JP5230338B2 - ポリエステル繊維用均染剤 - Google Patents
ポリエステル繊維用均染剤 Download PDFInfo
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- JP5230338B2 JP5230338B2 JP2008260495A JP2008260495A JP5230338B2 JP 5230338 B2 JP5230338 B2 JP 5230338B2 JP 2008260495 A JP2008260495 A JP 2008260495A JP 2008260495 A JP2008260495 A JP 2008260495A JP 5230338 B2 JP5230338 B2 JP 5230338B2
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- alkylene oxide
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- 239000003795 chemical substances by application Substances 0.000 title claims description 34
- 229920000728 polyester Polymers 0.000 title claims description 33
- 239000000835 fiber Substances 0.000 title claims description 31
- 238000004043 dyeing Methods 0.000 claims description 68
- -1 fatty acid diester Chemical class 0.000 claims description 28
- 238000000034 method Methods 0.000 claims description 23
- 125000002947 alkylene group Chemical group 0.000 claims description 19
- SESFRYSPDFLNCH-UHFFFAOYSA-N benzyl benzoate Chemical compound C=1C=CC=CC=1C(=O)OCC1=CC=CC=C1 SESFRYSPDFLNCH-UHFFFAOYSA-N 0.000 claims description 14
- MHDVGSVTJDSBDK-UHFFFAOYSA-N dibenzyl ether Chemical compound C=1C=CC=CC=1COCC1=CC=CC=C1 MHDVGSVTJDSBDK-UHFFFAOYSA-N 0.000 claims description 11
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 11
- 229930195729 fatty acid Natural products 0.000 claims description 11
- 239000000194 fatty acid Substances 0.000 claims description 11
- 150000001875 compounds Chemical class 0.000 claims description 10
- 125000004432 carbon atom Chemical group C* 0.000 claims description 8
- 229960002903 benzyl benzoate Drugs 0.000 claims description 7
- 238000006116 polymerization reaction Methods 0.000 claims description 7
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 4
- 229920001515 polyalkylene glycol Polymers 0.000 claims description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 2
- 125000001931 aliphatic group Chemical group 0.000 claims description 2
- 125000000129 anionic group Chemical group 0.000 claims description 2
- 125000004429 atom Chemical group 0.000 claims description 2
- 229910052751 metal Inorganic materials 0.000 claims description 2
- 239000002184 metal Substances 0.000 claims description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- 239000000975 dye Substances 0.000 description 30
- 230000000052 comparative effect Effects 0.000 description 15
- 230000008569 process Effects 0.000 description 15
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 12
- 238000002156 mixing Methods 0.000 description 12
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- 239000000203 mixture Substances 0.000 description 11
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical class CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 9
- 229910019142 PO4 Inorganic materials 0.000 description 8
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- 239000004744 fabric Substances 0.000 description 8
- 239000010452 phosphate Substances 0.000 description 8
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- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 7
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 6
- BYLSIPUARIZAHZ-UHFFFAOYSA-N 2,4,6-tris(1-phenylethyl)phenol Chemical compound C=1C(C(C)C=2C=CC=CC=2)=C(O)C(C(C)C=2C=CC=CC=2)=CC=1C(C)C1=CC=CC=C1 BYLSIPUARIZAHZ-UHFFFAOYSA-N 0.000 description 6
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 6
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 6
- 239000005642 Oleic acid Substances 0.000 description 6
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 6
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 150000004665 fatty acids Chemical class 0.000 description 6
- 229920001519 homopolymer Polymers 0.000 description 6
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 6
- 239000002736 nonionic surfactant Substances 0.000 description 6
- 238000012545 processing Methods 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 5
- 239000003945 anionic surfactant Substances 0.000 description 5
- 229920001400 block copolymer Polymers 0.000 description 5
