JP5432188B2 - 水素吸蔵材料を含む気体吸蔵材料 - Google Patents
水素吸蔵材料を含む気体吸蔵材料 Download PDFInfo
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
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- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
- B01J20/0248—Compounds of B, Al, Ga, In, Tl
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- C01B3/001—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes characterised by the uptaking medium; Treatment thereof
- C01B3/0026—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes characterised by the uptaking medium; Treatment thereof of one single metal or a rare earth metal; Treatment thereof
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- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/0005—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes
- C01B3/001—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes characterised by the uptaking medium; Treatment thereof
- C01B3/0031—Intermetallic compounds; Metal alloys; Treatment thereof
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/0005—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes
- C01B3/001—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes characterised by the uptaking medium; Treatment thereof
- C01B3/0084—Solid storage mediums characterised by their shape, e.g. pellets, sintered shaped bodies, sheets, porous compacts, spongy metals, hollow particles, solids with cavities, layered solids
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B6/00—Hydrides of metals including fully or partially hydrided metals, alloys or intermetallic compounds ; Compounds containing at least one metal-hydrogen bond, e.g. (GeH3)2S, SiH GeH; Monoborane or diborane; Addition complexes thereof
- C01B6/06—Hydrides of aluminium, gallium, indium, thallium, germanium, tin, lead, arsenic, antimony, bismuth or polonium; Monoborane; Diborane; Addition complexes thereof
- C01B6/10—Monoborane; Diborane; Addition complexes thereof
- C01B6/13—Addition complexes of monoborane or diborane, e.g. with phosphine, arsine or hydrazine
- C01B6/15—Metal borohydrides; Addition complexes thereof
- C01B6/19—Preparation from other compounds of boron
- C01B6/21—Preparation of borohydrides of alkali metals, alkaline earth metals, magnesium or beryllium; Addition complexes thereof, e.g. LiBH4.2N2H4, NaB2H7
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- C—CHEMISTRY; METALLURGY
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- C01B6/24—Hydrides containing at least two metals; Addition complexes thereof
- C01B6/243—Hydrides containing at least two metals; Addition complexes thereof containing only hydrogen, aluminium and alkali metals, e.g. Li(AlH4)
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
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- Y02E60/30—Hydrogen technology
- Y02E60/32—Hydrogen storage
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2991—Coated
- Y10T428/2993—Silicic or refractory material containing [e.g., tungsten oxide, glass, cement, etc.]
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2991—Coated
- Y10T428/2993—Silicic or refractory material containing [e.g., tungsten oxide, glass, cement, etc.]
- Y10T428/2996—Glass particles or spheres
Description
本願は、参照によりその内容が本明細書に組み込まれる、2008年2月22日に出願の米国特許出願番号第12/035,908号の優先権を主張する。
(吸蔵材料)
(中空要素)
(中空ミクロ球体形成)
(水素吸蔵複合体の封入および形成)
(水素の吸蔵および放出)
Claims (21)
- 気体の吸蔵および放出を可能にする材料であって、
複数の中空要素であって、各中空要素が内部空洞を囲む多孔性壁を有し、前記多孔性壁が前記内部空洞に面する内部表面を有する複数の中空要素を含み、
前記内部空洞が、前記多孔性壁の内部表面により支持される細長い構造の形態で気体吸蔵材料を含み、
前記気体吸蔵材料が、前記内部空洞に面する多孔性壁の内部表面より少なくとも1桁大きい表面積を有し、
前記気体が水素であり、前記気体吸蔵材料が金属水素化物であり、
前記中空要素が中空ガラス要素であり、
前記細長い構造が、多孔性壁の内部表面上に形成された針状結晶である、
材料。 - 前記の細長い構造の長さが0.1ミクロンから10ミクロンであり、断面寸法が1ミクロン未満である、請求項1に記載の材料。
- 前記針状結晶は、長さが0.1ミクロンから50ミクロンであり断面寸法が0.1ミクロンから1ミクロンである、請求項1に記載の材料。
- 前記中空要素がガラス球体である、請求項1に記載の材料。
- 前記ガラス球体が、平均直径が1ミクロンから500ミクロンのガラスミクロ球体である、請求項4に記載の材料。
- 前記ガラス球体が、平均直径が5ミクロンから100ミクロンのガラスミクロ球体である、請求項4に記載の材料。
- 前記多孔性壁が、平均細孔直径が10オングストロームから3000オングストロームの範囲の細孔を含む、請求項4に記載の材料。
- 前記多孔性壁の平均壁厚が0.1ミクロンから50ミクロンである、請求項4に記載の材料。
- 前記多孔性壁の壁厚が、0.5ミクロンから5ミクロンである、請求項4に記載の材料。
