JP5441442B2 - エマルション組成物及びそれを用いた塗料、接着剤 - Google Patents
エマルション組成物及びそれを用いた塗料、接着剤 Download PDFInfo
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- JP5441442B2 JP5441442B2 JP2009045979A JP2009045979A JP5441442B2 JP 5441442 B2 JP5441442 B2 JP 5441442B2 JP 2009045979 A JP2009045979 A JP 2009045979A JP 2009045979 A JP2009045979 A JP 2009045979A JP 5441442 B2 JP5441442 B2 JP 5441442B2
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- emulsion
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- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 235000021374 legumes Nutrition 0.000 description 1
- TWNIBLMWSKIRAT-VFUOTHLCSA-N levoglucosan Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@H]2CO[C@@H]1O2 TWNIBLMWSKIRAT-VFUOTHLCSA-N 0.000 description 1
- 239000002609 medium Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
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- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
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- OMNKZBIFPJNNIO-UHFFFAOYSA-N n-(2-methyl-4-oxopentan-2-yl)prop-2-enamide Chemical compound CC(=O)CC(C)(C)NC(=O)C=C OMNKZBIFPJNNIO-UHFFFAOYSA-N 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- RQAKESSLMFZVMC-UHFFFAOYSA-N n-ethenylacetamide Chemical compound CC(=O)NC=C RQAKESSLMFZVMC-UHFFFAOYSA-N 0.000 description 1
- ZQXSMRAEXCEDJD-UHFFFAOYSA-N n-ethenylformamide Chemical compound C=CNC=O ZQXSMRAEXCEDJD-UHFFFAOYSA-N 0.000 description 1
- 125000003136 n-heptyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 1
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- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 229930014626 natural product Natural products 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 239000010502 orange oil Substances 0.000 description 1
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- 239000004584 polyacrylic acid Substances 0.000 description 1
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- 229920000069 polyphenylene sulfide Polymers 0.000 description 1
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- 235000015277 pork Nutrition 0.000 description 1
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- YOSXAXYCARLZTR-UHFFFAOYSA-N prop-2-enoyl isocyanate Chemical compound C=CC(=O)N=C=O YOSXAXYCARLZTR-UHFFFAOYSA-N 0.000 description 1
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Landscapes
- Paints Or Removers (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polyurethanes Or Polyureas (AREA)
Description
例えば、デコパージュなどの表面保護材料としては、ビニルアセテートのホモポリマー若しくはその部分加水分解物、またはビニルアセテートと、アクリル酸エステル、アクリル酸アミド、アクリル酸、メタクリル酸、メタクリル酸エステル、マレイン酸、マレイン酸無水物、フマル酸、から選ばれる一種または二種以上のモノマーとのコポリマー若しくはその部分加水分解物、を含むポリマー成分と少なくとも樹液、果実液、蜂蜜、糖類から選ばれる1種の添加剤とからなる皮膜形成性を有するエマルション組成物(特許文献1)が提案されている。このものは、エマルション組成物の増粘性を得るために添加剤をある程度配合する必要があり、コスト面、得られる皮膜の性能、例えば透明性や柔軟性、耐熱性などを低下させるという面で満足できるものではなかった。
