JP5026628B2 - 新規アルミナ、その調製方法および触媒、触媒の担体または吸着剤としてのその使用 - Google Patents
新規アルミナ、その調製方法および触媒、触媒の担体または吸着剤としてのその使用 Download PDFInfo
- Publication number
- JP5026628B2 JP5026628B2 JP18024599A JP18024599A JP5026628B2 JP 5026628 B2 JP5026628 B2 JP 5026628B2 JP 18024599 A JP18024599 A JP 18024599A JP 18024599 A JP18024599 A JP 18024599A JP 5026628 B2 JP5026628 B2 JP 5026628B2
- Authority
- JP
- Japan
- Prior art keywords
- alumina
- activated alumina
- weight
- phase
- crystal structure
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 title claims description 86
- 238000000034 method Methods 0.000 title claims description 13
- 239000003054 catalyst Substances 0.000 title claims description 10
- 239000003463 adsorbent Substances 0.000 title description 4
- 238000002360 preparation method Methods 0.000 title description 4
- 239000000203 mixture Substances 0.000 claims description 19
- MXRIRQGCELJRSN-UHFFFAOYSA-N O.O.O.[Al] Chemical compound O.O.O.[Al] MXRIRQGCELJRSN-UHFFFAOYSA-N 0.000 claims description 18
- 229910001680 bayerite Inorganic materials 0.000 claims description 17
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims description 14
- 238000006297 dehydration reaction Methods 0.000 claims description 13
- 230000018044 dehydration Effects 0.000 claims description 11
- 238000006317 isomerization reaction Methods 0.000 claims description 11
- 239000013078 crystal Substances 0.000 claims description 10
- 239000011734 sodium Substances 0.000 claims description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 7
- 229910052783 alkali metal Inorganic materials 0.000 claims description 7
- 150000001340 alkali metals Chemical class 0.000 claims description 7
- 230000032683 aging Effects 0.000 claims description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 4
- 230000001747 exhibiting effect Effects 0.000 claims description 4
- 238000010304 firing Methods 0.000 claims description 4
- 229910052708 sodium Inorganic materials 0.000 claims description 4
- 150000001336 alkenes Chemical class 0.000 claims description 3
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 3
- 238000001354 calcination Methods 0.000 claims description 2
- 230000003197 catalytic effect Effects 0.000 claims description 2
- 239000011148 porous material Substances 0.000 claims description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 1
- -1 olefin compounds Chemical class 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 description 12
- 239000007789 gas Substances 0.000 description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
- 230000002378 acidificating effect Effects 0.000 description 4
- 150000001298 alcohols Chemical class 0.000 description 4
- 238000005469 granulation Methods 0.000 description 4
- 230000003179 granulation Effects 0.000 description 4
- 238000002347 injection Methods 0.000 description 4
- 239000007924 injection Substances 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 238000002441 X-ray diffraction Methods 0.000 description 3
- 239000003513 alkali Substances 0.000 description 3
- 150000004820 halides Chemical class 0.000 description 3
- 229910052734 helium Inorganic materials 0.000 description 3
- 239000001307 helium Substances 0.000 description 3
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000010517 secondary reaction Methods 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 238000004438 BET method Methods 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 2
- 238000004587 chromatography analysis Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000006356 dehydrogenation reaction Methods 0.000 description 2
- 238000007689 inspection Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 230000002000 scavenging effect Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000004604 Blowing Agent Substances 0.000 description 1
- ZAFNJMIOTHYJRJ-UHFFFAOYSA-N Diisopropyl ether Chemical compound CC(C)OC(C)C ZAFNJMIOTHYJRJ-UHFFFAOYSA-N 0.000 description 1
- LVLIEFGFKKWFLI-UHFFFAOYSA-N [C].CCC=C Chemical group [C].CCC=C LVLIEFGFKKWFLI-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 150000001350 alkyl halides Chemical class 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 150000001502 aryl halides Chemical class 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000006482 condensation reaction Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 239000002274 desiccant Substances 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 229910001679 gibbsite Inorganic materials 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000010335 hydrothermal treatment Methods 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000005453 pelletization Methods 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- IAQRGUVFOMOMEM-ONEGZZNKSA-N trans-but-2-ene Chemical compound C\C=C\C IAQRGUVFOMOMEM-ONEGZZNKSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F7/00—Compounds of aluminium
