JP5437193B2 - 軽油組成物 - Google Patents
軽油組成物Info
- Publication number
- JP5437193B2 JP5437193B2 JP2010173881A JP2010173881A JP5437193B2 JP 5437193 B2 JP5437193 B2 JP 5437193B2 JP 2010173881 A JP2010173881 A JP 2010173881A JP 2010173881 A JP2010173881 A JP 2010173881A JP 5437193 B2 JP5437193 B2 JP 5437193B2
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- JP
- Japan
- Prior art keywords
- light oil
- oil composition
- gas oil
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- fraction
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000203 mixture Substances 0.000 title claims description 55
- 238000004821 distillation Methods 0.000 claims description 38
- 239000011593 sulfur Substances 0.000 claims description 20
- 229910052717 sulfur Inorganic materials 0.000 claims description 20
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 19
- 239000000463 material Substances 0.000 claims description 19
- 125000003118 aryl group Chemical group 0.000 claims description 9
- 238000004523 catalytic cracking Methods 0.000 claims description 8
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims description 7
- 230000003009 desulfurizing effect Effects 0.000 claims description 5
- 230000003197 catalytic effect Effects 0.000 claims description 3
- 239000012530 fluid Substances 0.000 claims description 2
- 239000003921 oil Substances 0.000 description 108
- 235000019198 oils Nutrition 0.000 description 108
- 239000007789 gas Substances 0.000 description 46
- 239000000446 fuel Substances 0.000 description 34
- 239000013618 particulate matter Substances 0.000 description 18
- 239000003054 catalyst Substances 0.000 description 16
- 238000006477 desulfuration reaction Methods 0.000 description 13
- 230000023556 desulfurization Effects 0.000 description 13
- 239000003350 kerosene Substances 0.000 description 9
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 8
- 229910052739 hydrogen Inorganic materials 0.000 description 8
- 239000001257 hydrogen Substances 0.000 description 8
- 238000002156 mixing Methods 0.000 description 8
- 239000002994 raw material Substances 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 5
- 239000004071 soot Substances 0.000 description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- 230000002349 favourable effect Effects 0.000 description 4
- 238000005984 hydrogenation reaction Methods 0.000 description 4
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000010779 crude oil Substances 0.000 description 3
- 239000002283 diesel fuel Substances 0.000 description 3
- 238000004231 fluid catalytic cracking Methods 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- -1 silica Chemical class 0.000 description 3
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 238000004517 catalytic hydrocracking Methods 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 150000002894 organic compounds Chemical class 0.000 description 2
- 230000000737 periodic effect Effects 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 238000005292 vacuum distillation Methods 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- QZYDAIMOJUSSFT-UHFFFAOYSA-N [Co].[Ni].[Mo] Chemical compound [Co].[Ni].[Mo] QZYDAIMOJUSSFT-UHFFFAOYSA-N 0.000 description 1
- 230000002159 abnormal effect Effects 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 239000010775 animal oil Substances 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 229940064004 antiseptic throat preparations Drugs 0.000 description 1
- 239000002199 base oil Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 229910052792 caesium Inorganic materials 0.000 description 1
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- WHDPTDWLEKQKKX-UHFFFAOYSA-N cobalt molybdenum Chemical compound [Co].[Co].[Mo] WHDPTDWLEKQKKX-UHFFFAOYSA-N 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000002816 fuel additive Substances 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- DDTIGTPWGISMKL-UHFFFAOYSA-N molybdenum nickel Chemical compound [Ni].[Mo] DDTIGTPWGISMKL-UHFFFAOYSA-N 0.000 description 1