すなわち、本発明によれば、下記に示すエマルション組成物及びこれを用いた塗料、接着剤が提供される。
また、本発明のエマルション組成物を用いることにより、高機能化された塗料や接着剤が得られるため、特に表面保護剤や接着シート類、ペンキなどの分野に好適に用いられる。
なお、ここで(メタ)アクリレートとは、アクリレート又はメタクリレートを意味し、(メタ)アクリル酸とは、アクリル酸又はメタクリル酸を意味する。
本発明の(B)成分は少なくとも(b1)キサンタンガム、(b2)タラガム、(b3)カラヤガムを含有するものである。
本発明において、(b1)成分として用いられるキサンタンガムは、トウモロコシのようなデンプンを細菌により発酵させて得られる水溶性の天然多糖類で、D‐グルコースがβ‐1,4結合した主鎖とこの主鎖のアンヒドログルコースにD‐マンノース、D‐グルクロン酸からなる側鎖が結合した構造を有する物質である。分子量200万ないし5000万程度のものが知られているが、本発明においては、いずれの分子量のものも用いることができる。
本発明においては、天然物をそのまま用いてもよいし、加水分解により得られる低分子量のものを用いてもよい。
本発明のエマルション組成物は、前記(A)成分と(B)成分、所望に応じて用いられるレベリング剤、消泡剤、防腐剤、防かび剤、他の増粘剤、分散剤、界面活性剤、耐水化剤、染料、顔料、充填剤、酸化防止剤、紫外線吸収剤などの各種添加剤を水性媒体に均一に混合又は溶解することで調製される。このとき、前記(B)成分の配合割合は、前記(A)成分に対し0.1質量%以上である。(B)成分がこの範囲より少ないと所望の増粘性やエマルション性能の向上効果を得ることが難しくなるので好ましくない。粘度コントロール性などの増粘性やエマルション性能向上及び透明性等の塗膜特性向上塗膜、さらには生産コスト面から(B)成分の好ましい配合割合は0.1〜0.4質量%の範囲である。
しかしながら、簡便で、しかも安定した効果が得られる点で、(b1)成分と(b2)成分と(b3)成分をあらかじめ混合し、この混合物を水に溶解して一度に水性媒体に加えるのが有利である
加熱温度としては、60〜90℃、好ましくは80〜85℃の範囲の温度が用いられる。この加熱により、粘度はいったん低下するが、これを室温例えば30℃以下に冷却すると、粘度は著しく増大する。単に室温下で混合しただけでも、従来のエマルション組成物を用いた場合に比べ、優れた粘度向上が認められるが、いったん80℃以上に加熱して、再度冷却すると、著しい増粘効果が奏される。
本発明の塗料は少なくとも前記(A)成分と(B)成分とを含有するものである。
本発明の接着剤は少なくとも前記(A)成分と(B)成分とを含有し、所望により他の補助成分を1種以上含有するものである。この場合、所望により用いられる補助成分としては、例えば、染料、顔料、充填剤、酸化防止剤、紫外線吸収剤、発泡剤、熱膨張性微小球、接着付与樹脂などが挙げられる。
イオン交換水100gに糊料組成物をイオン交換水の温度30℃で添加し、1000rpmで60分間撹拌し、エマルション組成物を調製し、エマルション組成物のB型粘度を測定した。なお、B型粘度の測定はB型粘度計(東京計器社製、No.4ローターを用い、回転速度30rpmで5分間で測定)を用い、25℃、85℃、及び85℃に加熱後、25℃まで冷却後の3点で測定した。
得られたガラス/フィルム積層品を、90℃の条件化で96時間および240時間放置した後、濁度をHaze Meter NDH2000(NIPPON DENSHOKU社製)にて測定した。その結果を表1に示す。
得られたガラス/フィルム積層品を、95%RH、50℃または60℃の条件化で96時間および240時間放置した後、濁度をHaze Meter NDH2000(NIPPON DENSHOKU社製)にて測定した。その結果を表1に示す。
得られたガラス/フィルム積層品のガラス転移温度(℃)を、DSC3200S(MAC SCIENCE社製)を用い、測定温度−50〜200℃、昇温速度10℃/分の条件下で測定した。その結果を表2に示す。
以上
〔添加剤〕
キサンタンガム48部とタラガム21部とカラヤガム21部、チラバゾール10部とを、蒸留水100mlに溶解し、60分間撹拌して添加剤調製した。
実施例2
実施例3
〔添加剤〕
キサンタンガム95部とタラガム2.5部とカラヤガム2.5部とを、蒸留水100mlに溶解し、60分間撹拌して添加剤調製した。
比較例1
比較例2
比較例3
比較例4
〔添加剤〕
キサンタンガム100部を、蒸留水100mlに溶解し、60分間撹拌して添加剤調製した。
比較例5
〔添加剤〕
タラガム100部を、蒸留水100mlに溶解し、60分間撹拌して添加剤調製した。
比較例6
〔添加剤〕
カラヤガム100部を、蒸留水100mlに溶解し、60分間撹拌して添加剤調製した。
Claims (5)
- (A)ポリエチレン、ポリプロピレン、エチレン−酢酸ビニル共重合体、エチレン−エチルアクリレート共重合体から選ばれるポリオレフィン系樹脂、又は該ポリオレフィン系樹脂の変性物、ポリ塩化ビニル、ポリウレタン、ポリエステル、ポリエステル共重合体、ポリアミド、ポリアミド共重合体、アルキルアクリレート系又はアルキルメタクリレート系の単独重合体またはアルキルアクリレート又はアルキルメタクリレートと他のビニルモノマーとの共重合体の単独又は二種以上の混合物、ポリビニルアセテート、ビニルアセテートとそれと共重合可能なモノマーとの共重合体から選ばれる塗膜形成性を有するエマルション及び(B)添加剤を含有するエマルション組成物であって、該(B)成分の配合割合は、該(A)成分に対し0.1質量%以上であり、かつ該(B)成分は(b1)キサンタンガム、(b2)タラガム、(b3)カラヤガムとを質量比で(b1):(b2)+(b3)が99〜60:1〜40、(b2):(b3)が1:1〜10:1の範囲で含有することを特徴とするエマルション組成物。
- (B)添加剤が(A)エマルションに対し0.2〜0.4質量%配合することを特徴とする請求項1に記載のエマルション組成物。
- 請求項1又は2に記載のエマルション組成物を用いたことを特徴とする塗料。
- (A)成分がエマルション型接着剤であることを特徴とする請求項1又は2に記載のエマルション組成物。
- 請求項4に記載のエマルション組成物を用いたことを特徴とする接着剤。
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