JP5483724B2 - 両面粘着シート - Google Patents
両面粘着シート Download PDFInfo
- Publication number
- JP5483724B2 JP5483724B2 JP2010205422A JP2010205422A JP5483724B2 JP 5483724 B2 JP5483724 B2 JP 5483724B2 JP 2010205422 A JP2010205422 A JP 2010205422A JP 2010205422 A JP2010205422 A JP 2010205422A JP 5483724 B2 JP5483724 B2 JP 5483724B2
- Authority
- JP
- Japan
- Prior art keywords
- sensitive adhesive
- meth
- adhesive sheet
- pressure
- film
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- RUELTTOHQODFPA-UHFFFAOYSA-N toluene 2,6-diisocyanate Chemical compound CC1=C(N=C=O)C=CC=C1N=C=O RUELTTOHQODFPA-UHFFFAOYSA-N 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
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- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
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Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/29—Laminated material
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J201/00—Adhesives based on unspecified macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/22—Plastics; Metallised plastics
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
- C09J7/38—Pressure-sensitive adhesives [PSA]
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2203/00—Applications of adhesives in processes or use of adhesives in the form of films or foils
- C09J2203/318—Applications of adhesives in processes or use of adhesives in the form of films or foils for the production of liquid crystal displays
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
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- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
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- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
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- Adhesives Or Adhesive Processes (AREA)
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Description
本発明の両面粘着シートの導電性フィルムは、少なくとも一方の表面の表面抵抗率が500Ω/□以下であるフィルムである。導電性フィルムは、電磁波をシールドする役割を果たし、さらに機械的強度を担う芯材の役割を果たす。
本発明の両面粘着シートにおいて、粘着剤層は、被着体に対して良好な接着性を発揮し、さらに粘着シートの全光線透過率が80%以上となり、且つヘイズが5%以下となる限り、特に制限されない。また、本発明の両面粘着シートにおいて、両方の粘着剤層の組成は同じであってもよいし、異なっていてもよい。なお、本発明の両面粘着シートでは、導電性フィルムの導電層上に粘着剤層を有していてもよい。
一般式(1):−R1−O−
(式中、R1はアルキレン基である)
本発明の両面粘着シートの粘着剤層表面(粘着面)は、使用時までは剥離ライナー(セパレータ)により保護されていてもよい。なお、粘着シートの各粘着面は、2枚の剥離ライナーによりそれぞれ保護されていてもよいし、両面が剥離面となっている剥離ライナー1枚により、ロール状に巻回される形態で保護されていてもよい。剥離ライナーは粘着剤層の保護材として用いられており、被着体に貼着する際に剥がされる。なお、剥離ライナーは必ずしも設けられていなくてもよい。
アクリル酸ブチル:95重量部、アクリル酸:5重量部、及びアゾビスイソブチロニトリル:0.4重量部を、酢酸エチル100重量部に溶解させ、攪拌下に60℃で反応させて、アクリル系ポリマー溶液を得た。
該アクリル系ポリマー溶液に、イソシアネート系架橋剤(商品名「コロネートL、日本ポリウレタン工業株式会社製」を3重量部(固形分換算)配合し、粘着剤組成物(溶剤型の粘着剤組成物)とした。
該粘着剤組成物を、セパレーター(剥離ライナー)上に塗布して、加熱乾燥し、粘着剤層の厚みが25μmのアクリル系粘着シート(粘着剤層/セパレーターの構成)を得た。