- MOWMLACGTDMJRV-UHFFFAOYSA-N nickel tungsten Chemical compound [Ni].[W] MOWMLACGTDMJRV-UHFFFAOYSA-N 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 229910052701 rubidium Inorganic materials 0.000 description 1
- IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 231100000241 scar Toxicity 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical class S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 1
- 229910052815 sulfur oxide Inorganic materials 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Description
(1)常圧蒸留装置から留出する90%留出温度が330〜345℃の直留軽油留分と、流動接触分解装置から得られる90%留出温度が320〜350℃の接触分解軽油留分とを容量割合で95:5〜80:20で混合したものを、脱硫処理して得られる脱硫軽油基材のみを軽油留分として含む軽油組成物であって、
(a)セタン価が50〜60、
(b)90%留出温度が282〜335.5℃、
(c)15℃密度が0.832〜0.840g/cm3、
(d)引火点が61℃以上、
(e)40℃動粘度が1.9〜4.1mm2/s、
(f)硫黄分が50質量ppm以下、
(g)全芳香族量が30質量%以下、
(h)多環芳香族が4.5質量%以下、及び
(i)HFRRが420μm以下
であることを特徴とする軽油組成物を提供するものである。
(a)セタン価が50〜60、
(b)90%留出温度が282〜336℃、
(c)15℃密度が0.832〜0.848g/cm3、
(d)引火点が61℃以上、
(e)40℃動粘度が1.9〜4.1mm2/s、
(f)硫黄分が50質量ppm以下、
(g)全芳香族量が30質量%以下、
(h)多環芳香族が4.5質量%以下、及び
(i)HFRRが420μm以下。
本発明の軽油組成物において、常圧蒸留装置から留出する直留軽油(LGO)留分の90%留出温度は330〜345℃であり、好ましくは332〜343℃である。90%留出温度が330℃以上であることにより、ディーゼルエンジンの燃費を良好な範囲内に保つことができる。また、90%留出温度が345℃以下であることにより、エンジンから排出される粒子状物質の成分であるsootの排出量を低減させることができる。なお、本出願書類において、90%留出温度は、ASTM D86の規定に準拠して測定した値を意味する。
上記成分以外にリン、フッ素、ホウ素、亜鉛、塩素、ナトリウム、リチウム、カリウム、ルビジウム、マグネシウム、セシウム、ジルコニアなどの第三成分を担持したものも用いることができる。更に、クエン酸等のキレート性有機化合物を含ませてもよい。これらのキレート性有機化合物は、コバルト又はニッケルと錯体を形成した状態で水素化処理触媒に含まれるとより好ましい。
まず、表2に示すような性状を有する原料基材を、表3に示す配合で混合した。その後、ULGO−1〜6の脱硫処理は、CoMoP担持脱硫触媒を用い、表3に示す条件で脱硫した。一方、灯油基材(UKERO)は、原油を常圧蒸留装置で分留して得られる直留灯油(KERO)を、表3に示す脱硫条件−7で水素化脱硫処理を行うことにより、調製した。
脱硫処理により得られた脱硫軽油基材の性状を表4に示す。
Claims (1)
- 常圧蒸留装置から留出する90%留出温度が330〜345℃の直留軽油留分と、流動接触分解装置から得られる90%留出温度が320〜350℃の接触分解軽油留分とを容量割合で95:5〜80:20で混合したものを、脱硫処理して得られる脱硫軽油基材のみを軽油留分として含む軽油組成物であって、
(a)セタン価が50〜60、
(b)90%留出温度が282〜335.5℃、
(c)15℃密度が0.832〜0.840g/cm3、
(d)引火点が61℃以上、
(e)40℃動粘度が1.9〜4.1mm2/s、
(f)硫黄分が50質量ppm以下、
(g)全芳香族量が30質量%以下、
(h)多環芳香族が4.5質量%以下、及び
(i)HFRRが420μm以下
であることを特徴とする軽油組成物。
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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JP2010173881A JP5437193B2 (ja) | 2010-08-02 | 2010-08-02 | 軽油組成物 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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JP2010173881A JP5437193B2 (ja) | 2010-08-02 | 2010-08-02 | 軽油組成物 |
Publications (2)
Publication Number | Publication Date |
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JP2012031333A JP2012031333A (ja) | 2012-02-16 |
JP5437193B2 true JP5437193B2 (ja) | 2014-03-12 |
Family
ID=45845121
Family Applications (1)
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JP2010173881A Active JP5437193B2 (ja) | 2010-08-02 | 2010-08-02 | 軽油組成物 |
Country Status (1)
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JP (1) | JP5437193B2 (ja) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
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JP6360372B2 (ja) * | 2014-07-02 | 2018-07-18 | 出光興産株式会社 | 軽油基材の製造方法 |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP3828944B2 (ja) * | 1995-05-19 | 2006-10-04 | 出光興産株式会社 | ディーゼル軽油組成物 |
JPH08333586A (ja) * | 1995-06-05 | 1996-12-17 | Showa Yotsukaichi Sekiyu Kk | 高性能低硫黄分軽油組成物の製造方法 |
JP3990226B2 (ja) * | 2002-08-09 | 2007-10-10 | 新日本石油株式会社 | 軽油組成物 |
JP2004137353A (ja) * | 2002-10-17 | 2004-05-13 | Idemitsu Kosan Co Ltd | 軽油の水素化脱硫方法及びその方法で得られた軽油組成物 |
JP2005220329A (ja) * | 2004-02-09 | 2005-08-18 | Nippon Oil Corp | 軽油組成物 |
JP4555027B2 (ja) * | 2004-08-27 | 2010-09-29 | Jx日鉱日石エネルギー株式会社 | 軽油組成物 |
EP1832645A4 (en) * | 2004-12-28 | 2012-01-11 | Japan Energy Corp | METHOD FOR PRODUCING A GAS OIL BASED MATERIAL WITH SUPER LOW SULFUR CONTENT OR GAS OIL COMPOSITION WITH SUPER LOW SULFUR CONTENT AND GAS OIL COMPOSITION WITH SUPER LOW SULFUR CONTENT |
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