- C01F7/02—Aluminium oxide; Aluminium hydroxide; Aluminates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
- B01J21/04—Alumina
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F7/00—Compounds of aluminium
- C01F7/02—Aluminium oxide; Aluminium hydroxide; Aluminates
- C01F7/44—Dehydration of aluminium oxide or hydroxide, i.e. all conversions of one form into another involving a loss of water
- C01F7/447—Dehydration of aluminium oxide or hydroxide, i.e. all conversions of one form into another involving a loss of water by wet processes
- C01F7/448—Dehydration of aluminium oxide or hydroxide, i.e. all conversions of one form into another involving a loss of water by wet processes using superatmospheric pressure, e.g. hydrothermal conversion of gibbsite into boehmite
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/12—Surface area
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/14—Pore volume
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/80—Compositional purity
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Geology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9808089A FR2780392B1 (fr) | 1998-06-25 | 1998-06-25 | Nouvelle alumine, son procede de preparation et son utilisation en tant que catalyseur, support de catalyseur ou adsorbant |
| FR9808089 | 1998-06-25 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2000044231A JP2000044231A (ja) | 2000-02-15 |
| JP2000044231A5 JP2000044231A5 (enExample) | 2006-08-10 |
| JP5026628B2 true JP5026628B2 (ja) | 2012-09-12 |
Family
ID=9527872
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP18024599A Expired - Lifetime JP5026628B2 (ja) | 1998-06-25 | 1999-06-25 | 新規アルミナ、その調製方法および触媒、触媒の担体または吸着剤としてのその使用 |
Country Status (7)
| Country | Link |
|---|---|
| EP (1) | EP0967177B1 (enExample) |
| JP (1) | JP5026628B2 (enExample) |
| BR (1) | BR9902622B1 (enExample) |
| CA (1) | CA2276558C (enExample) |
| DE (1) | DE69905423T2 (enExample) |
| DK (1) | DK0967177T3 (enExample) |
| FR (1) | FR2780392B1 (enExample) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102718236B (zh) * | 2012-05-10 | 2014-08-27 | 华东理工大学 | 一种叶片具有取向的分级结构活性氧化铝及其制备方法 |
| FR3084267B1 (fr) | 2018-07-25 | 2021-10-08 | Axens | Alumine a acidite et structure de porosite optimales |
| KR102317405B1 (ko) * | 2020-07-31 | 2021-10-28 | 한국에너지기술연구원 | 1차 알코올 탈수 반응용 촉매, 이의 제조방법 및 이를 이용한 알파-올레핀의 제조방법 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1009556A (en) * | 1961-12-26 | 1965-11-10 | Air Prod & Chem | Production of xylene |
| JPS51146393A (en) * | 1975-06-11 | 1976-12-15 | Nippon Mining Co Ltd | Process for production of finely divided bayerite |
| FR2518986B1 (fr) * | 1981-12-30 | 1985-09-06 | Criceram | Procede de preparation d'alumines de haute purete a partir de solutions impures de chlorure d'aluminium |
| CA1208141A (en) * | 1982-12-20 | 1986-07-22 | John P. Hogan | Removal of carbon dioxide from olefin containing streams |
| DE3675327D1 (de) * | 1985-10-21 | 1990-12-06 | Sumitomo Chemical Co | Verfahren zur herstellung von 5-aethyliden-2-norbornen. |
| JPH02137718A (ja) * | 1988-11-16 | 1990-05-28 | Toray Ind Inc | 遠赤外線放射材料 |
| JP3469285B2 (ja) * | 1993-11-08 | 2003-11-25 | 水澤化学工業株式会社 | 粒状アルミナの製造方法及び球状アルミナ粒子 |
| JPH0824642A (ja) * | 1994-07-20 | 1996-01-30 | Sumitomo Metal Mining Co Ltd | 脱硝触媒の製造方法およびこれにより得られた触媒による脱硝方法 |
| JPH1045412A (ja) * | 1996-07-31 | 1998-02-17 | Sumitomo Chem Co Ltd | 耐熱性遷移アルミナ及びその製造方法 |
| JP4021513B2 (ja) * | 1997-02-21 | 2007-12-12 | 水澤化学工業株式会社 | 超低嵩密度、高比表面積、高多孔性を有するアルミナ又はアルミナ水和物、その製造方法並びに用途 |
-
1998
- 1998-06-25 FR FR9808089A patent/FR2780392B1/fr not_active Expired - Lifetime
-
1999
- 1999-06-18 DK DK99401509T patent/DK0967177T3/da active
- 1999-06-18 DE DE69905423T patent/DE69905423T2/de not_active Expired - Lifetime
- 1999-06-18 EP EP99401509A patent/EP0967177B1/fr not_active Expired - Lifetime
- 1999-06-23 CA CA002276558A patent/CA2276558C/fr not_active Expired - Lifetime
- 1999-06-24 BR BRPI9902622-8A patent/BR9902622B1/pt not_active IP Right Cessation
- 1999-06-25 JP JP18024599A patent/JP5026628B2/ja not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| DE69905423D1 (de) | 2003-03-27 |
| CA2276558A1 (fr) | 1999-12-25 |
| CA2276558C (fr) | 2009-01-20 |
| DE69905423T2 (de) | 2003-07-17 |
| BR9902622B1 (pt) | 2011-11-01 |
| JP2000044231A (ja) | 2000-02-15 |
| DK0967177T3 (da) | 2003-04-22 |
| FR2780392A1 (fr) | 1999-12-31 |
| BR9902622A (pt) | 2000-04-11 |
| EP0967177A1 (fr) | 1999-12-29 |
| EP0967177B1 (fr) | 2003-02-19 |
| FR2780392B1 (fr) | 2000-08-25 |
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