導電性フィルムとして、透明導電性フィルム(ITO蒸着フィルム、商品名「エレクリスタ V270L−TFMP」、日東電工株式会社製、厚み:180μm)を用いた。
この導電性フィルムの両面に前記のアクリル系粘着シートを各々貼り合わせて、両面粘着シート(セパレーター/粘着剤層(厚み:25μm)/導電性フィルム(厚み:180μm)/粘着剤層(厚み:25μm)/セパレーターの構成)を作製した。
導電性フィルムとして、透明導電性フィルム(ITO蒸着フィルム、商品名「エレクリスタ V270L−THMP」、日東電工株式会社製、厚み:180μm)を用いた。
この導電性フィルムの両面に前記のアクリル系粘着シートを各々貼り合わせて、両面粘着シート(セパレーター/粘着剤層(厚み:25μm)/導電性フィルム(厚み:180μm)/粘着剤層(厚み:25μm)/セパレーターの構成)を作製した。
各実施例について、用いたフィルムの表面抵抗率、粘着シートの全光線透過率及びヘイズ、粘着シートのシールド効果を測定した。そして、その測定結果を表1に示した。
実施例で用いたフィルム表面において、JIS K 6911に記載されている二重リング電極法に準じて、表面抵抗率を測定した。抵抗値の測定には、抵抗率計(装置名「ハイレスタUP MCP−HT450型」、三菱化学アナリテック社製)を使用した。なお、測定はフィルムの両面について行い、表面抵抗率の低い方の値をフィルムの表面抵抗率とした。
両面粘着シートを、一方のセパレーターを除き、スライドガラス(松浪硝子工業社製、商品名「S−1111」、全光線透過率91.8%、ヘイズ0.4%)に貼り合わせ、その後もう一方のセパレーターを除き、試験片[(粘着シート)/(スライドガラス)の構成]とした。
該試験片の全光線透過率及びヘイズを、ヘイズメータ(「村上色彩技術研究所製、商品名「HM−150」)を用いて測定した。
粘着シートのシールド効果は、シールド効果測定装置(装置名「TR−17301」、ADVANTEST社製)を用いて測定した。なお、シールド効果は、粘着シートの両側のセパレーターを剥離して除いてから、行った。
11 カバーガラス
12 粘着シート
13 ITOガラス基板
131 ITO膜
132 ガラス板
14 液晶ディスプレイ
15 印刷部
Claims (3)
- 少なくとも一方の表面の表面抵抗率が500Ω/□以下の導電性フィルムの両面側に粘着剤層を有し、全光線透過率が80%以上であり、ヘイズが5%以下であることを特徴とする光学部材の貼り合わせに用いられる両面粘着シート。
- 前記導電性フィルムが、導電層及びフィルム基材層により構成されている請求項1記載の両面粘着シート。
- 厚さが、3〜2000μmである請求項1又は2記載の両面粘着シート。
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2010205422A JP5483724B2 (ja) | 2010-09-14 | 2010-09-14 | 両面粘着シート |
US13/231,666 US20120064325A1 (en) | 2010-09-14 | 2011-09-13 | Double-sided pressure-sensitive adhesive sheet |
TW100133078A TW201217489A (en) | 2010-09-14 | 2011-09-14 | Double-sided pressure-sensitive adhesive sheet |
KR1020110092406A KR20120028276A (ko) | 2010-09-14 | 2011-09-14 | 양면 감압 접착 시트 |
CN2011102815060A CN102399508A (zh) | 2010-09-14 | 2011-09-14 | 双面压敏胶粘片 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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JP2010205422A JP5483724B2 (ja) | 2010-09-14 | 2010-09-14 | 両面粘着シート |
Publications (2)
Publication Number | Publication Date |
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JP2012062342A JP2012062342A (ja) | 2012-03-29 |
JP5483724B2 true JP5483724B2 (ja) | 2014-05-07 |
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JP2010205422A Active JP5483724B2 (ja) | 2010-09-14 | 2010-09-14 | 両面粘着シート |
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US (1) | US20120064325A1 (ja) |
JP (1) | JP5483724B2 (ja) |
KR (1) | KR20120028276A (ja) |
CN (1) | CN102399508A (ja) |
TW (1) | TW201217489A (ja) |
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JP5845611B2 (ja) * | 2011-04-11 | 2016-01-20 | 王子ホールディングス株式会社 | 両面粘着シート |
JP2013104028A (ja) * | 2011-11-15 | 2013-05-30 | Oji Holdings Corp | 光学部材用両面粘着シートおよび積層体 |
JP5896692B2 (ja) * | 2011-11-16 | 2016-03-30 | 日東電工株式会社 | 入力表示装置 |
CN103123547A (zh) * | 2011-11-16 | 2013-05-29 | 宸鸿科技(厦门)有限公司 | 光学面板的堆叠结构及其制造方法 |