- 前記吸蔵材料が固体状態金属水素化物である、請求項1に記載の材料。
- 前記吸蔵材料が、アルカリ金属アラネート、アルカリ土類金属アラネート、アルカリ金属ボロハイドライド、およびアルカリ土類金属ボロハイドライドからなる水素化物の群から選択される、請求項10に記載の材料。
- 気体を吸蔵する材料を調製する方法であって、
内部空洞を囲む内部表面を持つ多孔性壁を有する中空要素を準備する工程;
溶媒に吸蔵材料を溶解させた吸蔵材料の溶液の前記多孔性壁を通る拡散により内部空洞へ吸蔵材料を導入する工程;および
内部空洞から溶媒を除去し、前記多孔性壁の内部表面より少なくとも1桁大きい表面積を有する吸蔵材料の構造を内部空洞内に形成する工程を含み、
前記気体が水素であり、前記吸蔵材料が金属水素化物であり、
前記中空要素が中空ガラス要素であり、
前記吸蔵材料の構造が、多孔性壁の内部表面上に形成された針状結晶である、
方法。 - 前記溶媒が有機溶媒である、請求項12に記載の方法。
- 前記溶媒がテトラヒドロフランまたはエーテルである、請求項12に記載の方法。
- 前記構造が、前記多孔性壁の内部表面により支持された細長い構造を含む、請求項12に記載の方法。
- 前記中空要素がガラス球体である、請求項12に記載の方法。
- 前記ガラス球体が、平均直径が1ミクロンから500ミクロンであるガラスミクロ球体である、請求項16に記載の方法。
- 前記ガラス球体が、直径が5ミクロンから100ミクロンであるガラスミクロ球体であり、前記多孔性壁の壁厚が0.5ミクロンから5ミクロンである、請求項16に記載の方法。
- 前記吸蔵材料が、アルカリ金属アラネート、アルカリ土類金属アラネート、アルカリ金属ボロハイドライド、およびアルカリ土類金属ボロハイドライドからなる水素化物の群から選択される、請求項12に記載の方法。
- 水素の吸蔵および放出のための材料であって、
複数の中空ガラスミクロ球体であって、各中空ガラスミクロ球体が、内部空洞を囲む多孔性壁を含み、前記多孔性壁が、内部表面積を有する内部空洞に面する内部表面を有する複数の中空ガラスミクロ球体を含み、
前記中空ガラスミクロ球体が、1ミクロンから500ミクロンの平均直径を有し;
前記内部空洞内に配置された水素吸蔵材料であって、前記多孔性壁の内部表面により支持された固体金属水素化物の細長い構造を含み、
前記内部空洞内の水素吸蔵材料が、内部表面積よりも少なくとも1桁大きい表面積を呈し、
前記細長い構造が、多孔性壁の内部表面上に形成された針状結晶である、
材料。 - 前記固体金属水素化物が、アルカリ金属アラネート、アルカリ土類金属アラネート、アルカリ金属ボロハイドライド、アルカリ土類金属ボロハイドライド、またはこれらの組み合わせである、請求項20に記載の材料。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US12/035,908 | 2008-02-22 | ||
US12/035,908 US8377555B2 (en) | 2008-02-22 | 2008-02-22 | Gas storage materials, including hydrogen storage materials |
PCT/US2009/033003 WO2009105333A2 (en) | 2008-02-22 | 2009-02-04 | Gas storage materials, including hydrogen storage materials |
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Publication Number | Publication Date |
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JP2011514247A JP2011514247A (ja) | 2011-05-06 |
JP5432188B2 true JP5432188B2 (ja) | 2014-03-05 |
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JP2010547674A Expired - Fee Related JP5432188B2 (ja) | 2008-02-22 | 2009-02-04 | 水素吸蔵材料を含む気体吸蔵材料 |
Country Status (6)
Country | Link |
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US (2) | US8377555B2 (ja) |
EP (1) | EP2254828B1 (ja) |
JP (1) | JP5432188B2 (ja) |
CN (1) | CN102007069B (ja) |
BR (1) | BRPI0906001B1 (ja) |
WO (1) | WO2009105333A2 (ja) |
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US9174889B2 (en) * | 2007-11-26 | 2015-11-03 | The United States Of America, As Represented By The Secretary Of The Navy | Metal hydride nanoparticles |
US8758715B2 (en) | 2010-08-26 | 2014-06-24 | Savannah River Nuclear Solutions, Llc | Porous wall hollow glass microspheres as a medium or substrate for storage and formation of novel materials |
GB201223259D0 (en) | 2012-12-21 | 2013-02-06 | Cella Energy Ltd | A hydrogen storage pellet |
US11596780B2 (en) | 2013-05-28 | 2023-03-07 | The Johns Hopkins University | Controlled outgassing of hyberbarically loaded materials for the delivery of oxygen and other therapeutic gases in biomedical applications |
JP2015096805A (ja) * | 2013-11-15 | 2015-05-21 | 株式会社日立製作所 | 伝送装置 |
CN103972570A (zh) * | 2014-04-03 | 2014-08-06 | 上海华篷防爆科技有限公司 | 带有铁基多孔金属复合材料储氢瓶的发电装置 |
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CN103972572B (zh) * | 2014-04-03 | 2016-04-13 | 上海华篷防爆科技有限公司 | 带有银氧化镉复合材料储氢瓶的发电装置 |
CN103972548B (zh) * | 2014-04-03 | 2016-08-17 | 上海华篷防爆科技有限公司 | 带有非金属材料储氢瓶的发电装置 |
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CN103972547A (zh) * | 2014-04-03 | 2014-08-06 | 上海华篷防爆科技有限公司 | 含有聚合物电解质膜的固态氢能源装置 |
CN103972554A (zh) * | 2014-04-03 | 2014-08-06 | 上海华篷防爆科技有限公司 | 一种钛镍合金复合材料的储氢装置 |
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CN103972549A (zh) * | 2014-04-03 | 2014-08-06 | 上海华篷防爆科技有限公司 | 一种带有非金属材料储氢瓶的发电装置 |
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US8895146B2 (en) | 2014-11-25 |
CN102007069B (zh) | 2015-07-08 |
EP2254828B1 (en) | 2018-05-30 |
US20130136927A1 (en) | 2013-05-30 |
JP2011514247A (ja) | 2011-05-06 |
WO2009105333A2 (en) | 2009-08-27 |
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WO2009105333A3 (en) | 2009-10-22 |
CN102007069A (zh) | 2011-04-06 |
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