JP5221149B2 - プロピレン及び芳香族炭化水素の製造方法並びにその製造装置 - Google Patents

プロピレン及び芳香族炭化水素の製造方法並びにその製造装置 Download PDF

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JP5221149B2
JP5221149B2 JP2007553941A JP2007553941A JP5221149B2 JP 5221149 B2 JP5221149 B2 JP 5221149B2 JP 2007553941 A JP2007553941 A JP 2007553941A JP 2007553941 A JP2007553941 A JP 2007553941A JP 5221149 B2 JP5221149 B2 JP 5221149B2
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zeolite
fraction
propylene
hydrocarbon
carbon atoms
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JPWO2007080957A1 (ja
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光弘 関口
義和 高松
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Asahi Kasei Chemicals Corp
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Asahi Kasei Chemicals Corp
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G63/00—Treatment of naphtha by at least one reforming process and at least one other conversion process
    • C10G63/02—Treatment of naphtha by at least one reforming process and at least one other conversion process plural serial stages only
    • C10G63/04—Treatment of naphtha by at least one reforming process and at least one other conversion process plural serial stages only including at least one cracking step
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/42—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons homo- or co-oligomerisation with ring formation, not being a Diels-Alder conversion
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
    • B01J29/44—Noble metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B61/00—Other general methods
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C07C11/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/76—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen
    • C07C2/82—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen oxidative coupling
    • C07C2/84—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen oxidative coupling catalytic
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C4/00—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms
    • C07C4/02—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by cracking a single hydrocarbon or a mixture of individually defined hydrocarbons or a normally gaseous hydrocarbon fraction
    • C07C4/06—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
    • C10G11/04—Oxides
    • C10G11/05—Crystalline alumino-silicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G35/00—Reforming naphtha
    • C10G35/04—Catalytic reforming
    • C10G35/06—Catalytic reforming characterised by the catalyst used
    • C10G35/065—Catalytic reforming characterised by the catalyst used containing crystalline zeolitic molecular sieves, other than aluminosilicates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/16—After treatment, characterised by the effect to be obtained to increase the Si/Al ratio; Dealumination
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/186—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/36—Steaming
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C07C2529/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11 containing iron group metals, noble metals or copper
    • C07C2529/44—Noble metals
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1088—Olefins
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4018—Spatial velocity, e.g. LHSV, WHSV
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4081—Recycling aspects
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/20—C2-C4 olefins
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/30—Aromatics
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
JP2007553941A 2006-01-16 2007-01-12 プロピレン及び芳香族炭化水素の製造方法並びにその製造装置 Active JP5221149B2 (ja)

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JP2006008038 2006-01-16
JP2006008038 2006-01-16
JP2007553941A JP5221149B2 (ja) 2006-01-16 2007-01-12 プロピレン及び芳香族炭化水素の製造方法並びにその製造装置
PCT/JP2007/050311 WO2007080957A1 (ja) 2006-01-16 2007-01-12 プロピレン及び芳香族炭化水素の製造方法並びにその製造装置

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US (1) US8034987B2 (enExample)
EP (1) EP1975143B1 (enExample)
JP (1) JP5221149B2 (enExample)
KR (1) KR101073593B1 (enExample)
CN (1) CN101370755B (enExample)
BR (1) BRPI0707115B1 (enExample)
MY (1) MY147381A (enExample)
RU (1) RU2394803C2 (enExample)
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Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20100331590A1 (en) * 2009-06-25 2010-12-30 Debarshi Majumder Production of light olefins and aromatics
US9238600B2 (en) 2011-12-14 2016-01-19 Uop Llc Dual riser catalytic cracker for increased light olefin yield
US10099210B2 (en) 2013-04-29 2018-10-16 Saudi Basic Industries Corporation Catalytic methods for converting naphtha into olefins
US10519387B2 (en) * 2014-03-31 2019-12-31 Hindustan Petroleum Corporation Ltd. Catalyst composition for converting light naphtha to aromatic compounds and a process thereof
CN109071378B (zh) * 2016-04-11 2022-08-05 旭化成株式会社 低级烯烃的制造方法
US10016750B1 (en) 2017-01-10 2018-07-10 King Fahd University Of Petroleum And Minerals Method of producing propylene and ethylene with a core-shell ZSM catalyst
JP2019026571A (ja) * 2017-07-27 2019-02-21 東ソー株式会社 芳香族化合物の製造法
JP6977453B2 (ja) * 2017-09-28 2021-12-08 東ソー株式会社 芳香族化合物の製造方法
SG11202101704VA (en) * 2018-09-05 2021-03-30 Zeon Corp Method of producing piperylene
US20230113926A1 (en) * 2020-02-21 2023-04-13 Sumitomo Chemical Company, Limited Method for producing olefins
JP2024121026A (ja) * 2022-08-30 2024-09-06 旭化成株式会社 エタノール及びエチレンの変換方法、プロピレンの製造方法、芳香族化合物の製造方法、並びに、エタノール及びエチレンの変換装置
JP2024051654A (ja) * 2022-09-30 2024-04-11 旭化成株式会社 エタノールの変換方法、炭化水素の製造方法、プロピレンの製造方法、芳香族化合物の製造方法、並びに、エタノールの変換装置