TW201438027A (zh) * | 2013-03-22 | 2014-10-01 | Eturbo Touch Technology Inc | 觸控面板用之感光硬化導電膠 |
JP2014218624A (ja) * | 2013-05-10 | 2014-11-20 | 王子ホールディングス株式会社 | 比誘電率調整方法及び積層粘着シート |
US20180093451A1 (en) * | 2015-04-08 | 2018-04-05 | Nitto Denko Corporation | Sheet, moisture-proof method of adherend using the sheet and corrosion-proof method of metal plate using the sheet |
KR101686614B1 (ko) | 2015-04-27 | 2016-12-15 | 동국대학교 산학협력단 | 리튬 코발트 산화물의 표면처리 방법 및 이를 포함하는 리튬이차전지 |
CN106908988A (zh) * | 2016-01-04 | 2017-06-30 | 宁波长阳科技股份有限公司 | 一种液晶显示器的背光组件 |
CN109862739B (zh) * | 2019-03-27 | 2020-11-03 | 维沃移动通信有限公司 | 一种终端 |
US11635860B2 (en) * | 2020-01-02 | 2023-04-25 | Dongwoo Fine-Chem Co., Ltd. | Touch sensor panel |
KR20220153628A (ko) * | 2020-03-25 | 2022-11-18 | 플렉스콘 컴퍼니 인코포레이티드 | 등방성 비수성 전극 감지 물질 |
JP2023032966A (ja) * | 2021-08-27 | 2023-03-09 | 日東電工株式会社 | 積層体 |
JP2023032965A (ja) * | 2021-08-27 | 2023-03-09 | 日東電工株式会社 | 積層体 |
CN115494978A (zh) * | 2022-09-23 | 2022-12-20 | 武汉华星光电半导体显示技术有限公司 | 触控显示装置及其制造方法 |
CN117551405B (zh) * | 2024-01-11 | 2024-04-30 | 宁波长阳科技股份有限公司 | 一种导电聚丙烯酸酯压敏胶及其制备方法 |
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US5716669A (en) * | 1997-03-26 | 1998-02-10 | Avery Dennison Corporation | Process for producing polymer films from aqueous polymer compositions |
JP2001341239A (ja) * | 2000-06-05 | 2001-12-11 | Kyodo Giken Kagaku Kk | 帯電防止フィルム及び該帯電防止フィルムを用いた粘着テープ又はシート用剥離フィルム並びに粘着テープ又はシート |
JP2008088395A (ja) * | 2006-09-07 | 2008-04-17 | Sekisui Chem Co Ltd | 移動体通信端末用両面粘着シート、及び、移動体通信端末 |
JP2009084399A (ja) * | 2007-09-28 | 2009-04-23 | Gunze Ltd | 近赤外線吸収性粘着剤組成物及び多層光学フィルム |
JP4813509B2 (ja) * | 2008-03-13 | 2011-11-09 | 日東電工株式会社 | 両面粘着シートとその製造方法及びプラスチックフィルムの固定方法 |
JP5591477B2 (ja) * | 2008-03-13 | 2014-09-17 | 日東電工株式会社 | 光学部材用粘着剤組成物、光学部材用粘着剤層、粘着型光学部材、透明導電性積層体、タッチパネルおよび画像表示装置 |
US20100028564A1 (en) * | 2008-07-29 | 2010-02-04 | Ming Cheng | Antistatic optical constructions having optically-transmissive adhesives |
JP4800363B2 (ja) * | 2008-09-26 | 2011-10-26 | 日東電工株式会社 | 光学部材貼り合わせ用粘着シート |
DE102008061840A1 (de) * | 2008-12-15 | 2010-06-17 | Tesa Se | Haftklebemasse |
JP5277937B2 (ja) * | 2008-12-17 | 2013-08-28 | Dic株式会社 | 透明導電膜固定用両面粘着シート、透明導電膜積層体、タッチパネル装置 |
CN101775259A (zh) * | 2009-01-09 | 2010-07-14 | 3M创新有限公司 | 一种防静电的耐高温聚酰亚胺胶带 |
JP2010180367A (ja) * | 2009-02-06 | 2010-08-19 | Three M Innovative Properties Co | 再剥離性両面粘着シート |
JP5199917B2 (ja) * | 2009-02-25 | 2013-05-15 | 日東電工株式会社 | 粘着シートとその製造方法および粘着型機能性フィルム |
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US20120064325A1 (en) | 2012-03-15 |
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KR20120028276A (ko) | 2012-03-22 |
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