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical class C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 5
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 4
- 239000002131 composite material Substances 0.000 description 4
- 239000000986 disperse dye Substances 0.000 description 4
- 239000006260 foam Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 125000006353 oxyethylene group Chemical group 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- NPPQSCRMBWNHMW-UHFFFAOYSA-N Meprobamate Chemical compound NC(=O)OCC(C)(CCC)COC(N)=O NPPQSCRMBWNHMW-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 3
- 230000002776 aggregation Effects 0.000 description 3
- 238000004220 aggregation Methods 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 229920001778 nylon Polymers 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 3
- 229920001223 polyethylene glycol Polymers 0.000 description 3
- 239000004814 polyurethane Substances 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- OYHQOLUKZRVURQ-NTGFUMLPSA-N (9Z,12Z)-9,10,12,13-tetratritiooctadeca-9,12-dienoic acid Chemical compound C(CCCCCCC\C(=C(/C\C(=C(/CCCCC)\[3H])\[3H])\[3H])\[3H])(=O)O OYHQOLUKZRVURQ-NTGFUMLPSA-N 0.000 description 2
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 2
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 230000001804 emulsifying effect Effects 0.000 description 2
- 239000003063 flame retardant Substances 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 229920005604 random copolymer Polymers 0.000 description 2
- RPACBEVZENYWOL-XFULWGLBSA-M sodium;(2r)-2-[6-(4-chlorophenoxy)hexyl]oxirane-2-carboxylate Chemical compound [Na+].C=1C=C(Cl)C=CC=1OCCCCCC[C@]1(C(=O)[O-])CO1 RPACBEVZENYWOL-XFULWGLBSA-M 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 239000003784 tall oil Substances 0.000 description 2
- 230000000007 visual effect Effects 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- FFJCNSLCJOQHKM-CLFAGFIQSA-N (z)-1-[(z)-octadec-9-enoxy]octadec-9-ene Chemical compound CCCCCCCC\C=C/CCCCCCCCOCCCCCCCC\C=C/CCCCCCCC FFJCNSLCJOQHKM-CLFAGFIQSA-N 0.000 description 1
- WIGIPJGWVLNDAF-UHFFFAOYSA-N 8-methyl-1-(8-methylnonoxy)nonane Chemical compound CC(C)CCCCCCCOCCCCCCCC(C)C WIGIPJGWVLNDAF-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- OYHQOLUKZRVURQ-HZJYTTRNSA-N Linoleic acid Chemical compound CCCCC\C=C/C\C=C/CCCCCCCC(O)=O OYHQOLUKZRVURQ-HZJYTTRNSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 239000008351 acetate buffer Chemical class 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 238000012644 addition polymerization Methods 0.000 description 1
- 230000004931 aggregating effect Effects 0.000 description 1
- 125000003158 alcohol group Chemical group 0.000 description 1
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 description 1
- 230000003254 anti-foaming effect Effects 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 150000001558 benzoic acid derivatives Chemical class 0.000 description 1
- 239000001045 blue dye Substances 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 238000010014 continuous dyeing Methods 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 238000009998 heat setting Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000009940 knitting Methods 0.000 description 1
- 235000020778 linoleic acid Nutrition 0.000 description 1
- OYHQOLUKZRVURQ-IXWMQOLASA-N linoleic acid Natural products CCCCC\C=C/C\C=C\CCCCCCCC(O)=O OYHQOLUKZRVURQ-IXWMQOLASA-N 0.000 description 1
- 239000004973 liquid crystal related substance Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000021313 oleic acid Nutrition 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- FURYAADUZGZUGQ-UHFFFAOYSA-N phenoxybenzene;sulfuric acid Chemical class OS(O)(=O)=O.C=1C=CC=CC=1OC1=CC=CC=C1 FURYAADUZGZUGQ-UHFFFAOYSA-N 0.000 description 1
- FCJSHPDYVMKCHI-UHFFFAOYSA-N phenyl benzoate Chemical compound C=1C=CC=CC=1C(=O)OC1=CC=CC=C1 FCJSHPDYVMKCHI-UHFFFAOYSA-N 0.000 description 1
- 229920001281 polyalkylene Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000259 polyoxyethylene lauryl ether Polymers 0.000 description 1