Citations (7)

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JPS4941322A (enExample) * 1972-05-17 1974-04-18
JPS6314732A (ja) * 1986-07-08 1988-01-21 Res Assoc Util Of Light Oil 芳香族炭化水素の製造方法
JPH02115134A (ja) * 1988-10-26 1990-04-27 Sanyo Sekiyu Kagaku Kk 芳香族炭化水素の製造法
JPH08127546A (ja) * 1994-10-28 1996-05-21 Asahi Chem Ind Co Ltd 低級オレフィン及び単環芳香族炭化水素の製造法
JPH08157399A (ja) * 1994-10-03 1996-06-18 Sanyo Sekiyu Kagaku Kk 芳香族炭化水素の製造方法
WO2000010948A1 (en) * 1998-08-25 2000-03-02 Asahi Kasei Kogyo Kabushiki Kaisha Process for producing ethylene and propylene
WO2006009099A1 (ja) * 2004-07-16 2006-01-26 Asahi Kasei Chemicals Corporation エチレン及びプロピレンの製造法

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US3518319A (en) * 1965-03-30 1970-06-30 Exxon Research Engineering Co Process for improving oxo selectivity to unbranched alcohols
SU929618A1 (ru) * 1980-03-03 1982-05-23 Ордена Трудового Красного Знамени Институт Катализа Со Ан Ссср Способ получени олефинов с @ -с @
US4804801A (en) * 1986-09-08 1989-02-14 Mobil Oil Corporation Process for converting C2 to C8 aliphatics to aromatics over a metal-activated zeolite
GB8803112D0 (en) * 1988-02-11 1988-03-09 British Petroleum Co Plc Zeolite catalysts suitable for hydrocarbon conversion
JPH0639410B2 (ja) 1989-01-11 1994-05-25 軽質留分新用途開発技術研究組合 プロピレンを主成分とする低級オレフィンの製造方法
JPH06346063A (ja) 1993-06-04 1994-12-20 Asahi Chem Ind Co Ltd 軽質炭化水素の接触変換法
KR100228997B1 (ko) * 1994-10-03 1999-11-01 테라사끼 이와오 방향족 탄화수소의 제조방법
JP3905948B2 (ja) 1996-04-18 2007-04-18 山陽石油化学株式会社 高シリカゼオライト系触媒
US5773676A (en) 1996-08-06 1998-06-30 Phillips Petroleum Company Process for producing olefins and aromatics from non-aromatics

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4941322A (enExample) * 1972-05-17 1974-04-18
JPS6314732A (ja) * 1986-07-08 1988-01-21 Res Assoc Util Of Light Oil 芳香族炭化水素の製造方法
JPH02115134A (ja) * 1988-10-26 1990-04-27 Sanyo Sekiyu Kagaku Kk 芳香族炭化水素の製造法
JPH08157399A (ja) * 1994-10-03 1996-06-18 Sanyo Sekiyu Kagaku Kk 芳香族炭化水素の製造方法
JPH08127546A (ja) * 1994-10-28 1996-05-21 Asahi Chem Ind Co Ltd 低級オレフィン及び単環芳香族炭化水素の製造法
WO2000010948A1 (en) * 1998-08-25 2000-03-02 Asahi Kasei Kogyo Kabushiki Kaisha Process for producing ethylene and propylene
WO2006009099A1 (ja) * 2004-07-16 2006-01-26 Asahi Kasei Chemicals Corporation エチレン及びプロピレンの製造法

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US8034987B2 (en) 2011-10-11
MY147381A (en) 2012-11-30
EP1975143A4 (en) 2011-03-23
US20100022810A1 (en) 2010-01-28
RU2394803C2 (ru) 2010-07-20
WO2007080957A1 (ja) 2007-07-19
EP1975143B1 (en) 2015-10-21
CN101370755A (zh) 2009-02-18
EP1975143A1 (en) 2008-10-01
KR20080081288A (ko) 2008-09-09
TW200744983A (en) 2007-12-16
BRPI0707115A2 (pt) 2011-04-19
RU2008133617A (ru) 2010-02-27
KR101073593B1 (ko) 2011-10-14
JPWO2007080957A1 (ja) 2009-06-11
TWI360534B (enExample) 2012-03-21
CN101370755B (zh) 2013-05-08
BRPI0707115B1 (pt) 2017-03-28

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