chemical Ind | Flammverzögerndes Fasergemisch. |
US4668234A (en) * | 1985-08-15 | 1987-05-26 | E. I. Du Pont De Nemours And Company | Aromatic polyamide fibers and process for stabilizing such fibers with surfactants |
US4755335A (en) * | 1986-09-12 | 1988-07-05 | E. I. Du Pont De Nemours And Company | Method of improving impregnation of poly (meta-phenylene isophthalamide) fibers |
JPS63126913A (ja) * | 1986-11-17 | 1988-05-30 | Mitsubishi Rayon Co Ltd | 耐光性、透明性に優れた高難燃化アクリル繊維およびその製造法 |
US4883496A (en) * | 1988-02-14 | 1989-11-28 | E. I. Du Pont De Nemours And Company | Process for dyeing crystalline aromatic polyamide fibers with water-insoluble dyes |
GB8921636D0 (en) * | 1989-09-25 | 1989-11-08 | Universal Carbon Fibres Limite | Fabric |
US5096459A (en) * | 1990-09-26 | 1992-03-17 | E. I. Du Pont De Nemours And Company | Method of dyeing aromatic polyamide fibers with water-soluble dyes |
JPH05321145A (ja) * | 1992-05-12 | 1993-12-07 | Asahi Chem Ind Co Ltd | 耐光堅牢度の優れたアクリル系繊維の製造方法 |
US6489256B1 (en) | 1997-09-26 | 2002-12-03 | George M. Kent | Fire escape blanket and other melamine resin containing compositions and products with fire blocking properties |
US6410140B1 (en) * | 1999-09-28 | 2002-06-25 | Basf Corporation | Fire resistant corespun yarn and fabric comprising same |
JP3690283B2 (ja) * | 2001-01-18 | 2005-08-31 | 日産自動車株式会社 | 車線追従制御装置 |
US6787228B2 (en) * | 2001-05-09 | 2004-09-07 | Glen Raven, Inc. | Flame-resistant and high visibility fabric and apparel formed therefrom |
US20050025963A1 (en) * | 2003-07-28 | 2005-02-03 | Reiyao Zhu | Flame retardant fiber blends comprising modacrylic fibers and fabrics and garments made therefrom |
US20050032449A1 (en) * | 2003-08-06 | 2005-02-10 | Lovasic Susan L. | Lightweight protective apparel |
US7348059B2 (en) * | 2004-03-18 | 2008-03-25 | E. I. Du Pont De Nemours And Company | Modacrylic/aramid fiber blends for arc and flame protection and reduced shrinkage |
US20050208855A1 (en) * | 2004-03-18 | 2005-09-22 | Reiyao Zhu | Modacrylic/cotton/aramid fiber blends for arc and flame protection |
US7065950B2 (en) * | 2004-03-18 | 2006-06-27 | E. I. Du Pont De Nemours And Company | Modacrylic/aramid fiber blends for arc and flame protection |
US20060116043A1 (en) * | 2004-11-30 | 2006-06-01 | Doug Hope | Flame resistant fiber blend and fabrics made therefrom |
US7537831B2 (en) | 2007-08-22 | 2009-05-26 | E.I. Du Pont De Nemours And Company | Flame resistant spun staple yarns made from blends of fibers derived from diamino diphenyl sulfone and modacrylic fibers and fabrics and garments made therefrom and methods for making same |
US7744999B2 (en) * | 2008-07-11 | 2010-06-29 | E. I. Du Pont De Nemours And Company | Crystallized meta-aramid blends for improved flash fire and arc protection |
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US20100299817A1 (en) | 2010-12-02 |
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EP2438222B1 (en) | 2013-11-06 |
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