- 229920006306 polyurethane fiber Polymers 0.000 description 1
- LVTJOONKWUXEFR-FZRMHRINSA-N protoneodioscin Natural products O(C[C@@H](CC[C@]1(O)[C@H](C)[C@@H]2[C@]3(C)[C@H]([C@H]4[C@@H]([C@]5(C)C(=CC4)C[C@@H](O[C@@H]4[C@H](O[C@H]6[C@@H](O)[C@@H](O)[C@@H](O)[C@H](C)O6)[C@@H](O)[C@H](O[C@H]6[C@@H](O)[C@@H](O)[C@@H](O)[C@H](C)O6)[C@H](CO)O4)CC5)CC3)C[C@@H]2O1)C)[C@H]1[C@H](O)[C@H](O)[C@H](O)[C@@H](CO)O1 LVTJOONKWUXEFR-FZRMHRINSA-N 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
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- 239000011734 sodium Substances 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- JVBXVOWTABLYPX-UHFFFAOYSA-L sodium dithionite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])=O JVBXVOWTABLYPX-UHFFFAOYSA-L 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
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- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
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Images
Description
・染色対象の素材: 本発明のポリエステル繊維用の染色方法において、対象とするポリエステル繊維としてはレギュラーポリエステル、カチオン可染ポリエステル、高密度ポリエステルタフタ等があげられるが、特に高密度ポリエステル繊維に有効である。また、ナイロン、ポリウレタン等の複合素材にも対応できる。
DyStar社のDianix Red KB-SE; 0.2%owf 、
住化ケムテックス(株)のSumikalon Blue E-FBL;0.3%owf、
酢酸; 0.3g/L、
均染剤(表1に示す組成); 0.5g/L。
・使用機械:ミニ・カラー試験機(テクサム技研(株)製)
・浴比: 1:10 (10g/100cc)
・処理手順:供試布を60℃で試験機の染浴中にセット。→染浴を3℃/min.で昇温。→135℃×30分で密閉下に高温染色処理。→80℃に降温してから染浴より取り出し。→RCソーピング80℃×10分→ピンテンターによるヒートセット(ヒートクリーニングを兼ねる)180℃×30秒〜1分。RCソーピングには、次の組成の浴液を用い、浴比を1:30とした。ソーダ灰1.0g/L+ハイドロサルファイトナトリウム1.0g/L+「トライポールTK」(第一工業製薬(株)の繊維用界面活性剤製品)1.0g/L。
Claims (2)
- 安息香酸ベンジル及びジベンジルエーテルから選択された1種又は2種以上(成分A)5〜80重量部と、下記一般式(1)で表されるポリアルキレングリコール脂肪酸ジエステル(成分B)1〜50重量部と、下記一般式(2)で表される化合物(成分C)1〜50重量部とを含有することを特徴とするポリエステル繊維用均染剤。
- 請求項1に記載のポリエステル繊維用均染剤を用いてポリエステル繊維を染色する工程を含むことを特徴とするポリエステル繊維の染色方法。
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JP2008260495A JP5230338B2 (ja) | 2008-10-07 | 2008-10-07 | ポリエステル繊維用均染剤 |
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JP2008260495A JP5230338B2 (ja) | 2008-10-07 | 2008-10-07 | ポリエステル繊維用均染剤 |
Publications (2)
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JP2010090498A JP2010090498A (ja) | 2010-04-22 |
JP5230338B2 true JP5230338B2 (ja) | 2013-07-10 |
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Cited By (1)
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KR102622422B1 (ko) * | 2021-11-24 | 2024-01-08 | 이범소 | 환경 친화형 폴리에스터 염색용 캐리어 조성물 |
Families Citing this family (9)
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JP5960349B2 (ja) * | 2012-08-08 | 2016-08-02 | 日華化学株式会社 | ポリエステル繊維用染色助剤、並びにこれを用いたポリエステル繊維の染色方法及び染色物の製造方法 |
JP6214388B2 (ja) * | 2013-12-25 | 2017-10-18 | 日華化学株式会社 | 繊維用染色助剤、及び染色物の製造方法 |
JP6764475B2 (ja) * | 2015-12-18 | 2020-09-30 | 日華化学(中国)有限公司 | 均染剤及び染色繊維製品の製造方法 |
JP6661758B2 (ja) * | 2015-12-18 | 2020-03-11 | 日華化学(中国)有限公司 | 染色助剤及び染色繊維製品の製造方法 |
KR101896967B1 (ko) | 2017-08-21 | 2018-09-19 | 아이씨이아이우방(주) | 침염 연속식 황화 염색용 분산균염제 조성물, 이를 이용한 분산균염제 및 이의 제조방법 |
CN108166273B (zh) * | 2018-01-09 | 2020-06-16 | 苏州维明化学工业有限公司 | 一种用于涤纶纤维的分散均染剂及其制备方法 |
JP2021075828A (ja) * | 2019-11-13 | 2021-05-20 | 日華化学株式会社 | 染色助剤及び染色繊維製品の製造方法 |
CN112694609B (zh) * | 2020-12-24 | 2023-03-14 | 常熟耐素生物材料科技有限公司 | 一种聚酯纤维高温匀染用表面活性剂及其制备方法 |
CN113214466A (zh) * | 2021-06-04 | 2021-08-06 | 浙江皇马科技股份有限公司 | 一种三苯乙烯基苯酚嵌段聚醚、硫酸酯铵盐及其制备方法 |
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JPS60206872A (ja) * | 1984-03-30 | 1985-10-18 | Sanyo Chem Ind Ltd | 分散染料組成物 |
EP0414631A1 (de) * | 1989-02-22 | 1991-02-27 | Ciba-Geigy Ag | Hilfsmittelgemisch und seine Verwendung beim Färben von Polyesterfasermaterialien |
EP0403718A3 (de) * | 1989-06-20 | 1991-12-27 | Ciba-Geigy Ag | Styroloxid-Produkte |
JP2873181B2 (ja) * | 1995-02-13 | 1999-03-24 | 日華化学株式会社 | ポリエステル繊維染色用分散均染剤 |
JP4553175B2 (ja) * | 2003-06-24 | 2010-09-29 | 東レ株式会社 | ポリ乳酸系成形体用染色助剤 |
JP2005023496A (ja) * | 2003-07-01 | 2005-01-27 | Kanebo Ltd | ポリ乳酸系成形体用染色助剤 |
JP2005029928A (ja) * | 2003-07-07 | 2005-02-03 | Kanebo Ltd | ポリ乳酸系成形体用染色助剤 |
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KR102622422B1 (ko) * | 2021-11-24 | 2024-01-08 | 이범소 | 환경 친화형 폴리에스터 염색용 캐리어 조성물 |
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